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CN106818764A - A kind of Pesticidal combination of novel pesticide - Google Patents

A kind of Pesticidal combination of novel pesticide Download PDF

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Publication number
CN106818764A
CN106818764A CN201710029080.7A CN201710029080A CN106818764A CN 106818764 A CN106818764 A CN 106818764A CN 201710029080 A CN201710029080 A CN 201710029080A CN 106818764 A CN106818764 A CN 106818764A
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CN
China
Prior art keywords
worm
compound
pesticidal combination
novel pesticide
insecticide
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Pending
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CN201710029080.7A
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Chinese (zh)
Inventor
唐剑峰
潘光民
刘杰
额尔敦巴特尔
刘振邦
李冬蓉
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SHANDONG UNITED PESTICIDE INDUSTRY Co Ltd
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SHANDONG UNITED PESTICIDE INDUSTRY Co Ltd
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Priority to CN201710029080.7A priority Critical patent/CN106818764A/en
Publication of CN106818764A publication Critical patent/CN106818764A/en
Pending legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of Pesticidal combination of novel pesticide, compound a of its active ingredient comprising pyridyl pyrazoles acid amides female ring structure and at least one insecticide b, described insecticide b is acequinocyl, fluorine worm carbonic ester, pyrrole fluorine mite amine, acetyl worm nitrile, fluacrypyrim, pyridine are muttered the third worm of ring ester, pyridalyl or sulfanilamide (SN) mite ester etc.；Compound a in composition of the invention contains pyridyl pyrazoles acid amides female ring structure, the structure good disinsection effect, can be used for agricultural, forestry or the preventing and treating of sanitary insect pest, the especially compound can use with existing pesticide compositional, and confrontation property of medicine insect has good prevention effect；Compound a of the invention and existing conventional insecticide no interactions resistance, and have the advantages that hypotoxicity, it is environment-friendly, using safety, wide sterilization spectrum, drug effect is rapid and the duration is long.

Description

A kind of Pesticidal combination of novel pesticide
Technical field
The present invention relates to technical field of pesticide, specifically a kind of Pesticidal combination of novel pesticide.
Background technology
Because agricultural pests can cause very big loss to crops, thus to the preventing and treating of insect be improve crop quality and The important means of yield, the crop growth in insect infringement growth, causes yield to be remarkably decreased, and cost is wasted, raw to agricultural Produce totally unfavorable.The a large amount of of current insecticide use, and the infringement to crop is serious, and urging makes resistance increase rapidly, significantly The prevention effect to insect is reduced, and serious pollution is caused to environment；Want the prevention effect of raising insect, again can not The usage amount and the resistance to the action of a drug of insecticide are increased, new challenge is proposed to insecticide.
Current Pesticidal combination is applied to crop or place can cause sizable infringement, and its desinsection to imitate to crop Fruit depends on the concentration and method of application of insecticide, property and weather conditions of the crop soil etc., such as exposed to illumination Cycle, temperature and precipitation can all influence insecticidal effect.The infringement problem for insecticide to crop is typically at present Safener is added in insecticide to solve, but specific safener is suitable for specific crop plants and specific category Insecticide, therefore the scope of application is narrower, therefore is independent of safener, and to the less insecticide composition of crop detrimental effect Thing is urgently developed.
Substantial amounts of field test proves that the different medicine compounding of two kinds of mechanism of action can not only postpone the generation of resistance, also Can improve drug effect and residence time, reduce usage amount, reduce the dispenser cost of peasant, while the pollution of environment is reduced, Drug effect and duration are improved, the labour cost of peasant is reduced, good economic benefit and social benefit is obtained.
The content of the invention
To solve the above problems, it is an object of the invention to provide a kind of Pesticidal combination of novel pesticide.
The present invention to achieve the above object, is achieved through the following technical solutions：
A kind of Pesticidal combination of novel pesticide, its active ingredient is the compound a of I and at least one insecticide b comprising structural formula；
The structural formula I of described compound a is as follows,
Structural formula I；
Described insecticide b is that acequinocyl, fluorine worm carbonic ester, pyrrole fluorine mite amine, acetyl worm nitrile, fluacrypyrim, pyridine are muttered the third worm of ring ester, pyridine Worm propyl ether, sulfanilamide (SN) mite ester, fipronil bisamide, the pyridine of pyrazoles worm, kill line thiazole, fluorine thiophene worm sulfone, pyriminostrobin, bistrifluron, fluorine bacterium Mite ester, pyrrole fluorine quinoline worm azoles, chlorantraniliprole, pyrazine ethiprole, ethyl pleocidin, ring tebufenozide, more pyridine MTI-446, sterilization Element, clothianidin, gamma cyhalothrin, Envidor, bromine cyanogen insect amide, cyanogen imidazoles sulphur phosphorus, Spiromesifen, spiral shell worm ethyl ester, nitrile pyrrole Mite ester, thunder cuticulin, sulfoxaflor, flonicamid, fluorine chlorine ether chrysanthemum ester, etrafluorine ethofenprox, flufenzine, metaflumizone, thiophene Worm quinoline, dimefluthrin, methoxyfenozide, Diacloden, MTI-446, metofluthrin, desinsection bisgallic acid, ethiprole, polyfluoro Urea, Tolfenpyrad, acrinathrin, Acetamiprid, AVM, emamectin benzoate, Rynaxypyr, indoxacarb, pyrrole worm Quinoline, pymetrozine, fipronil bisamide, pyrrole fluorine quinoline worm azoles, etoxazole, paichongding, Nitenpyram, metaflumizone, fluorobenzene insect amide, four Chlorantraniliprole, butene-fipronil, bromine cyanogen insect amide or ring tebufenozide.
Preferably, insecticide b is Nitenpyram, pymetrozine, Acetamiprid, etoxazole, AVM or Rynaxypyr.
Preferably, the mass ratio of compound a and insecticide b is 1 ~ 20：20~1.
Preferably, active ingredient is 0.001 ~ 99.999% in the content of the Pesticidal combination of novel pesticide.
It is further preferred that the mass ratio of compound a and insecticide b is 1：1.
It is further preferred that active ingredient is 50% in the content of the Pesticidal combination of novel pesticide.
Preferably, the formulation of the Pesticidal combination is the formulation of permission in agricultural production.
It is further preferred that formulation is suspending agent, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, suspension emulsion, missible oil, water Agent, pulvis, water dispersible granules, granule, dry suspending agent, seed coat agent, suspension seed-coating agent, Seed Treatment emulsion, tablet, effervescent agent Or fumigant.
It is further preferred that the formulation of Pesticidal combination is wettable powder, in parts by weight, including compound a 25%, Ethiprole 25%, dodecyl phenol polyglycol ether 3.5%, sodium lignin sulfonate 4.0%, lagoriolite 5.5%, montmorillonite 2 5% With water 12%.
The present invention has advantages below compared to existing technology：
Compound a in composition of the invention contains pyridyl pyrazoles acid amides female ring structure, and the structure good disinsection effect can be used Can be used with existing pesticide compositional in agricultural, forestry or the preventing and treating of sanitary insect pest, the especially compound, resist the property of medicine Insect has good prevention effect；Compound a of the invention and existing conventional insecticide no interactions resistance, and with low Toxicity, it is environment-friendly, using safety, wide sterilization spectrum, the advantage that drug effect is rapid and the duration is long, can kill Lepidoptera, Dermaptera, The major part such as Acarina section purpose insect；The Pesticidal combination of novel pesticide of the invention belongs to low-toxin farm chemicals, to the consumption of crop Few to play good insecticidal effect, the injury to crop is small, and noresidue, environmental safety is high；Two kinds of compoundings of compound Using also having synergistic function, reduced when two kinds of consumptions of insecticide are than single use, so as to improve insecticidal effect, Security is increased, labour cost is reduced, environmental pollution is reduced.
Specific embodiment
It is an object of the invention to provide a kind of Pesticidal combination of novel pesticide, it is achieved through the following technical solutions：
A kind of Pesticidal combination of novel pesticide, its active ingredient is the compound a of I and at least one insecticide b comprising structural formula；
The structural formula I of described compound a is as follows,
Structural formula I；
Described insecticide b is that acequinocyl, fluorine worm carbonic ester, pyrrole fluorine mite amine, acetyl worm nitrile, fluacrypyrim, pyridine are muttered the third worm of ring ester, pyridine Worm propyl ether, sulfanilamide (SN) mite ester, fipronil bisamide, the pyridine of pyrazoles worm, kill line thiazole, fluorine thiophene worm sulfone, pyriminostrobin, bistrifluron, fluorine bacterium Mite ester, pyrrole fluorine quinoline worm azoles, chlorantraniliprole, pyrazine ethiprole, ethyl pleocidin, ring tebufenozide, more pyridine MTI-446, sterilization Element, clothianidin, gamma cyhalothrin, Envidor, bromine cyanogen insect amide, cyanogen imidazoles sulphur phosphorus, Spiromesifen, spiral shell worm ethyl ester, nitrile pyrrole Mite ester, thunder cuticulin, sulfoxaflor, flonicamid, fluorine chlorine ether chrysanthemum ester, etrafluorine ethofenprox, flufenzine, metaflumizone, thiophene Worm quinoline, dimefluthrin, methoxyfenozide, Diacloden, MTI-446, metofluthrin, desinsection bisgallic acid, ethiprole, polyfluoro Urea, Tolfenpyrad, acrinathrin, Acetamiprid, AVM, emamectin benzoate, Rynaxypyr, indoxacarb, pyrrole worm Quinoline, pymetrozine, fipronil bisamide, pyrrole fluorine quinoline worm azoles, etoxazole, paichongding, Nitenpyram, metaflumizone, fluorobenzene insect amide, four Chlorantraniliprole, butene-fipronil, bromine cyanogen insect amide or ring tebufenozide.
Preferably, insecticide b is Nitenpyram, pymetrozine, Acetamiprid, etoxazole, AVM or Rynaxypyr.
Preferably, the mass ratio of compound a and insecticide b is 1 ~ 20：20~1.
Preferably, active ingredient is 0.001 ~ 99.999% in the content of the Pesticidal combination of novel pesticide.
It is further preferred that the mass ratio of compound a and insecticide b is 1：1.
It is further preferred that active ingredient is 50% in the content of the Pesticidal combination of novel pesticide.
Preferably, the formulation of the Pesticidal combination is the formulation of permission in agricultural production.
It is further preferred that formulation is suspending agent, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, suspension emulsion, missible oil, water Agent, pulvis, water dispersible granules, granule, dry suspending agent, seed coat agent, suspension seed-coating agent, Seed Treatment emulsion, tablet, effervescent agent Or fumigant.
It is further preferred that the formulation of Pesticidal combination is wettable powder, in parts by weight, including compound a 25%, Ethiprole 25%, dodecyl phenol polyglycol ether 3.5%, sodium lignin sulfonate 4.0%, lagoriolite 5.5%, montmorillonite 2 5% With water 12%.
Title and the corresponding relation of No. CAS involved by insecticide b of the present invention is as follows：
Acequinocyl（No. CAS：57960-19-7）, fluorine worm carbonic ester（No. CAS：875775-74-9）, pyrrole fluorine mite amine（No. CAS： 926914-55-8）, acetyl worm nitrile（No. CAS：209861-58-5）, fluacrypyrim（No. CAS：229977-93-9）, pyridine mutters the worm of ring third Ester（No. CAS：915972-17-7）、Flubenarim（No. CAS：Temporary nothing）, pyridalyl（No. CAS：179101-81-6）, sulfanilamide (SN) Mite ester（No. CAS：84466-05-7）, fipronil bisamide（No. CAS：272451-65-7）, pyrazoles worm pyridine（No. CAS：394730- 71-3）, kill line thiazole（No. CAS：89583-90-4）, fluorine thiophene worm sulfone（No. CAS：318290-98-1）, pyriminostrobin（No. CAS： 1257598-43-8）, bistrifluron（No. CAS：201593-84-2）, fluorine bacterium mite ester（No. CAS：918162-02-4）, pyrrole fluorine Quinoline worm azoles（No. CAS：337458-27-2）, chlorantraniliprole（No. CAS：500008-45-7）, pyrazine ethiprole（No. CAS： 315208-17-4）, ethyl pleocidin（No. CAS：187166-40-1；187166-15-0）, ring tebufenozide（No. CAS： 143807-66-3）, pyridine MTI-446（No. CAS：951659-40-8）, pleocidin（No. CAS：168316-95-8）, clothianidin （No. CAS：210880-92-5；Once 205510-53-8 is used）, gamma cyhalothrin（No. CAS：91465-08-6）, Envidor （No. CAS：148477-71-8）, bromine cyanogen insect amide（No. CAS：736994-63-1）, cyanogen imidazoles sulphur phosphorus（No. CAS：140163-89- 9）, Spiromesifen（No. CAS：283594-90-1）, spiral shell worm ethyl ester（No. CAS：203313-25-1；382608-10-8）, nitrile pyrrole mite Ester（No. CAS：560121-52-0）, thunder cuticulin（No. CAS：Methyl esters 171249-10-8；Ethyl ester 171249-05-1）, fluorine pyridine worm Amine nitrile（No. CAS：946578-00-3）, flonicamid（No. CAS：158062-67-0）, fluorine chlorine ether chrysanthemum ester（No. CAS： 915288-13-0）, etrafluorine ethofenprox（No. CAS：84937-88-2）, flufenzine（No. CAS：162320-67-4）, metaflumizone （No. CAS：139968-49-3）, thiacloprid（No. CAS：111988-49-9）, dimefluthrin（No. CAS：271241-14- 6）, methoxyfenozide（No. CAS：161050-58-4）, Diacloden（No. CAS：153719-23-4）, MTI-446（No. CAS： 165252-70-0）, metofluthrin（No. CAS：240494-70-6）, desinsection bisgallic acid（No. CAS：98968-92-4）, second worm Nitrile（No. CAS：181587-01-9）, noviflumuron（No. CAS：121451-02-3）, Tolfenpyrad（No. CAS：129558-76-5）、 Acrinathrin（No. CAS：101007-06-1）, Acetamiprid（No. CAS：135410-20-7；160430-64-8）, AVM （No. CAS：71751-41-2）, emamectin benzoate（No. CAS：119791-41-2；Once it was 123997-28-4 and 137335- 79-6）, Rynaxypyr（No. CAS：500008-45-7）, indoxacarb（No. CAS：144171-61-9）, imidacloprid（No. CAS： 138261-41-3, once uses 105827-78-9）, pymetrozine（No. CAS：123312-89-0）, fipronil bisamide（No. CAS： 272451-65-7）, pyrrole fluorine quinoline worm azoles（No. CAS：337458-27-2）, etoxazole（No. CAS：153233-91-1）, paichongding （No. CAS：Temporary nothing）, Nitenpyram（No. CAS：120738-89-8）, metaflumizone（No. CAS：139968-49-3）, fluorobenzene worm acyl Amine（No. CAS：272451-65-7）, four chlorantraniliproles（No. CAS：1104384-14-6）, butene-fipronil（No. CAS：704886-18- 0）, bromine cyanogen insect amide（No. CAS：736994-63-1）, ring tebufenozide（No. CAS：143807-66-3）.
Also include at least one annexing ingredient in Pesticidal combination of the invention, described annexing ingredient is selected from surface-active All auxiliary agents for using are allowed in the pesticidal preparations such as agent, solid diluent and liquid diluent, carrier, film forming agent or adhesive, Select the preparation or composition components consistent with the physical characteristic with the active component, application method and environmental factor. The formulation allowed in all pesticide producings can be prepared into；Type of preparation includes fluid composition and solid composite.Liquid group Compound include suspending agent, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, suspension emulsion, missible oil, aqua, seed coat agent, suspension seed-coating agent, Seed Treatment emulsion etc., and they can optionally be crowded into gel.The general type of solid composite is pulvis, moisture dissipates Granula, granule, dry suspending agent, tablet, effervescent agent, fumigant etc..
, generally by auxiliary agents such as the active component comprising effective dose, diluent and surfactants, it is as follows for the preparation Probable ranges in, summation be by weight 100%.
Solid diluent includes：Clay, kaolin, mica, diatomite, calcium carbonate, urea, talcum, silica, starch, paste Essence, gypsum, cellulose, zinc oxide, titanium dioxide etc..
Liquid diluent includes：It is water, DMF, ethylene glycol, propane diols, paraffin, sorbierite, aromatic hydrocarbons, sweet Oil, laruyl alcohol, tridecanol, cottonseed oil, animal tallow etc..
Composition of the present invention, generally comprises one or more surfactant.The effect of surfactant, typically It is the surface tension for reducing liquid, covering power when raising is used.Hydrophilic radical and lipophilic in surfactant molecule Group properties, surfactant can be used as wetting agent, dispersant, emulsifying agent or defoamer.
Surfactant can be divided into nonionic surfactant, anion surfactant or cationic surfactant. The selectable surfactant of composition of the present invention is included but is not limited to：Alcohol alkoxylates, alkanolamide, alcoxyl The triglycerides of base, alkyl phenol alkoxylates, the aliphatic acid of ethoxylation, the methyl ester of ethoxylation, many ethyoxyls The ester of change, polyethylene glycol, cithrol, sorbitan ester, lanolin-based derivatives, glyceride, lignin With lignin derivative, maleic acid, protein-based surfactant, N, N- alkyltaurates, sulfosuccinate, N- alkane Base propane diamine, ethoxylation diamines, quaternary ammonium salt, ethoxylated amine etc..
Can be used for composition of the invention, can also be the mixing of nonionic surfactant and anion surfactant Thing, or nonionic surfactant and cationic surfactant mixture.Meanwhile, composition of the present invention may be used also Comprising it is known to those skilled in the art be the formulation auxiliary agents and additive of auxiliary agent, it is dilute that its purposes has been also considered as solid Release agent, liquid diluent or Action of Surfactant.In addition to such use, such auxiliary agent and the Main Function of additive Have：Buffering acid-base value, froth breaking reduces sedimentation, increases suspensibility, thickening, and anti-corrosion is antifreeze, dyeing, is coated, vaporization prevention etc. other Preparation attribute.Wherein, film forming agent may be selected from polyvinyl acetate and its copolymer, PVP-VA are common Polymers, polyvinyl alcohol and its copolymer and wax etc..
The Pesticidal combination is also optional comprising at least one additional biologically active cpds or reagent.In addition, not The possibility that nutrient for plants is added in above-mentioned composition is excluded, such as comprising the Fertilizer Combination of at least one nutrient for plants Thing, the nutrient for plants may be selected from nitrogen, phosphorus, potassium, Calcium Magnesium Sulphur, iron, copper, boron, molybdenum and zinc.
The active ingredient of Pesticidal combination of the invention can also be added as needed to less a kind of bactericide.
Involved in being disclosed such as the present invention, term " insect " includes ovum, larva and the adult of lepidoptera pest, brill moth Worm, casebearer, web spinner, loose Berry size, cabbage caterpillar, Pyralidae skele tonizer rolls up the leaf folder of Noctuidae, loxostege sticticalis, blattaria Purpose ovum, pupa and adult, the chafer of Scarabaeidae and other beetles, the ovum of Dermaptera, adult and larva, Semiptera and same wing Purpose ovum, immature body, adult and pupa（Such as Psyllidae wood louse, Aleyrodidae aleyrodid, Aphidiadae aphid）, the ovum of Acarina, larva, pupa And adult（Red mite and tetranychid, Tetranychus urticae such as Tetranychidae, the grape brevipalpus in Tenuipalpidae）, the ovum of Diptera, adult With immature body（Such as Liriomyza）, the invertebrate pests of the cereal of storage etc..
The example of agriculture and non-agricultural insect pest includes ovum, larva and the adult of lepidoptera pest, borer, casebearer, netting Caterpillar, loose Berry size, cabbage caterpillar, Pyralidae skele tonizer rolls up the leaf folder of Noctuidae, loxostege sticticalis, the ovum of Blattaria, pupa and into It is the ovum of worm, the chafer of Scarabaeidae and other beetles, the ovum of Dermaptera, adult and larva, Semiptera and Homoptera, immature Body, adult and pupa（Such as Psyllidae wood louse, Aleyrodidae aleyrodid, Aphidiadae aphid）, the ovum of Acarina, larva, pupa and adult（Such as tetranychid The red mite of section and tetranychid, Tetranychus urticae, the grape brevipalpus in Tenuipalpidae）, the ovum of Diptera, adult and immature body（Such as Liriomyza）, the invertebrate pests of the cereal of storage etc..Specific insect title for example corn borer, European corn borer, navel orangeworm, Beet armyworm, black cutworm, autumn armyworm, cotton leafworm, Anticarsia, lopper worm, cabbaze looper, tobacco aphid, tomato are small Borer, grape leaf folder, rice leaf roller, melon worm, yellow rice borer, oriental fruit months, rose band line volume noctuid, grape slurry Fruit moth, Cryptophlebia leucotreta, ligustrum fine tortricidae, diamondback moth, small heart-eating peach worm, phthorimaea operculella, American cockroach, grain weevil, Annual bluegrass weevil, black chafer, European red mite, apple aphid, wheat aphid, white backed planthopper, onion thrips etc..
Composition of the invention can mix multigroup to be formed with one or more other biologically active cpds or reagent Divide insecticide, so as to assign even broader spectrum of agricultural and non-agricultural purpose.The biologically active cpds or reagent, including Insecticide, bactericide, nematicide, acaricide, herbicide, herbicide-safener, growth regulator, chemosterilants, information Interferon, attractant etc..Therefore, the invention further relates to by formulaCompound, at least one annexing ingredient and at least one additional life The composition of thing reactive compound or reagent composition, the annexing ingredient is selected from surfactant, solid diluent and liquid Diluent.The present composition can be by its biologically active cpds or reagent and compound of the invention（Including formulaChemical combination Thing）Finished product preparation is configured to, or can be by its biologically active cpds or reagent and compound of the invention（Including formula's Compound）It is separately formulated, and before administration（For example in aerosol can）Two kinds of preparations are used in mixed way, or two kinds of preparations are made successively With.
" crops " include field crop（Such as corn and soybean, paddy rice, potato, sweet potato）, chamber crop（As lettuce, Kidney bean, eggplant, strawberry etc.）, industrial crops（Cherry, oranges and tangerines, banana, tomato, cucurbitaceous plant etc.）, potted plant crop（Without soil Culturing vegetable, there is native culturing vegetable etc.）Crop is produced etc. series of agricultural." non-crops " include forestry crop, nursery, view and admire A series of crop of non-agricultural purposes such as property flowers, lawn, room space.
In context disclosed by the invention, " pest control " refers to that pre- insect-pest occurs, and suppresses insect growth（Including dead Die, food ration declines and/or mating interference）, and the related expression of definition can be similar to.
Below in conjunction with specific embodiment, the invention will be further described.
The compound a of following examples is the material of Formulas I：
；
Embodiment 1
A kind of Pesticidal combination of novel pesticide, formulation is suspending agent, in parts by weight, including compound a 5%, acequinocyl 20%, Butyl polyoxyethylene block copolymer 3.5%, ethylene glycol copolymer 1.0%, styrene acrylic polmer 1.5%, xanthans 0.2%, propane diols 5.0%, silica 0.1%, BIT 0.2% and water supply surplus.
Embodiment 2
A kind of Pesticidal combination of novel pesticide, formulation is suspending agent, in parts by weight, including compound a 20%, fluorine worm carbonic ester 10%, Flusilazole 3.5%, butyl polyoxyethylene copolymer 4.0%, styrene acrylic polmer 1.5%, xanthans 0.2%, third Glycol 5.0%, silica 0.1%, BIT 0.2%, aromatic petroleum base hydrocarbon 20.0% and water are supplied remaining Amount.
Embodiment 3
A kind of Pesticidal combination of novel pesticide, formulation is microemulsion, in parts by weight, including compound a 2.0%, spiral shell worm ethyl ester 3.0%, PVP-VA copolymer 35.0%, alkyl polyglycoside 30.0%, monoolein 18.0% and water Supply surplus.
Embodiment 4
A kind of Pesticidal combination of novel pesticide, formulation is wettable powder, in parts by weight, including compound a 25%, ethiprole 25%, dodecyl phenol polyglycol ether 3.5%, sodium lignin sulfonate 4.0%, lagoriolite 5.5%, montmorillonite 2 5% and water 12%。
The synergy shown by two mixture of active principles can make these active components one or two While amount of application declines, it is ensured that good prevention effect.There is certain lasting effect more than expected effect after application, so that Be conducive to quickly killing insect, improve the death rate.The reduction of active component amount of application, reduces the cost of agricultural producer, and And chemically reactive substance residual in the environment is reduced, and environmental pressure is alleviated, improve foodsafety.
The presence of cooperative effect between two kinds of active components is can determine that by means of Colby formula：
P=A+B-AB/100；
Using Colby methods, by being primarily based on be administered alone two kinds of activity of component, the prediction activity P of mixture is calculated, The presence of cooperative interaction between to determine two kinds of active components.In above-mentioned formula, A is be administered alone with amount of application x Plant the bioactivity that component is represented with degree of preventing and treating percentage；B is the second component with amount of application y administrations with degree of preventing and treating percentage table The bioactivity shown.If it is adduction to be seen on their effect is strict, and in the absence of interaction, then the formula is applying The A and the expected bioactivity of the mixture of the B applied with amount of application y that amount x is applied calculate P.If the mixing set up in experiment More than expected activity, then there is synergistic function in P to the effect of thing.
It is below biology test example, the content displaying tested composition of the invention is prevented specific insect Control effect.Prevention effect represents the suppression to pest development, including dead, the described suppression of insect, including causes insect to ingest That measures substantially reduces.It will be understood by those skilled in the art that being not limited to these by the control of insect protection that the compound is provided Species.
Biology tests A
To evaluate the prevention effect to diamondback moth, test unit is made up of the interior small open container for having 12-14 days ages radish plants. Using the inoculator with auger conveyor, with about 50 newborn larvaes being dispersed in via corn cob grits in test unit by its Infect in advance.After being distributed in test unit, the larva is moved on test plant.
Test-compound and composition are prepared using the solution comprising nonionic surfactant.The compound of preparation and Composition, in each test unit applied on top 1ml liquid, will be tested in triplicate by sprayer.Testedization that will be prepared After compound or composition spray, each test unit is dried 1 hour, black square is then placed on top.Make test sheet Unit holding 6 days in the growth room of 25 DEG C and 70% relative humidity, are then based on ingested leaf visual assessment plant and ingest damage Evil.
Calculate the average value of result in triplicate, and will calculate that the results are shown in Table 1.Wherein compound a with 0.1ppm dosage is applied.
Prevention effect table of the table 1 to diamondback moth
* desired value using Colby formula based on being calculated.
The prevention effect of composition is can be seen that more than desired value, compound from the prevention effect table to diamondback moth of table 1 A and insecticide b have synergistic function.
Biology test b
To evaluate the prevention effect to black peach aphid, it is made up of 12 ~ 15 day small open container of age radish plants in test unit, is passed through 30 ~ 40 aphids being located on a piece of blade cut from cultivated plant are placed on the leaf of test plant, by institute Plant is stated to contaminate in advance.With leaf abscission, aphid is moved in test plants, after contaminating in advance, experiment is covered with one layer of sand The soil of unit.
Prepared as described in testing A and sprayed test-compound and composition.To test in triplicate, it is tested by what is prepared After compound or composition spray, each test unit is dried 1 hour, black square is then placed into top, make experiment , at 25 DEG C, in the growth room of 70% relative humidity holding 6 days, then the insect mortality of each test cell of visual evaluation for unit.
Result average value in triplicate is calculated, and by the results are shown in Table 2, compound a is applied with 0.1ppm dosage.
Prevention effect table of the table 2 to black peach aphid
* desired value using Colby formula based on being calculated.
The prevention effect of composition is can be seen that to the prevention effect of black peach aphid more than desired value from table 2, compound a and is killed Worm agent b has synergistic function.
Field test A
To evaluate the prevention effect of compound a and pymetrozine to cabbage aphid, in cabbage aphid early period of origination, by compound a and Pyrrole aphid is configured to suspending agent, is uniformly sprayed on cabbage leaves according to liquid point cell is converted into using various dose, sees on time Examine drug effect to be counted, test of pesticide effectiveness result is as shown in table 3.
The prevention effect table of the compound a of table 3 and pymetrozine to cabbage aphid
Compound a can be seen that to the prevention effect of cabbage aphid by the compound a of table 3 and pymetrozine and pymetrozine is applied in combination Prevention effect significantly better than the effect that compound a and pymetrozine are used alone, both can produce obvious Synergistic to make With.
Field test B
To evaluate the prevention effect of compound a and MTI-446 to rice hoppers, in planthopper early period of origination, by compound a and MTI-446 is configured to suspending agent, is uniformly sprayed on paddy rice according to liquid point cell is converted into using various dose, and medicine is observed on time Effect is counted, and test of pesticide effectiveness result is as shown in table 4.
The prevention effect table of the compound a of table 4 and MTI-446 to rice hoppers
Compound a is can be seen that to the prevention effect of rice hoppers by the compound a of table 4 and MTI-446 and MTI-446 is combined and made Significantly better than the effect that compound a and MTI-446 are used alone, both can produce obvious Synergistic to prevention effect Effect.

Claims (9)

1. a kind of Pesticidal combination of novel pesticide, it is characterised in that：Its active ingredient is comprising the compound a that structural formula is I and extremely A kind of few insecticide b；
The structural formula I of described compound a is as follows,
Structural formula I；
Described insecticide b is that acequinocyl, fluorine worm carbonic ester, pyrrole fluorine mite amine, acetyl worm nitrile, fluacrypyrim, pyridine are muttered the third worm of ring ester, pyridine Worm propyl ether, sulfanilamide (SN) mite ester, fipronil bisamide, the pyridine of pyrazoles worm, kill line thiazole, fluorine thiophene worm sulfone, pyriminostrobin, bistrifluron, fluorine bacterium Mite ester, pyrrole fluorine quinoline worm azoles, chlorantraniliprole, pyrazine ethiprole, ethyl pleocidin, ring tebufenozide, more pyridine MTI-446, sterilization Element, clothianidin, gamma cyhalothrin, Envidor, bromine cyanogen insect amide, cyanogen imidazoles sulphur phosphorus, Spiromesifen, spiral shell worm ethyl ester, nitrile pyrrole Mite ester, thunder cuticulin, sulfoxaflor, flonicamid, fluorine chlorine ether chrysanthemum ester, etrafluorine ethofenprox, flufenzine, metaflumizone, thiophene Worm quinoline, dimefluthrin, methoxyfenozide, Diacloden, MTI-446, metofluthrin, desinsection bisgallic acid, ethiprole, polyfluoro Urea, Tolfenpyrad, acrinathrin, Acetamiprid, AVM, emamectin benzoate, Rynaxypyr, indoxacarb, pyrrole worm Quinoline, pymetrozine, fipronil bisamide, pyrrole fluorine quinoline worm azoles, etoxazole, paichongding, Nitenpyram, metaflumizone, fluorobenzene insect amide, four Chlorantraniliprole, butene-fipronil, bromine cyanogen insect amide or ring tebufenozide.
2. the Pesticidal combination of novel pesticide according to claim 1, it is characterised in that：Described insecticide b is alkene pyridine worm Amine, pymetrozine, Acetamiprid, etoxazole, AVM or Rynaxypyr.
3. the Pesticidal combination of novel pesticide according to claim 1, it is characterised in that：The quality of compound a and insecticide b Than being 1 ~ 20：20~1.
4. the Pesticidal combination of novel pesticide according to claim 1, it is characterised in that：Desinsection of the active ingredient in novel pesticide The content of composition is 0.001 ~ 99.999%.
5. the Pesticidal combination of novel pesticide according to claim 3, it is characterised in that：The quality of compound a and insecticide b Than being 1：1.
6. the Pesticidal combination of novel pesticide according to claim 4, it is characterised in that：Desinsection of the active ingredient in novel pesticide The content of composition is 50%.
7. the Pesticidal combination of novel pesticide according to claim 1, it is characterised in that：The formulation of the Pesticidal combination is agriculture The formulation allowed in industry production.
8. the Pesticidal combination of novel pesticide according to claim 1, it is characterised in that：Described formulation is suspending agent, micro- Capsule suspending agent, microcapsule suspension-suspendinagent agent, suspension emulsion, missible oil, aqua, pulvis, water dispersible granules, granule, dry suspending agent, kind Clothing agent, suspension seed-coating agent, Seed Treatment emulsion, tablet, effervescent agent or fumigant.
9. the Pesticidal combination of novel pesticide according to claim 1, it is characterised in that：Described formulation is wettable powder Agent, in parts by weight, including compound a 25%, ethiprole 25%, dodecyl phenol polyglycol ether 3.5%, lignin sulfonic acid Sodium 4.0%, lagoriolite 5.5%, montmorillonite 2 5% and water 12%.
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CN107711869A (en) * 2017-11-28 2018-02-23 广东真格生物科技有限公司 A kind of Pesticidal combination containing fourth chlorantraniliprole and indoxacarb and its application
CN107980789A (en) * 2017-11-28 2018-05-04 广东真格生物科技有限公司 A kind of Pesticidal combination containing fourth chlorantraniliprole and its application
CN108308174A (en) * 2018-02-05 2018-07-24 广东真格生物科技有限公司 A kind of Pesticidal combination and its preparation containing fourth chlorantraniliprole and d ichlorbenzuron
CN114303860A (en) * 2021-12-31 2022-04-12 江西省林业科学院 A method for mixed afforestation of Chinese fir and nanmu
CN115005221A (en) * 2022-07-04 2022-09-06 中国农业大学开封实验站 Pesticide composition for preventing and treating wheat aphids
CN116264894A (en) * 2021-12-17 2023-06-20 湖南化工研究院有限公司 Preparation and application of 1-pyridylpyrazole amide compound

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CN101600682A (en) * 2006-07-19 2009-12-09 杜邦公司 Process for preparing 3-substituted 2-amino-5-halobenzamides
CN104003976A (en) * 2014-05-07 2014-08-27 肇庆市真格生物科技有限公司 Polysubstituted pyridyl pyrazole amide and its preparation method and use

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CN100391338C (en) * 2001-08-13 2008-06-04 纳幕尔杜邦公司 anthranilamide
CN101600682A (en) * 2006-07-19 2009-12-09 杜邦公司 Process for preparing 3-substituted 2-amino-5-halobenzamides
CN104003976A (en) * 2014-05-07 2014-08-27 肇庆市真格生物科技有限公司 Polysubstituted pyridyl pyrazole amide and its preparation method and use

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107711869A (en) * 2017-11-28 2018-02-23 广东真格生物科技有限公司 A kind of Pesticidal combination containing fourth chlorantraniliprole and indoxacarb and its application
CN107980789A (en) * 2017-11-28 2018-05-04 广东真格生物科技有限公司 A kind of Pesticidal combination containing fourth chlorantraniliprole and its application
CN108308174A (en) * 2018-02-05 2018-07-24 广东真格生物科技有限公司 A kind of Pesticidal combination and its preparation containing fourth chlorantraniliprole and d ichlorbenzuron
CN116264894A (en) * 2021-12-17 2023-06-20 湖南化工研究院有限公司 Preparation and application of 1-pyridylpyrazole amide compound
CN114303860A (en) * 2021-12-31 2022-04-12 江西省林业科学院 A method for mixed afforestation of Chinese fir and nanmu
CN115005221A (en) * 2022-07-04 2022-09-06 中国农业大学开封实验站 Pesticide composition for preventing and treating wheat aphids
CN115005221B (en) * 2022-07-04 2023-10-13 中国农业大学开封实验站 Pesticide composition for preventing and controlling wheat aphids

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