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CN107137857A - A kind of composition and its preparation and application for preparing water based fire suppressant - Google Patents

A kind of composition and its preparation and application for preparing water based fire suppressant Download PDF

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Publication number
CN107137857A
CN107137857A CN201710352173.3A CN201710352173A CN107137857A CN 107137857 A CN107137857 A CN 107137857A CN 201710352173 A CN201710352173 A CN 201710352173A CN 107137857 A CN107137857 A CN 107137857A
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China
Prior art keywords
parts
water based
fire suppressant
based fire
weight
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CN201710352173.3A
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Chinese (zh)
Inventor
徐西元
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Individual
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Individual
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Priority to CN201710352173.3A priority Critical patent/CN107137857A/en
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028Liquid extinguishing substances
    • A62D1/005Dispersions; Emulsions
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/06Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Dispersion Chemistry (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

The invention discloses a kind of composition and its preparation and application for preparing water based fire suppressant, it is by the material composition of following parts by weight:Sulfonic acid (R SO3H) 50 parts, 50 parts of caustic soda (NaOH), the sodium (Na of phosphoric acid five5P3O10), 10 20 parts, 100 parts of other materials;Wherein 100 parts other materials are by the material composition of following percentage by weight:Soda ash (Na2CO3) 15 30%, calcium hypochlorite [Ca (clo)2] 15 30%, sodium chloride (Nacl) 15 30%, fine particle calcium carbonate (CaCO3) 15 30%, cellulose [(C6H10O5)n] 15 30%.The reacted mixing of above-mentioned substance obtains water based fire suppressant and prepares face mud or dry powder.Add water to dissolve in proportion and obtain water based fire suppressant, the scene of catching fire is sprayed on sprinkler, you can fire extinguishing.The present invention can Extemporaneous at the scene, it is easy to use.

Description

A kind of composition and its preparation and application for preparing water based fire suppressant
Technical field
The present invention relates to fire-fighting domain, more particularly to extinguishing chemical.
Background technology
Common extinguishing chemical has dry-type, dichloromethane type, carbon dioxide-type in the modern life.Dry powder type fire extinguisher is easily blocked up Spray-hole is filled in, extinguishing effect is influenceed;Dichloromethane fire extinguisher, can be right easily because of the volatilization of residue in dicyandiamide solution after fire extinguishing Air pollutes phenomenon;Carbon dioxide extinguisher easily causes operator's asphyxia when crawl space is used.On overcoming State the deficiency of technology, application publication number:CN102350032A (on August 15th, 2011) discloses a kind of environmental-friendwater-based water-based fire extinguishing agent And preparation method thereof.The water based fire suppressant is by 80-85 parts of deionized water, 0.3-0.5 parts of preservative, metal antirusting agent 0.1- 0.3 part, 3-6 parts of halogen-free flame retardants, 5-7 parts of hc-surfactant, 0.5-1.0 parts of highly effective chelating agent, 2-5 parts of bleeding agent and height Imitate 0.3-0.5 parts of corrosion inhibiter, the agitated lysigenous shape feed liquid that is translucent.It is preventing combustion because containing halogen-free flame retardants It is non-volatile during burning, do not produce corrosive gas, do not produce black smoke, therefore environmental protection.But, this water based fire suppressant finished product be with The liquid made, stores, transports and inconvenient for use;Especially fire fighting truck is in use, be finished once needs to return to guard station again afterwards Fill it up with, influence the fire fighting time;If easily can prepare on the spot will greatly improve fire-fighting efficiency.
The content of the invention
In order to overcome the deficiencies in the prior art, the present invention discloses a kind of composite formula for preparing water based fire suppressant, and this is matched somebody with somebody The composition of face pureed state can be made in side, and the composition of dry powder can also be made;This composition dissolves can in water It is configured to water based fire suppressant.
The invention also discloses the preparation method of this composition and application method.
To reach above-mentioned purpose, the present invention is adopted the technical scheme that:
A kind of composition for preparing water based fire suppressant, it is characterised in that it is by the material composition of following parts by weight:
Sulfonic acid (R-SO3H) 50 parts, 50 parts of caustic soda (NaOH), the sodium (Na of phosphoric acid five5P3O10), 10-20 parts, other materials 100 Part;Wherein:
100 parts of other materials are by the material composition of following percentage by weight:Soda ash (Na2CO3) 15-30%, hypochlorous acid Calcium [Ca (clo)2] 15-30%, sodium chloride (Nacl) 15-30%, fine particle calcium carbonate (CaCO3) 15-30%, cellulose [(C6H10O5)n] 15-30%.
A kind of preparation method step for the composition for preparing water based fire suppressant is as follows:
First, it will be stirred by weight in 50 parts of sulfonic acid, 50 parts of addition containers of caustic soda, phosphoric acid added after reaction foaming Five 10-20 parts of sodium continue to stir, and the material of batter shape is turned into after reaction froth breaking;
Second, then other materials of 100 parts of parts by weight are added into above-mentioned batter shape material, and suitable quantity of water is added, continued Mix and rub pressure, the combination object plane mud as pureed;Other materials are by the material composition of following percentage by weight:Soda ash (Na2CO3) 15-30%, calcium hypochlorite [Ca (clo)2] 15-30%, sodium chloride (Nacl) 15-30%, fine particle calcium carbonate (CaCO3)15- 30%th, cellulose [(C6H10O5)n] 15-30%;
3rd, combination object plane mud is split and packed by different weight, that is, obtains preparing the face mud finished product of water based fire suppressant, Referred to as " water based fire suppressant prepares face mud ".
A kind of another preparation method for preparing water based fire suppressant composition is that the combination object plane mud for obtaining a upper method is spread out Open and dry, after being completely dried, be reprocessed into composition dry powder, weigh and pack by different weight obtain prepare water based fire suppressant Dry powder finished product, be referred to as " water based fire suppressant preparing dry ".This dry powder is easy to store, pack, transport and prepare water base fire extinguishing Agent.
The application method of above-mentioned " water based fire suppressant prepares face mud " is to add extinguishing chemical face mud by 1-2% addition In running water;After dissolving completely, water based fire suppressant is become, the scene of catching fire is sprayed on sprinkler, you can fire extinguishing.
The application method of above-mentioned " water based fire suppressant preparing dry " is to add extinguishing chemical dry powder by 1-2 ‰ addition In running water;After dissolving completely, water based fire suppressant is become, the scene of catching fire is sprayed on sprinkler, you can fire extinguishing.
The present invention fire-fighting principle and good effect be:
1st, the various components of the composition of present invention preparation water based fire suppressant are dissolved in the nonactive fire extinguishing component produced after water It is dispersed in water, super crystal particles respectively less than critical grain size is formed in the environment of heat, and single particle quality is smaller, Specific surface area is larger, and diffusivity is preferable, and suspension time is longer in atmosphere, forms metastable aerosol, catches flammable Thing free radical ability is larger.These fire extinguishing component sprays can guarantee that the particle activity of fire extinguishing component in space on fire, with burning During free radical produced by fuel or active group occur chemistry and resist and negative catalyst, interrupt the chain reaction of burning And put out a fire;When some fire extinguishing components fall outside combustible surface, chemically react, and one layer of glass of formation under high temperature action The covering of prize, so that starvation and fire smothering;These fire extinguishing components also play part of dilution and cooling effect.Such as phosphoric acid Water is to the Ca in water after five sodium are decomposed in water2+And Mg2+Deng complexing is played, soluble complexes are generated, are risen in extinguishing chemical Emulsion dispersion is acted on, and fire extinguishing component is preferably dissolved in water formation gaseous solvents;Carbon dioxide gas can be generated when soda ash, fine particle calcium carbonate high temperature Body, completely cuts off air and puts out a fire;Sodium chloride, sulfonic acid, caustic soda etc. generate coloured glaze shape covering in high-heat environment and are covered in flammable Starvation on thing and put out a fire.
2nd, the composition of preparation water based fire suppressant of the invention, which is dissolved in interacting after water, forms new fire extinguishing component, passes through Power set spray to the combustible of burning, the effect to A classes fire with infiltration, and such as timber, cloth can permeate combustible Inside, fails all to put out, its position sprayed can also be effectively blocked burning things which may cause a fire disaster, control spreading for fire even if the intensity of a fire is larger Speed;There is the effect of isolation to B classes fire, such as gasoline and volatile liquid, medicament can be formed for a long time on its surface Moisture film, even if moisture film is destroyed by extraneous factor, its unique mobility can heal rapidly, flame is suffocated.
3rd, because the present invention is configured to water based fire suppressant and used, do not influenceed by environment such as indoor and outdoor, strong wind, Comburant surface can be acted on to greatest extent.
4th, when the present invention is used can Extemporaneous at the scene, it is easy to use.Especially fire fighting truck is easy to carry, is gone out large-scale , also can be by matching somebody with somebody as long as fire scene when having water source in extemporaneous preparation, input fire-truck water tank, is rejoined without returning to guard station Fire extinguishing water smoke is formed than being directly added into High-Pressure Water.
4th, the composition of the preparation water based fire suppressant is nontoxic, harmless, deposit-free after fire extinguishing, corrosion-free pollution, and residual can Combustion things secondary can be utilized, and storage use time is long, cheap, and powerful effect of putting out a fire is good, there is great economic benefit and society Benefit.
Embodiment
The preparation method of the composition of water based fire suppressant is prepared to the present invention with reference to embodiment, is described in further detail.
Embodiment 1
A kind of water based fire suppressant prepares face mud, and its preparation methods steps are as follows:
One, it will be stirred by weight in 50 parts of sulfonic acid, 50 parts of addition containers of caustic soda, phosphoric acid five added after reaction foaming Sodium continues to stir, and the continuous sodium of phosphoric acid five adds total amount and is not more than 20 parts, turns into the material of batter shape after froth breaking;Above-mentioned number is weight Part;
Two, then other materials of 100 parts of parts by weight are added into above-mentioned batter shape material, and suitable quantity of water is added, continue to stir With rub pressure, the combination object plane mud as pureed;Other materials are by the material composition of following percentage by weight:Soda ash (Na2CO3) 15%, calcium hypochlorite [Ca (clo)2] 15%, sodium chloride (Nacl) 20%, fine particle calcium carbonate (CaCO3) 20%, cellulose [(C6H10O5)n] 30%;
Three, combination object plane mud is split and packed by different weight, that is, obtains preparing the face mud of water based fire suppressant, is referred to as " water based fire suppressant prepares face mud ".
Embodiment 2
As different from Example 1, other materials are by the material composition of following percentage by weight to embodiment 2:Soda ash (Na2CO3) 20%, calcium hypochlorite [Ca (clo)2] 20%, sodium chloride (Nacl) 15%, fine particle calcium carbonate (CaCO3) 15%, cellulose [(C6H10O5)n] 30%;
Embodiment 3
As different from Example 1, other materials are by the material composition of following percentage by weight to embodiment 3:Soda ash (Na2CO3) 30%, calcium hypochlorite [Ca (clo)2] 30%, sodium chloride (Nacl) 10%, fine particle calcium carbonate (CaCO3) 20%, cellulose [(C6H10O5)n] 10%;
Embodiment 4
The combination object plane mud that embodiment 1,2,3 is made, which is spread out, to be dried, and after being completely dried, is reprocessed into composition dry powder, The dry powder for obtaining preparing water based fire suppressant is weighed and packed by different weight, is referred to as " water based fire suppressant preparing dry ".
Embodiment 5
The water based fire suppressant that Example 4 is made is prepared face mud and added by 1% addition in running water, dissolves completely Afterwards, water based fire suppressant is become, is sub-packed in portable water base fire extinguishing device, it is standby;As long as being sprayed on the scene of catching fire, you can go out Fire.
Embodiment 6
The water based fire suppressant preparing dry that Example 5 is made is added in fire-truck water tank by 1 ‰ addition, then will be disappeared Spray is applied in anti-car shower nozzle insertion water pot to stir, and after dry powder dissolves completely, becomes water based fire suppressant, remote high pressure is sprayed on Catch fire scene, you can fire extinguishing.

Claims (5)

1. a kind of composition for preparing water based fire suppressant, it is characterised in that it is by the material composition of following parts by weight:
Sulfonic acid (R-SO3H) 50 parts, 50 parts of caustic soda (NaOH), the sodium (Na of phosphoric acid five5P3O10), 10-20 parts, 100 parts of other materials;Its In:
100 parts of other materials are by the material composition of following percentage by weight:Soda ash (Na2CO3) 15-30%, calcium hypochlorite [Ca(clo)2] 15-30%, sodium chloride (Nacl) 15-30%, fine particle calcium carbonate (CaCO3) 15-30%, cellulose [(C6H10O5)n]15- 30%.
2. a kind of water based fire suppressant prepares face mud, it is characterised in that it is prepared by following methods:
First, it will be stirred by weight in 50 parts of sulfonic acid, 50 parts of addition containers of caustic soda, the sodium of phosphoric acid five added after reaction foaming 10-20 parts are continued to stir, and the material of batter shape is turned into after reaction froth breaking;
Second, then other materials of 100 parts of parts by weight are added into above-mentioned batter shape material, and suitable quantity of water is added, continue to mix Pressure is rubbed, the combination object plane mud as pureed;Other materials are by the material composition of following percentage by weight:Soda ash (Na2CO3) 15-30%, calcium hypochlorite [Ca (clo)2] 15-30%, sodium chloride (Nacl) 15-30%, fine particle calcium carbonate (CaCO3) 15-30%, fiber Element [(C6H10O5)n] 15-30%;
3rd, combination object plane mud is split and packed by different weight, that is, obtains preparing the face mud finished product of water based fire suppressant, is referred to as " water based fire suppressant prepares face mud ".
3. a kind of water based fire suppressant as claimed in claim 2 prepares the application method of face mud, it is characterised in that by adding for 1wt% Enter amount to add in running water, after dissolving completely, become water based fire suppressant, the scene of catching fire is sprayed on sprinkler, you can go out Fire.
4. a kind of water based fire suppressant preparing dry, it is characterised in that it is prepared by following methods:
First, it will be stirred by weight in 50 parts of sulfonic acid, 50 parts of addition containers of caustic soda, the sodium of phosphoric acid five added after reaction foaming 10-20 parts are continued to stir, and the material of batter shape is turned into after reaction froth breaking;
Second, then other materials of 100 parts of parts by weight are added into above-mentioned batter shape material, and suitable quantity of water is added, continue to mix Pressure is rubbed, the combination object plane mud as pureed;Other materials are by the material composition of following percentage by weight:Soda ash (Na2CO3) 15-30%, calcium hypochlorite [Ca (clo)2] 15-30%, sodium chloride (Nacl) 15-30%, fine particle calcium carbonate (CaCO3) 15-30%, fiber Element [(C6H10O5)n] 15-30%;
3rd, combination object plane mud is spread out and dried, after being completely dried, composition dry powder is reprocessed into, weighed by different weight and Packaging obtains preparing the dry powder of water based fire suppressant, is referred to as " water based fire suppressant preparing dry ".
5. a kind of application method of water based fire suppressant preparing dry as claimed in claim 4, it is characterised in that by 1wt's ‰ Addition is added in running water, after dissolving completely, becomes water based fire suppressant, the scene of catching fire is sprayed on sprinkler, you can Fire extinguishing.
CN201710352173.3A 2017-05-18 2017-05-18 A kind of composition and its preparation and application for preparing water based fire suppressant Pending CN107137857A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710352173.3A CN107137857A (en) 2017-05-18 2017-05-18 A kind of composition and its preparation and application for preparing water based fire suppressant

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Application Number Priority Date Filing Date Title
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3843525A (en) * 1971-12-09 1974-10-22 Akira Hattori Method of extinguishing fires
CN103285550A (en) * 2013-06-25 2013-09-11 公安部天津消防研究所 A water-based fire extinguishing agent for extinguishing pulverized coal fire
CN103933694A (en) * 2014-05-13 2014-07-23 湖南省湘电试研技术有限公司 Rapid fire extinguishing agent for vegetation fire of power transmission lines
CN104815412A (en) * 2015-04-10 2015-08-05 天津盛安消科科技有限公司 Environment-friendly-type high-efficiency water-series fire extinguishing additive and preparation method thereof
CN105727490A (en) * 2014-12-10 2016-07-06 田建频 Efficient firebrand fire capture agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3843525A (en) * 1971-12-09 1974-10-22 Akira Hattori Method of extinguishing fires
CN103285550A (en) * 2013-06-25 2013-09-11 公安部天津消防研究所 A water-based fire extinguishing agent for extinguishing pulverized coal fire
CN103933694A (en) * 2014-05-13 2014-07-23 湖南省湘电试研技术有限公司 Rapid fire extinguishing agent for vegetation fire of power transmission lines
CN105727490A (en) * 2014-12-10 2016-07-06 田建频 Efficient firebrand fire capture agent
CN104815412A (en) * 2015-04-10 2015-08-05 天津盛安消科科技有限公司 Environment-friendly-type high-efficiency water-series fire extinguishing additive and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
程远平等: "《消防工程学 第1版第2次印刷》", 31 May 2002, 中国矿业大学出版社 *

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Application publication date: 20170908

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