CN106867401A - Water paint with high temperature resistant property - Google Patents
Water paint with high temperature resistant property Download PDFInfo
- Publication number
- CN106867401A CN106867401A CN201710251505.9A CN201710251505A CN106867401A CN 106867401 A CN106867401 A CN 106867401A CN 201710251505 A CN201710251505 A CN 201710251505A CN 106867401 A CN106867401 A CN 106867401A
- Authority
- CN
- China
- Prior art keywords
- parts
- high temperature
- coating
- temperature resistant
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 239000003973 paint Substances 0.000 title claims abstract description 34
- -1 phospho Chemical class 0.000 claims abstract description 31
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 30
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 29
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 26
- 239000002253 acid Substances 0.000 claims abstract description 23
- 239000001254 oxidized starch Substances 0.000 claims abstract description 19
- 235000013808 oxidized starch Nutrition 0.000 claims abstract description 19
- 229910021538 borax Inorganic materials 0.000 claims abstract description 17
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 17
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 17
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 17
- 239000011787 zinc oxide Substances 0.000 claims abstract description 15
- 239000004593 Epoxy Substances 0.000 claims abstract description 14
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 13
- 239000003822 epoxy resin Substances 0.000 claims abstract description 13
- 229920002050 silicone resin Polymers 0.000 claims abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004113 Sepiolite Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 11
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 10
- 229920005573 silicon-containing polymer Polymers 0.000 claims abstract description 10
- 239000004576 sand Substances 0.000 claims abstract description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 239000000080 wetting agent Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 42
- 238000000576 coating method Methods 0.000 abstract description 42
- 230000008859 change Effects 0.000 abstract description 6
- 238000007711 solidification Methods 0.000 abstract description 5
- 230000008023 solidification Effects 0.000 abstract description 5
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229940106691 bisphenol a Drugs 0.000 description 10
- 239000004925 Acrylic resin Substances 0.000 description 8
- 229920000178 Acrylic resin Polymers 0.000 description 8
- 229920002472 Starch Polymers 0.000 description 8
- 239000008107 starch Substances 0.000 description 8
- 235000019698 starch Nutrition 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 235000010215 titanium dioxide Nutrition 0.000 description 4
- 238000004500 asepsis Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- 229910018557 Si O Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 238000004042 decolorization Methods 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000001935 peptisation Methods 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- CZCSLHYZEQSUNV-UHFFFAOYSA-N [Na].OB(O)O Chemical compound [Na].OB(O)O CZCSLHYZEQSUNV-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses the water paint with high temperature resistant property, including following components：Water, epoxy modified silicone resin, bisphenol A epoxide resin, aqueous acroleic acid resin, oxidized starch, organic phospho acid, zinc oxide, Boratex, sepiolite, borax, silica sand, dimethyl silicone polymer, calcium carbonate, propandiol butyl ether.Present invention employs a large amount of components with resistance to elevated temperatures, at high temperature, the performance of each component will not change, and coating has good heat resistance, and, the maximum problem that coating faces at high temperature is exactly fast paint solidification, viscosity is low, poor fluidity, and the thickness of the film of formation is big, fragility is high, and the service life of coating is low；Therefore, present invention employs high temperature retarder, the hardening time of coating can be postponed, improve the decentralization of coating, it is to avoid coating at high temperature rapid curing and film forming is uneven.
Description
Technical field
The present invention relates to a kind of coating, and in particular to the water paint with high temperature resistant property.
Background technology
Ancient building has high history science, artistic value, if be destroyed, it is then not possible to exist again；And ancient building
It is of the remote past, inevitably by nature or it is artificial destroy, it would therefore be desirable to be repaired to ancient building and tieed up
Shield.To ancient building room, Men Qiang, inner and outer eaves are bulky, can often use coating in the reparative processes of helping bulky, ground, metope.Due to repairing
Process of copying is numerous and diverse, and the duration is more long, so repair work preferably once completing, this requires that coating has good high temperature resistant
Property, corrosion resistance, caking property, water resistance and mechanical performance, it is to avoid coating color-changing is destroyed.
At present, water paint can be widely applied to the industries such as electrical equipment, metallurgy, oil, aviation field, chemical industry, medicine, food
In various, but the resistance to elevated temperatures of the coating of equipment surface is poor, especially for exposed to outdoor equipment, is exposed to the sun for a long time
With drench with rain, cause coating to drop, damage equipment surface, reduce service life of equipment, increase cost.
The content of the invention
The technical problems to be solved by the invention are that water paint resistance to elevated temperatures is poor, it is therefore intended that providing has high temperature resistance
The water paint of performance, solves the resistant to elevated temperatures problem of water paint.
The present invention is achieved through the following technical solutions：
Water paint with high temperature resistant property, including following components：
Water, epoxy modified silicone resin, bisphenol A epoxide resin, aqueous acroleic acid resin, oxidized starch, organic phospho acid,
Zinc oxide, Boratex, sepiolite, borax, silica sand, dimethyl silicone polymer, calcium carbonate, propandiol butyl ether.
Epoxy modified silicone resin, bisphenol A epoxide resin, aqueous acroleic acid resin are film forming matters, and organosilicon is high poly-
Thing is heat-resist with Si-O keys as main chain；There are the excellent properties of many protrusions after epoxy resin is cured, it is such as special to various materials
It is not very strong to the adhesion of metal, has very strong chemical resistance, mechanical strength are very high, electrical insulating property is good, corrosion-resistant etc..
Additionally, epoxy resin can solidify within the scope of comparatively wide temperature, and volume contraction is small during solidification, bisphenol type epoxy tree
Fat is condensed in the basic conditions by bisphenol-A, epoxychloropropane, through washing, the macromolecular compound that desolventizing is refined；Water
Property acrylic resin include emulsion acrylic resin, aqueous acrylic resin dispersion and acrylic resin aqueous solution, it is and traditional
Solvent based coating is compared, and water paint has that price is low, use safety；Oxidized starch be starch in acid, alkali, neutral medium with
Oxidant is acted on, and a kind of converted starch obtained from starch oxidation, oxidized starch is reduced starch gelatinization temperature, heat paste viscosity
Diminish and heat endurance increase, product colour is pure white, paste transparent, good film-forming property, freeze-thaw resistance is good, is the increasing of low viscosity high concentration
Thick dose；Oxidized starch, organic phospho acid, zinc oxide, Boratex, sepiolite, borax synergy can effectively slow down at high temperature
Hardening time is applied, there is high temperature deferred action to coating solution；And oxidized starch, organic phospho acid, zinc oxide, Boratex, sea
Afrodite, borax asepsis environment-protecting, high temperature resistant property are good；It is good that silica sand has the performances such as the small, high-insulation of high temperature resistant, thermal coefficient of expansion
Good high-temperature stabilizer；The chemical state of dimethyl siloxane is dimethicone, colourless or light yellow liquid, tasteless, transparency
Height, varies with temperature small, water proofing property, surface tension small with heat resistance, cold resistance, viscosity；Calcium carbonate is used to strengthen paint film
Intensity, organic phospho acid is prevented from calcium carbonate sedimentation；Propandiol butyl ether is coalescents, promotes film forming of the present invention.The present invention is adopted
With a large amount of components with resistance to elevated temperatures, at high temperature, the performance of each component will not change, and coating has good
Heat resistance, also, the maximum problem that coating faces at high temperature is exactly fast paint solidification, and viscosity is low, poor fluidity, is formed
Film thickness it is big, fragility is high, and the service life of coating is low；Therefore, present invention employs by oxidized starch, organic phospho acid, oxygen
Change zinc, Boratex, sepiolite, the high temperature retarder of borax composition, the hardening time of coating can be postponed, improve dividing for coating
Divergence, it is to avoid coating at high temperature rapid curing and film forming is uneven.
The described water paint with high temperature resistant property, also including following components：Tristerin, defoamer, profit
Humectant, thickener, mould inhibitor, propyl trimethoxy silicane.Tristerin, dimethyl silicone polymer, defoamer, wetting
Agent, thickener, mould inhibitor cooperate, and increase dispersiveness of the invention, stability and resistance to going mouldy property；Propyl trimethoxy silicane
Increase the caking property of the present invention and coated article；Each material cooperates so that of the invention with good heat-resisting quantity and suitable
Viscosity, coating has good hardness, toughness.
The described water paint with high temperature resistant property, also including following components：Pearl essence, titanium dioxide, kaolin.Pearl
The nonhazardous of light powder, high temperature resistant, light shine, acid and alkali-resistance, not spontaneous combustion, it is not combustion-supporting, non-conductive, do not migrate, suitable color can be obtained
Light；The deflocculation of titanium dioxide, anti-decolourization are good；Kaolin is in pure white fine and smooth, soft earthy, with good plasticity
With the physics and chemistry such as fire resistance.
The described water paint with high temperature resistant property, including following parts by weight component：60-80 parts of water, 80-90
Part epoxy modified silicone resin, 40-50 parts of bisphenol A epoxide resin, 10-15 parts of aqueous acroleic acid resin, 30-40 parts of oxidation are formed sediment
Powder, 10-15 part organic phospho acid, 5-10 parts of zinc oxide, 1-5 parts of Boratex, 1-3 parts of sepiolite, 1-3 parts of borax, 10-15 parts of silicon
Sand, 10-15 part dimethyl silicone polymer, 5-8 parts of calcium carbonate, 5-10 parts of propandiol butyl ether.The present invention is based on existing aqueous painting
The consumption of material, Binding experiment result and production cost, have selected the amount of the excellent each component of coating property；Invention increases resistance to
The amount of the good component of high-temperature behavior, increased the component of raising coating resistance to elevated temperatures, but not influence the combination property of coating,
Coating film strength, stability and corrosion resistance etc. can be improved on the contrary.
The described water paint with high temperature resistant property, including following parts by weight component：70 parts of water, 90 parts of epoxies
Modified organic silicone resin, 40 parts of bisphenol A epoxide resins, 13 parts of aqueous acroleic acid resins, 35 parts of oxidized starch, 10 parts of organic phosphines
Acid, 8 parts of zinc oxide, 3 parts of Boratexes, 2 parts of sepiolites, 1 part of borax, 13 parts of silica sands, 12 parts of dimethyl silicone polymers, 6 parts of carbonic acid
Calcium, 8 parts of propandiol butyl ethers.The preferred amount of component of the present invention.
The present invention compared with prior art, has the following advantages and advantages：
1st, water paint of the present invention with high temperature resistant property employs a large amount of components with resistance to elevated temperatures, in high temperature
Under, the performance of each component will not change, and coating has good temperature tolerance；
2nd, water paint of the present invention with high temperature resistant property is employed by oxidized starch, organic phospho acid, zinc oxide, boric acid
Sodium, sepiolite, the high temperature retarder of borax composition, can postpone the hardening time of coating, improve the decentralization of coating, it is to avoid
Coating at high temperature rapid curing and film forming is uneven；
3rd, the good combination property such as water paint stability, resistance to going mouldy property, corrosion resistance with high temperature resistant property of the present invention
And asepsis environment-protecting.
Specific embodiment
To make the object, technical solutions and advantages of the present invention become more apparent, with reference to embodiment, the present invention is made
Further to describe in detail, exemplary embodiment of the invention and its explanation are only used for explaining the present invention, are not intended as to this
The restriction of invention.
Embodiment 1
Water paint of the present invention with high temperature resistant property, including following components：
Water, epoxy modified silicone resin, bisphenol A epoxide resin, aqueous acroleic acid resin, oxidized starch, organic phospho acid,
Zinc oxide, Boratex, sepiolite, borax, silica sand, dimethyl silicone polymer, calcium carbonate, propandiol butyl ether.
Epoxy modified silicone resin, bisphenol A epoxide resin, aqueous acroleic acid resin are film forming matters, and organosilicon is high poly-
Thing is heat-resist with Si-O keys as main chain；There are the excellent properties of many protrusions after epoxy resin is cured, it is such as special to various materials
It is not very strong to the adhesion of metal, has very strong chemical resistance, mechanical strength are very high, electrical insulating property is good, corrosion-resistant etc..
Additionally, epoxy resin can solidify within the scope of comparatively wide temperature, and volume contraction is small during solidification, bisphenol type epoxy tree
Fat is condensed in the basic conditions by bisphenol-A, epoxychloropropane, through washing, the macromolecular compound that desolventizing is refined；Water
Property acrylic resin include emulsion acrylic resin, aqueous acrylic resin dispersion and acrylic resin aqueous solution, it is and traditional
Solvent based coating is compared, and water paint has that price is low, use safety；Oxidized starch be starch in acid, alkali, neutral medium with
Oxidant is acted on, and a kind of converted starch obtained from starch oxidation, oxidized starch is reduced starch gelatinization temperature, heat paste viscosity
Diminish and heat endurance increase, product colour is pure white, paste transparent, good film-forming property, freeze-thaw resistance is good, is the increasing of low viscosity high concentration
Thick dose；Oxidized starch, organic phospho acid, zinc oxide, Boratex, sepiolite, borax synergy can effectively slow down at high temperature
Hardening time is applied, there is high temperature deferred action to coating solution；And oxidized starch, organic phospho acid, zinc oxide, Boratex, sea
Afrodite, borax asepsis environment-protecting, high temperature resistant property are good；It is good that silica sand has the performances such as the small, high-insulation of high temperature resistant, thermal coefficient of expansion
Good high-temperature stabilizer；The chemical state of dimethyl siloxane is dimethicone, colourless or light yellow liquid, tasteless, transparency
Height, varies with temperature small, water proofing property, surface tension small with heat resistance, cold resistance, viscosity；Calcium carbonate is used to strengthen paint film
Intensity, organic phospho acid is prevented from calcium carbonate sedimentation；Propandiol butyl ether is coalescents, promotes film forming of the present invention.The present invention is adopted
With a large amount of components with resistance to elevated temperatures, at high temperature, the performance of each component will not change, and coating has good
Heat resistance, also, the maximum problem that coating faces at high temperature is exactly fast paint solidification, and viscosity is low, poor fluidity, is formed
Film thickness it is big, fragility is high, and the service life of coating is low；Therefore, present invention employs by oxidized starch, organic phospho acid, oxygen
Change zinc, Boratex, sepiolite, the high temperature retarder of borax composition, the hardening time of coating can be postponed, improve dividing for coating
Divergence, it is to avoid coating at high temperature rapid curing and film forming is uneven.
The described water paint with high temperature resistant property, also including following components：Tristerin, defoamer, profit
Humectant, thickener, mould inhibitor, propyl trimethoxy silicane.Tristerin, dimethyl silicone polymer, defoamer, wetting
Agent, thickener, mould inhibitor cooperate, and increase dispersiveness of the invention, stability and resistance to going mouldy property；Propyl trimethoxy silicane
Increase the caking property of the present invention and coated article；Each material cooperates so that of the invention with good heat-resisting quantity and suitable
Viscosity, coating has good hardness, toughness.
Embodiment 2
Based on embodiment 1, the described water paint with high temperature resistant property, also including following components：Pearl essence, titanium white
Powder, kaolin.Pearl essence nonhazardous, high temperature resistant, light shine, acid and alkali-resistance, not spontaneous combustion, it is not combustion-supporting, non-conductive, do not migrate, can be with
Obtain suitable coloured light；Titanium dioxide deflocculation, anti-decolourization are good；Kaolin is in pure white fine and smooth, soft earthy, with good
The physics and chemistry such as good plasticity and fire resistance.
Embodiment 3
Based on above-described embodiment, the component of the described water paint with high temperature resistant property, including following parts by weight：
60-80 parts of water, 80-90 parts of epoxy modified silicone resin, 40-50 parts of bisphenol A epoxide resin, 10-15 parts of water soluble acrylic acid tree
Ester, 30-40 part oxidized starch, 10-15 parts of organic phospho acid, 5-10 parts of zinc oxide, 1-5 parts of Boratex, 1-3 parts of sepiolite, 1-3 parts
Borax, 10-15 part silica sand, 10-15 parts of dimethyl silicone polymer, 5-8 parts of calcium carbonate, 5-10 parts of propandiol butyl ether.Base of the present invention
In the consumption of existing water paint, Binding experiment result and production cost have selected the amount of the excellent each component of coating property；
Invention increases the amount of the good component of resistance to elevated temperatures, the component for improving coating resistance to elevated temperatures is increased, but do not influence
The combination property of coating, can improve coating film strength, stability and corrosion resistance etc. on the contrary.
Embodiment 4
Based on above-described embodiment, the component of the described water paint with high temperature resistant property, including following parts by weight：
70 parts of water, 90 parts of epoxy modified silicone resins, 40 parts of bisphenol A epoxide resins, 13 parts of aqueous acroleic acid resins, 35 parts of oxidations are formed sediment
Powder, 10 parts of organic phospho acids, 8 parts of zinc oxide, 3 parts of Boratexes, 2 parts of sepiolites, 1 part of borax, 13 parts of silica sands, 12 parts of poly dimethyl silicon
Oxygen alkane, 6 parts of calcium carbonate, 8 parts of propandiol butyl ethers.The preferred amount of component of the present invention.
Above-described specific embodiment, has been carried out further to the purpose of the present invention, technical scheme and beneficial effect
Describe in detail, should be understood that and the foregoing is only specific embodiment of the invention, be not intended to limit the present invention
Protection domain, all any modification, equivalent substitution and improvements within the spirit and principles in the present invention, done etc. all should include
Within protection scope of the present invention.
Claims (5)
1. there is the water paint of high temperature resistant property, it is characterised in that including following components：Water, epoxy modified silicone resin,
Bisphenol A epoxide resin, aqueous acroleic acid resin, oxidized starch, organic phospho acid, zinc oxide, Boratex, sepiolite, borax, silicon
Sand, dimethyl silicone polymer, calcium carbonate, propandiol butyl ether.
2. the water paint with high temperature resistant property according to claim 1, it is characterised in that also including following components：
Tristerin, defoamer, wetting agent, thickener, mould inhibitor, propyl trimethoxy silicane.
3. the water paint with high temperature resistant property according to claim 2, it is characterised in that also including following components：
Pearl essence, titanium dioxide, kaolin.
4. the water paint with high temperature resistant property according to claim 1, it is characterised in that including following parts by weight
Component：60-80 parts of water, 80-90 parts of epoxy modified silicone resin, 40-50 parts of bisphenol A epoxide resin, 10-15 parts aqueous third
Olefin(e) acid resin, 30-40 part oxidized starch, 10-15 parts of organic phospho acid, 5-10 parts of zinc oxide, 1-5 parts of Boratex, 1-3 parts of Hai Pao
Stone, 1-3 part borax, 10-15 parts of silica sand, 10-15 parts of dimethyl silicone polymer, 5-8 parts of calcium carbonate, 5-10 parts of propandiol butyl ether.
5. the water paint with high temperature resistant property according to claim 4, it is characterised in that including following parts by weight
Component：70 parts of water, 90 parts of epoxy modified silicone resins, 40 parts of bisphenol A epoxide resins, 13 parts of aqueous acroleic acid resins, 35
Part oxidized starch, 10 parts of organic phospho acids, 8 parts of zinc oxide, 3 parts of Boratexes, 2 parts of sepiolites, 1 part of borax, 13 parts of silica sands, 12 parts gather
Dimethyl siloxane, 6 parts of calcium carbonate, 8 parts of propandiol butyl ethers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710251505.9A CN106867401A (en) | 2017-04-18 | 2017-04-18 | Water paint with high temperature resistant property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710251505.9A CN106867401A (en) | 2017-04-18 | 2017-04-18 | Water paint with high temperature resistant property |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106867401A true CN106867401A (en) | 2017-06-20 |
Family
ID=59162343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710251505.9A Pending CN106867401A (en) | 2017-04-18 | 2017-04-18 | Water paint with high temperature resistant property |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106867401A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109536018A (en) * | 2018-11-24 | 2019-03-29 | 上海凯虹特种材料科技有限公司 | A kind of corrosion-and high-temp-resistant paint and preparation method thereof |
| CN109971225A (en) * | 2017-12-28 | 2019-07-05 | 东莞市广信知识产权服务有限公司 | A kind of novel architecture water-repellent paint |
| CN112020158A (en) * | 2020-09-11 | 2020-12-01 | 广州烯健康新材料科技有限公司 | Energy-saving PTC electric heating film |
| CN112932617A (en) * | 2021-03-09 | 2021-06-11 | 济南新本信息技术有限公司 | Touch medium for precise control and clamping device for narrow cavity channel using same |
| CN115160870A (en) * | 2022-07-12 | 2022-10-11 | 广西维一涂料制造有限公司 | Water-soluble paint |
| CN119552553A (en) * | 2024-10-31 | 2025-03-04 | 重庆凯茜蔓科技有限公司 | Artistic coating with stable pearlescent texture and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1321177A (en) * | 1998-09-30 | 2001-11-07 | 沃纳-兰伯特公司 | Modified starch film compositions |
| CN105176386A (en) * | 2015-10-21 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | High-temperature-resistant water-borne coating and preparation method thereof |
-
2017
- 2017-04-18 CN CN201710251505.9A patent/CN106867401A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1321177A (en) * | 1998-09-30 | 2001-11-07 | 沃纳-兰伯特公司 | Modified starch film compositions |
| CN105176386A (en) * | 2015-10-21 | 2015-12-23 | 苏州赛斯德工程设备有限公司 | High-temperature-resistant water-borne coating and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109971225A (en) * | 2017-12-28 | 2019-07-05 | 东莞市广信知识产权服务有限公司 | A kind of novel architecture water-repellent paint |
| CN109536018A (en) * | 2018-11-24 | 2019-03-29 | 上海凯虹特种材料科技有限公司 | A kind of corrosion-and high-temp-resistant paint and preparation method thereof |
| CN112020158A (en) * | 2020-09-11 | 2020-12-01 | 广州烯健康新材料科技有限公司 | Energy-saving PTC electric heating film |
| CN112932617A (en) * | 2021-03-09 | 2021-06-11 | 济南新本信息技术有限公司 | Touch medium for precise control and clamping device for narrow cavity channel using same |
| CN115160870A (en) * | 2022-07-12 | 2022-10-11 | 广西维一涂料制造有限公司 | Water-soluble paint |
| CN119552553A (en) * | 2024-10-31 | 2025-03-04 | 重庆凯茜蔓科技有限公司 | Artistic coating with stable pearlescent texture and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106867401A (en) | Water paint with high temperature resistant property | |
| CN106700844B (en) | Preparation of a weather-resistant and temperature-resistant anti-corrosion coating | |
| CN103965775A (en) | Water-based organosilicone high temperature resistant anticorrosive coating and preparation method thereof | |
| CN103305094B (en) | Organic coating and preparation method thereof is compounded with based on epoxy novolac Vinylite | |
| CN107573845A (en) | A kind of extra-weather-proof type cracking resistance anticorrosive paint of organosilicon | |
| CN102533061A (en) | High-solid-content superhigh-corrosion-resistant water-based epoxy static conductive paint and preparation method thereof | |
| CN103709903B (en) | High solid conduction type epoxy zinc rich primer | |
| CN103360904A (en) | Tar-free epoxy resin coating and its preparation method | |
| CN104631207A (en) | Waterproof coating for water-based paperboards and preparation method thereof | |
| KR101306989B1 (en) | Non solvent type thick-film typed epoxy silicone resin paints | |
| CN104312225A (en) | High-flexibility and high-glossiness inorganic coating and preparation method | |
| US20190315911A1 (en) | Fire Retardant Compositions | |
| CN104789116A (en) | High-temperature-resistant paint for hydraulic cylinder and preparation method thereof | |
| CN102719164B (en) | Preparation process of multi-performance paint based on ultrathin coating | |
| CN104804642A (en) | Corrosion resistant paint for hydraulic cylinder and preparation method of corrosion resistant paint | |
| CN106833207A (en) | A kind of aqueous double-component anticorrosive paint and preparation method thereof | |
| CN102051105B (en) | Solvent-free coumarone modified epoxy heavy-duty anticorrosive coating | |
| CN104610842A (en) | Preparation method and construction method of fire retardant coating | |
| CN107974172A (en) | High-wearing feature anticorrosive paint | |
| CN108250963B (en) | Acid-resistant non-cured waterproof coating and production process thereof | |
| CN105860619B (en) | Water-based workshop primer composition and antirust steel | |
| KR101388836B1 (en) | Super weather- and ammonia resistant teflon top coating composition | |
| RU2456318C2 (en) | Water-dispersion paint composition | |
| CN113227267B (en) | Coating composition kits and their uses | |
| KR102312833B1 (en) | Flame retardant one liquid type Ceramic Coating Agents Having Excellent Chemical Resistance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170620 |