[go: up one dir, main page]

CN106891271A - 一种不锈钢切割砂轮及其制备方法 - Google Patents

一种不锈钢切割砂轮及其制备方法 Download PDF

Info

Publication number
CN106891271A
CN106891271A CN201710267926.0A CN201710267926A CN106891271A CN 106891271 A CN106891271 A CN 106891271A CN 201710267926 A CN201710267926 A CN 201710267926A CN 106891271 A CN106891271 A CN 106891271A
Authority
CN
China
Prior art keywords
stainless steel
emery wheel
abrasive grains
silicon carbide
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710267926.0A
Other languages
English (en)
Other versions
CN106891271B (zh
Inventor
陈金身
陈锋
智红梅
樊雪琴
白静
董德胜
张朝阳
杜晓冉
段晓琴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongqi Pipeline Technology Henan Co ltd
Original Assignee
Henan University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan University of Technology filed Critical Henan University of Technology
Priority to CN201710267926.0A priority Critical patent/CN106891271B/zh
Publication of CN106891271A publication Critical patent/CN106891271A/zh
Application granted granted Critical
Publication of CN106891271B publication Critical patent/CN106891271B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • B24D18/0009Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/20Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
    • B24D3/28Resins or natural or synthetic macromolecular compounds
    • B24D3/285Reaction products obtained from aldehydes or ketones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/20Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
    • B24D3/28Resins or natural or synthetic macromolecular compounds
    • B24D3/32Resins or natural or synthetic macromolecular compounds for porous or cellular structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/34Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
    • B24D3/342Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent
    • B24D3/344Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent the bonding agent being organic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/34Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
    • B24D3/346Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties utilised during polishing, or grinding operation

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

一种不锈钢切割砂轮,其特征在于,该切割砂轮原料包括混合磨粒、填料、造孔剂、树脂、增强材料组成。所述混合磨粒为黑碳化硅、单晶刚玉、棕刚玉、棕刚玉‑氧化铈核/壳复合磨粒、铁尖晶石,所述填料为沸石、碳化硅微粉,树脂为腰果酚改性的酚醛树脂,增强材料为含有石墨的玻璃纤维网。本发明的优点在于:1、磨具孔隙率大,便于容屑;2、磨削区温度低不会导致工件烧伤;3、氧化铈的化学机械抛光原理,从而改善切割加工表面的微观状况,降低粗糙度;4、由于混合磨粒采用了不同硬度的不同种类的磨粒搭配,切削效率高;5、切割刀口窄,切割面平整,节约昂贵的被切割材料;6、采用了磨削层和非磨削层设计降低了成本;7、不含氟化物,减少了环境污染。

Description

一种不锈钢切割砂轮及其制备方法
技术领域
本发明属机械加工领域,具体涉及一种不锈钢切割砂轮及其制备方法。
背景技术
不锈钢以其优良的耐腐蚀性能,良好的力学性能和加工性能及较好的焊接性能,成为被广泛选用的工程材料。同时,通过不同的抛光加工方法,可以使各种不锈钢板材、管材、棒材、异型材的表面具有不同等级的表面光洁度,大大改善了不锈钢的外观,使之达到美学效果,增加了对消费者的吸引力,给人们以美的享受。但是, 从钢厂购来的耐热不锈钢长杆要落成短料,用剪切方法导致模具大量损坏, 且剪切后的材料纵向有微小裂纹存在,用普通砂轮切断,其砂轮的磨损较大,且刀口消耗不锈钢量大,这严重影响着产品质量和劳动生产效率,也造成极大地浪费。
发明内容
本发明的目的正是针对现有技术中所存在的问题而提供的一种切削效率高、耐磨性好、表面光洁度高的不锈钢切割专用砂轮。
本发明的目的是通过以下技术方案来实现的:
本发明的新型不锈钢切割砂轮,原料包括混合磨粒、填料、造孔剂、树脂、增强材料组成。所述混合磨粒为黑碳化硅、单晶刚玉、棕刚玉、棕刚玉-氧化铈核/壳复合磨粒、铁尖晶石,所述填料为沸石、碳化硅微粉,树脂为腰果酚改性的酚醛树脂,增强材料为含有石墨的玻璃纤维网。各原料的重量百分比为:混合磨粒75%~85%,填料3%~7%,造孔剂1%~3%,树脂10%~15%。
具体制备方法为:
本发明的切割砂轮的制造方法具体步骤如下:
a、混合磨粒→润湿剂→混合→填料→混合→树脂粉→混合均匀为成型料;
b、玻璃纤维网浸润一层含有石墨且经硫酸钙晶须原位聚合而成腰果酚改性的酚醛树脂;
c、将成型料投入已加热至85℃的模具中,中间加入玻璃纤维网,温热成型;
d、投料时非磨削层和磨削层同时投,第一道非磨削层80g,磨削层180g,第二道非磨削层180g,磨削层280g;
e、非磨削层配方为:30#棕刚玉20%,36#石榴石30%,40#尖晶石20%,石膏15%,树脂15%;
f、采用梯度固化工艺。
本发明的有益效果是:
1、采用黑碳化硅、单晶刚玉、棕刚玉、棕刚玉-氧化铈核/壳复合磨粒、铁尖晶石五种磨粒混合,形成硬度梯度,能发挥各自的优点,使得切割效率高,切割面光洁度好,工件不烧伤;
2、沸石的加入既有利于增加结合强度,又便于排屑;
3、碳化硅微粉和石墨的加入有利于导热,使得磨削区温度不至于积累过高烧伤工件。
造孔剂选用经高温煅烧过的硅藻土颗粒,由于其具有多孔性和不可压缩性,其孔隙率可达90%,密度小,经表面封孔,使得硅藻土在砂轮中结合强度高,磨削时保持了高孔隙率,有利于排削和散热,降低磨削区温度。
具体实施方式
实施例1
混合磨粒质量百分比:黑碳化硅5%、单晶刚玉20%、棕刚玉45%、棕刚玉-氧化铈核/壳复合磨粒20%、铁尖晶石10%。
本实施例中的不锈钢切割砂轮是按温热压制成型工艺制作,按1把组分A混合磨料和B树脂液充分混合,2再与组分C填料沸石和组分D碳化硅微粉充分混合,3再与E造孔剂硅藻土充分混合,4再与组分F树脂粉充分混合,过筛,过筛后放置于恒温恒湿车间放置72h,过筛即为磨削层成型料。
将棕刚玉、石榴石、尖晶石和树脂液混匀,加入石膏混匀,加入树脂粉混匀,过筛,即为非磨削层成型料。
将成型料分别投入到已加热至85℃的模具中;中间加入玻璃纤维网(已浸润一层含有石墨的腰果酚改性的酚醛树脂),温热成型。采用梯度固化工艺固化,最高固化温度为185℃。不锈钢切割砂轮各原料组分重量比例为:混合磨粒24:15.98; 混合磨粒30:35.96;混合磨粒36:11.99 ;混合磨粒46:14.86;沸石:3.81;造孔剂:1.12;碳化硅微粉0.5µm:2.56;树脂液:4.73;树脂粉:8.99。
实施例2
本实施例中的不锈钢切割砂轮是按温热压制成型工艺制作,按1把组分A混合磨粒及棕刚玉磨粒和B树脂液充分混合,2再与组分C填料沸石和组分D碳化硅微粉充分混合,3再与E造孔剂硅藻土充分混合,4再与组分F树脂粉充分混合,过筛,过筛后放置于恒温恒湿车间放置96h,过筛即为磨削层成型料。
将棕刚玉、石榴石、尖晶石和树脂液混匀,加入石膏混匀,加入树脂粉混匀,过筛,即为非磨削层成型料。
将成型料投入到已加热至85℃的模具中;中间加入玻璃纤维网(已浸润一层含有石墨的腰果酚改性的酚醛树脂),温热成型。采用梯度固化工艺固化,最高固化温度为185℃。不锈钢切割砂轮各原料组分重量比例为:混合磨粒24:15.98; 棕刚玉磨粒30:40.96;混合磨粒36:11.99 ;混合磨粒46:13.71;沸石:1.66;造孔剂:1.12;碳化硅微粉0.5µm:0.36;树脂液:4.73;树脂粉:9.49。
实施例3
本实施例中的不锈钢切割砂轮是按温热压制成型工艺制作,按1把组分A混合磨料及棕刚玉磨粒和B树脂液充分混合,2再与组分C填料沸石和组分D碳化硅微粉充分混合,3再与E造孔剂硅藻土充分混合,4再与组分F树脂粉充分混合,过筛,过筛后放置于恒温恒湿车间放置120h,过筛即为磨削层成型料。
将棕刚玉、石榴石、尖晶石和树脂液混匀,加入石膏混匀,加入树脂粉混匀,过筛,即为非磨削层成型料。
将成型料投入到已加热至85℃的模具中;中间加入玻璃纤维网(已浸润一层含有石墨的腰果酚改性的酚醛树脂),温热成型。采用梯度固化工艺固化,最高固化温度为185℃。不锈钢切割砂轮各原料组分重量比例为:混合磨粒24:15.98;混合磨粒 30:35.96;棕刚玉磨粒36:11.99 ;混合磨粒46:14.86;沸石:3.81;造孔剂:1.12;碳化硅微粉0.5µm:2.56;树脂液:4.73;树脂粉:8.99。
本发明和现市面质量较好品牌切割砂轮的切割实验比较

Claims (6)

1.一种不锈钢切割砂轮,其特征在于,该切割砂轮原料包括混合磨粒、填料、造孔剂、树脂、增强材料组成;所述混合磨粒为黑碳化硅、单晶刚玉、棕刚玉、棕刚玉-氧化铈核/壳复合磨粒、铁尖晶石,所述填料为沸石、碳化硅微粉,树脂为腰果酚改性的酚醛树脂,增强材料为含有石墨的玻璃纤维网;所述腰果酚改性的酚醛树脂是经硫酸钙晶须原位聚合而成;各原料的重量百分比为:混合磨粒75%~85%,填料3%~7%,造孔剂1%~3%,树脂10%~15%。
2.根据权利要求1所述的不锈钢切割砂轮,其特征在于:混合磨粒中黑碳化硅、单晶刚玉、棕刚玉、棕刚玉-氧化铈核/壳复合磨粒、铁尖晶石重量百分比分别为黑碳化硅5%、单晶刚玉20%、棕刚玉45%、棕刚玉-氧化铈核/壳复合磨粒20%、铁尖晶石10%。
3.根据权利要求1所述的不锈钢切割砂轮,其特征在于:混合磨粒的粒度为24# -46# ,含有石墨的玻璃纤维网浸含有经硫酸钙晶须原位聚合而成的腰果酚改性的酚醛树脂。
4.根据权利要求1所述的不锈钢切割砂轮,其特征在于: 造孔剂是由煅烧硅藻土组成的,且硅藻土是经树脂表面封孔而成。
5.根据权利要求1所述的不锈钢切割砂轮,其特征在于:砂轮是由内外两层组成,外层是磨削层,内层是非磨削层。
6.根据权利要求1所述的不锈钢切割砂轮,其特征在于:制备砂轮的成型料混好后经过恒温恒湿(温度25℃,湿度65%),浸润72-100h。
CN201710267926.0A 2017-04-22 2017-04-22 一种不锈钢切割砂轮及其制备方法 Active CN106891271B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710267926.0A CN106891271B (zh) 2017-04-22 2017-04-22 一种不锈钢切割砂轮及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710267926.0A CN106891271B (zh) 2017-04-22 2017-04-22 一种不锈钢切割砂轮及其制备方法

Publications (2)

Publication Number Publication Date
CN106891271A true CN106891271A (zh) 2017-06-27
CN106891271B CN106891271B (zh) 2019-05-07

Family

ID=59196928

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710267926.0A Active CN106891271B (zh) 2017-04-22 2017-04-22 一种不锈钢切割砂轮及其制备方法

Country Status (1)

Country Link
CN (1) CN106891271B (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109176330A (zh) * 2018-07-13 2019-01-11 白鸽磨料磨具有限公司 一种砂轮用添加剂及其制备方法、砂轮及其制备方法
CN110293485A (zh) * 2019-07-24 2019-10-01 盐城市锐金磨料磨具有限公司 一种打磨小麦尾部毛絮专用砂轮
CN111113284A (zh) * 2019-12-14 2020-05-08 江西联洲研磨科技有限公司 一种高散热型刚玉树脂切割砂轮

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101804604A (zh) * 2010-05-24 2010-08-18 高成喜 高性能柔性切割树脂结合剂砂轮及其生产工艺
CN201573124U (zh) * 2009-06-18 2010-09-08 阳泉市中嘉磨料磨具有限公司 不锈钢专用砂轮
CN102463530A (zh) * 2010-11-12 2012-05-23 张耀南 一种超硬钢材切割片的配方及制作方法
CN103567892A (zh) * 2013-11-01 2014-02-12 阳泉市中嘉磨料磨具有限公司 不锈钢专用超薄片砂轮及制备方法
CN103831734A (zh) * 2014-02-11 2014-06-04 当涂县南方红月磨具磨料有限公司 一种含沸石粉的金刚玉砂轮
CN203792190U (zh) * 2014-03-25 2014-08-27 郑德水 树脂增强切割片
CN102343558B (zh) * 2011-10-20 2015-03-18 宁波大华砂轮有限公司 一种树脂切割砂轮及其制备方法
CN104669131A (zh) * 2015-02-16 2015-06-03 江西峰竺新材料科技有限公司 一种硫酸钙晶须增强树脂砂轮及其制备方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201573124U (zh) * 2009-06-18 2010-09-08 阳泉市中嘉磨料磨具有限公司 不锈钢专用砂轮
CN101804604A (zh) * 2010-05-24 2010-08-18 高成喜 高性能柔性切割树脂结合剂砂轮及其生产工艺
CN102463530A (zh) * 2010-11-12 2012-05-23 张耀南 一种超硬钢材切割片的配方及制作方法
CN102343558B (zh) * 2011-10-20 2015-03-18 宁波大华砂轮有限公司 一种树脂切割砂轮及其制备方法
CN103567892A (zh) * 2013-11-01 2014-02-12 阳泉市中嘉磨料磨具有限公司 不锈钢专用超薄片砂轮及制备方法
CN103831734A (zh) * 2014-02-11 2014-06-04 当涂县南方红月磨具磨料有限公司 一种含沸石粉的金刚玉砂轮
CN203792190U (zh) * 2014-03-25 2014-08-27 郑德水 树脂增强切割片
CN104669131A (zh) * 2015-02-16 2015-06-03 江西峰竺新材料科技有限公司 一种硫酸钙晶须增强树脂砂轮及其制备方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
智红梅,蒋清民,陈金身,董德胜,郭钰龙: "氧化铝-氧化铈核/壳复合磨料的性能测定", 《金刚石与磨料磨具工程》 *
牛文龙: "影响树脂薄片砂轮使用性能的因素及切割试验方法", 《金刚石与磨料磨具工程》 *
高翀,朱峰,刘明耀,赵延军: "酚醛树脂改性及在超硬磨具中的应用研究现状", 《金刚石与磨料磨具工程》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109176330A (zh) * 2018-07-13 2019-01-11 白鸽磨料磨具有限公司 一种砂轮用添加剂及其制备方法、砂轮及其制备方法
CN110293485A (zh) * 2019-07-24 2019-10-01 盐城市锐金磨料磨具有限公司 一种打磨小麦尾部毛絮专用砂轮
CN111113284A (zh) * 2019-12-14 2020-05-08 江西联洲研磨科技有限公司 一种高散热型刚玉树脂切割砂轮

Also Published As

Publication number Publication date
CN106891271B (zh) 2019-05-07

Similar Documents

Publication Publication Date Title
CN1076251C (zh) 用水作临时粘合剂压制磨料制品
CN103465179B (zh) 一种树脂粗磨砂轮及其制备方法
CN105538177B (zh) 复合结合剂砂轮及其制造方法
CN104526577B (zh) 一种陶瓷树脂复合结合剂砂轮的制备方法
CN101905446B (zh) 树脂精磨砂轮制作方法
CN108188950A (zh) 超硬磨料陶瓷结块与树脂锆刚玉复合砂轮
CN105563355B (zh) 一种用于工件表面快速打磨的砂轮及其制备方法
CN102343559B (zh) 一种树脂砂轮及其制备方法
SK2202004A3 (en) Porous abrasive tool and method for making the same
CN104149037B (zh) 一种树脂陶瓷结合剂金刚石砂轮
CN102179774A (zh) 一种复合型多用途树脂磨具及其制备方法
CN105773449A (zh) 一种细粒度高厚度陶瓷结合剂砂轮的制造方法
CN105922144A (zh) 超硬材料磨具的造孔剂及其制造方法
CN102814745B (zh) 一种锆刚玉树脂砂轮及其制备方法
CN102554811A (zh) 一种湿法制备砂轮的方法
CN102179775A (zh) 一种硬质合金用树脂磨具及其制备方法
CN108188948A (zh) 一种多层磨粒砂带结构及其制造方法
CN106891271A (zh) 一种不锈钢切割砂轮及其制备方法
CN106553135A (zh) 一种结合剂、制备方法及砂轮
CN104325416B (zh) 一种用于制作尼龙磨块的配方以及采用该配方制作尼龙磨块的方法
CN107685294A (zh) 一种陶瓷结合剂及其制备方法
CN104669128A (zh) 一种无机与有机复合结合剂的超硬磨具及其制备方法
CN109227411B (zh) 一种环保树脂钹型砂轮
CN106607770B (zh) 一种微晶刚玉陶瓷磨片的制备方法
CN103551996A (zh) 一种陶瓷基金刚石磨块及制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20250214

Address after: No. 1-2D, 2nd Floor, Building 1, Sheraton Plaza, Liangyuan District, Shangqiu City, Henan Province, China 476099

Patentee after: Henan Kexing Information Technology Co.,Ltd.

Country or region after: China

Address before: 450001 science and Technology Department of Henan University of technology, No.100 Lianhua street, Zhengzhou high tech Industrial Development Zone, Henan Province

Patentee before: He'nan University of Technology

Country or region before: China

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20250313

Address after: 476300 Wanglou 012, Zhanji Township, Yucheng County, Shangqiu City, Henan Province

Patentee after: Wang Qishuai

Country or region after: China

Address before: No. 1-2D, 2nd Floor, Building 1, Sheraton Plaza, Liangyuan District, Shangqiu City, Henan Province, China 476099

Patentee before: Henan Kexing Information Technology Co.,Ltd.

Country or region before: China

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20250331

Address after: Building 1-6, Henan Jinyi Technology Industrial Park, Minquan County High tech Zone, Shangqiu City, Henan Province 476800

Patentee after: Zhongqi Pipeline Technology (Henan) Co.,Ltd.

Country or region after: China

Address before: 476300 Wanglou 012, Zhanji Township, Yucheng County, Shangqiu City, Henan Province

Patentee before: Wang Qishuai

Country or region before: China

TR01 Transfer of patent right