CN107346803A - The manufacture method of silicon substrate backboard light-emitting diode display - Google Patents
The manufacture method of silicon substrate backboard light-emitting diode display Download PDFInfo
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Abstract
本发明提供了一种硅基背板LED显示器的制造方法,包括步骤:提供硅基背板;在硅基背板上形成基板光学对位标志;提供第一掩膜板;在所述第一掩膜板上形成第一掩膜板光学对位标志,以及多个第一通孔组成第一通孔阵列;将第一掩膜板与硅基背板临时键合;从第一掩膜板上表面上方通过所述第一通孔将第一LED发射层沉积于硅基背板上表面所暴露的多个第一子像素区域所构成的第一子像素区域阵列内;解除第一掩膜板下表面与硅基背板上表面的临时键合,并移开第一掩膜板;在硅基背板上表面形成透明的密封封盖。该方法有助于进一步缩小硅基背板多原色LED发光阵列像素矩阵显示器的像素尺寸,使得硅基背板有源矩阵OLED微显示器向高像素密度多色混合的方向发展成为可能。
The invention provides a method for manufacturing an LED display with a silicon-based backplane, comprising the steps of: providing a silicon-based backplane; forming a substrate optical alignment mark on the silicon-based backplane; providing a first mask; The first mask plate optical alignment mark is formed on the mask plate, and a plurality of first through holes form a first through hole array; the first mask plate is temporarily bonded to the silicon-based backplane; from the first mask plate Depositing the first LED emission layer on the upper surface of the upper surface through the first through hole in the first sub-pixel region array formed by the plurality of first sub-pixel regions exposed on the upper surface of the silicon substrate backplane; releasing the first mask The lower surface of the board is temporarily bonded to the upper surface of the silicon-based backplane, and the first mask is removed; a transparent sealing cover is formed on the upper surface of the silicon-based backplane. The method helps to further reduce the pixel size of the silicon-based backplane multi-primary-color LED light-emitting array pixel matrix display, making it possible for the silicon-based backplane active matrix OLED microdisplay to develop towards the direction of high pixel density and multi-color mixing.
Description
技术领域technical field
本发明涉及显示技术领域,尤其涉及一种硅基背板LED显示器的制造方法。The invention relates to the field of display technology, in particular to a method for manufacturing a silicon-based backplane LED display.
背景技术Background technique
以有机发光二极管(OLED)为核心的有源矩阵LED显示器,与TFT-LCD为代表的传统显示器相比,具有响应速度快、色域大、对比度高、视角宽、光电效率高、器件厚度薄等诸多优点,不仅成为移动终端、便携电子乃至数字电视等终端应用系统的最佳显示技术选择,尤其成为虚拟现实(Virtual Reality)等新兴应用终端系统的最佳显示技术方案。其中,以微显示器为核心的VR头盔显示器系统,对微显示器的成像区域有尺寸及面积的限制,而且在有限的面积和尺寸内对微显示器的分辨率要求越来越高,也就是对像素密度(即单位面积内的像素数目)的要求将不断提高。Compared with the traditional display represented by TFT-LCD, the active matrix LED display with organic light-emitting diode (OLED) as the core has fast response speed, large color gamut, high contrast ratio, wide viewing angle, high photoelectric efficiency, and thin device thickness. And many other advantages, not only become the best display technology choice for terminal application systems such as mobile terminals, portable electronics, and even digital TVs, but also become the best display technology solution for emerging application terminal systems such as virtual reality (Virtual Reality). Among them, the VR helmet-mounted display system with microdisplay as the core has restrictions on the size and area of the imaging area of the microdisplay, and within the limited area and size, the resolution of the microdisplay is getting higher and higher, that is, the resolution of the pixel Density (that is, the number of pixels per unit area) requirements will continue to increase.
具体而言,OLED显示器中的每个像素点上的OLED单元的核心,是阳极和阴极之间的有机发射层,从阳极提供的空穴以及从阴极提供的电子,会在有机发射层中复合以产生一个激发子,该激发子为电子空穴对,并且该激发子返回到基态,以光发射的形式释放能量。Specifically, the core of the OLED unit on each pixel in an OLED display is the organic emission layer between the anode and the cathode, and the holes provided from the anode and the electrons provided from the cathode will recombine in the organic emission layer To generate an exciton, which is an electron-hole pair, and the exciton returns to the ground state, releasing energy in the form of light emission.
基于玻璃基板TFT工艺制造的有源矩阵OLED显示器,由于其自身基板的大尺寸以及工艺设备的局限,很大程度地制约了加工工艺的光刻精度、像素尺寸的缩小和像素密度的提高,因而约束了显示器分辨率的提高。例如,要实现1,500PPI(即每英寸1千5百个像素)的像素密度,就意味着像素尺寸需要缩小到17微米左右,所需的光刻工艺几乎进入亚微米尺度,这对基于玻璃基板的传统TFT工艺制造来说,是个相当大的技术挑战。同时,根据VR显示及其系统应用的需要,在提高分辨率的同时进一步提高帧频率,这对TFT(薄膜晶体管)响应速度等性能呈现相当的技术挑战。因此,以大规模集成电路工艺和CMOS晶体管为基础的硅基背板有源矩阵OLED微显示器技术,自然成为解决高帧频率和高分辨率技术两大门槛的更佳选择。The active matrix OLED display manufactured based on the glass substrate TFT process, due to the large size of its own substrate and the limitations of process equipment, greatly restricts the lithography accuracy of the processing technology, the reduction of pixel size and the improvement of pixel density. The improvement of display resolution is constrained. For example, to achieve a pixel density of 1,500PPI (that is, 1,500 pixels per inch), it means that the pixel size needs to be reduced to about 17 microns, and the required photolithography process almost enters the sub-micron scale. For the traditional TFT process manufacturing of the substrate, it is a considerable technical challenge. At the same time, according to the needs of VR display and its system applications, the frame frequency should be further increased while increasing the resolution, which poses considerable technical challenges to the performance of TFT (thin film transistor) response speed and so on. Therefore, the silicon-based backplane active matrix OLED microdisplay technology based on large-scale integrated circuit technology and CMOS transistors naturally becomes a better choice to solve the two thresholds of high frame frequency and high resolution technology.
以包括红、绿、蓝乃至白色组成的多原色OLED阵列像素矩阵显示器,相比以纯白色OLED发射层配置红、绿、蓝三色透明彩色滤光阵列(Color filterarray)的矩阵显示器,具有更大的色域和更高的光电效率,成为各种终端应用系统的更佳选择,但是加工难度更大。Compared with the matrix display with red, green and blue transparent color filter array (Color filter array) configured with pure white OLED emission layer, the multi-primary-color OLED array pixel matrix display has a larger The color gamut and higher photoelectric efficiency make it a better choice for various end application systems, but the processing is more difficult.
同时,由于OLED发射层的性能和可靠性对水分子与其它溶液和离子污染以及化学反应极为敏感,传统硅基晶圆的刻蚀方法已经不能适用于由多原色OLED发射层子像素所组成的发光像素阵列的微加工,而借鉴TFT基板上加工多原色OLED阵列显示器所采用的主流方法,就成为较为可行的技术路径,这一方法的核心是透过多个含有微小窗口并与TFT基板形成一定垂直的金属网筛(掩膜),轮流在TFT基板上相应的下电极表面,局部沉积(如蒸镀)上不同色有机发射层。遗憾的是,这种方法不仅要求一个大尺度的、多少有弯曲变形的金属掩膜以最大程度地接近TFT平板表面,又必须防止它与TFT平板表面有任何接触(以造成表面损坏或残留),要提高金属掩膜与TFT平板上的下电极的光学对位精度,同时进一步缩小金属网筛孔的尺寸,会遭遇巨大的技术挑战,因而约束像素尺寸的进一步缩小,成为硅基背板有源矩阵多原色OLED微显示器向高像素密度多色混合发展的一个根本工艺技术瓶颈。At the same time, because the performance and reliability of the OLED emissive layer are extremely sensitive to water molecules and other solutions and ion contamination and chemical reactions, the traditional silicon-based wafer etching method is no longer suitable for OLED emissive layer sub-pixels composed of multi-primary colors. The micromachining of light-emitting pixel arrays has become a more feasible technical path by referring to the mainstream method used in the processing of multi-primary-color OLED array displays on TFT substrates. Certain vertical metal mesh screens (masks) are placed on the corresponding lower electrode surfaces on the TFT substrate in turn, and organic emission layers of different colors are locally deposited (such as evaporated). Unfortunately, this method not only requires a large-scale, somewhat curved metal mask to maximize the proximity to the TFT panel surface, but also must prevent it from any contact with the TFT panel surface (to cause surface damage or residue) In order to improve the optical alignment accuracy between the metal mask and the lower electrode on the TFT panel, and to further reduce the size of the metal mesh screen hole, it will encounter huge technical challenges, thus constraining the further reduction of the pixel size, and it has become a silicon-based backplane. A fundamental technological bottleneck in the development of source-matrix multi-primary-color OLED microdisplays to high-pixel-density multi-color mixing.
发明内容Contents of the invention
本发明的目的在于,提供一种硅基背板LED显示器的制造方法,包括步骤:The object of the present invention is to provide a method for manufacturing a silicon-based backplane LED display, comprising steps:
提供硅基背板,包含硅基背板上表面和与之相对的硅基背板下表面;Provide a silicon-based backplane, including the upper surface of the silicon-based backplane and the lower surface of the silicon-based backplane opposite thereto;
在硅基背板上形成基板光学对位标志;Form substrate optical alignment marks on the silicon-based backplane;
提供第一掩膜板,包含第一掩膜板上表面和相对的第一掩膜板下表面;providing a first mask, including an upper surface of the first mask and an opposite lower surface of the first mask;
在第一掩膜板上形成第一掩膜板光学对位标志,以及多个第一通孔组成第一通孔阵列;forming a first mask optical alignment mark on the first mask, and a plurality of first through holes forming a first through hole array;
将第一掩膜板平行置于硅基背板之上,形成所述第一掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位;placing the first mask in parallel on the silicon-based backplane to form a vertical optical alignment between the optical alignment mark of the first mask and the optical alignment mark of the substrate;
基于所述第一掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位,形成第一掩膜板与硅基背板的临时键合,其中第一掩膜板下表面与硅基背板上表面相对;Based on the vertical optical alignment between the optical alignment mark of the first mask plate and the optical alignment mark of the substrate, the temporary bonding of the first mask plate and the silicon-based backplane is formed, wherein the lower surface of the first mask plate opposite to the upper surface of the silicon-based backplane;
从第一掩膜板上表面上方通过所述第一通孔将第一LED发射层沉积于硅基背板上表面所暴露的多个第一子像素区域所构成的第一子像素区域阵列内;Depositing the first LED emission layer from above the upper surface of the first mask plate through the first through hole in the first sub-pixel region array formed by the plurality of first sub-pixel regions exposed on the upper surface of the silicon substrate backplane ;
解除第一掩膜板与硅基背板的临时键合,并移开第一掩膜板;Release the temporary bonding between the first mask plate and the silicon-based backplane, and remove the first mask plate;
在硅基背板上表面形成透明的密封封盖。A transparent sealing cover is formed on the surface of the silicon-based backplane.
相比于现有技术,本发明的制造方法采用一组特殊制备的各自含有相应通孔阵列的硬掩模板,通过硬掩膜板和硅基背板的光学对位标志,分别与所述硅基背板轮流在垂直方向形成高精度对位以及临时键合,使得硬掩模板上的通孔阵列分别与硅基背板上对应的下电极阵列在垂直方向形成准确光学对位,然后透过所述通孔在所述电极上沉积相应色的OLED发射层,之后解除该组硬掩模板分别与所述硅基背板的临时键合;重复完成所有硬掩模板与硅基背板的临时键合、相对应色的OLED发射层沉积和硬掩模板与硅基背板键合解除的过程后,通过薄膜沉积形成覆盖OLED发射层的透明上电极和实现表面密封的封盖层。这种方法,通过硬掩模板与硅基背板高精度对位键合,借助硬掩模板上通孔阵列将OLED发射层准确沉积于相应的下电极上,从而为进一步缩小了像素尺寸,使得硅基背板有源矩阵OLED微显示器向高像素密度多色混合的方向发展成为可能。Compared with the prior art, the manufacturing method of the present invention adopts a set of specially prepared hard mask plates each containing a corresponding through-hole array, through the optical alignment marks of the hard mask plate and the silicon-based backplane, and the silicon-based backplane respectively. The substrate and the backplane take turns to form high-precision alignment and temporary bonding in the vertical direction, so that the through hole array on the hard mask and the corresponding lower electrode array on the silicon substrate form an accurate optical alignment in the vertical direction, and then through Deposit the OLED emission layer of the corresponding color on the electrode through the through hole, and then release the temporary bonding of the group of hard mask templates and the silicon-based backplane respectively; repeat the temporary bonding of all hard mask templates and silicon-based backplanes After the process of bonding, deposition of OLED emission layer of corresponding color and release of bonding between hard mask and silicon backplane, a transparent upper electrode covering OLED emission layer and a capping layer for surface sealing are formed by thin film deposition. In this method, through the high-precision alignment bonding between the hard mask and the silicon-based backplane, the OLED emission layer is accurately deposited on the corresponding lower electrode by means of the through-hole array on the hard mask, thereby further reducing the pixel size, making Silicon-based backplane active-matrix OLED microdisplays are likely to develop in the direction of high pixel density and multi-color mixing.
附图说明Description of drawings
图1为本发明第一实施例的硅基背板OLED微显示器的制造方法流程图;Fig. 1 is the flow chart of the manufacturing method of the silicon-based backplane OLED microdisplay of the first embodiment of the present invention;
图2至图10为本发明第一实施例的硅基背板OLED微显示器的制造方法的示意图;2 to 10 are schematic diagrams of a method for manufacturing a silicon-based backplane OLED microdisplay according to a first embodiment of the present invention;
图11为本发明第二实施例的硅基背板OLED微显示器的制造方法流程图;11 is a flowchart of a method for manufacturing a silicon-based backplane OLED microdisplay according to a second embodiment of the present invention;
图12至图14为本发明第二实施例的硅基背板OLED微显示器的制造方法的示意图;12 to 14 are schematic diagrams of a method for manufacturing a silicon-based backplane OLED microdisplay according to a second embodiment of the present invention;
图15为本发明第三实施例的硅基背板OLED微显示器的制造方法的流程图;15 is a flowchart of a method for manufacturing a silicon-based backplane OLED microdisplay according to a third embodiment of the present invention;
图16至图19为本发明第三实施例的硅基背板OLED微显示器的制造方法的示意图。16 to 19 are schematic diagrams of a method for manufacturing an OLED microdisplay with a silicon-based backplane according to a third embodiment of the present invention.
具体实施方式detailed description
下面将结合示意图对本发明的有源可视显示器及其驱动电路做更详细的说明,应该理解本领域技术人员可以修改在此描述的本发明,而仍然实现本发明的有利效果。因此,下列描述应当被理解为对于本领域技术人员的广泛知道,而并不作为对本发明的限制。需说明的是,附图均采用非常简化的形式且均使用非精准的比例,仅用以方便、明晰地辅助说明本发明实施例的目的。The active visual display and its drive circuit of the present invention will be described in more detail below with reference to schematic diagrams. It should be understood that those skilled in the art can modify the present invention described here while still achieving the advantageous effects of the present invention. Therefore, the following description should be understood as the broad knowledge of those skilled in the art, but not as a limitation of the present invention. It should be noted that all the drawings are in a very simplified form and use imprecise scales, and are only used to facilitate and clearly assist the purpose of illustrating the embodiments of the present invention.
第一实施例first embodiment
图1为本发明第一实施例的硅基背板OLED微显示器的制造方法流程图,参考图1,本发明的硅基背板LED显示器的制造方法,包括步骤:Fig. 1 is the flow chart of the manufacturing method of the silicon-based backplane OLED microdisplay of the first embodiment of the present invention, with reference to Fig. 1, the manufacturing method of the silicon-based backplane LED display of the present invention, comprises steps:
S10,提供硅基背板;S10, providing a silicon-based backplane;
S20,在硅基背板上接近硅基背板下表面或硅基背板下表面形成基板光学对位标志;S20, forming an optical alignment mark of the substrate on the silicon-based backplane close to the lower surface of the silicon-based backplane or the lower surface of the silicon-based backplane;
S30,提供第一掩膜板,包含第一掩膜板上表面和相对的第一掩膜板下表面;S30, providing a first mask, including an upper surface of the first mask and an opposite lower surface of the first mask;
S40,在第一掩膜板上形成第一掩膜板光学对位标志,以及多个第一通孔组成第一通孔阵列;S40, forming a first mask optical alignment mark on the first mask, and a plurality of first through holes forming a first through hole array;
S50,将第一掩膜板平行置于硅基背板之上,形成所述第一掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位;S50, placing the first mask on the silicon-based backplane in parallel, forming a vertical optical alignment between the optical alignment mark of the first mask and the optical alignment mark of the substrate;
S60,基于所述第一掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位,形成第一掩膜板与硅基背板的临时键合;S60, based on the vertical optical alignment between the first mask optical alignment mark and the substrate optical alignment mark, forming a temporary bond between the first mask plate and the silicon-based backplane;
S70,从第一掩膜板上表面上方通过所述第一通孔将第一LED发射层沉积于硅基背板上表面所暴露的多个第一子像素区域所构成的第一子像素区域阵列内;S70, depositing the first LED emission layer on the first sub-pixel region formed by the plurality of first sub-pixel regions exposed on the upper surface of the silicon substrate backplane through the first through hole from above the upper surface of the first mask plate inside the array;
S80,解除第一掩膜板与硅基背板的临时键合,并移开第一掩膜板;S80, releasing the temporary bonding between the first mask plate and the silicon-based backplane, and removing the first mask plate;
S90,在硅基背板上表面形成透明的密封封盖。S90, forming a transparent sealing cover on the surface of the silicon-based backplane.
图2至图10为本发明第一实施例的硅基背板OLED微显示器的制造方法的示意图,参考图2至图10,对第一实施例进行详细说明。2 to 10 are schematic diagrams of a method for manufacturing a silicon-based backplane OLED microdisplay according to a first embodiment of the present invention. Referring to FIGS. 2 to 10 , the first embodiment will be described in detail.
执行步骤S10,参考图2,提供硅基背板100,包含硅基背板上表面101和与之相对的硅基背板下表面102,所述硅基背板100为单晶硅材料。硅基背板OLED微显示器区别于常规利用非晶硅、微晶硅或低温多晶硅薄膜晶体管为背板的AMOLED器件,它以单晶硅芯片为基底,像素尺寸大约为传统显示器件的1/10左右甚至更小,精细度远远高于传统器件。单晶硅作为基底可以采用现有成熟的集成电路CMOS工艺,集成度更高,大大减少了器件的外部连线,增加了可靠性,实现了轻量化。Execute step S10 , referring to FIG. 2 , providing a silicon-based backplane 100 , including an upper surface 101 of the silicon-based backplane and a lower surface 102 of the silicon-based backplane opposite thereto. The silicon-based backplane 100 is made of a single crystal silicon material. Silicon-based backplane OLED microdisplays are different from conventional AMOLED devices that use amorphous silicon, microcrystalline silicon or low-temperature polysilicon thin-film transistors as backplanes. It is based on a single-crystal silicon chip, and the pixel size is about 1/10 of traditional display devices. The left and right are even smaller, and the fineness is much higher than that of traditional devices. Monocrystalline silicon can be used as the base of the existing mature integrated circuit CMOS process, which has a higher integration level, greatly reduces the external wiring of the device, increases reliability, and realizes light weight.
执行步骤S20,继续参考图2,在硅基背板100上接近硅基背板下表面102或硅基背板下表面102形成基板光学对位标志105,用于进行后期与掩膜板之间的对位,提高工艺的精确度。Execute step S20, continue to refer to FIG. 2 , and form a substrate optical alignment mark 105 on the silicon-based backplane 100 close to the lower surface 102 of the silicon-based backplane or the lower surface 102 of the silicon-based backplane, for performing post-processing between the substrate and the mask. The alignment improves the accuracy of the process.
在本实施例中,优选的,参考图3,还包括步骤:在所述硅基背板上表面的每个第一子像素区域内形成一个第一下电极111,所述第一子像素区域阵列内的多个第一下电极111构成一个第一下电极阵列。In this embodiment, preferably, referring to FIG. 3 , it further includes the step of: forming a first lower electrode 111 in each first sub-pixel region on the upper surface of the silicon-based backplane, and the first sub-pixel region Multiple first lower electrodes 111 in the array form a first lower electrode array.
在本实施例中,优选的,所述的第一下电极为具有较低逸出功的LED阴极,并由金属Mg、Ca、Al、Ag以及它们的合金材料中任意一种或几种构成。优选的,所述第一下电极阵列中相邻近的两个第一下电极之间间距小于25微米,这是基于现有硅基晶圆间实施键合技术,其水平对位精度已经能够达到0.5微米甚至0.25微米以下。该步骤位于提供硅基背板步骤S10之后、形成所述第一掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位步骤S20之前。In this embodiment, preferably, the first lower electrode is an LED cathode with a relatively low work function, and is composed of any one or more of metals Mg, Ca, Al, Ag and their alloy materials . Preferably, the distance between two adjacent first lower electrodes in the first lower electrode array is less than 25 microns, which is based on the existing bonding technology between silicon-based wafers, and its horizontal alignment accuracy has been able to Reach 0.5 microns or even below 0.25 microns. This step is located after the step S10 of providing a silicon-based backplane and before the step S20 of forming the vertical optical alignment mark of the first mask plate and the optical alignment mark of the substrate.
在本实施例中,优选的,还包括步骤:In this embodiment, preferably, further comprising steps:
S203,参考图4,提供一个静电吸附底板500,并将静电吸附底板500结合于硅基背板100底部。该静电吸附底板借助静电作用吸附硅基背板底部,从而在有效拿持硅基背板的同时减小了对硅基背板的损伤,使得操作方便。该步骤位于将第一掩膜板平行置于硅基背板之上步骤S50之前,从而可以对硅基背板进行操作使其和第一掩膜板临时键合。当然除此之外也可以用其他的方法,在此不做限定。S203 , referring to FIG. 4 , providing an electrostatic adsorption bottom plate 500 , and bonding the electrostatic adsorption bottom plate 500 to the bottom of the silicon-based backplane 100 . The electrostatic adsorption bottom plate absorbs the bottom of the silicon-based backplane by means of electrostatic action, thereby reducing damage to the silicon-based backplane while effectively holding the silicon-based backplane, and making the operation convenient. This step is before the step S50 of placing the first mask in parallel on the silicon-based backplane, so that the silicon-based backplane can be temporarily bonded to the first mask. Of course, other methods can also be used, which are not limited here.
在本实施例中,优选的,还包括步骤:在所述硅基背板上形成有源矩阵驱动电路160,所述源矩阵驱动电路160包含与每个第一下电极111形成电学连接的第一像素子电路以及外围驱动电路;形成有源矩阵驱动电路的输入输出管腿。In this embodiment, preferably, a step is further included: forming an active matrix drive circuit 160 on the silicon-based backplane, and the source matrix drive circuit 160 includes a first electrode electrically connected to each first lower electrode 111. A pixel sub-circuit and peripheral driving circuit; form the input and output pins of the active matrix driving circuit.
执行步骤S30,参考图5,提供第一掩膜板200,包含第一掩膜板上表面201和相对的第一掩膜板下表面202。在本实施例中,优选的,所述第一掩膜板200的材料也为硅,从而在后面的工艺过程中不至于与硅基背板产生水平方向热膨胀差别而导致第一通孔211与第一电极111的垂直位错,影响第一LED发射层151与第一电极111的垂直对位。除此之外,也可以为其他材料,只要能配置这一掩膜板的热膨胀系数与硅基相同或接近。Step S30 is executed, and referring to FIG. 5 , a first mask 200 is provided, including an upper surface 201 of the first mask and an opposite lower surface 202 of the first mask. In this embodiment, preferably, the material of the first mask plate 200 is also silicon, so that there will be no difference in horizontal thermal expansion between the first through hole 211 and the silicon-based backplane in the subsequent process. The vertical dislocation of the first electrode 111 affects the vertical alignment between the first LED emitting layer 151 and the first electrode 111 . In addition, other materials can also be used, as long as the thermal expansion coefficient of the mask can be configured to be the same or close to that of the silicon base.
执行步骤S40,继续参考图5,在第一掩膜板200上形成第一掩膜板光学对位标志205,以及多个第一通孔211组成第一通孔阵列。所述第一通孔211之间的间距以及排列顺序与所述硅基背板上的第一下电极111的位置一一对应,确保在后续的键合过程中可以位置对应,所述第一通孔可以用本领域技术人员所熟知的刻蚀的方法形成,不再赘述。在本实施例中,优选的,第一通孔表面钝化层为金属构成,包括但不限于金属铝、钛、钴、钨、钽、镍、金、银及其任何合金物。可以在清洗步骤中保护第一通孔表面,也使得清洗更加容易去除杂质。Step S40 is executed, and referring to FIG. 5 , a first mask optical alignment mark 205 is formed on the first mask 200 , and a plurality of first through holes 211 form a first through hole array. The spacing and arrangement sequence between the first through holes 211 are in one-to-one correspondence with the positions of the first lower electrodes 111 on the silicon substrate backplate, so as to ensure that the positions can be corresponding in the subsequent bonding process, and the first The through holes can be formed by etching methods known to those skilled in the art, and details will not be repeated here. In this embodiment, preferably, the surface passivation layer of the first through hole is made of metal, including but not limited to aluminum, titanium, cobalt, tungsten, tantalum, nickel, gold, silver and any alloy thereof. It is possible to protect the surface of the first through hole during the cleaning step, and also make cleaning easier to remove impurities.
执行步骤S50,继续参考图5,将第一掩膜板200平行置于硅基背板100之上,形成所述第一掩膜板光学对位标志205与所述基板光学对位标志105的垂直光学对位。Execute step S50, continue to refer to FIG. 5, place the first mask 200 in parallel on the silicon-based backplane 100, and form the optical alignment mark 205 of the first mask and the optical alignment mark 105 of the substrate. Vertical optical alignment.
执行步骤S60,参考图6,基于所述第一掩膜板光学对位标志205与所述基板光学对位标志105的垂直光学对位,形成第一掩膜板200与硅基背板100的临时键合,从而使得所述第一通孔211恰好暴露第一下电极111。在本实施例中,优选的第一掩模板和硅基背板的键合是通过底部垫片220实现的,除此之外也可以利用其他的方法,例如直接热熔键合。Execute step S60, referring to FIG. 6 , based on the vertical optical alignment between the first mask optical alignment mark 205 and the substrate optical alignment mark 105, the first mask plate 200 and the silicon-based backplane 100 are formed. Temporary bonding, so that the first through hole 211 just exposes the first lower electrode 111 . In this embodiment, the bonding of the first mask plate and the silicon-based backplane is preferably achieved through the bottom pad 220 , other methods may also be used, such as direct thermal fusion bonding.
在本实施例中,参考图7,优选的,所述第一掩膜板下表面与硅基背板上表面的临时键合,是凭借多个边缘夹具610个别与硅基背板100形成机械钳夹来实现的。In this embodiment, referring to FIG. 7 , preferably, the temporary bonding between the lower surface of the first mask plate and the upper surface of the silicon-based backplane is by means of a plurality of edge clamps 610 that are individually mechanically bonded to the silicon-based backplane 100 . Clamp to achieve.
执行步骤S70,参考图8,从第一掩膜板上表面201上方通过所述第一通孔211将第一LED发射层151沉积于硅基背板上表面101所暴露的多个第一子像素区域所构成的第一子像素区域阵列内,即覆盖第一下电极111。所述的第一LED发射层优选的为无机半导体构成,除此之外也可以为有机化合物半导体构成。所述第一LED发射层的沉积,是通过蒸镀、气相沉积和喷墨印刷中的任何一种方法实现的,例如蒸镀。Execute step S70, referring to FIG. 8 , depositing the first LED emission layer 151 on the plurality of first sub-layers exposed by the upper surface 101 of the silicon-based backplane through the first through hole 211 from above the upper surface 201 of the first mask plate. The first sub-pixel area array formed by the pixel area covers the first lower electrode 111 . The first LED emitting layer is preferably composed of an inorganic semiconductor, and may also be composed of an organic compound semiconductor. The deposition of the first LED emitting layer is realized by any one method among evaporation, vapor deposition and inkjet printing, such as evaporation.
执行步骤S80,参考图9,解除第一掩膜板200与硅基背板100的临时键合,并移开第一掩膜板200。Step S80 is executed, referring to FIG. 9 , releasing the temporary bonding between the first mask plate 200 and the silicon-based backplane 100 , and removing the first mask plate 200 .
执行步骤S90,参考图10,在硅基背板上表面101形成透明的密封封盖190,所述密封封盖可以为半导体材料例如二氧化硅,可以通过气相淀积的方法形成,也可以利用封装的方式直接键合在硅基背板表面。。Execute step S90, referring to FIG. 10, a transparent sealing cover 190 is formed on the upper surface 101 of the silicon-based backplane. The sealing cover can be a semiconductor material such as silicon dioxide, which can be formed by vapor deposition, or can be formed by using The packaging method is directly bonded to the surface of the silicon-based backplane. .
第二实施例second embodiment
第二实施例同样包括步骤:The second embodiment also includes the steps of:
S10,提供硅基背板100;S10, providing a silicon-based backplane 100;
S20,在硅基背板100上接近硅基背板下表面或硅基背板下表面形成基板光学对位标志105;S20, forming a substrate optical alignment mark 105 on the silicon-based backplane 100 close to the lower surface of the silicon-based backplane or the lower surface of the silicon-based backplane;
在所述硅基背板上表面的每个第一子像素区域内形成一个第一下电极111,所述第一子像素区域阵列内的多个第一下电极111构成一个第一下电极阵列。A first lower electrode 111 is formed in each first sub-pixel region on the upper surface of the silicon-based backplane, and a plurality of first lower electrodes 111 in the first sub-pixel region array constitute a first lower electrode array .
S30,提供第一掩膜板200,包含第一掩膜板上表面和相对的第一掩膜板下表面;S30, providing a first mask 200, including an upper surface of the first mask and an opposite lower surface of the first mask;
S40,在第一掩膜板上形成第一掩膜板光学对位标志205,以及多个第一通孔211组成第一通孔阵列;S40, forming a first mask optical alignment mark 205 on the first mask, and a plurality of first through holes 211 to form a first through hole array;
S50,将第一掩膜板200平行置于硅基背板100之上,形成所述第一掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位;S50, placing the first mask plate 200 in parallel on the silicon-based backplane 100, forming a vertical optical alignment between the optical alignment mark of the first mask plate and the optical alignment mark of the substrate;
S60,基于所述第一掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位,形成第一掩膜板200与硅基背板100的临时键合;S60, based on the vertical optical alignment between the first mask optical alignment mark and the substrate optical alignment mark, forming a temporary bond between the first mask 200 and the silicon-based backplane 100;
S70,从第一掩膜板上表面上方通过所述第一通孔将第一LED发射层151沉积于硅基背板上表面所暴露的多个第一子像素区域所构成的第一子像素区域阵列内;S70, depositing the first LED emission layer 151 on the first sub-pixel formed by the plurality of first sub-pixel regions exposed on the upper surface of the silicon substrate backplane through the first through hole from above the upper surface of the first mask plate inside the area array;
S80,解除第一掩膜板与硅基背板的临时键合,并移开第一掩膜板;S80, releasing the temporary bonding between the first mask plate and the silicon-based backplane, and removing the first mask plate;
与第一实施例相同的步骤不再赘述,不同在于:The same steps as the first embodiment will not be repeated, the difference is:
参考图11,在形成第一下电极111阵列之后,在硅基背板100上形成透明的密封封盖步骤S90之前,包括步骤:Referring to FIG. 11 , after forming the array of the first lower electrodes 111, before the step S90 of forming a transparent sealing cover on the silicon-based backplane 100, the steps include:
在所述硅基背板上表面101的每个第二子像素区域内形成一个第二下电极121,所述第二子像素区域阵列内的多个第二下电极121构成一个第二下电极阵列。A second lower electrode 121 is formed in each second sub-pixel region on the upper surface 101 of the silicon-based backplane, and a plurality of second lower electrodes 121 in the second sub-pixel region array form a second lower electrode array.
优选的还包括,在所述硅基背板100上形成有源矩阵驱动电路,所述源矩阵驱动电路包含分别与每个第一下电极111、第二下电极121形成电学连接的第一像素子电路、第二像素子电路以及外围驱动电路。Preferably, an active matrix driving circuit is formed on the silicon-based backplane 100, and the source matrix driving circuit includes first pixels electrically connected to each of the first lower electrode 111 and the second lower electrode 121 respectively. sub-circuit, second pixel sub-circuit and peripheral driving circuit.
在解除第一掩膜板200与硅基背板100的临时键合并移开第一掩膜板200步骤S80之后、在硅基背板100上形成透明的密封封盖S90之前,包括下列子步骤:After releasing the temporary bonding between the first mask 200 and the silicon-based backplane 100 and removing the first mask 200 in step S80, and before forming a transparent sealing cover on the silicon-based backplane 100 S90, the following sub-steps are included :
子步骤S821,参考图12,提供第二掩膜板300,包含第二掩膜板上表面301和相对的第二掩膜板下表面302;在本实施例中,出于上述原因,所述第二掩膜板300的材料也为和第一掩膜板相同的硅。Sub-step S821, referring to FIG. 12 , provides a second mask 300, including the upper surface 301 of the second mask and the lower surface 302 of the second mask opposite; in this embodiment, for the above reasons, the The material of the second mask 300 is also the same silicon as that of the first mask.
子步骤S822,参考图12,在第二掩膜板上形成第二掩膜板光学对位标志305,以及多个第二通孔311组成的第二通孔阵列;所述第二通孔311之间的间距以及排列顺序与所述硅基背板上的第二下电极121的位置一一对应,确保在后续的键合过程中可以位置对应,所述第二通孔可以用本领域技术人员所熟知的刻蚀的方法形成,不再赘述。在本实施例中,优选的,第二通孔表面钝化层为金属构成,包括但不限于金属铝、钛、钴、钨、钽、镍、金、银及其任何合金物。可以在清洗步骤中保护第二通孔表面,也使得清洗更加容易去除杂质。Sub-step S822, referring to FIG. 12 , forming a second mask optical alignment mark 305 on the second mask, and a second through-hole array composed of a plurality of second through-holes 311; the second through-holes 311 The spacing between them and the arrangement sequence correspond to the positions of the second lower electrodes 121 on the silicon-based backplate one by one to ensure that the positions can be corresponding in the subsequent bonding process. The etching method well-known to personnel is formed, and will not be repeated here. In this embodiment, preferably, the surface passivation layer of the second through hole is made of metal, including but not limited to aluminum, titanium, cobalt, tungsten, tantalum, nickel, gold, silver and any alloy thereof. The surface of the second through hole can be protected during the cleaning step, which also makes cleaning easier to remove impurities.
子步骤S823,参考图12,将第二掩膜板300平行置于硅基背板100之上,形成所述第二掩膜板光学对位标志305与所述基板光学对位标志105的垂直光学对位。Sub-step S823, referring to FIG. 12 , placing the second mask 300 in parallel on the silicon-based backplane 100 to form a vertical line between the optical alignment mark 305 of the second mask and the optical alignment mark 105 of the substrate. Optical alignment.
基于所述第二掩膜板光学对位标志305与所述基板光学对位标志105的垂直光学对位,形成第二掩膜板300与硅基背板100的临时键合,从而使得所述第二通孔311恰好暴露第二下电极121。在本实施例中,值得注意的是,由于已经在硅基背板上表面102形成覆盖第一下电极111的第一LED发射层151,因此在本实施例中,第二掩模板300和硅基背板100之间的键合是通过粘附底部垫片实现的,从而将第一LED发射层151架空,架空的高度要超过第一LED发射层151的顶层相对硅基表面的高度,使其不受损伤,也避免在沉积第二LED发射层152时不至于与第二通孔212底部粘连。如果是采用静电吸附的方式实现第二掩膜板300的下表面302与所述硅基背板100上表面101的临时键合,为了实现静电隔离,所述底部垫片220以介电质材料构成为好。Based on the vertical optical alignment between the second mask optical alignment mark 305 and the substrate optical alignment mark 105, the temporary bonding between the second mask plate 300 and the silicon-based backplane 100 is formed, so that the The second through hole 311 just exposes the second lower electrode 121 . In this embodiment, it is worth noting that since the first LED emitting layer 151 covering the first lower electrode 111 has been formed on the upper surface 102 of the silicon-based backplane, in this embodiment, the second mask 300 and the silicon The bonding between the base and backplanes 100 is achieved by adhering the bottom gasket, so that the first LED emission layer 151 is raised above the height of the top layer of the first LED emission layer 151 relative to the surface of the silicon base, so that It is not damaged, and it is also prevented from sticking to the bottom of the second through hole 212 when the second LED emitting layer 152 is deposited. If the temporary bonding between the lower surface 302 of the second mask 300 and the upper surface 101 of the silicon-based backplane 100 is achieved by electrostatic adsorption, in order to achieve electrostatic isolation, the bottom gasket 220 is made of a dielectric material Poses as well.
除此之外,在其它实施例中也可以采用其他的方法键合,例如在第二掩膜板或者硅基背板可以包括具有凹槽的介质层,从而通过热熔的方式进行键合,使得第一LED发射层位于所述凹槽内。In addition, other bonding methods can also be used in other embodiments, for example, the second mask or the silicon-based backplane can include a dielectric layer with grooves, so as to perform bonding by thermal fusion, The first LED emission layer is located in the groove.
子步骤S824,继续参考图12,基于所述第二掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位,形成第二掩膜板300与硅基背板100的临时键合,是凭借多个边缘夹具610个别与硅基背板100形成机械钳夹来实现的,当然也可以只选择利用静电吸附底板。Sub-step S824, continue to refer to FIG. 12 , based on the vertical optical alignment between the optical alignment mark of the second mask plate and the optical alignment mark of the substrate, a temporary alignment between the second mask plate 300 and the silicon-based backplane 100 is formed. Bonding is achieved by means of a plurality of edge clamps 610 individually forming mechanical clamps with the silicon-based backplane 100 , of course, it is also possible to choose to only use electrostatic adsorption to the bottom plate.
子步骤S825,继续参考图12,从第二掩膜板上表面301上方通过所述第二通孔311将第二LED发射层152沉积于硅基背板上表面101所暴露的多个第二子像素区域所构成第二子像素区域阵列内,即覆盖第二下电极121;Sub-step S825, continue to refer to FIG. 12 , deposit the second LED emitting layer 152 on the plurality of second LED emission layers exposed by the upper surface 101 of the silicon substrate backplane from above the upper surface 301 of the second mask plate through the second through hole 311. The second sub-pixel area array formed by the sub-pixel area covers the second lower electrode 121;
所述的第一子像素区域、第二子像素区域两者在硅基背板上表面上不相交或重叠。The first sub-pixel area and the second sub-pixel area do not intersect or overlap on the upper surface of the silicon substrate backplane.
所述的第二LED发射层优选的为无机半导体构成,除此之外也可以为有机化合物半导体构成。所述第二LED发射层的沉积,是通过蒸镀、气相沉积和喷墨印刷中的任何一种方法实现的,例如蒸镀。The second LED emitting layer is preferably composed of an inorganic semiconductor, and may also be composed of an organic compound semiconductor. The deposition of the second LED emitting layer is realized by any one method among evaporation, vapor deposition and inkjet printing, such as evaporation.
子步骤S826,参考图13,解除第二掩膜板300与硅基背板100的临时键合,并移开第二掩膜板300。Sub-step S826 , referring to FIG. 13 , releases the temporary bonding between the second mask 300 and the silicon-based backplane 100 , and removes the second mask 300 .
在本实施例中,参考图14,优选的,还包括步骤S827,在硅基背板上表面上,形成与第一LED发射层151和第二LED发射层152物理接触的共享上电极薄膜180。In this embodiment, referring to FIG. 14 , preferably, step S827 is further included, forming a shared upper electrode film 180 in physical contact with the first LED emission layer 151 and the second LED emission layer 152 on the upper surface of the silicon substrate backplane. .
执行步骤S90,参考图13,在硅基背板上表面101形成透明的密封封盖190。Step S90 is executed, referring to FIG. 13 , forming a transparent sealing cover 190 on the upper surface 101 of the silicon substrate backplane.
第三实施例third embodiment
第三实施例同样包括步骤:The third embodiment also includes the steps of:
S10,提供硅基背板100;S10, providing a silicon-based backplane 100;
S20,在硅基背板100上接近硅基背板下表面或硅基背板下表面形成基板光学对位标志105;S20, forming a substrate optical alignment mark 105 on the silicon-based backplane 100 close to the lower surface of the silicon-based backplane or the lower surface of the silicon-based backplane;
在所述硅基背板上表面的每个第一子像素区域内形成一个第一下电极111,所述第一子像素区域阵列内的多个第一下电极111构成一个第一下电极阵列。A first lower electrode 111 is formed in each first sub-pixel region on the upper surface of the silicon-based backplane, and a plurality of first lower electrodes 111 in the first sub-pixel region array constitute a first lower electrode array .
在所述硅基背板上表面101的每个第二子像素区域内形成一个第二下电极121,所述第二子像素区域阵列内的多个第二下电极121构成一个第二下电极阵列。A second lower electrode 121 is formed in each second sub-pixel region on the upper surface 101 of the silicon-based backplane, and a plurality of second lower electrodes 121 in the second sub-pixel region array form a second lower electrode array.
S30,提供第一掩膜板200,包含第一掩膜板上表面和相对的第一掩膜板下表面;S30, providing a first mask 200, including an upper surface of the first mask and an opposite lower surface of the first mask;
S40,在第一掩膜板上形成第一掩膜板光学对位标志205,以及多个第一通孔211组成第一通孔阵列;S40, forming a first mask optical alignment mark 205 on the first mask, and a plurality of first through holes 211 to form a first through hole array;
S50,将第一掩膜板200平行置于硅基背板100之上,形成所述第一掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位;S50, placing the first mask plate 200 in parallel on the silicon-based backplane 100, forming a vertical optical alignment between the optical alignment mark of the first mask plate and the optical alignment mark of the substrate;
S60,基于所述第一掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位,形成第一掩膜板200与硅基背板100的临时键合;S60, based on the vertical optical alignment between the first mask optical alignment mark and the substrate optical alignment mark, forming a temporary bond between the first mask 200 and the silicon-based backplane 100;
S70,从第一掩膜板上表面上方通过所述第一通孔将第一LED发射层151沉积于硅基背板上表面所暴露的多个第一子像素区域所构成的第一子像素区域阵列内;S70, depositing the first LED emission layer 151 on the first sub-pixel formed by the plurality of first sub-pixel regions exposed on the upper surface of the silicon substrate backplane through the first through hole from above the upper surface of the first mask plate inside the area array;
S80,解除第一掩膜板与硅基背板的临时键合,并移开第一掩膜板;S80, releasing the temporary bonding between the first mask plate and the silicon-based backplane, and removing the first mask plate;
子步骤S821,提供第二掩膜板300;Sub-step S821, providing a second mask 300;
子步骤S822,在第二掩膜板上形成第二掩膜板光学对位标志305,以及多个第二通孔311组成的第二通孔阵列;Sub-step S822, forming a second mask optical alignment mark 305 and a second through-hole array composed of a plurality of second through-holes 311 on the second mask;
子步骤S823,将第二掩膜板300平行置于硅基背板100之上,形成所述第二掩膜板光学对位标志305与所述基板光学对位标志105的垂直光学对位;Sub-step S823, placing the second mask 300 in parallel on the silicon-based backplane 100 to form a vertical optical alignment between the optical alignment mark 305 of the second mask and the optical alignment mark 105 of the substrate;
子步骤S824,基于所述第二掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位,形成第二掩膜板300与硅基背板100的临时键合;Sub-step S824, based on the vertical optical alignment between the second mask optical alignment mark and the substrate optical alignment mark, forming a temporary bond between the second mask 300 and the silicon-based backplane 100;
子步骤S825,从第二掩膜板上表面301上方通过所述第二通孔311将第二LED发射层152沉积于硅基背板上表面101所暴露的多个第二子像素区域所构成第二子像素区域阵列内,即覆盖第二下电极121;Sub-step S825, depositing the second LED emission layer 152 from above the upper surface 301 of the second mask plate through the second through hole 311 on the exposed second sub-pixel regions of the silicon substrate backplane upper surface 101 In the second sub-pixel area array, that is, covering the second lower electrode 121;
执行子步骤S826,解除第二掩膜板300与硅基背板100的临时键合,并移开第二掩膜板300。Sub-step S826 is executed to release the temporary bonding between the second mask plate 300 and the silicon-based backplane 100 , and remove the second mask plate 300 .
第三实施例与第二实施例相同的步骤不再赘述,不同在于:The same steps of the third embodiment and the second embodiment will not be repeated, the difference is:
参考图15,在形成第一下电极111阵列和第二下电极121阵列步骤之后,在硅基背板100上形成透明的密封封盖之前,包括步骤S231:Referring to FIG. 15 , after forming the first lower electrode 111 array and the second lower electrode 121 array step, before forming a transparent sealing cover on the silicon-based backplane 100, step S231 is included:
在所述硅基背板上表面101的每个第三子像素区域内形成一个第三下电极131,所述第三子像素区域阵列内的多个第三下电极131构成一个第三下电极阵列;其中各个第三下电极131分别与第一下电极111和第二下电极121一一对应、相间有序排列。A third lower electrode 131 is formed in each third sub-pixel region on the upper surface 101 of the silicon-based backplane, and a plurality of third lower electrodes 131 in the third sub-pixel region array constitute a third lower electrode array; wherein each third lower electrode 131 is in one-to-one correspondence with the first lower electrode 111 and the second lower electrode 121 , and is arranged in an orderly manner.
优选的还包括,在所述硅基背板100上形成有源矩阵驱动电路,所述源矩阵驱动电路包含分别与每个第一下电极、第二下电极和第三下电极形成电学连接的第一像素子电路、第二像素子电路和第三像素子电路以及外围驱动电路;形成有源矩阵驱动电路的输入输出管腿。Preferably, an active matrix driving circuit is formed on the silicon-based backplane 100, and the source matrix driving circuit includes electrical connections with each of the first lower electrode, the second lower electrode and the third lower electrode, respectively. The first pixel sub-circuit, the second pixel sub-circuit, the third pixel sub-circuit and the peripheral driving circuit form the input and output pins of the active matrix driving circuit.
在解除第二掩膜板300下表面与硅基背板上表面的临时键合并移开第二掩膜板300的步骤后,在硅基背板上形成透明的密封封盖的步骤前,进一步包括下列子步骤:After releasing the temporary bonding between the lower surface of the second mask 300 and the upper surface of the silicon-based backplane and removing the second mask 300, before the step of forming a transparent sealing cover on the silicon-based backplane, further Include the following sub-steps:
S8211,参考图16,提供第三掩膜400,包含第三掩膜板上表面401和相对的第三掩膜板下表面402;在本实施例中,所述第三掩膜板400的材料为和第一掩膜板和第二掩膜板相同的硅,从而在后面的可是步骤更方便操作,精确度更高,工艺兼容性更好。除此之外,也可以为其他材料。S8211, referring to FIG. 16 , providing a third mask 400, including the upper surface 401 of the third mask plate and the lower surface 402 of the third mask plate opposite; in this embodiment, the material of the third mask plate 400 It is made of the same silicon as the first mask plate and the second mask plate, so that the subsequent steps are more convenient to operate, with higher precision and better process compatibility. Besides, other materials are also possible.
S8212,参考图16,在第三掩膜板400上形成第三掩膜板光学对位标志405,以及多个第三通孔411组成的第三通孔阵列;所述第三通孔411之间的间距以及排列顺序与所述硅基背板上的第一电极111或第二下电极121的位置一一对应,确保在后续的键合过程中可以位置对应,所述第三通孔411可以用本领域技术人员所熟知的刻蚀的方法形成,不再赘述。在本实施例中,优选的,第三通孔表面钝化层为金属构成,包括但不限于金属铝、钛、钴、钨、钽、镍、金、银及其任何合金物。可以在清洗步骤中保护第三通孔表面,也使得清洗更加容易去除杂质。S8212, referring to FIG. 16 , forming a third mask optical alignment mark 405 on the third mask 400, and a third through hole array composed of a plurality of third through holes 411; The spacing between them and the order of arrangement are in one-to-one correspondence with the positions of the first electrodes 111 or the second lower electrodes 121 on the silicon-based backplate, so as to ensure that the positions can be corresponding in the subsequent bonding process, and the third through holes 411 It can be formed by an etching method well known to those skilled in the art, and will not be repeated here. In this embodiment, preferably, the surface passivation layer of the third through hole is made of metal, including but not limited to aluminum, titanium, cobalt, tungsten, tantalum, nickel, gold, silver and any alloy thereof. The surface of the third through hole can be protected during the cleaning step, which also makes cleaning easier to remove impurities.
S8213,参考图16,将第三掩膜板平行置于硅基背板之上,形成所述第三掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位;S8213, referring to FIG. 16 , placing a third mask in parallel on the silicon-based backplane to form a vertical optical alignment between the optical alignment mark of the third mask and the optical alignment mark of the substrate;
S8214,参考图16,基于所述第三掩膜板光学对位标405与所述基板光学对位标志105的垂直光学对位,形成第三掩膜板下表面402与硅基背板上表面101的临时键合从而使得所述第三通孔411恰好暴露第三下电极131。在本实施例中,同样值得注意的是,由于已经在硅基背板上表面102形成覆盖第一下电极111的第一LED发射层151以及形成覆盖第二下电极112的第二LED发射层152,因此在本实施例中,第三掩模板400和硅基背板100之间的键合是通过粘附底部垫片实现的,从而将第一LED发射层151和第二LED发射层152架空,架空的高度要超过第一LED发射层151和第二LED发射层的顶层相对硅基表面的高度,使其不受损伤,也避免在沉积第三LED发射层153时不至于与第三通孔底部粘连。如果是采用静电吸附的方式实现第三掩膜板400的下表面402与所述硅基背板100上表面101的临时键合,为了实现静电隔离,底部垫片220以介电质材料构成为好。S8214, referring to FIG. 16 , based on the vertical optical alignment between the third mask optical alignment mark 405 and the substrate optical alignment mark 105, form the third mask lower surface 402 and the upper surface of the silicon substrate backplane. The temporary bonding of 101 makes the third through hole 411 just expose the third bottom electrode 131 . In this embodiment, it is also worth noting that since the first LED emitting layer 151 covering the first lower electrode 111 and the second LED emitting layer covering the second lower electrode 112 have been formed on the upper surface 102 of the silicon substrate backplane 152, so in this embodiment, the bonding between the third mask plate 400 and the silicon-based backplane 100 is realized by adhering the bottom pad, so that the first LED emission layer 151 and the second LED emission layer 152 Overhead, the height of the overhead will exceed the height of the top layer of the first LED emission layer 151 and the second LED emission layer relative to the surface of the silicon base, so that it will not be damaged, and it will also avoid contact with the third LED emission layer 153 when depositing the third LED emission layer 153. Via bottom sticking. If the temporary bonding between the lower surface 402 of the third mask 400 and the upper surface 101 of the silicon-based backplane 100 is achieved by electrostatic adsorption, in order to achieve electrostatic isolation, the bottom gasket 220 is made of a dielectric material. it is good.
除此之外,在其它实施例中也可以采用其他的方法键合,例如在第三掩膜板或者硅基背板可以包括具有凹槽的介质层,从而通过热熔的方式进行键合,使得第一LED发射层和第二LED发射层位于所述凹槽内。In addition, other bonding methods can also be used in other embodiments, for example, the third mask or the silicon-based backplane can include a dielectric layer with grooves, so as to perform bonding by thermal fusion, The first LED emitting layer and the second LED emitting layer are located in the groove.
其中,所述第一掩膜板、第三掩膜板和第三掩膜板分别与硅基背板的临时键合,均可以通过所述静电吸附底板对第一掩膜板的静电吸附作用来实现。当然也可以凭借多个边缘夹具610个别与硅基背板100形成机械钳夹来实现的。Wherein, the temporary bonding of the first mask, the third mask and the third mask to the silicon-based backplane respectively can be achieved through the electrostatic adsorption effect of the electrostatic adsorption base on the first mask. to fulfill. Of course, it can also be realized by means of a plurality of edge clamps 610 individually forming mechanical clamps with the silicon-based backplane 100 .
S8215,从第三掩膜板上表面401上方通过所述第三通孔411将第三LED发射层153沉积于硅基背板上表面101所披露的多个第三子像素区域所构成第三子像素区域阵列内;所述的第一子像素区域、第二子像素区域和第三子像素区域中的任意两者在硅基背板上表面上不相交或重叠。S8215, depositing the third LED emission layer 153 on the upper surface 101 of the silicon substrate backplane from above the upper surface 401 of the third mask plate through the third through hole 411 to form a third In the sub-pixel area array; any two of the first sub-pixel area, the second sub-pixel area and the third sub-pixel area do not intersect or overlap on the upper surface of the silicon substrate backplane.
所述的第三LED发射层优选的为无机半导体构成,除此之外也可以为有机化合物半导体构成。所述第三LED发射层的沉积,是通过蒸镀、气相沉积和喷墨印刷中的任何一种方法实现的,例如蒸镀。The third LED emitting layer is preferably composed of an inorganic semiconductor, and may also be composed of an organic compound semiconductor. The deposition of the third LED emitting layer is realized by any one method among evaporation, vapor deposition and inkjet printing, such as evaporation.
S8217,参考图17解除第三掩膜板400与硅基背板100的临时键合,并移开第三掩膜板400。S8217 , referring to FIG. 17 , releasing the temporary bonding between the third mask 400 and the silicon-based backplane 100 , and removing the third mask 400 .
参考图18,在移开第三掩膜板步骤之后、形成透明的密封封盖步骤之前,进一步包括:Referring to FIG. 18, after the step of removing the third mask plate and before the step of forming a transparent sealing cover, further include:
在硅基背板上表面上,形成与第一LED发射151、第二LED发射层152和第三LED发射层153物理接触的共享上电极薄膜180。On the upper surface of the silicon base backplane, a shared upper electrode film 180 is formed in physical contact with the first LED emitter 151 , the second LED emitter layer 152 and the third LED emitter layer 153 .
S90,参考图19,在硅基背板上表面101形成透明的密封封盖190。S90, referring to FIG. 19 , forming a transparent sealing cover 190 on the upper surface 101 of the silicon substrate backplane.
在上述实施例中,优选的,第一掩膜板、第二掩膜板和第三掩膜板中至少之一是由硅构成。优选的方案包括,在所有掩膜板采用与硅基背板同一大小的硅晶圆片制成,以确保掩膜板与硅基背板具有同样的热膨胀系数,以减少在加工过程的升温所引起的掩膜板及其通孔与硅基背板在水平方向位错。In the above embodiment, preferably, at least one of the first mask, the second mask and the third mask is made of silicon. The preferred solution includes that all masks are made of silicon wafers of the same size as the silicon-based backplane, so as to ensure that the mask and the silicon-based backplane have the same coefficient of thermal expansion, so as to reduce the temperature increase during processing. The mask plate and its through holes are dislocated in the horizontal direction with the silicon-based backplane.
优选的,第一通孔、第二通孔和第三通孔表面至少之一镀有一层通孔表面钝化层。在整个所述的表面钝化层选用与硅基具有较好粘合性的金属或合金构成,包括但不限于金属铝、钛、钴、钨、钽、镍、金、银及其任何合金物。这样不仅可以减少在沉积过程中LED发光材料对掩膜板尤其是通孔表面的腐蚀,也可以在解除掩膜板与硅基背板间的临时键合后,对要重复使用的掩膜板进行清洗过程对掩膜板表面的腐蚀,从而提高掩膜板的重复利用率、降低成本。Preferably, at least one of the surfaces of the first through hole, the second through hole and the third through hole is plated with a passivation layer on the surface of the through hole. The entire surface passivation layer is made of metals or alloys with good adhesion to the silicon base, including but not limited to metals such as aluminum, titanium, cobalt, tungsten, tantalum, nickel, gold, silver and any alloys thereof . This can not only reduce the corrosion of the LED luminescent material on the mask plate, especially the surface of the through hole, but also remove the temporary bonding between the mask plate and the silicon-based backplane, and the mask plate to be reused The cleaning process corrodes the surface of the mask plate, thereby improving the reusability of the mask plate and reducing costs.
优选的,所述的第一LED发射层、第三LED发射层和第三LED发射层至少之一为无机半导体或有机化合物半导体构成。Preferably, at least one of the first LED emitting layer, the third LED emitting layer and the third LED emitting layer is composed of an inorganic semiconductor or an organic compound semiconductor.
优选的,所述的共享上电极薄膜为LED的阳极,具有较高的逸出功,并由较透明的铟锡氧化物(ITO)或掺铟氧化锌(IZO)构成;所述的第一下电极、第二下电极或第三下电极为具有较低逸出功的LED阴极,并由金属Mg、Ca、Al、Ag以及它们的合金材料构成。Preferably, the shared upper electrode film is the anode of the LED, has a relatively high work function, and is composed of relatively transparent indium tin oxide (ITO) or indium-doped zinc oxide (IZO); the first The lower electrode, the second lower electrode or the third lower electrode is an LED cathode with a relatively low work function, and is composed of metals such as Mg, Ca, Al, Ag and their alloy materials.
优选的,所述的第一下电极、第二下电极或第三下电极为具有较高逸出功的LED阳极,由铟锡氧化物(ITO)或掺铟氧化锌(IZO)构成,所述的共享上电极薄膜为具有较低逸出功且透光率较高的LED阴极,由金属Mg、Ca、Al、Ag以及它们的合金材料构成。Preferably, the first lower electrode, the second lower electrode or the third lower electrode is an LED anode with a relatively high work function, which is composed of indium tin oxide (ITO) or indium-doped zinc oxide (IZO), so The shared upper electrode thin film is an LED cathode with low work function and high light transmittance, and is composed of metals Mg, Ca, Al, Ag and their alloy materials.
优选的,所述的第一LED发射层、第三LED发射层和第三LED发射层相互有别,分别为对应不同光谱区域的发光材料,以通过组合生成期望的色域。Preferably, the first LED emitting layer, the third LED emitting layer and the third LED emitting layer are different from each other, being luminescent materials corresponding to different spectral regions, so as to generate a desired color gamut through combination.
优选的,所述的第一LED发射层、第三LED发射层和第三LED发射层相互有别,每个分别为对应红、蓝、绿三原色中的一个原色发光材料,也就是显示器最常见的三原色组合。Preferably, the first LED emission layer, the third LED emission layer and the third LED emission layer are different from each other, and each is a primary color luminescent material corresponding to the three primary colors of red, blue, and green, that is, the most common display combination of the three primary colors.
优选的,所述的第一LED发射层、第三LED发射层和第三LED发射层相互有别,每个分别为对应黄、品红、青三原色中的一个原色发光材料,即显示器另一个最常见的三原色组合。Preferably, the first LED emission layer, the third LED emission layer and the third LED emission layer are different from each other, and each is a primary color luminescent material corresponding to one of the three primary colors of yellow, magenta, and cyan, that is, the other of the display The most common combination of the three primary colors.
优选的,所述第一LED发射层、第二LED发射层或第三LED发射层的沉积,是通过蒸镀、气相沉积和喷墨印刷中的任何一种方法实现的。Preferably, the deposition of the first LED emitting layer, the second LED emitting layer or the third LED emitting layer is achieved by any one method among evaporation, vapor deposition and inkjet printing.
优选的,所述在硅基背板上表面形成多个第一下电极构成第一下电极阵列、同等数目的第二下电极构成第二下电极阵列和同等数目的第三下电极构成第三下电极阵列的步骤,也可以采用同样的含有通孔阵列的掩膜板与硅基背板键合以及穿过通孔的电极材料沉积来实现,具体的步骤包括:Preferably, a plurality of first lower electrodes are formed on the upper surface of the silicon substrate to form a first lower electrode array, an equal number of second lower electrodes forms a second lower electrode array, and an equal number of third lower electrodes forms a third lower electrode array. The step of the lower electrode array can also be achieved by bonding the same mask plate containing the through hole array to the silicon backplane and depositing the electrode material through the through holes. The specific steps include:
提供第四掩膜板,包含第四掩膜板上表面和相对的第四掩膜板下表面;providing a fourth mask plate, including the upper surface of the fourth mask plate and the opposite lower surface of the fourth mask plate;
在第四掩膜板上形成第四掩膜板光学对位标志,以及多个第一电极沉淀通孔组成第一电极沉淀通孔阵列、同等数目的第二电极沉淀通孔组成第二电极沉淀通孔阵列和同等数目的第三电极沉淀通孔组成第三电极沉淀通孔阵列;Form the fourth mask plate optical alignment mark on the fourth mask plate, and a plurality of first electrode precipitation through holes form the first electrode precipitation through hole array, and the same number of second electrode precipitation through holes form the second electrode precipitation The through hole array and the same number of third electrode precipitation through holes form the third electrode precipitation through hole array;
将第四掩膜板平行置于硅基背板之上,形成基板光学对位标志与第四掩膜板光学对位标志的垂直光学对位;placing the fourth mask in parallel on the silicon-based backplane to form a vertical optical alignment between the optical alignment mark of the substrate and the optical alignment mark of the fourth mask;
基于所述第四掩膜板光学对位标志与所述基板光学对位标志的垂直光学对位,形成第四掩膜板下表面与硅基背板上表面的临时键合;Based on the vertical optical alignment between the fourth mask optical alignment mark and the substrate optical alignment mark, forming a temporary bond between the lower surface of the fourth mask plate and the upper surface of the silicon substrate backplane;
从第四掩膜板上表面上方通过第一电极沉淀通孔、第二电极沉淀通孔和第三电极沉淀通孔将共享LED下电极材料,分别沉积在相对应的第一子像素区域、第二子像素区域和第三子像素区域内;Through the first electrode precipitation through hole, the second electrode precipitation through hole and the third electrode precipitation through hole from above the upper surface of the fourth mask plate, the shared LED lower electrode material is respectively deposited in the corresponding first sub-pixel area, the second In the second sub-pixel area and the third sub-pixel area;
解除第四掩膜板下表面与硅基背板上表面的临时键合,并移开第四掩膜板。The temporary bonding between the lower surface of the fourth mask plate and the upper surface of the silicon substrate backplane is released, and the fourth mask plate is removed.
上述针对硅基背板OLED微显示器的制造方法,同样适用于硅基背板上以无机半导体LED为自发光元器件的微显示器的制造。例如,第一LED发射层可以是产生蓝光的无机半导体LED薄膜材料氮化镓,而将其通过第一通孔阵列沉积于硅基背板第一电极阵列电极上的方法可以最常用的金属有机化学气相沉积(MOCVD)。此外,第二LED发射层和第三LED发射层,既可以采用产生红和绿原色的无机半导体材料砷化镓和磷化镓,也同样可以是产生蓝光原色的氮化镓配合置于其上的红色和绿色荧光材料来实现三元色显示。The above-mentioned method for manufacturing OLED microdisplays on silicon-based backplanes is also applicable to the manufacture of microdisplays using inorganic semiconductor LEDs as self-luminous components on silicon-based backplanes. For example, the first LED emission layer can be gallium nitride, an inorganic semiconductor LED thin film material that produces blue light, and the method of depositing it on the first electrode array electrode of the silicon-based backplane through the first through hole array can be the most commonly used metal organic Chemical Vapor Deposition (MOCVD). In addition, the second LED emission layer and the third LED emission layer can be made of inorganic semiconductor materials gallium arsenide and gallium phosphide that produce red and green primary colors, or gallium nitride that produces blue primary colors can be placed on them. Red and green fluorescent materials are used to realize three-color display.
此外,上述针对硅基背板OLED微显示器的制造方法,也同样适用于超过三原色组合的硅基背板OLED微显示器制造;例如,可以采用五原色组合,来进一步拓宽较常见的红绿蓝三原色组合所能表征的色域幅度。同样,上述披露的方法,凭借含有单一通孔阵列(如第一通阵列)的单一掩膜板(如第一掩膜板)与硅基背板的高精度对位临时键合,也同样适用于以纯白色OLED发射层配置红、绿、蓝三色透明彩色滤光阵列的显示器的制造。In addition, the above-mentioned manufacturing method for silicon-based backplane OLED microdisplays is also applicable to the manufacture of silicon-based backplane OLED microdisplays with more than three primary color combinations; for example, five primary color combinations can be used to further broaden the more common red, green and blue three primary colors The range of color gamuts that can be represented by the combination. Similarly, the method disclosed above is also applicable to the high-precision alignment temporary bonding of a single mask plate (such as the first mask plate) containing a single through-hole array (such as the first through-hole array) and a silicon-based backplane. It is used in the manufacture of displays with red, green and blue transparent color filter arrays configured with pure white OLED emission layers.
显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内,则本发明也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the present invention without departing from the spirit and scope of the present invention. Thus, if these modifications and variations of the present invention fall within the scope of the claims of the present invention and equivalent technologies thereof, the present invention also intends to include these modifications and variations.
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