CN107056257A - 60 ° of three-dimensional network IPN mutually hands over ceramic skeleton metal-base composites and preparation method thereof - Google Patents
60 ° of three-dimensional network IPN mutually hands over ceramic skeleton metal-base composites and preparation method thereof Download PDFInfo
- Publication number
- CN107056257A CN107056257A CN201710102668.0A CN201710102668A CN107056257A CN 107056257 A CN107056257 A CN 107056257A CN 201710102668 A CN201710102668 A CN 201710102668A CN 107056257 A CN107056257 A CN 107056257A
- Authority
- CN
- China
- Prior art keywords
- ceramic
- ceramic skeleton
- skeleton
- mutually
- dimensional network
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D23/00—Casting processes not provided for in groups B22D1/00 - B22D21/00
- B22D23/04—Casting by dipping
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/624—Sol-gel processing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
Centimetre of the present invention has opened a kind of 60 ° of three-dimensional network IPN and has mutually handed over ceramic skeleton metal-base composites.The composite includes ceramic skeleton reinforcement and metallic matrix.The ceramic skeleton reinforcement is 3-D solid structure, and each connecting cylinder is mutually communicated, and connecting cylinder center line is mutually 60 °, is most stable, most firm stereochemical structure.The metallic matrix is integrally formed with ceramic skeleton by technology of infiltration casting.Preparation method is：Ceramic skeleton is first prepared, outward appearance is designed by the requirement of composite, then ceramic skeleton is fixed in casting mold, cast metallic cementation liquid, composite is obtained after cooling.Instant invention overcomes the skewness of ceramic unit in ceramic phase reinforcement metal-base composites, the problems such as ceramic particle comes off in use, skeleton is solid cylinder, three-dimensional IPN links, mutually it is integrated, is evenly distributed in collective, ceramic skeleton reinforcement is firmly combined with metallic matrix, come off problem in the absence of ceramic phase reinforcement, significantly increase the service life of composite.Suitable for friction, there are the various wear-resisting fields such as brinelling.
Description
Technical field
The present invention relates to Ceramic Reinforced MMCs and preparation method, more particularly to a kind of three-dimensional network IPN
60 ° are mutually handed over ceramic skeleton-metal-base composites and preparation method.
The ceramic unit of Ceramic Reinforced MMCs mainly has ceramic particle, ceramic fibre, porous or network pottery
The uniformity controlling that porcelain precast body etc., ceramic particle and ceramic fibre are distributed in metallic matrix makes its preparation technology complicated, system
Cause originally to dramatically increase, ceramic particle particularly in use can come off too early, have impact on service life.For common porous
Ceramics or net-based education central server reinforcement metal-base composites, more using porous, expanded plastics precursor dipping pottery sizing process,
There is hole in complex manufacturing technology, ceramic body.Low intensity, impact resistance is poor, and mechanical property is not high, so as to cause what is prepared to answer
Condensation material service life is relatively short.
The content of the invention
Ceramic skeleton-metal-base composites and preparation method are mutually handed over the invention provides a kind of 60 ° of three-dimensional network IPN,
The composite overcomes ceramic unit nonunf ormity, preparation technology in ceramic particle reinforcement-metal-base composites
The problems such as ceramic particle in complicated and use is easy to fall off.Also the hole problem in foam porous ceramic unit, ceramics is not present
Skeleton is 60 ° of intersections of solid cylinder IPN.This stereochemical structure is most stable, and mechanical property is best, effectively in point of impact energy
Dissipate, absorb, impact resistance is best.Skeleton is integrated connected, in the absence of the problem of coming off, ceramic enhancing has been played to greatest extent single
The wear-resistant effect of member, composite is using reliably, and the life-span greatly prolongs.
The technical scheme is that：
First prepare the ceramic skeleton that 60 ° of three-dimensional network IPN is mutually handed over：
(1) hole that 60 ° of three-dimensional network IPN is mutually handed over is produced in the material of the low melting points such as paraffin, plastics.
(2) ceramic mud is injected in hole, is solidified after being molded with gel method, is dried, sintering.Obtain three dimensional network
The ceramic skeleton that 60 ° of network IPN is mutually handed over.Ceramic skeleton material is high alumina ceramic, ZrO2REINFORCED Al2O3Ceramics, silicon carbide ceramics or
Other ceramics.
In such scheme, the diameter of network ceramic cylinder uses field between 0.1-10 millimeters according to composite
Difference is closed to be adjusted.
The profile of ceramic skeleton if composite volume is larger, can fit situation pair according to designing the need for composite
Its progress is divided into fritter, and the shape according still further to fritter designs ceramic skeleton, and the total of composite is finally spliced into casting mold
Shape.
Ceramic skeleton is fixed in casting mold, casting mold can be sand mold, it is also possible to metal mold.Casting mold shape is according to composite wood
Expect shape design, ceramic skeleton shape matches with casting mold shape.
Ceramic skeleton is preheated, preheating temperature is adjusted at 400 DEG C -1000 DEG C according to casting metallic cementation material difference
It is whole.
Casting metallic cementation liquid is carried out to ceramic skeleton in casting mold, molten metal is rich chromium cast iron, potassium steel, alloy abrasion resistant steel,
One kind of heat resisting steel or certain non-ferrous alloy.
Brief description of the drawings
Fig. 1 is ceramic skeleton schematic diagram
Specific implementation
The following is case study on implementation, the present invention is described in further detail.
ZrO2Toughness reinforcing Al2O360 ° of three-dimensional network IPN mutually hands over the preparation of ceramic skeleton-rich chromium cast iron composite.
The preparation of ceramic skeleton
In paraffin, with self-control manipulator and multi-hole drill, 4 millimeters of Circularhole diameter, the three-dimensional network that 10 millimeters of spacing are made
The porous block that 60 ° of IPN is mutually handed over.
Injecting ZrO in ready-made block with holes2Content 40%, Al2O3Account for the ceramic mud of 60% and auxiliary material, mud shape
Into after gel solidification, it is slowly heated make it is paraffin melting, drying obtain ceramic skeleton blank.
Proceed drying to ceramic skeleton, fat takes off, sintering obtains ceramic skeleton standby.
Ceramic skeleton is fixed in sand mold, 600 DEG C -1000 DEG C of preheating is carried out.
High-chromium cast iron alloy liquid of 200 DEG C -300 DEG C higher than fusing point under negative pressure of vacuum, casting is seeped into sand mold skeleton, cold
But composite abrasion resistance material is obtained afterwards.
Although technical scheme is described above-mentioned case, the present invention is not limited to above-mentioned specific case
Example, above-mentioned specific embodiment be only it is schematical, it is guiding, rather than limitation, it is every in spirit of the invention
On any improvement for being done each fall within protection scope of the present invention.
Claims (5)
1. a kind of 60 ° of three-dimensional network IPN mutually hands over ceramic skeleton-metal-base composites, it is characterised in that：Including ceramic skeleton
Reinforcement and metallic matrix, metallic matrix wrap up ceramic skeleton, form one.
2. 60 ° of three-dimensional network IPN according to claim 1 mutually hands over ceramic skeleton-metal-base composites, its feature exists
In：The ceramic skeleton is shaped as three-dimensional network IPN, and cylinder interconnection, its center line is mutually 60 °, constitutes positive triangular pyramid
Solid extension assembly shape.
3. 60 ° of three-dimensional network IPN according to claim 1 mutually hands over ceramic skeleton-metal-base composites, its feature exists
In the material of the ceramic skeleton is high alumina ceramic, ZrO2Toughening ceramic, the ceramic material such as silicon carbide ceramics.
4. 60 ° of three-dimensional network IPN according to claim 1 mutually hands over ceramic skeleton-metallic matrix to be combined composite, base
It is characterised by：The metal matrix material is high lattice cast iron, potassium steel, wear-resisting alloy steel, heat resisting steel and non-ferrous alloy material
It is a kind of.
5. a kind of 60 ° of third hand tap network interpenetrating mutually hands over ceramic skeleton-metal matrix composite materials, it is characterised in that：Its preparation includes
Following steps：
(1) preparation of ceramic skeleton：Making that face shaping is compound in wax stone, plastics or other organic meltable, combustible materials will
The porous body that 60 ° of the three-dimensional network IPN asked mutually is handed over.
(2) ceramic slurry is noted to porous body, and solidifies it, dry, sintering obtains 60 ° of three-dimensional network IPN and mutually hands over ceramic bone
Frame.
(3) preparation of ceramic-metal composite material：
Cast design is carried out according to the appearance and size of composite, then the ceramic skeleton matched with casting mold shape is fixed on casting
In type, metallic cementation liquid is then cast, finally cools down, obtains composite.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2016109925806 | 2016-10-31 | ||
| CN201610992580 | 2016-10-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107056257A true CN107056257A (en) | 2017-08-18 |
Family
ID=59622660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710102668.0A Pending CN107056257A (en) | 2016-10-31 | 2017-02-09 | 60 ° of three-dimensional network IPN mutually hands over ceramic skeleton metal-base composites and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107056257A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108171798A (en) * | 2017-12-25 | 2018-06-15 | 中南大学 | A kind of carbon ceramic composite material bone plate of personalization and preparation method thereof |
| CN110128144A (en) * | 2019-06-11 | 2019-08-16 | 北京中煤煤炭洗选技术有限公司 | A kind of metal and ceramic composite |
| CN110819843A (en) * | 2019-11-15 | 2020-02-21 | 南京理工大学 | Negative Poisson's ratio cell lattice-shaped ceramic skeleton reinforced composite material and manufacturing method |
| CN110872655A (en) * | 2018-09-02 | 2020-03-10 | 张志国 | Long-column-shaped ceramic particle reinforcement metal-matrix composite wear-resistant material |
| CN112240729A (en) * | 2019-07-16 | 2021-01-19 | 张志国 | Three-dimensional network ceramic framework metal-based composite armor substrate and liquid forging compounding method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101912957A (en) * | 2010-08-18 | 2010-12-15 | 西安交通大学 | Network interpenetrating ceramic-metal composite material and preparation method thereof |
| CN201959831U (en) * | 2010-11-10 | 2011-09-07 | 广州有色金属研究院 | Ceramic/metal matrix composite hammer |
| CN103060597A (en) * | 2013-01-11 | 2013-04-24 | 浙江天乐新材料科技有限公司 | Reinforced metal composite material of ceramic skeleton with periodical micro truss structure |
-
2017
- 2017-02-09 CN CN201710102668.0A patent/CN107056257A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101912957A (en) * | 2010-08-18 | 2010-12-15 | 西安交通大学 | Network interpenetrating ceramic-metal composite material and preparation method thereof |
| CN201959831U (en) * | 2010-11-10 | 2011-09-07 | 广州有色金属研究院 | Ceramic/metal matrix composite hammer |
| CN103060597A (en) * | 2013-01-11 | 2013-04-24 | 浙江天乐新材料科技有限公司 | Reinforced metal composite material of ceramic skeleton with periodical micro truss structure |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108171798A (en) * | 2017-12-25 | 2018-06-15 | 中南大学 | A kind of carbon ceramic composite material bone plate of personalization and preparation method thereof |
| CN108171798B (en) * | 2017-12-25 | 2020-09-22 | 中南大学 | Personalized carbon-ceramic composite bone fracture plate and preparation method thereof |
| CN110872655A (en) * | 2018-09-02 | 2020-03-10 | 张志国 | Long-column-shaped ceramic particle reinforcement metal-matrix composite wear-resistant material |
| CN110872655B (en) * | 2018-09-02 | 2022-02-08 | 张志国 | Long-column-shaped ceramic particle reinforcement metal-matrix composite wear-resistant material |
| CN110128144A (en) * | 2019-06-11 | 2019-08-16 | 北京中煤煤炭洗选技术有限公司 | A kind of metal and ceramic composite |
| CN112240729A (en) * | 2019-07-16 | 2021-01-19 | 张志国 | Three-dimensional network ceramic framework metal-based composite armor substrate and liquid forging compounding method |
| CN110819843A (en) * | 2019-11-15 | 2020-02-21 | 南京理工大学 | Negative Poisson's ratio cell lattice-shaped ceramic skeleton reinforced composite material and manufacturing method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106978561B (en) | A method of it being in the form of a column the precast body of body bridging arrangement and prepares localization enhancing composite material using the precast body | |
| CN107056257A (en) | 60 ° of three-dimensional network IPN mutually hands over ceramic skeleton metal-base composites and preparation method thereof | |
| CN103641487B (en) | Preparation method and application of ceramic preform | |
| CN101899586B (en) | A kind of preparation technology of composite material prefabricated body | |
| CN109022882B (en) | Preparation method of ceramic particle reinforced metal matrix space lattice composite material | |
| CN104439192B (en) | A kind of ceramic honeycomb metallic composite grinding roller of vertical mill preparation method | |
| CN108342657A (en) | A kind of high abrasion cermet composite roll set and preparation method thereof | |
| CN102389962B (en) | A particle immersion casting process for preparing cemented carbide/steel laminated composites | |
| CN102861905B (en) | Preparation method of aluminum oxide metal ceramic reinforced iron-based composite | |
| JP2002542035A (en) | Dies and methods for manufacturing parts | |
| CN101134237A (en) | Reinforced Phase Metal Gradient Composite Manufacturing Process and Equipment | |
| JP2006188421A5 (en) | ||
| CN104399930A (en) | Method for centrifugally casting vertical mill roller made of ceramic-metal honeycomb composite materials | |
| CN104692803B (en) | The preparation method of wearing composite material precast body | |
| CN104707972B (en) | A kind of preparation method of composite wear-resistant part | |
| CN102513520A (en) | Method for preparing heat-fatigue-resistance wear-resistance laminated particle reinforced composite material | |
| CN104801695A (en) | Method for preparing grey cast iron-based wear-resistant surface layer composite by utilizing normal-pressure cast-infiltration | |
| CN109280795A (en) | A kind of nano-micron SiC particle reinforced wear-resistant aluminum matrix composite material and preparation method thereof | |
| CN113718156B (en) | Preparation method of WC particle reinforced iron-based composite material with three-dimensional prefabricated body structure | |
| US6403153B1 (en) | Mechanical locking/constrainment of an active layer on a solid support | |
| CN103785841A (en) | Manufacturing method for composite wear-resistant parts formed by slurry coating surface activation ZTA particles and reinforced iron matrixes | |
| CN107587043A (en) | The preparation method of reaction induced impregnated porcelain particle reinforced steel-base composite material tup | |
| CN205270754U (en) | A combined type ceramic core for making quick -witted casket component of large -scale complicacy | |
| CN102416462B (en) | A kind of preparation method of metal-base composites of local enhancement | |
| CN105750481B (en) | A kind of water based paint for preventing large-scale steel-casting orange peel defect |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |