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CN106908866B - Optical film set and method for preventing adhesion - Google Patents

Optical film set and method for preventing adhesion Download PDF

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Publication number
CN106908866B
CN106908866B CN201710156710.7A CN201710156710A CN106908866B CN 106908866 B CN106908866 B CN 106908866B CN 201710156710 A CN201710156710 A CN 201710156710A CN 106908866 B CN106908866 B CN 106908866B
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optical diaphragm
roughness
optical
film
diaphragm
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CN106908866A (en
Inventor
陈兮婷
郭建生
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Sumika Technology Co Ltd
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Sumika Technology Co Ltd
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/12Optical coatings produced by application to, or surface treatment of, optical elements by surface treatment, e.g. by irradiation
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Polarising Elements (AREA)
  • Laminated Bodies (AREA)

Abstract

一种光学膜片组及防止黏片的方法,光学膜片组包括第一光学膜片以及第二光学膜片,第一光学膜片与第二光学膜片分别包括第一表面以及位于第一表面的相反一侧的第二表面。其中,第一表面具有第一粗糙度,第二表面具有第二粗糙度;第一光学膜片与第二光学膜片互相叠合时,第一光学膜片的第一表面与第二光学膜片的第二表面间具有一最大拉力。且第一粗糙度和第二粗糙度的数值总与最大拉力的数值乘积实质小于1000。

An optical film set and a method for preventing film sticking. The optical film set includes a first optical film and a second optical film. The first optical film and the second optical film respectively include a first surface and a first optical film located on the first surface. A second surface on the opposite side of the surface. Wherein, the first surface has a first roughness, and the second surface has a second roughness; when the first optical film and the second optical film are overlapped, the first surface of the first optical film and the second optical film There is a maximum tensile force between the second surfaces of the sheets. And the product of the total numerical value of the first roughness and the second roughness and the numerical value of the maximum tensile force is substantially less than 1000.

Description

Optical diaphragm group and the method for preventing glutinous piece
Technical field
The present invention relates to a kind of plasticizing diaphragms and preparation method thereof.In particular to a kind of optical diaphragm group and its production side Method.
Background technique
Has the plasticizing diaphragm of high-insulativity, because having the property of accumulation electrostatic, in the object that will not leak electrostatic with other Electrostatic can be generated when friction or removing, not only the dirt in air, dust etc. are easy to attach, but will make two two films being in contact with each other Piece mutually sticks together.
When the packaging technology of liquid crystal display panel to be carried out, single piece of optical diaphragm is generally drawn with vacuum slot, to carry out Back segment assembling or working process.Due to, there are electrostatic, causing mutually to inhale between optical diaphragm between the optical diaphragm of mutual storehouse Draw glutinous piece, can not once pluck single piece of optical diaphragm, and interrupt packaging technology, influences the production capacity and yield of liquid crystal display panel.
Summary of the invention
The purpose of the present invention is to provide a kind of advanced optical diaphragm group and glutinous piece method is prevented, to solve the prior art Problem encountered.
It is to provide a kind of optical diaphragm group, including the first optical diaphragm and the second light according to an embodiment of this specification Learn diaphragm, the first optical diaphragm and the second optical diaphragm respectively include first surface and the opposite side positioned at first surface Second surface.Wherein, first surface has the first roughness, and second surface has the second roughness;First optical diaphragm and When two optical diaphragms are mutually superimposed, between the first surface of the first optical diaphragm and the second surface of the second optical diaphragm most with one Big pulling force.And first the numerical value of roughness and the second roughness be always essentially less than 1000 with the numerical value product of maximum pull.
It is to provide a kind of method for preventing optical diaphragm from sticking piece, including following steps according to another embodiment of this specification Rapid: firstly, providing at least two optical diaphragms, making each optical diaphragm includes first surface and the phase positioned at first surface The second surface of anti-side;And makes first surface that there is the first roughness, make second surface that there is the second roughness.Then heap These optical diaphragms of stack, contact the first surface of one of optical diaphragm with the second surface of another one.Wherein, first is coarse The numerical value product of degree and the total maximum pull between first surface and second surface of numerical value of the second roughness is essentially less than 1000.
According to above-mentioned, a kind of method that the embodiment of this specification proposes optical diaphragm group and prevents its glutinous piece, by making The surface that optical diaphragm is located at two opposite sides has different roughness, and meets two surface roughness values sum total and the two Between maximum pull condition of the numerical value product less than 1000.Come at least two optical diaphragms when reducing mutual storehouse due to electrostatic The chance of glutinous piece occurs, to solve the problems, such as that the prior art causes packaging technology production capacity and yield bad because optical diaphragm sticks piece.
Below in conjunction with the drawings and specific embodiments, the present invention will be described in detail, but not as a limitation of the invention.
Detailed description of the invention
A kind of Figure 1A structural perspective of optical diaphragm according to depicted in an embodiment of this specification;
Figure 1B is the structure sectional view of optical diaphragm depicted in tangent line S along Figure 1A;
The structure sectional view of Fig. 1 C optical diaphragm according to depicted in another embodiment of this specification;And
Fig. 2 is painted the structural perspective of the optical diaphragm of attached several mutual storehouses according to an embodiment of this specification.
Wherein, appended drawing reference
100: optical diaphragm 100 ': optical diaphragm
100 ": optical diaphragm 101: polarizing layer
101a: sub- 101b: the first protective layer of polarisation
101c: the second protective layer 102: protective film
102a: protective film upper surface 102b: protective film lower surface
102c: micro-structure 103: stripping film
103a: stripping film lower surface 103b: stripping film upper surface
103c: micro-structure 104: adhesion layer
A: the maximum pull between stripping film lower surface and protective film upper surface
B: protective film upper surface roughness C: stripping film following table surface roughness
F: lateral pull
Specific embodiment
This specification is to provide a kind of optical diaphragm that glutinous piece problem will not occur in packaging technology and prevents its glutinous piece Method, can effectively promote liquid crystal display panel assembling technique production capacity and yield.To allow above and other purpose of the invention, feature It can be clearer and more comprehensible with advantage, connection with several embodiments detailed description is cited below particularly.
But it must be noted that these specific case study on implementation and method, be not intended to limit the invention.The present invention still may be used It is implemented using other features, component, method and parameter.The it is proposed of preferred embodiment is only of the invention to illustrate Technical characteristic, the scope of the claims being not intended to limit the invention.Have usually intellectual in the technical field, it can basis The description of following description is not departing from scope of the invention, makees impartial modification and variation.
Figure 1A and Figure 1B are please referred to, Figure 1A is a kind of optical diaphragm 100 according to depicted in an embodiment of this specification Structural perspective.Figure 1B is the structure sectional view of optical diaphragm 100 depicted in tangent line S along Figure 1A.Wherein, optical film Piece 100 includes at least 101, protective films 102 of a polarizing layer and a stripping film 103.Wherein, protective film 102 has The lower lower surface 102b of upper surface 102a and the opposite side positioned at upper surface 102a;Stripping film 103 has lower surface 103a And the upper surface 103b of the opposite side positioned at lower surface 103a;And the upper surface 103b of stripping film 103 faces protective film 102 Lower surface 102b.Polarizing layer is then located between the upper surface 103b of stripping film 103 and the lower surface 102b of protective film 102.
Among the present embodiment, optical diaphragm 100 is a kind of polarizer, and wherein the polarizing layer 101 of optical diaphragm 100 is at least Including the sub- 101a of a polarisation, a first protective layer 101b and a second protective layer 101c.Wherein, polarisation is 101a sub- Between the first protective layer 101b and the second protective layer 101c;First protective layer 101b is located at protective film 102 and the sub- 101a of polarisation Between;And second protective layer 101c be located between stripping film 103 and the sub- 101a of polarisation.
The sub- 101a of polarisation can be polyvinyl alcohol (PVA) resin film, can be made by saponified poly resin.Poly-vinegar The example of vinyl acetate resin includes single polymer of vinyl acetate, i.e., the co-polymer of polyvinyl acetate and vinyl acetate and Other can carry out the monomer of combined polymerization with vinyl acetate.The example of other monomers that combined polymerization can be carried out with vinyl acetate includes not Saturated carboxylic acid (such as acrylic acid, methacrylic acid, ethyl acrylate, positive propyl acrylate, methyl methacrylate), alkene (such as ethylene, propylene, 1- butylene, 2- first propylene), vinethene (such as ethyl vinyl ether, ethylene methacrylic ether, n-propyl ethylene Ether, isopropyl-ethylene ether), unsaturated sulfonic acid (such as vinyl sulfonic acid, sodium vinyl sulfonate) etc..
The material of first protective layer 101b and/or the second protective layer 101c can be respectively selected from by polymethyl methacrylate (Polymethylmethacrylate, PMMA), trimerization cellulose acetate (Triacetyl Cellulose, TAC), acrylic acid Resin film, poly aromatic hydroxyl resin film, polyether resin film, cyclic polyolefin resin film (such as poly- bornylene resin film), polyester (Polyethylene Terephthalate, PET), polypropylene (Polypropylene, PP), cyclic olefin polymer (Cyclo Olefin Polymer, COP), a group composed by polycarbonate (Polycarbonate, PC) and above-mentioned any combination.
Protective film 102 and stripping film 103 are produced by protecting the complete of polarizing layer 101 and reducing because colliding or stacking Scratch or pressure wound.Protective film 102 and stripping film 103 can have identical or different material.In one embodiment, protective film 102 and stripping film 103 thickness essence between 15 microns to 40 microns.
Such as among some embodiments of this specification, the optional autopolyester tree of the material of protective film 102 and stripping film 103 Rouge, olefin resin, acetyl cellulose resins, polycarbonate resin, acrylic resin, polybutylene terephthalate (polyethylene terephthalate, PET), polyethylene (polyethylene, PE) or polypropylene (Polypropylene, PP), cyclic olefin resins or combinations of the above.Wherein, polyester resin may, for example, be poly terephthalic acid Second diester or polyethylene naphthalate, and acrylic resin may, for example, be polymethyl methacrylate (PMMA).
In addition, further including an adhesion layer 104 between the second protective layer 101c and the upper surface 103b of stripping film 103, it is used to Stripping film 103 is sticked on polarizing layer 101.In the present embodiment, it includes acrylic acid tree that adhesion layer 104, which can be one kind, The pressure-sensing glue (Pressure Sensitive Adhesive, PSA) of ester.
In one embodiment, the upper surface 102a of protective film 102 has essence between 40 nanometers (nm) between 90 nanometers Roughness C.The lower surface 103a of stripping film 103 has roughness B of the essence between 15 nanometers to 40 nanometers.It is real one It applies in example, roughness B and roughness C can be generated in film stretching.
Among some embodiments of this specification, the roughness C of the roughness B of stripping film 103 and protective film 102 can be with By formation micro-structure 103c and micro- knot on the upper surface 102a of the lower surface 103a of stripping film 103 and protective film 102 respectively The mode of structure 102c is realized.Such as Fig. 1 C is please referred to, Fig. 1 C is according to depicted in another embodiment of this specification The structure sectional view of optical diaphragm 100 '.Among the present embodiment, the micro-structure 102c and micro-structure 103c of optical diaphragm 100 ' Generation type, be by blasting treatment or etching process, using without chemically active particulate (not being painted) to protective film 102 The lower surface 103a of upper surface 102a and stripping film 103 is impacted, in the upper surface 102a and stripping film of protective film 102 Multiple recessed portions are formed on 103 lower surface 103a.
Among other embodiments of this specification, the generation type of micro-structure 102c and micro-structure 103c, then be by It is multiple to be formed on the upper surface 102a of protective film 102 and the lower surface 103a of stripping film 103 by deposition and Patternized technique Protrusion.And the numerical value of roughness B and roughness C are adjusted by the density for controlling multiple protrusions or recessed portion.
It please refers to depicted in Fig. 2, an optical diaphragm 100 " is fixed with adhesive tape (not being painted), and by another optical diaphragm 100 are stacked the upper surface 102a and top optical diaphragm 100 for making the protective film 102 of fixed optical diaphragm 100 " thereon Stripping film 103 lower surface 103a contact.It, can by tensile test when top optical diaphragm 100 is pulled by lateral pull F Measure the lower surface 103a of the stripping film 103 of top optical diaphragm 100 and the protective film 102 of fixed optical diaphragm 100 " Upper surface 102a maximum pull A between the two.
Among the embodiment of this specification, the numerical value summation (B+C) and 103 following table of stripping film of roughness B and roughness C Numerical value product (B+C) × A of maximum pull A between 102 upper surface 102a of face 103a and protective film is essentially less than 1000.Its In, maximum pull A value real value is less than 8 newton (N).
The relationship of roughness B, roughness C and maximum pull A are as follows:
A×(B+C)<1000;A<8
Among some embodiments of this specification, it is also an option that property ground (optionally) table on protective film 102 It is respectively coated one layer of antistatic coating (not being painted) on 103 lower surface 103a of face 102a and/or stripping film, uses further adjustment Maximum pull A between 102 upper surface 102a of 103 lower surface 103a of stripping film and protective film.
Wherein, the material of antistatic coating can be (a) with the sun such as 4 grades of ammonium salts, pyridinium salt, the 1st to 3 grade of amido from The various cationic antistatic agents of sub- property group;(b) there is sulfonate group, sulfuric ester alkali, phosphate alkali, phosphonic acids alkali Etc. anionic groups anionic property antistatic agent;(c) both sexes with amido acids, amido sulfuric acid ester etc. are antistatic Agent;(d) the nonionic antistatic agent with amido alcohol system, glycerol system, polyethylene glycol system etc.;Or (e) comprising it is above-mentioned resist it is quiet The macromolecule of electric agent is formed by Polymer Antistatic Agent.
If the lower surface 103a of the stripping film 103 of single optical diaphragm 100 and the upper surface 102a roughness of protective film 102 When B and roughness C and maximum pull A meet the condition of aforementioned mathematical formula, by multiple optical diaphragms 100 in a manner of mutual storehouse It between two optical diaphragms 100 to contact with each other and is not in glutinous when the packaging technology of row transport, storage or progress optical diaphragm The phenomenon that piece.
In one embodiment, also the stripping film 103 for meeting roughness B can be first selected before the formation of optical diaphragm 100, After the protective film 102 of roughness C and the former membrane material of maximum pull A, then the production of optical diaphragm 100 is carried out, to avoid subsequent The phenomenon that glutinous piece.
Following spy enumerates the embodiment of multiple conditions for meeting above-mentioned mathematical expression and the condition for not meeting above-mentioned mathematical expression Multiple comparative examples carry out glutinous built-in testing.By optical diaphragm 100 provided by several pieces of embodiments (or optical diaphragm of comparative example) With the lower surface of the upper surface 102a of the protective film 102 of lower section optical diaphragm 100 and the stripping film 103 of top optical diaphragm 100 The mode that 103a contacts with each other storehouse each other, then pressed 5 minutes or more with weight, after removing weight, taken with hand or with optics Suction nozzle used in diaphragm packaging technology draws (or the optical film of comparative example of a piece of optical diaphragm 100 positioned at the top Piece), detect whether it can adsorb the optical diaphragm 100 (or optical diaphragm of comparative example) of lower section.Testing result, X representative do not stick Piece;O represents glutinous piece
Detailed test situation please refers to following table:
It is worth living to anticipate, although the size for being used to carry out the optical diaphragm of glutinous built-in testing in the above-described embodiments is all 31.5 cun, but be still applied to other sizes in the method and parameter condition of aforementioned anti-glutinous piece, be greater than 40 cun (such as 42 cun, 50 cun or 65 cun) larger size embodiment, be also applied for the smaller ruler less than 26 cun (such as between 15 cun to 26 cun) Very little embodiment.
According to above-mentioned, the embodiment of this specification is a kind of method for proposing optical diaphragm group and preventing its glutinous piece, by The surface for making optical diaphragm be located at two opposite sides has different roughness, and meets two surface roughness values sum total and two Condition of the numerical value product less than 1000 of maximum pull between person.Come at least two optical diaphragms when reducing mutual storehouse because of electrostatic And the chance of glutinous piece occurs, to solve the prior art, because optical diaphragm sticks, piece leads to packaging technology production capacity and yield is bad asks Topic.
It can be before making optical diaphragm by the embodiment of this specification, first suitable according to roughness screening protective layer and stripping From membrane material membrane material, the chance of glutinous piece occurs because of electrostatic come at least two optical diaphragms when reducing mutual storehouse, it is existing to solve There is technology to lead to packaging technology production capacity and the bad problem of yield because optical diaphragm sticks piece.
Although the present invention has been disclosed as a preferred embodiment, however, it is not to limit the invention.Work described herein Skill step and structure are not covered by the complete manufacturing process of production over all Integration circuit.The present invention can be currently known with many or The different production of integrated circuits technologies that future is developed, which merge, to be implemented.There is usual knowledge in the technical field of the invention Person, without departing from the spirit and scope of the present invention, when can be used for a variety of modifications and variations.Therefore, protection scope of the present invention Subject to view appended claims range institute defender.

Claims (10)

1. a kind of optical diaphragm group, including one first optical diaphragm and one second optical diaphragm, first optical diaphragm with should Second optical diaphragm all includes a first surface and a second surface, wherein the first surface of first optical diaphragm with The second surface is located at the opposite side of first optical diaphragm, the first surface of second optical diaphragm and the second surface position In the opposite side of second optical diaphragm;The first surface of first optical diaphragm and first table of second optical diaphragm Face has one first roughness;The second surface of first optical diaphragm has with the second surface of second optical diaphragm One second roughness;When first optical diaphragm and second optical diaphragm are mutually superimposed, first optical diaphragm this first There is a maximum pull between surface and the second surface of second optical diaphragm;
It is characterized in that, a numerical value product of a numerical value summation of first roughness and second roughness and the maximum pull Less than 1000.
2. optical diaphragm group according to claim 1,
It is characterized in that, first roughness between 15 nanometers to 40 nanometers and second roughness between 40 nanometers extremely Between 90 nanometers.
3. optical diaphragm group according to claim 1, which is characterized in that first optical diaphragm and second optical film Piece all includes:
One protective film has the first surface and a third surface,
One stripping film is located at the opposite side of the second surface with the second surface and one the 4th surface, and in face of being somebody's turn to do Third surface;And
One polarizing layer, between the third surface and the 4th surface.
4. optical diaphragm group according to claim 3, which is characterized in that the material of the protective film and the stripping film is selected from poly- Butylene terephthalate (polyethylene terephthalate, PET), polyethylene (polyethylene, PE) or poly- Propylene (Polypropylene, PP), polyethylene terephthalate, polyethylene naphthalate, polymethyl methacrylate (PMMA) or combinations of the above.
5. optical diaphragm group according to claim 3, wherein the polarizing layer is a polarizer characterized by comprising
One first protective layer;
One second protective layer;And
One polarisation, between first protective layer and second protective layer.
6. optical diaphragm group according to claim 1, which is characterized in that first optical diaphragm and second optical film Piece all further includes an antistatic coating and is coated on the first surface and the second surface at least one.
7. optical diaphragm group according to claim 1, which is characterized in that the maximum pull is less than 8 newton.
8. a kind of method for preventing optical diaphragm from sticking piece characterized by comprising
There is provided at least two optical diaphragms, make at least two optical diaphragms each include a first surface and one second table Face, positioned at the opposite side of the first surface;And make the first surface that there is one first roughness, which has one the Two roughness;And
Storehouse at least two optical diaphragms make at least first surface of one of two optical diaphragms and at least two optical films The second surface of the another one of piece contacts;
Wherein, one between first roughness and the numerical value summation and the first surface and the second surface of second roughness One numerical value product of maximum pull is less than 1000.
9. the method according to claim 8 for preventing optical diaphragm from sticking piece, it is characterised in that first roughness is between 15 Nanometer is between 40 nanometers;Second roughness is between 40 nanometers to 90 nanometers;The maximum pull is less than 8 newton.
10. it is according to claim 8 prevent optical diaphragm stick piece method, which is characterized in that first optical diaphragm with Second optical diaphragm all includes:
One protective film, has the first surface and a third surface, and a stripping film has the second surface and one the 4th table Face is located at the opposite side of the second surface, and faces the third surface, and a polarizing layer is located at the third surface and the 4th table Between face;And
Wherein the material of the protective film and the stripping film is selected from polybutylene terephthalate (polyethylene Terephthalate, PET), it is polyethylene (polyethylene, PE) or polypropylene (Polypropylene, PP), poly- to benzene two Formic acid second diester, polyethylene naphthalate, polymethyl methacrylate (PMMA) or combinations of the above.
CN201710156710.7A 2016-06-03 2017-03-16 Optical film set and method for preventing adhesion Active CN106908866B (en)

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TW105117598A TWI581039B (en) 2016-06-03 2016-06-03 Optical film set and anti-adhesion method
TW105117598 2016-06-03

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6553800B1 (en) * 2018-12-26 2019-07-31 グンゼ株式会社 Protective film, protective film with adhesive layer, and transparent film with protective film
CN109683221A (en) * 2019-01-16 2019-04-26 苏州世沃电子科技有限公司 A kind of novel optical diaphragm group and preparation method for preventing glutinous piece
TWI755283B (en) * 2021-02-20 2022-02-11 住華科技股份有限公司 Polarizer structure, manufacturing method and evaluation method of the same, and display device using the same

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US20080143928A1 (en) * 2005-02-03 2008-06-19 Fujifilm Corporation Polarizing Plate and Liquid Crystal Display Device
TW200831962A (en) * 2006-09-21 2008-08-01 Fujifilm Corp Polaring plate and liquid crystal device
CN101887143A (en) * 2009-05-14 2010-11-17 吉罗企划股份有限公司 Protective film for polarizing element, polarizing plate and liquid crystal display element
CN103922606A (en) * 2014-04-09 2014-07-16 上海和辉光电有限公司 Coater chuck capable of preventing glass sticking
TW201542369A (en) * 2014-03-03 2015-11-16 Konica Minolta Inc Functional film, polarizing plate and display device

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Publication number Priority date Publication date Assignee Title
US20080143928A1 (en) * 2005-02-03 2008-06-19 Fujifilm Corporation Polarizing Plate and Liquid Crystal Display Device
TW200831962A (en) * 2006-09-21 2008-08-01 Fujifilm Corp Polaring plate and liquid crystal device
CN101887143A (en) * 2009-05-14 2010-11-17 吉罗企划股份有限公司 Protective film for polarizing element, polarizing plate and liquid crystal display element
TW201542369A (en) * 2014-03-03 2015-11-16 Konica Minolta Inc Functional film, polarizing plate and display device
CN103922606A (en) * 2014-04-09 2014-07-16 上海和辉光电有限公司 Coater chuck capable of preventing glass sticking

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TWI581039B (en) 2017-05-01
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