CN106810974A - A kind of visible ray photocuring marime fouling thing prevents and treats coating - Google Patents
A kind of visible ray photocuring marime fouling thing prevents and treats coating Download PDFInfo
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- CN106810974A CN106810974A CN201710043999.1A CN201710043999A CN106810974A CN 106810974 A CN106810974 A CN 106810974A CN 201710043999 A CN201710043999 A CN 201710043999A CN 106810974 A CN106810974 A CN 106810974A
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- China
- Prior art keywords
- coating
- visible ray
- prevents
- fouling
- fluorine
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- 239000011248 coating agent Substances 0.000 title claims abstract description 37
- 238000000576 coating method Methods 0.000 title claims abstract description 37
- 238000000016 photochemical curing Methods 0.000 title claims abstract description 17
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 45
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 38
- 239000011737 fluorine Substances 0.000 claims abstract description 38
- -1 sensitizer Substances 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000003999 initiator Substances 0.000 claims abstract description 12
- 239000002519 antifouling agent Substances 0.000 claims abstract description 11
- 229920000592 inorganic polymer Polymers 0.000 claims abstract description 11
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 59
- 239000004925 Acrylic resin Substances 0.000 claims description 41
- 229920000178 Acrylic resin Polymers 0.000 claims description 41
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 38
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 35
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 19
- 239000003973 paint Substances 0.000 claims description 19
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 13
- 229930016911 cinnamic acid Natural products 0.000 claims description 13
- 235000013985 cinnamic acid Nutrition 0.000 claims description 13
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims description 13
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims description 12
- 238000002604 ultrasonography Methods 0.000 claims description 10
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 claims description 9
- 229960002504 capsaicin Drugs 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 229920001503 Glucan Polymers 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- VDRSDNINOSAWIV-UHFFFAOYSA-N [F].[Si] Chemical group [F].[Si] VDRSDNINOSAWIV-UHFFFAOYSA-N 0.000 claims description 5
- 239000002086 nanomaterial Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 2
- GQDHEYWVLBJKBA-UHFFFAOYSA-H copper(ii) phosphate Chemical compound [Cu+2].[Cu+2].[Cu+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GQDHEYWVLBJKBA-UHFFFAOYSA-H 0.000 claims description 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 2
- 229940112669 cuprous oxide Drugs 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 229920002521 macromolecule Polymers 0.000 claims 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 1
- 125000005323 thioketone group Chemical group 0.000 claims 1
- 244000005700 microbiome Species 0.000 abstract description 9
- 231100000419 toxicity Toxicity 0.000 abstract description 5
- 230000001988 toxicity Effects 0.000 abstract description 5
- 210000003097 mucus Anatomy 0.000 abstract description 4
- 230000002745 absorbent Effects 0.000 abstract description 2
- 239000002250 absorbent Substances 0.000 abstract description 2
- 238000013461 design Methods 0.000 abstract description 2
- 230000000366 juvenile effect Effects 0.000 abstract description 2
- 210000004400 mucous membrane Anatomy 0.000 abstract description 2
- 230000002633 protecting effect Effects 0.000 abstract description 2
- 230000028327 secretion Effects 0.000 abstract description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 230000003373 anti-fouling effect Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- PORQOHRXAJJKGK-UHFFFAOYSA-N 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone Chemical compound CCCCCCCCN1SC(Cl)=C(Cl)C1=O PORQOHRXAJJKGK-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 235000010215 titanium dioxide Nutrition 0.000 description 8
- 238000001035 drying Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 231100000331 toxic Toxicity 0.000 description 5
- 230000002588 toxic effect Effects 0.000 description 5
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000000967 suction filtration Methods 0.000 description 4
- CYIGRWUIQAVBFG-UHFFFAOYSA-N 1,2-bis(2-ethenoxyethoxy)ethane Chemical group C=COCCOCCOCCOC=C CYIGRWUIQAVBFG-UHFFFAOYSA-N 0.000 description 3
- 241000238586 Cirripedia Species 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 230000001629 suppression Effects 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- PFWRHNFNTNMKPC-UHFFFAOYSA-N 4-trimethoxysilylbutan-2-yl prop-2-enoate Chemical compound CO[Si](OC)(OC)CCC(C)OC(=O)C=C PFWRHNFNTNMKPC-UHFFFAOYSA-N 0.000 description 2
- 229920002581 Glucomannan Polymers 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940046240 glucomannan Drugs 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000700670 Bryozoa Species 0.000 description 1
- 241000522254 Cassia Species 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 244000274883 Urtica dioica Species 0.000 description 1
- 235000009108 Urtica dioica Nutrition 0.000 description 1
- RMKZLFMHXZAGTM-UHFFFAOYSA-N [dimethoxy(propyl)silyl]oxymethyl prop-2-enoate Chemical compound CCC[Si](OC)(OC)OCOC(=O)C=C RMKZLFMHXZAGTM-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000035587 bioadhesion Effects 0.000 description 1
- 230000003559 chemosterilizing effect Effects 0.000 description 1
- 150000001851 cinnamic acid derivatives Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical group [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005713 exacerbation Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- VHGVQWCOEGRFQZ-UHFFFAOYSA-N methoxysilane oxygen(2-) titanium(4+) Chemical compound [O--].[O--].[Ti+4].CO[SiH3] VHGVQWCOEGRFQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002120 nanofilm Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A kind of visible ray photocuring marime fouling thing prevents and treats coating, including following components：Inorganic polymer film forming matter solvent, sensitizer, initiator, anti-fouling agent.The present invention is using fluorine, silicones or the fluorine silicon compound resin for sending out low-surface-energy so that the external biological mucus of microorganism or juvenile worm secretion is difficult to be soaked in coating surface, and marine fouling organism is difficult to adhere to or adhere to loosely, reaches protecting effect；The coating of formation has special fine micro-nano surface design feature surface, and can discharge the emplastic with absorbent function, forms smooth mucous membrane in matrix surface so that fouling organism cannot adhere to；Low, the "dead" anti-fouling agent of product toxicity, will not impact to marine ecology.
Description
Technical field
The invention belongs to marime fouling thing Prevention Technique field, and in particular to a kind of visible ray photocuring marime fouling thing is prevented
Control coating.
Background technology
Bioadhesion in ocean, refers to that undesirable microcosmic organism tissue, plant or animal are all kinds of in ocean
The deposition pollution produced in artificial surfaces.Biological study shows, after any object is plunged into the commercial sea, its surface will be rapid in a few houres
The microorganisms such as attachment organic matter molecular film, bacterium, diatom, and mucus covering body surface is secreted, microorganism adhering layer is formed, this
Influence of the layer mucus adhesion layer to biodeterioration backward is very big.The attachment of marine fouling organism is endangered very ocean engineering system
Greatly：Ship's navigation coefficient of frictional resistance can be increased, the speed of a ship or plane is reduced, increased oil consumption, and ship is manipulated difficult, deck drying time
Reduce, or even hull interior can be corroded, cause hull to damage；Block the property of the oceanographic instrumentations such as sea water conveying pipelines, influence sonar
The cost of maintenance can simultaneously be increased；Increase the load of offshore oil platform, accelerate the corrosion of its structure；Obstruction netting gear, nettle etc. are supported
The mesh of facility, the growth of influence fish or shellfish are grown, while the equipment of exacerbation is immobilized, reduction of service life.Prevent marine organisms
The method being stained mainly is had application antifouling paint, is cleared up using anti-fouling rubber, electrolysis antifouling system and submarine mechanical.Its
In, application antifouling paint is to prevent marine biofouling most economical, effectively and easily method.
The content of the invention
The problem to be solved in the present invention is：A kind of coating that can effectively prevent marine biofouling is provided.
The object of the present invention is achieved like this：
A kind of visible ray photocuring marime fouling thing prevents and treats coating, including following components：Inorganic polymer film forming matter solvent, sensitizing
Agent, initiator.
Preferably, inorganic polymer film forming matter solvent, sensitizer, the mass ratio of initiator are：1-1.3：1.2-2.5：
0.1-0.3。
Preferably, described inorganic polymer film forming matter solvent is fluorine, silicones or fluorine silicon compound resin.
It is further preferred that the inorganic polymer film forming matter solvent is by nano-titanium dioxide modified fluorine silicon propylene
Acid resin is received, and its preparation method is that nano titanium oxide is added into ultrasound in the solution that fluorine silicone acrylic resin is received, and is obtained and receives
The titania modified fluorine silicone acrylic resin of rice is received, and receives fluorine silicone acrylic resin during being somebody's turn to do and again will after being completely dissolved in dimethylbenzene
Nano titanium oxide is added, and the nano titanium oxide is 1-3 with the mass ratio that fluorine silicone acrylic resin is received：10, the ultrasound
Power be 200-300W, process time 2-3 h.
It is further preferred that the nano titanium oxide is added before the solution that fluorine silicone acrylic resin is received by γ-first
Base acryloxypropyl trimethoxy silane is modified, and the nano-titanium dioxide modified method is nanometer two after the pre-treatment
γ-methacryloxypropyl trimethoxy silane and distilled water, γ-methacryloxypropyl three are added in titanium oxide
Methoxy silane consumption is the 23%-26%, ultrasonic disperse 10-30min of nano titanium oxide quality；70-80 DEG C of temperature control, magnetic force is stirred
Mix, be heated to reflux 3-6 h, reaction terminate after with ethanolic extraction, washing, suction filtration, drying, grind to obtain modified nano-titanium dioxide.
Should during note receiving fluorine silicone acrylic resin be completely dissolved in dimethylbenzene after nano titanium oxide is added again, otherwise resin glue
Degree is very big easily to cause that nano titanium oxide dispersion is uneven.
Preferably, described sensitizer is Bisdiazonium salts or azido compound.
Preferably, described initiator is silicon-fluorine polymer thing.
Preferably, the preventing and treating coating also includes anti-fouling agent, and the anti-fouling agent addition is the 0.1-0.8 μ of anticorrosive paint
G/mL, the anti-fouling agent is copper pyrithione, ZPT, zinc oxide, cupric phosphate or cuprous oxide.
It is further preferred that the preventing and treating coating can also be capsaicine or cinnamic acid or its combination.
Beneficial effect of the present invention：
1st, the present invention is using fluorine, silicones or the fluorine silicon compound resin for sending out low-surface-energy so that the body of microorganism or juvenile worm secretion
Outer biological mucus is difficult to be soaked in coating surface, and marine fouling organism is difficult to adhere to or adhere to loosely, reaches protecting effect；Formed
Coating there is special fine micro-nano surface design feature surface, and the emplastic with absorbent function can be discharged, in base
Body surface face forms smooth mucous membrane so that fouling organism cannot adhere to；Low, the "dead" anti-fouling agent of product toxicity, will not be right
Marine ecology is impacted.
2nd, cinnamic acid of the invention or capsaicine, can avoid the medicaments such as chemosterilant to produced by microorganism adhering layer
Polluted-water environment, make microorganism adhering layer produce toxic and side effect.Cinnamic acid used in the present invention is traditional Chinese medicine Chinese cassia tree
The main component of volatile oil, capsaicine purges with the material for taking for foodstuff raw material, and toxic and side effect is low, and environment is not polluted, and has
Good suppression microorganism adhering layer is adsorbed and microorganism adhering layer is difficult to produce drug resistance to it.
3rd, fluorine silicone acrylic resin receives middle addition influences by modified nano titanium oxide on its viscosity and adhesive force
It is smaller, but form the micro-nano projection of similar lotus leaf structure, resin surface and water on the surface that fluorine silicone acrylic resin is received
Contact angle reaches 120 ° -128 °, belongs to low-surface-energy material, anti-fouling effect of the anti-fouling effect than traditional acrylic acid antifouling paint
It is good.
4th, there is hydroxyl in unmodified nano titanium oxide surface, and these hydroxyls form associate hydrogen bond each other so that nanometer
Produce reunion between titanium dioxide granule, modified nano titanium oxide dispersiveness in organic solvent and stability are improved,
With stronger hydrophobicity.Titanium dioxide surface γ-methacryloxypropyl trimethoxy silane after modified nanometer
The lipophile of group is stronger, thus agglomeration of the nano titanium oxide in fluorine silicone acrylic resin is received be improved significantly.
5th, the Glucomannan added in anti-corrosion material has water holding thickening, stabilization, suspension, gelling, bonding, film forming etc. many
Unique physicochemical property is planted, increase mobility can be improved, and reduce viscosity, reduce the absorption of seabed microbial layer, reduced
It is stained.
Brief description of the drawings
Dispersiveness and stability of Fig. 1 titanium dioxide in organic solvent dimethylbenzene.
Wherein：A rutile type nano titanic oxides, b anatase-type nanometer titanium dioxides, the homemade nano titanium oxides of c.
Specific embodiment
The present invention is further illustrated with reference to embodiment, but the scope of protection of present invention is not limited to implement
The scope of example statement.
Embodiment 1
A kind of visible ray photocuring marime fouling thing prevents and treats coating, from inorganic polymer film forming matter solvent, sensitizer, initiation
Agent, the mass ratio of anti-fouling agent are：1：1.2：0.1：3, mixing obtains this coating.
Described sensitizer is Bisdiazonium salts or azido compound.
Described initiator is silicon-fluorine polymer thing.
Described activated monomer is triethyleneglycol divinylether.
The inorganic nano material modified resin is to be received by nano-titanium dioxide modified fluorine silicone acrylic resin, its
Preparation method is that nano titanium oxide is added into ultrasound in the solution that fluorine silicone acrylic resin is received, and prepared nano titanium oxide changes
Property fluorine silicone acrylic resin receive, should during fluorine silicone acrylic resin received be completely dissolved in after dimethylbenzene again by nano titanium oxide
Add, the nano titanium oxide is 2 with the mass ratio that fluorine silicone acrylic resin is received：10, the power of the ultrasound is 200W, place
The h of reason time 2.
The anticorrosive paint also includes cinnamic acid, and the cinnamic acid addition is 0.1 μ g/mL of anticorrosive paint.
Embodiment 2
A kind of visible ray photocuring marime fouling thing prevents and treats coating, including following components：Inorganic polymer film forming matter solvent, sensitizing
Agent, initiator, the mass ratio of anti-fouling agent are：1.2：2.0：0.2：4, mixing obtains this coating.
Described sensitizer is Bisdiazonium salts or azido compound.
Described initiator is silicon-fluorine polymer thing.
Described activated monomer is triethyleneglycol divinylether.
The inorganic nano material modified resin is to be received by nano-titanium dioxide modified fluorine silicone acrylic resin, its
Preparation method is that nano titanium oxide is added into ultrasound in the solution that fluorine silicone acrylic resin is received, and prepared nano titanium oxide changes
Property fluorine silicone acrylic resin receive, should during fluorine silicone acrylic resin received be completely dissolved in after dimethylbenzene again by nano titanium oxide
Add, the nano titanium oxide is 3 with the mass ratio that fluorine silicone acrylic resin is received：10, the power of the ultrasound is 300W, place
The h of reason time 3.
It is further preferred that the nano titanium oxide is added before the solution that fluorine silicone acrylic resin is received by γ-methyl
Acryloxypropyl trimethoxy silane is modified, and the nano-titanium dioxide modified method is nano-silica after the pre-treatment
Change addition γ-methacryloxypropyl trimethoxy silane and distilled water, γ-methacryloxypropyl front three in titanium
TMOS consumption is the 26% of nano titanium oxide quality, ultrasonic disperse 30min；80 DEG C of temperature control, magnetic agitation is heated to reflux 5
H, reaction terminate after with ethanolic extraction, washing, suction filtration, drying, grind to obtain modified nano-titanium dioxide.Note fluorine during being somebody's turn to do
Silicone acrylic resin is received after being completely dissolved in dimethylbenzene and again adds nano titanium oxide, and otherwise resin viscosity is very big easily causes to receive
Rice titanium dioxide dispersion is uneven.Modified nano titanium oxide in organic solvent dispersed and stabilization as shown in Figure 1
Property improve, with stronger hydrophobicity, the modified effect of rutile type nano titanic oxide compares anatase-type nanometer titanium dioxide
Modified effect it is good, stability preferably, place the long period, still can in xylene solvent stable dispersion.
The anticorrosive paint also includes capsaicine, and the capsaicine addition is 0.6 μ g/mL of anticorrosive paint.
Embodiment 3
A kind of visible ray photocuring marime fouling thing prevents and treats coating, inorganic polymer film forming matter solvent, sensitizer, initiator, anti-
The mass ratio of dirty agent is： 1.3： 2.5：0.3：5, mixing obtains this coating.
Described sensitizer is Bisdiazonium salts or azido compound.
Described initiator is silicon-fluorine polymer thing.
Described activated monomer is triethyleneglycol divinylether.
The inorganic nano material modified resin is to be received by nano-titanium dioxide modified fluorine silicone acrylic resin, its
Preparation method is that nano titanium oxide is added into ultrasound in the solution that fluorine silicone acrylic resin is received, and prepared nano titanium oxide changes
Property fluorine silicone acrylic resin receive, should during fluorine silicone acrylic resin received be completely dissolved in after dimethylbenzene again by nano titanium oxide
Add, the nano titanium oxide is 2 with the mass ratio that fluorine silicone acrylic resin is received：10, the power of the ultrasound is 300W, place
Reason time 2.5h.
It is further preferred that the nano titanium oxide is added before the solution that fluorine silicone acrylic resin is received by γ-methyl
Acryloxypropyl trimethoxy silane is modified, and the nano-titanium dioxide modified method is nano-silica after the pre-treatment
Change addition γ-methacryloxypropyl trimethoxy silane and distilled water, γ-methacryloxypropyl front three in titanium
TMOS consumption is the 25% of nano titanium oxide quality, ultrasonic disperse 20min；75 DEG C of temperature control, magnetic agitation is heated to reflux
5h, reaction terminate after with ethanolic extraction, washing, suction filtration, drying, grind to obtain modified nano-titanium dioxide.Noting during being somebody's turn to do will
Fluorine silicone acrylic resin is received after being completely dissolved in dimethylbenzene and again adds nano titanium oxide, and otherwise resin viscosity is very big easily causes
Nano titanium oxide dispersion is uneven.
Because one layer of organic matter of commercially available rutile type nano titanic oxide Surface coating, thus using it is preceding need it is right
Nano titanium oxide is pre-processed.Preprocess method to take rutile type nano titanic oxide, add absolute ethyl alcohol by its
Dissolving, then disperse 1h at a high speed with multifunctional mixer, by scattered solution suction filtration, drying, most treated at last nanometer two
Titanium oxide is stored in drier.
Preferably, the anticorrosive paint also includes cinnamic acid, and the cinnamic acid addition is 0.7 μ g/mL of anticorrosive paint.
Preferably, the anticorrosive paint also includes glucan, and the glucan addition is accounted for as inorganic nano material modified
The 0.6% of resin quality.
Viscosity and adhesive force change that nano-titanium dioxide modified fluorine silicone acrylic resin is received
By DCOIT（DCOI）Fluorine silicone acrylic resin is added separately to receive and nanometer
During titania modified fluorine silicone acrylic resin is received, resin is equably coated on slide using sol evenning machine, is placed in cool place
Place's drying.Then the slide that fluorine silicone acrylic resin receives will be scribbled to be put into the triangular flask for filling 200 mL water, using shaking table
Simulating ocean environment, controls temperature for 25 DEG C, is sampled at interval of a period of time, using ultraviolet-uisible spectrophotometer or
Agilent1200 high performance liquid chromatography determines in this period DCOI seepage discharges in the aqueous solution, analysis nano titanium oxide plus
Enter the influence for oozing out speed of other materials in being received to fluorine silicone acrylic resin.Dissolving in experimentation due to DCOI in water
Degree is smaller, therefore in experimentation, all carries out changing water after measurement every time.The results are shown in Table 1.
The absorbance of DCOI in the aqueous solution of table 1
Fluorine silicone acrylic resin is received the speed of oozing out of middle DCOI and is all gradually reduced before and after nano-titanium dioxide modified, passes through
Contrast finds that the rate of release of the addition for DCOI in resin of nano titanium oxide does not influence significantly, the 18 of experiment
In it fluorine silicone acrylic resin receive middle DCOI leaching rate it is identical in error range, the addition of this explanation nano titanium oxide
Do not have an impact fluorine silicone acrylic resin and receive the leaching rate of middle DCOI.Show the addition of nano titanium oxide to fluorine silica acrylic acid tree
The viscosity and adhesive force influence that fat is received are smaller.
The inhibitory action that coating of the present invention adheres to line kentrogon
Anticorrosive paint of the present invention is tested using the experimental model for suppressing the attachment of line barnacle cyprids and suppresses kentrogon attachment
Ability.The anti-larva attachment activity of anticorrosive paint of the present invention is determined using 24 well culture plates.Line adult barnacle (Darwin) is adopted
From Dalian harbor intertidal zone.The sea of 8L filterings is put into the polystyrene plastics culture vessel of 12L
, then be put into line adult barnacle in container by water, and placement allows it to discharge larva, collects larva after 2.5 h, the children in the stage
Worm is referred to as naupiar larva, does not have adhesive ability.Naupiar larva is put into equipped with 8L filtering seas (filter sizes are 0.22 μm)
It is bright in 24 DEG C of temperature and 15h in container：Ventilated under 9h dark periodicity of illumination and cultivated, and feeding angle hair diatom, after cultivating 3 days
Collection larva is standby, and the larva in the stage is referred to as cyprids, there is adhesive ability.Added in each hole of 24 well culture plates
Coating of the present invention.Isometric aseptic filtration seawater does blank.24 well culture plates are bright in 24 DEG C of temperature and 15h：9h is dark
Periodicity of illumination under cultivate 48h after, under the microscope statistics attachment larva number.The results are shown in Table 2.Table 2 shows painting of the present invention
Material has significant anti-biofouling activity.For embodiment 1, embodiment 2, adhering to suppressing larva for glucan is added
Effect is stronger, and adhesive rate is 0, it is seen that the addition of glucan, due to Glucomannan have water holding thicken, stabilization, suspend, gelling,
Various unique physicochemical properties such as bonding, film forming, can improve increase mobility, and reduce viscosity, reduce seabed microorganism
The absorption of layer, reduction is stained.
The effect that the coating of the present invention of table 2 adheres to line kentrogon
Anticorrosive paint is to kentrogon toxicity size
Addition cinnamic acid or capsaicine or its combination in same amount to anticorrosive paint, do not detected to kentrogon toxicity size, 48h's
EC50(semi-inhibit adheres to concentration, i.e., corresponding concentration when suppression larva adhesive rate is the 50% of maximum suppression larva adhesive rate),
By EC50Understand the height of detection material anti-biofouling activity.And after 24h, the mortality of larva is calculated, tied according to experiment
Fruit can obtain the LC of 24h50(half lethal concentration), by LC50/EC50(toxic effect ratio) understands that cinnamic acid is big to the toxicity of kentrogon
It is small.Experiment analysis results are shown in Table 3, show that cinnamic acid or capsaicine or its combination have the work for significantly inhibiting the attachment of line kentrogon
Property.Toxic effect is nontoxic anti-biofouling compound than the anti-biofouling compound more than more than 10.The toxic effect ratio tested is all
More than 10, show that this cinnamic acid or capsaicine or its combination suppress the attachment of line kentrogon, but to line kentrogon without poison
Property.
The inhibitory action that the cinnamic acid of table 3 adheres to bryozoan larva.
The key technical indexes of preventing and treating coating provided by the present invention
According to standard GB/T/T 6822-1986《Ship bottom anti-fouling paint general technical specifications》Detected, its result such as 4, table
Shown in the key technical indexes of the provided anticorrosive paint of invention.
The key technical indexes of the preventing and treating coating provided by the present invention of table 4
From table 4, preventing and treating coating provided by the present invention is can be by ten experiments in cycle.Long-acting environment friendly of the invention
Organotin (TBT) and DDT poison of the ship bottom anti-fouling paint without international disabling, easy construction are well attached with hull bottom, have
Excellent physical and mechanical properties, can reach the effect of antifouling phase of 50 to ten years.
The above embodiments are only the preferred technical solution of the present invention, and are not construed as limitation of the invention, this Shen
Please in embodiment and the feature in embodiment in the case where not conflicting, can mutually be combined.Protection model of the invention
Enclose the equivalent side of technical characteristic in the technical scheme that should be recorded with claim, including the technical scheme of claim record
Case is protection domain.Equivalent i.e. within this range is improved, also within protection scope of the present invention.
Claims (9)
1. a kind of visible ray photocuring marime fouling thing prevents and treats coating, it is characterised in that：Including following components：Inorganic polymer into
Film thing solvent, sensitizer, initiator.
2. visible ray photocuring marime fouling thing according to claim 1 prevents and treats coating, it is characterised in that：Inorganic polymer
Film forming matter solvent, sensitizer, the mass ratio of initiator are：1-1.3：1.2-2.5：0.1-0.3.
3. visible ray photocuring marime fouling thing according to claim 1 and 2 prevents and treats coating, it is characterised in that：Described
Sensitizer is Bisdiazonium salts or azido compound.
4. visible ray photocuring marime fouling thing according to claim 1 and 2 prevents and treats coating, it is characterised in that：Described
Initiator is silicon-fluorine polymer thing.
5. visible ray photocuring marime fouling thing according to claim 1 and 2 prevents and treats coating, it is characterised in that：It is described anti-
Controlling coating also includes glucan, and it is the 0.5%-0.8% of inorganic nano material modified resin quality that the glucan addition is accounted for.
6. visible ray photocuring marime fouling thing according to claim 1 and 2 prevents and treats coating, it is characterised in that：Described
Inorganic polymer film forming matter solvent is fluorine, silicones or fluorine silicon compound resin.
7. visible ray photocuring marime fouling thing according to claim 1 and 2 prevents and treats coating, it is characterised in that：The nothing
Machine macromolecule filming thing solvent is to be received by nano-titanium dioxide modified fluorine silicone acrylic resin, and its preparation method is by nanometer
Titanium dioxide is added to ultrasound in the solution that fluorine silicone acrylic resin is received, and nano-titanium dioxide modified fluorine silicone acrylic resin is obtained
Receive, fluorine silicone acrylic resin is received during being somebody's turn to do again adds nano titanium oxide after being completely dissolved in dimethylbenzene, the nanometer two
Titanium oxide is 1-3 with the mass ratio that fluorine silicone acrylic resin is received：10, the power of the ultrasound is 200-300W, process time 2-3
h。
8. visible ray photocuring marime fouling thing according to claim 1 and 2 prevents and treats coating, it is characterised in that：It is described anti-
Controlling coating also includes anti-fouling agent, and the anti-fouling agent addition is the 0.1-0.8 μ g/mL of anticorrosive paint, and the anti-fouling agent is pyridine
Thioketones copper, ZPT, zinc oxide, cupric phosphate or cuprous oxide.
9. visible ray photocuring marime fouling thing according to claim 1 and 2 prevents and treats coating, it is characterised in that：It is described anti-
It can be also cinnamic acid or capsaicine or its combination to control coating.
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| JPS6322872A (en) * | 1986-03-19 | 1988-01-30 | Mitsubishi Cable Ind Ltd | Ultraviolet-curing coating compound and optical fiber using same |
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