CN107428132A - 可发光的复合玻璃板 - Google Patents
可发光的复合玻璃板 Download PDFInfo
- Publication number
- CN107428132A CN107428132A CN201780000399.5A CN201780000399A CN107428132A CN 107428132 A CN107428132 A CN 107428132A CN 201780000399 A CN201780000399 A CN 201780000399A CN 107428132 A CN107428132 A CN 107428132A
- Authority
- CN
- China
- Prior art keywords
- glass
- composite
- intermediate layer
- pane
- glass pane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/067—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
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- B32B17/10339—Specific parts of the laminated safety glass or glazing being colored or tinted
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- B60—VEHICLES IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B60Q—ARRANGEMENT OF SIGNALLING OR LIGHTING DEVICES, THE MOUNTING OR SUPPORTING THEREOF OR CIRCUITS THEREFOR, FOR VEHICLES IN GENERAL
- B60Q2400/00—Special features or arrangements of exterior signal lamps for vehicles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60Q—ARRANGEMENT OF SIGNALLING OR LIGHTING DEVICES, THE MOUNTING OR SUPPORTING THEREOF OR CIRCUITS THEREFOR, FOR VEHICLES IN GENERAL
- B60Q2400/00—Special features or arrangements of exterior signal lamps for vehicles
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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Abstract
本发明涉及复合玻璃板(10),其至少包含:‑外玻璃板(1)和内玻璃板(2),它们经由中间层(3)相互接合,和‑至少一根/束光散射的玻璃纤维(4),其适合于通过沿其延伸长度在其侧壁上的散射来发射光,其中所述玻璃纤维(4)部分地布置在所述中间层(3)和所述外玻璃板(1)之间和在所述中间层(3)和所述内玻璃板(2)之间,并且通过中间层(3)的至少一个开口(15)引导。
Description
本发明涉及一种可发光的复合玻璃板,特别是车辆的挡风玻璃、后窗玻璃、侧窗玻璃或车顶玻璃,以及它们的制造方法和它们的用途。
复合玻璃板由至少一个外玻璃板、内玻璃板和将外玻璃板与内玻璃板平面式接合的粘性中间层。典型的中间层在此是聚乙烯醇缩丁醛薄膜,其除了其粘合性能,还具有高的韧性和高的声阻尼。中间层阻止在损坏的情况下复合玻璃质玻璃板的崩解。该复合玻璃板仅获得裂纹,但保持形状稳定的。
复合玻璃板具有相对单层安全玻璃明显的优点:例如可通过复合玻璃板来实现高隔音,这例如对于将车辆内部空间与它们的外部环境的分离是特别有利的。因此,除了挡风玻璃,日益增多的机动车辆的侧窗玻璃也由复合玻璃制成。同时,复合玻璃板具有比单层安全玻璃更高的击穿抑制,和因此相对异物或盗窃企图的侵入是更稳定的。
DE 10 2005 036869 A1、WO 2008/061789 A1、WO 2007/077099 A1、US 2015/253486 A1和US 2013/299856 A1披露复合材料结构,其通过玻璃纤维布或玻璃纤维网可平面式发光。
本发明的目的是提供一种改进的复合玻璃板,其至少部分地可发光。发光应可简单且成本有利地整合到复合玻璃板中。
本发明的目的根据本发明由根据权利要求1的复合玻璃板实现。优选实施方案由从属权利要求得出。
根据本发明的复合玻璃板至少包含:
- 外玻璃板和内玻璃板,它们经由中间层相互接合,和
- 至少一根/束光散射的玻璃纤维,其适合于通过沿其延伸长度在其侧壁上的散射来发射光,
其中,玻璃纤维部分地布置在中间层和外玻璃板之间和在中间层和内玻璃板之间,和玻璃纤维由中间层的至少一个开口引导。
通过玻璃纤维在中间层的至少一个开口中的布置使玻璃纤维的位置相对于中间层是固定的,从而在复合玻璃板的制造和层压期间可避免玻璃纤维的滑移。
在一个有利的实施方案中,本发明的复合玻璃板是用于水陆空交通运输工具的窗玻璃,尤其是在火车、船只和机动车辆中例如作为挡风玻璃、后窗玻璃、侧窗玻璃和/或车顶玻璃,在建筑物中,特别是在通道区域、窗区域、屋顶区域或外墙区域中,家具和设备中作为内装部件。
在一个特别有利的实施方案中,本发明的复合玻璃板是层压侧窗玻璃,其设计用于优选可以打开的车辆的侧窗。可以打开的侧窗是指侧窗,其可通过侧窗玻璃基本上垂直移入车身门内打开和再次关闭。
术语外玻璃板和内玻璃板仅用于区分第一玻璃板和第二玻璃板。在使用复合玻璃板作为车辆玻璃板或作为建筑玻璃板的情况下,外玻璃板优选但非必须地朝向该复合玻璃板的外部空间和内玻璃板优选但非必须地朝向内部空间。
根据本发明的玻璃纤维是光散射的玻璃纤维,其通过散射而沿其延伸长度在其侧壁上发射光。这种玻璃纤维通常由至少一种玻璃纤维芯组成,该玻璃纤维芯被一个或多个包裹式围绕玻璃纤维芯布置的层包围。在这种情况下,包层通常具有众多散射中心,例如纳米孔或纳米颗粒。合适的光散射的玻璃纤维在本领域是公知的。在这里仅示例参阅在US2011/0122646 A1或US 2015/0131955 A1中提及的玻璃纤维。玻璃纤维的厚度通常为5微米至300微米,优选100微米至250微米。应当理解,玻璃纤维通过合适的制造或加工也仅可以具有部分光散射的区域。
在根据本发明的玻璃纤维的一个有利实施方案中,在其上该玻璃纤维在其侧壁上不间断发射光的延伸长度为至少5 cm,优选至少10 cm,且更优选至少30 cm。
术语光散射的玻璃纤维在本发明的范围中也指多根单独的玻璃纤维的束或网。在一个有利的实施方案中,本发明的复合玻璃板具有少于或等于50根/束单独的玻璃纤维,优选正好一根/束玻璃纤维,正好两根/束玻璃纤维,正好三根/束玻璃纤维,正好四根/束玻璃纤维,正好五根/束玻璃纤维,正好六根/束玻璃纤维,正好七根/束玻璃纤维,正好八根/束玻璃纤维,正好九根/束玻璃纤维或正好十根/束玻璃纤维。特别地,本发明的复合玻璃板不具有玻璃纤维网。所述1至50根/束的玻璃纤维优选各自独立地可控,即可各自独立地发光。所述1至50根/束的玻璃纤维优选并排布置。替代地,玻璃纤维可交叉,优选地每根/束玻璃纤维最多10次。在根据本发明的复合玻璃板的一个有利的实施方案中,玻璃纤维嵌入中间层的表面。这可能是在外玻璃板、中间层和内玻璃板的层压期间自动完成,因为在层压的温度和压力下外玻璃板和内玻璃板基本上是刚性的,而中间层是软的且柔性的。
开口在本发明的意义上优选是指中间层中的敞开处,其完整地被中间层包围。应当理解,在制成的层压的本发明复合玻璃板中,中间层可以封合该开口的敞开区域,从而使中间层直接接触通过中间层引导的玻璃纤维。中间层的开口这时则被玻璃纤维填充。
在本发明复合玻璃板的一个有利的实施方案中,开口是凹部,优选地是圆形、椭圆形、矩形或三角形的凹部、冲孔或槽缝,优选纵向于玻璃纤维的延伸方向的槽缝(简称:纵向槽缝)或横向于玻璃纤维的延伸方向的槽缝(简称:横向槽缝)。
在本发明复合玻璃板的一个有利的实施方案中,开口横向于玻璃纤维的延伸方向的宽度b为玻璃纤维的一倍直径d至最多40倍直径d。
在本发明复合玻璃板的一个有利的实施方案中,开口横向于玻璃纤维的延伸方向的宽度b为0.5 mm至10 mm,优选为1 mm至5 mm。
在本发明复合玻璃板的一个有利的实施方案中,所述中间层具有至少2个,优选3至100个开口,通过开口引导玻璃纤维。通过多个开口,使玻璃纤维更牢固地固定,和可以实现玻璃纤维的复杂线路。
在本发明复合玻璃板的一个有利的实施方案中,相邻开口之间的距离为0.5 cm至50 cm,优选为0.5 cm至20 cm,更优选为0.5 cm至5 cm,且特别是1 cm至3 cm。玻璃纤维是由相邻开口之间这样的距离牢固地固定并且可以实现玻璃纤维的复杂线路。
为进一步简化复合玻璃板的制造,玻璃纤维可以在压力和温度的作用下的层压之前固定在中间层的表面中。这具有特别的优点,即使得玻璃纤维在制造复合玻璃板期间在其相对于中间层的位置上额外地固定,从而避免滑移。压力和温度的作用可优选通过加热元件,优选钎焊烙铁,加热的压辊,热板,尤其是熨斗,或热空气流与压紧件组合地产生。
在根据本发明的复合玻璃板的另一个有利实施方案中,玻璃纤维通过至少一个紧固件与中间层、外玻璃板和/或内玻璃板接合。这具有特别的优点,即使得玻璃纤维在制造复合玻璃板期间在其相对于中间层的位置上额外地固定,从而避免滑移。紧固件优选是透明的,使得透过复合玻璃板的透视性不会或基本上不受损。
在根据本发明复合玻璃板的另一个特别有利的实施方案中,该紧固件是粘合剂,优选在施加时为液体的粘合剂,单面粘性的胶带(简称:单面胶带)或双面粘性的胶带(简称:双面胶带)。单面胶带或双面胶带由承载膜,优选塑料的承载膜构成,该承载膜单面或双面地具有粘合剂。
特别有利的粘合剂是丙烯酸酯粘合剂、甲基丙烯酸甲酯粘合剂、氰基丙烯酸酯粘合剂、多环氧化物、有机硅粘合剂和/或硅烷交联的聚合物粘合剂,它们的混合物和/或共聚物。
在一个备选的有利实施方案中,该紧固件是单丝线或编结线,优选为透明的线,特别优选塑料线和特别是聚酰胺(例如尼龙),聚乙烯(如Dyneema或Spectra)或聚芳酰胺(例如Kevlar)的线。这样的线具有典型的0.01 mm至2 mm,优选0.02 mm至0.1 mm的直径。
外玻璃板和/或内玻璃板优选包括玻璃,特别是钠钙玻璃,或塑料,优选为刚性塑料,特别是聚碳酸酯或聚甲基丙烯酸甲酯。玻璃板的厚度可变化很大,和因此出色地适应在各种情况下的要求。优选地,外玻璃板和内玻璃板的厚度为0.5 mm至10 mm,优选为1至5mm,更优选为1.4至3 mm。
外玻璃板、内玻璃板或中间层可以是透明和无色的,但也可以为着色的、混浊的或彩色的。外玻璃板和内玻璃板可由非预应力玻璃、部分预应力玻璃或预应力玻璃构成。外玻璃板和/或内玻璃板可在其一侧上具有遮盖印刷物,优选黑色印刷物,该印刷物例如遮盖玻璃板粘入房屋或车辆车身内的透视或其它布置在玻璃板内或玻璃板上的元件。遮盖印刷物可以是不透明的和整面式形成。可替代地,遮盖印刷物也可以是半透明的,例如形成为点网格、条网格或纹格网格。可替代地,遮盖印刷物也可具有梯度,例如由不透明覆盖到半透明覆盖。
在一个有利的实施方案中,本发明复合玻璃板至少部分地在外玻璃板上或在内玻璃板上具有遮盖印刷物和尤其是黑色印刷物,其中玻璃纤维至少部分地布置在遮盖印刷物的区域中。在不透明的遮盖印刷物的情况下,这具有特别的优点,即玻璃纤维和可能的紧固件不易被看到和同时通过玻璃纤维的发光仅在玻璃板的一个表面上,即,在所述外玻璃板的外侧表面上或在内玻璃板的内侧表面上可以看到。
所述中间层由至少一个热塑性接合薄膜构成。热塑性接合薄膜包含至少一种热塑性聚合物,优选乙烯醋酸乙烯酯(EVA),聚乙烯醇缩丁醛(PVB)或聚氨酯(PU),或它们的混合物或共聚物或衍生物。中间层和尤其是热塑性接合薄膜的厚度优选为0.2至2 mm,更优选0.3 mm至1 mm,例如0.38 mm或0.76 mm。
在另一个有利的实施方案中,本发明的复合玻璃板具有用于电加热所述复合玻璃板的加热件。优选的加热件在此是导电线和/或一个或多个可电加热的、透明的导电层。
本发明的复合玻璃板可以除了由加热件产生的加热功能还具有另外的功能性。在一个有利的实施方案中,复合玻璃板具有针对红外范围的反射涂层。这样的涂层可以施加到外玻璃板的表面上或内玻璃板的表面上,优选在朝向中间层的表面上,以保护涂层免受腐蚀和机械作用。可替代地,该涂层可以是以涂覆的热塑性薄膜的形式,例如由聚对苯二甲酸乙二醇酯(PET)构成,引入复合材料中。在这种情况下,经涂覆的薄膜优选布置在第一和第二热塑性接合薄膜之间。IR-反射涂层通常具有至少一个导电层。该涂层可以额外具有介电层,该介电层例如用于调节层电阻、防腐蚀或减弱反射。导电层优选包含银或导电氧化物(透明导电氧化物,TCO),如氧化铟锡(氧化铟锡,ITO)。导电层优选具有10 nm至200 nm的厚度。为了在同时高的透明度下提高导电率,所述涂层可具有多个导电层,它们通过至少一个介电层彼此分隔开。该导电涂层可以包含例如两个、三个或四个导电层。典型的介电层包含氧化物或氮化物,诸如氮化硅、氧化硅、氮化铝、氧化铝、氧化锌或氧化钛。应当理解,这些导电的透明涂层还可用于玻璃板的电加热。该涂层优选具有比复合玻璃板小的面积,以使宽度优选为0.5 mm至15 mm的周围边缘区域未设有所述涂层。导电涂层由此在中间层内受免于接触周围大气的保护,这对于避免腐蚀是有利的。复合玻璃板也可以包含另外的未涂覆区域,例如数据传输窗口或通讯窗口。
本发明的另一个方面是复合玻璃板装置,其至少包括:
- 本发明的复合玻璃板,和
- 发光物,其用于将光耦合(einkopplung)到玻璃纤维中。
所述发光物优选地布置在复合玻璃板的一个侧边缘处。在如可打开的侧窗玻璃的可移动的复合玻璃板的情况下,发光物优选与该复合玻璃板接合和同样布置成可移动的。应当理解,该发光物还可以独立于复合玻璃板安装并可经由优选非光散射的玻璃纤维与本发明的光散射的玻璃纤维接合。
有利的发光物是,例如激光二极管,发光二极管(LED)或灯泡,其中本发明包括适合于各自的用途的任何类型的光源。本发明的发光物还包括透镜系统、镜面系统、反射系统或其它光波导,其可用于将光耦合到本发明的玻璃纤维中。
该发光物可以是彩色或白色的。发光物也可以在紫外区域发射光,只要玻璃纤维或它们的环境可以将紫外光转换成可见光。优选的光的颜色是红色(由于突出的信号作用),绿色(由于人眼对绿色光谱高的敏感度)和蓝色(由于其特别的美学效果和较少的刺眼效果)。
应当理解,复合玻璃板可具有一根/束或多根/束玻璃纤维。在这种情况下,优选所有的玻璃纤维一起与发光物耦合或各玻璃纤维单独地与发光物耦合。所述一根/束玻璃纤维或所述多根/束玻璃纤维可以以任何技术上可能的每一种形式布置在复合玻璃板中,例如在边缘区域,在中间,直线的,弯曲的或作为标志或符号。
本发明的另一个方面是用于制造本发明复合玻璃板的方法,其至少包括:
(a)提供玻璃纤维、中间层、具有内侧表面II的外玻璃板和具有外侧表面III的内玻璃板,
(b)将至少一个开口引入中间层中和引导玻璃纤维通过所述开口,
(c)将所述中间层布置在所述外玻璃板和所述内玻璃板之间,
(d)经中间层通过层压将所述外玻璃板的内侧表面II与所述内玻璃板的外侧表面III接合。
层压用本领域技术人员已知的常规方法进行,例如高压釜法、真空袋法、真空环法、压延机法、真空层压机或它们的组合。外玻璃板和内玻璃板的接合在此通常在热、真空和/或压力的作用下进行。
在本发明方法的一个有利的扩展实施方案中,在步骤(b)中将所述开口冲压或冲压成形,优选借助针、冲孔器或合适成形的冲压工具。
在本发明方法的一个有利的扩展实施方案中,在步骤(b)中通过优选用解剖刀、刀刃、刀或激光切入所述中间层来制造所述开口。
本发明的另一个方面包括本发明的复合玻璃板在水陆空交通运输工具中,尤其是在火车、船只和机动车辆中例如作为挡风玻璃、后窗玻璃、侧窗玻璃和/或车顶玻璃,在建筑物中,特别是在通道区域、窗区域、屋顶区域或外墙区域中,家具和设备中作为内装部件的用途。
本发明的复合玻璃板特别优选是部分无框的窗玻璃,其中本发明的光散射的玻璃纤维布置在无框侧边缘的附近。光散射的玻璃纤维还可以布置在内侧边缘处,例如在从窗玻璃切出的部分的区域内,如车顶玻璃中的玻璃天窗中。
本发明的复合玻璃板优选形成为固定的窗玻璃,即,该窗玻璃是相对于它的环境固定布置的并例如通过部分的紧固固定,例如作为在车辆中的挡风玻璃或作为建筑物或家具中的分隔玻璃板。
本发明的复合玻璃板可选地形成为可移动的窗玻璃,即,该窗玻璃是相对于其环境可移动地布置的,例如作为可移动地布置在门内的窗玻璃如在车门内的侧窗玻璃。
本发明的另一个方面包括本发明的发光物在复合玻璃板装置中用于标示电功能,优选加热功能,本发明复合玻璃板的移动,优选可以打开或闭合的侧窗和/或作为警告功能,优选在打开的车门中的无框侧窗玻璃的用途。优选的用途包括复合玻璃板装置用于回家功能和/或离开家功能的用途。应当理解,标示发光物的电功能不仅是发光物的运行,还有其它的。
被称为回家功能(英语:“回家”)的通常是一种功能,其中在离开车辆后,车辆发光仍发光一定的时间,和然后自动关闭。这样做的目的是照亮从停车处到家门的路径,即使回家变得容易,以及在下车过程中使车辆保持较可见。
被称为离开家功能(英语:“离开家”)的通常是一种功能,其中,例如在打开车辆后通过远程遥控将车辆发光打开,用于将从家门至车的路径照亮。
以下参照附图和实施例进一步说明本发明。附图是示意性说明,而不完全符合规模。附图不以任何方式限制本发明。
在图中:
图1A是本发明复合玻璃板装置的一个实施方案的顶视图,
图1B是沿着剖面线A-A'通过图1A的复合玻璃板的横截面图,
图1C是图1A的局部Z的具有玻璃纤维的中间层的放大图,
图1D是沿图1C的局部Z的剖面线B-B'的横截面,
图1E是沿图1C的局部Z的剖面线B-B'的横截面,
图1F是层压后沿图1C的局部Z的剖面线B-B'的横截面,
图2A是本发明复合玻璃板装置的一个替代实施方案的顶视图,
图2B是沿剖面线A-A'通过图2A的复合玻璃板的横截面图,
图3A是本发明复合玻璃板装置的一个替代实施方案的顶视图,
图3B是沿剖面线A-A'通过图3A的复合玻璃板的横截面图,
图3C是图3A的局部Z的具有玻璃纤维的中间层的放大图,
图4是本发明方法的一个实施方案的流程图。
图1A示出本发明复合玻璃板装置100的顶视图,其包含本发明的复合玻璃板10和发光物20。图1B示出了沿着剖面线A-A'通过图1A的复合玻璃板10的横截面图。该复合玻璃板10在该实施例中被配置为轿车的车顶玻璃。
本发明的复合玻璃板10包含具有内侧表面II的外玻璃板1、具有外侧表面III的内玻璃板2和热塑性中间层3,该热塑性中间层将外玻璃板1的内侧表面II与内玻璃板2的外侧表面III经由玻璃板面彼此接合。外玻璃板1和内玻璃板2由例如钠钙玻璃制成,并具有例如各为1.5 mm的厚度。热塑性中间层3是例如由聚乙烯醇缩丁醛(PVB)制成的三层薄膜,其总厚度为0.86 mm。应当理解,其它的玻璃质玻璃板或聚合物玻璃板也可以用作外玻璃板和内玻璃板。此外,可以使外玻璃板1和内玻璃板2的厚度适应各自的用途。
根据本发明将玻璃纤维4部分地布置在外玻璃板1的内侧表面II和中间层3之间,且部分地布置在中间层3和内玻璃板2的外侧表面III之间。在图1B所示的截面中,在外玻璃板1的内侧表面II和中间层3之间布置玻璃纤维4。
玻璃纤维4具有例如200微米的直径d,并且对此适合于在其侧壁上沿其延伸长度发射光。光在此经玻璃纤维4的端面耦合入玻璃纤维4中。为此,将发光物20布置在玻璃纤维4的一端。所述发光物20由例如激光二极管组成,该激光二极管可例如经反射器将光耦合入玻璃纤维4中。在将电压施加到所述激光二极管的情况下,则使光耦合入玻璃纤维4中。玻璃纤维4随后在其表面上沿其整个延伸长度散射光,从而使玻璃纤维4在其整个延伸长度上发光。
图1C示出图1A的局部Z的具有玻璃纤维4的中间层3的放大图,在中间层3的朝向外玻璃板1的内侧表面II的侧面上的顶视图中。中间层3在该实施例中在局部Z中具有3个圆形开口15,这些开口例如通过冲压成形引入中间层3中。玻璃纤维4交替地从上至下和从下至上通过中间层3的开口15引导。应当理解,中间层3在在此示出的局部Z之外还具有另外的开口15,通过这些开口引导玻璃纤维4。这样的根据本发明的布置具有特别的优点,即该玻璃纤维4牢固地与中间层3接合和在本发明的复合玻璃板10的制造时在其位置相对于中间层3不能滑移。
图1D示出了层压之前具有本发明的复合玻璃板10的元件的局部Z。这些包括具有内侧表面II的外玻璃板1和具有外侧表面III的内玻璃板2以及玻璃纤维4和热塑性中间层3。为制造,例如首先将多个开口15引入中间层3。在示出的局部Z中,例如将三个开口15引入中间层3中。对于图1A的整个复合玻璃板10,例如将20个开口15引入中间层中。应当理解,可使开口15的数量任意地适应于各技术情况,如例如玻璃纤维4的刚性,所述玻璃纤维4在复合玻璃板10中所需的分布形状的曲率等。
开口15在此例如是圆形的,并且例如通过冲孔器冲压到中间层3中。应当理解,开口15也可以是槽缝形的,例如以纵向于玻璃纤维4的延伸方向的纵截面的形式,或以横向于玻璃纤维4的延伸方向的横截面的形式。应当理解,所述开口15的类型也可以变化,并且不同的开口类型可以组合。
在进一步的方法步骤中,玻璃纤维4引导通过中间层3的开口15。在此,玻璃纤维4部分地布置在中间层3的一侧上,和在引导通过开口15之后布置在所述中间层3的另一侧上。
应当理解,开口15的引入和玻璃纤维4通过中间层3的引导也可以交替进行。这意味着,首先将开口15引入中间层3中,和然后将玻璃纤维4通过开口15引导。随后将另一开口15引入中间层3中和将玻璃纤维4通过该另外的开口15引导,等等。
在进一步的方法步骤中,将中间层3连同穿入的玻璃纤维4布置在外玻璃板1和内玻璃板2之间。例如,在其中具有玻璃纤维4的中间层3布置在内玻璃板2的外侧表面III上(箭头P1)和然后将外玻璃板1以其内侧表面II布置在中间层3上(箭头P2)。应当理解,堆叠顺序也可以颠倒。
图1E示出了在层压之前沿如此制造的堆叠顺序的局部Z的剖面线B-B'的横截面。由于聚合物中间层3是柔性的,和玻璃质内玻璃板2和玻璃质外玻璃板1在很大程度上是刚性的,玻璃纤维4穿入中间层3的各自相邻表面的区域中。
在进一步的方法步骤中,外玻璃板1、中间层3和内玻璃板2在压力和温度的作用下通过层压接合。
图1F示出了在层压之后沿本发明的复合玻璃板10的局部Z的剖面线B-B'的横截面。通过在层压时的压力和温度的作用,所述热塑性中间层3被软化,从而使玻璃纤维4嵌入中间层3的表面。同时用中间层3的材料填充开口15,使得开口15在透过本发明的复合玻璃板10的透视中不再可见或基本上不可见。因此,开口15在最佳的情况下被减小到将玻璃纤维4在从中间层3的一侧引导至中间层3的相对侧所占用的空间。
图2A示出本发明的复合玻璃板装置100的顶视图,其包含本发明的复合玻璃板10和发光物20。图2B示出了沿着剖面线A-A'通过图2A的复合玻璃板10的横截面图。该复合玻璃板10在该实施例中设计为用于轿车的侧窗的侧窗玻璃。
本发明的复合玻璃板10包含具有内侧表面II的外玻璃板1、具有外侧表面III的内玻璃板2和热塑性中间层3,该热塑性中间层将外玻璃板1的内侧表面II与内玻璃板2的外侧表面III经由玻璃板面彼此接合。外玻璃板1和内玻璃板2由例如钠钙玻璃制成,并具有例如各为2.1 mm的厚度。热塑性中间层3是例如由聚乙烯醇缩丁醛(PVB)制成的薄膜,其厚度为0.76 mm。应当理解,其它的玻璃质玻璃板或聚合物玻璃板也可以用作外玻璃板和内玻璃板。此外,可以使外玻璃板1和内玻璃板2的厚度适应各自的用途。
在此同样地,玻璃纤维4引导通过中间层的开口15。局部Z和制造方法的示例性详细说明在图1C至1F中和相关联的说明中示出。
光散射的玻璃纤维4具有例如200微米的直径d,并且对此适合于在其侧壁上沿其延伸长度发射光。光在此经玻璃纤维4的端面耦合入玻璃纤维4中。为此,将发光物20布置在玻璃纤维4的一端。所述发光物20由例如激光二极管组成,该激光二极管可例如经反射器将光耦合入玻璃纤维4中。在将电压施加到所述激光二极管的情况下,则使光耦合入玻璃纤维4中。玻璃纤维4在其表面上沿其整个延伸长度散射光,从而使玻璃纤维4在其整个延伸长度上发光。
该复合玻璃板10在此例如是轿车车门的侧窗玻璃,和玻璃纤维4布置在复合玻璃板10的前面和 上面的侧边缘6的附近。车门内的侧窗玻璃的镶边例如是无框的,使只有在其下侧引导侧窗玻璃,并插入到车门内。发光物20在此例如是高性能的发光二极管。
用该复合玻璃板10制造的复合玻璃板装置100例如如此配置,使得所述发光物20在车门打开时被启用和使玻璃纤维4发光。这具有特别的优点,即车门在打开状态下发光,并且对于其它道路使用者特别容易辨识。这种发光的复合玻璃板10的可见性在黑暗中特别增强 - 尤其是因为该复合玻璃板10在该实施例中是无框的,和仅以其下侧边缘固定在车门中。通过玻璃纤维4发光的复合玻璃板10的侧边缘因此是不受限且无阻碍可见的。
发光物20可以在此是纯色或通过不同的颜色标示各种状态。例如,对于红色的发光物警告功能是特别高的,因为红色通常与危险相关联。绿色的发光物在黑暗中特别容易辨识,因为人眼对绿色光谱具有特别高的敏感度。
在进一步的示例性实施方案中,发光物20例如具有红色的发光二极管和蓝色的发光二极管。该复合玻璃板装置100在此是例如这样与车辆电子设备连接,使得经由电动窗玻璃升降器打开复合玻璃板10时,玻璃纤维4以蓝光发光和在复合玻璃板10闭合时,玻璃纤维4以红光发光。这具有特别的优点,即由此复合玻璃板10相对于门框的移动方向可见和人员可快速辨识身体部位或物体被夹入闭合的窗口的危险。应当理解,其它颜色或白光可用于使玻璃纤维4发光。此外,其它功能也可经由复合玻璃板10的发光显示或尤其可以实现美学发光。
本发明复合玻璃板10可任选地具有额外的电功能,且例如具有电加热功能。在此可例如布置在此未示出的加热件,如加热丝或加热层在所述外玻璃板1和内玻璃板2之间的区域中。这样的加热丝由例如铜或钨制成,并且具有例如30微米的厚度。作为加热层,例如透明的导电涂层是已知的,如上例如进行了说明。加热丝和加热层可例如通过汇流排,例如厚度为例如100微米和宽度为例如7 mm的铜箔条形成。当在汇流排上施加电压时,电流流过加热丝或加热层,从而产生加热作用。该电压可以是14V的通用的KFZ-车载电压,或例如42V或48V的电压。应当理解,所述电压也可以是例如110V或220V的通用的电源电压,特别是当在建筑工业中使用根据本发明的复合玻璃板10时,如透明的加热体。该复合玻璃板10的相应的加热程度进而可以经由玻璃纤维4的发光通过发光物20显示。
图3A示出了替代的本发明的复合玻璃板装置100的顶视图,其包括替代的本发明的复合玻璃板10和发光物20。图3B示出沿剖面线A-A'通过图3A的复合玻璃板10的横截面图。该复合玻璃板10在该实施例中设计为轿车的挡风玻璃。
本发明的复合玻璃板10包含具有内侧表面II的外玻璃板1、具有外侧表面III的内玻璃板2和热塑性中间层3,该热塑性中间层将外玻璃板1的内侧表面II与内玻璃板2的外侧表面III经由玻璃板面彼此接合。外玻璃板1和内玻璃板2由例如钠钙玻璃制成,并具有例如各为2.1 mm的厚度。热塑性中间层3是例如由聚乙烯醇缩丁醛(PVB)制成的薄膜,其厚度为0.76 mm。应当理解,其它的玻璃质玻璃板或聚合物玻璃板也可以用作外玻璃板1和内玻璃板2。此外,可以使外玻璃板1和内玻璃板2的厚度适应各自的用途。
在该实施例中,在外玻璃板1和内玻璃板2之间布置两个光散射的玻璃纤维4。在此,玻璃纤维4也通过中间层3的开口15引导。
图3C示出中间层3的局部Z的示例性详细示图,其具有由图3A中的局部Z的玻璃纤维4。开口15在这里例如形成为横向于玻璃纤维4的延伸方向的槽缝。槽缝的宽度b为例如5mm。进一步的制造方法例如在图1D至1F和相关联的描述中示出。
光散射的玻璃纤维4具有各为150微米的直径d,并且对此适合于在其侧壁上沿其延伸长度发射光。光在此经玻璃纤维4的端面耦合入玻璃纤维4中。为此,将发光物20布置在各玻璃纤维4的一端。所述发光物20由例如激光二极管组成,该激光二极管可例如经反射器将光耦合入玻璃纤维4中。在将电压施加到所述激光二极管的情况下,则使光耦合入玻璃纤维4中。然后玻璃纤维4在其表面上沿其整个延伸长度散射光,从而使玻璃纤维4在其整个延伸长度上发光。
复合玻璃板10在该实施例中在内玻璃板2的外侧表面III的周围边缘区域上具有不透明遮盖印刷物7,例如陶瓷颜色的黑色印刷物,其通过烧制与内玻璃板2的玻璃质表面III牢固接合。遮盖印刷物7的目的在于,遮盖将复合玻璃板10粘入车身中所用的粘合位点的透视性。同时,保护粘合位点免受光照射,尤其是UV光照射,这些照射会导致粘合位点的加速老化。
玻璃纤维4在该实施例中框形布置在复合玻璃板10的边缘区域中。与侧边缘6的距离是例如1 cm至20 cm。
玻璃纤维4在这里例如布置在由内玻璃板2的内侧表面IV被遮盖印刷物7遮盖的区域中。这意味着,从车辆内部空间不能看到玻璃纤维4。特别地,在玻璃纤维4的侧壁处发出的光也到不了车辆内部空间,使得内部人员由此不会被刺眼或干扰。
发光物20在此是例如高性能的激光二极管。用该复合玻璃板10制造的复合玻璃板装置100例如如此构造,使得发光物20在车门上锁或解锁时使玻璃纤维4发光一段时间,例如1分钟。这可独立地或与其它车辆发光同时进行。这样的发光可被例如借助无线电接收器进行上锁和解锁的人员用作明确的信号,该车辆已经可靠地上锁或解锁。在同一时间可以因此实现回家或离开家功能。
发光物20可以是纯色或通过不同的颜色标示各种状态。不同的颜色在此可使车辆的上锁与解锁可见地容易区分开。若玻璃纤维4的发光用作警告功能,可例如使用红色或橙色的发光物,因为红色或橙色通常与危险相关联。绿色的发光物在黑暗中特别容易辨识,因为人眼对绿色光谱具有特别高的敏感度。
应当理解,所述玻璃纤维4不必或不必仅沿玻璃板的一个侧边缘布置,而是可以任意布置。特别地,一根/束或多根/束玻璃纤维4可以以符号的形式,例如警告三角形的形式布置,或形成标志。
还应当理解,玻璃纤维4可以具有这样的区域,其中光可以在玻璃纤维4的侧壁上发出,从而可以使彼此无关联的符号发光。
还应当理解,在所有本发明的实施例中可以在中间层3和玻璃板1、2之一之间布置另外的在此未示出的中间层。特别有利的是,中间层3不具有粘合性质,如PET-薄膜,其经由另外的中间层,例如PVB-薄膜与玻璃板1、2粘合。玻璃纤维4然后例如通过中间层3或其它中间层的开口引导。
图4示出了用于制造本发明复合玻璃板10的本发明方法的一个实施例的流程图。本发明的方法例如包括以下步骤:
(a)提供玻璃纤维4、热塑性中间层3、具有内侧表面II的外玻璃板1和具有外侧表面III的内玻璃板2,
(b)将至少一个开口15引入中间层3中和引导玻璃纤维4通过所述开口15,
(c)将所述中间层3布置在所述外玻璃板1和所述内玻璃板2之间,
(d)经中间层3通过层压将所述外玻璃板1的内侧表面II与所述内玻璃板2的外侧表面III接合。
附图标记:
1 外玻璃板
2 内玻璃板
3 中间层,热塑性中间层
4 玻璃纤维
6 侧边缘
7 遮盖印刷物
10 复合玻璃板
15 开口
20 发光物
100 复合玻璃板装置
b 开口15的宽度
d 光散射的玻璃纤维4的直径
A-A' 剖面线
B-B' 剖面线
P1, P2 箭头
Z 局部
I 外玻璃板1的外侧表面
II 外玻璃板1的内侧表面
III 内玻璃板2的外侧表面
IV 内玻璃板2的内侧表面
Claims (15)
1.复合玻璃板(10),其至少包含:
- 外玻璃板(1)和内玻璃板(2),它们经由中间层(3)相互接合,和
- 至少一根/束光散射的玻璃纤维(4),其适合于通过沿其延伸长度在其侧壁上的散射来发射光,
其中所述玻璃纤维(4)部分地布置在所述中间层(3)和所述外玻璃板(1)之间和在所述中间层(3)和所述内玻璃板(2)之间,并且通过中间层(3)的至少一个开口(15)引导。
2.根据权利要求1的复合玻璃板(10),其中将所述玻璃纤维(4)嵌入所述中间层(3)的表面。
3.根据权利要求1和2之一的复合玻璃板(10),其中所述开口(15)是圆形、椭圆形、矩形或三角形的凹部、冲孔或槽缝,优选纵向槽缝或横向槽缝。
4.根据权利要求1至3中任一项的复合玻璃板(10),其中开口(15)横向于玻璃纤维(4)的延伸方向的宽度b为玻璃纤维(4)的一倍直径d至最多40倍直径d。
5.根据权利要求1至3中任一项的复合玻璃板(10),其中开口(15)横向于玻璃纤维(4)的延伸方向的宽度b为0.5 mm至10 mm,优选为1 mm至5 mm。
6.根据权利要求1至5中任一项的复合玻璃板(10),其中所述玻璃纤维(4)通过至少2个,优选通过3至100个开口(15)引导。
7.根据权利要求1至6中任一项的复合玻璃板(100),其中相邻开口(15)的距离为0.5cm至50 cm,优选为0.5 cm至20 cm,更优选为0.5 cm至5 cm,且特别是1 cm至3 cm。
8.复合玻璃板装置(100),其包含:
- 根据权利要求1至7中任一项的复合玻璃板(10),和
- 用于将光耦合入玻璃纤维(4)的发光物(20)。
9.根据权利要求8的复合玻璃板装置(10),其中所述发光物(20)包括至少一个激光二极管或至少一个发光二极管。
10.用于制造根据权利要求1至7中任一项的复合玻璃板(10)的方法,其至少包括:
(a)提供玻璃纤维(4)、热塑性中间层(3)、具有内侧表面(II)的外玻璃板(1)和具有外侧表面(III)的内玻璃板(2),
(b)将至少一个开口(15)引入中间层(3)中和引导玻璃纤维(4)通过所述开口(15),
(c)将所述中间层(3)布置在所述外玻璃板(1)和所述内玻璃板(2)之间,
(d)经中间层(3)通过层压将所述外玻璃板(1)的内侧表面(II)与所述内玻璃板(2)的外侧表面(III)接合。
11.根据权利要求10的方法,其中在步骤(b)中将所述开口(15)冲压成形,优选借助针或冲孔器。
12.根据权利要求10的方法,其中在步骤(b)中通过优选用解剖刀、刀刃、刀或激光切入所述中间层(3)来制造所述开口(15)。
13.根据权利要求10至12中任一项的方法,其中在步骤(b)中引入横向于玻璃纤维(4)的延伸方向的宽度b为0.5 mm至10 mm,优选为1 mm至5 mm的开口(15)。
14.根据权利要求1至7中任一项的复合玻璃板(10)或根据权利要求8或9的复合玻璃板装置(100)在水陆空交通运输工具中,尤其是在火车、船只和机动车辆中例如作为挡风玻璃、后窗玻璃、侧窗玻璃和/或车顶玻璃,在建筑物中,特别是在通道区域、窗区域、屋顶区域或外墙区域中,家具和设备中作为内装部件的用途。
15.发光物(20)在根据权利要求8或9的复合玻璃板装置(100)中用于标示电功能,优选加热功能和/或复合玻璃板(10)的移动,优选可打开或闭合的侧窗的复合玻璃板(10)的移动,用于标示位置,作为警告功能或用于另外的信号发出,尤其是用于指示建筑物或车辆的门和/或窗的上锁或解锁,或作为回家功能和/或离开家功能的用途,其中所述电功能不是所述发光物本身的运行。
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| BR112016028344B1 (pt) * | 2014-07-01 | 2021-07-27 | Saint-Gobain Glass France | Painel lateral laminado aquecível, método para produzir um painel lateral e uso de um painel lateral |
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2017
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- 2017-03-06 MA MA045885A patent/MA45885A/fr unknown
- 2017-03-06 KR KR1020187017794A patent/KR102134710B1/ko active Active
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