CN1070674A - Novel synthetic liquid fuel and production method thereof - Google Patents
Novel synthetic liquid fuel and production method thereof Download PDFInfo
- Publication number
- CN1070674A CN1070674A CN 92110621 CN92110621A CN1070674A CN 1070674 A CN1070674 A CN 1070674A CN 92110621 CN92110621 CN 92110621 CN 92110621 A CN92110621 A CN 92110621A CN 1070674 A CN1070674 A CN 1070674A
- Authority
- CN
- China
- Prior art keywords
- liquid fuel
- fume
- oil
- naphthenate
- eliminating energy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 27
- 239000007788 liquid Substances 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000000654 additive Substances 0.000 claims abstract description 15
- 230000000996 additive effect Effects 0.000 claims abstract description 15
- 239000002283 diesel fuel Substances 0.000 claims abstract description 11
- 239000003350 kerosene Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- NKFIBMOQAPEKNZ-UHFFFAOYSA-N 5-amino-1h-indole-2-carboxylic acid Chemical compound NC1=CC=C2NC(C(O)=O)=CC2=C1 NKFIBMOQAPEKNZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 3
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 claims description 3
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 238000007865 diluting Methods 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052799 carbon Inorganic materials 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- 238000002485 combustion reaction Methods 0.000 abstract description 4
- 239000003915 liquefied petroleum gas Substances 0.000 abstract description 4
- 150000001298 alcohols Chemical class 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 230000009965 odorless effect Effects 0.000 abstract description 3
- 238000004880 explosion Methods 0.000 abstract description 2
- 238000011109 contamination Methods 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Landscapes
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The present invention relates to a kind of civil synthetic liquid fuel and production method thereof that does not contain alcohols.This fuel is with extractive virgin oil, No. zero diesel oil, four kinds of raw materials of fume-eliminating energy-saving additive in useless aviation kerosene, the refinery atmospheric unit, makes with the technological process of production by a certain percentage of the weight.This liquid fuel is equipped with special cylinder, on special furnace set, use, have easy igniting, sufficient combustion, calorific value up to 1000～11000 kilocalorie/kilograms, do not have because of carbon distribution causes stove and accessory spray nozzle clogging, no explosion hazard, safe in utilization, nontoxic, odorless, smokeless, free of contamination characteristics, be a kind of ideal liquefied petroleum gas (LPG) substitute.
Description
The present invention relates to the liquid carbon-containing hydrogen fuel, especially for a kind of be the main civil synthetic liquid fuel and the production method thereof that do not contain alcohols that contain the fume-eliminating energy-saving additive based on hydrocarbon mixture.
Current, though there is much the report of test based on the liquefied synthetic gas of liquid fuel, small serial production, use China various places, owing to the problem on some technology and the raw material, great majority are not also obtained practical function preferably.Trace it to its cause: 1. material performance is not good, wherein contains more impurity, colloid, makes easy carbon distribution of when burning, stops up nozzle, the flame shakiness, the time little and flame-out trouble arranged when big; 2. contain methyl alcohol in the raw material that has, health risk; 3. when using by manually inflating, and igniting inconvenience, warm up time is long; 4. incomplete combustion, flue gas is big, causes environmental pollution.
From patented technology " liquid fuel combination " (application number: 87103060.8, publication number: CN1033392A), the method for liquid compound fuel " produce " (application number: 90105854.8, publication number: CN1048881A), " civil compound liquid fuel without alcohol and manufacture method thereof " (application number: 90108551.0, publication number CN1050040A) performance, the user is reflected the frowziness that has when using these liquid fuels, cigarette is arranged, layering and precipitating is arranged; Have to contain colloid many because of raw material, carbon distribution during burning stops up the stove and accessory nozzle; Contain methyl alcohol in the raw material that has, toxicity is big, is detrimental to health; Need manually inflate pressurization during the use that has, troublesome poeration; Therefore be difficult to apply.
The objective of the invention is to adopt relatively reasonably, formulating of recipe has solved above-mentioned the deficiencies in the prior art, a kind of alcohols composition of not containing is provided, need not artificial pressurization and combustionproperty very good (easily igniting, sufficient combustion, no carbon distribution, calorific value height, nontoxic, odorless, smokeless, pollution-free) during use, safe in utilization, raw material is easy to get uncomplicated novel synthetic liquid fuel of production technique and production method thereof.
The object of the present invention is achieved like this:
1. desired raw material and source thereof:
(1) useless aviation kerosene
All there are many useless aviation kerosenes civilian, military aircraft field.This oil plant is the useless aviation kerosene that no longer is suitable in the drome flying and uses, its calorific value height, and peculiar smell is little, turns waste into wealth, and obtains easily.
(2) virgin oil
Virgin oil is the extractive straight-run spirit of refinery atmospheric unit, and it is many that it does not resemble the condensate oil gum level, do not make the easy phenomenon of blocking of stove and accessory nozzle because of burn soot during use.1500 tons of the North Sea, Guangxi synthesization factory atmospheric unit extracting virgin oil monthly outputs at present can satisfy the demands.
(3) No. zero diesel oil
The shared ratio of No. zero diesel oil is little in each component of the present invention, and its requirement all can solve in various places.
(4) fume-eliminating energy-saving additive
The fume-eliminating energy-saving additive refers to cobalt naphthenate, or iron naphthenate, or calcium naphthenate, or manganese naphthenate, or barium naphthenate.This additive plays in the present invention and improves combustionproperty and reach effect energy-conservation and that eliminate smoke.Because its requirement is few, can buy on market.
2. composition of the present invention, proportioning, production method:
(1) composition of the present invention, proportioning:
The present invention is made up of useless aviation kerosene, virgin oil, No. zero diesel oil, fume-eliminating energy-saving additive, and the weight ratio of its each component is:
Useless aviation kerosene 40～55%
Virgin oil 25～35%
No. zero diesel oil 15～30%
Fume-eliminating energy-saving additive 0.03～0.05%
With cobalt naphthenate, or iron naphthenate, or calcium naphthenate, or manganese naphthenate, or barium naphthenate is as the fume-eliminating energy-saving additive.
(2) production method of the present invention:
Below production method of the present invention is described.
Fig. 1 is a technological process of production synoptic diagram of the present invention.According to shown in Figure 1, production stage of the present invention has:
A. with the virgin oil of a small amount of (just being suitable for dissolving or diluting the amount of fume-eliminating energy-saving additive) synthesizer is evenly put in quantitative fume-eliminating energy-saving additive dissolving or diluted mixture earlier;
B. inject synthesizer with will give up aviation kerosene, virgin oil, No. zero diesel oil of oiling machine respectively in proportion;
C. put into large-scale pan tank with after each component mixes in the synthesizer, the mixing of flowing once more promptly obtains the synthetic liquid fuel of finished product;
D. with oiling machine quantitative finished product synthetic liquid fuel is injected special cylinder, then be pressed into air, make the interior pressure of steel cylinder reach the 2-4 kg/cm and get final product with air compressor.
More than said synthesizer be that a kind of nothing stirs carbon steel reactor.
3. embodiments of the invention:
(1) with 25 kilograms of useless aviation kerosenes, 13.5 kilograms of virgin oils, 12.5 kilograms No. zero diesel oil, 25 milliliters of cobalt naphthenates, mixes, stirs and make novel synthetic liquid fuel by aforementioned production method.
(2) with 32.0 kilograms of useless aviation kerosenes, 16 kilograms of virgin oils, 12.5 kilograms No. zero diesel oil, 25 milliliters of iron naphthenates, mix, stir and make novel synthetic liquid fuel by aforementioned production method.
The calorific value of the novel synthetic liquid fuel that the foregoing description 1～2 is prepared is within 1000～11000 kilocalorie/kilograms.Through using proof, this synthetic liquid fuel on special furnace set with the water of 5 kilograms in 15～17 minutes boiled kettles of energy of medium fire burns, if only need 12～14 minutes with big fire, its burnup is less than 0.2 kilogram/hour, and easily igniting in use, sufficient combustion, calorific value height, do not have because of carbon distribution in the burning and cause the stove and accessory nozzle to stop up, do not have explosion hazard, nontoxic, odorless, smokeless, pollution-free easily.Therefore novel synthetic liquid fuel of the present invention is that present liquefied petroleum gas (LPG) substitutes more satisfactory domestic fuel, has vast market prospect.
Claims (4)
1, a kind of novel synthetic liquid fuel is characterized in that this liquid fuel is made up of useless aviation kerosene, virgin oil, No. zero diesel oil, fume-eliminating energy-saving additive, and the weight ratio of its each component is:
Useless aviation kerosene 40～55%
Virgin oil 25～35%
No. zero diesel oil 15～30%
Fume-eliminating energy-saving additive 0.03～0.05%
2, liquid fuel according to claim 1 is characterized in that described virgin oil is an extractive virgin oil in the refinery atmospheric unit.
3, liquid fuel according to claim 1 is characterized in that described fume-eliminating energy-saving additive is a cobalt naphthenate, or iron naphthenate, or calcium naphthenate, or manganese naphthenate, or barium naphthenate.
4, a kind of production method of novel synthetic liquid fuel is characterized in that:
(1) with the virgin oil of a small amount of (just being suitable for dissolving or diluting the amount of fume-eliminating energy-saving additive) synthesizer is evenly put in quantitative fume-eliminating energy-saving additive dissolving or diluted mixture earlier;
(2) inject synthesizer with will give up aviation kerosene, virgin oil, No. zero diesel oil of oiling machine respectively in proportion;
(3) put into pan tank after each component mixes in the synthesizer, flow again and mix;
(4) with oiling machine quantitative finished product synthetic liquid fuel is injected special cylinder, then be pressed into air, make the interior pressure of steel cylinder reach the 2-4 kg/cm and get final product with air compressor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92110621 CN1070674A (en) | 1992-09-10 | 1992-09-10 | Novel synthetic liquid fuel and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92110621 CN1070674A (en) | 1992-09-10 | 1992-09-10 | Novel synthetic liquid fuel and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1070674A true CN1070674A (en) | 1993-04-07 |
Family
ID=4944911
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92110621 Pending CN1070674A (en) | 1992-09-10 | 1992-09-10 | Novel synthetic liquid fuel and production method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1070674A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112121720A (en) * | 2020-09-11 | 2020-12-25 | 国网通用航空有限公司 | Waste aviation kerosene treatment method and device |
-
1992
- 1992-09-10 CN CN 92110621 patent/CN1070674A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112121720A (en) * | 2020-09-11 | 2020-12-25 | 国网通用航空有限公司 | Waste aviation kerosene treatment method and device |
| CN112121720B (en) * | 2020-09-11 | 2022-02-11 | 国网通用航空有限公司 | Waste aviation kerosene treatment method and device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Yilmaz et al. | Diesel blends with high concentrations of biodiesel and n-butanol: Effects on regulated pollutants and polycyclic aromatic hydrocarbons | |
| Uyar et al. | Production of low sulfur diesel-like fuel from crude oil wastes by pyrolytic distillation and its usage in a diesel engine | |
| CN109207212A (en) | Environment-friendly combustion-supporting diesel additive and preparation method thereof | |
| CN1242028C (en) | Alcohol base liquid fuel | |
| CN103122263B (en) | Fuel additive and clean low-carbon fuel with same | |
| CN101633859B (en) | High-cleanness diesel oil | |
| CN1070674A (en) | Novel synthetic liquid fuel and production method thereof | |
| CN106947555B (en) | Biological alcohol-based fuel power heat value agent | |
| CN101191085A (en) | High cleanness composite diesel oil | |
| Prabu et al. | Combustion, performance and emission behavior of soap-nut oil biodiesel/diesel blends in DI diesel engine with diethyl-ether additive | |
| Gopalakrishnan et al. | Impact OF fuel injection pressure in diesel fuelled engine using biodiesel, flammable and non-flammable gas in mixed fuel mode | |
| CN107353945A (en) | High energy alcohol vaporising fuel and its production method | |
| CN113122343A (en) | Synthetic diesel oil and preparation method thereof | |
| Liu | Current Status of Research on Biodiesel as an Alternative Fuel for Internal Combustion Engines [J] | |
| CN1054609A (en) | The new type of safe liquefied gas | |
| Yoshimoto et al. | Influence of boost pressure on the combustion characteristics of a dual fuel diesel engine ignited by biofuels with natural gas | |
| Kotaiah et al. | Effect of three and five holes nozzle on thermal efficiency and emission characters of DI-CI diesel engine with lemongrass biodiesel as alternate fuel | |
| CN116445193B (en) | Modified methanol fuel for industrial field and preparation method thereof | |
| Amba Prasad Rao et al. | Evaluation of CRDi Engine Fueled With Binary and Ternary Blends of Biodiesel, Butanol, and Diesel | |
| Alagao | Real‐Time Analysis of Engine Power, Thermal Efficiency, and Emission Characteristics Using Refined and Transesterified Waste Vegetable Oil | |
| Yogesh | Effect of Exhaust Gas Recirculation on a CRDI Engine Fuelled with Biodiesel, Ethanol and Butanol. | |
| CN1281031A (en) | Synthetic liquefied gas as fuel | |
| Hussain et al. | Performance and emission analysis of diesel-fired boiler using biodiesel made from waste cooking oil | |
| CA1127393A (en) | Light high volatile fuel with heavier lower volatility oil and method for processing | |
| CN115820309A (en) | Preparation method of composite fuel for replacing heavy oil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication |