CN106832856A - A kind of ageing-resistant nano modification color masterbatch carrier for preventing and treating radiation and preparation method thereof - Google Patents
A kind of ageing-resistant nano modification color masterbatch carrier for preventing and treating radiation and preparation method thereof Download PDFInfo
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- 239000004595 color masterbatch Substances 0.000 title claims abstract description 21
- 230000005855 radiation Effects 0.000 title claims abstract description 19
- 230000004048 modification Effects 0.000 title claims abstract description 18
- 238000012986 modification Methods 0.000 title claims abstract description 18
- 230000032683 aging Effects 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 229920001577 copolymer Polymers 0.000 claims abstract description 28
- -1 benzene dicarboxylic acid butanediol ester Chemical class 0.000 claims abstract description 21
- 239000000835 fiber Substances 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 14
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 14
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 14
- 239000004425 Makrolon Substances 0.000 claims abstract description 12
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 12
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 49
- 239000000049 pigment Substances 0.000 claims description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 18
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 16
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 11
- 229910000564 Raney nickel Inorganic materials 0.000 claims description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 11
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 11
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 11
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 11
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 10
- 238000002347 injection Methods 0.000 claims description 10
- 239000007924 injection Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000007767 bonding agent Substances 0.000 claims description 9
- 150000001768 cations Chemical class 0.000 claims description 8
- 239000012153 distilled water Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 6
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 6
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 5
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 5
- 239000010426 asphalt Substances 0.000 claims description 5
- 239000004917 carbon fiber Substances 0.000 claims description 5
- 230000015556 catabolic process Effects 0.000 claims description 5
- 238000013329 compounding Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 230000003247 decreasing effect Effects 0.000 claims description 5
- 238000006731 degradation reaction Methods 0.000 claims description 5
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 5
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 5
- 238000004898 kneading Methods 0.000 claims description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 3
- OFGVPLJWXLEAEN-UHFFFAOYSA-N 2,2-dimethylpropoxy-diethoxy-pentylsilane Chemical compound CC(CO[Si](OCC)(OCC)CCCCC)(C)C OFGVPLJWXLEAEN-UHFFFAOYSA-N 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 4
- 239000004417 polycarbonate Substances 0.000 abstract description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 abstract 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 6
- 239000002131 composite material Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical group C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 238000000527 sonication Methods 0.000 description 2
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical group CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- UCQFCFPECQILOL-UHFFFAOYSA-N diethyl hydrogen phosphate Chemical group CCOP(O)(=O)OCC UCQFCFPECQILOL-UHFFFAOYSA-N 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 230000008774 maternal effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- WYMSBXTXOHUIGT-UHFFFAOYSA-N paraoxon Chemical compound CCOP(=O)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 WYMSBXTXOHUIGT-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000004375 physisorption Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 238000003878 thermal aging Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D49/00—Separating dispersed particles from gases, air or vapours by other methods
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
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- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a kind of ageing-resistant nano modification color masterbatch carrier for preventing and treating radiation and preparation method thereof, the weight portion of constitutive material benzene dicarboxylic acid butanediol ester 15 25, the weight portion of tetrafluoroethene hexafluoropropylene copolymer 10 15, the weight portion of acrylonitrile styrene acrylic ester copolymer 10 20, the weight portion of makrolon 60 80, the weight portion of nano barium carbonate 10 15, the weight portion of aramid fiber short fibre 20 25, the weight portion of silicon carbide platelets 2 10 etc..The present invention improves toughness, wearability, chemical stability, impact strength and the radiation resistance of material with benzene dicarboxylic acid butanediol ester, tetrafluoroethene hexafluoropropylene copolymer, acrylonitrile styrene acrylic ester copolymer and polycarbonate blending；Blending and modifying is carried out using the raw material such as nano barium carbonate, aramid fiber short fibre, silicon carbide platelets polyblend, the shielding property of material can be improved, simultaneously harmful gas high temperature resistant will not be also produced under higher temperature, the performance such as tear-resistant is perfectly merged so that the present invention can apply to be worked under various mal-conditions.
Description
Technical field
The present invention relates to technical field of air purification, more particularly to a kind of ageing-resistant nano modification color for preventing and treating radiation
Maternal carrier and preparation method thereof.
Background technology
Haze is the mixture of mist and haze, and during morning and evening high humidity, the composition of mist is more.Humidity hour on daytime, haze occupies the main force,
Relative humidity is between 80% to 90%.Wherein mist is natural weather phenomenon, the steam generative forces of heaven and earth in air.Although using dust as condensation
Core, but it is overall nontoxic；The core substance of haze is suspended in the materials such as cigarette, the dust in air, and relative air humidity is less than
80%, yellowish.During gas can be directly entered and stick to human body lower respiratory tract and the lobe of the lung, there is injury to health.Haze
The formation of weather is mainly artificial environmental pollution, and along with temperature is low, wind is small etc., natural conditions cause pollutant to be difficult to expand
Dissipate.
Toner pigment is that the outward appearance that a kind of carbonaceous material is made is in black, and internal pore structure is flourishing, and specific surface area is big, energy of adsorption
The strong class carbon materials of power, is a kind of conventional adsorbent, catalyst or catalyst carrier.Toner pigment has extensive use
On the way, in order to improve the application quality of toner pigment, it is necessary to carry out acidification, this hair to the toner pigment using Physical production
The bright toner pigment from after crushing, grain fineness≤0.5 millimeter of toner pigment.
It is used for the toner paint material that purification of air, haze are prevented and treated in the market, its action principle is mainly by thing
The mode for managing suction-operated is separated the pollutant in haze with air.Toner pigment is due to huge specific surface area
And the gap structure of prosperity, therefore with stronger adsorption capacity, it is adaptable to haze deep purifying.In order that toner pigment is effective
Ground function, it is desirable to which toner pigment has appropriate physical property, it is proposed that by improveing toner pigment to improve various characteristics
Technology.
The content of the invention
To overcome above-mentioned deficiency, the present invention provide a kind of ageing-resistant nano modification color masterbatch carrier for preventing and treating radiation and its
Preparation method.
The present invention takes following technical scheme to realize：A kind of ageing-resistant nano modification color masterbatch for preventing and treating radiation
Carrier, the constitutive material that it includes is：Benzene dicarboxylic acid butanediol ester 15-25 weight portions, tetrafluoraoethylene-hexafluoropropylene copolymer
10-15 weight portions, acrylonitrile-styrene-acrylic ester copolymer 10-20 weight portions, makrolon 60-80 weight portions, nanometer
Barium carbonate 10-15 weight portions, aramid fiber short fibre 20-25 weight portions, silicon carbide platelets 2-10 weight portions, asphalt base carbon fiber powder
30-35 parts, non-halogenated organophosphinate 5-7 parts, hexamethylenetetramine 8-10 parts, tri-methyl-amyl triethoxysilane 2-4
Part, conductive mica powder 0.3-0.5 weight portions, conductive nano graphite powder 0.2-0.4 weight portions, the tripolymer 0.8- of polyisocyanates
1 weight portion, polytetrafluoroethylene fibre 1-2 weight portions, toner pigment 65-85 weight portions, montmorillonite 12-20 weight portions, nanometer two
Titanium oxide 5-12 weight portions, silica 3-7 weight portions, gamma-aminopropyl-triethoxy-silane 1-10 weight portions, hydroxypropyl methyl
Cellulose 6-12 weight portions, metal cation flocculant 0.5-5.5 weight portions, nickel nitrate 4-8 weight portions, PAFC 1-
10 weight portions, Raney's nickel 8-12 weight portions, manganese oxide 1-5 weight portions, oligomeric 3- aminopropyl triethoxysilanes 5-10 weight
Part, bonding agent 2-8 weight portions.
The present invention also provides a kind of preparation method for preventing and treating the ageing-resistant nano modification color masterbatch carrier of radiation, by following
Step is constituted：
1）By toner pigment and montmorillonite, nano titanium oxide, silica, gamma-aminopropyl-triethoxy-silane according to right
It is required that ratio grinding described in 1, crosses 100 mesh sieves, mixture A is obtained；
2）Hydroxypropyl methyl cellulose, metal cation flocculant, nickel nitrate, PAFC Raney's nickel and manganese oxide are pressed
After ratio is pulverized and mixed described in claim 1, step 1 is added）、2）10 times of distillations of quality of all compounding substances quality
Water, then carries out ultrasonically treated to it, and ultrasonically treated condition is：90-100 DEG C of temperature, ultrasonic power 500W, ultrasonic time 40-
50min；Mixture B is obtained；
3）Plasticate, by benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer, acrylonitrile-styrene-acrylic ester
Copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets are put into inside according to ratio described in claim 1
Temperature is to mix 30min in 120 DEG C of plasticator, obtains mixture E,
4）By remaining component according to ratio is pulverized and mixed described in claim 1 after, add its 8 times of distilled water of quality, then
It is carried out ultrasonically treated, ultrasonically treated condition is：70-80 DEG C of temperature, ultrasonic power 450W, ultrasonic time 30-40min；System
Obtain mixture C；
5）Mixture A, B are inserted in mixture C, then it is carried out ultrasonically treated, ultrasonically treated condition is：Temperature 60 C, surpasses
Acoustical power 500W, ultrasonic time 75min；Mixture D is obtained；
6）Mixing, internal temperature is put into mix 20min in 120 DEG C of kneading machines by mixture D, E；In the injection of injection machine
Compare color on colour table, be formulated away from adjustment according to colour-difference, the proportioning of color master batch is increased or decreased, after adjustment is qualified；Pass through
Double screw extruder melt blending, extruding pelletization, cooling, the dry prepared biological degradation plastics Masterbatch；
7）Shaping, the product of previous step is put into forming machine, obtains product.
In sum the invention has the advantages that：The present invention is with benzene dicarboxylic acid butanediol ester, tetrafluoroethene-hexafluoro
Propylene copolymer, acrylonitrile-styrene-acrylic ester copolymer and polycarbonate blending, improve the toughness of material, wear-resisting
Property, chemical stability, impact strength and radiation resistance；Using raw materials such as nano barium carbonate, aramid fiber short fibre, silicon carbide platelets
Polyblend carries out blending and modifying, can improve the shielding property of material.Pigment-dispersing, compatibility are good；Meet face
Color requirement, can meet the requirement of composite performance again, and its action principle is mainly in haze by way of physisorption
Pollutant separated with air, toner pigment composite prepared by the present invention has huge specific surface area and prosperity
Gap structure, therefore with stronger adsorption capacity, preferable thixotropy, heat endurance, plasticity, caking property and dry compression
High the features such as, improve toner pigment clean-up effect, meanwhile, instant component by ultrasound, calcining etc. after PROCESS FOR TREATMENT, and
The bonding agent of addition can make the pellet for obtaining be not in the situation of slagging of coming off, and form constitutionally stable composite, nothing
The advantage of secondary pollution, the simple science of preparation method, it is adaptable to promote on a large scale.The rock gangue of addition, conductive mica powder, receive
The reinforcing agents such as rice electrically conductive graphite powder can improve resistant to thermal aging cracking performance, so as to improve casting efficiency, reduce casting cost；Together
When, preparation process is simple science of the invention, it is adaptable to promote on a large scale.
Specific embodiment
For technological means, creation characteristic, reached purpose and effect for making present invention realization are easy to understand, with reference to
Specific embodiment, is expanded on further the present invention.
Embodiment 1
A kind of ageing-resistant nano modification color masterbatch carrier for preventing and treating radiation, the constitutive material that it includes is：Phthalic acid fourth two
The weight portion of alcohol ester 15, the weight portion of tetrafluoraoethylene-hexafluoropropylene copolymer 10, the weight of acrylonitrile-styrene-acrylic ester copolymer 10
Amount part, the weight portion of makrolon 60, the weight portion of nano barium carbonate 10, the weight portion of aramid fiber short fibre 20, the weight of silicon carbide platelets 2
Part, 6 parts of asphalt base carbon fiber powder, 5 parts of non-halogenated organophosphinate, 8 parts of hexamethylenetetramine, the ethoxy of tri-methyl-amyl three
2 parts of base silane, the weight portion of conductive mica powder 0.3, the weight portion of conductive nano graphite powder 0.2, the weight of tripolymer 0.8 of polyisocyanates
Amount part, the weight portion of polytetrafluoroethylene fibre 1, the weight portion of toner pigment 65, the weight portion of montmorillonite 12, the weight of nano titanium oxide 5
Part, the weight portion of silica 3, the weight portion of gamma-aminopropyl-triethoxy-silane 1, the weight portion of hydroxypropyl methyl cellulose 6, metal
The weight portion of cationic flocculant 0.5, the weight portion of nickel nitrate 4, the weight portion of PAFC 1, the weight portion of Raney's nickel 8, manganese oxide 1
Weight portion, the oligomeric weight portion of 3- aminopropyl triethoxysilanes 5, the weight portion of bonding agent 2.
Described non-halogenated organophosphinate is diethyl phosphate；Described bonding agent is pitch.
The present invention also provides a kind of preparation method for preventing and treating the ageing-resistant nano modification color masterbatch carrier of radiation, by following
Step is constituted：
1）By toner pigment with montmorillonite, nano titanium oxide, silica, gamma-aminopropyl-triethoxy-silane according to described
Ratio is ground, and crosses 100 mesh sieves, and mixture A is obtained；
2）Hydroxypropyl methyl cellulose, metal cation flocculant, nickel nitrate, PAFC Raney's nickel and manganese oxide are pressed
After ratio is pulverized and mixed described in claim 1, step 1 is added）、2）10 times of distillations of quality of all compounding substances quality
Water, then carries out ultrasonically treated to it, and ultrasonically treated condition is：90 DEG C of temperature, ultrasonic power 500W, ultrasonic time 40min；System
Obtain mixture B；
3）Plasticate, by benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer, acrylonitrile-styrene-acrylic ester
It is 120 that copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets are put into internal temperature according to the ratio
DEG C plasticator in mix 30min, obtain mixture E,
4）After remaining component is pulverized and mixed according to the ratio, its 8 times of distilled water of quality are added, then it is surpassed
Sonication, ultrasonically treated condition is：Temperature 70 C, ultrasonic power 450W, ultrasonic time 30min；Mixture C is obtained；
5）Mixture A, B are inserted in mixture C, then it is carried out ultrasonically treated, ultrasonically treated condition is：Temperature 60 C, surpasses
Acoustical power 500W, ultrasonic time 75min；Mixture D is obtained；
6）Mixing, internal temperature is put into mix 20min in 120 DEG C of kneading machines by mixture D, E；In the injection of injection machine
Compare color on colour table, be formulated away from adjustment according to colour-difference, the proportioning of color master batch is increased or decreased, after adjustment is qualified；Pass through
Double screw extruder melt blending, extruding pelletization, cooling, the dry prepared biological degradation plastics Masterbatch；
7）Shaping, the product of previous step is put into forming machine, obtains product.
Embodiment 2
A kind of ageing-resistant nano modification color masterbatch carrier for preventing and treating radiation and preparation method thereof
A kind of ageing-resistant nano modification color masterbatch carrier for preventing and treating radiation, the constitutive material that it includes is：Phthalic acid fourth two
The weight portion of alcohol ester 25, the weight portion of tetrafluoraoethylene-hexafluoropropylene copolymer 15, the weight of acrylonitrile-styrene-acrylic ester copolymer 20
Amount part, the weight portion of makrolon 80, the weight portion of nano barium carbonate 15, the weight portion of aramid fiber short fibre 25, the weight of silicon carbide platelets 10
Part, 8 parts of asphalt base carbon fiber powder, 7 parts of non-halogenated organophosphinate, 10 parts of hexamethylenetetramine, the second of tri-methyl-amyl three
4 parts of TMOS, the weight portion of conductive mica powder 0.5, the weight portion of conductive nano graphite powder 0.4, the weight of tripolymer 1 of polyisocyanates
Amount part, the weight portion of polytetrafluoroethylene fibre 2, the weight portion of toner pigment 85, the weight portion of montmorillonite 20, the weight of nano titanium oxide 12
Part, the weight portion of silica 7, the weight portion of gamma-aminopropyl-triethoxy-silane 10, the weight portion of hydroxypropyl methyl cellulose 2, metal
The weight portion of cationic flocculant 5.5, the weight portion of nickel nitrate 8, the weight portion of PAFC 10, the weight portion of Raney's nickel 12, oxidation
The weight portion of manganese 5, the oligomeric weight portion of 3- aminopropyl triethoxysilanes 10, the weight portion of bonding agent 8.
Described non-halogenated organophosphinate is triethyl phosphate；Described bonding agent is butadiene-styrene rubber.
The present invention also provides a kind of preparation method for preventing and treating the ageing-resistant nano modification color masterbatch carrier of radiation, by following
Step is constituted：
1）By toner pigment with montmorillonite, nano titanium oxide, silica, gamma-aminopropyl-triethoxy-silane according to described
Ratio is ground, and crosses 100 mesh sieves, and mixture A is obtained；
2）Hydroxypropyl methyl cellulose, metal cation flocculant, nickel nitrate, PAFC Raney's nickel and manganese oxide are pressed
After being pulverized and mixed according to the ratio, step 1 is added）、2）10 times of distilled water of quality of all compounding substances quality, it is then right
It carries out ultrasonically treated, and ultrasonically treated condition is：100 DEG C of temperature, ultrasonic power 500W, ultrasonic time 50min；Mixture is obtained
B；
3）Plasticate, by benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer, acrylonitrile-styrene-acrylic ester
It is 120 that copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets are put into internal temperature according to the ratio
DEG C plasticator in mix 30min, obtain mixture E,
4）By remaining component according to ratio is pulverized and mixed described in claim 1 after, add its 8 times of distilled water of quality, then
It is carried out ultrasonically treated, ultrasonically treated condition is：80 DEG C of temperature, ultrasonic power 450W, ultrasonic time 40min；Mixing is obtained
Thing C；
5）Mixture A, B are inserted in mixture C, then it is carried out ultrasonically treated, ultrasonically treated condition is：Temperature 60 C, surpasses
Acoustical power 500W, ultrasonic time 75min；Mixture D is obtained；
6）Mixing, internal temperature is put into mix 20min in 120 DEG C of kneading machines by mixture D, E；In the injection of injection machine
Compare color on colour table, be formulated away from adjustment according to colour-difference, the proportioning of color master batch is increased or decreased, after adjustment is qualified；Pass through
Double screw extruder melt blending, extruding pelletization, cooling, the dry prepared biological degradation plastics Masterbatch；
7）Shaping, the product of previous step is put into forming machine, obtains product.
Embodiment 3
A kind of ageing-resistant nano modification color masterbatch carrier for preventing and treating radiation and preparation method thereof
A kind of ageing-resistant nano modification color masterbatch carrier for preventing and treating radiation, the constitutive material that it includes is：Phthalic acid fourth two
The weight portion of alcohol ester 23, the weight portion of tetrafluoraoethylene-hexafluoropropylene copolymer 12, the weight of acrylonitrile-styrene-acrylic ester copolymer 18
Amount part, the weight portion of makrolon 78, the weight portion of nano barium carbonate 13, the weight portion of aramid fiber short fibre 23, the weight of silicon carbide platelets 8
Part, 7 parts of asphalt base carbon fiber powder, 6 parts of non-halogenated organophosphinate, 9 parts of hexamethylenetetramine, the ethoxy of tri-methyl-amyl three
3 parts of base silane, the weight portion of conductive mica powder 0.4, the weight portion of conductive nano graphite powder 0.3, the weight of tripolymer 0.8 of polyisocyanates
Amount part, the weight portion of polytetrafluoroethylene fibre 1.5, the weight portion of toner pigment 83, the weight portion of montmorillonite 18, the weight of nano titanium oxide 10
Amount part, the weight portion of silica 6, the weight portion of gamma-aminopropyl-triethoxy-silane 9, the weight portion of hydroxypropyl methyl cellulose 1.8,
The weight portion of metal cation flocculant 5.4, the weight portion of nickel nitrate 7, the weight portion of PAFC 9, the weight portion of Raney's nickel 11, oxygen
Change the weight portion of manganese 4, the oligomeric weight portion of 3- aminopropyl triethoxysilanes 9, the weight portion of bonding agent 7.
Described non-halogenated organophosphinate is triethyl phosphate；Described bonding agent is butadiene-styrene rubber.
The present invention also provides a kind of preparation method for preventing and treating the ageing-resistant nano modification color masterbatch carrier of radiation, by following
Step is constituted：
1）By toner pigment with montmorillonite, nano titanium oxide, silica, gamma-aminopropyl-triethoxy-silane according to described
Ratio is ground, and crosses 100 mesh sieves, and mixture A is obtained；
2）Hydroxypropyl methyl cellulose, metal cation flocculant, nickel nitrate, PAFC Raney's nickel and manganese oxide are pressed
After being pulverized and mixed according to the ratio, step 1 is added）、2）10 times of distilled water of quality of all compounding substances quality, it is then right
It carries out ultrasonically treated, and ultrasonically treated condition is：90 DEG C of temperature, ultrasonic power 500W, ultrasonic time 40min；Mixture is obtained
B；
3）Plasticate, by benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer, acrylonitrile-styrene-acrylic ester
It is 120 that copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets are put into internal temperature according to the ratio
DEG C plasticator in mix 30min, obtain mixture E,
4）After remaining component is pulverized and mixed according to the ratio, its 8 times of distilled water of quality are added, then it is surpassed
Sonication, ultrasonically treated condition is：Temperature 70 C, ultrasonic power 450W, ultrasonic time 40min；Mixture C is obtained；
5）Mixture A, B are inserted in mixture C, then it is carried out ultrasonically treated, ultrasonically treated condition is：Temperature 60 C, surpasses
Acoustical power 500W, ultrasonic time 75min；Mixture D is obtained；
6）Mixing, internal temperature is put into mix 20min in 120 DEG C of kneading machines by mixture D, E；In the injection of injection machine
Compare color on colour table, be formulated away from adjustment according to colour-difference, the proportioning of color master batch is increased or decreased, after adjustment is qualified；Pass through
Double screw extruder melt blending, extruding pelletization, cooling, the dry prepared biological degradation plastics Masterbatch；
7）Shaping, the product of previous step is put into forming machine, obtains product.
Raw material purchasing channel and manufacturer in following examples are respectively：
Toner pigment, montmorillonite, nano titanium oxide, silica, gamma-aminopropyl-triethoxy-silane channel Alibaba,
Taiwan Qimei Industry Co., Ltd.；Shanghai Jin Yue Chemical Co., Ltd.s；
In hydroxypropyl methyl cellulose, metal cation flocculant, nickel nitrate, PAFC Raney's nickel, manganese oxide channel
State's manufacture transaction net, Dow Chemical (China) Co., Ltd；
By benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer channel Alibaba, the Zhejiang hot science and technology of yang exhaustion of shaking has
Limit company；
Acrylonitrile-styrene-acrylic ester copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets canal
Road China Chemical Industry net, Yangzhou Sandeli Chemical Co., Ltd.；
Other raw material channel Alibaba, american exxon Chemical Co., Ltd.；Carefree commerce Net, Hebei province's Dongsheng beeswax is limited
Company；Cover to obtain chemical industry net, Ke Di Chemical Industry Science Co., Ltd of Huainan City
Testing result is as shown in the table：
The above is embodiments of the invention, therefore what all constructions according to described in the present patent application scope, feature and principle were done
Equivalent change or modification, is included in the range of present patent application.
Claims (2)
1. a kind of ageing-resistant nano modification color masterbatch carrier for preventing and treating radiation, it is characterised in that the constitutive material that it includes is：
Toner pigment 65-85 weight portions, benzene dicarboxylic acid butanediol ester 15-25 weight portions, tetrafluoraoethylene-hexafluoropropylene copolymer 10-15
Weight portion, acrylonitrile-styrene-acrylic ester copolymer 10-20 weight portions, makrolon 60-80 weight portions, nano barium carbonate
10-15 weight portions, aramid fiber short fibre 20-25 weight portions, silicon carbide platelets 2-10 weight portions, asphalt base carbon fiber powder 30-35
Part, non-halogenated organophosphinate 5-7 parts, hexamethylenetetramine 8-10 parts, 2-4 parts of tri-methyl-amyl triethoxysilane, lead
Electric mica powder 0.3-0.5 weight portions, conductive nano graphite powder 0.2-0.4 weight portions, the tripolymer 0.8-1 weight of polyisocyanates
Part, polytetrafluoroethylene fibre 1-2 weight portions, montmorillonite 12-20 weight portions, nano titanium oxide 5-12 weight portions, silica
3-7 weight portions, gamma-aminopropyl-triethoxy-silane 1-10 weight portions, hydroxypropyl methyl cellulose 6-12 weight portions, metal sun from
Sub- flocculant 0.5-5.5 weight portions, nickel nitrate 4-8 weight portions, PAFC 1-10 weight portions, Raney's nickel 8-12 weight
Part, manganese oxide 1-5 weight portions, oligomeric 3- aminopropyl triethoxysilanes 5-10 weight portions, bonding agent 2-8 weight portions.
2. it is according to claim 1 it is a kind of for prevent and treat radiation ageing-resistant nano modification color masterbatch carrier preparation method,
It is characterized in that：Comprise the steps of：
1）By toner pigment and montmorillonite, nano titanium oxide, silica, gamma-aminopropyl-triethoxy-silane according to right
It is required that ratio grinding described in 1, crosses 100 mesh sieves, mixture A is obtained；
2）Hydroxypropyl methyl cellulose, metal cation flocculant, nickel nitrate, PAFC Raney's nickel and manganese oxide are pressed
After ratio is pulverized and mixed described in claim 1, step 1 is added）、2）10 times of distillations of quality of all compounding substances quality
Water, then carries out ultrasonically treated to it, and ultrasonically treated condition is：90-100 DEG C of temperature, ultrasonic power 500W, ultrasonic time 40-
50min；Mixture B is obtained；
3）Plasticate, by benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer, acrylonitrile-styrene-acrylic ester
Copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets are put into inside according to ratio described in claim 1
Temperature is to mix 30min in 120 DEG C of plasticator, obtains mixture E,
4）By remaining component according to ratio is pulverized and mixed described in claim 1 after, add its 8 times of distilled water of quality, then
It is carried out ultrasonically treated, ultrasonically treated condition is：70-80 DEG C of temperature, ultrasonic power 450W, ultrasonic time 30-40min；System
Obtain mixture C；
5）Mixture A, B are inserted in mixture C, then it is carried out ultrasonically treated, ultrasonically treated condition is：Temperature 60 C, surpasses
Acoustical power 500W, ultrasonic time 75min；Mixture D is obtained；
6）Mixing, internal temperature is put into mix 20min in 120 DEG C of kneading machines by mixture D, E；In the injection of injection machine
Compare color on colour table, be formulated away from adjustment according to colour-difference, the proportioning of color master batch is increased or decreased, after adjustment is qualified；Pass through
Double screw extruder melt blending, extruding pelletization, cooling, the dry prepared biological degradation plastics Masterbatch；
7）Shaping, the product of previous step is put into forming machine, obtains product.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113024851A (en) * | 2021-03-25 | 2021-06-25 | 佛山市高明彩盈福新材料有限公司 | High-dispersibility black master batch and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009083913A1 (en) * | 2007-12-28 | 2009-07-09 | Sabic Innovative Plastics Ip B.V. | Polyester-polyamide compositions, articles, and method of manufacture thereof |
| CN102250480A (en) * | 2011-05-25 | 2011-11-23 | 佛山市顺德区高怡新塑料有限公司 | Plastic-based magnetic composite material and preparation method thereof |
| CN106084647A (en) * | 2016-08-02 | 2016-11-09 | 苏州锐特捷化工制品有限公司 | A kind of construction material of resistance to expansion nano for preventing and treating haze and preparation method thereof |
| CN106189169A (en) * | 2016-08-28 | 2016-12-07 | 肖丽燕 | A kind of protective window radioprotective shock resistance polycarbonate plate and preparation method thereof |
-
2016
- 2016-12-30 CN CN201611270638.2A patent/CN106832856A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009083913A1 (en) * | 2007-12-28 | 2009-07-09 | Sabic Innovative Plastics Ip B.V. | Polyester-polyamide compositions, articles, and method of manufacture thereof |
| CN102250480A (en) * | 2011-05-25 | 2011-11-23 | 佛山市顺德区高怡新塑料有限公司 | Plastic-based magnetic composite material and preparation method thereof |
| CN106084647A (en) * | 2016-08-02 | 2016-11-09 | 苏州锐特捷化工制品有限公司 | A kind of construction material of resistance to expansion nano for preventing and treating haze and preparation method thereof |
| CN106189169A (en) * | 2016-08-28 | 2016-12-07 | 肖丽燕 | A kind of protective window radioprotective shock resistance polycarbonate plate and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113024851A (en) * | 2021-03-25 | 2021-06-25 | 佛山市高明彩盈福新材料有限公司 | High-dispersibility black master batch and preparation method thereof |
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