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CN1073071A - Herbicidal composition with synergism - Google Patents

Herbicidal composition with synergism Download PDF

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Publication number
CN1073071A
CN1073071A CN92113786A CN92113786A CN1073071A CN 1073071 A CN1073071 A CN 1073071A CN 92113786 A CN92113786 A CN 92113786A CN 92113786 A CN92113786 A CN 92113786A CN 1073071 A CN1073071 A CN 1073071A
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consumption
mixture
colby
calculating
herbicide
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Inventor
G·约翰
R·里斯
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Merck Sharp and Dohme LLC
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Schering Corp
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
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Abstract

本文描述了一种具有增效活性的新的除草剂组 合物,其中含有2-[7-氟-3,4-二氢-3-氧代-4-(2- 丙炔基)-2H-1,4-苯并嗪-6-基]全氢化咪唑并[1, 5-a]吡啶-1,3-酮和选自下组包括的一种除草剂:草 甘膦(II),嘧黄隆(III),imazapyr(IV),2,4-滴(V), 麦草畏(VI),敌草隆(VII),氟黄草醚(VIII), glufosinate-ammonium(IX),杀草强(X),稀禾定 (XI),塞克津(XII),利谷隆(XIII),氟锁草醚 (XIV),克阔乐(XV),氟磺胺草醚(XVI),胺硝草 (XVII),草不绿(XVIII),丙草安(XIX),氟乐灵 (XX),氯嘧磺隆(XXI),imazaquin(XXII)和普杀特 (XXIII)的混合物。This paper describes a new herbicide group with synergistic activity compounds containing 2-[7-fluoro-3,4-dihydro-3-oxo-4-(2- Proynyl)-2H-1,4-benzoxazin-6-yl]perhydroimidazo[1, 5-a] pyridin-1,3-one and a herbicide selected from the group consisting of grass Glyphosate (II), rimsulfuron (III), imazapyr (IV), 2,4-D (V), Dicamba (VI), Diuron (VII), Fenzafen (VIII), glufosinate-ammonium(IX), abicide (X), sethoxydim (XI), Sekezin (XII), Liguron (XIII), Acifluorfen (XIV), Kekule (XV), Fomesafen (XVI), Pendimethalin (XVII), Grass Green (XVIII), Protraclon (XIX), Trifluralin (XX), chlorimuron-methyl (XXI), imazaquin (XXII) and Prozant Mixtures of (XXIII).

Description

Herbicidal composition with synergism
The present invention relates to a kind of synergistic activity of having, wherein contain 2-[7-fluoro-3.4-dihydro-3-oxo-4-(2-propinyl)-2H-1.4-benzoxazine-6-yl] herbicidal composition of mixture of all hydrogenated imidazo [1.5-a] pyridine-1.3-ketone and another kind of selective herbicide, with and in crop the purposes of controlling weeds.
2-[7-fluoro-3.4-dihydro-3-oxo-4-(2-propinyl)-and 2H-1.4-benzoxazine-6-yl] the weeding vigor of all hydrogenated imidazo [1.5-a] pyridine-1.3-ketone is known (Ep311135).This compound has following chemical constitution (I):
Figure 921137869_IMG1
Have been found that now, contain 2-[7-fluoro-3.4-dihydro-3-oxo-4-(2-propinyl as active ingredient)-2H-1.4-benzoxazine-6-yl] all hydrogenated imidazo [1.5-a] pyridine-1.3-ketone and be selected from down and organize the herbicide glyphosate (II) comprise, ethyl methyl (III), the imazapyr(IV), 2.4-drip (V) dicamba (VI), diuron (VII), fomesafen (VIII), the glufosinate-ammonium(IX), Amrol (X), and sethoxydim (XI), and metribuzin (XII), lorox (X III), acifluorfen (X IV) restrains wealthy pleasure (X V), fomesafen (X VI), pendimethalin (X VII), alachlor (X VIII), Bing Caoan (X IX), trefanocide (XX), chlorimuronethyl (X XI), imazaquin(X XII) and the herbicidal composition of the mixture of Imazethapyr (XX III), do not losing in crops optionally simultaneously, enlarged the weeds spectrum that to prevent and treat, and compared with single composition and to show high activity of weeding.
Glyphosate is the N-(phosphonomethyl) common name of glycine;
Sulfometuron Methyl is a 2-(4.6-lutidines-2-base carbamoyl sulfamoyl) common name of benzoic acid methyl ester;
Imazapyr is 2-(4-isopropyl-4-methyl-5-oxo-2-imidazoline-2-yl)-common name of nicotinic acid;
2.4-drip is 2-(4-chloro-2-methyl-benzene oxygen) common name of acetate;
Dicamba is 3.6-two chloro-2-methoxyl group-benzoic common names;
Diuron is the 3-(3.4-dichlorophenyl)-1,1)-common name of dimethyl urea;
Fomesafen is 2-chloro-α, α, and α-three fluoro-is right-common name of tolyl 3-Z oxygen base-4-nitrobenzophenone ether;
Glufosinate-ammonium is 4-[hydroxyl (methyl) phosphino-]-common name of DL-high lactamine ammonium;
Amrol is the common name of 1H-1.2.4-triazole-3-base amine;
Sethoxydim is (±)-(EZ)-2-(1-ethyoxyl imines butyl)-the 5-[2-(ethylmercapto group) propyl group]-common name of 3-hydroxyl hexamethylene-2-ketenes;
Metribuzin is the common name of 4-amino-6-tert-butyl-4.5-dihydro-3-methyl mercapto-1.2.4-triazine-5-ketone;
Lorox is the 3-(3.4-dichlorophenyl)-common name of 1-methoxyl group-1-methyl urea;
Acifluorfen is a 5-[2-chloro-4-(trifluoromethyl) phenoxy group]-common name of 2-nitrobenzoic acid;
Restraining wealthy pleasure is 5-[chloro-4-(trifluoromethyl) phenoxy group]-common name of 2-nitrobenzoic acid (±)-2-ethyoxyl-1-ethyl-2-oxygen ethyl ester;
Fomesafen is a 5-[2-chloro-4-(trifluoromethyl) phenoxy group]-the N-(methyl sulphonyl)-common name of 2-nitrobenzamide;
Pendimethalin is the N-(1-ethyl propyl)-common name of 3.4-dimethyl-2.6-dinitroaniline;
Alachlor is 2-chloro-2', the common name of 6'-diethyl-N-methoxy monoacetylaniline;
The third careless amine is 2-chloro-6'-ethyl-2'-methyl-N-(2-methoxyl group-1-Methylethyl) common name of monoacetylaniline;
Trefanocide is 2.6-dinitro-N, N-dipropyl-4-(trifluoromethyl) common name of aniline;
Chlorimuronethyl is a 2-(4-chloro-6-Sulfamonomethoxine-2-base carbamoyl sulfamoyl)-common name of benzoic acid ethyl ester;
Imazaquin is (±)-2-[4.5-dihydro-4-methyl-4-(1-Methylethyl)-5-oxo-1H-imidazoles-2-yl]-common name of 5-ethyl-3-picolinic acid; With
Imazethapyr is (±)-2-[4.5-dihydro-4-methyl-4-(1-Methylethyl)-5-oxo-1H-2-yl]-3-quinoline carboxylic acid's common name.
All these weed killer herbicides are described in " agricultural chemicals handbook " (" Pesticide Manual ", the 9th edition, 1991, London, the publication of Britain crop protection association) to some extent.
Various bond of the present invention is applicable to the annual and perennial weed that control is important, particularly in kind of plant and the perennial crop, for example in fruit tree, wine material crop, citrus, in forest and the appreciation and cultivation plant, in the non-planting season in arable land (for example stubble is handled), and at the industrial circle that comprises highway and railway.Further purposes is the main weeds in the control crop-planting zone, for example in the soybean planting district.
The bond of each active ingredient of the present invention can be used for resisting plant species described as follows:
Sinapis, separate row Vegetable spp, Bedstraw, Stellaria, Matricaria, Anthemis, ox achyranthes chrysanthemum spp, Chenopodium, Bu Lansishi Cymbidium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, japanese bearbind belongs to, Ipomoea, Polygonum, Daubentonia, Ambrosia, Cirsium, bristlethistle, sonchus, Solanum , Han Lepidium, lamium Fiber crops belong to, Datura,
Figure 921137869_IMG3
Lepidium, the weasel hemp nettle belongs to, papaver, the broadleaf weed of bachelor's-button and Chrysanthemum.
Avena, amur foxtail belongs to, Echinochloa, setaria, Panicum, knotgrass, annual bluegrass belongs to, belongs to, Brachiaria, lolium temulentum belongs to, Brome, Cyperus, Agropyron (wild wheat belongs to), Aunt belongs to, water mallow, genus fimbristylis, Eleocharis, ischaemum and strand monocotyledon weed that grain husk belongs to.
But I and II be to the bond preemergence application of XI, but and I and XII to the bond postemergence application of XX III.According to purposes, the amount of application of mixture is between 0.001 to 5 kilogram/hectare.Essential weed killer herbicide consumption generally can reduce to use this mixture to be used to control weeds.
Components I) and the weight ratio of other component generally between 50: 1 to 1: 100.
According to concrete needs, composition of the present invention also can with other activating agent, for example plant protection product or insecticide mix to use.
By adding action intensity and the speed that suitable adjuvant can be improved, for example, add as organic solvent, wetting agent and oils.This class additive dosage capable of reducing using.
Default active component or their mixture can use by rights, for example, added liquid and/or solid carrier and/or thinner, and also can at random have bonding, powder, pulvis, granule, liquor, emulsion or the suspending agent of moistening, emulsification and/or dispersing aid.
The liquid-carrier that is suitable for is as benzene, toluene, dimethylbenzene, cyclohexanone, isophorone, dimethyl sulfoxide (DMSO), the aliphatic series and the aromatic hydrocarbon of dimethyl formamide and other mineral oil fractions and plant oil.
The solid carrier that is suitable for comprises, bentonite for example, silica gel, talcum, kaolin, Attagel, lime stone, mineral soil and for example pulverous vegetable products of silicic acid.
As for surfactant, can use for example calcium lignosulfonate, polyoxyethylene alkyl phenyl ether, naphthalene sulfonic acids and its salt, phenolsulfonic acid and its salt, formaldehyde condensation products, the sulfuric ester of aliphatic alcohol, and the benzene sulfonic acid that replaces and its salt.
In various prepared products, the ratio of active constituent can change in very wide scope.For example, can contain the active component of about 10 to 90% weight in the composition, the liquid of about 90 to 10% weight or immobilization carrier, and, the surfactant of 20% weight nearly at random.
This preparation can be used with common mode, for example, is that the carrier mixing sprays approximately from 100 to 1000 liters/hectare of consumptions with water.This preparation can be with low capacity or ultra low volume technology, or uses in the mode of so-called fine granule.
The preparation of these preparations can be carried out with known method, for example with pulverizing or mixed method.Choose wantonly, independent component can be just before use with mixing as being commonly referred to a jar method of mixing.
Following example has illustrated the purposes of composition of the present invention.Synergistic effect is shown " synergy and the antagonistic effect that calculate Herbicidal mixtures " Weeds 15/1,1967 according to S.R.Cobly, and the method for 20-22 page or leaf is calculated.Wherein used following formula:
E=X+Y-XY/100
In the formula, the herbicide action (%) of X=substance A under P gram/hectare consumption,
The herbicide action (%) of Y=substance B under q gram/hectare consumption,
The herbicide action (%) that the give phase of E=substance A+B under P+q gram/hectare consumption increases.
If the observation beguine is big according to the numerical value of the E that Cobly calculates, then said composition has synergistic activity.
In the greenhouse, the plant species of listing among Table A-K is carried out the seedling post processing with various components with the consumption that illustrates.With 500 premium on currency diluted compositions, and be sprayed onto plant equably.Two weeks after treatment is estimated herbicidal effect.
Table A
The mixture of I and glyphosate (II)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Amaranthus retroflexus (Amaranthus retroflexus)
Ⅰ 1 80
Ⅱ 50 5
Ⅰ+Ⅱ 1+50 85 (81)
Earth almona (Cvperus esculentus)
Ⅰ 4 40
Ⅱ 400 5
Ⅰ+Ⅱ 4+400 90 (43)
The lyme grass that creeps
(Elvmus repens)
Ⅰ 4 50
Ⅱ 400 40
Ⅲ 4+400 85 (70)
Table B
The mixture of I and Sulfometuron Methyl (III)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Blunt shape arm shape grass
(Brachiaria mutica)
Ⅰ 8 10
Ⅲ 2 50
Ⅰ+Ⅲ 8+2 75 (59)
High sesbania
(Sesbania exaltata)
Ⅰ 4 20
Ⅲ 2 60
Ⅰ+Ⅲ 4+2 75 (68)
Bromegrass
(Bromus sp)
Ⅰ 8 20
Ⅲ 4 60
Ⅰ+Ⅲ 8+4 75 (68)
Table C
The mixture of I and imazapyr (IV)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Green foxtail
(Setaria viridis)
Ⅰ 1 30
Ⅳ 2 80
Ⅰ+Ⅳ 1+2 90 (86)
False Chinese sorghum
(Sorghum halepense)
Ⅰ 8 70
Ⅳ 1 20
Ⅰ+Ⅳ 8+1 90 (76)
Earth almona
(Cvperus esculentus)
Ⅰ 4 80
Ⅳ 4 10
Ⅰ+Ⅳ 4+4 98 (82)
Table D
I and 2.4-drip the mixture of (V)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Bidens pilosa
(Bidens pilosa)
I 4 60
V 100 0
200 10
I+V 4+100 80 (60)
4+200 85 (64)
High sesbania
(Sesbania exaltata)
I 4 40
8 80
V 100 0
I+V 4+100 90 (40)
8+100 98 (80)
Amaranthus retroflexus
(Amaranthus retroflexus)
I 2 70
V 50 10
200 20
I+V 2+50 90 (73)
2+200 90 (76)
Table E
The mixture of I and triallate (VI)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
High sesbania
(Sesbania exaltata)
I 1 20
VI 25 70
I+VI 1+25 90 (76)
Bidens pilosa
(Bidens pilosa)
I 1 40
VI 25 60
I+VI 1+25 85 (76)
Table F
The mixture of I and diuron (VII)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
High sesbania
(Sesbania exaltata)
I 0.5 0
1 0
2 30
4 90
VII 50 5
100 80
I+VII 0.5+100 95 (80)
1+100 95 (80)
2+50 75 (34)
4+50 95 (91)
Bidens pilosa
(Bidens pilosa)
I 2 50
4 65
8 80
VII 25 0
I+VII 2+25 85 (50)
4+25 99 (65)
8+25 100 (80)
Earth almona
(Cvperus esculentus)
I 8 40
VII 100 0
200 5
I+VII 8+100 70 (40)
8+200 80 (43)
Green foxtail
(Setaria viridis)
I 1 5
VII 100 70
I+VII 1+100 97 (72)
Table G
The mixture of I and fomesafen (VIII)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
High sesbania (Sesbania exaltata)
I 1 20
2 50
VIII 2 30
I+VIII 1+2 70 (49)
2+2 90 (65)
Amaranthus retroflexus (Amaranthus retroflexus)
I 1 60
VIII 2 70
I+VIII 1+2 98 (88)
Table H
The mixture of I and glufosinate-ammonium (IX)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Green foxtail
(Setaria viridis)
I 4 20
IX 80 60
I+IX 4+80 80 (68)
Blunt shape arm shape grass
(Brachiaria mutica)
I 8 20
IX 80 20
I+IX 8+80 95 (36)
False Chinese sorghum
(Sorghum halepense)
I 8 50
IX 40 0
I+IX 8+50 90 (50)
High sesbania
(Sesbania exaltata)
I 2 60
IV 80 0
I+IX 2+80 98 (60)
Table I
The mixture of I and Amrol (X)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Green foxtail
(Setaria viridis)
I 4 20
X 200 60
I+X 4+200 80 (68)
Blunt shape arm shape grass
(Bracharia mutica)
I 4 0
8 5
X 200 30
I+X 4+200 70 (30)
8+200 95 (33)
Bidens pilosa
(Bidens pilosa)
I 4 70
X 50 20
I+X 4+50 85 (76)
High sesbania
(Sesbania exaltata)
I 1 30
2 50
X 25 5
50 30
I+X 1+25 70 (33)
1+50 85 (51)
2+25 90 (53)
2+50 95 (65)
Table K
The mixture of I and sethoxydim (XI)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Green foxtail
(Setaria viridis)
I 4 10
XI 100 70
I+XI 4+100 98 (73)
Blunt shape arm shape grass
(Brachiaria mutica)
I 8 15
XI 50 80
I+XI 8+50 95 (83)
Bromegrass
(Bromus sp.)
I 2 10
XI 200 60
I+XI 2+200 85 (64)
In the greenhouse plant species of listing among the table L-W is carried out the seedling pre-treatment with various components with the consumption that illustrates, with 500 premium on currency diluted compositions, and be sprayed onto equably on the soil, two weeks after treatment is estimated herbicidal effect.
Table L
The mixture of I and metribuzin (XII)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean (Soiabohne)
I 4 0
8 0
XII 12.5 0
50 0
100 5
I+XII 4+12.5 5 (0)
8+12.5 5 (0)
4+50 0 (0)
8+50 5 (0)
4+100 5 (5)
8+100 10 (5)
Pharbitis purpurea
(Ipomoea purpurea)
I 8 60
XII 50 5
I+XII 8+50 70 (62)
Amaranthus retroflexus
(Amaranthus retroflexus)
I 4 10
8 10
XII 50 50
I+XII 4+50 98 (55)
8+50 98 (55)
Table M
The mixture of I and lorox (VIII)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean
(Soiabohne)
I 2 0
8 0
XIII 100 0
200 0
I+XIII 2+100 0 (0)
2+200 0 (0)
8+100 0 (6)
8+200 5 (5)
Amaranthus retroflexus
(Amaranthus retroflexus)
I 8 20
XIII 100 0
I+XIII 8+100 80 (20)
Pale persicaria
(Polygonum lapathiflolium)
I 2 20
XIII 200 50
I+XIII 2+200 80 (50)
Green foxtail
(Setaria viridis)
I 8 40
XIII 100 0
I+XIII 8+100 75 (40)
Table N
The mixture of I and acifluorfen (XIV)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean (Soiabohne)
I 2 0
4 20
8 40
XIV 10 0
20 5
40 10
I+XIV 2+10 0 (0)
2+20 10 (5)
2+40 0 (10)
4+10 0 (20)
4+20 20 (24)
4+40 10 (27)
8+10 20 (40)
8+20 50 (43)
8+40 10 (46)
Pharbitis purpurea
(Ipomoea purpurea)
I 8 70
XIV 10 0
20 10
I+XIV 8+10 85 (70)
8+20 95 (73)
Amaranthus retroflexus
(Amaranthus retroflexus)
I 4 40
XIV 40 30
I+XIV 4+40 90 (58)
Pale persicaria
(Polygonum lapathifolium)
I 8 80
XIV 10 0
I+XIV 8+10 95 (80)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
False Chinese sorghum
(Sorghum halepense)
I 2 20
XIV 20 70
I+XIV 2+20 90 (76)
Digitaria ischaemum (Schreib.) Schreib. Ex Mubl
(Digitaria ischaemum)
I 2 10
XIV 20 50
I+XIV 2+20 75 (55)
Table O
I and the mixture that restrains wealthy pleasure (XV)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean
(So
Figure 921137869_IMG5
abohne)
I 1 0
2 5
4 10
XV 20 0
I+XV 1+20 0 (0)
2+20 0 (5)
4+20 0 (10)
Amaranthus retroflexus
(Amaranthus retroflexus)
I 2 20
4 50
XV 20 40
I+XV 2+20 85 (52)
4+20 90 (70)
Pale persicaria
(Polygonum lapathiflolium)
I 2 40
4 70
XV 20 0
I+XV 2+20 90 (40)
4+20 95 (70)
Digitaria ischaemum (Schreib.) Schreib. Ex Mubl
(Digitaria ischaemum)
I 1 0
XV 20 50
I+XV 1+20 90 (50)
Table P
The mixture of I and fomesafen (XVI)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean (Soiabohne)
I 2 0
4 20
8 20
XVI 10 10
40 20
80 20
I+XVI 2+10 0 (10)
2+40 30 (20)
2+80 20 (20)
4+10 10 (28)
4+40 10 (36)
4+80 20 (36)
8+10 20 (28)
8+40 20 (36)
8+80 20 (36)
Pharbitis purpurea
(Impomoea purpurea)
I 8 60
XVI 40 20
80 40
I+XVI 8+40 90 (68)
8+80 95 (76)
Pale persicaria
(Polygonum lapathiflolium)
I 2 5
4 75
XVI 10 5
I+XVI 2+10 80 (8)
4+10 98 (77)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
False Chinese sorghum
(Sorghum halepense)
I 4 50
XVI 10 10
I+XVI 4+10 85 (55)
Digitaria ischaemum (Schreib.) Schreib. Ex Mubl
(Digitaria ischaemum)
I 4 50
XVI 10 30
I+XVI 4+10 90 (65)
Table Q
The mixture of I and pendimethalin (XV II)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean (Soiabohne)
I 2 0
4 0
8 0
XVII 25 0
200 0
I+XVII 2+25 0 (0)
4+25 0 (0)
8+25 0 (0)
2+200 0 (0)
4+200 0 (0)
8+200 0 (0)
Green foxtail
(Setaria viridis)
I 8 0
XVII 200 75
I+XVII 8+200 98 (75)
Pale persicaria
(Polvgonum lapathiflolium)
I 4 50
XVII 25 0
I+XVII 4+25 85 (50)
Amaranthus retroflexus
(Amaranthus retroflexus)
I 2 0
XVII 200 20
I+XVII 2+200 85 (20)
Table R
The mixture of I and alachlor (X VIII)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean
(Soiabohne)
I 4 0
8 0
XVIII 50 0
I+XVIII 4+50 0 (0)
8+50 0 (0)
Pale persicaria
(Polygonum lapathifolium)
I 4 20
8 80
XVIII 50 0
I+XVIII 4+50 95 (20)
8+50 100 (80)
Digitaria ischaemum (Schreib.) Schreib. Ex Mubl
(Digitaria ischaemum)
I 4 0
8 40
XVIII 50 30
I+XVIII 4+50 90 (30)
8+50 97 (58)
Table S
The mixture of the I and the third careless amine (XIX)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean
(Soiabohne)
I 4 0
8 0
XIX 50 0
100 0
I+XIX 4+50 0 (0)
8+50 0 (0)
4+100 0 (0)
8+100 0 (0)
Amaranthus retroflexus
(Amaranthus retroflexus)
I 8 40
XIX 100 0
I+XIX 8+100 70 (40)
Green foxtail
(Setaria viridis)
I 8 40
XIX 50 40
I+XIX 8+50 85 (64)
Digitaria ischaemum (Schreib.) Schreib. Ex Mubl
(Digitaria ischaemum)
I 4 20
8 30
XIX 50 60
I+XIX 4+50 90 (68)
8+50 95 (72)
Table T
The mixture of I and trefanocide (XX)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean
(Soiabohne)
I 2 0
4 10
8 10
XX 100 0
200 10
400 10
I+XX 2+100 0 (0)
4+100 0 (10)
8+100 10 (10)
2+200 0 (10)
4+200 10 (19)
8+200 10 (19)
2+400 0 (10)
4+400 0 (19)
8+400 10 (19)
Amaranthus retroflexus
(Amaranthus retroflexus)
I 4 50
XX 200 15
400 50
I+XX 4+200 90 (58)
4+400 95 (75)
Piemarker
(Abutilon theophrasti)
I 4 80
XX 400 15
I+XX 4+400 90 (83)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Pale persicaria
(Polygonum lapathifolium)
I 8 50
XX 200 0
400 10
I+XX 8+200 95 (50)
8+400 95 (55)
Big broomcorn millet
(Panicum maximum)
I 2 0
4 10
XX 100 90
I+XX 2+100 99 (90)
4+100 99 (91)
Table U
The mixture of I and chlorimuronethyl (XXI)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean
(Soiabohne)
I 8 0
XXI 4 0
8 0
I+XXI 8+4 5 (0)
8+8 5 (0)
Pharbitis purpurea
(Ipomoea purpurea)
I 8 5
XXI 4 40
I+XXI 8+4 70 (43)
Bidens pilosa
(Bidens pilosa)
I 8 0
XXI 8 70
I+XXI 8+8 80 (70)
Table V
I and ima
Figure 921137869_IMG6
The mixture of aguin (XX II)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean
(Soiabohne)
I 2 0
8 0
XXII 4 0
16 0
I+XXII 2+4 0 (0)
2+16 0 (0)
8+4 0 (0)
8+16 5 (0)
Pharbitis purpurea
(Ipomoea purpurea)
I 8 10
XXII 16 60
I+XXII 8+16 75 (64)
Amaranthus retroflexus
(Amaranthus retroflexus)
I 8 50
XXII 16 20
I+XXII 8+16 90 (60)
Pale persicaria
(Polvgonum lapathifolium)
I 2 20
XXII 4 20
I+XXII 2+4 80 (36)
Table W
The mixture of I and Imazethapyr (XX III)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Soybean
(Soiabohne)
I 1 0
2 0
4 0
8 0
XXIII 2 0
4 0
8 10
16 0
I+XXIII 1+2 0 (0)
1+4 0 (0)
1+8 0 (10)
1+16 0 (0)
2+2 0 (0)
2+4 0 (0)
2+8 0 (10)
2+16 0 (0)
4+2 0 (0)
4+4 0 (0)
4+8 0 (10)
4+16 0 (0)
8+2 0 (0)
8+4 0 (0)
8+8 0 (10)
8+16 10 (0)
Pharbitis purpurea
(Ipomoea purpurea)
I 8 15
XXIII 8 40
I+XXIII 8+8 70 (49)
E
Consumption (g/ha) herbicide action (%) (calculating) according to CoLby
Amaranthus retroflexus
(Amaranthus retroflexus)
I 4 75
XXIII 2 0
4 0
I+XXIII 4+2 85 (75)
4+4 85 (75)
Pale persicaria
(Polygonum lapathifolium)
I 4 70
XXIII 2 10
I+XXIII 4+2 95 (73)
Green foxtail
(Setaria viridis)
I 1 0
2 0
XXIII 16 50
I+XXIII 1+16 75 (50)
2+16 80 (50)

Claims (4)

1、一种除草剂组合物,其中含有2-[7-氟-3.4-二氢-3-氧代-4-(2-丙炔基)-2H-1.4-苯并噁嗪-6-基]全氢化咪唑并[1.5-a]吡啶-1.3-酮和选自下组包括的一种除草剂的混合物:草甘膦(Ⅱ),嘧黄隆(Ⅲ),imazapy(Ⅳ)2.4-滴(Ⅴ),麦草畏(Ⅵ),敌草隆(Ⅶ),氟黄草醚(Ⅷ),glufosinate-ammonium(Ⅸ),杀草强(Ⅹ),稀禾定(Ⅺ),塞克津(Ⅻ),利谷隆(ⅩⅢ),氟锁草醚(ⅩⅣ),克阔乐(ⅩⅤ),氟磺胺草醚(ⅩⅥ),胺硝草(ⅩⅦ),草不绿(ⅩⅧ),丙草安(ⅩⅨ),氟乐灵(ⅩⅩ),氯嘧磺隆(ⅩⅪ),imazaquin(ⅩⅫ)和普杀特(ⅩⅩⅢ)。1. A herbicide composition containing 2-[7-fluoro-3.4-dihydro-3-oxo-4-(2-propynyl)-2H-1.4-benzoxazin-6-yl ] a mixture of perhydroimidazo[1.5-a]pyridin-1.3-one and a herbicide selected from the group consisting of: glyphosate (II), rimsulfuron (III), imazapy (IV) 2.4-D (Ⅴ), dicamba (Ⅵ), diuron (Ⅶ), fenoxafen (Ⅷ), glufosinate-ammonium (Ⅸ), chlorpyrrole (Ⅹ), sethoxydim (Ⅺ), sekzine ( Ⅻ), Ligulong (ⅩIII), Acifluorfen (XIV), Kekule (XV), Fomesafen (XVI), Pendimethalin (XVII), Grass Green (XⅧ), Triclofenac (XXIX), trifluralin (XX), chlorimuron-methyl (XXI), imazaquin (XXII) and proxazol (XXIII). 2、根据权利要求1的组合物,其中,混合组份的重量比在50∶1至1∶100之间。2. The composition according to claim 1, wherein the weight ratio of the mixed components is between 50:1 and 1:100. 3、一种灭除杂草的方法,其中,包括苗后施用根据权利要求1或2的含有组份Ⅰ和至少一种组分Ⅱ到Ⅺ的组合物。3. A method of controlling weeds, which comprises post-emergence application of a composition according to claim 1 or 2 comprising component I and at least one of components II to XI. 4、一种灭除杂草的方法,其中,包括苗前施用根据权利要求1或2的含有组份Ⅰ和至少一种组分Ⅻ至ⅩⅩⅢ的组合物。4. A method of controlling weeds, which comprises pre-emergence application of a composition according to claim 1 or 2 comprising component I and at least one of components XII to XXIII.
CN92113786A 1991-11-05 1992-11-05 Herbicidal composition with synergism Pending CN1073071A (en)

Applications Claiming Priority (2)

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DE4136740A DE4136740A1 (en) 1991-11-05 1991-11-05 HERBICIDES WITH SYNERGISTIC EFFECT

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Cited By (5)

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CN100490649C (en) * 2002-03-05 2009-05-27 拜尔作物科学股份公司 Herbicidal compositions comprising specific sulfonylureas
CN102256485A (en) * 2008-12-19 2011-11-23 巴斯夫欧洲公司 Aqueous flowable concentrate compositions of a microencapsulated dinitroaniline herbicide
CN103120180A (en) * 2011-11-17 2013-05-29 浙江新安化工集团股份有限公司 Herbicide composition prepared by glyphosate and diuron, and preparation method thereof
CN103547155A (en) * 2011-05-20 2014-01-29 日本农药株式会社 Crop wilting defoliant composition
CN108782597A (en) * 2017-04-26 2018-11-13 四川利尔作物科学有限公司 A kind of suspending agent containing glyphosate and flumioxazin

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WO1995023509A1 (en) * 1994-03-01 1995-09-08 E.I. Du Pont De Nemours And Company Herbicidal bicyclic hydantoins
KR100703303B1 (en) 2005-04-28 2007-04-03 삼성전자주식회사 Uplink Resource Allocation Request Method of Extended Real-Time Polling Service in Wireless Communication System
EA019754B1 (en) * 2011-07-13 2014-06-30 Юрий Аглямович ГАРИПОВ Synergetic herbicidal composition
JP2016027002A (en) * 2012-11-16 2016-02-18 日本農薬株式会社 Herbicidal composition

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DE3734745A1 (en) * 1987-10-09 1989-04-20 Schering Ag TETRAHYDROPYRROLO (2,1-C) (1,2,4) -THIADIAZOL-3-YLIDENIMINOBENZOXAZINONE AND OTHER HETEROCYCLICALLY SUBSTITUTED AZOLES AND AZINES, METHODS FOR THE PRODUCTION THEREOF AND THEIR USE AS AGENTS WITH HERBICIDES

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100490649C (en) * 2002-03-05 2009-05-27 拜尔作物科学股份公司 Herbicidal compositions comprising specific sulfonylureas
CN102256485A (en) * 2008-12-19 2011-11-23 巴斯夫欧洲公司 Aqueous flowable concentrate compositions of a microencapsulated dinitroaniline herbicide
CN103547155A (en) * 2011-05-20 2014-01-29 日本农药株式会社 Crop wilting defoliant composition
CN103120180A (en) * 2011-11-17 2013-05-29 浙江新安化工集团股份有限公司 Herbicide composition prepared by glyphosate and diuron, and preparation method thereof
CN108782597A (en) * 2017-04-26 2018-11-13 四川利尔作物科学有限公司 A kind of suspending agent containing glyphosate and flumioxazin

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