CN1069920C - 一种无磷消毒洗衣粉 - Google Patents
一种无磷消毒洗衣粉 Download PDFInfo
- Publication number
- CN1069920C CN1069920C CN97107718A CN97107718A CN1069920C CN 1069920 C CN1069920 C CN 1069920C CN 97107718 A CN97107718 A CN 97107718A CN 97107718 A CN97107718 A CN 97107718A CN 1069920 C CN1069920 C CN 1069920C
- Authority
- CN
- China
- Prior art keywords
- sodium
- washing powder
- phosphate
- disinfecting washing
- washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005406 washing Methods 0.000 title claims abstract description 13
- 239000000843 powder Substances 0.000 title claims abstract description 11
- 230000000249 desinfective effect Effects 0.000 title claims description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 6
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 9
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 5
- 239000004744 fabric Substances 0.000 abstract description 4
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 4
- 241000894006 Bacteria Species 0.000 abstract description 3
- 239000000645 desinfectant Substances 0.000 abstract description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 229940045872 sodium percarbonate Drugs 0.000 abstract 1
- 239000002351 wastewater Substances 0.000 abstract 1
- 239000003599 detergent Substances 0.000 description 7
- 229920000136 polysorbate Polymers 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000002087 whitening effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000001205 polyphosphate Substances 0.000 description 2
- 235000011176 polyphosphates Nutrition 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000000172 allergic effect Effects 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 229910052722 tritium Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
一种无磷消毒洗衣粉，由二聚硅酸钠，聚丙烯酸钠，阴离子、非离子表面活性剂的复配，过碳酸钠，碳酸氢钠，硫酸钠等配成，具有去污力等各项指标达到和超过国家标准，洗涤废水排放实现100%无磷化，所用材料可生物降解，对环境不形成任何污染，杀灭细菌能力高达95%以上，对人体无刺激，无蓄积毒性作用，对织物和器皿无损害、无腐蚀、长期使用安全无害，是适用范围广泛的消毒洗涤用品。
Description
本发明涉及一种粉状合成洗涤剂无磷化消毒配方。
现有的有磷洗衣粉的配方中含有15-50％的聚磷酸盐，聚磷酸盐导致地表水”富营养”化，从而造成极大的环境污染，破坏生态平衡。世界上的发达国家已明文规定在合成洗涤品中限制或禁止使用磷酸盐，用无磷洗衣粉代替有磷洗衣粉是发展的方向。无磷洗衣粉的现有配方(专利申请号：94104517)采用偏硅酸钠和聚丙烯酸钠的混配物，也有采用柠檬酸盐、氮氚醋酸盐、沸石等作为无磷洗衣粉的软水成份，以及使用单纯非离子活性剂等的配方均存在对污垢离子的悬浮、分散性能较差、去污力不理想等缺陷。
现有消毒洗衣粉多为含氯或含季氨盐的产品，前者有刺激性大，冲洗不净会损伤衣物的缺点；后者消毒效果差，去污能力不强，有致皮肤过敏现象。
本发明的目的是改进上述现有技术的缺点，提供一种无磷，去污力强，具有消毒作用，对人体无刺激，对织物无损害，能完全生物降解，对环境彻底无污染的洗衣粉。
本发明是这样实现的：本发明的无磷化消毒洗衣粉是选用下列成份及其重量百分比：
二聚硅酸钠10-30％；聚丙烯酸钠4-10％；非离子表面活性剂10-20％；阴离子表面活性剂4-10％；过碳酸钠8-20％；碳酸氢钠10-30％；硫酸钠10-30％。另含香精少量。
二聚硅酸钠能与水中金属离子起置换反应而生成水不溶物。由于聚硅酸盐的分子量大于正硅酸盐和偏硅酸盐，所形成的胶体溶液对污垢离子的悬浮，分散作用优于后两者；聚丙烯酸钠能降低水的硬度，有絮凝作用，使污渍不易沉积；当二聚硅酸钠和聚丙烯酸钠混合使用时，对污垢离子有较强的悬浮、分散、乳化作用，且能降低水的硬度，使形成的悬浮液易于清洗；采用非离子表面活性剂与阴离子表面活性剂的复配，是洗涤的主要成份，具有较高的去污除垢能力；碳酸氢钠起助洗作用，进一步提高去污力；在配方中采用过碳酸钠，能释放出一种过氧化物H2O2，对细菌有较强的杀灭作用，对织物有漂白、增艳的作用，其水溶解度高，与其它成分协同作用，使得本产品既有较强的去污除垢能力，能较好的杀菌消毒。
本发明产品去污力等各项指标达到和超过国家标准，洗涤废水排放实现100％无磷化，所用材料可生物降解，对环境不形成任何污染，杀灭细菌能力高达95％以上，对人体无刺激，无蓄积毒性作用，对织物和器皿无损害、无腐蚀、长期使用安全无害，是适用范围广泛的消毒洗涤用品。
实施例：
本发明可按以下配方实施：
实施例1．材料名称 用量(％)二聚硅酸钠 30聚丙烯酸钠 4非离子活性剂 20阴离子活性剂 4过碳酸钠 20碳酸氢钠 10增白剂、香精 微量硫酸钠 12
实施例2．材料名称 用量(％)二聚硅酸钠 10聚丙烯酸钠 10非离子活性剂 10阴离子活性剂 10过碳酸钠 8碳酸氢钠 30硫酸钠 22增白剂、香精 微量
实施例3．材料名称 用量(％)二聚硅酸钠 15聚丙烯酸钠 8非离子活性剂 15阴离子活性剂 8过碳酸钠 10碳酸氢钠 20硫酸钠 28增白剂、香精 微量
在本发明的实施过程中，二聚硅酸钠的用量优选为：15-30％(重量百分比)；聚丙烯酸钠的用量优选为：5-10％(重量百分比)。
本发明经四川省日用化工产品质量监督检验站检验，未检出总五氧化二磷，去污力大于1.0，符合国家标准GB13174对无磷洗衣粉WL--B型的要求。
Claims (3)
1．一种无磷消毒洗衣粉，其特征在于它是选用下列成分及其重量百分比：
二聚硅酸钠 10-30％
非离子表面活性剂 10-20％
阴离子表面活性剂 4-10％
聚丙烯酸钠 4-10％
过碳酸钠 8-20％
碳酸氢钠 10-30％
硫酸钠 10-30％。
2．如权利要求1所述的一种无磷消毒洗衣粉，其特征在于：二聚硅酸钠的用量为15-30％。
3．如权利要求1所述的一种无磷消毒洗衣粉，其特征在于：聚丙烯酸钠的用量为5-10％。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97107718A CN1069920C (zh) | 1997-10-14 | 1997-10-14 | 一种无磷消毒洗衣粉 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97107718A CN1069920C (zh) | 1997-10-14 | 1997-10-14 | 一种无磷消毒洗衣粉 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1214362A CN1214362A (zh) | 1999-04-21 |
| CN1069920C true CN1069920C (zh) | 2001-08-22 |
Family
ID=5169812
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97107718A Expired - Fee Related CN1069920C (zh) | 1997-10-14 | 1997-10-14 | 一种无磷消毒洗衣粉 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1069920C (zh) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109095C (zh) * | 2000-01-28 | 2003-05-21 | 杜倩 | 一种无磷无铝洗衣粉及其制造工艺 |
| CN101514308B (zh) * | 2009-03-19 | 2010-12-01 | 同济大学 | 一种以聚环氧琥珀酸为洗涤助剂的环境友好型合成洗涤剂 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0042647A1 (en) * | 1980-06-20 | 1981-12-30 | Unilever N.V. | Particulate, soap-containing detergent composition |
| CN1110987A (zh) * | 1994-04-27 | 1995-11-01 | 唐继孟 | 消毒无磷洗衣粉及其制作方法 |
-
1997
- 1997-10-14 CN CN97107718A patent/CN1069920C/zh not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0042647A1 (en) * | 1980-06-20 | 1981-12-30 | Unilever N.V. | Particulate, soap-containing detergent composition |
| CN1110987A (zh) * | 1994-04-27 | 1995-11-01 | 唐继孟 | 消毒无磷洗衣粉及其制作方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1214362A (zh) | 1999-04-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8211842B2 (en) | Preventive and/or curative agent for cleaning materials that are brought into contact with water | |
| CN102382728A (zh) | 一种内衣专用洗衣液及其制备方法 | |
| CN101070512B (zh) | 洗衣机槽清洁剂 | |
| CN106190639A (zh) | 一种清洁剂 | |
| WO2008040151A1 (fr) | Détergent synthétique et son procédé de préparation | |
| CN103194326B (zh) | 一种阴阳离子表面活性剂复合型的消毒洗衣液及制备方法 | |
| KR100533123B1 (ko) | 의료의 세탁 방법 및 이를 위한 세정제 조성물 | |
| CN109370799A (zh) | 一种抗菌洗衣液及其用途 | |
| CN101248168A (zh) | 衣料的洗涤方法及用于该方法的洗涤剂组合物 | |
| CN1069920C (zh) | 一种无磷消毒洗衣粉 | |
| CN109135958A (zh) | 一种具有时序性的抗菌洗涤颗粒及其制备方法 | |
| CN103805351A (zh) | 一种无泡洗涤剂及其制备方法 | |
| CN103773617A (zh) | 一种鞋袜专用洗涤液及其制备方法 | |
| CN1030227C (zh) | 一种高效无毒杀菌多用途洗涤剂 | |
| CN101376869A (zh) | 盐白洗衣粉 | |
| WO2008040152A1 (fr) | Détergent solide et son procédé de préparation | |
| JP5852843B2 (ja) | 殺菌性組成物 | |
| CN1045990C (zh) | 消毒、无磷洗衣粉及其制作方法 | |
| CN1094749A (zh) | 一种兼具消毒、杀菌作用的洗涤剂 | |
| CN100389659C (zh) | 消毒方法,消毒/洗涤剂,以及洗涤方法 | |
| JP6184024B2 (ja) | 粒状洗剤 | |
| JP3938445B2 (ja) | 洗浄剤 | |
| JPH11302694A (ja) | 硬質表面用固形洗浄剤組成物 | |
| CN1978611A (zh) | 新型无磷无毒强力杀菌洗衣粉 | |
| CN102816646A (zh) | 一种医院用抑菌漂白洗衣液及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |