CN107286875A - A kind of one-component ceramic tile interface adhesive material and preparation method thereof - Google Patents
A kind of one-component ceramic tile interface adhesive material and preparation method thereof Download PDFInfo
- Publication number
- CN107286875A CN107286875A CN201710616958.7A CN201710616958A CN107286875A CN 107286875 A CN107286875 A CN 107286875A CN 201710616958 A CN201710616958 A CN 201710616958A CN 107286875 A CN107286875 A CN 107286875A
- Authority
- CN
- China
- Prior art keywords
- ceramic tile
- adhesive material
- interface adhesive
- component ceramic
- filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 title claims abstract description 29
- 239000000853 adhesive Substances 0.000 title claims abstract description 22
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims description 12
- 239000000945 filler Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011230 binding agent Substances 0.000 claims abstract description 7
- 239000002270 dispersing agent Substances 0.000 claims abstract description 7
- 239000000375 suspending agent Substances 0.000 claims abstract description 7
- 239000002562 thickening agent Substances 0.000 claims abstract description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 13
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000839 emulsion Substances 0.000 claims description 7
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical group [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- 238000009790 rate-determining step (RDS) Methods 0.000 claims description 3
- KMWBBMXGHHLDKL-UHFFFAOYSA-N [AlH3].[Si] Chemical compound [AlH3].[Si] KMWBBMXGHHLDKL-UHFFFAOYSA-N 0.000 claims 1
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical group [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000011449 brick Substances 0.000 description 2
- 239000011083 cement mortar Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229920005792 styrene-acrylic resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
A kind of one-component ceramic tile interface adhesive material, it includes following component, and following components is mass ratio：Binding agent 25%, the first filler 20%, the second filler 45%, dispersant 1%, suspending agent 3%, thickener 1%, water 5%.
Description
Technical field
The present invention relates to tile laying materials industry technical field, especially a kind of one-component ceramic tile interface adhesive material and
Its preparation method.
Background technology
The high speed development of ceramic tile industry, ceramic tile manufacturing process increasingly lean density more and more higher, ceramic tile new product, which updates, to be changed
Fast for speed, water absorption rate is but more and more lower, causes the requirement more and more higher to paving material, and tile laying Materials at present
It is delayed, therefore the difficult situation of tile laying is occurred in that, the serious hollowing of appearance is mainly manifested in, comes off, falls the phenomenons such as brick.Background skill
The shortcoming of art, is two-component gum, it is necessary to could paving after grade of having been constructed after blending is dry.
Therefore there is existing ceramic tile particularly vitrified tile in the prior art causes ceramic tile to come off because water absorption rate is low, interface is smooth
The problem of.
The content of the invention
In view of this, the present invention provides a kind of improvement ceramic tile interface performance and the one-component ceramic tile interfacial adhesion of workability
Material and preparation method thereof.
A kind of one-component ceramic tile interface adhesive material, it includes following component, and following components is mass ratio：
Binding agent 25%, the first filler 20%, the second filler 45%, dispersant 1%, suspending agent 3%, thickener 1%, water
5%.
In component ceramic tile interface adhesive material of the present invention, first filler is silica, described second
Filler is calcium carbonate, and the calcium carbonate is the calcium carbonate of 600 mesh.
In component ceramic tile interface adhesive material of the present invention, it is characterised in that
The binding agent is emulsion acrylic resin, and the dispersant is Sodium Polyacrylate, and the suspending agent is manosil AS
Salt, the thickener is polyurethane.
This also invention also provides a kind of preparation method of above-mentioned one-component ceramic tile interface adhesive material, and it includes following step
Suddenly：The number appeared below is weight ratio,
S1, take emulsion acrylic resin 25%, silica 20%, the calcium carbonate 45% of 600 mesh, Sodium Polyacrylate 1%,
Aluminosilicate 3%, polyurethane 1%, water 5% are used as raw materials of compound；
S2, the raw materials of compound in step S1 is inserted in mixer be stirred；
S3, the mixing time in rate-determining steps S2 and rotating speed；The mixing time is 1 hour；The mixing time is
400-500 revs/min.
In the preparation method of one-component ceramic tile interface adhesive material of the present invention,
Mixing speed is 450 revs/min in the step S3.
One-component ceramic tile interface adhesive material of the present invention and preparation method thereof can realize the two-component gum from before
Need A groups and B groups to blend and use, be now one-component；Ability paving after waiting is needed after construction before, is now pasted for i.e. brush.
Embodiment
The principle of the present invention is as follows, a kind of one-component ceramic tile interface adhesive material, and it includes following component, and following components is equal
For mass ratio：
Binding agent 25%, the first filler 20%, the second filler 45%, dispersant 1%, suspending agent 3%, thickener 1%, water
5%.
In component ceramic tile interface adhesive material of the present invention, first filler is that silica (is commonly called as quartz
Sand), second filler is calcium carbonate, and the calcium carbonate is the calcium carbonate of 600 mesh.
In component ceramic tile interface adhesive material of the present invention, it is characterised in that
The binding agent is emulsion acrylic resin (being commonly called as styrene-acrylic resin emulsion), and the dispersant is Sodium Polyacrylate,
The suspending agent is aluminosilicate (being commonly called as kaolin), and the thickener is polyurethane.
This also invention also provides a kind of preparation method of above-mentioned one-component ceramic tile interface adhesive material, and it includes following step
Suddenly：The number appeared below is weight ratio,
S1, take emulsion acrylic resin 25%, silica 20%, the calcium carbonate 45% of 600 mesh, Sodium Polyacrylate 1%,
Aluminosilicate 3%, polyurethane 1%, water 5% are used as raw materials of compound；
S2, the raw materials of compound in step S1 is inserted in mixer be stirred；
S3, the mixing time in rate-determining steps S2 and rotating speed；The mixing time is 1 hour；The mixing time is
400-500 revs/min.
In the preparation method of one-component ceramic tile interface adhesive material of the present invention,
Mixing speed is 450 revs/min in the step S3.
One-component ceramic tile interface adhesive material of the present invention and preparation method thereof can realize the two-component gum from before
Need A groups and B groups to blend and use, be now one-component；Ability paving after waiting is needed after construction before, is now pasted for i.e. brush.
The principle of the embodiment of the present invention is as follows：The adhesive theory of the embodiment of the present invention is as follows：Binding material molecule and cement
That starches surface molecular is pasted with two processes, and the first stage is the binding material molecule for brushing the ceramic tile back side by means of Brownian movement
To cement mortar diffusion into the surface, make the polar group at two interfaces or link close to each other, in the process, heating, apply pressure
Power and reduction tile bonding viscosity of material are all conducive to the reinforcement of Brownian movement；Second stage is the generation of absorption affinity, works as ceramic tile
When back side binding material reaches 5-10nm with cement mortar molecule distance, attractive interaction is just produced between interfacial molecular, is made intermolecular
Distance further shorten in maximum stable state, so as to reach superpower adherence force.So as to solve vitreous in existing design
Brick causes the problem of ceramic tile comes off because water absorption rate is low, interface is smooth.
It is understood that for the person of ordinary skill of the art, can be done with technique according to the invention design
Go out other various corresponding changes and deformation, and all these changes and deformation should all belong to the protection model of the claims in the present invention
Enclose.
Claims (5)
1. a kind of one-component ceramic tile interface adhesive material, it is characterised in that it includes following component, following components is quality
Than：
Binding agent 25%, the first filler 20%, the second filler 45%, dispersant 1%, suspending agent 3%, thickener 1%, water 5%.
2. component ceramic tile interface adhesive material as claimed in claim 1, it is characterised in that first filler is titanium dioxide
Silicon, second filler is calcium carbonate, and the calcium carbonate is the calcium carbonate of 600 mesh.
3. one-component ceramic tile interface adhesive material as claimed in claim 1 or 2, it is characterised in that
The binding agent is emulsion acrylic resin, and the dispersant is Sodium Polyacrylate, and the suspending agent is aluminosilicate, institute
Thickener is stated for polyurethane.
4. the preparation method of the one-component ceramic tile interface adhesive material described in a kind of claim 3, it is characterised in that it is included such as
Lower step：The number appeared below is weight ratio,
S1, take emulsion acrylic resin 25%, silica 20%, the calcium carbonate 45% of 600 mesh, Sodium Polyacrylate 1%, aluminium silicon
Hydrochlorate 3%, polyurethane 1%, water 5% are used as raw materials of compound；
S2, the raw materials of compound in step S1 is inserted in mixer be stirred；
S3, the mixing time in rate-determining steps S2 and rotating speed；The mixing time is 1 hour；The mixing time is 400-
500 revs/min.
5. the preparation method of one-component ceramic tile interface adhesive material as claimed in claim 1, it is characterised in that
Mixing speed is 450 revs/min in the step S3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710616958.7A CN107286875A (en) | 2017-07-26 | 2017-07-26 | A kind of one-component ceramic tile interface adhesive material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710616958.7A CN107286875A (en) | 2017-07-26 | 2017-07-26 | A kind of one-component ceramic tile interface adhesive material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107286875A true CN107286875A (en) | 2017-10-24 |
Family
ID=60102707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710616958.7A Pending CN107286875A (en) | 2017-07-26 | 2017-07-26 | A kind of one-component ceramic tile interface adhesive material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107286875A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1051380A (en) * | 1989-10-19 | 1991-05-15 | 亨克尔两合股份公司 | Early rain-proof joint filling materials |
| CN102076632A (en) * | 2008-06-27 | 2011-05-25 | 阿克佐诺贝尔股份有限公司 | Redispersible polymer powder composition |
| CN103214212A (en) * | 2013-04-17 | 2013-07-24 | 北京东方雨虹防水技术股份有限公司 | Paste tile adhesive and use thereof |
| CN105505166A (en) * | 2015-12-25 | 2016-04-20 | 澳达树熊涂料(惠州)有限公司 | High-performance and single-component white waterborne adhesion primer and preparation method thereof |
-
2017
- 2017-07-26 CN CN201710616958.7A patent/CN107286875A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1051380A (en) * | 1989-10-19 | 1991-05-15 | 亨克尔两合股份公司 | Early rain-proof joint filling materials |
| CN102076632A (en) * | 2008-06-27 | 2011-05-25 | 阿克佐诺贝尔股份有限公司 | Redispersible polymer powder composition |
| CN103214212A (en) * | 2013-04-17 | 2013-07-24 | 北京东方雨虹防水技术股份有限公司 | Paste tile adhesive and use thereof |
| CN105505166A (en) * | 2015-12-25 | 2016-04-20 | 澳达树熊涂料(惠州)有限公司 | High-performance and single-component white waterborne adhesion primer and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171024 |