CN107160801A - A kind of primary colors film - Google Patents
A kind of primary colors film Download PDFInfo
- Publication number
- CN107160801A CN107160801A CN201710339288.9A CN201710339288A CN107160801A CN 107160801 A CN107160801 A CN 107160801A CN 201710339288 A CN201710339288 A CN 201710339288A CN 107160801 A CN107160801 A CN 107160801A
- Authority
- CN
- China
- Prior art keywords
- primary colors
- film
- colors film
- masterbatch
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003086 colorant Substances 0.000 title claims abstract description 28
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 23
- 238000010521 absorption reaction Methods 0.000 claims abstract description 13
- 239000005416 organic matter Substances 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- XCKGFJPFEHHHQA-UHFFFAOYSA-N 5-methyl-2-phenyl-4-phenyldiazenyl-4h-pyrazol-3-one Chemical compound CC1=NN(C=2C=CC=CC=2)C(=O)C1N=NC1=CC=CC=C1 XCKGFJPFEHHHQA-UHFFFAOYSA-N 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- TVRGPOFMYCMNRB-UHFFFAOYSA-N quinizarine green ss Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000008360 acrylonitriles Chemical class 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- 238000013329 compounding Methods 0.000 claims description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 150000003918 triazines Chemical class 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 238000007792 addition Methods 0.000 claims 3
- 241001062009 Indigofera Species 0.000 claims 1
- 239000010408 film Substances 0.000 description 30
- 238000000034 method Methods 0.000 description 8
- 238000003851 corona treatment Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- TVBNRFCUTVWHQB-UHFFFAOYSA-N 1-anilino-4-(methylamino)anthracene-9,10-dione Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(NC)=CC=C1NC1=CC=CC=C1 TVBNRFCUTVWHQB-UHFFFAOYSA-N 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000004595 color masterbatch Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 201000009030 Carcinoma Diseases 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012788 optical film Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/71—Resistive to light or to UV
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/006—Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The present invention, which provides a kind of primary colors film, includes surface-treated layer C, sandwich layer B and top layer A, the sandwich layer B addition UV absorption master batches and Masterbatch；Or top layer A add functional agglomerate, sandwich layer B addition Masterbatch.The color of the primary colors film that the present invention is designed energy flexible modulation film on the premise of transmitance requirement is met, can directly pass through former film and obstruct ultraviolet.
Description
Technical field：
The present invention relates to optical film field, and in particular to primary colors film, available for automobile or building pad pasting.
Background technology：
Fenestrated membrane is called solar film, is divided into building film and automobile film by its purposes.Fenestrated membrane is a kind of functional film, and it is attached to
It is used to improve the performance and intensity of glass on glass surface, makes it have insulation, heat-insulated, energy-conservation, explosion-proof, antiultraviolet, beautification
The functions such as outward appearance, security protection, are mainly used in vehicle glass and building window, cut-off, ceiling etc..
Solar radiation is divided into ultraviolet, visible and infrared three regions by wavelength.The energy of wherein ultraviolet light accounts for the whole sun
The 2% of radiation energy.UV ultraviolets are divided into three regions again：UVC (200-290nm), UVB (290-320nm), UVA (320-
400nm), wherein most serious is UVB sections of ultraviolets.All disappear and be predominantly absorbed in overcast and rainy three wave bands, to the wound of human body
Evil is little, but when fine, injury of the ultraviolet radiation to human body is very serious, can cause color spot, cutaneum carcinoma etc. one
Series of disease.Thus either building fenestrated membrane or automobile window films are required for the function with antiultraviolet.
The content of the invention：
It is an object of the invention to provide a kind of primary colors film, ultraviolet can be obstructed, solar heat can be obstructed and difference can be adjusted
Color.
To achieve the above object, the technical scheme is that：
A kind of primary colors film, including surface-treated layer C, sandwich layer B and top layer A, the sandwich layer B addition UV absorption master batches and color
Master batch；Or top layer A add UV absorption master batch, sandwich layer B addition Masterbatch.
Further, one or more of the UV absorption master batch in inorganic matter or organic matter；Or will be described
Inorganic matter obtains UV absorption master batch with organic matter compounding, zinc oxide, titanium oxide and cerium oxide that the inorganic matter is selected from；
The organic matter is selected from benzotriazole, group-substituted acrylonitrile and triazines.
Further, the gross thickness of the primary colors film is 20-75 μm.
Further, the addition of the UV absorption master batch is 0.1-50wt%.
Further, top layer A thickness accounts for the 10-30% of primary colors film gross thickness.
Further, Masterbatch is selected from solvent of red 135, solvent green 3, solvent blue 19 04,3 four kinds of organic dyestuff of solvent yellow 16
In one or more.
Beneficial effect：
The color of the primary colors film that the present invention is designed energy flexible modulation film on the premise of transmitance requirement is met, Neng Gouzhi
Connected former film barrier ultraviolet.
Brief description of the drawings：
With reference to structural representation and embodiment, the present invention is further described.
Fig. 1 shows the primary colors film of one embodiment of the present invention.
Fig. 2 shows the primary colors film of another embodiment of the invention
Embodiment：
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
The preparation method of UV absorption master batch：UV absorption auxiliary agent and resin proportioning are completed by certain formula rate
Afterwards, be placed in high-speed mixer carry out at a high speed or mixed on low speed, it is to be mixed after the completion of take out compound be placed in double screw extruder
Middle carry out extruding pelletization.
Formula is as shown in the table：
The preparation method of Masterbatch：By certain formula rate by after the completion of dyestuff and resin proportioning, mixed at high speed is placed in
Carried out in machine at a high speed or mixed on low speed, it is to be mixed after the completion of take out compound and be placed in double screw extruder and carry out extruding pelletization.
Formula is as shown in the table：
| Raw material | Masterbatch S1 | Masterbatch S2 | Masterbatch S3 |
| Solvent of red 135 | 3.2% | 2.8% | 3% |
| Solvent green 3 | 4.5% | 3.6% | 3.5% |
| Solvent blue 19 04 | 1.5% | 1% | 1.2% |
| Solvent yellow 16 3 | 0.8% | 2.6% | 2.3% |
Primary colors film shown in Fig. 1 includes surface-treated layer C, top layer A and sandwich layer B, and the surface-treated layer C is in the window of resistance to UV
Online coating or sided corona treatment film surface during film primary colors film, the gross thickness of the primary colors film is 23 μm, and top layer A thickness is
3.8 μm, sandwich layer B thickness is 19 μm.The specific preparation method of the primary colors film is：By UV absorption master batch, specific color masterbatch
Grain is added in main extruder after being well mixed with blank section according to certain ratio, will add the blank of a certain amount of opening agent
Melt, extruded through measuring pump, melt pipe, coarse filter, fine filter, distributor, co-extrusion die head in the auxiliary extruder of section feeding,
A/B/A three-decker polyester sheets are formed, then again through longitudinal stretching technique, online coating or sided corona treatment technique are laterally drawn
Final products one are made in stretching process, winding process, separating and cutting process.
Fig. 2 primary colors film includes surface-treated layer C, top layer A and sandwich layer B, and the gross thickness of the primary colors film is 50 μm；Top layer A
Thickness be 10 μm, sandwich layer B thickness is 38.8 μm.The surface-treated layer C be during the fenestrated membrane of resistance to UV primary colors film
Line is coated or sided corona treatment film surface.Specifically preparation method is：Functional agglomerate and blank section are mixed equal according to certain ratio
It is added in auxiliary extruder, will be melted in the section feeding main extruder of the blank containing Masterbatch mixed according to special ratios after even
Melt, extruded through measuring pump, melt pipe, coarse filter, fine filter, distributor, co-extrusion die head, form A/B/A three-deckers and gather
Ester sheet, then again through longitudinal stretching technique, online, coating or sided corona treatment technique, cross directional stretch technique, winding process, point
Final products two are made in cutting process.
Coating or sided corona treatment online are carried out to film surface so that simple production process, the easily controllable excellent performance of condition, easily
Mass produced in batch.
The embodiment of table 1 and comparative example formula and every physical property measurement tables of data
Note：23 μm and 38 μm of samples (embodiment 1-4) are product one；50 μm and 75 μm (embodiment 5-8) is product two.
By the color of above-described embodiment primary colors film energy flexible modulation film on the premise of transmitance requirement is met, Neng Gouzhi
Connected former film barrier ultraviolet.
The foregoing is only the preferred embodiment of invention, be not intended to limit the present invention, it is all the spirit and principles in the present invention it
Interior made modifications, equivalent substitutions and improvements etc., should be included in the scope of the protection.Attempt according to this to the present invention
Make any formal limitation, therefore all have any modification or change for making the relevant present invention under identical spirit,
It should all be included in that the invention is intended to the category protected.
Claims (6)
1. a kind of primary colors film, including surface-treated layer C, sandwich layer B and top layer A, it is characterised in that the sandwich layer B additions are ultraviolet to inhale
Receive master batch and Masterbatch；Or add UV absorption master batch, sandwich layer B addition Masterbatch in top layer A.
2. primary colors film according to claim 1, it is characterised in that the UV absorption master batch is selected from inorganic matter or organic matter
In one or more；Or the inorganic matter and organic matter compounding are obtained into UV absorption master batch, the inorganic matter choosing
From zinc oxide, titanium oxide and cerium oxide；The organic matter is selected from benzotriazole, group-substituted acrylonitrile and triazines.
3. primary colors film according to claim 1, it is characterised in that the gross thickness of the primary colors film is 20-75 μm.
4. primary colors film according to claim 1, it is characterised in that the addition of the UV absorption master batch is 0.1-
20wt%.
5. primary colors film according to claim 1, it is characterised in that top layer A thickness accounts for the 10- of primary colors film gross thickness
30%.
6. primary colors film according to claim 1, it is characterised in that Masterbatch is selected from by solvent of red 135, solvent green 3, solvent
One or more in indigo plant 104,3 four kinds of organic dyestuff of solvent yellow 16.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710339288.9A CN107160801A (en) | 2017-05-15 | 2017-05-15 | A kind of primary colors film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710339288.9A CN107160801A (en) | 2017-05-15 | 2017-05-15 | A kind of primary colors film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107160801A true CN107160801A (en) | 2017-09-15 |
Family
ID=59816039
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710339288.9A Pending CN107160801A (en) | 2017-05-15 | 2017-05-15 | A kind of primary colors film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107160801A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108501489A (en) * | 2018-02-02 | 2018-09-07 | 张家港康得新光电材料有限公司 | A kind of primary colors film |
| CN119329159A (en) * | 2024-09-04 | 2025-01-21 | 康辉南通新材料科技有限公司 | A highly weather-resistant UV-blocking photovoltaic backplane base film and its preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104175666A (en) * | 2014-08-08 | 2014-12-03 | 常州山由帝杉防护材料制造有限公司 | Colored anti-fog window film capable of insulating ultraviolet light |
| CN106061729A (en) * | 2014-03-07 | 2016-10-26 | 3M创新有限公司 | Durable extruded dyed polyester film |
-
2017
- 2017-05-15 CN CN201710339288.9A patent/CN107160801A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106061729A (en) * | 2014-03-07 | 2016-10-26 | 3M创新有限公司 | Durable extruded dyed polyester film |
| CN104175666A (en) * | 2014-08-08 | 2014-12-03 | 常州山由帝杉防护材料制造有限公司 | Colored anti-fog window film capable of insulating ultraviolet light |
Non-Patent Citations (2)
| Title |
|---|
| 王忠法等: "《塑料着色入门》", 30 January 2004 * |
| 秦立洁等: "《农用塑料制品生产与应用》", 30 July 2002 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108501489A (en) * | 2018-02-02 | 2018-09-07 | 张家港康得新光电材料有限公司 | A kind of primary colors film |
| CN119329159A (en) * | 2024-09-04 | 2025-01-21 | 康辉南通新材料科技有限公司 | A highly weather-resistant UV-blocking photovoltaic backplane base film and its preparation method and application |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20170915 |