CN107407056A - wrapping paper - Google Patents
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- CN107407056A CN107407056A CN201680011852.8A CN201680011852A CN107407056A CN 107407056 A CN107407056 A CN 107407056A CN 201680011852 A CN201680011852 A CN 201680011852A CN 107407056 A CN107407056 A CN 107407056A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/12—Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/14—Polyalkenes, e.g. polystyrene polyethylene
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/02—Patterned paper
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
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- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
- Wrappers (AREA)
- Buffer Packaging (AREA)
Abstract
Description
技术领域technical field
本发明涉及包装用纸,详细而言,涉及由施有白水印的图案纸形成的包装用纸。The present invention relates to packaging paper, and specifically relates to packaging paper formed of white watermarked design paper.
背景技术Background technique
施有水印图案的图案纸根据其外观特征被广泛用于包装用、装饰用、印刷用等领域。施在纸上的水印图案有图案部分透出可见的“白水印”和图案部分比周围黑而可见的“黑水印”。这些水印图案通常在抄纸工序中的湿纸形成阶段(造纸机网部)通过使纸浆的单位面积重量部分地发生变化而形成。造纸机网部中,使用施有凸模的图案的抄纸网时,对湿纸中与该凸模的图案部分对应的部分实施厚度比周边部薄的压模,该经压模的部分成为将该湿纸干燥而得到的纸中的白水印。另外,作为白水印的其他形成方法,还已知对在造纸机网部形成的湿纸(纸浆单位面积重量均一的湿纸)按压在外表面施有凸模的图案的压辊等按压手段的该外表面,从而将该图案转印到湿纸而赋形的方法。Design paper on which a watermark pattern is applied is widely used in fields such as packaging, decoration, and printing due to its appearance characteristics. The watermark pattern applied on the paper has a "white watermark" in which the pattern part is visible and a "black watermark" in which the pattern part is darker than the surrounding and is visible. These watermark patterns are usually formed by partially changing the basis weight of pulp in the wet paper formation stage (paper machine wire section) in the papermaking process. In the paper machine wire section, when using a papermaking wire with a pattern of a punch, the part of the wet paper corresponding to the pattern of the punch is molded with a thickness thinner than the peripheral part, and the pressed part becomes The white watermark in the paper obtained by drying this wet paper. In addition, as other methods of forming white watermarks, there are also known press means such as press rollers that press a pattern of a punch on the outer surface of wet paper (wet paper with a uniform pulp basis weight) formed on the wire section of a paper machine. The outer surface, so that the pattern is transferred to the wet paper to form the method.
专利文献1中公开了带白水印的防伪用纸。该带白水印的防伪用纸通过将对天然纸浆和聚烯烃系纤维混合抄纸而得到的纸用抄纸后的机外加工进行热压处理而得到,白水印通过在该热压处理下聚烯烃系纤维软化熔融而形成。Patent Document 1 discloses anti-counterfeiting paper with a white watermark. The anti-counterfeit paper with white watermark is obtained by heat-pressing the paper obtained by mixing papermaking of natural pulp and polyolefin-based fibers after papermaking. Olefin fibers are softened and melted.
专利文献patent documents
专利文献1:日本特开2005-330622号公报Patent Document 1: Japanese Patent Laid-Open No. 2005-330622
发明内容Contents of the invention
发明所要解决的课题The problem to be solved by the invention
本发明涉及在迎着光时水印部与非水印部处产生对比度,水印部清晰可见、设计性优异、并且缓冲性也优异的包装用纸。The present invention relates to a packaging paper having a contrast between a watermark portion and a non-watermark portion when exposed to light, the watermark portion is clearly visible, excellent in design, and excellent in cushioning properties.
用于解决课题的手段means to solve the problem
本发明的包装用纸为将天然纸浆与烯烃系合成纸浆混合抄纸而得到的包装用纸,其具有透光率比周边部高的水印部,该水印部不存在纸浆或者纸浆比周边部少。The packaging paper of the present invention is a packaging paper obtained by mixing natural pulp and olefin-based synthetic pulp, and has a watermark portion having a higher light transmittance than the peripheral portion, and the watermark portion does not have pulp or has less pulp than the peripheral portion .
另外,本发明的包装用纸的制造方法为上述本发明的包装用纸的制造方法,其具有从上述天然纸浆及上述合成纸浆的分散液中将两纸浆抄出形成湿纸、然后将该湿纸干燥的工序,在干燥前的该湿纸中形成有不存在纸浆或者纸浆比周边部少的部分。Moreover, the manufacturing method of the packaging paper of this invention is the manufacturing method of the said packaging paper of this invention, It comprises making both pulp from the dispersion liquid of the said natural pulp and the said synthetic pulp to form wet paper, and then making this wet paper In the drying step, the wet paper before drying has a portion where there is no pulp or less pulp than the peripheral portion.
上述本发明的包装用纸的制造方法中,湿纸中的“不存在纸浆或者纸浆比周边部少的部分”优选在湿纸的形成工序中、通过有目的地阻碍上述水印部的形成预定部分中的纸浆的堆积来形成。In the method for producing packaging paper according to the present invention, it is preferable that the "portion where there is no pulp or pulp is less than the peripheral portion" in the wet paper be formed by purposely blocking the portion to be formed of the watermark portion during the wet paper forming process. Formed by the accumulation of pulp in it.
发明效果Invention effect
根据本发明,提供在迎着光时水印部与非水印部处产生对比度、水印部清晰可见、设计性优异、并且缓冲性也优异的包装用纸。According to the present invention, there is provided a packaging paper that produces a contrast between the watermarked portion and the non-watermarked portion when exposed to light, the watermarked portion is clearly visible, has excellent designability, and is also excellent in cushioning properties.
附图说明Description of drawings
图1中,图1(a)为实施例1的包装用纸的照片、图1(b)为比较例1的包装用纸的照片。In FIG. 1 , FIG. 1( a ) is a photograph of the packaging paper of Example 1, and FIG. 1( b ) is a photograph of the packaging paper of Comparative Example 1.
具体实施方式detailed description
本发明的包装用纸通过将天然纸浆与烯烃系合成纸浆混合抄纸而得到。本发明中,作为天然纸浆,主要使用针叶树漂白硫酸盐纸浆(NBKP)、阔叶树漂白硫酸盐纸浆(LBKP)、针叶树漂白亚硫酸盐纸浆(NBSP)等木材漂白化学纸浆,根据需要使用碎木纸浆(GP)、热磨机械纸浆(TMP)、化学热磨机械纸浆(BCTMP)等机械纸浆;麻、竹、稻草、洋麻、结香、楮、棉花等非木材纸浆;废纸纸浆。本发明中,可以将这些天然纸浆1种单独使用或者将2种以上组合使用。The packaging paper of the present invention is obtained by mixing natural pulp and olefin-based synthetic pulp to produce paper. In the present invention, as natural pulp, wood bleached chemical pulps such as conifer bleached kraft pulp (NBKP), broadleaf bleached kraft pulp (LBKP), and conifer bleached sulfite pulp (NBSP) are mainly used, and groundwood pulp ( GP), thermomechanical pulp (TMP), chemical thermomechanical pulp (BCTMP) and other mechanical pulp; non-wood pulp such as hemp, bamboo, straw, kenaf, knotwood, mulberry, and cotton; waste paper pulp. In this invention, these natural pulps can be used individually by 1 type or in combination of 2 or more types.
本发明中使用的天然纸浆的JIS P8121中规定的加拿大标准游离度(CanadianStandard freeness)优选为100~500ml、进一步优选为250~400ml。游离度是表示纸浆打浆(在水存在下对纸浆进行机械敲打、磨碎的处理)的程度的值,通常游离度的值越小,打浆的程度越强,打浆对纤维的损伤越大、纤丝化进行。天然纸浆的游离度在上述范围内时,包装用纸的单位面积重量降低、液体透过性提高等各特性的平衡变得良好。游离度的调整、即纸浆的打浆程度的调整可通过对打浆装置的种类、处理条件(纸浆浓度、温度、压力、转速、刀的形状、处理次数等)进行适当调整来进行。作为打浆装置,可以使用公知的装置,例如除了打浆机、PFI磨、单盘盘磨机、双盘盘磨机等打浆机之外,还可以使用颜料等的分散、粉碎中使用的球磨机、DYNO-MILL等分散机。The Canadian standard freeness (Canadian Standard freeness) stipulated in JIS P8121 of the natural pulp used in the present invention is preferably 100 to 500 ml, more preferably 250 to 400 ml. Freeness is a value indicating the degree of pulp beating (mechanical beating and grinding of pulp in the presence of water). Usually, the smaller the value of freeness, the stronger the degree of beating, and the greater the damage of beating to fibers. Filamentation proceeds. When the freeness of the natural pulp is within the above range, the balance of various properties such as a reduction in the basis weight of the packaging paper and an improvement in liquid permeability becomes good. Adjustment of freeness, that is, adjustment of pulp beating degree can be performed by appropriately adjusting the type of beating device and processing conditions (pulp concentration, temperature, pressure, rotation speed, shape of blade, number of processing, etc.). As the beating device, known devices can be used. For example, in addition to beating machines such as a beating machine, a PFI mill, a single-disk mill, and a double-disk mill, a ball mill used for dispersing and pulverizing pigments, etc., and DYNO can also be used. -Dispersing machines such as MILL.
作为构成本发明中使用的烯烃系合成纸浆的烯烃系树脂,可列举出例如聚乙烯、聚丙烯等。Examples of the olefin-based resin constituting the olefin-based synthetic pulp used in the present invention include polyethylene, polypropylene, and the like.
本发明中使用的烯烃系合成纸浆从确保实用上充分的纸力等观点出发,优选与天然纸浆同样地进行了纤丝化的纸浆。烯烃系合成纸浆的纤丝化可以采用与天然纸浆的纤丝化同样的方法进行。本发明中使用的烯烃系合成纸浆的游离度优选为100~700ml、进一步优选为300~600ml。The olefin-based synthetic pulp used in the present invention is preferably fibrillated like natural pulp from the viewpoint of securing practically sufficient paper strength. Fibrillation of olefin-based synthetic pulp can be performed by the same method as fibrillation of natural pulp. The freeness of the olefin-based synthetic pulp used in the present invention is preferably 100 to 700 ml, more preferably 300 to 600 ml.
作为本发明中优选使用的市售的烯烃系合成纸浆,可列举出三井化学株式会社制的SWP(注册商标)。该SWP为经纤丝化的烯烃系合成纸浆。Mitsui Chemicals, Inc. SWP (registered trademark) is mentioned as a commercially available olefin-based synthetic pulp preferably used in this invention. This SWP is a fibrillated olefin-based synthetic pulp.
另外,本发明中使用的烯烃系合成纸浆的纤维长度优选为0.1~2.0mm、进一步优选为0.5~1.5mm。烯烃系合成纸浆的纤维长度在该范围内时,在通过湿式造纸法制造包装用纸时的抄纸工序中的造纸机网部,排水提高,易于形成水印部。In addition, the fiber length of the olefin-based synthetic pulp used in the present invention is preferably 0.1 to 2.0 mm, more preferably 0.5 to 1.5 mm. When the fiber length of the olefin-based synthetic pulp is within this range, water drainage is improved in the paper machine wire section in the papermaking process when packaging paper is produced by the wet papermaking method, and watermarks are easily formed.
本发明的包装用纸中根据需要可含有除天然纸浆及烯烃系合成纸浆以外的其他成分,例如淀粉、聚丙烯酰胺、聚胺聚酰胺环氧氯丙烷等纸力增强剂或固着剂、施胶剂、填料、滤水助留剂、耐水化剂、固着剂、消泡剂、杀粘菌剂等在湿式造纸法中通常使用的添加剂中的1种或2种以上。The packaging paper of the present invention may contain other components other than natural pulp and olefin-based synthetic pulp as required, such as paper strength enhancers such as starch, polyacrylamide, polyamine polyamide epichlorohydrin, or fixing agents, sizing agents, etc. One or more of the additives commonly used in the wet papermaking process, such as additives, fillers, drainage and retention aids, water-resistant agents, fixing agents, defoamers, and slimeicides.
本发明的包装用纸具有透光率比周边部高的水印部。本发明的水印部为不存在纸浆或纸浆比周边部(非水印部)少的部分,换言之,为将包装用纸沿厚度方向贯通的贯通孔或纸浆的堆积量比周边部(非水印部)少的低纸浆堆积部,在透射光下观察时,为比周边部明亮、通透可见的所谓的白水印。本发明的包装用纸中,水印部的俯视形状、大小、数量、形成样式(pattern)等没有特殊限制,可以根据用途等适当调整。作为本发明的包装用纸的一个例子,可列举出多个水印部以规定的样式形成,各水印部被非水印部包围的形态。水印部可以仅为贯通孔、也可仅为低纸浆堆积部,也可包含两者,作为此种情况的一个例子,可列举出包含将包装用纸沿厚度方向贯通的贯通孔、和包围该贯通孔且纸浆的堆积量比周边部少的低纸浆堆积部而构成的水印部。另一方面,水印部的周边部即非水印部为纸浆的堆积量比水印部多的高纸浆堆积部,是不使光透射或透光率比水印部低的部位。The packaging paper of the present invention has a watermark portion having a higher light transmittance than the peripheral portion. The watermark portion of the present invention is a portion where there is no pulp or less pulp than the peripheral portion (non-watermark portion), in other words, it is a through hole that penetrates the packaging paper in the thickness direction or the amount of pulp accumulated is lower than that of the peripheral portion (non-watermark portion). The few low-pulp accumulation parts are so-called white watermarks that are brighter and transparent than the peripheral parts when viewed under transmitted light. In the wrapping paper of the present invention, the plan view shape, size, number, pattern, etc. of the watermark portion are not particularly limited, and may be appropriately adjusted according to applications. An example of the wrapping paper of the present invention includes a form in which a plurality of watermark portions are formed in a predetermined pattern, and each watermark portion is surrounded by a non-watermark portion. The watermark portion may be only a through hole, or only a low pulp accumulation portion, or both. As an example of this case, a through hole that penetrates the packaging paper in the thickness direction, and a The watermark part is composed of a low pulp accumulation part with a through hole and less pulp accumulation than the peripheral part. On the other hand, the non-watermarked portion, which is the peripheral portion of the watermarked portion, is a high pulp accumulation portion having a larger amount of pulp accumulation than the watermarked portion, and is a portion that does not transmit light or has a light transmittance lower than that of the watermarked portion.
根据本发明者们的认知,包含天然纸浆和烯烃系合成纸浆的带白水印的纸与包含天然纸浆但不包含烯烃系合成纸浆的通常的纸相比,在迎着光时水印部与非水印部的对比度更为明显,因此能够给予观察者宛如水印部浮起这样的印象,因此水印部清晰、设计性高。即,烯烃系合成纸浆发挥使纸的不透明度提高、使白水印清晰可见的效果。另外通常,烯烃系合成纸浆与天然纸浆相比纤维长度短且排水性好,其结果当将具有这样的特性的烯烃系合成纸浆用作纤维原料时,在将包装用纸通过湿式造纸法制造时的抄纸工序中的造纸机网部中,能够容易地在湿纸上形成贯通孔或低纸浆堆积部,因此还具有水印部的形成容易的优点。本发明的包装用纸正是基于这样的认知而完成的发明。According to the knowledge of the present inventors, compared with normal paper containing natural pulp but not containing olefin-based synthetic pulp, the white-watermarked paper containing natural pulp and olefin-based synthetic pulp has a watermark portion that is different from that of non-olefin-based synthetic pulp when exposed to light. Since the contrast of the watermark is more conspicuous, the observer can have the impression that the watermark is floating, so the watermark is clear and has high designability. That is, olefin-based synthetic pulp exhibits the effect of increasing the opacity of paper and making white watermarks visible. In addition, in general, olefin-based synthetic pulp has shorter fiber length and better drainage than natural pulp. In the wire part of the paper machine in the papermaking process, through holes or low pulp accumulation parts can be easily formed on the wet paper, so there is also an advantage that the formation of the watermark part is easy. The wrapping paper of the present invention is an invention based on such knowledge.
本发明的包装用纸的JIS P8149中规定的不透明度〔除水印部以外的部分(非水印部)的不透明度〕优选为35~80%、进一步优选为40~65%。包装用纸的不透明度可通过对烯烃系合成纸浆的种类、含量进行适当调整来调整。The opacity [opacity of the portion other than the watermark portion (non-watermark portion)] specified in JIS P8149 of the packaging paper of the present invention is preferably 35 to 80%, more preferably 40 to 65%. The opacity of packaging paper can be adjusted by appropriately adjusting the type and content of olefin-based synthetic pulp.
另外,作为烯烃系合成纸浆的其他作用效果,还有提高缓冲性的效果。即,包含天然纸浆和烯烃系合成纸浆的本发明的包装用纸与包含天然纸浆但不包含烯烃系合成纸浆的通常的纸相比,具有低密度且缓冲性高的特长,因此适于充分利用其缓冲性的物品的包装用途。In addition, as another function and effect of olefin-based synthetic pulp, there is an effect of improving cushioning properties. That is, the packaging paper of the present invention comprising natural pulp and olefin-based synthetic pulp has the characteristics of low density and high cushioning properties compared to ordinary paper comprising natural pulp but not olefin-based synthetic pulp, and thus is suitable for making full use of It is used for packaging of cushioning items.
本发明的包装用纸的密度优选为0.2~0.6g/cm3、进一步优选为0.3~0.5g/cm3。另外,将本发明的包装用纸通过后述的1)或2)的方法(在干燥前的湿纸上形成贯通孔或低纸浆堆积部的方法)进行制造时,即湿纸中的“不存在纸浆或纸浆比周边部少的部分”(湿纸在干燥后成为水印部的部分)在湿纸的形成工序中,通过有目的地阻碍水印部的形成预定部分中的纸浆的堆积来形成时,如此得到的包装用纸中的水印部的密度与其周边的非水印部相同或更低。与此相对,专利文献1记载的纸中的水印部(白水印)由于通过抄纸后的机外加工的热压处理使聚烯烃系纤维软化熔融来形成,因此推测其密度比周边的非水印部高。The density of the packaging paper of the present invention is preferably 0.2 to 0.6 g/cm 3 , more preferably 0.3 to 0.5 g/cm 3 . In addition, when the packaging paper of the present invention is produced by the method of 1) or 2) described later (the method of forming through-holes or low-pulp accumulation parts in the wet paper before drying), that is, the "no pulp" in the wet paper Pulp is present or a portion with less pulp than the peripheral portion" (a portion of wet paper that becomes a watermark after drying) is formed by deliberately inhibiting the accumulation of pulp in a portion to be formed of a watermark in the wet paper forming process , the density of the watermark portion in the packaging paper thus obtained is the same as or lower than that of the surrounding non-watermark portion. In contrast, the watermark portion (white watermark) in the paper described in Patent Document 1 is formed by softening and melting polyolefin-based fibers through hot-press treatment in the external processing after papermaking, so it is presumed that its density is higher than that of the surrounding non-watermark. department high.
另外,专利文献1记载的纸通过对纸浆的单位面积重量均一的纸的一部分实施热压处理而形成水印部,由于其制造方法,热压处理形成的水印部和其周边未实施热压处理的非水印部在纸浆的量上没有实质变化。关于这点,本发明的水印部如前所述,为不存在纸浆或纸浆比周边部(非水印部)少的部分,与将干燥的纸通过热压处理而形成的水印部不仅在密度方面而且在纸浆的量方面都是不同的。这样的纸浆的量相对少的水印部无法通过纸的热压处理形成,而是如后所述,通过在湿纸的形成工序中有目的地阻碍水印部的形成预定部分中的纸浆的堆积来形成。In addition, in the paper described in Patent Document 1, the watermark portion is formed by subjecting a part of the paper having a uniform basis weight of the pulp to a heat press treatment. Due to its manufacturing method, the watermark portion formed by the heat press treatment and its surrounding areas are not subjected to heat press treatment. There was no substantial change in the amount of pulp in the non-watermarked portion. In this regard, the watermark portion of the present invention is a portion where there is no pulp or less pulp than the peripheral portion (non-watermark portion) as described above. And they are all different in terms of the amount of pulp. Such a watermark with a relatively small amount of pulp cannot be formed by hot pressing of paper, but as described later, it can be formed by deliberately preventing the accumulation of pulp in the part where the watermark is to be formed in the wet paper forming process. form.
另外,如专利文献1中记载的那样,通过热压处理形成的水印部也决定于热压处理的条件,但通常在热压处理下烯烃系合成纸浆熔融软化,因此无法维持纤维形态,与周边的未实施热压处理的非水印部相比,纤维间空隙小、根据情况纤维间空隙基本完全消失而可可能为薄膜样的膜状的形态。关于这点,未经热压处理的本发明的水印部的纤维形态得以维持,与周边部的非水印部相比,作为纤维集合体的形态并没有实质上的不同。In addition, as described in Patent Document 1, the watermark formed by hot-pressing treatment also depends on the conditions of the hot-pressing treatment, but usually the olefin-based synthetic pulp melts and softens under the hot-pressing treatment, so the fiber shape cannot be maintained, and the surrounding Compared with the non-watermarked part that has not been subjected to hot pressing treatment, the interfiber voids are smaller, and in some cases the interfiber voids almost completely disappear, and may be in a film-like film-like form. In this regard, the fiber shape of the watermarked portion of the present invention that has not been subjected to hot-pressing treatment is maintained, and there is no substantial difference in the shape of the fiber assembly compared with the non-watermarked portion of the peripheral portion.
包装用纸的缓冲性可用包装用纸的压缩强度来评价,压缩强度的数值越大,该包装用纸的缓冲性的评价越高。但是,压缩强度的数值过大时,由于包装用纸的刚性增加,因此包装用纸难以追随被包装物的形状,有作为包装用纸的功能降低的担忧。考虑到以上情况,本发明的包装用纸的压缩强度优选为0.2~0.9、进一步优选为0.4~0.6。包装用纸的压缩强度(缓冲性)可通过对烯烃系合成纸浆的种类、含量进行适当调整来调整。另外,为了将包装用纸的压缩强度调整到上述范围,如后所述,在将包装用纸通过湿式造纸法进行制造时的抄纸工序中,优选对将湿纸干燥而得到的纸(包装用纸)不进行按压。The cushioning properties of the packaging paper can be evaluated by the compressive strength of the packaging paper, and the larger the numerical value of the compressive strength, the higher the evaluation of the cushioning properties of the packaging paper. However, when the numerical value of the compressive strength is too large, since the rigidity of the packaging paper increases, it is difficult for the packaging paper to follow the shape of the object to be packaged, and there is a possibility that the function as the packaging paper may be reduced. In consideration of the above, the compressive strength of the wrapping paper of the present invention is preferably 0.2 to 0.9, more preferably 0.4 to 0.6. The compressive strength (cushioning property) of packaging paper can be adjusted by appropriately adjusting the type and content of olefin-based synthetic pulp. In addition, in order to adjust the compressive strength of the packaging paper to the above-mentioned range, as described later, in the papermaking process when the packaging paper is produced by the wet papermaking method, it is preferable to dry the paper obtained by drying the wet paper (packaging paper) without pressing.
使用公知的KES压缩试验机测定“包装用纸的压缩硬度”,通过从1中减去该测定值来算出包装用纸的压缩强度。即,“压缩强度=1-压缩硬度”,压缩硬度的数值越大、该包装用纸的压缩强度(缓冲性)越为低评价。使用了KES压缩试验机的压缩硬度的测定方法为用圆形平面(2cm2)测定将测定对象(包装用纸)压缩时的应力的方法,压缩硬度用压缩的直线性表示,其数值越接近1,则表示测定对象越硬。The "compression hardness of the packaging paper" was measured using a known KES compression tester, and the compression strength of the packaging paper was calculated by subtracting the measured value from 1. That is, "compression strength=1-compression hardness", the larger the numerical value of the compression hardness, the lower the compression strength (cushioning property) of the packaging paper is evaluated. The compression hardness measurement method using the KES compression tester is a method of measuring the stress when the measurement object (packaging paper) is compressed with a circular plane (2cm 2 ). The compression hardness is expressed by the linearity of compression. The closer the value is to 1 means that the measured object is harder.
对压缩强度的测定方法更具体地进行说明。测定中使用的KES压缩试验机具备与测定对象的接触部分的面积为2cm2的金属制加压子,作为这样构成的KES压缩试验机,可列举出例如具备圆板状的金属制加压子的、Kato Tech株式会社制的商品名“KES-G5”。将测定对象(包装用纸)固定在KES压缩试验机的样品载置台上,从该测定对象的上方将加压子以规定的压入速度向测定对象的厚度方向以规定的压力压入,测定此时应力的最大值。使加压子的压入速度在0.0067~0.02mm/秒、压入压力为50~500gf/cm2的范围内。对测定对象的面积为100cm2的各区域在任意3处实施该最大应力的测定,将如此得到的多个测定值的平均值作为测定对象的压缩硬度,通过下式算出测定对象的压缩强度。The method of measuring the compressive strength will be described more specifically. The KES compression testing machine used in the measurement is equipped with a metal pressure element with an area of 2 cm 2 in contact with the measurement object. As a KES compression testing machine configured in this way, for example, a disc-shaped metal pressure element is provided. The brand name "KES-G5" manufactured by Kato Tech Co., Ltd. Fix the measurement object (packaging paper) on the sample mounting table of the KES compression testing machine, press the pressure member from above the measurement object at a predetermined speed into the thickness direction of the measurement object with a predetermined pressure, and measure The maximum stress at this time. The pressing speed of the presser is 0.0067-0.02mm/sec, and the pressing pressure is within the range of 50-500gf/cm 2 . The measurement of the maximum stress is carried out at any three places in each area of the measurement object with an area of 100 cm 2 , and the average value of a plurality of measured values obtained in this way is regarded as the compression hardness of the measurement object, and the compressive strength of the measurement object is calculated by the following formula.
压缩强度=1-压缩硬度Compressive strength = 1 - compressive hardness
缓冲性(压缩强度)或纸力等作为包装用纸的重要特性受到其包装用纸所具有的水印部的样式的不小影响。即,包装用纸的压缩强度可因其包装用纸中的水印部的俯视形状、大小、数量等而变动。特别是,如单位面积重量为30g/m2以下这样的低单位面积重量的包装用纸对缓冲性或纸力具有正向作用的纸浆的绝对量少,因此该包装用纸中的水印部的样式对缓冲性等的影响不可忽视。而且,本发明的水印部如前所述,为不存在纸浆或纸浆比周边部(非水印部)少的部分,其结果为了进一步确实地满足作为包装用纸的重要特性,这样纸浆相对少的部分与在包装用纸中局部存在相比,更优选在包装用纸整体中离散或散点状地存在。Important properties of packaging paper such as cushioning properties (compressive strength) and paper strength are largely influenced by the pattern of the watermark portion of the packaging paper. That is, the compressive strength of the wrapping paper may vary depending on the planar shape, size, number, etc. of the watermark portions in the wrapping paper. In particular, packaging paper with a low basis weight of 30 g /m or less has a small absolute amount of pulp that has a positive effect on cushioning properties or paper strength, so the watermark portion in the packaging paper The effect of style on cushioning etc. cannot be ignored. Furthermore, the watermark portion of the present invention, as described above, is a portion where there is no pulp or less pulp than the peripheral portion (non-watermark portion). It is more preferable to partially exist in a discrete or scattered point form in the entire wrapping paper than to exist locally in the wrapping paper.
本发明中,对水印部的样式没有特殊限制,例如可以是从包装用纸的一端到另一端连续的线状那样、“未被非水印部包围的形状”(非闭合的形状)的水印部多个离散地存在的形态,但考虑到缓冲性等包装用纸的重要特性,优选“多个水印部散点状存在于包装用纸整体、且各水印部被非水印部包围即形成闭合的形状的样式”。后述的各实施例的包装用纸为该优选的水印部的样式的具体表现。各水印部的俯视形状没有特殊限制,可以从圆形状、椭圆形状、三角形形状、四边形以上的多边形形状、直线或曲线等线状等中任意地选择,另外还可以将俯视形状不同的2种以上组合。In the present invention, there is no particular limitation on the pattern of the watermark portion, and for example, the watermark portion may be a “shape not surrounded by a non-watermark portion” (non-closed shape) such as a continuous line from one end to the other end of the wrapping paper. A plurality of discrete forms, but in consideration of the important characteristics of packaging paper such as cushioning, it is preferable that "a plurality of watermarks are scattered in the entire packaging paper, and each watermark is surrounded by a non-watermark, that is, closed. Shape Style". The wrapping paper of each Example described later is a concrete representation of the pattern of the preferred watermark portion. The top view shape of each watermark portion is not particularly limited, and can be arbitrarily selected from a circle shape, an ellipse shape, a triangle shape, a polygon shape larger than a quadrilateral, a straight line or a curve, etc., and two or more different top view shapes can also be used. combination.
从确实地满足缓冲性等作为包装用纸的重要特性的观点出发,包装用纸中的1个水印部的面积优选为1.5cm2以下、进一步优选为0.01~1.0cm2。The area of one watermark portion in the packaging paper is preferably 1.5 cm 2 or less, more preferably 0.01 to 1.0 cm 2 , from the viewpoint of reliably satisfying important properties of packaging paper such as cushioning properties.
另外从同样的观点出发,1个水印部的面积在上述优选的范围内时,包装用纸的每100cm2面积的水印部的数量优选为5个以上、进一步优选为10~600个。From the same viewpoint, when the area of one watermark is within the above preferred range, the number of watermarks per 100 cm 2 area of the packaging paper is preferably 5 or more, more preferably 10 to 600.
另外从同样的观点出发,相邻的水印部之间的中心间的距离(水印部的间距)优选为1~50mm、进一步优选为3~30mm。From the same viewpoint, the distance between the centers of adjacent watermarks (the pitch of the watermarks) is preferably 1 to 50 mm, more preferably 3 to 30 mm.
另外,从更确实地发挥前文所述的烯烃系合成纸浆的作用效果的观点出发,本发明的包装用纸中的烯烃系合成纸浆的含量相对于该包装用纸中的天然纸浆100质量份,优选为1~70质量份、进一步优选为5~40质量份。烯烃系合成纸浆相对于天然纸浆的含量过少时,有无法充分获得前文所述的烯烃系合成纸浆的作用效果的担忧,当烯烃系合成纸浆相对于天然纸浆的含量过多时,有片材强度变弱、无法获得作为包装纸所需的强度的担忧。In addition, from the viewpoint of more reliably exerting the effect of the above-mentioned olefin-based synthetic pulp, the content of the olefin-based synthetic pulp in the packaging paper of the present invention is 100 parts by mass of the natural pulp in the packaging paper, Preferably it is 1-70 mass parts, More preferably, it is 5-40 mass parts. When the content of olefin-based synthetic pulp is too small relative to natural pulp, there is a concern that the effect of the above-mentioned olefin-based synthetic pulp cannot be sufficiently obtained. When the content of olefin-based synthetic pulp is too large relative to natural pulp, the sheet strength may be reduced Weak and unable to obtain the strength required as wrapping paper.
本发明的包装用纸可以通过公知的湿式造纸法制造,具体而言经过下述工序进行制造:使用抄纸网从天然纸浆及合成纸浆的分散液中将两纸浆抄出形成湿纸,然后将该湿纸干燥。上述水印部、即将包装用纸沿厚度方向贯通的贯通孔或纸浆的堆积量比周边部少的低纸浆堆积部可通过向使湿纸干燥而得到的纸按压外表面施有凹凸图案的辊的该外表面进行赋形,对该纸转印该凹凸图案进行赋形的方法(干压图案法)来形成,但在这样的按压干燥的纸的方法中,有前文所述的烯烃系合成纸浆带来的缓冲性提高的效果降低的担忧。因此,从确实地得到缓冲性优异的包装用纸的观点出发,优选在干燥前的湿纸上形成不存在纸浆或纸浆比周边部少的部分(贯通孔或低纸浆堆积部)。湿纸上形成的贯通孔或低纸浆堆积部在将该湿纸干燥而得到的纸(包装用纸)中成为水印部(白水印)。The packaging paper of the present invention can be produced by a known wet papermaking method, specifically, through the following steps: using a papermaking wire to draw out both pulps from a dispersion of natural pulp and synthetic pulp to form wet paper, and then Wet paper to dry. The above-mentioned watermark portion, that is, the through hole through which the packaging paper penetrates in the thickness direction, or the low pulp accumulation portion in which the amount of pulp accumulation is smaller than that of the peripheral portion can be obtained by pressing a roller with a concave-convex pattern on the outer surface of the paper obtained by drying the wet paper. The outer surface is shaped, and the concave-convex pattern is transferred to the paper and shaped (dry press pattern method). There is a concern that the effect of cushioning improvement is reduced. Therefore, from the viewpoint of reliably obtaining packaging paper excellent in cushioning properties, it is preferable to form a portion (through-hole or low-pulp accumulation portion) where no pulp exists or less pulp than the peripheral portion on the wet paper before drying. The through-holes and low-pulp accumulation portions formed in the wet paper serve as watermarks (white watermarks) in paper (packaging paper) obtained by drying the wet paper.
作为在湿纸上形成贯通孔或低纸浆堆积部的方法(抑制烯烃系合成纸浆带来的缓冲性提高的效果降低的方法),可列举出例如1)将安装有与贯通孔或低纸浆堆积部(包装用纸中的水印部)对应的凹凸部的抄纸网、或者对准贯通孔或低纸浆堆积部将网孔用树脂等塞住的抄纸网用作圆网造纸机的圆网圆筒或长网造纸机的水印辊的上网等,从天然纸浆及合成纸浆的分散液中将两纸浆抄出形成湿纸的方法、2)将从天然纸浆及合成纸浆的分散液中用长网造纸机、圆网造纸机等公知造纸机的造纸机网部抄出而形成的湿纸用外表面具有与贯通孔或低纸浆堆积部对应的凹凸部的辊(压辊、吸引辊等)的该外表面按压的方法。上述2)的方法由于将湿纸部分地按压,因此有在将其干燥而得到的包装用纸中其被按压部的缓冲性降低的担忧,因此优选尽可能减小按压湿纸时的压力(压辊等按压手段的线压)。与此相对,上述1)的方法、即部分地阻碍或限制湿纸形成时纸浆的堆积、形成预先形成有贯通孔或低纸浆堆积部的湿纸的方法由于没有缓冲性降低的担忧,因此在本发明中优选使用。As a method of forming through-holes or low-pulp accumulation parts in wet paper (a method of suppressing the decrease in the effect of improving cushioning properties by olefin-based synthetic pulp), for example, 1) combining with through-holes or low-pulp accumulation parts The papermaking wire with the concave and convex part corresponding to the part (watermark part in packaging paper), or the papermaking wire with the through hole or the low pulp accumulation part and plug the mesh with resin, etc. is used as the cylinder of the cylinder paper machine The watermarking roll of the cylinder or fourdrinier paper machine, etc., the method of copying the two pulps from the dispersion liquid of natural pulp and synthetic pulp to form wet paper, 2) using the fourdrinier wire from the dispersion liquid of natural pulp and synthetic pulp Rolls (press rolls, suction rolls, etc.) having concave and convex portions on the outer surface corresponding to through holes or low pulp accumulation portions for wet paper formed by paper machine wires of known paper machines such as paper machines and cylinder paper machines. The method of pressing the outer surface. In the method of 2) above, since the wet paper is partially pressed, there is a concern that the cushioning properties of the pressed portion in the packaging paper obtained by drying it may be reduced. Therefore, it is preferable to reduce the pressure when pressing the wet paper as much as possible ( Line pressure of pressing means such as pressure roller). In contrast, the method of 1) above, that is, the method of partially inhibiting or restricting the accumulation of pulp during wet paper formation, and the method of forming wet paper with through holes or low pulp accumulation parts formed in advance, has no risk of reducing cushioning properties, so it is used in It is preferably used in the present invention.
本发明的包装用纸的单位面积重量没有特殊限制,本发明的包装用纸由于具有“形成低单位面积重量,其结果,即使该包装用纸的不透明性降低,在迎着光时水印部与非水印部的对比度明显、水印部清晰可见”的特征,因此从充分发挥该特征的观点出发,优选较低的单位面积重量,具体而言,优选为30g/m2以下、进一步优选为10~25g/m2。The weight per unit area of the packaging paper of the present invention is not particularly limited, and the packaging paper of the present invention has "a low basis weight, as a result, even if the opacity of the packaging paper is reduced, the watermark and The contrast of the non-watermarked part is obvious, and the watermarked part is clearly visible". Therefore, from the viewpoint of fully utilizing this feature, a lower basis weight is preferred. Specifically, it is preferably 30 g/ m2 or less, and more preferably 10 to 10 g/m2. 25g/m 2 .
本发明的包装用纸可以着色为任意颜色,可以为单层结构,也可以为多层层叠而成的多层结构。多层结构时,优选各层抄合而一体化。另外,多层结构时,可以在多层的全部或仅一部分中形成水印部,一个层中的水印部与其他层中的水印部在俯视下可以重叠。The packaging paper of the present invention may be colored in any color, and may have a single-layer structure or a multi-layer structure in which multiple layers are laminated. In the case of a multilayer structure, it is preferable that each layer is laminated and integrated. In addition, in the case of a multi-layer structure, the watermark portion may be formed in all or only a part of the layers, and the watermark portion in one layer may overlap with the watermark portion in another layer in plan view.
实施例Example
以下,举出实施例对本发明更详细地进行说明,但本发明并不受以下实施例的限制。Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to the following examples.
〔实施例1〕[Example 1]
作为天然纸浆使用NBKP。将NBKP用双盘盘磨机打浆至加拿大标准游离度达到400ml,相对于NBKP100质量份,向其中添加烯烃系合成纸浆(三井化学株式会社制的SWP(注册商标)、品名“E620”)40质量份,制备纸料。使用该纸料,用圆网造纸机按照上述1)的方法得到单位面积重量为17g/m2的单层结构且无着色的包装用纸。得到的包装用纸如图1(a)所示,大量散在地形成了不存在纸浆或纸浆比周边部少的水印部。更具体而言,被非水印部包围的闭合形状的水印部为散点状存在于包装用纸整体的样式,1个水印部的面积为0.04cm2、每100cm2面积的水印部的数量为311个、邻接的水印部之间的间距平均为7mm。NBKP was used as natural pulp. NBKP was beaten with a double-disk refiner until the Canadian standard freeness reached 400 ml, and 40 parts by mass of olefin-based synthetic pulp (SWP (registered trademark) manufactured by Mitsui Chemicals, Inc., product name "E620") was added to 100 parts by mass of NBKP. copies, prepare paper stock. Using this paper stock, according to the method of above-mentioned 1) with cylinder paper machine, obtain the packaging paper with unit area weight of 17g/m 2 single-layer structure and no coloring. In the obtained packaging paper, as shown in FIG. 1( a ), a large number of scattered watermarks were formed with no pulp or less pulp than the peripheral portion. More specifically, the closed-shaped watermark portion surrounded by the non-watermark portion is in the form of scattered dots throughout the packaging paper, the area of one watermark portion is 0.04 cm 2 , and the number of watermark portions per 100 cm 2 area is The average pitch between 311 adjacent watermark portions is 7 mm.
〔实施例2〕[Example 2]
相对于NBKP100质量份添加5质量份的烯烃系合成纸浆,除此以外,与实施例1同样地操作,得到单位面积重量为17g/m2的单层结构且无着色的包装用纸。Except for adding 5 parts by mass of olefin-based synthetic pulp to 100 parts by mass of NBKP, it was carried out in the same manner as in Example 1 to obtain a packaging paper with a single-layer structure and no coloring having a basis weight of 17 g/m 2 .
〔实施例3〕[Example 3]
相对于NBKP100质量份添加10质量份的烯烃系合成纸浆,除此以外,与实施例1同样地操作,得到单位面积重量17g/m2的单层结构且无着色的包装用纸。Except for adding 10 parts by mass of olefin-based synthetic pulp to 100 parts by mass of NBKP, it was carried out in the same manner as in Example 1 to obtain a single-layer structure with a basis weight of 17 g/m 2 and a non-colored packaging paper.
〔实施例4〕[Example 4]
相对于NBKP100质量份添加20质量份的烯烃系合成纸浆,除此以外,与实施例1同样地操作,得到单位面积重量17g/m2的单层结构且无着色的包装用纸。Except for adding 20 parts by mass of olefin-based synthetic pulp to 100 parts by mass of NBKP, it was carried out in the same manner as in Example 1 to obtain a single-layer structure with a basis weight of 17 g/m 2 and an uncolored packaging paper.
〔实施例5〕[Example 5]
除了使单位面积重量为30g/m2以外,与实施例1同样地操作,得到单层结构且无着色的包装用纸。Except that the weight per unit area was 30 g/m 2 , it was carried out in the same manner as in Example 1 to obtain a packaging paper with a single-layer structure and no coloring.
〔比较例1〕[Comparative Example 1]
除了不使用烯烃系合成纸浆以外,与实施例1同样地操作,得到单位面积重量为17g/m2的单层结构且无着色的包装用纸。Except not using olefin-based synthetic pulp, it was carried out in the same manner as in Example 1 to obtain a single-layer packaging paper with a basis weight of 17 g/m 2 and no coloring.
〔比较例2〕[Comparative Example 2]
将水印部按照专利文献1的方法、即通过对将湿纸干燥而得到的纸以规定的样式实施热压处理的方法来形成,除此以外,与实施例1同样地操作,得到单位面积重量为17g/m2的单层结构且无着色的包装用纸。更具体而言,使用与实施例1相同的纸料,通过圆网造纸机制造单位面积重量均一的纸,对该纸以与实施例1的水印部样式相同的样式实施加热温度为140℃、加热时间为4秒的热压处理,形成水印部。通过热压处理形成的水印部由于其中存在的烯烃系合成纸浆在热压处理下发生熔融软化,因此与周边的非水印部相比,纸浆的量没有实质上的差异,但是密度高且纤维形态未能维持。The watermark portion was formed in accordance with the method of Patent Document 1, that is, by applying hot pressing to paper obtained by drying wet paper in a predetermined pattern, except that it was performed in the same manner as in Example 1 to obtain the basis weight It is a 17g/m 2 single-layer structure and non-colored packaging paper. More specifically, using the same paper stock as in Example 1, paper with a uniform weight per unit area was produced by a cylinder paper machine, and the paper was heated in the same pattern as the watermark part in Example 1. The heating temperature was 140 ° C. The watermark portion was formed by hot pressing with a heating time of 4 seconds. The watermarked portion formed by hot-pressing treatment has an olefin-based synthetic pulp that is melted and softened under hot-pressing treatment, so there is no substantial difference in the amount of pulp compared with the surrounding non-watermarked part, but the density is high and the fiber shape failed to maintain.
对各实施例及比较例的包装用纸分别按照上述方法评价不透明度及压缩强度。将其结果示于下表1中。The opacity and compressive strength of the packaging papers of the respective examples and comparative examples were evaluated according to the above-mentioned methods. The results are shown in Table 1 below.
表1Table 1
如表1所示,各实施例的包装用纸由于在天然纸浆外还包含烯烃系合成纸浆,因此与不包含烯烃系合成纸浆的比较例1的包装用纸相比,非水印部的不透明度高且压缩强度即缓冲性高。如前文所述,当非水印部的不透明度高时,由于包装用纸在迎着光时水印部与非水印部的对比度变得明显,因此发挥水印部浮起的视觉效果,水印部清晰可见、设计性提高。实际上,如图1所示,实施例1的包装用纸(参照图1(a))与比较例1的包装用纸(参照图1(b))相比,水印部与非水印部的对比度明显,水印部清晰可见。As shown in Table 1, since the packaging paper of each example contains olefin-based synthetic pulp in addition to natural pulp, the opacity of the non-watermarked part is lower than that of the packaging paper of Comparative Example 1 that does not contain olefin-based synthetic pulp. High compressive strength, that is, high cushioning. As mentioned above, when the opacity of the non-watermark part is high, the contrast between the watermark part and the non-watermark part becomes obvious when the packaging paper faces the light, so the visual effect of the watermark part floating is exerted, and the watermark part is clearly visible , Improved design. In fact, as shown in FIG. 1, the packaging paper of Example 1 (see FIG. 1(a)) compared with the packaging paper of Comparative Example 1 (see FIG. 1(b)), the watermark portion and the non-watermark portion The contrast is obvious, and the watermark is clearly visible.
从以上内容可知,为了得到设计性及缓冲性优异的带水印部的包装用纸,将天然纸浆与烯烃系合成纸浆混合抄纸是有效的。As can be seen from the above, in order to obtain packaging paper with a watermark portion excellent in designability and cushioning properties, it is effective to make paper by mixing natural pulp and olefin-based synthetic pulp.
另外,比较例2在水印部通过热压处理形成这点上与实施例1不同,其结果由于该制造方法的差异,在比较例2中水印部与周边的非水印部(非热压处理部)处的纸浆量实质上相同,这点与水印部不存在纸浆或纸浆比周边部少的实施例1的构成不同。另外,比较例2由于水印部经过热压处理,因此无法维持纤维形态,这点与水印部的纤维形态得以维持、纤维形态与非水印部实质上相同的实施例1的构成不同。而且,实施例1与比较例2尽管水印部的样式相同,但是如表1所示,在压缩强度方面可见显著差异,为实施例1的缓冲性更为优异的结果。In addition, Comparative Example 2 is different from Example 1 in that the watermark portion is formed by thermal pressing. ) is substantially the same amount of pulp, which is different from the configuration of Example 1 in which there is no pulp in the watermark portion or less pulp than in the peripheral portion. In addition, Comparative Example 2 is different from the configuration of Example 1 in which the fiber form of the watermark is maintained and the fiber form is substantially the same as that of the non-watermark, since the watermark is heat-pressed, so the fiber form cannot be maintained. Furthermore, although the pattern of the watermark portion is the same between Example 1 and Comparative Example 2, as shown in Table 1, there is a significant difference in compressive strength, which is the result that Example 1 is more excellent in cushioning properties.
由以上内容可知,为了获得缓冲性高的带水印的包装用纸,优选水印部不存在纸浆或纸浆比周边部(非水印部)少,或者优选在水印部中维持纤维形态。From the above, in order to obtain a watermarked packaging paper with high cushioning properties, it is preferable that there is no or less pulp in the watermarked portion than in the peripheral portion (non-watermarked portion), or that the watermarked portion maintains a fibrous form.
Claims (4)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015-038896 | 2015-02-27 | ||
| JP2015038896 | 2015-02-27 | ||
| PCT/JP2016/055858 WO2016136954A1 (en) | 2015-02-27 | 2016-02-26 | Wrapping paper |
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| Publication Number | Publication Date |
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| CN107407056A true CN107407056A (en) | 2017-11-28 |
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| CN201680011852.8A Pending CN107407056A (en) | 2015-02-27 | 2016-02-26 | wrapping paper |
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| JP (1) | JP6781691B2 (en) |
| CN (1) | CN107407056A (en) |
| TW (1) | TW201641780A (en) |
| WO (1) | WO2016136954A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110344284A (en) * | 2018-04-04 | 2019-10-18 | 特种东海制纸株式会社 | Printing |
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| JP7728320B2 (en) * | 2023-12-14 | 2025-08-22 | 日本製紙株式会社 | Packaging substrate, packaging material, and method for manufacturing packaging material |
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| JP2005041012A (en) * | 2003-07-23 | 2005-02-17 | Mitsui Chemicals Inc | Film for in-mold label and container using it |
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- 2016-02-26 JP JP2017502515A patent/JP6781691B2/en not_active Expired - Fee Related
- 2016-02-26 WO PCT/JP2016/055858 patent/WO2016136954A1/en not_active Ceased
- 2016-02-26 TW TW105106091A patent/TW201641780A/en unknown
- 2016-02-26 CN CN201680011852.8A patent/CN107407056A/en active Pending
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| CN1207784A (en) * | 1996-01-12 | 1999-02-10 | 波特尔斯有限公司 | Bond paper |
| CN101748660A (en) * | 2008-12-01 | 2010-06-23 | 中国印钞造币总公司 | Anti-counterfeit water marked paper and manufacturing method thereof |
| CN102400420A (en) * | 2010-09-16 | 2012-04-04 | 保定钞票纸业有限公司 | Anti-counterfeiting paper with wide multi-layer white watermark and manufacturing method thereof |
| CN102296485A (en) * | 2011-08-22 | 2011-12-28 | 保定钞票纸业有限公司 | Watermarked paper having multiple observed effects, and preparation method thereof |
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| CN110344284A (en) * | 2018-04-04 | 2019-10-18 | 特种东海制纸株式会社 | Printing |
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| JPWO2016136954A1 (en) | 2017-12-07 |
| JP6781691B2 (en) | 2020-11-04 |
| TW201641780A (en) | 2016-12-01 |
| WO2016136954A1 (en) | 2016-09-01 |
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