CN107033603A - A kind of high-temperature-rescontrol control cable material - Google Patents
A kind of high-temperature-rescontrol control cable material Download PDFInfo
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- CN107033603A CN107033603A CN201710221292.5A CN201710221292A CN107033603A CN 107033603 A CN107033603 A CN 107033603A CN 201710221292 A CN201710221292 A CN 201710221292A CN 107033603 A CN107033603 A CN 107033603A
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- control cable
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- 239000000463 material Substances 0.000 title claims abstract description 23
- 239000010455 vermiculite Substances 0.000 claims abstract description 34
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 34
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 21
- 150000002148 esters Chemical class 0.000 claims abstract description 20
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 13
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 11
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 11
- 241001330002 Bambuseae Species 0.000 claims abstract description 11
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 11
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 11
- ZNZHSFWSIXLDJQ-UHFFFAOYSA-M [O-][Cr](O[Cr](O)(=O)=O)(=O)=O.N.[K+] Chemical compound [O-][Cr](O[Cr](O)(=O)=O)(=O)=O.N.[K+] ZNZHSFWSIXLDJQ-UHFFFAOYSA-M 0.000 claims abstract description 11
- 239000011425 bamboo Substances 0.000 claims abstract description 11
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 11
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 11
- 239000003610 charcoal Substances 0.000 claims abstract description 11
- BJAJDJDODCWPNS-UHFFFAOYSA-N dotp Chemical compound O=C1N2CCOC2=NC2=C1SC=C2 BJAJDJDODCWPNS-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001971 elastomer Polymers 0.000 claims abstract description 11
- 239000012530 fluid Substances 0.000 claims abstract description 11
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 10
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims abstract description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 10
- GYUPBLLGIHQRGT-UHFFFAOYSA-N pentane-2,4-dione;titanium Chemical compound [Ti].CC(=O)CC(C)=O GYUPBLLGIHQRGT-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000010451 perlite Substances 0.000 claims abstract description 10
- 235000019362 perlite Nutrition 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000010457 zeolite Substances 0.000 claims abstract description 10
- 239000006096 absorbing agent Substances 0.000 claims abstract description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 34
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 29
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 27
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 13
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 13
- 238000001994 activation Methods 0.000 claims description 10
- 230000004913 activation Effects 0.000 claims description 10
- -1 dimethyl formyl Amine Chemical class 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000001694 spray drying Methods 0.000 claims description 7
- 238000005292 vacuum distillation Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 5
- 229920001732 Lignosulfonate Polymers 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 5
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 5
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 claims description 3
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 claims description 3
- 230000031709 bromination Effects 0.000 claims description 2
- 238000005893 bromination reaction Methods 0.000 claims description 2
- 229920005549 butyl rubber Polymers 0.000 claims description 2
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- NICYNNGYHJJJMJ-UHFFFAOYSA-N propan-2-one;titanium Chemical compound [Ti].CC(C)=O NICYNNGYHJJJMJ-UHFFFAOYSA-N 0.000 claims 1
- 239000011435 rock Substances 0.000 claims 1
- 239000001993 wax Substances 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- QDMGKUOANLJICG-UHFFFAOYSA-N [Mg].[N+](=O)(O)[O-] Chemical compound [Mg].[N+](=O)(O)[O-] QDMGKUOANLJICG-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 241000545744 Hirudinea Species 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Fireproofing Substances (AREA)
- Insulated Conductors (AREA)
Abstract
The invention discloses a kind of high-temperature-rescontrol control cable material, its raw material includes by weight：25 35 parts of fluorosioloxane rubber, 10 20 parts of brombutyl, 320 28 parts of type neoprenes, 12 parts of benzoyl peroxide, 0.5 1.2 parts of ammonium dichromate potassium, 0.4 0.8 parts of titanium acetylacetone, 12 parts of OPE, 0.2 0.6 parts of vinyl-terminated silicone fluid, 0.5 1.2 parts of di-n-octyl sebacate, 0.1 0.8 parts of DOTP, 15 25 parts of PERFORMANCE OF MODIFIED VERMICULITE, 45 55 parts of perlite, 28 parts of alkaline residue, 4 10 parts of zeolite powder, 15 parts of bamboo charcoal powder, three (16 carbon alcohol) 13 parts of esters, three 12 parts of last of the ten Heavenly stems esters, 531 12 parts of UV absorbers UV.Resistance to elevated temperatures of the present invention is good, excellent fireproof performance, and mechanical property is good.
Description
Technical field
The present invention relates to field of cable technology, more particularly to a kind of high-temperature-rescontrol control cable material.
Background technology
Cable application is extensively, of a great variety, in ac rated voltage 450/750V and following control, monitoring loop and protection
In circuit, each electric appliances, instrument are accomplished by by controlling cable to be attached, and are marked according to the countries of existing GB/T9330-2008
Standard, the long-term permission operating temperature for controlling cable conductor is 70-95 DEG C, and temperature resistant grade is low, and control cable is by high temperature hostile ring
Border or equipment are easy to heating using high-power influence, can also bear in short-term, for a long time can be more and more hotter, or even can occur
It is on fire, trigger a series of security incidents, how to prepare that a kind of resistance to elevated temperatures is good, excellent fireproof performance, the good control of mechanical property
CABLE MATERIALS processed turns into the current technical issues that need to address.
The content of the invention
The present invention proposes a kind of high-temperature-rescontrol control cable material, and resistance to elevated temperatures is good, excellent fireproof performance, mechanical property
It is good.
A kind of high-temperature-rescontrol control cable material proposed by the present invention, its raw material includes by weight：25-35 parts of fluorosioloxane rubber,
10-20 parts of brombutyl, 320 2-8 parts of type neoprenes, 1-2 parts of benzoyl peroxide, 0.5-1.2 parts of ammonium dichromate potassium,
0.4-0.8 parts of titanium acetylacetone, 1-2 parts of OPE, 0.2-0.6 parts of vinyl-terminated silicone fluid, di-n-octyl sebacate 0.5-
1.2 parts, 0.1-0.8 parts of DOTP, 15-25 parts of PERFORMANCE OF MODIFIED VERMICULITE, 45-55 parts of perlite, 2-8 parts of alkaline residue, zeolite
4-10 parts of powder, 1-5 parts of bamboo charcoal powder, three (16 carbon alcohol) 1-3 parts of esters, three ester 1-2 parts of the last of the ten Heavenly stems, UV absorbers UV-531 1-2
Part.
Preferably, PERFORMANCE OF MODIFIED VERMICULITE is prepared using following technique：
Wooden disulfonate acid, zinc nitrate, magnesium nitrate are well mixed, water is added and mixes, nitrogen protection is lower to add hydrogen
Sodium oxide molybdena regulation system pH value is 9-9.8, in 80-90 DEG C of stirring of temperature, centrifuges, dries, pre-process sodium lignin sulfonate；Nitrogen
Under protection, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, VTES are well mixed, added
Azodiisobutyronitrile is well mixed, and is added dimethylformamide in 110-118 DEG C of stirring of temperature, is added the oily ether epoxide third of 3- shrinks
Base trimethoxy silane, mixed in hydrochloric acid stirring, add chloroform in 85-95 DEG C of stirring of temperature, vacuum distillation removes dimethyl
Formamide, chloroform, vermiculite, hyperbranched polyorganosiloxane, pretreatment sodium lignin sulfonate, the acetone for adding hydrochloric acid activation are mixed
Stirring, whipping temp is 75-85 DEG C, ultrasonically treated, is filtered, and spray drying obtains PERFORMANCE OF MODIFIED VERMICULITE.
Preferably, wooden disulfonate acid, zinc nitrate, the weight ratio of magnesium nitrate are 2-6：5-15：2-4.
Preferably, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, VTES, azo two
Isobutyronitrile, the weight ratio of the oily ether epoxide propyl trimethoxy silicane of 3- shrinks are 4-8：5-15：0.15-0.45：0.5-1.5.
Preferably, the vermiculite of hydrochloric acid activation, hyperbranched polyorganosiloxane, the weight ratio of pretreatment sodium lignin sulfonate are 40-
60：2-6：2-4.
Preferably, PERFORMANCE OF MODIFIED VERMICULITE is prepared using following technique：
2-6 parts of wooden disulfonate acids, 5-15 parts of zinc nitrates, 2-4 parts of magnesium nitrates are well mixed by weight, 80- is added
120 parts of water mix 2-4h, and the lower sodium hydroxide regulation system pH value that adds of nitrogen protection is 9-9.8, and in temperature, 80-90 DEG C is stirred
2-4h is mixed, is centrifuged, is dried, sodium lignin sulfonate is pre-processed；Under nitrogen protection, by weight by 4-8 parts 9,10- dihydro-9-oxies
Miscellaneous -10- phospho hetero phenanthrenes -10- oxides, 5-15 parts of VTESs are well mixed, and add 0.15-0.45 parts of azos two
Isobutyronitrile is well mixed, and is added 60-100 parts of dimethylformamides in 110-118 DEG C of stirring 2-4h of temperature, is added 0.5-1.5 parts
The oily ether epoxide propyl trimethoxy silicane of 3- shrinks, 2-8 parts of concentration are that 0.2-0.8mol/L mixed in hydrochloric acid stirs 50-100min,
35-45 parts of chloroforms are added in 85-95 DEG C of stirring 60-100min of temperature, vacuum distillation removes dimethylformamide, three chloromethanes
Alkane, adds vermiculite, 2-6 parts of hyperbranched polyorganosiloxanes, 2-4 parts of pretreatment sodium lignin sulfonates, the 60- of 40-60 parts of hydrochloric acid activations
100 parts of acetone mix 2-4h, and whipping temp is 75-85 DEG C, and ultrasonically treated 40-80min is filtered, and spray drying is changed
Property vermiculite.
Preferably, described high-temperature-rescontrol control cable material, its raw material includes by weight：26-30 parts of fluorosioloxane rubber, bromination
14-18 parts of butyl rubber, 320 4-6 parts of type neoprenes, 1.2-1.5 parts of benzoyl peroxide, 0.6-0.8 parts of ammonium dichromate potassium,
0.5-0.7 parts of titanium acetylacetone, 1.4-1.8 parts of OPE, 0.3-0.5 parts of vinyl-terminated silicone fluid, di-n-octyl sebacate
0.6-1 parts, 0.2-0.5 parts of DOTP, 20-22 parts of PERFORMANCE OF MODIFIED VERMICULITE, 50-52 parts of perlite, 4-6 parts of alkaline residue, boiling
6-8 parts of stone flour, 2-4 parts of bamboo charcoal powder, three (16 carbon alcohol) 1.5-2 parts of esters, three ester 1.2-1.5 parts of the last of the ten Heavenly stems, UV absorbers UV-
531 1.5-1.8 parts.
In the PERFORMANCE OF MODIFIED VERMICULITE of the present invention, by certain technique to sodium lignin sulfonate intercalation modifying, obtained pretreatment wood
Quality sodium sulfonate excellent adsorption, solubilising is good, hyperbranched polyorganosiloxane be three-dimensional globular structure highly branched thing, 9,10- hydrogen-
9- oxa- -10- phospho hetero phenanthrene -10- oxides, VTES shrink oily under the initiation of azodiisobutyronitrile with 3-
Ether epoxide propyl trimethoxy silicane is acted on, and vermiculite with hydrochloric acid activation, pretreatment sodium lignin sulfonate be grafted on it is hyperbranched
On polysiloxanes, product is not only thermally-stabilised good, moderate viscosity, and phosphorus content is low, and good flame retardation effect, dispersive property is excellent, solubilising
Toughening effect is good, coordinates fluorosioloxane rubber, brombutyl, 320 type neoprene compatibilities good, by benzoyl peroxide,
After ammonium dichromate potassium, titanium acetylacetone crosslinking curing, resistance to elevated temperatures is fabulous, is ensureing product toughness and the preferable bar of hardness
Under part, the ageing-resistant and sealing property of material is excellent, and resistance to tearing can be extremely excellent, and corrosion, and resistance are exempted from inside protection cable
Fire performance extremely excellent.
PERFORMANCE OF MODIFIED VERMICULITE coordinates with perlite, alkaline residue, zeolite powder, bamboo charcoal powder, and not only filling effect is fabulous, and can significantly increase
The mechanical property of material, product hardness and resistance to elevated temperatures are excellent, in addition using OPE, vinyl-terminated silicone fluid, the last of the ten Heavenly stems
Adipate, DOTP synergy, are remarkably improved product pliability, impact resistance, are ensureing physics
While satisfactory mechanical property, enhancing the ageing-resistant of CABLE MATERIALS, toughness and hardness, further with three (16 carbon alcohol) esters, three last of the ten Heavenly stems
Ester, UV absorbers UV-531 coordinate, and further enhance product ageing-resistant performance.The present invention has good high temperature resistant, resistance to
Corrosive nature, it is adaptable to the place of the requirement such as fire-retardant, fire resisting, asepsis environment-protecting, it is to avoid cable skin breakage occurs and severe
Environment is corroded, and extends the service life of cable.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of high-temperature-rescontrol control cable material, its raw material includes by weight：35 parts of fluorosioloxane rubber, brombutyl 10
Part, 320 8 parts of type neoprenes, 1 part of benzoyl peroxide, 1.2 parts of ammonium dichromate potassium, 0.4 part of titanium acetylacetone aoxidizes poly- second
2 parts of alkene wax, 0.2 part of vinyl-terminated silicone fluid, 1.2 parts of di-n-octyl sebacate, 0.1 part of DOTP, PERFORMANCE OF MODIFIED VERMICULITE 25
Part, 45 parts of perlite, 8 parts of alkaline residue, 4 parts of zeolite powder, 5 parts of bamboo charcoal powder, three (16 carbon alcohol) 1 part of esters, three 2 parts of last of the ten Heavenly stems esters, ultraviolet light
1 part of absorbent UV-531.
Embodiment 2
A kind of high-temperature-rescontrol control cable material, its raw material includes by weight：25 parts of fluorosioloxane rubber, brombutyl 20
Part, 320 2 parts of type neoprenes, 2 parts of benzoyl peroxide, 0.5 part of ammonium dichromate potassium, 0.8 part of titanium acetylacetone aoxidizes poly- second
1 part of alkene wax, 0.6 part of vinyl-terminated silicone fluid, 0.5 part of di-n-octyl sebacate, 0.8 part of DOTP, PERFORMANCE OF MODIFIED VERMICULITE 15
Part, 55 parts of perlite, 2 parts of alkaline residue, 10 parts of zeolite powder, 1 part of bamboo charcoal powder, three (16 carbon alcohol) 3 parts of esters, three 1 part of last of the ten Heavenly stems esters, ultraviolet light
2 parts of absorbent UV-531.
Embodiment 3
A kind of high-temperature-rescontrol control cable material, its raw material includes by weight：30 parts of fluorosioloxane rubber, brombutyl 14
Part, 320 6 parts of type neoprenes, 1.2 parts of benzoyl peroxide, 0.8 part of ammonium dichromate potassium, 0.5 part of titanium acetylacetone, oxidation is poly-
1.8 parts of ethylene waxes, 0.3 part of vinyl-terminated silicone fluid, 1 part of di-n-octyl sebacate, 0.2 part of DOTP, PERFORMANCE OF MODIFIED VERMICULITE
22 parts, 50 parts of perlite, 6 parts of alkaline residue, 6 parts of zeolite powder, 4 parts of bamboo charcoal powder, three (16 carbon alcohol) 1.5 parts of esters, three 1.5 parts of last of the ten Heavenly stems esters,
UV-5311.5 parts of UV absorbers.
PERFORMANCE OF MODIFIED VERMICULITE is prepared using following technique：By weight by 6 parts of wooden disulfonate acids, 5 parts of zinc nitrates, 4 parts of nitric acid
Magnesium is well mixed, and is added 80 parts of water and is mixed 4h, it is 9 to add sodium hydroxide regulation system pH value under nitrogen protection, in temperature
90 DEG C of stirring 2h, centrifuge, dry, pre-process sodium lignin sulfonate；Under nitrogen protection, by weight by 8 parts of 9,10- dihydros -9-
Oxa- -10- phospho hetero phenanthrene -10- oxides, 5 parts of VTESs are well mixed, and add 0.45 part of azodiisobutyronitrile
It is well mixed, 60 parts of dimethylformamides are added in 118 DEG C of stirring 2h of temperature, add 1.5 parts of oily ether epoxide propyl group three of 3- shrinks
Methoxy silane, 2 parts of concentration are that 0.8mol/L mixed in hydrochloric acid stirs 50min, add 45 parts of chloroforms in 85 DEG C of stirrings of temperature
100min, vacuum distillation removes dimethylformamide, chloroform, adds vermiculite, the 6 parts of hyperbranched poly silicon of 40 parts of hydrochloric acid activations
Oxygen alkane, 2 parts of pretreatment sodium lignin sulfonates, 100 parts of acetone mix 2h, and whipping temp is 85 DEG C, ultrasonically treated 40min,
Filtering, spray drying, obtains PERFORMANCE OF MODIFIED VERMICULITE.
Embodiment 4
A kind of high-temperature-rescontrol control cable material, its raw material includes by weight：26 parts of fluorosioloxane rubber, brombutyl 18
Part, 320 4 parts of type neoprenes, 1.5 parts of benzoyl peroxide, 0.6 part of ammonium dichromate potassium, 0.7 part of titanium acetylacetone, oxidation is poly-
1.4 parts of ethylene waxes, 0.5 part of vinyl-terminated silicone fluid, 0.6 part of di-n-octyl sebacate, 0.5 part of DOTP, modified leech
20 parts of stone, 52 parts of perlite, 4 parts of alkaline residue, 8 parts of zeolite powder, 2 parts of bamboo charcoal powder, three (16 carbon alcohol) 2 parts of esters, three 1.2 parts of last of the ten Heavenly stems esters,
UV-5311.8 parts of UV absorbers.
PERFORMANCE OF MODIFIED VERMICULITE is prepared using following technique：By weight by 2 parts of wooden disulfonate acids, 15 parts of zinc nitrates, 2 parts of nitric acid
Magnesium is well mixed, and is added 120 parts of water and is mixed 2h, it is 9.8 to add sodium hydroxide regulation system pH value under nitrogen protection, in temperature
80 DEG C of stirring 4h of degree, centrifuge, dry, pre-process sodium lignin sulfonate；Nitrogen protection under, by weight by 4 parts of 9,10- dihydros-
9- oxa- -10- phospho hetero phenanthrene -10- oxides, 15 parts of VTESs are well mixed, and add 0.15 part of azo two different
Butyronitrile is well mixed, and is added 100 parts of dimethylformamides in 110 DEG C of stirring 4h of temperature, is added 0.5 part of oily ether epoxide third of 3- shrinks
Base trimethoxy silane, 8 parts of concentration are that 0.2-mol/L mixed in hydrochloric acid stirs 100min, add 35 parts of chloroforms in temperature 95
DEG C stirring 60min, vacuum distillation remove dimethylformamide, chloroform, add 60 parts of hydrochloric acid activations vermiculite, 2 parts over-expense
Change polysiloxanes, 4 parts of pretreatment sodium lignin sulfonates, 60 parts of acetone and mix 4h, whipping temp is 75 DEG C, ultrasonically treated
80min, is filtered, and spray drying obtains PERFORMANCE OF MODIFIED VERMICULITE.
Embodiment 5
A kind of high-temperature-rescontrol control cable material, its raw material includes by weight：28 parts of fluorosioloxane rubber, brombutyl 16
Part, 320 5 parts of type neoprenes, 1.4 parts of benzoyl peroxide, 0.7 part of ammonium dichromate potassium, 0.6 part of titanium acetylacetone, oxidation is poly-
1.6 parts of ethylene waxes, 0.4 part of vinyl-terminated silicone fluid, 0.8 part of di-n-octyl sebacate, 0.4 part of DOTP, modified leech
21 parts of stone, 51 parts of perlite, alkaline residue 5,7 parts of zeolite powder, 3 parts of bamboo charcoal powder, three (16 carbon alcohol) 1.8 parts of esters, three 1.4 parts of last of the ten Heavenly stems esters,
UV-5311.6 parts of UV absorbers.
PERFORMANCE OF MODIFIED VERMICULITE is prepared using following technique：By weight by 4 parts of wooden disulfonate acids, 12 parts of zinc nitrates, 3 parts of nitric acid
Magnesium is well mixed, and is added 115 parts of water and is mixed 3h, it is 9.4 to add sodium hydroxide regulation system pH value under nitrogen protection, in temperature
86 DEG C of stirring 2-4h of degree, centrifuge, dry, pre-process sodium lignin sulfonate；Under nitrogen protection, by weight by 6 parts of 9,10- bis-
Hydrogen -9- oxa- -10- phospho hetero phenanthrene -10- oxides, 12 parts of VTESs are well mixed, and add 0.15-0.45 parts
Azodiisobutyronitrile is well mixed, and is added 85 parts of dimethylformamides in 114 DEG C of stirring 3h of temperature, is added 0.985 part of 3- and shrink
Oily ether epoxide propyl trimethoxy silicane, 4 parts of concentration are that 0.6mol/L mixed in hydrochloric acid stirs 80min, add 40 parts of chloroforms
In 92 DEG C of temperature stirring 80min, vacuum distillation removes dimethylformamide, chloroform, add 55 parts of hydrochloric acid activations vermiculite,
4 parts of hyperbranched polyorganosiloxanes, 3 parts of pretreatment sodium lignin sulfonates, 80 parts of acetone mix 3h, and whipping temp is 82 DEG C, is surpassed
Sonication 65min, is filtered, and spray drying obtains PERFORMANCE OF MODIFIED VERMICULITE.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of high-temperature-rescontrol control cable material, it is characterised in that its raw material includes by weight：25-35 parts of fluorosioloxane rubber, bromination
10-20 parts of butyl rubber, 320 2-8 parts of type neoprenes, 1-2 parts of benzoyl peroxide, 0.5-1.2 parts of ammonium dichromate potassium, acetyl
0.4-0.8 parts of acetone titanium, 1-2 parts of OPE, 0.2-0.6 parts of vinyl-terminated silicone fluid, di-n-octyl sebacate 0.5-1.2
Part, 0.1-0.8 parts of DOTP, 15-25 parts of PERFORMANCE OF MODIFIED VERMICULITE, 45-55 parts of perlite, 2-8 parts of alkaline residue, zeolite powder 4-
10 parts, 1-5 parts of bamboo charcoal powder, three (16 carbon alcohol) 1-3 parts of esters, three ester 1-2 parts of the last of the ten Heavenly stems, 1-2 parts of UV absorbers UV-531.
2. high-temperature-rescontrol control cable material according to claim 1, it is characterised in that PERFORMANCE OF MODIFIED VERMICULITE uses following technique system
It is standby：Wooden disulfonate acid, zinc nitrate, magnesium nitrate are well mixed, water is added and mixes, nitrogen protection is lower to add sodium hydroxide
Regulation system pH value is 9-9.8, in 80-90 DEG C of stirring of temperature, centrifuges, dries, pre-process sodium lignin sulfonate；Nitrogen is protected
Under, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, VTES are well mixed, azo is added
Bis-isobutyronitrile is well mixed, and is added dimethylformamide in 110-118 DEG C of stirring of temperature, is added the oily ether epoxide propyl group three of 3- shrinks
Methoxy silane, mixed in hydrochloric acid stirring, add chloroform in 85-95 DEG C of stirring of temperature, vacuum distillation removes dimethyl formyl
Amine, chloroform, vermiculite, hyperbranched polyorganosiloxane, pretreatment sodium lignin sulfonate, the acetone for adding hydrochloric acid activation are mixed and stirred
Mix, whipping temp is 75-85 DEG C, ultrasonically treated, is filtered, spray drying obtains PERFORMANCE OF MODIFIED VERMICULITE.
3. high-temperature-rescontrol control cable material according to claim 2, it is characterised in that wooden disulfonate acid, zinc nitrate, nitric acid
The weight ratio of magnesium is 2-6：5-15：2-4.
4. high-temperature-rescontrol control cable material according to claim 2, it is characterised in that the miscellaneous -10- phosphas of 9,10- dihydro-9-oxies
Phenanthrene -10- oxides, VTES, azodiisobutyronitrile, 3- shrink oily ether epoxide propyl trimethoxy silicane
Weight ratio is 4-8：5-15：0.15-0.45：0.5-1.5.
5. high-temperature-rescontrol control cable material according to claim 2, it is characterised in that vermiculite, the hyperbranched poly of hydrochloric acid activation
Siloxanes, the weight ratio of pretreatment sodium lignin sulfonate are 40-60：2-6：2-4.
6. the high-temperature-rescontrol control cable material according to claim any one of 2-5, it is characterised in that PERFORMANCE OF MODIFIED VERMICULITE is using as follows
It is prepared by technique：2-6 parts of wooden disulfonate acids, 5-15 parts of zinc nitrates, 2-4 parts of magnesium nitrates are well mixed by weight, 80- is added
120 parts of water mix 2-4h, and the lower sodium hydroxide regulation system pH value that adds of nitrogen protection is 9-9.8, and in temperature, 80-90 DEG C is stirred
2-4h is mixed, is centrifuged, is dried, sodium lignin sulfonate is pre-processed；Under nitrogen protection, by weight by 4-8 parts 9,10- dihydro-9-oxies
Miscellaneous -10- phospho hetero phenanthrenes -10- oxides, 5-15 parts of VTESs are well mixed, and add 0.15-0.45 parts of azos two
Isobutyronitrile is well mixed, and is added 60-100 parts of dimethylformamides in 110-118 DEG C of stirring 2-4h of temperature, is added 0.5-1.5 parts
The oily ether epoxide propyl trimethoxy silicane of 3- shrinks, 2-8 parts of concentration are that 0.2-0.8mol/L mixed in hydrochloric acid stirs 50-100min,
35-45 parts of chloroforms are added in 85-95 DEG C of stirring 60-100min of temperature, vacuum distillation removes dimethylformamide, three chloromethanes
Alkane, adds vermiculite, 2-6 parts of hyperbranched polyorganosiloxanes, 2-4 parts of pretreatment sodium lignin sulfonates, the 60- of 40-60 parts of hydrochloric acid activations
100 parts of acetone mix 2-4h, and whipping temp is 75-85 DEG C, and ultrasonically treated 40-80min is filtered, and spray drying is changed
Property vermiculite.
7. the high-temperature-rescontrol control cable material according to claim any one of 1-6, it is characterised in that its raw material is wrapped by weight
Include：26-30 parts of fluorosioloxane rubber, 14-18 parts of brombutyl, 320 4-6 parts of type neoprenes, benzoyl peroxide 1.2-1.5
Part, 0.6-0.8 parts of ammonium dichromate potassium, 0.5-0.7 parts of titanium acetylacetone, 1.4-1.8 parts of OPE, vinyl-terminated silicone fluid
0.3-0.5 parts, 0.6-1 parts of di-n-octyl sebacate, 0.2-0.5 parts of DOTP, 20-22 parts of PERFORMANCE OF MODIFIED VERMICULITE, pearl
50-52 parts of rock, 4-6 parts of alkaline residue, 6-8 parts of zeolite powder, 2-4 parts of bamboo charcoal powder, three (16 carbon alcohol) 1.5-2 parts of esters, three last of the ten Heavenly stems ester 1.2-
1.5 parts, 1.5-1.8 parts of UV absorbers UV-531.
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| CN201710221292.5A CN107033603A (en) | 2017-04-06 | 2017-04-06 | A kind of high-temperature-rescontrol control cable material |
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| CN201710221292.5A CN107033603A (en) | 2017-04-06 | 2017-04-06 | A kind of high-temperature-rescontrol control cable material |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140065336A1 (en) * | 2011-03-31 | 2014-03-06 | Zeon Corporation | Highly saturated nitrile rubber composition and cross-linked rubber |
| CN104240814A (en) * | 2014-09-30 | 2014-12-24 | 王子跃 | Technical manufacturing method for heat-dissipation cable |
| CN105185451A (en) * | 2015-09-22 | 2015-12-23 | 晋源电气集团股份有限公司 | Marine anti-aging and corrosion resistant cable |
-
2017
- 2017-04-06 CN CN201710221292.5A patent/CN107033603A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140065336A1 (en) * | 2011-03-31 | 2014-03-06 | Zeon Corporation | Highly saturated nitrile rubber composition and cross-linked rubber |
| CN104240814A (en) * | 2014-09-30 | 2014-12-24 | 王子跃 | Technical manufacturing method for heat-dissipation cable |
| CN105185451A (en) * | 2015-09-22 | 2015-12-23 | 晋源电气集团股份有限公司 | Marine anti-aging and corrosion resistant cable |
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