CN107312409A - A kind of aqueous, environmental protective antibiotic paint - Google Patents
A kind of aqueous, environmental protective antibiotic paint Download PDFInfo
- Publication number
- CN107312409A CN107312409A CN201710584663.6A CN201710584663A CN107312409A CN 107312409 A CN107312409 A CN 107312409A CN 201710584663 A CN201710584663 A CN 201710584663A CN 107312409 A CN107312409 A CN 107312409A
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- aqueous
- water
- environmental protective
- antibiotic paint
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of aqueous, environmental protective antibiotic paint, include the raw material of following parts by weight：Citrus terpene oil：1 10 parts, eugenol：1 10 parts, honokiol：15 parts, water-based acrylic resin：10 25 parts, color stuffing：10 30 parts, levelling agent：13 parts, dispersant：13 parts, defoamer：13 parts, rheological agent：13 parts, water：50 80 parts.The aqueous, environmental protective antibiotic paint of the present invention has the good feature of environmental protection, using natural antipathogenic composition：Citrus terpene oil, eugenol and honokiol, the growth of microorganism can effectively be suppressed, restraining and sterilizing bacteria, purification air, and the present invention uses Multiple components science compounding use, composition is reasonable, obtained coating has excellent tack, mechanical property, filming performance, antibiotic property, is a kind of coating of excellent quality.
Description
Technical field
The present invention relates to paint field, a kind of aqueous, environmental protective antibiotic paint is specifically related to.
Background technology
In life, people inevitably touch the microorganisms such as various bacteriums, fungi, and these microorganisms exist
It under suitable external condition, can rapidly breed, and be spread disease by modes such as contacts, it is some moist especially in domestic environment
Occasion (such as kitchen, toilet) is easier cooperating microorganisms, causes room air bacterium dense and the article surface dense increase of bacterium, shadow
Ring healthy and normal work, the studying and living of people.Therefore the research and application of antibiotic property coating are to the protection mankind
Health, tool of bettering people's living environment is of great significance.
Chinese patent application CN201110407686 be related to a kind of high-efficiency environment friendly antibacterial gas defence inorganic composite nano coating and
Its preparation method, including inorganic composite nano antiseptic thickened pulp, negative ion powder, emulsion etc..The shortcoming of the technology is original used
Expect that Alternative is complicated, such as maleic anhydride dust and steam have obvious irritation in coating, and pharyngitis, bronchitis can be caused after suction
Deng and direct skin contact has obvious stimulation effect, and causes and burn.
The content of the invention
There is provided a kind of very excellent aqueous, environmental protective antibacterial painting of anti-microbial property according to the deficiencies in the prior art by the present invention
Material.
To achieve the above object, the present invention is adopted the following technical scheme that：
The present invention provides a kind of aqueous, environmental protective antibiotic paint, includes the raw material of following parts by weight：
Citrus terpene oil：1-10 parts；
Eugenol：1-10 parts；
Honokiol：1-5 parts.
Further, the aqueous, environmental protective antibiotic paint, includes the raw material of following parts by weight：
Water-based acrylic resin：10-25 parts；
Color stuffing：10-30 parts；
Levelling agent：1-3 parts；
Dispersant：1-3 parts；
Defoamer：1-3 parts；
Rheological agent：1-3 parts；
Water：50-80 parts.
Further, the aqueous, environmental protective antibiotic paint, includes the raw material of following parts by weight：
Citrus terpene oil：3-8 parts；
Eugenol：3-8 parts；
Honokiol：2-4 parts；
Water-based acrylic resin：15-20 parts；
Color stuffing：15-25 parts；
Levelling agent：1.5-2.5 part；
Dispersant：1.5-2.5 part；
Defoamer：1.5-2.5 part；
Rheological agent：1.5-2.5 part；
Water：60-70 parts.
Further, the color stuffing is at least one of calcium carbonate superfine powder, barium sulfate, silica, kaolin.
Further, the aqueous, environmental protective antibiotic paint, is made up of the raw material of following parts by weight：
Citrus terpene oil：5 parts；
Eugenol：5 parts；
Honokiol：3 parts；
Water-based acrylic resin：17 parts；
Calcium carbonate superfine powder：20 parts；
Levelling agent：2 parts；
Dispersant：2 parts；
Defoamer：2 parts；
Rheological agent：2 parts；
Water：65 parts.
Further, the present invention also provides a kind of preparation method of aqueous, environmental protective antibiotic paint：First by water soluble acrylic acid tree
Fat is added to the water, and is stirring evenly and then adding into after color stuffing, 20-40min and sequentially adds dispersant, defoamer, levelling agent, stirs 5-
10min, mixing speed is 3000-4000r/min, is subsequently added into citrus terpene oil, eugenol, honokiol, stirs 5-10min,
Mixing speed is 3000-4000r/min, is eventually adding rheological agent, obtains aqueous, environmental protective antibiotic paint.
Citrus is a kind of plant of Rutaceae Aurantiae, has six category.China is among the people to burn cigarette drive with regard to useful orange peel
The practice of mosquitos and flies is caught up with, this is had proven to both at home and abroad and is mainly by the citrus oils in orange peel in action, this explanation citrus oils has
Good bactericidal action.
Cloves has had very long history in the use of China.Its volatile oil main component-eugenol (4- pi-allyls -2-
Metoxyphenol, engenol) there is stronger suppression bacterial fungus to act on, and to thermally-stabilised within 100 DEG C.Citrus oils
The active ingredient of bioactivity is terpene oil therein (mainly (R)-4-isopropenyl-1-methyl-1-cyclohexene), and terpene oil is largely given up during the de- terpene of citrus essential oil is produced
The accessory substance abandoned.
The bark of official magnolia (cortex magnoliae officinalis) is a kind of rare Chinese medicine of Sichuan special product, is mainly grown in the Sichuan Basin 800~1700m's of height above sea level
Knob, belongs to the rare and endangered medicinal plant of national second class protection.Recorded according to medical book, the bark of official magnolia has middle benefit gas, promoting the circulation of qi, dry
Wet, eliminating the phlegm work(.Foreign Modern pharmacological testing proves that the bark of official magnolia has broad spectrum antibacterial.The active ingredient of the bark of official magnolia is mainly from the bark of official magnolia
Root skin, the phenolic compound (mainly magnolol and honokiol) of separation is extracted in branch skin.Honokiol is a kind of biphenyl
Phenolic compound, is one of principle active component of the bark of official magnolia.
Compared with prior art, beneficial effects of the present invention are：With the good feature of environmental protection, using it is natural it is antibacterial into
Point：Citrus terpene oil, eugenol and honokiol, can effectively suppress the growth of microorganism, restraining and sterilizing bacteria, purification air, safety
It is non-stimulated, and the present invention uses Multiple components science compounding use, and composition is reasonable, and obtained coating has excellent attachment
Property, mechanical property, filming performance, antibiotic property, are a kind of coating of excellent quality.
Embodiment
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of aqueous, environmental protective antibiotic paint, is made up of the raw material of following parts by weight：
Citrus terpene oil：5 parts；
Eugenol：5 parts；
Honokiol：3 parts；
Water-based acrylic resin：17 parts；
Calcium carbonate superfine powder：20 parts；
Levelling agent：2 parts；
Dispersant：2 parts；
Defoamer：2 parts；
Rheological agent：2 parts；
Water：65 parts.
The preparation method of above-mentioned aqueous, environmental protective antibiotic paint, comprises the following steps：
First water-based acrylic resin is added to the water, is stirring evenly and then adding into after calcium carbonate superfine powder, 20min and sequentially adds point
Powder, defoamer, levelling agent, stir 5min, mixing speed is 3000r/min, are subsequently added into citrus terpene oil, eugenol and thickness
Plain phenol, stirs 5min, mixing speed is 3000r/min, is eventually adding rheological agent, obtains aqueous, environmental protective antibiotic paint.
Embodiment 2
A kind of aqueous, environmental protective antibiotic paint, is made up of the raw material of following parts by weight：
Citrus terpene oil：3 parts；
Eugenol：3 parts；
Honokiol：2 parts；
Water-based acrylic resin：15 parts；
Barium sulfate：10 parts；
Silica：5 parts；
Levelling agent：1.5 part；
Dispersant：1.5 part；
Defoamer：1.5 part；
Rheological agent：1.5 part；
Water：60 parts.
The preparation method of above-mentioned aqueous, environmental protective antibiotic paint, comprises the following steps：
First water-based acrylic resin is added to the water, is stirring evenly and then adding into after barium sulfate, silica, 30min successively
Dispersant, defoamer, levelling agent are added, 6min is stirred, mixing speed is 3500r/min, citrus terpene oil, cloves is subsequently added into
Phenol, honokiol, stir 6min, mixing speed is 3500r/min, is eventually adding rheological agent, obtains aqueous, environmental protective antibiotic paint.
Embodiment 3
A kind of aqueous, environmental protective antibiotic paint, is made up of the raw material of following parts by weight：
Citrus terpene oil：8 parts；
Eugenol：8 parts；
Honokiol：4 parts；
Water-based acrylic resin：20 parts；
Barium sulfate：15 parts；
Kaolin：10 parts；
Levelling agent：2.5 part；
Dispersant：2.5 part；
Defoamer：2.5 part；
Rheological agent：2.5 part；
Water：70 parts.
The preparation method of above-mentioned aqueous, environmental protective antibiotic paint, comprises the following steps：
First water-based acrylic resin is added to the water, is stirring evenly and then adding into after barium sulfate, kaolin, 40min and adds successively
Enter dispersant, defoamer, levelling agent, stir 7min, mixing speed is 4000r/min, be subsequently added into citrus terpene oil, eugenol,
Honokiol, stirs 7min, mixing speed is 4000r/min, is eventually adding rheological agent, obtains aqueous, environmental protective antibiotic paint.
Embodiment 4
A kind of aqueous, environmental protective antibiotic paint, is made up of the raw material of following parts by weight：
Citrus terpene oil：1 part；
Eugenol：1 part；
Honokiol：1 part.
Water-based acrylic resin：10 parts；
Calcium carbonate superfine powder：10 parts；
Levelling agent：1 part；
Dispersant：1 part；
Defoamer：1 part；
Rheological agent：1 part；
Water：50 parts.
The preparation method of above-mentioned aqueous, environmental protective antibiotic paint, comprises the following steps：
First water-based acrylic resin is added to the water, is stirring evenly and then adding into after calcium carbonate superfine powder, 25min and sequentially adds point
Powder, defoamer, levelling agent, stir 9min, mixing speed is 3500r/min, are subsequently added into citrus terpene oil, eugenol and thickness
Plain phenol, stirs 9min, mixing speed is 3500r/min, is eventually adding rheological agent, obtains aqueous, environmental protective antibiotic paint.
Embodiment 5
A kind of aqueous, environmental protective antibiotic paint, is made up of the raw material of following parts by weight：
Citrus terpene oil：10 parts；
Eugenol：10 parts；
Honokiol：5 parts.
Water-based acrylic resin：25 parts；
Barium sulfate：20 parts；
Silica：10 parts；
Levelling agent：3 parts；
Dispersant：3 parts；
Defoamer：3 parts；
Rheological agent：3 parts；
Water：80 parts.
The preparation method of above-mentioned aqueous, environmental protective antibiotic paint, comprises the following steps：
First water-based acrylic resin is added to the water, is stirring evenly and then adding into after barium sulfate, silica, 35min successively
Dispersant, defoamer, levelling agent are added, 10min is stirred, mixing speed is 4000r/min, citrus terpene oil, cloves is subsequently added into
Phenol, honokiol, stir 10min, mixing speed is 4000r/min, is eventually adding rheological agent, obtains aqueous, environmental protective antibiotic paint.
Comparative example 1
In addition to citrus terpene oil is not added with component, other components and preparation method are same as Example 1.
Comparative example 2
In addition to eugenol is not added with component, other components and preparation method are same as Example 1.
Comparative example 3
In addition to honokiol is not added with component, other components and preparation method are same as Example 1.
Comparative example 4
In addition to citrus terpene oil, eugenol, honokiol are not added with component, other components and preparation method and embodiment 1
It is identical.
Antibacterial film coating performance test
Preferably to prove that a kind of aqueous, environmental protective antibiotic paint provided by the present invention has excellent effect, choose and implement
Example 1,2,3,4,5 distinguishes roller coat in applying body surface with comparative example 1,2,3,4, and gained film carries out performance described in following table and surveyed
Examination.
Table 1, table 2 are test index and result.
Table 1
Table 2
As a result show：
From table 1, embodiment 1-5 prepares the equal flat smooth of film, no demoulding cracking phenomena, with excellent attachment
Property, mechanical property, filming performance, antibiotic property.Table 2 is understood with the contrast of table 1, adds citrus terpene oil, eugenol, the reality of honokiol
Apply an antibiotic rate for 1-5 coating higher, and far above comparative example 1-4, show that its anti-microbial property is very excellent, show citrus
Terpene oil, eugenol, the addition of honokiol make coating have excellent anti-microbial property.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art is in the technical scope of present disclosure, the change or replacement that can be readily occurred in,
It should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection of claims
Scope is defined.
Claims (6)
1. a kind of aqueous, environmental protective antibiotic paint, it is characterised in that include the raw material of following parts by weight：Citrus terpene oil：1-10 parts,
Eugenol：1-10 parts, honokiol：1-5 parts.
2. aqueous, environmental protective antibiotic paint according to claim 1, it is characterised in that also include the original of following parts by weight
Material：Water-based acrylic resin：10-25 parts, color stuffing：10-30 parts, levelling agent：1-3 parts, dispersant：1-3 parts, defoamer：1-3
Part, rheological agent：1-3 parts, water：50-80 parts.
3. aqueous, environmental protective antibiotic paint according to claim 2, it is characterised in that include the raw material of following parts by weight：
Citrus terpene oil：3-8 parts, eugenol：3-8 parts, honokiol：2-4 parts, water-based acrylic resin：15-20 parts, color stuffing：15-
25 parts, levelling agent：1.5-2.5 part, dispersant：1.5-2.5 part, defoamer：1.5-2.5 part, rheological agent：1.5-2.5 part, water：
60-70 parts.
4. the aqueous, environmental protective antibiotic paint according to Claims 2 or 3, it is characterised in that the color stuffing is ultra-fine carbonic acid
At least one of calcium, barium sulfate, silica, kaolin.
5. aqueous, environmental protective antibiotic paint according to claim 4, it is characterised in that by the raw material system of following parts by weight
Into：Citrus terpene oil：5 parts, eugenol：5 parts, honokiol：3 parts, water-based acrylic resin：17 parts, calcium carbonate superfine powder：20 parts,
Levelling agent：2 parts, dispersant：2 parts, defoamer：2 parts, rheological agent：2 parts, water：65 parts.
6. the preparation method of the aqueous, environmental protective antibiotic paint according to claim any one of 2-5, it is characterised in that including such as
Lower step：First water-based acrylic resin is added to the water, be stirring evenly and then adding into after color stuffing, 20-40min sequentially add it is scattered
Agent, defoamer, levelling agent, stir 5-10min, mixing speed is 3000-4000r/min, are subsequently added into citrus terpene oil, cloves
Phenol, honokiol, stir 5-10min, mixing speed is 3000-4000r/min, is eventually adding rheological agent, obtain aqueous, environmental protective and resist
Bacterium coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710584663.6A CN107312409A (en) | 2017-07-15 | 2017-07-15 | A kind of aqueous, environmental protective antibiotic paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710584663.6A CN107312409A (en) | 2017-07-15 | 2017-07-15 | A kind of aqueous, environmental protective antibiotic paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107312409A true CN107312409A (en) | 2017-11-03 |
Family
ID=60178912
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710584663.6A Pending CN107312409A (en) | 2017-07-15 | 2017-07-15 | A kind of aqueous, environmental protective antibiotic paint |
Country Status (1)
| Country | Link |
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| CN (1) | CN107312409A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603412A (en) * | 2017-10-16 | 2018-01-19 | 长春顺风新材料有限公司 | A kind of antimicrobial coating material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101818005A (en) * | 2010-02-21 | 2010-09-01 | 苏州科斯伍德油墨股份有限公司 | Antibacterial and bacteriostatic UV offset printing ink |
| CN105968973A (en) * | 2016-06-30 | 2016-09-28 | 河北晨阳工贸集团有限公司 | Mildew-proof, antibacterial and antiviral coating with Chinese herbal medicines and method for manufacturing mildew-proof, antibacterial and antiviral coating |
-
2017
- 2017-07-15 CN CN201710584663.6A patent/CN107312409A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101818005A (en) * | 2010-02-21 | 2010-09-01 | 苏州科斯伍德油墨股份有限公司 | Antibacterial and bacteriostatic UV offset printing ink |
| CN105968973A (en) * | 2016-06-30 | 2016-09-28 | 河北晨阳工贸集团有限公司 | Mildew-proof, antibacterial and antiviral coating with Chinese herbal medicines and method for manufacturing mildew-proof, antibacterial and antiviral coating |
Non-Patent Citations (2)
| Title |
|---|
| 常景玲: "《天然生物活性物质及其制备技术》", 31 August 2007, 河南科学技术出版社 * |
| 彭珊珊等: "《食品添加剂》", 31 January 2009, 中国轻工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603412A (en) * | 2017-10-16 | 2018-01-19 | 长春顺风新材料有限公司 | A kind of antimicrobial coating material and preparation method thereof |
| CN107603412B (en) * | 2017-10-16 | 2019-09-17 | 长春顺风新材料有限公司 | A kind of antimicrobial coating material and preparation method thereof |
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Application publication date: 20171103 |