CN106832855A - One kind is for modified radiation-resisting functional color masterbatch plastic material of magnetic and preparation method thereof - Google Patents
One kind is for modified radiation-resisting functional color masterbatch plastic material of magnetic and preparation method thereof Download PDFInfo
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- CN106832855A CN106832855A CN201611262702.2A CN201611262702A CN106832855A CN 106832855 A CN106832855 A CN 106832855A CN 201611262702 A CN201611262702 A CN 201611262702A CN 106832855 A CN106832855 A CN 106832855A
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- 230000005291 magnetic effect Effects 0.000 title claims abstract description 54
- 239000000463 material Substances 0.000 title claims abstract description 41
- 229920003023 plastic Polymers 0.000 title claims abstract description 39
- 239000004033 plastic Substances 0.000 title claims abstract description 38
- 239000004595 color masterbatch Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 229920001577 copolymer Polymers 0.000 claims abstract description 28
- -1 benzene dicarboxylic acid butanediol ester Chemical class 0.000 claims abstract description 24
- 239000000835 fiber Substances 0.000 claims abstract description 21
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 14
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 14
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 14
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 13
- 239000004425 Makrolon Substances 0.000 claims abstract description 12
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims abstract description 10
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 44
- 229910002804 graphite Inorganic materials 0.000 claims description 33
- 239000010439 graphite Substances 0.000 claims description 33
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 22
- 239000000243 solution Substances 0.000 claims description 22
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 17
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 16
- 239000000049 pigment Substances 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 11
- 239000004115 Sodium Silicate Substances 0.000 claims description 10
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 10
- 238000002347 injection Methods 0.000 claims description 10
- 239000007924 injection Substances 0.000 claims description 10
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000853 adhesive Substances 0.000 claims description 8
- 230000001070 adhesive effect Effects 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- 239000012760 heat stabilizer Substances 0.000 claims description 8
- 239000012286 potassium permanganate Substances 0.000 claims description 8
- 229920001690 polydopamine Polymers 0.000 claims description 7
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 7
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 5
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- 239000010426 asphalt Substances 0.000 claims description 5
- 239000004917 carbon fiber Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000003365 glass fiber Substances 0.000 claims description 5
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 5
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 5
- 150000003949 imides Chemical class 0.000 claims description 5
- 238000004898 kneading Methods 0.000 claims description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 4
- 229960001484 edetic acid Drugs 0.000 claims description 4
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 229920002627 poly(phosphazenes) Polymers 0.000 claims description 2
- OFGVPLJWXLEAEN-UHFFFAOYSA-N 2,2-dimethylpropoxy-diethoxy-pentylsilane Chemical compound CC(CO[Si](OCC)(OCC)CCCCC)(C)C OFGVPLJWXLEAEN-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 claims 1
- 238000006731 degradation reaction Methods 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 9
- 239000002131 composite material Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000001179 sorption measurement Methods 0.000 abstract description 3
- 239000004417 polycarbonate Substances 0.000 abstract description 2
- 230000005855 radiation Effects 0.000 abstract description 2
- 229920001893 acrylonitrile styrene Polymers 0.000 abstract 2
- 239000000047 product Substances 0.000 description 9
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 5
- 239000004594 Masterbatch (MB) Substances 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 4
- 239000000440 bentonite Substances 0.000 description 4
- 229910000278 bentonite Inorganic materials 0.000 description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 230000003413 degradative effect Effects 0.000 description 4
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 4
- 239000004135 Bone phosphate Substances 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical group C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 3
- RLGQACBPNDBWTB-UHFFFAOYSA-N cetyltrimethylammonium ion Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)C RLGQACBPNDBWTB-UHFFFAOYSA-N 0.000 description 3
- 230000036571 hydration Effects 0.000 description 3
- 238000006703 hydration reaction Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical group CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- 238000005266 casting Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- FHVAUDREWWXPRW-UHFFFAOYSA-N triethoxy(pentyl)silane Chemical compound CCCCC[Si](OCC)(OCC)OCC FHVAUDREWWXPRW-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 229910001021 Ferroalloy Inorganic materials 0.000 description 1
- 235000016639 Syzygium aromaticum Nutrition 0.000 description 1
- 244000223014 Syzygium aromaticum Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- WYMSBXTXOHUIGT-UHFFFAOYSA-N paraoxon Chemical compound CCOP(=O)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 WYMSBXTXOHUIGT-UHFFFAOYSA-N 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- MLGWTHRHHANFCC-UHFFFAOYSA-N prop-2-en-1-amine;hydrochloride Chemical compound Cl.NCC=C MLGWTHRHHANFCC-UHFFFAOYSA-N 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003878 thermal aging Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/01—Magnetic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses one kind for modified radiation-resisting functional color masterbatch plastic material of magnetic and preparation method thereof, the constitutive material that it includes is：The weight portion of benzene dicarboxylic acid butanediol ester 15 25, the weight portion of tetrafluoroethene hexafluoropropylene copolymer 10 15, the weight portion of acrylonitrile styrene acrylic ester copolymer 10 20, the weight portion of makrolon 60 80, the weight portion of nano barium carbonate 10 15, the weight portion of aramid fiber short fibre 20 25, the weight portion of silicon carbide platelets 2 10, benzene dicarboxylic acid butanediol ester, tetrafluoroethene hexafluoropropylene copolymer, acrylonitrile styrene acrylic ester copolymer and polycarbonate blending, improve toughness, wearability, chemical stability, impact strength and the radiation resistance of material；Blending and modifying is carried out using the raw material such as nano barium carbonate, aramid fiber short fibre, silicon carbide platelets polyblend, the shielding property of material can be improved.With reference to nano-graphene between layers, the hole and specific surface area for improving composite adsorption film exist, and enhance effect.Meet color requirement, the requirement of composite performance can be met again.
Description
Technical field
The present invention relates to technical field of function materials, more particularly to one kind is for the modified radiation-resisting functional color masterbatch plastics of magnetic
Material and preparation method thereof.
Background technology
Magnetic plastics is a kind of novel high polymer functional material that the seventies grow up, and is modern science and technology field
One of important foundation material.Magnetic plastics can be divided into structural type and compound two kinds, structural type magnetic plastics by composition
Refer to
Polymer has ferromagnetic magnet in itself, this kind of magnetic plastics also in the exploratory stage, from it is practical also have it is certain
Distance；Compound magnetic plastics refer to the magnet being made as base material is processed with plastics or rubber, and this kind of magnetic plastics is real
Existing commercialization, the toner pigment currently used for filling is mainly ferrite toner pigment and rare earth toner pigment forever.
At present, most of functional plasticses such as fire retardant antistatic plastic, conductive plastics, wear-resistant plastic, luminescent plastic etc. is all
Achieved the goal by adding various functions auxiliary agent, its functional layer is limited only to top layer, the function additive of nexine is not played mostly
Actual utility, so as to cause auxiliary agent to waste, increased cost, and auxiliary agent addition excessively causes that material property declines substantially.
Meanwhile, the preparation technology existing defects of current functional material, preparation technology is relatively cumbersome etc..
For the above-mentioned deficiency of existing capability material, the excellent specific property of magnetic plastics is introduced color masterbatch functional material by the present invention
Field, so as to overcome the shortcoming of existing color masterbatch functional material, the performance of modified function material.
The content of the invention
To overcome above-mentioned deficiency, the present invention to provide a kind of for magnetic modified radiation-resisting functional color masterbatch plastic material and its system
Preparation Method.
The present invention takes following technical scheme to realize：One kind is for the modified radiation-resisting functional color masterbatch plastics material of magnetic
Expect, the constitutive material that it includes is：Benzene dicarboxylic acid butanediol ester 15-25 weight portions, tetrafluoraoethylene-hexafluoropropylene copolymer 10-
15 weight portions, acrylonitrile-styrene-acrylic ester copolymer 10-20 weight portions, makrolon 60-80 weight portions, nano-calcium carbonate
Barium 10-15 weight portions, aramid fiber short fibre 20-25 weight portions, silicon carbide platelets 2-10 weight portions, nano-graphene 10-15 weight
Part, toner pigment 65-85 weight portions, sodium metasilicate 5-10 weight portions, magnetic iron oxide 10-20 weight portions, magnetic alumina 4-8 weight
Amount part, 30-35 parts of asphalt base carbon fiber powder, non-halogenated organophosphinate 5-7 parts, hexamethylenetetramine 8-10 parts, front three
2-4 parts of base amyl triethoxysilane, conductive mica powder 0.3-0.5 weight portions, conductive nano graphite powder 0.2-0.4 weight portions,
The tripolymer 0.8-1 weight portions of polyisocyanates, polytetrafluoroethylene fibre 1-2 weight portions, nano titanium oxide 8-12 weight portions,
Poly-dopamine 1-5 weight portions, poly phosphazene 2-6 weight portions, magnetic ferroferric oxide particle 12-20 weight portions, 2- phosphoric acid ethamine 4-8
Weight portion, polyethylene imide 1-5 weight portions, paraffin 8-12 weight portions, senior aliphat alcohol 7-13 weight portions, ethylenediamine tetrem
Sour 5-9 weight portions, glass fibre 7-13 weight portions, heat stabilizer 6-12 weight portions, adhesive 6-12 weight portions, poly dimethyl two
Allyl ammonium chloride 1-5 weight portions, bentonite 8-16 weight portions, nano-cerium oxide 1-5 weight portions.
The preparation method of the nano-graphene is：By in concentrated sulfuric acid addition graphite, stirred by -20 DEG C ~ -10 DEG C low temperature
5-12 hours, then by after 0 DEG C ~ 5 DEG C stirrings 5-12 hour, addition potassium permanganate carries out oxidation reaction, and to obtain graphite oxide molten
Liquid；To obtain being directly added into CTAB in graphite oxide solution, CTAB flocculates graphite oxide and modified-reaction is modified
Graphite oxide solution；By the filtering of modified graphite oxide solution, washing, it is vacuum dried 24 hours at 50 DEG C, that is, obtains nano-graphite
Alkene.
The present invention also provides a kind of preparation method for the modified radiation-resisting functional color masterbatch plastic material of magnetic, by following step
Rapid composition：
(1) according to the ratio by toner pigment, sodium metasilicate, magnetic iron oxide, magnetic alumina, nano titanium oxide, poly- many
Bar amine dimension is placed in pulverizer to be crushed, and crosses 100-200 mesh sieves, standby as component A；
(2) plasticate, according to the ratio by benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer, acrylonitrile-benzene
Vinyl-acrylate copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets are put into internal temperature and are
30min is mixed in 120 DEG C of plasticator, component B is obtained,
3）Mixing, internal temperature is put into add other components according to the ratio in 120 DEG C of kneading machines by component A, B, is mixed
Stirring 20min；Compare color on the injection colour table of injection machine, be formulated away from adjustment according to colour-difference, increase or decrease color female
The proportioning of grain, after adjustment is qualified；By double screw extruder melt blending, extruding pelletization, cooling, the dry prepared full biology
Degradative plastics Masterbatch；
4）Shaping, the product of previous step is put into forming machine, obtains product.
In sum the invention has the advantages that：The present invention is with benzene dicarboxylic acid butanediol ester, tetrafluoroethene-hexafluoro
Propylene copolymer, acrylonitrile-styrene-acrylic ester copolymer and polycarbonate blending, improve the toughness of material, wear-resisting
Property, chemical stability, impact strength and radiation resistance；Using raw materials such as nano barium carbonate, aramid fiber short fibre, silicon carbide platelets
Polyblend carries out blending and modifying, can improve the shielding property of material.The functional material for magnetic plastics is obtained final product,
Component prepares reasonable, and method is easy, with low cost, environmental protection, phenomenon will not be peeling in manufacturing process and enhances material
Durability of guaranteeing the quality, greatly reinforced the close-coupled degree of material, obtained functional material stable performance, security are good, tool
There are magnetic advantages higher, not only greatly improve the feature and persistence of magnetic plastics product, also to a great extent
The consumption of auxiliary agent is reduced, cost has been saved, the performance impact to plastic substrate is smaller, it is preferably maintained original property
Energy and intensity, it is adaptable to promote on a large scale.The reinforcing agents such as rock gangue, conductive mica powder, the conductive nano graphite powder of addition can
To improve resistant to thermal aging cracking performance, so as to improve casting efficiency, casting cost is reduced.Selection photochemical catalyst and degradable poly breast
Sour shitosan prepares filter fiber film, the dual-use function with absorption aerosol and volatile organic matter, with degradable ring
The advantage of guarantor, the shitosan of use can make it have sterilized work(because molecule is positively charged with the bacterium of adsorption site negative electrical charge
Energy；In structure, the fiber film layer of different-diameter and hole is prepared for, with reference to nano-graphene between layers, is improved
The hole and specific surface area of composite adsorption film exist, and enhance effect.The present invention meets color requirement, and composite performance can be met again
It is required that.
Specific embodiment
For technological means, creation characteristic, reached purpose and effect for making present invention realization are easy to understand, with reference to
Specific embodiment, is expanded on further the present invention.
Embodiment 1
One kind is for modified radiation-resisting functional color masterbatch plastic material of magnetic and preparation method thereof
One kind is used for the modified radiation-resisting functional color masterbatch plastic material of magnetic, and the constitutive material that it includes is：Benzene dicarboxylic acid butanediol
The weight portion of ester 15, the weight portion of tetrafluoraoethylene-hexafluoropropylene copolymer 10, the weight of acrylonitrile-styrene-acrylic ester copolymer 10
Part, the weight portion of makrolon 60, the weight portion of nano barium carbonate 10, the weight portion of aramid fiber short fibre 20, the weight portion of silicon carbide platelets 2,
It is the weight portion of nano-graphene 10, the weight portion of toner pigment 65, the weight portion of sodium metasilicate 5, the weight portion of magnetic iron oxide 10, magnetic oxygenated
The weight portion of aluminium 4,6 parts of asphalt base carbon fiber powder, 5 parts of non-halogenated organophosphinate, 8 parts of hexamethylenetetramine, trimethyl penta
2 parts of ethyl triethoxy silicane alkane, the weight portion of conductive mica powder 0.3, the weight portion of conductive nano graphite powder 0.2, the three of polyisocyanates
The weight portion of aggressiveness 0.8, the weight portion of polytetrafluoroethylene fibre 1, the weight portion of nano titanium oxide 8, the weight portion of poly-dopamine 1, poly- phosphine
The weight portion of nitrile 2, the weight portion of magnetic ferroferric oxide particle 12, the weight portion of 2- phosphoric acid ethamine 4, the weight portion of polyethylene imide 1, stone
The weight portion of wax 8, the weight portion of senior aliphat alcohol 7, the weight portion of ethylenediamine tetra-acetic acid 5, the weight portion of glass fibre 7, the weight of heat stabilizer 6
Amount part, the weight portion of adhesive 6, the weight portion of PDDA 1, the weight portion of bentonite 8, the weight of nano-cerium oxide 1
Amount part.
Described non-halogenated organophosphinate is triethyl phosphate；Described heat stabilizer is the tribasic sulfuric acid of hydration
Lead；Described adhesive is butadiene-styrene rubber；Described senior aliphat alcohol is polyvinyl alcohol.
The preparation method of the nano-graphene is：By in 75% concentrated sulfuric acid addition graphite（The graphite and the concentrated sulfuric acid
Mass volume ratio is 1g:50mL）, stirred 5 hours by -20 DEG C of low temperature, then after 0 DEG C is stirred 5 hours, add potassium permanganate
Carry out oxidation reaction and obtain graphite oxide solution（The potassium permanganate is with the mass volume ratio of concentrated sulfuric acid graphite mixed solution：
1g:60ml）；To obtain being directly added into the CTAB (mass volume ratios of the CTAB and graphite oxide solution in graphite oxide solution
For：1g:30ml, CTAB are cetyl trimethyl ammonium), CTAB is flocculated to graphite oxide and modified-reaction is modified
Graphite oxide solution；By the filtering of modified graphite oxide solution, washing, it is vacuum dried 24 hours at 50 DEG C, that is, obtains nano-graphite
Alkene.
The present invention also provides a kind of preparation method for the modified radiation-resisting functional color masterbatch plastic material of magnetic, by following step
Rapid composition：
(1) according to the ratio by toner pigment, sodium metasilicate, magnetic iron oxide, magnetic alumina, nano titanium oxide, poly- many
Bar amine dimension is placed in pulverizer to be crushed, and crosses 100 mesh sieves, standby as component A；
(2) plasticate, according to the ratio by benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer, acrylonitrile-benzene
Vinyl-acrylate copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets are put into internal temperature and are
30min is mixed in 120 DEG C of plasticator, component B is obtained,
3）Mixing, internal temperature is put into add other components according to the ratio in 120 DEG C of kneading machines by component A, B, is mixed
Stirring 20min；Compare color on the injection colour table of injection machine, be formulated away from adjustment according to colour-difference, increase or decrease color female
The proportioning of grain, after adjustment is qualified；By double screw extruder melt blending, extruding pelletization, cooling, the dry prepared full biology
Degradative plastics Masterbatch；
4）Shaping, the product of previous step is put into forming machine, obtains product.
Embodiment 2
One kind is for modified radiation-resisting functional color masterbatch plastic material of magnetic and preparation method thereof
One kind is used for the modified radiation-resisting functional color masterbatch plastic material of magnetic, and the constitutive material that it includes is：Benzene dicarboxylic acid butanediol
The weight portion of ester 25, the weight portion of tetrafluoraoethylene-hexafluoropropylene copolymer 15, the weight of acrylonitrile-styrene-acrylic ester copolymer 20
Part, the weight portion of makrolon 80, the weight portion of nano barium carbonate 15, the weight portion of aramid fiber short fibre 25, the weight portion of silicon carbide platelets 10,
The weight portion of nano-graphene 15, the weight portion of toner pigment 85, the weight portion of sodium metasilicate 10, the weight portion of magnetic iron oxide 20, magnetic oxygen
Change the weight portion of aluminium 8,8 parts of asphalt base carbon fiber powder, 7 parts of non-halogenated organophosphinate, 10 parts of hexamethylenetetramine, trimethyl
4 parts of amyl triethoxysilane, the weight portion of conductive mica powder 0.5, conductive nano graphite powder 0.4 weight portion, polyisocyanates
The weight portion of tripolymer 1, the weight portion of polytetrafluoroethylene fibre 2, the weight portion of nano titanium oxide 12, the weight portion of poly-dopamine 5, poly- phosphine
The weight portion of nitrile 6, the weight portion of magnetic ferroferric oxide particle 20, the weight portion of 2- phosphoric acid ethamine 8, the weight portion of polyethylene imide 5, stone
The weight portion of wax 12, the weight portion of senior aliphat alcohol 13, the weight portion of ethylenediamine tetra-acetic acid 9, the weight portion of glass fibre 13, heat stabilizer
It is 12 weight portions, the weight portion of adhesive 12, the weight portion of PDDA 5, the weight portion of bentonite 16, nano oxidized
The weight portion of cerium 5.
Described non-halogenated organophosphinate is triethyl phosphate；Described heat stabilizer is the tribasic sulfuric acid of hydration
Lead；Described adhesive is butadiene-styrene rubber；Described senior aliphat alcohol is polyvinyl alcohol.
The preparation method of the nano-graphene is：By in 75% concentrated sulfuric acid addition graphite（The graphite and the concentrated sulfuric acid
Mass volume ratio is 1g:50mL）, stirred 5 hours by -20 DEG C of low temperature, then after 0 DEG C is stirred 5 hours, add potassium permanganate
Carry out oxidation reaction and obtain graphite oxide solution（The potassium permanganate is with the mass volume ratio of concentrated sulfuric acid graphite mixed solution：
1g:60ml）；To obtain being directly added into the CTAB (mass volume ratios of the CTAB and graphite oxide solution in graphite oxide solution
For：1g:30ml, CTAB are cetyl trimethyl ammonium), CTAB is flocculated to graphite oxide and modified-reaction is modified
Graphite oxide solution；By the filtering of modified graphite oxide solution, washing, it is vacuum dried 24 hours at 50 DEG C, that is, obtains nano-graphite
Alkene.
The present invention also provides a kind of preparation method for the modified radiation-resisting functional color masterbatch plastic material of magnetic, by following steps group
Into：
(1) according to the ratio by toner pigment, sodium metasilicate, magnetic iron oxide, magnetic alumina, nano titanium oxide, poly- many
Bar amine dimension is placed in pulverizer to be crushed, and crosses 100 mesh sieves, standby as component A；
(2) plasticate, according to the ratio by benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer, acrylonitrile-benzene
Vinyl-acrylate copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets are put into internal temperature and are
30min is mixed in 120 DEG C of plasticator, component B is obtained,
3）Mixing, internal temperature is put into add other components according to the ratio in 120 DEG C of kneading machines by component A, B, is mixed
Stirring 20min；Compare color on the injection colour table of injection machine, be formulated away from adjustment according to colour-difference, increase or decrease color female
The proportioning of grain, after adjustment is qualified；By double screw extruder melt blending, extruding pelletization, cooling, the dry prepared full biology
Degradative plastics Masterbatch；
4）Shaping, the product of previous step is put into forming machine, obtains product.
Embodiment 3
One kind is for modified radiation-resisting functional color masterbatch plastic material of magnetic and preparation method thereof
One kind is used for the modified radiation-resisting functional color masterbatch plastic material of magnetic, and the constitutive material that it includes is：Benzene dicarboxylic acid butanediol
The weight portion of ester 17, the weight portion of tetrafluoraoethylene-hexafluoropropylene copolymer 12, the weight of acrylonitrile-styrene-acrylic ester copolymer 12
Part, the weight portion of makrolon 63, the weight portion of nano barium carbonate 12, the weight portion of aramid fiber short fibre 23, the weight portion of silicon carbide platelets 3,
It is the weight portion of nano-graphene 11, the weight portion of toner pigment 67, the weight portion of sodium metasilicate 6, the weight portion of magnetic iron oxide 11, magnetic oxygenated
The weight portion of aluminium 5,7 parts of asphalt base carbon fiber powder, 6 parts of non-halogenated organophosphinate, 9 parts of hexamethylenetetramine, trimethyl penta
3 parts of ethyl triethoxy silicane alkane, the weight portion of conductive mica powder 0.4, the weight portion of conductive nano graphite powder 0.3, the three of polyisocyanates
The weight portion of aggressiveness 0.9, the weight portion of polytetrafluoroethylene fibre 2, the weight portion of nano titanium oxide 9, the weight portion of poly-dopamine 2, poly- phosphine
The weight portion of nitrile 3, the weight portion of magnetic ferroferric oxide particle 14, the weight portion of 2- phosphoric acid ethamine 5, the weight portion of polyethylene imide 2, stone
The weight portion of wax 9, the weight portion of senior aliphat alcohol 8, the weight portion of ethylenediamine tetra-acetic acid 6, the weight portion of glass fibre 8, the weight of heat stabilizer 7
Amount part, the weight portion of adhesive 7, the weight portion of PDDA 2, the weight portion of bentonite 9, the weight of nano-cerium oxide 2
Amount part.
Described non-halogenated organophosphinate is triethyl phosphate；Described heat stabilizer is the tribasic sulfuric acid of hydration
Lead；Described adhesive is butadiene-styrene rubber；Described senior aliphat alcohol is polyvinyl alcohol.
The preparation method of the nano-graphene is：By in 75% concentrated sulfuric acid addition graphite（The graphite and the concentrated sulfuric acid
Mass volume ratio is 1g:50mL）, stirred 5 hours by -20 DEG C of low temperature, then after 0 DEG C is stirred 5 hours, add potassium permanganate
Carry out oxidation reaction and obtain graphite oxide solution（The potassium permanganate is with the mass volume ratio of concentrated sulfuric acid graphite mixed solution：
1g:60ml）；To obtain being directly added into the CTAB (mass volume ratios of the CTAB and graphite oxide solution in graphite oxide solution
For：1g:30ml, CTAB are cetyl trimethyl ammonium), CTAB is flocculated to graphite oxide and modified-reaction is modified
Graphite oxide solution；By the filtering of modified graphite oxide solution, washing, it is vacuum dried 24 hours at 50 DEG C, that is, obtains nano-graphite
Alkene.
The present invention also provides a kind of preparation method for the modified radiation-resisting functional color masterbatch plastic material of magnetic, by following steps group
Into：
(1) according to the ratio by toner pigment, sodium metasilicate, magnetic iron oxide, magnetic alumina, nano titanium oxide, poly- many
Bar amine dimension is placed in pulverizer to be crushed, and crosses 150 mesh sieves, standby as component A；
(2) plasticate, according to the ratio by benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer, acrylonitrile-benzene
Vinyl-acrylate copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets are put into internal temperature and are
30min is mixed in 120 DEG C of plasticator, component B is obtained,
3）Mixing, internal temperature is put into add other components according to the ratio in 120 DEG C of kneading machines by component A, B, is mixed
Stirring 20min；Compare color on the injection colour table of injection machine, be formulated away from adjustment according to colour-difference, increase or decrease color female
The proportioning of grain, after adjustment is qualified；By double screw extruder melt blending, extruding pelletization, cooling, the dry prepared full biology
Degradative plastics Masterbatch；
4）Shaping, the product of previous step is put into forming machine, obtains product.
Raw material purchasing channel and manufacturer in following examples are respectively：
Toner pigment, sodium metasilicate channel Alibaba, Taiwan Qimei Industry Co., Ltd.；The Shanghai brocade limited public affairs of happy chemical industry
Department；
Magnetic iron oxide, magnetic alumina, nano titanium oxide, poly-dopamine dimension channel made in China transaction net, LG-DOW
Chemical (China) Co., Ltd；
Benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer channel Alibaba, Zhejiang shake yang exhaustion heat science and technology it is limited
Company；China Chemical Industry net, Yangzhou Sandeli Chemical Co., Ltd.；
Acrylonitrile-styrene-acrylic ester copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets canal
Road Alibaba, american exxon Chemical Co., Ltd.；
Other carefree commerce Nets of raw material channel, Dongsheng beeswax Co., Ltd of Hebei province；Cover to obtain chemical industry net, section of Huainan City Dihua industry science
Skill Co., Ltd；Lip river gram chemical industry net, Hubei Ju Sheng Science and Technology Ltd.s；Cover to obtain chemical industry net, Jiande City's intelligence friend's limited public affairs of silicon materials
Department；Cover to obtain chemical industry net, the bright Chemical Co., Ltd. in Guangzhou sincere one；Wise net, Jiangsu Jing Ruite environmental friendly materials Co., Ltd；Ah
Li Baba, Anyang Guo Chang ferroalloys Co., Ltd；Chinese supplier, Xinyang Chuan Xing Industrial Co., Ltd.s；Cloves is led to, on
Hai Jianglai bio tech ltd；Intelligent clever net, Tai'an SunHao Chemical Co., Ltd.s；
Testing result is as shown in the table：
The above is embodiments of the invention, therefore what all constructions according to described in the present patent application scope, feature and principle were done
Equivalent change or modification, is included in the range of present patent application.
Claims (2)
1. it is a kind of for the modified radiation-resisting functional color masterbatch plastic material of magnetic, it is characterised in that the constitutive material that it includes is benzene
Dioctyl phthalate butanediol ester 15-25 weight portions, tetrafluoraoethylene-hexafluoropropylene copolymer 10-15 weight portions, acrylonitrile-styrene-the third
Olefin(e) acid ester copolymer 10-20 weight portions, makrolon 60-80 weight portions, nano barium carbonate 10-15 weight portions, aramid fiber short fibre
20-25 weight portions, silicon carbide platelets 2-10 weight portions, nano-graphene 10-15 weight portions, toner pigment 65-85 weight portions, silicon
Sour sodium 5-10 weight portions, magnetic iron oxide 10-20 weight portions, magnetic alumina 4-8 weight portions, asphalt base carbon fiber powder 30-
35 parts, non-halogenated organophosphinate 5-7 parts, hexamethylenetetramine 8-10 parts, 2-4 parts of tri-methyl-amyl triethoxysilane,
Conductive mica powder 0.3-0.5 weight portions, conductive nano graphite powder 0.2-0.4 weight portions, the tripolymer 0.8-1 weights of polyisocyanates
Amount part, polytetrafluoroethylene fibre 1-2 weight portions, nano titanium oxide 8-12 weight portions, poly-dopamine 1-5 weight portions, poly phosphazene
2-6 weight portions, magnetic ferroferric oxide particle 12-20 weight portions, 2- phosphoric acid ethamine 4-8 weight portions, polyethylene imide 1-5 weights
Amount part, paraffin 8-12 weight portions, senior aliphat alcohol 7-13 weight portions, ethylenediamine tetra-acetic acid 5-9 weight portions, glass fibre 7-13
It is weight portion, heat stabilizer 6-12 weight portions, adhesive 6-12 weight portions, PDDA 1-5 weight portions, swollen
Profit soil 8-16 weight portions, nano-cerium oxide 1-5 weight portions；
The preparation method of the nano-graphene is：By in concentrated sulfuric acid addition graphite, 5-12 are stirred by -20 DEG C ~ -10 DEG C low temperature
Hour, then after 0 DEG C ~ 5 DEG C are stirred 5-12 hours, add potassium permanganate to carry out oxidation reaction and obtain graphite oxide solution；Will
Obtain being directly added into CTAB in graphite oxide solution, CTAB flocculates graphite oxide and modified-reaction obtains modified oxidized stone
Black solution；By the filtering of modified graphite oxide solution, washing, it is vacuum dried 24 hours at 50 DEG C, that is, obtains nano-graphene.
2. a kind of preparation method for the modified radiation-resisting functional color masterbatch plastic material of magnetic according to claim 1, its
It is characterised by：Comprise the steps of：
(1) by toner pigment, sodium metasilicate, magnetic iron oxide, magnetic alumina, nano titanium oxide, poly-dopamine dimension according to power
Profit requires that ratio described in 1 is placed in crushing in pulverizer, crosses 100-200 mesh sieves, standby as component A；
(2) plasticate, by benzene dicarboxylic acid butanediol ester, tetrafluoraoethylene-hexafluoropropylene copolymer, acrylonitrile-styrene-acrylic ester
Copolymer, makrolon, nano barium carbonate, aramid fiber short fibre, silicon carbide platelets are put into inside according to ratio described in claim 1
Temperature is to mix 30min in 120 DEG C of plasticator, obtains component B,
3）Mixing, internal temperature is put into add other components in 120 DEG C of kneading machines by component A, B, mixes 20min；
Compare color on the injection colour table of injection machine, be formulated away from adjustment according to colour-difference, increase or decrease the proportioning of color master batch, adjust
After qualified；By double screw extruder melt blending, extruding pelletization, cooling, the dry prepared biological degradation plastics color masterbatch
Grain；
4）Shaping, the product of previous step is put into forming machine, obtains product.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107215043A (en) * | 2017-06-17 | 2017-09-29 | 合肥市晨雷思建筑材料科技有限公司 | A kind of high definition waterproof radiation protective film and preparation method |
| CN107974066A (en) * | 2017-11-20 | 2018-05-01 | 滁州华美塑业有限公司 | One kind is used for magnetic modified radiation-resisting functional color masterbatch plastic material |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101451638A (en) * | 2007-11-29 | 2009-06-10 | 上海泺安医药技术有限公司 | Novel plastic hose with magnetic material |
| WO2009083913A1 (en) * | 2007-12-28 | 2009-07-09 | Sabic Innovative Plastics Ip B.V. | Polyester-polyamide compositions, articles, and method of manufacture thereof |
| CN106147188A (en) * | 2016-08-05 | 2016-11-23 | 江苏金发科技新材料有限公司 | A kind of high fluidity polycarbonate alloy and preparation method thereof |
| CN106189169A (en) * | 2016-08-28 | 2016-12-07 | 肖丽燕 | A kind of protective window radioprotective shock resistance polycarbonate plate and preparation method thereof |
| CN106188695A (en) * | 2016-08-17 | 2016-12-07 | 常熟市瑞思知识产权服务有限公司 | A kind of for magnetic oil resistant fibre modification nanometer functional materials for building and preparation method thereof |
-
2016
- 2016-12-30 CN CN201611262702.2A patent/CN106832855A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101451638A (en) * | 2007-11-29 | 2009-06-10 | 上海泺安医药技术有限公司 | Novel plastic hose with magnetic material |
| WO2009083913A1 (en) * | 2007-12-28 | 2009-07-09 | Sabic Innovative Plastics Ip B.V. | Polyester-polyamide compositions, articles, and method of manufacture thereof |
| CN106147188A (en) * | 2016-08-05 | 2016-11-23 | 江苏金发科技新材料有限公司 | A kind of high fluidity polycarbonate alloy and preparation method thereof |
| CN106188695A (en) * | 2016-08-17 | 2016-12-07 | 常熟市瑞思知识产权服务有限公司 | A kind of for magnetic oil resistant fibre modification nanometer functional materials for building and preparation method thereof |
| CN106189169A (en) * | 2016-08-28 | 2016-12-07 | 肖丽燕 | A kind of protective window radioprotective shock resistance polycarbonate plate and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107215043A (en) * | 2017-06-17 | 2017-09-29 | 合肥市晨雷思建筑材料科技有限公司 | A kind of high definition waterproof radiation protective film and preparation method |
| CN107974066A (en) * | 2017-11-20 | 2018-05-01 | 滁州华美塑业有限公司 | One kind is used for magnetic modified radiation-resisting functional color masterbatch plastic material |
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Application publication date: 20170613 |