CN106876872A - Preparation method of Ge-based reconfigurable dipole antenna based on AlAs/Ge/AlAs structure - Google Patents
Preparation method of Ge-based reconfigurable dipole antenna based on AlAs/Ge/AlAs structure Download PDFInfo
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 28
- 239000011241 protective layer Substances 0.000 claims description 27
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 17
- 238000005530 etching Methods 0.000 claims description 17
- 235000012239 silicon dioxide Nutrition 0.000 claims description 16
- 239000000377 silicon dioxide Substances 0.000 claims description 16
- 239000012535 impurity Substances 0.000 claims description 12
- 238000005229 chemical vapour deposition Methods 0.000 claims description 10
- 238000001312 dry etching Methods 0.000 claims description 10
- 238000001039 wet etching Methods 0.000 claims description 9
- 238000005468 ion implantation Methods 0.000 claims description 8
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- 229910052681 coesite Inorganic materials 0.000 claims description 5
- 229910052906 cristobalite Inorganic materials 0.000 claims description 5
- 229910052682 stishovite Inorganic materials 0.000 claims description 5
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- 229910052732 germanium Inorganic materials 0.000 description 2
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- H01Q1/22—Supports; Mounting means by structural association with other equipment or articles
- H01Q1/2283—Supports; Mounting means by structural association with other equipment or articles mounted in or on the surface of a semiconductor substrate as a chip-type antenna or integrated with other components into an IC package
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01Q—ANTENNAS, i.e. RADIO AERIALS
- H01Q1/00—Details of, or arrangements associated with, antennas
- H01Q1/36—Structural form of radiating elements, e.g. cone, spiral, umbrella; Particular materials used therewith
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01Q—ANTENNAS, i.e. RADIO AERIALS
- H01Q1/00—Details of, or arrangements associated with, antennas
- H01Q1/50—Structural association of antennas with earthing switches, lead-in devices or lightning protectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01Q—ANTENNAS, i.e. RADIO AERIALS
- H01Q5/00—Arrangements for simultaneous operation of antennas on two or more different wavebands, e.g. dual-band or multi-band arrangements
- H01Q5/30—Arrangements for providing operation on different wavebands
- H01Q5/307—Individual or coupled radiating elements, each element being fed in an unspecified way
- H01Q5/314—Individual or coupled radiating elements, each element being fed in an unspecified way using frequency dependent circuits or components, e.g. trap circuits or capacitors
- H01Q5/321—Individual or coupled radiating elements, each element being fed in an unspecified way using frequency dependent circuits or components, e.g. trap circuits or capacitors within a radiating element or between connected radiating elements
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
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Abstract
本发明涉及一种基于AlAs/Ge/AlAs结构的Ge基可重构偶极子天线的制备方法,其中,所述可重构偶极子天线包括:GeOI衬底、第一天线臂、第二天线臂、同轴馈线以及直流偏置线;所述制备方法包括:选取GeOI衬底;在所述GeOI衬底上制作AlAs/Ge/AlAs结构的Ge基SPiN二极管;由多个所述AlAs/Ge/AlAs结构的Ge基SPiN二极管依次首尾相连形成SPiN二极管串;由多个所述SPiN二极管串制作所述第一天线臂和第二天线臂;在所述GeOI衬底上制作所述直流偏置线;在所述第一天线臂和第二天线臂上制作同轴馈线以形成所述可重构偶极子天线,本发明制备的可重构偶极子天线,通过金属直流偏置线控制SPiN二极管导通,形成等离子天线臂的长度可调,从而实现天线工作频率的可重构,具有易集成、可隐身、频率可快速跳变的特点。
The invention relates to a method for preparing a Ge-based reconfigurable dipole antenna based on an AlAs/Ge/AlAs structure, wherein the reconfigurable dipole antenna includes: a GeOI substrate, a first antenna arm, a second Antenna arm, coaxial feeder and DC bias line; the preparation method includes: selecting a GeOI substrate; making a Ge-based SPiN diode of AlAs/Ge/AlAs structure on the GeOI substrate; The Ge-based SPiN diodes of the Ge/AlAs structure are connected end-to-end in turn to form an SPiN diode string; the first antenna arm and the second antenna arm are fabricated from a plurality of the SPiN diode strings; the DC bias is fabricated on the GeOI substrate line; make a coaxial feeder on the first antenna arm and the second antenna arm to form the reconfigurable dipole antenna, the reconfigurable dipole antenna prepared by the present invention, through the metal DC bias line Control the conduction of the SPiN diode to form an adjustable length of the plasma antenna arm, so as to realize the reconfigurable antenna operating frequency, which has the characteristics of easy integration, stealth, and fast frequency jump.
Description
技术领域technical field
本发明属于半导体技术领域,具体涉及一种基于AlAs/Ge/AlAs结构的Ge基可重构偶极子天线的制备方法。The invention belongs to the technical field of semiconductors, and in particular relates to a preparation method of a Ge-based reconfigurable dipole antenna based on an AlAs/Ge/AlAs structure.
背景技术Background technique
在天线技术发展迅猛的今天,新一代无线通信系统的发展趋势包括实现高速数据传输,实现多个无线系统之间的互联,实现有限的频谱资源的有效利用,获得对周围环境的自适应能力等。为突破传统天线固定不变的工作性能难以满足多样的系统需求和复杂多变的应用环境,可重构天线的概念得到重视并获得发展。可重构微带天线因其体积小,剖面低等优点成为可重构天线研究的热点。Today, with the rapid development of antenna technology, the development trend of the new generation of wireless communication systems includes the realization of high-speed data transmission, the interconnection of multiple wireless systems, the effective use of limited spectrum resources, and the ability to adapt to the surrounding environment. . The concept of reconfigurable antennas has been paid attention to and developed in order to break through the fact that the fixed performance of traditional antennas is difficult to meet diverse system requirements and complex and changeable application environments. Reconfigurable microstrip antennas have become a hotspot in the research of reconfigurable antennas because of their small size and low profile.
随着无线系统向大容量、多功能、多频段/超宽带方向的发展,不同通信系统相互融合,使得在同一平台上搭载的信息子系统数量增加,天线数量也相应增加,但天线数量的增加对通信系统的电磁兼容性、成本、重量等方面有较大的负面影响。因此,无线通信系统要求天线能根据实际使用环境来改变其电特性,即实现天线特性的“可重构”。可重构天线具有多个天线的功能,减少了系统中天线的数量。其中,可重构微带天线因其体积较小,剖面低等优点受到可重构天线研究领域的关注。With the development of wireless systems in the direction of large-capacity, multi-function, multi-band/ultra-broadband, and the integration of different communication systems, the number of information subsystems carried on the same platform has increased, and the number of antennas has also increased accordingly. However, the increase in the number of antennas It has a relatively large negative impact on the electromagnetic compatibility, cost, weight, etc. of the communication system. Therefore, the wireless communication system requires the antenna to change its electrical characteristics according to the actual use environment, that is, to realize "reconfigurable" antenna characteristics. The reconfigurable antenna has the function of multiple antennas, reducing the number of antennas in the system. Among them, the reconfigurable microstrip antenna has attracted the attention of the reconfigurable antenna research field because of its small size and low profile.
目前的频率可重构微带天线的各部分有互耦影响,频率跳变慢,馈源结构复杂,隐身性能不佳,剖面高,集成加工的难度高等问题亟待解决。The various parts of the current frequency reconfigurable microstrip antenna have mutual coupling effects, slow frequency hopping, complex feed structure, poor stealth performance, high profile, and high difficulty in integrated processing.
发明内容Contents of the invention
为了解决现有技术中存在的上述问题,本发明提供了一种基于AlAs/Ge/AlAs结构的Ge基可重构偶极子天线的制备方法。本发明要解决的技术问题通过以下技术方案实现:In order to solve the above-mentioned problems in the prior art, the present invention provides a method for preparing a Ge-based reconfigurable dipole antenna based on an AlAs/Ge/AlAs structure. The technical problem to be solved in the present invention is realized through the following technical solutions:
本发明的实施例提供了一种基于AlAs/Ge/AlAs结构的Ge基可重构偶极子天线的制备方法,其中,所述可重构偶极子天线包括:GeOI衬底、第一天线臂、第二天线臂、同轴馈线以及直流偏置线;所述制备方法包括:An embodiment of the present invention provides a method for preparing a Ge-based reconfigurable dipole antenna based on an AlAs/Ge/AlAs structure, wherein the reconfigurable dipole antenna includes: a GeOI substrate, a first antenna arm, second antenna arm, coaxial feeder and DC bias line; the preparation method includes:
选取GeOI衬底;Select GeOI substrate;
在所述GeOI衬底上制作AlAs/Ge/AlAs结构的Ge基SPiN二极管;making a Ge-based SPiN diode of AlAs/Ge/AlAs structure on the GeOI substrate;
由多个所述AlAs/Ge/AlAs结构的Ge基SPiN二极管依次首尾相连形成SPiN二极管串;A plurality of Ge-based SPiN diodes of the AlAs/Ge/AlAs structure are sequentially connected end-to-end to form an SPiN diode string;
由多个所述SPiN二极管串制作所述第一天线臂和第二天线臂;fabricating the first antenna arm and the second antenna arm from a plurality of the SPiN diode strings;
在所述GeOI衬底上制作所述直流偏置线;在所述第一天线臂和第二天线臂上制作同轴馈线以形成所述可重构偶极子天线。Fabricating the DC bias line on the GeOI substrate; fabricating a coaxial feeder line on the first antenna arm and the second antenna arm to form the reconfigurable dipole antenna.
在本发明的一个实施例中,在所述GeOI衬底上制作AlAs/Ge/AlAs结构的Ge基SPiN二极管,包括:In one embodiment of the present invention, the Ge-based SPiN diode of AlAs/Ge/AlAs structure is made on described GeOI substrate, comprises:
(a)选取GeOI衬底,并在所述GeOI衬底内设置隔离区;(a) selecting a GeOI substrate, and setting an isolation region in the GeOI substrate;
(b)刻蚀所述GeOI衬底形成P型沟槽和N型沟槽;(b) etching the GeOI substrate to form a P-type trench and an N-type trench;
(c)氧化所述P型沟槽和所述N型沟槽以使所述P型沟槽和所述N型沟槽的内壁形成氧化层;(c) oxidizing the P-type trench and the N-type trench to form an oxide layer on the inner walls of the P-type trench and the N-type trench;
(d)利用湿法刻蚀工艺刻蚀所述P型沟槽和所述N型沟槽内壁的氧化层以完成所述P型沟槽和所述N型沟槽内壁的平整化;(d) etching the oxide layer on the inner wall of the P-type trench and the N-type trench by a wet etching process to complete the planarization of the inner wall of the P-type trench and the N-type trench;
(e)在所述P型沟槽和所述N型沟槽内淀积AlAs材料,并对所述P型沟槽和所述N型沟槽内的AlAs材料进行离子注入形成P型有源区和N型有源区;(e) Deposit AlAs material in the P-type trench and the N-type trench, and carry out ion implantation to the AlAs material in the P-type trench and the N-type trench to form a P-type active area and N-type active area;
(f)在整个衬底表面生成SiO2材料;利用退火工艺激活所述P型有源区及所述N型有源区中的杂质;(f) generating SiO2 material on the entire substrate surface; using an annealing process to activate impurities in the P-type active region and the N-type active region;
(g)在所述P型有源区和所述N型有源区表面形成引线,以完成所述AlAs/Ge/AlAs结构的基等离子pin二极管的制备。(g) forming leads on the surface of the P-type active region and the N-type active region to complete the preparation of the AlAs/Ge/AlAs-based plasma pin diode.
其中,步骤(a)包括:Wherein, step (a) comprises:
(a1)在所述GeOI衬底表面形成第一保护层;(a1) forming a first protective layer on the surface of the GeOI substrate;
(a2)利用光刻工艺在所述第一保护层上形成第一隔离区图形;(a2) forming a first isolation region pattern on the first protective layer by using a photolithography process;
(a3)利用干法刻蚀工艺,在所述第一隔离区图形的指定位置处刻蚀所述第一保护层及所述GeOI衬底以形成隔离槽,且所述隔离槽的深度大于等于所述GeOI衬底的顶层Ge的厚度;(a3) using a dry etching process, etching the first protective layer and the GeOI substrate at a designated position of the first isolation region pattern to form isolation grooves, and the depth of the isolation grooves is greater than or equal to The thickness of the top layer Ge of the GeOI substrate;
(a4)填充所述隔离槽以形成所述隔离区。(a4) Filling the isolation trench to form the isolation region.
在上述实施例的基础上,步骤(b)包括:On the basis of above-mentioned embodiment, step (b) comprises:
(b1)在所述GeOI衬底表面形成第二保护层;(b1) forming a second protective layer on the surface of the GeOI substrate;
(b2)利用光刻工艺在所述第二保护层上形成第二隔离区图形;(b2) forming a second isolation region pattern on the second protective layer by using a photolithography process;
(b3)利用干法刻蚀工艺在所述第二隔离区图形的指定位置处刻蚀所述第二保护层及所述GeOI衬底的顶层Ge层以在所述顶层Ge层内形成所述P型沟槽和所述N型沟槽。(b3) etching the second protective layer and the top layer Ge layer of the GeOI substrate at the designated position of the second isolation region pattern by a dry etching process to form the top layer Ge layer in the top layer Ge layer. P-type trenches and the N-type trenches.
其中,步骤(e)包括:Wherein, step (e) comprises:
(e1)利用MOCVD工艺,在所述P型沟槽和所述N型沟槽内及整个衬底表面淀积AlAs材料;(e1) Depositing an AlAs material in the P-type trench and the N-type trench and on the entire substrate surface by using an MOCVD process;
(e2)利用CMP工艺,平整化处理GeOI衬底后,在GeOI衬底上形成AlAs层;(e2) using a CMP process to planarize the GeOI substrate, and then forming an AlAs layer on the GeOI substrate;
(e3)光刻AlAs层,并采用带胶离子注入的方法对所述P型沟槽和所述N型沟槽所在位置分别注入P型杂质和N型杂质以形成所述P型有源区和所述N型有源区且同时形成P型接触区和N型接触区;(e3) photoetching the AlAs layer, and implanting P-type impurities and N-type impurities into the positions of the P-type trench and the N-type trench by using glued ion implantation to form the P-type active region forming a P-type contact region and an N-type contact region simultaneously with the N-type active region;
(e4)去除光刻胶;(e4) removing photoresist;
(e5)利用湿法刻蚀去除P型接触区和N型接触区以外的AlAs材料。(e5) Using wet etching to remove the AlAs material other than the P-type contact region and the N-type contact region.
其中,步骤(g)包括:Wherein, step (g) comprises:
(g1)利用各向异性刻蚀工艺刻蚀掉所述P型接触区和所述N型接触区表面指定位置的SiO2材料以形成所述引线孔;(g1) using an anisotropic etching process to etch away the SiO2 material at the specified position on the surface of the P-type contact region and the N-type contact region to form the lead hole;
(g2)向所述引线孔内淀积金属材料,对整个衬底材料进行钝化处理并光刻PAD以形成所述AlAs/Ge/AlAs结构的Ge基SPiN二极管。(g2) Depositing metal material into the lead hole, passivating the entire substrate material and photoetching the PAD to form the Ge-based SPiN diode with the AlAs/Ge/AlAs structure.
在本发明的一个实施例中,所述直流偏置线包括第一直流偏置线(5)、第二直流偏置线(6)、第三直流偏置线(7)、第四直流偏置线(8)、第五直流偏置线(9)、第六直流偏置线(10)、第七直流偏置线(11)、第八直流偏置线(12),所述直流偏置线采用化学气相淀积的方法固定于所述GeOI衬底(1)上。In one embodiment of the present invention, the DC bias line includes a first DC bias line (5), a second DC bias line (6), a third DC bias line (7), a fourth DC bias line The bias line (8), the fifth DC bias line (9), the sixth DC bias line (10), the seventh DC bias line (11), the eighth DC bias line (12), the DC The bias line is fixed on the GeOI substrate (1) by chemical vapor deposition.
在本发明的一个实施例中,其特征在于,In one embodiment of the present invention, it is characterized in that,
所述第一天线臂(2)和所述第二天线臂(3)分别设置于所述同轴馈线(4)的两侧,第一天线臂(2)包括依次串接的第一SPiN二极管串(w1)、第二SPiN二极管串(w2)及第三SPiN二极管串(w3),所述第二天线臂(3)包括依次串接的第四SPiN二极管串(w4)、第五SPiN二极管串(w5)及第六SPiN二极管串(w6);The first antenna arm (2) and the second antenna arm (3) are respectively arranged on both sides of the coaxial feeder (4), and the first antenna arm (2) includes first SPiN diodes connected in series string (w1), a second SPiN diode string (w2) and a third SPiN diode string (w3), and the second antenna arm (3) includes a fourth SPiN diode string (w4) and a fifth SPiN diode string connected in series in sequence a string (w5) and a sixth SPiN diode string (w6);
其中,所述第一SPiN二极管串(w1)的长度等于所述第六SPiN二极管串(w6)的长度,所述第二SPiN二极管串(w2)的长度等于所述第五SPiN二极管串(w5)的长度,所述第三SPiN二极管串(w3)的长度等于所述第四SPiN二极管串(w4)的长度;所述第一天线臂(2)和所述第二天线臂(3)的长度为其 接收或发送的电磁波波长的四分之一。Wherein, the length of the first SPiN diode string (w1) is equal to the length of the sixth SPiN diode string (w6), and the length of the second SPiN diode string (w2) is equal to the fifth SPiN diode string (w5 ), the length of the third SPiN diode string (w3) is equal to the length of the fourth SPiN diode string (w4); the first antenna arm (2) and the second antenna arm (3) The length is a quarter of the wavelength of the electromagnetic wave it receives or transmits.
在本发明的一个实施例中,所述SPiN二极管串中的SPiN二极管包括P+区(27)、N+区(26)和本征区(22),且还包括第一金属接触区(23)和第二金属接触区(24);其中,In one embodiment of the present invention, the SPiN diode in the SPiN diode string includes a P+ region (27), an N+ region (26) and an intrinsic region (22), and also includes a first metal contact region (23) and The second metal contact area (24); wherein,
所述第一金属接触区(23)分别电连接所述P+区(27)与所述直流偏置电压的正极,所述第二金属接触区(24)分别电连接所述N+区(26)与所述直流偏置电压的负极,以使对应SPiN二极管串被施加直流偏置电压后其所有SPiN二极管处于正向导通状态。The first metal contact area (23) is electrically connected to the P+ area (27) and the anode of the DC bias voltage respectively, and the second metal contact area (24) is electrically connected to the N+ area (26) respectively. and the negative electrode of the DC bias voltage, so that all the SPiN diodes of the corresponding SPiN diode string are in a forward conduction state after the DC bias voltage is applied.
在本发明的一个实施例中,所述同轴馈线(4)的内芯线焊接于所述第一天线臂(2)的金属片,所述第一天线臂(2)的金属片与直流偏置线(5)相连;所述同轴馈线(4)的屏蔽层焊接于所述第二天线臂(3)的金属片,所述第二天线臂(3)的金属片与第二直流偏置线(6)相连;所述第一直流偏置线(5)、第二直流偏置线(6)均与直流偏置电压的负极相连,以形成公共负极;In one embodiment of the present invention, the inner core wire of the coaxial feeder (4) is welded to the metal sheet of the first antenna arm (2), and the metal sheet of the first antenna arm (2) is connected to the DC The bias line (5) is connected; the shielding layer of the coaxial feeder (4) is welded to the metal sheet of the second antenna arm (3), and the metal sheet of the second antenna arm (3) is connected to the second DC The bias line (6) is connected; the first DC bias line (5) and the second DC bias line (6) are both connected to the negative pole of the DC bias voltage to form a common negative pole;
由第三直流偏置线(7)和第八直流偏置线(12)形成第一直流偏置线组(7、12),由第四直流偏置线(8)和第七直流偏置线(11)形成第二直流偏置线组(8、11),由第五直流偏置线(9)和第六直流偏置线(10)形成第三直流偏置线组(9、10),在天线工作中仅选择所述第一直流偏置线组(7、12)、所述第二直流偏置线组(8、11)及所述第三直流偏置线组(9、10)中的一组与所述直流偏置电压的正极相连,以使不同长度的所述二极管串处于导通状态,所述二极管在本征区(22)产生具有类金属特性的固态等离子体以用于天线的辐射结构,以形成不同长度的天线臂进而实现天线工作频率的可重构。The first DC bias line group (7, 12) is formed by the third DC bias line (7) and the eighth DC bias line (12), and the fourth DC bias line (8) and the seventh DC bias line The line (11) forms the second DC bias line group (8, 11), and the fifth DC bias line (9) and the sixth DC bias line (10) form the third DC bias line group (9, 10), select only the first DC bias line group (7, 12), the second DC bias line group (8, 11) and the third DC bias line group ( 9, 10), one group is connected with the anode of the DC bias voltage, so that the diode strings of different lengths are in a conduction state, and the diodes produce a solid state with metal-like properties in the intrinsic region (22). Plasma is used in the radiation structure of the antenna to form antenna arms of different lengths to achieve reconfigurable antenna operating frequency.
与现有技术相比,本发明的有益效果:Compared with prior art, the beneficial effect of the present invention:
本发明制备的AlAs/Ge/AlAs结构的Ge基可重构偶极子天线,体积小、 剖面低,结构简单、易于加工、无复杂馈源结构、频率可快速跳变,且天线关闭时将处于电磁波隐身状态,可用于各种跳频电台或设备;由于其所有组成部分均在半导体基片一侧,为平面结构,易于组阵,可用作相控阵天线的基本组成单元。The Ge-based reconfigurable dipole antenna of the AlAs/Ge/AlAs structure prepared by the present invention has small volume, low profile, simple structure, easy processing, no complicated feed source structure, rapid frequency jump, and the antenna will be turned off when the antenna is closed. In the state of electromagnetic wave stealth, it can be used in various frequency hopping stations or equipment; because all its components are on the side of the semiconductor substrate, it is a planar structure, easy to form an array, and can be used as the basic component of a phased array antenna.
附图说明Description of drawings
图1为本发明实施例提供的一种AlAs/Ge/AlAs结构的Ge基可重构偶极子天线的结构示意图;FIG. 1 is a schematic structural diagram of a Ge-based reconfigurable dipole antenna with an AlAs/Ge/AlAs structure provided by an embodiment of the present invention;
图2为本发明实施例提供的一种AlAs/Ge/AlAs结构的Ge基可重构偶极子天线的制备方法示意图;2 is a schematic diagram of a method for preparing a Ge-based reconfigurable dipole antenna with an AlAs/Ge/AlAs structure provided by an embodiment of the present invention;
图3为本发明实施例提供的一种SPiN二极管的制备方法示意图;Fig. 3 is the schematic diagram of the preparation method of a kind of SPiN diode provided by the embodiment of the present invention;
图4a-图4r为本发明实施例的一种AlAs/Ge/AlAs结构的Ge基SPiN二极管的制备方法示意图;4a-4r are schematic diagrams of a method for preparing a Ge-based SPiN diode with an AlAs/Ge/AlAs structure according to an embodiment of the present invention;
图5为本发明实施例提供的一种AlAs/Ge/AlAs结构的Ge基SPiN二极管结构示意图;FIG. 5 is a schematic structural diagram of a Ge-based SPiN diode with an AlAs/Ge/AlAs structure provided by an embodiment of the present invention;
图6为本发明实施例提供的一种AlAs/Ge/AlAs结构的Ge基SPiN二极管串的结构示意图。FIG. 6 is a schematic structural diagram of a Ge-based SPiN diode string with an AlAs/Ge/AlAs structure provided by an embodiment of the present invention.
具体实施方式detailed description
下面结合具体实施例对本发明做进一步详细的描述,但本发明的实施方式不限于此。The present invention will be described in further detail below in conjunction with specific examples, but the embodiments of the present invention are not limited thereto.
实施例一Embodiment one
请参见图1,图1为本发明实施例提供的一种基于AlAs/Ge/AlAs结构的Ge基可重构偶极子天线结构示意图,其中,所述可重构偶极子天线包括:GeOI衬底、第一天线臂、第二天线臂、同轴馈线以及直流偏置线;请参见 图2,图2为所述基于AlAs/Ge/AlAs结构的Ge基可重构偶极子天线制备方法流程图:Please refer to Fig. 1. Fig. 1 is a structural diagram of a Ge-based reconfigurable dipole antenna based on an AlAs/Ge/AlAs structure provided by an embodiment of the present invention, wherein the reconfigurable dipole antenna includes: GeOI Substrate, first antenna arm, second antenna arm, coaxial feeder and DC bias line; please refer to Figure 2, Figure 2 is the preparation of the Ge-based reconfigurable dipole antenna based on the AlAs/Ge/AlAs structure Method flow chart:
选取GeOI衬底;Select GeOI substrate;
在所述GeOI衬底上制作AlAs/Ge/AlAs结构的Ge基SPiN二极管;making a Ge-based SPiN diode of AlAs/Ge/AlAs structure on the GeOI substrate;
由多个所述AlAs/Ge/AlAs结构的Ge基SPiN二极管依次首尾相连形成SPiN二极管串;A plurality of Ge-based SPiN diodes of the AlAs/Ge/AlAs structure are sequentially connected end-to-end to form an SPiN diode string;
由多个所述SPiN二极管串制作所述第一天线臂和第二天线臂;fabricating the first antenna arm and the second antenna arm from a plurality of the SPiN diode strings;
在所述GeOI衬底上制作所述直流偏置线;在所述第一天线臂和第二天线臂上制作同轴馈线以形成所述可重构偶极子天线。Fabricating the DC bias line on the GeOI substrate; fabricating a coaxial feeder line on the first antenna arm and the second antenna arm to form the reconfigurable dipole antenna.
请参见图3,图3为所述GeOI衬底上制作AlAs/Ge/AlAs结构的Ge基SPiN二极管制备方法流程图:包括:Please refer to Fig. 3, Fig. 3 is the flow chart of the Ge-based SPiN diode preparation method of making AlAs/Ge/AlAs structure on the GeOI substrate: including:
(a)选取GeOI衬底,并在所述GeOI衬底内设置隔离区;(a) selecting a GeOI substrate, and setting an isolation region in the GeOI substrate;
(b)刻蚀所述GeOI衬底形成P型沟槽和N型沟槽;(b) etching the GeOI substrate to form a P-type trench and an N-type trench;
(c)氧化所述P型沟槽和所述N型沟槽以使所述P型沟槽和所述N型沟槽的内壁形成氧化层;(c) oxidizing the P-type trench and the N-type trench to form an oxide layer on the inner walls of the P-type trench and the N-type trench;
(d)利用湿法刻蚀工艺刻蚀所述P型沟槽和所述N型沟槽内壁的氧化层以完成所述P型沟槽和所述N型沟槽内壁的平整化;(d) etching the oxide layer on the inner wall of the P-type trench and the N-type trench by a wet etching process to complete the planarization of the inner wall of the P-type trench and the N-type trench;
(e)在所述P型沟槽和所述N型沟槽内淀积AlAs材料,并对所述P型沟槽和所述N型沟槽内的AlAs材料进行离子注入形成P型有源区和N型有源区;(e) Deposit AlAs material in the P-type trench and the N-type trench, and carry out ion implantation to the AlAs material in the P-type trench and the N-type trench to form a P-type active area and N-type active area;
(f)在整个衬底表面生成SiO2材料;利用退火工艺激活所述P型有源区及所述N型有源区中的杂质;(f) generating SiO2 material on the entire substrate surface; using an annealing process to activate impurities in the P-type active region and the N-type active region;
(g)在所述P型有源区和所述N型有源区表面形成引线,以完成所述AlAs/Ge/AlAs结构的基等离子pin二极管的制备。(g) forming leads on the surface of the P-type active region and the N-type active region to complete the preparation of the AlAs/Ge/AlAs-based plasma pin diode.
其中,对于步骤(a),采用GeOI衬底的原因在于,对于固态等离子天线由于其需要良好的微波特性,而固态等离子pin二极管为了满足这个需求,需要具备良好的隔离特性和载流子即固态等离子体的限定能力,而GeOI衬底由于其具有能够与隔离槽方便的形成pin隔离区域、二氧化硅(SiO2)也能够将载流子即固态等离子体限定在顶层Ge中,所以优选采用GeOI作为固态等离子pin二极管的衬底。并且,由于锗材料的载流子迁移率比较大,故可在I区内形成较高的等离子体浓度,提高器件的性能。Among them, for step (a), the reason for using the GeOI substrate is that the solid-state plasma antenna needs good microwave characteristics, and the solid-state plasma pin diode needs to have good isolation characteristics and carriers that are solid state in order to meet this requirement. Plasma confinement ability, and GeOI substrate is preferably used because it has a pin isolation region that can be easily formed with the isolation groove, and silicon dioxide (SiO 2 ) can also confine carriers, that is, solid-state plasma, in the top layer Ge. GeOI is used as a substrate for solid-state plasmonic pin diodes. Moreover, since the carrier mobility of the germanium material is relatively large, a relatively high plasma concentration can be formed in the I region, thereby improving the performance of the device.
在本发明的一个实施例中,步骤(a)包括:In one embodiment of the invention, step (a) includes:
(a1)在所述GeOI衬底表面形成第一保护层;(a1) forming a first protective layer on the surface of the GeOI substrate;
(a2)利用光刻工艺在所述第一保护层上形成第一隔离区图形;(a2) forming a first isolation region pattern on the first protective layer by using a photolithography process;
(a3)利用干法刻蚀工艺,在所述第一隔离区图形的指定位置处刻蚀所述第一保护层及所述GeOI衬底以形成隔离槽,且所述隔离槽的深度大于等于所述GeOI衬底的顶层Ge的厚度;(a3) using a dry etching process, etching the first protective layer and the GeOI substrate at a designated position of the first isolation region pattern to form isolation grooves, and the depth of the isolation grooves is greater than or equal to The thickness of the top layer Ge of the GeOI substrate;
(a4)填充所述隔离槽以形成所述隔离区。(a4) Filling the isolation trench to form the isolation region.
具体地,第一保护层包括第一二氧化硅(SiO2)层和第一氮化硅(SiN)层;则第一保护层的形成包括:在GeOI衬底表面生成二氧化硅(SiO2)以形成第一二氧化硅(SiO2)层;在第一二氧化硅(SiO2)层表面生成氮化硅(SiN)以形成第一氮化硅(SiN)层。这样做的好处在于,利用二氧化硅(SiO2)的疏松特性,将氮化硅(SiN)的应力隔离,使其不能传导进顶层Ge,保证了顶层Ge性能的稳定;基于氮化硅(SiN)与Ge在干法刻蚀时的高选择比,利用氮化硅(SiN)作为干法刻蚀的掩蔽膜,易于工艺实现。当然,可以理解的是,保护层的层数以及保护层的材料此处不做限制,只要能够形成保护层即可。Specifically, the first protective layer includes a first silicon dioxide (SiO 2 ) layer and a first silicon nitride (SiN) layer; then the formation of the first protective layer includes: generating silicon dioxide (SiO 2 ) to form a first silicon dioxide (SiO 2 ) layer; generating silicon nitride (SiN) on the surface of the first silicon dioxide (SiO 2 ) layer to form a first silicon nitride (SiN) layer. The advantage of doing this is that the stress of silicon nitride (SiN) is isolated by using the loose characteristics of silicon dioxide (SiO 2 ), so that it cannot be conducted into the top layer Ge, which ensures the stability of the performance of the top layer Ge; based on silicon nitride (SiN) SiN) and Ge have a high selectivity ratio during dry etching, and silicon nitride (SiN) is used as a masking film for dry etching, which is easy to process. Of course, it can be understood that the number of layers of the protective layer and the material of the protective layer are not limited here, as long as the protective layer can be formed.
其中,隔离槽的深度大于等于顶层Ge的厚度,保证了后续槽中二氧化硅(SiO2)与GeOI衬底的氧化层的连接,形成完整的绝缘隔离。Wherein, the depth of the isolation groove is greater than or equal to the thickness of the top Ge layer, which ensures the connection of silicon dioxide (SiO 2 ) and the oxide layer of the GeOI substrate in the subsequent groove, forming a complete insulation isolation.
在本发明的一个实施例中,步骤(b)包括:In one embodiment of the invention, step (b) includes:
(b1)在所述GeOI衬底表面形成第二保护层;(b1) forming a second protective layer on the surface of the GeOI substrate;
(b2)利用光刻工艺在所述第二保护层上形成第二隔离区图形;(b2) forming a second isolation region pattern on the second protective layer by using a photolithography process;
(b3)利用干法刻蚀工艺在所述第二隔离区图形的指定位置处刻蚀所述第二保护层及所述GeOI衬底的顶层Ge层以在所述顶层Ge层内形成所述P型沟槽和所述N型沟槽。(b3) etching the second protective layer and the top layer Ge layer of the GeOI substrate at the designated position of the second isolation region pattern by a dry etching process to form the top layer Ge layer in the top layer Ge layer. P-type trenches and the N-type trenches.
具体地,第二保护层包括第二二氧化硅(SiO2)层和第二氮化硅(SiN)层;则第二保护层的形成包括:在GeOI衬底表面生成二氧化硅(SiO2)以形成第二二氧化硅(SiO2)层;在第二二氧化硅(SiO2)层表面生成氮化硅(SiN)以形成第二氮化硅(SiN)层。这样做的好处类似于第一保护层的作用,此处不再赘述。Specifically, the second protective layer includes a second silicon dioxide (SiO 2 ) layer and a second silicon nitride (SiN) layer; then the formation of the second protective layer includes: generating silicon dioxide (SiO 2 ) to form a second silicon dioxide (SiO 2 ) layer; generating silicon nitride (SiN) on the surface of the second silicon dioxide (SiO 2 ) layer to form a second silicon nitride (SiN) layer. The benefits of doing this are similar to the role of the first protective layer, so I won't repeat them here.
其中,P型沟槽和N型沟槽的深度大于第二保护层厚度且小于第二保护层与GeOI衬底顶层Ge厚度之和。优选地,该P型沟槽和N型沟槽的底部距GeOI衬底的顶层Ge底部的距离为0.5微米~30微米,形成一般认为的深槽,这样在形成P型和N型有源区时可以形成杂质分布均匀、且高掺杂浓度的P、N区和和陡峭的Pi与Ni结,以利于提高i区等离子体浓度。Wherein, the depths of the P-type trench and the N-type trench are greater than the thickness of the second protection layer and less than the sum of the thickness of the second protection layer and the top Ge layer of the GeOI substrate. Preferably, the distance between the bottom of the P-type trench and the bottom of the N-type trench is 0.5 micron to 30 micron from the bottom of the top layer Ge of the GeOI substrate, forming a generally considered deep trench, so that when forming the P-type and N-type active regions When the impurity distribution is uniform, the P and N regions with high doping concentration and the steep Pi-Ni junction can be formed to facilitate the increase of the plasma concentration in the i region.
在本发明的一个实施例中,步骤(e)包括:In one embodiment of the invention, step (e) includes:
(e1)利用MOCVD工艺,在所述P型沟槽和所述N型沟槽内及整个衬底表面淀积AlAs材料;(e1) Depositing an AlAs material in the P-type trench and the N-type trench and on the entire substrate surface by using an MOCVD process;
(e2)利用CMP工艺,平整化处理GeOI衬底后,在GeOI衬底上形成AlAs层;(e2) using a CMP process to planarize the GeOI substrate, and then forming an AlAs layer on the GeOI substrate;
(e3)光刻AlAs层,并采用带胶离子注入的方法对所述P型沟槽和所述N型沟槽所在位置分别注入P型杂质和N型杂质以形成所述P型有源区和所述N型有源区且同时形成P型接触区和N型接触区;(e3) photoetching the AlAs layer, and implanting P-type impurities and N-type impurities into the positions of the P-type trench and the N-type trench by using glued ion implantation to form the P-type active region forming a P-type contact region and an N-type contact region simultaneously with the N-type active region;
(e4)去除光刻胶;(e4) removing photoresist;
(e5)利用湿法刻蚀去除P型接触区和N型接触区以外的AlAs材料。(e5) Using wet etching to remove the AlAs material other than the P-type contact region and the N-type contact region.
在本发明的一个实施例中,步骤(g)包括:In one embodiment of the invention, step (g) comprises:
(g1)利用各向异性刻蚀工艺刻蚀掉所述P型接触区和所述N型接触区表面指定位置的SiO2材料以形成所述引线孔;(g1) using an anisotropic etching process to etch away the SiO2 material at the specified position on the surface of the P-type contact region and the N-type contact region to form the lead hole;
(g2)向所述引线孔内淀积金属材料,对整个衬底材料进行钝化处理并光刻PAD以形成所述AlAs/Ge/AlAs结构的Ge基SPiN二极管。(g2) Depositing metal material into the lead hole, passivating the entire substrate material and photoetching the PAD to form the Ge-based SPiN diode with the AlAs/Ge/AlAs structure.
在本发明的一个实施例中,所述直流偏置线包括第一直流偏置线(5)、第二直流偏置线(6)、第三直流偏置线(7)、第四直流偏置线(8)、第五直流偏置线(9)、第六直流偏置线(10)、第七直流偏置线(11)、第八直流偏置线(12),所述直流偏置线采用化学气相淀积的方法固定于所述GeOI衬底(1)上。In one embodiment of the present invention, the DC bias line includes a first DC bias line (5), a second DC bias line (6), a third DC bias line (7), a fourth DC bias line The bias line (8), the fifth DC bias line (9), the sixth DC bias line (10), the seventh DC bias line (11), the eighth DC bias line (12), the DC The bias line is fixed on the GeOI substrate (1) by chemical vapor deposition.
在本发明的一个实施例中,所述第一天线臂(2)和所述第二天线臂(3)分别设置于所述同轴馈线(4)的两侧,第一天线臂(2)包括依次串接的第一SPiN二极管串(w1)、第二SPiN二极管串(w2)及第三SPiN二极管串(w3),所述第二天线臂(3)包括依次串接的第四SPiN二极管串(w4)、第五SPiN二极管串(w5)及第六SPiN二极管串(w6);In one embodiment of the present invention, the first antenna arm (2) and the second antenna arm (3) are respectively arranged on both sides of the coaxial feeder (4), and the first antenna arm (2) It includes a first SPiN diode string (w1), a second SPiN diode string (w2) and a third SPiN diode string (w3) connected in series, and the second antenna arm (3) includes a fourth SPiN diode connected in series string (w4), fifth SPiN diode string (w5) and sixth SPiN diode string (w6);
其中,所述第一SPiN二极管串(w1)的长度等于所述第六SPiN二极管串(w6)的长度,所述第二SPiN二极管串(w2)的长度等于所述第五SPiN二极管串(w5)的长度,所述第三SPiN二极管串(w3)的长度等于所述第四SPiN二极管串(w4)的长度;所述第一天线臂(2)和所述第二天线臂(3)的长度为其 接收或发送的电磁波波长的四分之一。Wherein, the length of the first SPiN diode string (w1) is equal to the length of the sixth SPiN diode string (w6), and the length of the second SPiN diode string (w2) is equal to the fifth SPiN diode string (w5 ), the length of the third SPiN diode string (w3) is equal to the length of the fourth SPiN diode string (w4); the first antenna arm (2) and the second antenna arm (3) The length is a quarter of the wavelength of the electromagnetic wave it receives or transmits.
在本发明的一个实施例中,请一并参见图4及图5,图4为本发明提供的SPiN二极管的结构示意图;图5为本发明实施例提供的一种SPiN二极管串的结构示意图。所述SPiN二极管串中的SPiN二极管包括P+区(27)、N+区(26)和本征区(22),且还包括第一金属接触区(23)和第二金属接触区(24);其中,In an embodiment of the present invention, please refer to FIG. 4 and FIG. 5 together. FIG. 4 is a schematic structural diagram of an SPiN diode provided by the present invention; FIG. 5 is a schematic structural diagram of an SPiN diode string provided by an embodiment of the present invention. The SPiN diode in the SPiN diode string includes a P+ region (27), an N+ region (26) and an intrinsic region (22), and also includes a first metal contact region (23) and a second metal contact region (24); in,
所述第一金属接触区(23)分别电连接所述P+区(27)与所述直流偏置电压的正极,所述第二金属接触区(24)分别电连接所述N+区(26)与所述直流偏置电压的负极,以使对应SPiN二极管串被施加直流偏置电压后其所有SPiN二极管处于正向导通状态。The first metal contact area (23) is electrically connected to the P+ area (27) and the anode of the DC bias voltage respectively, and the second metal contact area (24) is electrically connected to the N+ area (26) respectively. and the negative electrode of the DC bias voltage, so that all the SPiN diodes of the corresponding SPiN diode string are in a forward conduction state after the DC bias voltage is applied.
在本发明的一个实施例中,所述同轴馈线(4)的内芯线焊接于所述第一天线臂(2)的金属片,所述第一天线臂(2)的金属片与直流偏置线(5)相连;所述同轴馈线(4)的屏蔽层焊接于所述第二天线臂(3)的金属片,所述第二天线臂(3)的金属片与第二直流偏置线(6)相连;所述第一直流偏置线(5)、第二直流偏置线(6)均与直流偏置电压的负极相连,以形成公共负极;In one embodiment of the present invention, the inner core wire of the coaxial feeder (4) is welded to the metal sheet of the first antenna arm (2), and the metal sheet of the first antenna arm (2) is connected to the DC The bias line (5) is connected; the shielding layer of the coaxial feeder (4) is welded to the metal sheet of the second antenna arm (3), and the metal sheet of the second antenna arm (3) is connected to the second DC The bias line (6) is connected; the first DC bias line (5) and the second DC bias line (6) are both connected to the negative pole of the DC bias voltage to form a common negative pole;
由第三直流偏置线(7)和第八直流偏置线(12)形成第一直流偏置线组(7、12),由第四直流偏置线(8)和第七直流偏置线(11)形成第二直流偏置线组(8、11),由第五直流偏置线(9)和第六直流偏置线(10)形成第三直流偏置线组(9、10),在天线工作中仅选择所述第一直流偏置线组(7、12)、所述第二直流偏置线组(8、11)及所述第三直流偏置线组(9、10)中的一组与所述直流偏置电压的正极相连,以使不同长度的所述二极管串处于导通状态,所述二极管在本征区(22)产生具有类金属特性的固态等离子体以用于天线的辐射结构,以形成不同长度的天线臂进而实现天线工作频率的可重构。The first DC bias line group (7, 12) is formed by the third DC bias line (7) and the eighth DC bias line (12), and the fourth DC bias line (8) and the seventh DC bias line The line (11) forms the second DC bias line group (8, 11), and the fifth DC bias line (9) and the sixth DC bias line (10) form the third DC bias line group (9, 10), select only the first DC bias line group (7, 12), the second DC bias line group (8, 11) and the third DC bias line group ( 9, 10), one group is connected with the anode of the DC bias voltage, so that the diode strings of different lengths are in a conduction state, and the diodes produce a solid state with metal-like properties in the intrinsic region (22). Plasma is used in the radiation structure of the antenna to form antenna arms of different lengths to achieve reconfigurable antenna operating frequency.
本发明提供的基于AlAs/Ge/AlAs结构的Ge基可重构偶极子天线的制备方法具备如下优点:The preparation method of the Ge-based reconfigurable dipole antenna based on the AlAs/Ge/AlAs structure provided by the present invention has the following advantages:
1、体积小、剖面低,结构简单、易于加工。1. Small size, low profile, simple structure and easy processing.
2、采用同轴电缆作为馈源,无复杂馈源结构。2. Coaxial cable is used as the feed source without complicated feed source structure.
3、采用SPiN二极管作为天线的基本组成单元,只需通过控制其导通或断开,即可实现频率的可重构。3. The SPiN diode is used as the basic unit of the antenna, and the reconfigurable frequency can be realized only by controlling its conduction or disconnection.
4、所有组成部分均在半导体基片一侧,易于制版加工。4. All components are on the side of the semiconductor substrate, which is easy for plate making and processing.
实施例二Embodiment two
请参见图4a-图4r,图4a-图4r为本发明实施例的一种AlAs/Ge/AlAs结构的基等离子pin二极管的制备方法示意图,在上述实施例一的基础上,以制备沟道长度为22nm(固态等离子区域长度为100微米)的AlAs/Ge/AlAs结构的基等离子pin二极管为例进行详细说明,具体步骤如下:Please refer to Fig. 4a-Fig. 4r, Fig. 4a-Fig. 4r is a schematic diagram of the preparation method of an AlAs/Ge/AlAs structure-based plasmonic pin diode according to the embodiment of the present invention, on the basis of the above-mentioned embodiment 1, to prepare the channel An AlAs/Ge/AlAs-based plasmonic pin diode with a length of 22nm (the length of the solid-state plasma region is 100 microns) will be described in detail as an example. The specific steps are as follows:
步骤1,衬底材料制备步骤:Step 1, substrate material preparation steps:
(1a)如图4a所示,选取(100)晶向,掺杂类型为p型,掺杂浓度为1014cm-3的GeOI衬底片101,顶层Ge的厚度为50μm;(1a) As shown in Figure 4a, select the (100) crystal orientation, the doping type is p-type, the GeOI substrate sheet 101 with a doping concentration of 10 14 cm -3 , and the thickness of the top layer Ge is 50 μm;
(1b)如图4b所示,采用化学气相沉积(Chemical vapor deposition,简称CVD)的方法,在GeOI衬底上淀积一层40nm厚度的第一SiO2层201;(1b) As shown in FIG. 4b, a first SiO layer 201 with a thickness of 40nm is deposited on the GeOI substrate by chemical vapor deposition (Chemical vapor deposition, CVD for short) ;
(1c)采用化学气相淀积的方法,在衬底上淀积一层2μm厚度的第一Si3N4/SiN层202;(1c) Depositing a first Si 3 N 4 /SiN layer 202 with a thickness of 2 μm on the substrate by chemical vapor deposition;
步骤2,隔离制备步骤:Step 2, isolation preparation steps:
(2a)如图4c所示,通过光刻工艺在上述保护层上形成隔离区,湿法刻蚀隔离区第一Si3N4/SiN层202,形成隔离区图形;采用干法刻蚀,在隔离区形成宽5μm,深为50μm的深隔离槽301;(2a) As shown in FIG. 4c, an isolation region is formed on the protective layer by a photolithography process, and the first Si 3 N 4 /SiN layer 202 in the isolation region is wet-etched to form an isolation region pattern; dry etching is used, forming a deep isolation trench 301 with a width of 5 μm and a depth of 50 μm in the isolation region;
(2b)如图4d所示,采用CVD的方法,淀积SiO2401将该深隔离槽填满;(2b) As shown in FIG. 4d , deposit SiO 2 401 by CVD to fill up the deep isolation trench;
(2c)如图4e所示,采用化学机械抛光(Chemical Mechanical Polishing,简称CMP)方法,去除表面第一Si3N4/SiN层202和第一SiO2层201,使GeOI衬底表面平整;(2c) As shown in FIG. 4e, the first Si 3 N 4 /SiN layer 202 and the first SiO 2 layer 201 on the surface are removed by using a chemical mechanical polishing (CMP) method to make the surface of the GeOI substrate smooth;
步骤3,P、N区深槽制备步骤:Step 3, preparation steps of deep grooves in P and N regions:
(3a)如图4f所示,采用CVD方法,在衬底上连续淀积延二层材料,第一层为300nm厚度的第二SiO2层601,第二层为500nm厚度的第二Si3N4/SiN层602;(3a) As shown in FIG. 4f, adopt CVD method to continuously deposit two layers of materials on the substrate, the first layer is the second SiO 2 layer 601 with a thickness of 300nm, and the second layer is the second SiO with a thickness of 500nm. N4 /SiN layer 602;
(3b)如图4g所示,光刻P、N区深槽,湿法刻蚀P、N区第二Si3N4/SiN层602和第二SiO2层601,形成P、N区图形;采用干法刻蚀,在P、N区形成宽4μm,深5μm的深槽701,P、N区槽的长度根据在所制备的天线中的应用情况而确定;(3b) As shown in Figure 4g, photolithography of deep grooves in the P and N regions, wet etching of the second Si 3 N 4 /SiN layer 602 and the second SiO 2 layer 601 in the P and N regions, to form patterns in the P and N regions ;Use dry etching to form a deep groove 701 with a width of 4 μm and a depth of 5 μm in the P and N regions, and the length of the grooves in the P and N regions is determined according to the application in the prepared antenna;
(3c)如图4h所示,在850℃下,高温处理10分钟,氧化槽内壁形成氧化层801,以使P、N区槽内壁平整;(3c) As shown in Figure 4h, at 850° C., high temperature treatment for 10 minutes, an oxide layer 801 is formed on the inner wall of the oxidation tank, so that the inner wall of the tank in the P and N regions is smooth;
(3d)如图4i所示,利用湿法刻蚀工艺去除P、N区槽内壁的氧化层801。(3d) As shown in FIG. 4i , remove the oxide layer 801 on the inner walls of the trenches in the P and N regions by using a wet etching process.
步骤4,P、N接触区制备步骤:Step 4, P, N contact region preparation steps:
(4a)如图4j所示,利用有机金属化学气相沉积(Metal-organic Chemical VaporDeposition,简称MOCVD)工艺,在P、N区槽中淀积多晶AlAs1001,并将沟槽填满;(4a) As shown in FIG. 4j , using a Metal-organic Chemical Vapor Deposition (MOCVD) process, deposit polycrystalline AlAs1001 in the grooves of the P and N regions, and fill the grooves;
(4b)如图4k所示,采用CMP,去除表面多晶AlAs1001与第二Si3N4/SiN层602,使表面平整;(4b) As shown in FIG. 4k, use CMP to remove the surface polycrystalline AlAs1001 and the second Si 3 N 4 /SiN layer 602 to make the surface smooth;
(4c)如图4l所示,采用CVD的方法,在表面淀积一层多晶AlAs1201,厚度为200~500nm;(4c) As shown in Figure 4l, a layer of polycrystalline AlAs12O1 is deposited on the surface by CVD method, with a thickness of 200-500nm;
(4d)如图4m所示,光刻P区有源区,采用带胶离子注入方法进行P+注入,使P区有源区掺杂浓度达到0.5×1020cm-3,去除光刻胶,形成P接触1301;(4d) As shown in Figure 4m, photoresist the active region of the P region, and perform P + implantation using the ion implantation method with glue, so that the doping concentration of the active region of the P region reaches 0.5×10 20 cm -3 , and remove the photoresist , forming a P-contact 1301;
(4e)光刻N区有源区,采用带胶离子注入方法进行N+注入,使N区有源区掺杂浓度为0.5×1020cm-3,去除光刻胶,形成N接触1302;(4e) Lithographically etching the active region of the N region, performing N + implantation by using the ion implantation method with glue, so that the doping concentration of the active region of the N region is 0.5×10 20 cm -3 , removing the photoresist, and forming the N contact 1302;
(4f)如图4n所示,采用湿法刻蚀,刻蚀掉P、N接触区以外的多晶AlAs1201,形成P、N接触区;(4f) As shown in FIG. 4n, wet etching is used to etch away the polycrystalline AlAs1201 outside the P and N contact regions to form P and N contact regions;
(4g)如图4o所示,采用CVD的方法,在表面淀积SiO21501,厚度为800nm;(4g) As shown in Fig. 4o, adopt CVD method to deposit SiO 2 1501 on the surface with a thickness of 800nm;
(4h)在1000℃,退火1分钟,使离子注入的杂质激活、并且推进AlAs中杂质;(4h) Annealing at 1000°C for 1 minute to activate the ion-implanted impurities and advance the impurities in AlAs;
步骤5,构成PIN二极管步骤:Step 5, forming the PIN diode steps:
(5a)如图4p所示,在P、N接触区光刻引线孔1601;(5a) As shown in FIG. 4p, photolithographic lead holes 1601 are formed in the P and N contact areas;
(5b)如图4q所示,衬底表面溅射金属,在750℃合金形成金属硅化物1701,并刻蚀掉表面的金属;(5b) As shown in Figure 4q, metal is sputtered on the surface of the substrate, a metal silicide 1701 is formed at 750° C., and the metal on the surface is etched away;
(5c)衬底表面溅射金属,光刻引线;(5c) sputtering metal on the surface of the substrate, and photoetching leads;
(5d)如图4r所示,淀积Si3N4/SiN形成钝化层1801,光刻PAD,形成PIN二极管,作为制备固态等离子天线材料。(5d) As shown in FIG. 4r , deposit Si 3 N 4 /SiN to form a passivation layer 1801 , photolithographically PAD, and form a PIN diode as a solid-state plasma antenna material.
本实施例中,上述各种工艺参数均为举例说明,依据本领域技术人员的常规手段所做的变换均为本申请之保护范围。In this embodiment, the above-mentioned various process parameters are all examples, and the transformations made according to the conventional means of those skilled in the art are within the protection scope of the present application.
本发明制备的应用于基于AlAs/Ge/AlAs结构的Ge基可重构偶极子天线,首先,所使用的锗材料,由于其高迁移率和大载流子寿命的特性,提高了pin二极管的固态等离子体浓度;其次,锗材料由于其氧化物GeO热 稳定性差的特性,P区和N区深槽侧壁平整化的处理可在高温环境自动完成,简化了材料的制备方法;再次,本发明制备的应用于固态等离子可重构天线的GeOI基pin二极管采用了一种基于刻蚀的深槽介质隔离工艺,有效地提高了器件的击穿电压,抑制了漏电流对器件性能的影响。The Ge-based reconfigurable dipole antenna based on the AlAs/Ge/AlAs structure prepared by the present invention, first of all, the germanium material used improves the pin diode due to its high mobility and large carrier lifetime characteristics. solid-state plasma concentration; secondly, due to the poor thermal stability of the germanium oxide GeO, the sidewall planarization of the P-region and N-region deep grooves can be automatically completed in a high-temperature environment, which simplifies the preparation method of the material; thirdly, The GeOI-based pin diode applied to the solid-state plasma reconfigurable antenna prepared by the present invention adopts a deep groove dielectric isolation process based on etching, which effectively improves the breakdown voltage of the device and suppresses the influence of leakage current on device performance .
综上所述,本文中应用了具体个例对本发明基于AlAs/Ge/AlAs结构的Ge基可重构偶极子天线的制备方法的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本发明的方法及其核心思想;同时,对于本领域的一般技术人员,依据本发明的思想,在具体实施方式及应用范围上均会有改变之处,综上所述,本说明书内容不应理解为对本发明的限制,本发明的保护范围应以所附的权利要求为准。In summary, this paper uses specific examples to illustrate the principle and implementation of the method for preparing the Ge-based reconfigurable dipole antenna based on the AlAs/Ge/AlAs structure of the present invention. The descriptions of the above examples are only used To help understand the method of the present invention and its core idea; at the same time, for those of ordinary skill in the art, according to the idea of the present invention, there will be changes in the specific implementation and scope of application. In summary, this specification The content should not be construed as limiting the present invention, and the scope of protection of the present invention should be based on the appended claims.
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Application publication date: 20170620 |