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CN106966506A - A kind of SBR method of wastewater treatment and device that carbon is released including online eddy flow - Google Patents

A kind of SBR method of wastewater treatment and device that carbon is released including online eddy flow Download PDF

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CN106966506A
CN106966506A CN201710369165.XA CN201710369165A CN106966506A CN 106966506 A CN106966506 A CN 106966506A CN 201710369165 A CN201710369165 A CN 201710369165A CN 106966506 A CN106966506 A CN 106966506A
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carbon
eddy flow
sludge
cyclone
sbr
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徐银香
汪华林
刘毅
方元元
王振华
曾涛
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Shanghai Huachang Environmental Protection Co Ltd
Sichuan University of Science and Engineering
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Shanghai Huachang Environmental Protection Co Ltd
Sichuan University of Science and Engineering
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/301Aerobic and anaerobic treatment in the same reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C19/00Other disintegrating devices or methods
    • B02C19/0012Devices for disintegrating materials by collision of these materials against a breaking surface or breaking body and/or by friction between the material particles (also for grain)
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C2201/00Codes relating to disintegrating devices adapted for specific materials
    • B02C2201/06Codes relating to disintegrating devices adapted for specific materials for garbage, waste or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/04Flow arrangements

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Activated Sludge Processes (AREA)

Abstract

本发明涉及一种包括在线旋流释碳的SBR废水处理方法,所述方法包括在SBR生化池中进行的进水阶段、曝气阶段、沉淀阶段、滗水阶段和闲置阶段,其中在曝气阶段通过旋流释碳器对SBR生化池中的内回流混合液进行在线旋流释碳,以及其中将经过在线旋流释碳的混合液再次回流到SBR生化池。本发明还涉及用于实施上述包括在线旋流释碳的SBR废水处理方法的装置。本发明的有益效果在于提高生化效能和污泥减量;具有“过程减排”的创新思路,减少污泥处理处置成本;以及旋流释碳器具有能耗低、无二次污染、结构简单、易更换和不影响系统稳定运行的特点。

The present invention relates to a kind of SBR waste water treatment method that comprises on-line cyclone release carbon, and described method comprises the water inflow stage, aeration stage, sedimentation stage, decanting stage and idle stage carried out in SBR biochemical tank, wherein in aeration In the first stage, the internal return mixed liquid in the SBR biochemical pool is subjected to online cyclone carbon release through the cyclone carbon release device, and the mixed liquid that has undergone online cyclone carbon release is returned to the SBR biochemical pool again. The present invention also relates to a device for implementing the above-mentioned SBR wastewater treatment method including online swirl carbon release. The invention has the beneficial effects of improving biochemical performance and sludge reduction; it has the innovative idea of "process emission reduction" and reduces the cost of sludge treatment and disposal; and the cyclone carbon release device has low energy consumption, no secondary pollution, and a simple structure , Easy to replace and does not affect the stable operation of the system.

Description

一种包括在线旋流释碳的SBR废水处理方法及装置A SBR wastewater treatment method and device including online swirling carbon release

技术领域technical field

本发明属于活性污泥法废水处理工艺改造领域,涉及一种包括在线旋流释碳的SBR废水处理方法及装置,具体地,在传统的SBR生化池旁安装旋流释碳装置,在曝气阶段同步引入在线旋流释碳工艺强化缺氧/好氧生物脱氮效能和和实现污泥减量的方法,以及实现该方法的装置。The invention belongs to the field of activated sludge process wastewater treatment process transformation, and relates to an SBR wastewater treatment method and device including online swirl carbon release, specifically, a swirl carbon release device is installed next to the traditional SBR biochemical pool, and the aeration At the same time, the online cyclone carbon release process is introduced to enhance the performance of anoxic/aerobic biological nitrogen removal and realize the method of sludge reduction, as well as the device to realize the method.

背景技术Background technique

现有较成熟的工业生活废水的净化处理技术包括物理、化学、生物处理法,因自然界存在大量的微生物,具有氧化分解有机物并将其转化为无机物的巨大功能,还可以使某些有毒的有机物如酚、醛、脂等无害化,故生物处理法是污水处理的主体工艺。SBR(Sequencing Batch Activated Sludge Reactor Technology)即序批式活性污泥法与其它工艺不同,它采用时间分割代替空间分割的操作方式,工艺过程包括5个阶段,即进水、曝气、沉淀、滗水、闲置阶段。该工艺构筑物数量少、造价低,不需要二沉地,便于操作和维护管理,避免了传统厌氧反应器处理效率低、占地大的缺点,被全球广泛认同。The existing relatively mature purification and treatment technologies for industrial and domestic wastewater include physical, chemical and biological treatment methods. Because there are a large number of microorganisms in nature, they have the great function of oxidatively decomposing organic matter and converting it into inorganic matter, and can also make some toxic substances Organic substances such as phenols, aldehydes, fats, etc. are harmless, so biological treatment is the main process of sewage treatment. SBR (Sequencing Batch Activated Sludge Reactor Technology) is different from other processes. It uses time division instead of space division. The process includes 5 stages, namely water inflow, aeration, sedimentation, decanting Water, idle phase. The process has a small number of structures, low cost, no need for secondary sinking, easy operation and maintenance management, and avoids the shortcomings of traditional anaerobic reactors such as low treatment efficiency and large land occupation, and is widely recognized around the world.

现有的工业污水存在大量的毒性和难降解污染物,长期包裹在活性污泥絮体表面无法降解或脱离而造成传质受阻、导致硝化或反硝化细菌不能及时得到营养供应使细菌活性变差。另外,随着人民生活水平的提高,城镇化建设的加快,生活废水中营养元素N、P浓度提高,导致进水C相对浓度降低,影响反硝化脱氮效果。除污泥传质受阻、污泥活性低、脱氮除磷效率等问题外,剩余污泥产量大、有机毒性高、难以资源化处理等问题也是现有污水处理所面临的重大难题。针对以上问题,中国发明专利申请201210067683.3公开了一种在污水处理主要工艺内填充生物载体填料富有供微生物生长的微量元素,生物载体独特的形式能形成DO多变环境,污泥停留时间长,实现污泥减量的目的;中国发明专利申请201210172789.X公开了一种在厌氧池中入固态营养盐进行反硝化等厌氧生化反应,实现污泥减量;中国发明专利申请200910072268.5公开了一种将部分污泥超声破碎、臭氧处理后与城市污水一起进入初沉池进行水解酸化处理,提高污泥活性、强化脱氮除磷效果;中国发明专利申请201410753368.5公开了一种强化型同步脱氮除磷污水处理方法及装置;中国发明专利申请201310392290.4公开一种污水脱氮处理工艺,通过向污水中投加有机物以补充脱氮除磷碳源不足。以上专利主要通过额外添加一些物质或者增加能耗实现污泥减量、强化脱氮除磷,但这些方法存在二次污染、运行不稳定、运行成本高等问题。污泥产量和不稳定性主要在于污泥絮体内富含大量有机质所致,故考虑在生化处理过程中,对污泥絮体进行机械破碎,释放絮体内多糖和蛋白质等有机质,并作为有机碳源在反应池中再利用,以实现过程减排;活性游离菌群可在生物处理过程中再次形成高活性污泥絮体,以强化系统生化效能,符合污泥源头减量和实现污泥资源化利用的要求。There are a lot of toxic and refractory pollutants in the existing industrial sewage, which cannot be degraded or detached from the surface of activated sludge flocs for a long time, resulting in blocked mass transfer, resulting in the inability of nitrifying or denitrifying bacteria to obtain nutrient supply in time, resulting in poor bacterial activity . In addition, with the improvement of people's living standards and the acceleration of urbanization, the concentration of nutrient elements N and P in domestic wastewater has increased, resulting in a decrease in the relative concentration of C in the influent, affecting the effect of denitrification and denitrification. In addition to problems such as hindered sludge mass transfer, low sludge activity, and nitrogen and phosphorus removal efficiency, problems such as large excess sludge output, high organic toxicity, and difficulty in recycling are also major problems faced by existing sewage treatment. In view of the above problems, Chinese invention patent application 201210067683.3 discloses a method of filling biological carrier filler in the main process of sewage treatment, which is rich in trace elements for microbial growth. The unique form of biological carrier can form a DO variable environment, and the sludge residence time is long. Realize The purpose of sludge reduction; Chinese invention patent application 201210172789.X discloses a kind of anaerobic biochemical reaction such as denitrification in the anaerobic tank, which is filled with solid nutrient salts, to achieve sludge reduction; Chinese invention patent application 200910072268.5 discloses a Part of the sludge is ultrasonically crushed and ozone treated, and then enters the primary sedimentation tank together with urban sewage for hydrolysis and acidification treatment to improve sludge activity and strengthen the effect of nitrogen and phosphorus removal; Chinese invention patent application 201410753368.5 discloses an enhanced synchronous denitrification Phosphorus removal sewage treatment method and device; Chinese invention patent application 201310392290.4 discloses a sewage denitrification treatment process, by adding organic matter to sewage to supplement the lack of carbon sources for nitrogen and phosphorus removal. The above patents mainly achieve sludge reduction and enhanced nitrogen and phosphorus removal by adding some additional substances or increasing energy consumption. However, these methods have problems such as secondary pollution, unstable operation, and high operating costs. The sludge yield and instability are mainly caused by the large amount of organic matter in the sludge flocs. Therefore, it is considered to mechanically crush the sludge flocs during the biochemical treatment process to release organic matter such as polysaccharides and proteins in the flocs, and use them as organic carbon. The source is reused in the reaction tank to achieve process emission reduction; the active free bacteria can form highly active sludge flocs again in the biological treatment process to strengthen the biochemical efficiency of the system, which is in line with the reduction of sludge source and the realization of sludge resources utilization requirements.

在现有SBR污水处理工程中,为强化污泥絮体周边的剪切效应,保持活性污泥具有高活性、小絮体的结构特性,以及去除包覆在絮体表面难降解胶体物质提高有机污染物到絮体活性区的传质,常通过强化曝气强度以加强池内混合和剪切效果。这样势必造成空气曝气的能耗浪费。为此,在传统SBR工艺曝气阶段增设旋流释碳器,利用废水旋流场中的剪切应力场使大部分污泥絮体破碎和进行絮体周边剪切处理,脱除细菌和絮体表面吸附的胶体物质,暴露酶活性位点、提高污泥活性。再者,在旋流剪切应力和离心力作用下,絮体细胞内或孔隙中的多糖和蛋白质等有机碳源脱离至水体中,用于补充异养菌降解污染物(氨氮等)所需能源。生化系统中有机物的消耗避免了其沉积转化为剩余污泥排出,防止湿泥大面积堆放导致的环境污染。在传统的SBR污水处理系统旁只需建立旋流释碳器,运行过程中不需要投加药剂,能耗主要为旋流释碳器前潜污泵加压,具有运行成本低,无副产物的优点,而且在生化处理过程中减少剩余污泥产量,减少了污泥处理成本和运输成本,符合国家提倡的“过程减排”环保策略。In the existing SBR sewage treatment project, in order to strengthen the shear effect around the sludge flocs, maintain the activated sludge with high activity and the structural characteristics of small flocs, and remove the refractory colloidal substances coated on the surface of the flocs to improve the organic The mass transfer of pollutants to the floc active area is often enhanced by strengthening the aeration intensity to enhance the mixing and shearing effect in the tank. This will inevitably result in waste of energy consumption for air aeration. For this reason, a cyclone carbon release device is added in the aeration stage of the traditional SBR process, and the shear stress field in the wastewater swirl field is used to break most of the sludge flocs and perform shearing treatment around the flocs to remove bacteria and flocs. The colloidal substances adsorbed on the body surface expose the enzyme active sites and increase the sludge activity. Furthermore, under the action of swirling shear stress and centrifugal force, organic carbon sources such as polysaccharides and proteins in floc cells or pores are detached into the water body to supplement the energy required by heterotrophic bacteria to degrade pollutants (ammonia nitrogen, etc.) . The consumption of organic matter in the biochemical system avoids its deposition and conversion into excess sludge and discharge, and prevents environmental pollution caused by large-scale stacking of wet mud. Next to the traditional SBR sewage treatment system, it is only necessary to set up a cyclone carbon release device, and there is no need to add chemicals during operation. The energy consumption is mainly to pressurize the submersible sewage pump before the cyclone carbon release device. It has low operating costs and no by-products. In addition, it reduces the production of excess sludge in the process of biochemical treatment, reduces the cost of sludge treatment and transportation, and is in line with the environmental protection strategy of "process emission reduction" advocated by the state.

发明内容Contents of the invention

本发明提供一种包括在线旋流释碳的SBR废水处理方法,在传统SBR污水处理系统中增设旋流释碳器管路,以提高活性污泥生物活性、强化污水处理工艺效能和实现污泥减量。用于实施上述方法的装置结构简单、能耗低并能减少湿泥大面积堆积造成的环境污染。The invention provides an SBR wastewater treatment method including on-line swirl carbon release, in which a swirl carbon release device pipeline is added to the traditional SBR sewage treatment system to improve the biological activity of activated sludge, strengthen the efficiency of sewage treatment process and realize the sludge decrease. The device used for implementing the above method has simple structure, low energy consumption and can reduce environmental pollution caused by large area accumulation of wet mud.

为了解决现有技术中存在的问题,本发明提供下述技术方案:In order to solve the problems in the prior art, the present invention provides the following technical solutions:

在第一方面中,本发明提供一种包括在线旋流释碳的SBR废水处理方法,所述方法包括在SBR生化池中进行的进水阶段、曝气阶段、沉淀阶段、滗水阶段和闲置阶段,其中在曝气阶段通过旋流释碳器对SBR生化池中的内回流混合液进行在线旋流释碳,以及其中将经过在线旋流释碳的混合液再次回流到SBR生化池。In a first aspect, the present invention provides a method for treating SBR wastewater comprising online cyclone release of carbon, said method comprising the water intake stage, aeration stage, settling stage, decanting stage and idle stage carried out in the SBR biochemical tank stage, wherein in the aeration stage, the internal return mixed liquid in the SBR biochemical pool is subjected to online cyclone carbon release through the cyclone carbon release device, and the mixed liquid that has undergone online cyclone carbon release is returned to the SBR biochemical pool again.

在第一方面的一种实施方式中,所述在线旋流释碳构造成(1)利用外加能量场将污泥絮团破散成更小的絮体结构,清理细胞表面杂质并疏通所述絮体结构内部营养物质传递通道,强化所述絮体结构的界面传质性能,使所述絮体结构保持比污泥絮团更高的活性和生化性能;或(2)在旋流剪切场作用下,使完全破解的污泥絮团将有机质释放至水体中,补充微生物进行反硝化反应所需电子供体,强化脱氮效能,所述有机质包括胞外聚合物(Extracellular Polymeric Substances,EPS)、胞内多糖和蛋白质等;或(3)使污泥絮体释放至水体中的有机质被微生物降解,阻碍系统生物总量的增加和代谢废物的产生,最终削减剩余污泥产量;或(4)提高反应池内流体湍动度,促进细菌反应产物间传递速率,增加微生物与废水污染物的接触概率,强化生化效能;或者(1)-(4)中的任意组合。In one embodiment of the first aspect, the online swirling carbon release is configured to (1) use an external energy field to break up the sludge flocs into smaller floc structures, clean up impurities on the cell surface and dredge the Nutrient transfer channel inside the floc structure, strengthen the interfacial mass transfer performance of the floc structure, so that the floc structure maintains higher activity and biochemical properties than the sludge floc; or (2) in the swirl shear Under the action of the field, the completely disintegrated sludge flocs will release organic matter into the water body, supplement the electron donors required by microorganisms for denitrification reaction, and strengthen the denitrification performance. The organic matter includes Extracellular Polymeric Substances (EPS ), intracellular polysaccharides and proteins, etc.; or (3) the organic matter released from the sludge flocs into the water body is degraded by microorganisms, which hinders the increase of the total biomass of the system and the generation of metabolic waste, and finally reduces the remaining sludge production; or ( 4) Increase the fluid turbulence in the reaction tank, promote the transfer rate between bacterial reaction products, increase the contact probability between microorganisms and wastewater pollutants, and strengthen the biochemical efficiency; or any combination of (1)-(4).

在第一方面的另一种实施方式中,所述旋流释碳器在曝气阶段引入,其同步运行时间根据污水水质设定,其中旋流释碳器的剪切作用和离心作用释放包覆在絮体表面和孔隙的堵塞杂质,暴露酶活性位点,提高絮体结构的活性,且其中旋流释碳器入口流速是1-10m/s,优选地1-7m/s。In another embodiment of the first aspect, the cyclone carbon release device is introduced in the aeration stage, and its synchronous operation time is set according to the water quality of the sewage, wherein the shearing action and centrifugal action of the cyclone carbon release device release the package The clogging impurities covering the surface and pores of the flocs expose enzyme active sites and improve the activity of the floc structure, and the flow rate at the inlet of the cyclone carbon release device is 1-10m/s, preferably 1-7m/s.

在第一方面的另一种实施方式中,所述旋流释碳器内部强剪切效应的形成来自于旋流场内液体自身流动形成的速度梯度和压力梯度,所述旋流释碳器包括进料口、圆柱段、锥段、溢流管和底流管,所述旋流释碳器进料口和底流管之间的压降为0.02MPa-0.5MPa,溢流口质量流量为进料口流量的1%-10%,使流场切变速率G>1000s-1In another embodiment of the first aspect, the formation of the strong shear effect inside the cyclone carbon release device comes from the velocity gradient and pressure gradient formed by the liquid's own flow in the swirl field, and the cyclone carbon release device Including the feed inlet, cylindrical section, cone section, overflow pipe and underflow pipe, the pressure drop between the feed inlet and the underflow pipe of the cyclone carbon releaser is 0.02MPa-0.5MPa, and the mass flow rate of the overflow outlet is 1%-10% of the flow rate at the feed port, so that the flow field shear rate G>1000s -1 .

在第一方面的另一种实施方式中,在在线旋流释碳过程中,部分细菌在旋流剪切作用下死亡,释放出的有机质被异养菌降解,减少了剩余污泥产量。In another embodiment of the first aspect, during the online cyclone carbon release process, some bacteria die under the action of cyclone shearing, and the released organic matter is degraded by heterotrophic bacteria, reducing the output of excess sludge.

在第一方面的另一种实施方式中,在SBR污水处理工艺曝气阶段引入旋流释碳器,促进池内流体快速流动,污泥絮体间相互剪切,释放包覆在絮体表面杂质,促进界面传质;同时增加细菌与废水污染物的接触概率,提高污染物的降解速率,强化生化效能。In another embodiment of the first aspect, a cyclone carbon release device is introduced in the aeration stage of the SBR sewage treatment process to promote the rapid flow of fluid in the tank, and the sludge flocs shear each other to release the impurities coated on the surface of the flocs , promote interfacial mass transfer; at the same time increase the contact probability between bacteria and wastewater pollutants, increase the degradation rate of pollutants, and enhance biochemical efficiency.

在第二方面中,本发明提供一种用于实施如权利要求1所述的方法的装置,所述装置可包括通过管线连接的用于污水预处理的沉砂池、用于脱氮除磷的SBR生化池、用于进行在线旋流释碳的旋流释碳器。In a second aspect, the present invention provides a device for implementing the method as claimed in claim 1, the device may include a grit chamber connected by pipelines for sewage pretreatment, a denitrification and dephosphorization SBR biochemical pool, cyclone carbon release device for online cyclone carbon release.

在第二方面的一种实施方式中,所述旋流释碳器可包括进料口、圆柱段、锥段、溢流管和底流管,所述旋流释碳器进料口的流量范围为1-100m3/h,根据实际混合液回流量确定旋流释碳器单管的公称直径,或通过并联多根旋流释碳器单管的方式解决大流量混合液处理工况。In an embodiment of the second aspect, the cyclone carbon release device may include a feed inlet, a cylindrical section, a cone section, an overflow pipe and an underflow pipe, and the flow range of the feed inlet of the cyclone carbon release device is 1-100m 3 /h, determine the nominal diameter of the cyclone carbon releaser single tube according to the actual mixed liquid return flow, or solve the large flow mixed liquid treatment condition by connecting multiple cyclone carbon releaser single tubes in parallel.

在第二方面的另一种实施方式中,所述旋流释碳器可采用单进口或多进口,锥段锥角为4°-20°。In another embodiment of the second aspect, the cyclone carbon release device can adopt single inlet or multiple inlets, and the cone angle of the cone section is 4°-20°.

在第二方面的另一种实施方式中,所述旋流释碳器进料口可采用切线进口,进口形状采用圆形或方形。In another embodiment of the second aspect, the feed inlet of the cyclone carbon release device may adopt a tangential inlet, and the shape of the inlet may be circular or square.

在第二方面的另一种实施方式中,所述旋流释碳器可采用串联方式以增加污泥絮体在旋流场中的停留时间,以适应不同工况下所要求的污泥絮团破碎率。In another embodiment of the second aspect, the cyclone carbon release device can be connected in series to increase the residence time of the sludge flocs in the swirl field, so as to adapt to the sludge flocs required under different working conditions. Group breakage rate.

与现有技术相比,本发明的有益效果在于利用旋流释碳器的旋流剪切和离心作用破碎活性污泥,释放污泥中的多糖和蛋白质等有机碳源至水体中,补充微生物进行反硝化反应所需碳源降解污染物,提高生化效能和污泥减量。与其它污泥破解技术相比,此技术处理对象并不是对已经产生的剩余污泥进行破解,而是在生化处理过程中阻止了生物量的大量增加和代谢产物产生,具有“过程减排”的创新思路,减少污泥处理处置成本。另一方面,存活微生物在剪切场作用下仍保持着高活性,用于污水高效处理。再者,旋流释碳器具有能耗低、无二次污染、结构简单、易更换和不影响系统稳定运行的特点。Compared with the prior art, the beneficial effect of the present invention is that the activated sludge is crushed by the cyclone shearing and centrifugal action of the cyclone carbon release device, the organic carbon sources such as polysaccharides and proteins in the sludge are released into the water body, and the microorganisms are replenished. The carbon source required for denitrification reaction degrades pollutants, improving biochemical efficiency and sludge reduction. Compared with other sludge cracking technologies, the treatment object of this technology is not to crack the excess sludge that has already been produced, but to prevent the large increase of biomass and the production of metabolites during the biochemical treatment process, which has "process emission reduction" Innovative ideas to reduce sludge treatment and disposal costs. On the other hand, surviving microorganisms still maintain high activity under the action of shear field, which can be used for efficient sewage treatment. Furthermore, the cyclone carbon release device has the characteristics of low energy consumption, no secondary pollution, simple structure, easy replacement and does not affect the stable operation of the system.

附图说明:Description of drawings:

根据结合附图进行的如下详细说明,本发明的目的和特征将变得更加明显,附图中:According to the following detailed description carried out in conjunction with the accompanying drawings, the objects and features of the present invention will become more apparent, in the accompanying drawings:

图1是根据本发明的一个实施方式的一种活性污泥旋流释碳在线强化SBR废水处理的工艺流程图;Fig. 1 is a process flow diagram of an activated sludge cyclone release carbon online strengthening SBR wastewater treatment according to an embodiment of the present invention;

图2是根据本发明的实施例的旋流释碳器的半剖结构示意图;以及Fig. 2 is a schematic diagram of a half-section structure of a cyclone carbon release device according to an embodiment of the present invention; and

图3是根据本发明的实施例的旋流释碳器的正视结构示意图。Fig. 3 is a front structural schematic diagram of a cyclone carbon release device according to an embodiment of the present invention.

具体实施方式detailed description

本申请的发明人在经过广泛而深入的研究之后发现,随着人民生活水平的提高,废水中氮、磷等元素含量增加,碳源不足,从而导致在生物法净化废水过程中反硝化细菌脱氮效果差,而且产生了大量的剩余污泥,严重污染环境。通过外加甲醇、葡萄糖和碳酸钠等碳源虽然可以提高微生物脱氮除磷的生化效能和降低剩余污泥产量,但增加了大量能耗和资源成本。本发明提出通过旋流释碳器中的特殊流场破解污泥絮体释放EPS和胞内的糖类、蛋白质等有机质以补充微生物降解污染物所需碳源,此方式不但提高了SBR生化池的生化性能和实现剩余污泥过程减排,还降低了剩余污泥处理处置成本、实现污泥资源化和稳定化利用。基于以上发现,本发明得以完成。After extensive and in-depth research, the inventors of the present application found that with the improvement of people's living standards, the content of elements such as nitrogen and phosphorus in wastewater increases, and the carbon source is insufficient, which leads to denitrification bacteria denitrification in the process of biological purification of wastewater. The effect of nitrogen is poor, and a large amount of excess sludge is produced, which seriously pollutes the environment. Although the biochemical efficiency of microbial nitrogen and phosphorus removal can be improved and the yield of excess sludge can be reduced by adding carbon sources such as methanol, glucose and sodium carbonate, but it increases a lot of energy consumption and resource costs. The present invention proposes to release EPS and intracellular carbohydrates, proteins and other organic matter through the special flow field in the cyclone carbon release device to break down the sludge flocs to supplement the carbon source required by microorganisms to degrade pollutants. This method not only improves the SBR biochemical pool It also reduces the cost of excess sludge treatment and disposal, and realizes the resource utilization and stable utilization of sludge. Based on the above findings, the present invention has been accomplished.

在本发明的第一方面,提供一种在SBR生化处理系统短程硝化反硝化过程控制中引入旋流释碳工艺以强化系统生化性能和污泥减量的改进工艺,它包括以下流程:In a first aspect of the present invention, there is provided a kind of improved process that introduces the swirl carbon release process to strengthen the system biochemical performance and sludge reduction in the short-range nitrification and denitrification process control of the SBR biochemical treatment system, which includes the following processes:

在污水处理厂目前采用的SBR污水处理曝气阶段引入旋流释碳器,利用剪切力场、离心力场等外加能量场把大污泥絮团破散成小絮体结构,清理长期覆盖在细胞表面的难降解污染物杂质并疏通絮体内部营养物质传递通道,强化絮体界面传质性能,使小絮体结构保持高活性和高生化性能;In the aeration stage of SBR sewage treatment currently used in sewage treatment plants, a cyclone carbon release device is introduced, and the shear force field, centrifugal force field and other external energy fields are used to break up large sludge flocs into small floc structures, and clean up long-term coverage Refractory pollutants and impurities on the cell surface can dredge the internal nutrient transfer channel of the floc, strengthen the mass transfer performance of the floc interface, and keep the small floc structure with high activity and high biochemical performance;

在强剪切流场中,部分污泥絮体完全破碎释放胞外聚合物(EPS)、胞内多糖和蛋白质等有机质至水体中,用于补充SBR生化池中微生物反硝化反应所需碳源,强化系统脱氮除磷效能;与此同时,系统中有机质的降解,阻碍了系统生物量的增加和代谢产物的产生,防止其沉积成为污泥排出,最终削减了系统剩余污泥产量;In the strong shear flow field, some sludge flocs are completely broken and release organic matter such as extracellular polymeric substances (EPS), intracellular polysaccharides and proteins into the water body, which is used to supplement the carbon source required for microbial denitrification in the SBR biochemical tank , to strengthen the nitrogen and phosphorus removal efficiency of the system; at the same time, the degradation of organic matter in the system hinders the increase of system biomass and the production of metabolites, prevents them from being deposited and discharged as sludge, and finally reduces the remaining sludge output of the system;

另外,反应池混合液经旋流释碳器作用后提高了反应池内(特别是死角区域)流体流动速度,促进了微生物反应产物间传递速率,增加了微生物与废水污染物的接触概率,强化生化效能。In addition, the mixed liquid in the reaction tank increases the fluid flow rate in the reaction tank (especially in the dead zone) after being acted on by the cyclone carbon release device, promotes the transfer rate between microbial reaction products, increases the contact probability between microorganisms and wastewater pollutants, and strengthens the biochemical process. efficacy.

较佳地,SBR污水处理工艺是序列间歇式活性污泥法,包括进水、曝气、沉淀、滗水、闲置共5个阶段,本发明在曝气阶段引入旋流释碳器,其同步运行时间根据污水水质设定;旋流释碳器入口流速控制在1-10m/s,例如优选地1-7m/s,调节其溢流口流量以体积计为进口流量的1%-15%,例如优选地为1%-10%,进出口压降大于0.02MPa,例如进出口压降为0.02MPa-0.5MPa,优选地为0.05-0.1MPa,使流场切变速率G>1000s-1,例如2000s-1、4000s-1,即可利用内部剪切力和离心力作用清理包覆在絮体表面和堵塞孔隙的杂质以暴露蛋白酶活性位点,提高小絮体结构的活性。Preferably, the SBR sewage treatment process is a sequential batch activated sludge process, including five stages of water intake, aeration, sedimentation, decanting, and idleness. The present invention introduces a cyclone carbon release device in the aeration stage, which synchronizes The running time is set according to the water quality of the sewage; the inlet flow rate of the cyclone carbon releaser is controlled at 1-10m/s, such as preferably 1-7m/s, and the flow at the overflow port is adjusted to be 1%-15% of the inlet flow in volume , such as preferably 1%-10%, the inlet and outlet pressure drop is greater than 0.02MPa, for example, the inlet and outlet pressure drop is 0.02MPa-0.5MPa, preferably 0.05-0.1MPa, so that the flow field shear rate G>1000s -1 , such as 2000s -1 , 4000s -1 , the internal shear force and centrifugal force can be used to clean the impurities coated on the surface of the flocs and blocking the pores to expose the protease active sites and improve the activity of the small floc structure.

较佳地,大量污泥絮体经过旋流释碳器破解后释放出的EPS和胞内多糖、蛋白质等有机物用于补充微生物反硝化反应所需碳源,解决了外加碳源所带来的成本高和二次污染等问题。Preferably, EPS, intracellular polysaccharides, protein and other organic matter released after a large amount of sludge flocs are cracked by the cyclone carbon release device are used to supplement the carbon source required for microbial denitrification reaction, which solves the problem caused by the external carbon source. Problems such as high cost and secondary pollution.

较佳地,本发明是在生化处理过程中对活性污泥进行破解,相比于对已经产生的剩余污泥进行破解,既减少了污泥运输成本,又减少了剩余污泥产量,具有过程减排的创新思路。Preferably, the present invention decomposes the activated sludge during the biochemical treatment process. Compared with decomposing the excess sludge that has already been produced, it not only reduces the sludge transportation cost, but also reduces the excess sludge output. It has a process Innovative ideas for reducing emissions.

较佳地,混合液经过旋流释碳器作用后回到SBR生化池中增强了流体湍动度,导致污泥絮体间相互剪切,强化微生物反应产物和溶解氧(Dissolved Oxygen,DO)传质,提高了存活微生物生化活性,可节省曝气能耗20%左右。Preferably, the mixed liquid returns to the SBR biochemical tank after passing through the cyclone carbon release device to enhance the fluid turbulence, resulting in the mutual shearing between the sludge flocs, and the strengthening of microbial reaction products and dissolved oxygen (Dissolved Oxygen, DO) Mass transfer improves the biochemical activity of surviving microorganisms and can save about 20% of aeration energy consumption.

本发明的第二方面,提供旋流强化活性污泥脱氮性能和污泥减量的SBR污水处理改进工艺所需要的主要装置:用于污水预处理的沉砂池、用于脱氮除磷的SBR生化池、用于优化处理工艺的旋流释碳器。The second aspect of the present invention provides the main devices needed for the SBR sewage treatment improvement process of swirl-enhanced activated sludge denitrification performance and sludge reduction: grit chamber for sewage pretreatment, for denitrification and dephosphorization Advanced SBR biochemical pool, cyclone carbon release device for optimizing treatment process.

较佳地,用于优化处理工艺的旋流释碳器流量范围为1-100m3/h,根据实际混合液流量选择旋流释碳器单管的公称直径。Preferably, the flow rate range of the cyclone carbon releaser for optimizing the treatment process is 1-100m 3 /h, and the nominal diameter of the single tube of the cyclone carbon releaser is selected according to the actual mixed liquid flow rate.

较佳地,对于大流量的污泥破解,采用多个小直径旋流释碳器进行并联工作,以保证污泥絮体破碎效率。Preferably, for large-flow sludge cracking, multiple small-diameter cyclone carbon releasers are used to work in parallel to ensure the sludge floc breaking efficiency.

较佳地,旋流释碳器可采用单进口或多进口,锥段锥角为4°-20°,实现污泥高破解率。Preferably, the cyclone carbon release device can adopt a single inlet or multiple inlets, and the cone angle of the cone section is 4°-20°, so as to achieve a high decomposition rate of sludge.

较佳地,旋流释碳器进口采用切线进口,进口形状采用圆形或方形。Preferably, the inlet of the cyclone carbon releaser adopts a tangent inlet, and the shape of the inlet adopts a circle or a square.

较佳地,旋流释碳器采用串联方式来增加污泥絮体在旋流场中的停留时间,以适应不同工况下所要求的污泥破碎率。Preferably, the cyclone carbon release device adopts a series connection method to increase the residence time of the sludge flocs in the cyclone field, so as to adapt to the required sludge crushing rate under different working conditions.

较佳地,旋流释碳器可采用竖向、横向和斜向的安装方式。Preferably, the cyclone carbon release device can be installed vertically, horizontally and obliquely.

以下根据附图详细说明本发明的方法。The method of the present invention will be described in detail below with reference to the accompanying drawings.

图1是根据本发明的一个实施方式的SBR污水处理系统改进工艺流程图。如图1所示,生活或工业废水进入沉砂池1进行过滤分离,预处理后得到的废水进入SBR生化池2,废水中有机污染物在SBR生化池2中通过微生物硝化反硝化反应被降解,从而达到净化污水的目的。旋流释碳器旁路主要用于强化废水处理工艺。其主要步骤如下:在曝气阶段,SBR生化池混合液被泵入旋流释碳器4,旋流场中液体自身流动形成的速度梯度场、压力梯度场和离心场将污泥絮体破碎成小絮体结构,污泥絮体中EPS多糖和蛋白质释放至水体中,破碎后的混合液又回到SBR生化池2,补充SBR生化池2中反硝化所需有机碳源,以强化脱氮及污泥减量。Fig. 1 is an improved process flow chart of the SBR sewage treatment system according to an embodiment of the present invention. As shown in Figure 1, domestic or industrial wastewater enters the grit chamber 1 for filtration and separation, and the pretreated wastewater enters the SBR biochemical pool 2, where the organic pollutants in the wastewater are degraded by microbial nitrification and denitrification reactions in the SBR biochemical pool 2 , so as to achieve the purpose of purifying sewage. The cyclone carbon releaser bypass is mainly used to enhance the wastewater treatment process. The main steps are as follows: In the aeration stage, the mixed liquid of the SBR biochemical tank is pumped into the cyclone carbon release device 4, and the velocity gradient field, pressure gradient field and centrifugal field formed by the liquid's own flow in the cyclone field break up the sludge flocs Form a small floc structure, the EPS polysaccharides and proteins in the sludge flocs are released into the water body, and the broken mixed solution returns to the SBR biochemical pool 2 to supplement the organic carbon source required for denitrification in the SBR biochemical pool 2 to strengthen denitrification. Nitrogen and sludge reduction.

图2是本发明的实施例的一个旋流释碳器的半剖结构示意图。图3是根据本发明的实施例的旋流释碳器的正视结构示意图。旋流释碳器包括进料口21、圆柱段22、锥段23、溢流管24和底流管25,进口采用切线方形进口,锥度为14°。Fig. 2 is a schematic diagram of a half-section structure of a cyclone carbon release device according to an embodiment of the present invention. Fig. 3 is a front structural schematic diagram of a cyclone carbon release device according to an embodiment of the present invention. The cyclone carbon release device includes a feed inlet 21, a cylindrical section 22, a cone section 23, an overflow pipe 24 and an underflow pipe 25. The inlet adopts a tangential square inlet with a taper of 14°.

实施例Example

下面结合具体的实施例进一步阐述本发明。但是,应该明白,这些实施例仅用于说明本发明而不构成对本发明范围的限制。下列实施例中未注明具体条件的试验方法,通常按照常规条件,或按照制造厂商所建议的条件。The present invention is further described below in conjunction with specific examples. However, it should be understood that these examples are only used to illustrate the present invention and not to limit the scope of the present invention. The test methods for which specific conditions are not indicated in the following examples are generally in accordance with conventional conditions, or in accordance with the conditions suggested by the manufacturer.

1、实施流程1. Implementation process

本实施例应用于某生活污水处理厂SBR污水处理系统,进水水质如表1所示。工艺流程示意图如图1所示,废水首先进入沉砂池1去除浮渣,减轻后续工序处理负担,在曝气阶段开启曝气装置,旋流释碳器4支路上泵开关自动打开,污泥絮团被泵入旋流释碳器4,流体自身形成的速度梯度和压力梯度场对污泥絮团剪切破碎,污泥絮团破解成更小的絮体结构,促进污泥絮团中EPS、多糖、蛋白质等释放,破碎后的混合液返回至SBR生化池2,补充微生物反硝化反应所需碳源,以强化微生物脱氮及污泥减量。而且引入旋流释碳器后,增加了污水的流动和混合程度,增加活性污泥与污水的界面传质和接触面积,缩短微生物短程硝化反硝化时间。曝气时间为2h,曝气后经过3小时沉淀后滗水,排放剩余污泥,此为一个周期。旋流释碳器流速为5m/s,其结构示意图如图2和图3所示。This embodiment is applied to an SBR sewage treatment system of a domestic sewage treatment plant, and the influent water quality is shown in Table 1. The schematic diagram of the process flow is shown in Figure 1. The wastewater first enters the grit chamber 1 to remove scum, which reduces the processing burden of the subsequent process. The aeration device is turned on during the aeration stage, and the pump switch on the 4 branches of the cyclone carbon releaser is automatically turned on, and the sludge The flocs are pumped into the cyclone carbon release device 4, and the velocity gradient and pressure gradient field formed by the fluid itself shear and break the sludge flocs, and the sludge flocs are broken into smaller floc structures, which promotes the process of sludge flocs EPS, polysaccharides, proteins, etc. are released, and the crushed mixed solution is returned to the SBR biochemical pool 2 to replenish the carbon source required for microbial denitrification to strengthen microbial denitrification and sludge reduction. Moreover, after the introduction of the cyclone carbon release device, the flow and mixing degree of sewage are increased, the interface mass transfer and contact area between activated sludge and sewage are increased, and the short-range nitrification and denitrification time of microorganisms is shortened. The aeration time is 2 hours. After aeration, after 3 hours of sedimentation, decant the water and discharge the remaining sludge. This is a cycle. The flow rate of the cyclone carbon release device is 5m/s, and its structural schematic diagram is shown in Fig. 2 and Fig. 3 .

表1某生活污水厂进水水质Table 1 Influent water quality of a domestic sewage plant

2、运行结果2. Running results

该污水处理厂的污泥絮体浓度为3000~4000mg/L,SV30为45%左右,操作温度为常温。进水COD为328mg/L,氨氮为38mg/L左右。SBR生化池中活性污泥经过旋流释碳器作用一次平均需要间隔1.5h,实现了35%-80%的污泥絮体被破碎为小絮体结构,释放出絮体内多糖、蛋白质等有机质至水体中被利用,利用本发明提高污水处理系统生化效能和污泥减量。运行过程中,出水COD≤50mg/L,NH4 +-N≤5mg/L,NO3-N≤15mg/L,TP<2mg/L,SS<20mg/L,可实现污泥减量40%左右。The sludge floc concentration of the sewage treatment plant is 3000-4000mg/L, the SV 30 is about 45%, and the operating temperature is normal temperature. Influent COD is 328mg/L, ammonia nitrogen is about 38mg/L. The activated sludge in the SBR biochemical tank needs an average interval of 1.5 hours to pass through the cyclone carbon release device, and 35%-80% of the sludge flocs are broken into small floc structures, releasing organic matter such as polysaccharides and proteins in the flocs. It can be utilized in water bodies, and the biochemical efficiency and sludge reduction of the sewage treatment system can be improved by using the present invention. During operation, effluent COD≤50mg/L, NH 4 + -N≤5mg/L, NO 3 -N≤15mg/L, TP<2mg/L, SS<20mg/L, can achieve 40% sludge reduction about.

能耗方面,相比于传统工艺,本发明所增加的能耗主要是用于支持旋流释碳器作用的泵所提耗能量,所述旋流释碳器的压力损失(即旋流释碳器的进口和底流口之间的损失)在0.15Mpa以下,相对于其它污泥释碳技术来说,极大地降低了能耗成本。In terms of energy consumption, compared with the traditional process, the increased energy consumption of the present invention is mainly used to support the energy consumption of the pump of the cyclone carbon release device, and the pressure loss of the cyclone carbon release device (that is, the cyclone carbon release device) The loss between the inlet of the carbonizer and the underflow outlet) is below 0.15Mpa, which greatly reduces the cost of energy consumption compared with other sludge carbon release technologies.

操作范围和稳定性方面,旋流释碳器装置和操作简单,对不同粒径的污泥絮体都有效,而且从实验结果来看,经过旋流释碳器作用的混合液沉降性有微小的提升作用,不影响系统稳定运行。In terms of operating range and stability, the installation and operation of the cyclone carbon release device is simple, and it is effective for sludge flocs of different particle sizes, and from the experimental results, the settlement of the mixed solution after the cyclone carbon release device is slightly The lifting effect does not affect the stable operation of the system.

3、技术效果3. Technical effect

该技术是在传统的SBR污水处理工艺上进行改造,结构简单,操作简单,能耗低,在生化处理过程中无二次污染,不影响系统稳定运行,在提高净化水出水水质的同时实现过程污泥减量,从而减少污泥处置成本40%左右。且污泥产量的减少防止了污水处理厂的湿泥大面积堆积造成的场地压力和环境污染,给企业带来经济和环保效益。This technology is modified on the traditional SBR sewage treatment process, with simple structure, simple operation, low energy consumption, no secondary pollution in the process of biochemical treatment, and does not affect the stable operation of the system. Sludge reduction, thereby reducing sludge disposal costs by about 40%. Moreover, the reduction of sludge production prevents the site pressure and environmental pollution caused by the large-scale accumulation of wet sludge in sewage treatment plants, and brings economic and environmental benefits to enterprises.

综上所述仅为发明的较佳实施例而已,并非用来限定本发明的实施范围。即凡依本发明申请专利范围的内容所作的等效变化与修饰,都应为本发明的技术范畴。In summary, the above are only preferred embodiments of the invention, and are not intended to limit the implementation scope of the invention. That is, all equivalent changes and modifications made according to the content of the patent scope of the present invention shall be within the technical scope of the present invention.

Claims (10)

1. a kind of SBR method of wastewater treatment that carbon is released including online eddy flow, methods described is included in entering of being carried out in SBR biochemistry pools Water stage, aeration phase, precipitate phase, water stage and idle stage are strained, wherein releasing carbon device to SBR by eddy flow in aeration phase Interior backflow mixed liquor in biochemistry pool carries out online eddy flow and releases carbon, and wherein will release the mixed liquor of carbon again by online eddy flow It is back to SBR biochemistry pools.
2. the method as described in claim 1, it is characterised in that the online eddy flow, which releases carbon and is configured to (1), utilizes external energy Sludge floc sedimentation is broken in field dissipates into smaller flocculation structure, clears up cell surface impurity and simultaneously dredges nutrients inside the flocculation structure Matter transmission channels, strengthen the interfacial mass transfer performance of the flocculation structure, the flocculation structure is kept higher than sludge floc sedimentation Activity and biochemical property;Or (2) are under rotational-flow shearing field action, the sludge floc sedimentation cracked completely is set to discharge organic matter to water body In, supplement microorganism carries out electron donor needed for anti-nitration reaction, and strengthened denitrification efficiency, the organic matter includes extracellular polymeric EPS, intracellular polyse and protein etc.;Or (3) make sludge flco discharge the organic matter into water body to be degraded by microorganisms, system is hindered The increase and the generation of metabolic waste of the biological total amount of system, finally cut down excess sludge production;Or (4) improve fluid rapids in reaction tank Dynamic degree, promotes the contact probability of transfer rate between bacterial reaction product, increase microorganism and Wastewater Pollutant, the biochemical effect of reinforcing Energy;Or any combination in (1)-(4).
3. the method as described in claim 1, it is characterised in that the eddy flow is released carbon device and introduced in aeration phase, it is synchronously transported The row time sets according to sewage quality, wherein eddy flow release carbon device shear action and centrifugal action release be coated on flco surface and The blocking impurity of hole, exposure enzyme active sites, improves the activity of flocculation structure, and it is 1- that wherein eddy flow, which releases carbon device inlet flow rate, 10m/s, preferably 1-7m/s.
4. the method as described in claim 1, it is characterised in that the formation that the eddy flow releases Strong shear effect inside carbon device comes from The velocity gradient and barometric gradient formed is flowed in liquid in eddy flow field itself, the eddy flow, which releases carbon device, includes charging aperture, cylinder Section, cone section, overflow pipe and underflow pipe, the pressure drop that the eddy flow releases between carbon device charging aperture and underflow pipe is 0.02MPa- 0.5MPa, overfall mass flow is the 1%-10% of charging aperture flow, makes flow field shearing G>1000s-1
5. the method as described in claim 1, it is characterised in that during online eddy flow releases carbon, part bacterium is cut in eddy flow The lower death of the effect of cutting, the organic matter discharged is degraded by heterotroph, reduces excess sludge production.
6. a kind of device for being used to implement the method as described in claim 1, described device was included by being used for that pipeline is connected The setting pot of sewage disinfection treatment, the SBR biochemistry pools for denitrogenation dephosphorizing, the eddy flow for releasing for carrying out online eddy flow carbon release carbon device.
7. device as claimed in claim 6, it is characterised in that the eddy flow release carbon device including charging aperture, cylindrical section, cone section, Overflow pipe and underflow pipe, the range of flow that the eddy flow releases carbon device charging aperture are 1-100m3/ h, according to actual mixed-liquor return amount Determine that eddy flow releases the nominal diameter of carbon device single tube, or big flow mixing is solved by way of many eddy flows in parallel release carbon device single tube Liquid handles operating mode.
8. device as claimed in claim 7, it is characterised in that the eddy flow releases carbon device using single import or many imports, bores section Cone angle is 4 ° -20 °.
9. device as claimed in claim 7, it is characterised in that the eddy flow releases carbon device charging aperture and uses tangential inlet, import Shape is using circular or square.
10. device as claimed in claim 6, it is characterised in that the eddy flow releases carbon device and uses series system to increase sludge Residence time of the flco in eddy flow field, to adapt to sludge floc sedimentation percentage of damage required under different operating modes.
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CN110183060A (en) * 2019-06-24 2019-08-30 上海华畅环保设备发展有限公司 Compact aerobic/anaerobic technique waste water handles eddy flow intensifying method and device
CN111233146A (en) * 2020-01-16 2020-06-05 华东理工大学 Sludge rotational flow sorting activation treatment method and device
CN114426329A (en) * 2020-10-10 2022-05-03 中国石油化工股份有限公司 Method and device for enhancing nitrogen and phosphorus removal of SBR system
CN114853118A (en) * 2022-06-06 2022-08-05 北控水务(中国)投资有限公司 Sewage treatment device, system and method
CN116062903A (en) * 2021-10-31 2023-05-05 中国石油化工股份有限公司 A carrier for cultivating anammox bacteria and its preparation method and application

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CN104108794A (en) * 2014-08-11 2014-10-22 吕慧 Wastewater treatment device and method of sequencing batch A/O (Anaerobic/Oxic) linked system for realizing partial nitrification of wastewater
CN105565491A (en) * 2014-10-16 2016-05-11 中国石油化工股份有限公司 Activated sludge treatment method and system for wastewater

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108046550A (en) * 2017-11-28 2018-05-18 四川理工学院 A kind of excess sludge ultrasound rotational flow, which is combined, cracks technique
CN110183060A (en) * 2019-06-24 2019-08-30 上海华畅环保设备发展有限公司 Compact aerobic/anaerobic technique waste water handles eddy flow intensifying method and device
CN111233146A (en) * 2020-01-16 2020-06-05 华东理工大学 Sludge rotational flow sorting activation treatment method and device
CN114426329A (en) * 2020-10-10 2022-05-03 中国石油化工股份有限公司 Method and device for enhancing nitrogen and phosphorus removal of SBR system
CN114426329B (en) * 2020-10-10 2023-01-10 中国石油化工股份有限公司 Method and device for enhancing nitrogen and phosphorus removal of SBR system
CN116062903A (en) * 2021-10-31 2023-05-05 中国石油化工股份有限公司 A carrier for cultivating anammox bacteria and its preparation method and application
CN116062903B (en) * 2021-10-31 2025-10-03 中国石油化工股份有限公司 A carrier for culturing anaerobic ammonia-oxidizing bacteria, and its preparation method and application
CN114853118A (en) * 2022-06-06 2022-08-05 北控水务(中国)投资有限公司 Sewage treatment device, system and method

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