CN106758408A - A kind of blend polyester dyeing fabric liquid and preparation method thereof - Google Patents
A kind of blend polyester dyeing fabric liquid and preparation method thereof Download PDFInfo
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- CN106758408A CN106758408A CN201611180582.1A CN201611180582A CN106758408A CN 106758408 A CN106758408 A CN 106758408A CN 201611180582 A CN201611180582 A CN 201611180582A CN 106758408 A CN106758408 A CN 106758408A
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- 239000004744 fabric Substances 0.000 title claims abstract description 74
- 238000004043 dyeing Methods 0.000 title claims abstract description 66
- 239000000203 mixture Substances 0.000 title claims abstract description 58
- 229920000728 polyester Polymers 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- 239000007788 liquid Substances 0.000 title claims abstract description 33
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 26
- 235000011187 glycerol Nutrition 0.000 claims abstract description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 16
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 15
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 claims abstract description 15
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 15
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims abstract description 15
- 229960001484 edetic acid Drugs 0.000 claims abstract description 15
- 239000011790 ferrous sulphate Substances 0.000 claims abstract description 15
- 235000003891 ferrous sulphate Nutrition 0.000 claims abstract description 15
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 15
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims abstract description 15
- 239000010446 mirabilite Substances 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 15
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- 239000011812 mixed powder Substances 0.000 claims abstract description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 25
- 229920004933 Terylene® Polymers 0.000 claims description 24
- 239000003093 cationic surfactant Substances 0.000 claims description 16
- 101710123874 Protein-glutamine gamma-glutamyltransferase Proteins 0.000 claims description 12
- 150000003242 quaternary ammonium salts Chemical group 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- 239000000052 vinegar Substances 0.000 claims description 6
- 235000021419 vinegar Nutrition 0.000 claims description 6
- 210000002268 wool Anatomy 0.000 claims description 6
- 229920002334 Spandex Polymers 0.000 claims description 5
- 239000004759 spandex Substances 0.000 claims description 5
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 125000005233 alkylalcohol group Chemical group 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 150000001768 cations Chemical group 0.000 claims 1
- 150000001805 chlorine compounds Chemical class 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- AYAUBWSUZRFVQO-UHFFFAOYSA-N 2-[2-(4-phenyl-5-sulfanylidene-1h-1,2,4-triazol-3-yl)ethyl]benzo[de]isoquinoline-1,3-dione Chemical compound O=C1C(C=23)=CC=CC3=CC=CC=2C(=O)N1CCC1=NNC(=S)N1C1=CC=CC=C1 AYAUBWSUZRFVQO-UHFFFAOYSA-N 0.000 abstract description 4
- 238000004383 yellowing Methods 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 abstract description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 239000000835 fiber Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 239000003643 water by type Substances 0.000 description 9
- 235000019270 ammonium chloride Nutrition 0.000 description 7
- 238000012545 processing Methods 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 229920000647 polyepoxide Polymers 0.000 description 5
- 150000003841 chloride salts Chemical class 0.000 description 4
- 239000000975 dye Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 206010003549 asthenia Diseases 0.000 description 2
- 210000004209 hair Anatomy 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- XEGMDUOAESTQCC-UHFFFAOYSA-N 1-(naphthalen-1-ylmethyl)naphthalene;sodium Chemical compound [Na].C1=CC=C2C(CC=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1 XEGMDUOAESTQCC-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229920000433 Lyocell Polymers 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 108060008539 Transglutaminase Proteins 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- NMYPVNCHTWFDNI-UHFFFAOYSA-L disodium naphthalene-1-sulfonate Chemical compound [Na+].[Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1.C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 NMYPVNCHTWFDNI-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 238000005935 nucleophilic addition reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 102000003601 transglutaminase Human genes 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8276—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing ester groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
- D06P1/625—Aromatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
- D06P1/66—Compounds containing ammonium groups containing quaternary ammonium groups
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of blend polyester dyeing fabric liquid and preparation method thereof, comprise the following steps：（1）In the mixed-powder of cobaltous sulfate, ferrous sulfate and glauber salt, deionized water is added, maintain temperature at 30 ~ 55 DEG C, stir 0.5 ~ 1.5h;（2）In step（1）In the material for obtaining, first add glycerine to be well mixed, add oxydiphthalic, AEO, trimethylolpropane, antifebrin and ethylenediamine tetra-acetic acid two and receive, maintain temperature at 40 ~ 65 DEG C, process 1.5 ~ 4h；（3）In step（2）Catalyst, modifying agent, diffusant and surfactant are added in the material for obtaining, temperature is maintained in 25 ~ 40 DEG C, 0.5 ~ 2h of ultrasonic reaction.The dyeing liquor provided by preparation method of the invention, the dyeing temperature of polyester blended fabric can not only be reduced, low salt dyeing is realized, moreover it is possible to improve dye-uptake, level-dyeing property and the color fastness of polyester blended fabric, while the flexibility of fabric, antistatic behaviour, anti-yellowing property and bactericidal properties can also be improved.
Description
Technical field
The present invention relates to weaving face fabric processing technology field, more particularly to a kind of blend polyester dyeing fabric liquid preparation side
Method.
Background technology
At present, the conventional fabric of in the market weaving face fabric is most based on cotton, terylene, polyamide fibre and regenerated celulose fibre,
Although these fabrics can meet the demand of people substantially, some shortcomings are there is also.Such as, dacron has good heat-resisting
Property, but its hygroscopicity is poor, and electrostatic phenomenon is serious, is a kind of hard-packed hydrophobic fibre mainly due to polyster fibre, point
Without specific dye radical in son, lack hydrophily, expanded level is low in water, and certain difficulty is brought to dyeing.
In recent years, continuing to bring out with tencel, multi-component fibre compound fabric application is more extensive, such as terylene and sheep
The fiber mixed fabrics such as hair, silk, vinegar fibre, spandex make fabric have unique style due to having gathered the advantage of various fibers,
Increasingly favored by consumer.But, there is difficult, the easy staining of colouring, easily in dyeing process in multicomponent blend fabric
Damage, level-dyeing property is poor, the low problem of color fastness.In order that blend fabric is easily painted and uniform, it usually needs add a large amount of salt
Promote dye, increased sewage disposal difficulty, environment can be caused harm.Therefore, a kind of blend polyester fabric dyeing of research and development is needed badly
Color liquid and preparation method thereof.
The content of the invention
Paint that difficult, easy staining, easy damaged, level-dyeing property be poor, the low problem of color fastness to solve blend polyester fabric,
Invention first aspect provides a kind of blend polyester dyeing fabric liquid and preparation method thereof, comprises the following steps：
(1) in the mixed-powder of cobaltous sulfate, aluminum sulfate, ferrous sulfate and glauber salt, deionized water is added, maintains temperature 30
~55 DEG C, stir 0.5~1.5h；
(2) in the material that step (1) is obtained, first add glycerine and glycerine well mixed, add oxydiphthalic,
AEO, trimethylolpropane, antifebrin and ethylenediamine tetra-acetic acid two are received, and maintain temperature at 40~65 DEG C,
1.5~4h for the treatment of；
(3) catalyst, modifying agent, diffusant and surfactant are added in the material that step (2) is obtained, temperature is maintained 25
~40 DEG C, 0.5~2h of ultrasonic reaction.
Preferably,
In the step (1), maintain temperature at 35~45 DEG C, stir 0.5~1h；
In the step (2), maintain temperature at 45~55 DEG C, process 2~3h；
In the step (3), temperature is maintained in 28~35 DEG C, 1~1.5h of ultrasonic reaction.
Wherein, described catalyst is TGase.
Wherein, described modifying agent is made up of shitosan and 2,3- epoxypropyltrimethylchloride chloride.
Wherein, described diffusant is sodium metnylene bis-naphthalene sulfonate.
Wherein, described surfactant is cationic surfactant.
Wherein, described cationic surfactant is quaternary ammonium salt cationic surfactant.
Wherein, in described blend polyester fabric is terylene, spandex fine with wool, silk, vinegar any one or it is several
Plant the mixed goods of composition.
Wherein, in described mixed goods, the weight ratio of terylene is 40%~90%.
Preferably, the weight ratio of terylene is 60%~80%.
It is further preferred that the weight ratio of terylene is 62%, 65%, 68%, 70%, 72%, 75%, 78%.
Second aspect present invention provides a kind of dyeing liquor prepared by above-mentioned preparation method, and the dyeing liquor is by weight
Amount part meter is composed of the following components：0.5~1.5 part of cobaltous sulfate, 1~2 part of ferrous sulfate, 0.5~1 part of glauber salt, glycerine 3~5
Part, 3~5 parts of oxydiphthalic, 2~4 parts of AEO, 2~6 parts of trimethylolpropane, antifebrin 1~
5 parts, ethylenediamine tetra-acetic acid two receives 2~4 parts, 0.5~2 part of catalyst, 3~6 parts of modifying agent, 2~3 parts of diffusant, surface-active
2~6 parts of agent.
Beneficial effects of the present invention：
First aspect present invention adds TGase to be used as catalyst by dyeing liquor, can not only be in blend polyester
Network structure is formed in fabric, plays a part of to improve molecular functional, it is to avoid fabric is led due to damaging in dyeing course
Cause Color to be deteriorated, improve dye-uptake；Dyeing temperature can also be reduced simultaneously, from 120~140 DEG C of drops of existing dyeing temperature
To 80~105 DEG C.
Second aspect present invention adds shitosan and 2,3- epoxypropyltrimethylchloride chlorides to be used as by dyeing liquor
Modifying agent, on the one hand due to shitosan in acidic aqueous solution can and H+With reference to and there is electropositive and good water solubility；
On the other hand quaternary ammonium salt structure is introduced in chitosan molecule, it can be made to obtain good water solubility, and can be in larger pH value
In the range of apply；In addition with polyester blended fabric there is the reactivity worth of nucleophilic addition in shitosan in the basic conditions, from
And the binding strength with polyster fibre is improved, such that it is able to improve dye-uptake, realize low salt dyeing.
Third aspect present invention adds sodium metnylene bis-naphthalene sulfonate to be used as diffusant by dyeing liquor, can avoid washing
Synthetic fibre blend fabric molecular structure hinders diffusion of the dyestuff in fabric, can not only improve the dye-uptake of fabric, level-dyeing property and color jail
Degree, moreover it is possible to reduce the strength loss of fabric.
Fourth aspect present invention adds quaternary ammonium salt cationic surfactant by blend polyester dyeing fabric liquid,
Flexibility, the antistatic behaviour of polyester blended fabric are improve, while also having excellent anti-yellowing property and bactericidal properties.
Specific embodiment
The following is the preferred embodiment of the present invention, it is noted that for those skilled in the art,
Under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications are also considered as this hair
Bright protection domain.
The invention provides a kind of blend polyester dyeing fabric liquid and preparation method thereof, comprise the following steps：
(1) in the mixed-powder of cobaltous sulfate, aluminum sulfate, ferrous sulfate and glauber salt, deionized water is added, maintains temperature 30
~55 DEG C, stir 0.5~1.5h；
(2) in the material that step (1) is obtained, first add glycerine and glycerine well mixed, add oxydiphthalic,
AEO, trimethylolpropane, antifebrin and ethylenediamine tetra-acetic acid two are received, and maintain temperature at 40~65 DEG C,
1.5~4h for the treatment of；
(3) catalyst, modifying agent, diffusant and surfactant are added in the material that step (2) is obtained, temperature is maintained 25
~40 DEG C, 0.5~2h of ultrasonic reaction.
Preferably,
In the step (1), maintain temperature at 35~45 DEG C, stir 0.5~1h；
In the step (2), maintain temperature at 45~55 DEG C, process 2~3h；
In the step (3), temperature is maintained in 28~35 DEG C, 1~1.5h of ultrasonic reaction.
In embodiments of the present invention, described catalyst is TGase, described modifying agent by shitosan and
2,3- epoxypropyltrimethylchloride chlorides are constituted, and described diffusant is sodium metnylene bis-naphthalene sulfonate, described surfactant
It is cationic surfactant.
Preferably, described cationic surfactant is quaternary ammonium salt cationic surfactant.
In embodiments of the present invention, described blend polyester fabric is in terylene and wool, silk, vinegar fibre, spandex
The mixed goods of any one or several compositions, the weight ratio of terylene is 40%~90% in described mixed goods.
Preferably, the weight ratio of terylene is 60%~80%.
It is further preferred that the weight ratio of terylene is 62%, 65%, 68%, 70%, 72%, 75%, 78%.
Embodiment 1
The blend polyester fabric that this embodiment of the invention is used is terylene and the blend fabric of wool, and the weight ratio of wherein terylene is
60%, use medicine by weight.
A kind of blend polyester dyeing fabric liquid and preparation method thereof of the invention, comprises the following steps：
(1) 0.5 part of cobaltous sulfate is taken, 1 part of ferrous sulfate, 0.5 part of glauber salt adds 10 parts of deionized waters, is 35 DEG C in temperature, stirs
Mix 0.5h；
(2) in the material that step (1) is obtained, first add 3 parts of glycerine to be well mixed, add 3 parts of oxydiphthalic, fat
2 parts of fat alcohol APEO, 3 parts of trimethylolpropane, 4 parts of antifebrin, ethylenediamine tetra-acetic acid two receives 2 parts, maintains temperature to exist
45 DEG C, process 2h；
(3) 1 part of TGase, 2 parts of shitosan, 2,3- epoxies are added in the material that step (2) is obtained
3 parts of ammonium chloride, 2 parts of sodium metnylene bis-naphthalene sulfonate, 4 parts of quaternary ammonium salt cationic surfactant maintains temperature in 30 DEG C, ultrasonic reaction
1h。
Embodiment 2
The blend polyester fabric that this embodiment of the invention is used is terylene and wool and the fine blend fabric of vinegar, the wherein weight of terylene
Amount uses medicine by weight than being 65%.
A kind of blend polyester dyeing fabric liquid and preparation method thereof of the invention, comprises the following steps：
(1) 1 part of cobaltous sulfate is taken, 1.5 parts of ferrous sulfate, 0.8 part of glauber salt adds 10 parts of deionized waters, is 38 DEG C in temperature, stirs
Mix 1h；
(2) in the material that step (1) is obtained, first add 4 parts of glycerine to be well mixed, add 4 parts of oxydiphthalic, fat
3 parts of fat alcohol APEO, 4 parts of trimethylolpropane, 3 parts of antifebrin, ethylenediamine tetra-acetic acid two receives 4 parts, maintains temperature to exist
50 DEG C, process 2.5h；
(3) 2 parts of TGase, 1 part of shitosan, 2,3- epoxies are added in the material that step (2) is obtained
3 parts of ammonium chloride, 3 parts of sodium metnylene bis-naphthalene sulfonate, 5 parts of quaternary ammonium salt cationic surfactant maintains temperature in 32 DEG C, ultrasonic reaction
1.2h。
Embodiment 3
The blend polyester fabric that this embodiment of the invention is used is terylene and the blend fabric of silk and spandex, the wherein weight of terylene
Amount uses medicine by weight than being 70%.
A kind of blend polyester dyeing fabric liquid and preparation method thereof of the invention, comprises the following steps：
(1) 0.5 part of cobaltous sulfate is taken, 1 part of ferrous sulfate, 1 part of glauber salt adds 10 parts of deionized waters, is 40 DEG C in temperature, stirring
0.5h；
(2) in the material that step (1) is obtained, first add 4 parts of glycerine to be well mixed, add 4 parts of oxydiphthalic, fat
4 parts of fat alcohol APEO, 3 parts of trimethylolpropane, 4 parts of antifebrin, ethylenediamine tetra-acetic acid two receives 4 parts, maintains temperature to exist
50 DEG C, process 3h；
(3) 0.5 part of TGase, 3 parts of shitosan, 2,3- glycidyl front threes are added in the material that step (2) is obtained
3 parts of ammonium chloride, 2 parts of sodium metnylene bis-naphthalene sulfonate, 4 parts of quaternary ammonium salt cationic surfactant maintains temperature in 35 DEG C, ultrasonic reaction
1.5h。
Embodiment 4
The blend polyester fabric that this embodiment of the invention is used is terylene and the fine blend fabric of vinegar, and the weight ratio of wherein terylene is
75%, use medicine by weight.
A kind of blend polyester dyeing fabric liquid and preparation method thereof of the invention, comprises the following steps：
(1) 1.5 parts of cobaltous sulfate is taken, 1 part of ferrous sulfate, 0.5 part of glauber salt adds 10 parts of deionized waters, is 45 DEG C in temperature, stirs
Mix 0.8h；
(2) in the material that step (1) is obtained, first add 5 parts of glycerine to be well mixed, add 3 parts of oxydiphthalic, fat
2 parts of fat alcohol APEO, 4 parts of trimethylolpropane, 4 parts of antifebrin, ethylenediamine tetra-acetic acid two receives 2 parts, maintains temperature to exist
50 DEG C, process 2h；
(3) 1.5 parts of TGase, 2 parts of shitosan, 2,3- glycidyl front threes are added in the material that step (2) is obtained
4 parts of ammonium chloride, 3 parts of sodium metnylene bis-naphthalene sulfonate, 5 parts of quaternary ammonium salt cationic surfactant maintains temperature in 30 DEG C, ultrasonic reaction
1.2h。
Embodiment 5
The blend polyester fabric that this embodiment of the invention is used is terylene and the blend fabric of silk, and the weight ratio of wherein terylene is
80%, use medicine by weight.
A kind of blend polyester dyeing fabric liquid and preparation method thereof of the invention, comprises the following steps：
(1) 1.2 parts of cobaltous sulfate is taken, 1 part of ferrous sulfate, 0.8 part of glauber salt adds 10 parts of deionized waters, is 45 DEG C in temperature, stirs
Mix 1h；
(2) in the material that step (1) is obtained, first add 5 parts of glycerine to be well mixed, add 4 parts of oxydiphthalic, fat
3 parts of fat alcohol APEO, 5 parts of trimethylolpropane, 4 parts of antifebrin, ethylenediamine tetra-acetic acid two receives 3 parts, maintains temperature to exist
55 DEG C, process 2h；
(3) 2 parts of TGase, 3 parts of shitosan, 2,3- epoxies are added in the material that step (2) is obtained
2 parts of ammonium chloride, 2 parts of sodium metnylene bis-naphthalene sulfonate, 4 parts of quaternary ammonium salt cationic surfactant maintains temperature in 35 DEG C, ultrasonic reaction
1.5h。
The dyeing liquor that the dyeing liquid and preparation method thereof provided using the present invention is obtained refers to for processing polyester blended fabric performance
Mark is shown in Table 1.
The different embodiment dyeability test results of table 1
From table 1 knowable to the performance test results of each embodiment, the dyeing liquor that the dyeing liquid and preparation method thereof that the present invention is provided is obtained
For polyester blended fabric dyeing, with color fastness it is excellent, strength loss is small, dye-uptake is high and the low Optimality of dyeing temperature
Energy.
In order to verify the effect of the embodiment of the present invention, the present invention with embodiment 1 as reference, there is provided comparative example.
Comparative example 1
A kind of blend polyester dyeing fabric liquid and preparation method thereof of the invention, comprises the following steps：
(1) 0.5 part of cobaltous sulfate is taken, 1 part of ferrous sulfate, 0.5 part of glauber salt adds 10 parts of deionized waters, is 35 DEG C in temperature, stirs
Mix 0.5h；
(2) in the material that step (1) is obtained, first add 3 parts of glycerine to be well mixed, add 3 parts of oxydiphthalic, fat
2 parts of fat alcohol APEO, 3 parts of trimethylolpropane, 4 parts of antifebrin, ethylenediamine tetra-acetic acid two receives 2 parts, maintains temperature to exist
45 DEG C, process 2h；
(3) 2 parts of shitosan, 2,3- 3 parts of epoxypropyltrimethylchloride chlorides, methylene are added in the material that step (2) is obtained
2 parts of sodium dinaphthalenesulfonate, 4 parts of quaternary ammonium salt cationic surfactant maintains temperature in 30 DEG C, ultrasonic reaction 1h.
Comparative example 2
A kind of blend polyester dyeing fabric liquid and preparation method thereof of the invention, comprises the following steps：
(1) 0.5 part of cobaltous sulfate is taken, 1 part of ferrous sulfate, 0.5 part of glauber salt adds 10 parts of deionized waters, is 35 DEG C in temperature, stirs
Mix 0.5h；
(2) in the material that step (1) is obtained, first add 3 parts of glycerine to be well mixed, add 3 parts of oxydiphthalic, fat
2 parts of fat alcohol APEO, 3 parts of trimethylolpropane, 4 parts of antifebrin, ethylenediamine tetra-acetic acid two receives 2 parts, maintains temperature to exist
45 DEG C, process 2h；
(3) 1 part of TGase, 2 parts of sodium metnylene bis-naphthalene sulfonate, quaternary are added in the material that step (2) is obtained
4 parts of surfactant, maintains temperature in 30 DEG C, ultrasonic reaction 1h.
Comparative example 3
A kind of blend polyester dyeing fabric liquid and preparation method thereof of the invention, comprises the following steps：
(1) 0.5 part of cobaltous sulfate is taken, 1 part of ferrous sulfate, 0.5 part of glauber salt adds 10 parts of deionized waters, is 35 DEG C in temperature, stirs
Mix 0.5h；
(2) in the material that step (1) is obtained, first add 3 parts of glycerine to be well mixed, add 3 parts of oxydiphthalic, fat
2 parts of fat alcohol APEO, 3 parts of trimethylolpropane, 4 parts of antifebrin, ethylenediamine tetra-acetic acid two receives 2 parts, maintains temperature to exist
45 DEG C, process 2h；
(3) 1 part of TGase, 2 parts of shitosan, 2,3- epoxies are added in the material that step (2) is obtained
3 parts of ammonium chloride, 4 parts of quaternary ammonium salt cationic surfactant maintains temperature in 30 DEG C, ultrasonic reaction 1h.
Comparative example 4
A kind of blend polyester dyeing fabric liquid and preparation method thereof of the invention, comprises the following steps：
(1) 0.5 part of cobaltous sulfate is taken, 1 part of ferrous sulfate, 0.5 part of glauber salt adds 10 parts of deionized waters, is 35 DEG C in temperature, stirs
Mix 0.5h；
(2) in the material that step (1) is obtained, first add 3 parts of glycerine to be well mixed, add 3 parts of oxydiphthalic, fat
2 parts of fat alcohol APEO, 3 parts of trimethylolpropane, 4 parts of antifebrin, ethylenediamine tetra-acetic acid two receives 2 parts, maintains temperature to exist
45 DEG C, process 2h；
(3) 1 part of TGase, 2 parts of shitosan, 2,3- epoxies are added in the material that step (2) is obtained
3 parts of ammonium chloride, 2 parts of sodium metnylene bis-naphthalene sulfonate maintains temperature in 30 DEG C, ultrasonic reaction 1h.
The blend polyester fabric that comparative example of the present invention uses is terylene and the blend fabric of wool, the wherein weight of terylene
Than being 60%, the dyeing liquor that embodiment 1 and comparative example 1-4 are prepared is used to process above-mentioned polyester blended fabric amount
Energy index is shown in Table 2.
The embodiment 1 of table 2 and comparative example's 1-4 dyeability test results
From table 2 knowable to the performance test results of each comparative example：
The dyeing liquor that the dyeing liquid and preparation method thereof provided using comparative example 1 is prepared (lacks catalyst transglutamin-ase 9
Enzyme) processing above-mentioned fabrics, when dyeing temperature brings up to 125~138 DEG C, fabric dye-uptake can be only achieved 90~94%；
Using comparative example 2 provide dyeing liquid and preparation method thereof prepare dyeing liquor (lack modifying agent shitosan and 2,
3- epoxypropyltrimethylchloride chlorides) processing above-mentioned fabrics, colour fastness to rubbing and fastness to soaping are all substantially reduced；
The dyeing liquor that the dyeing liquid and preparation method thereof provided using comparative example 3 is prepared (lacks diffusant methylene dinaphthalene
Sodium sulfonate) processing above-mentioned fabrics, than larger, strength rate of descent is 24.35% to strength loss；
The dyeing liquor that the dyeing liquid and preparation method thereof provided using comparative example 4 is prepared (lacks quaternary surface-active
Agent) processing above-mentioned fabrics, strength rate of descent has been increased to 19.82%, the flexibility of fabric, antistatic behaviour, anti-yellowing property and kills
Bacterium property all decreases with respect to embodiment 1.
It follows that containing catalyst, modifying agent, diffusant and surface-active simultaneously in the dyeing liquor of present invention offer
Agent, can substantially reduce dyeing temperature, improve dye-uptake and color fastness, reduce strength loss of the fabric in dyeing course, carry
The flexibility of fabric high, antistatic behaviour, anti-yellowing property and bactericidal properties.
Above example only expresses one embodiment of the present invention, and its description is more specific and detailed, but can not
Therefore it is interpreted as the limitation to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art,
Without departing from the inventive concept of the premise, various modifications and improvements can be made, these are all belonging to protection of the invention
Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. a kind of blend polyester dyeing fabric liquid and preparation method thereof, it is characterised in that comprise the following steps：
（1）In the mixed-powder of cobaltous sulfate, ferrous sulfate and glauber salt, deionized water is added, maintains temperature at 30 ~ 55 DEG C,
0.5 ~ 1.5h of stirring;
（2）In step（1）In the material for obtaining, first add glycerine to be well mixed, add oxydiphthalic, poly alkyl alcohol
Oxygen vinethene, trimethylolpropane, antifebrin and ethylenediamine tetra-acetic acid two are received, and maintain temperature at 40 ~ 65 DEG C, and treatment 1.5 ~
4h；
（3）In step（2）Catalyst, modifying agent, diffusant and surfactant are added in the material for obtaining, temperature is maintained 25
~ 40 DEG C, 0.5 ~ 2h of ultrasonic reaction.
2. blend polyester dyeing fabric liquid and preparation method thereof according to claim 1, it is characterised in that：
The step（1）In, maintain temperature at 35 ~ 45 DEG C, stir 0.5 ~ 1h；
The step（2）In, maintain temperature at 45 ~ 55 DEG C, process 2 ~ 3h；
The step（3）In, temperature is maintained in 28 ~ 35 DEG C, 1 ~ 1.5h of ultrasonic reaction.
3. blend polyester dyeing fabric liquid and preparation method thereof according to claim 1, it is characterised in that：Described catalyst is
TGase.
4. blend polyester dyeing fabric liquid and preparation method thereof according to claim 1, it is characterised in that：Described modifying agent by
Shitosan and 2,3- epoxypropyltrimethylchloride chlorides are constituted.
5. blend polyester dyeing fabric liquid and preparation method thereof according to claim 1, it is characterised in that：Described diffusant is
Sodium metnylene bis-naphthalene sulfonate.
6. blend polyester dyeing fabric liquid and preparation method thereof according to claim 1, it is characterised in that：Described surface-active
Agent is cationic surfactant.
7. blend polyester dyeing fabric liquid and preparation method thereof according to claim 6, it is characterised in that：Described cation form
Face activating agent is quaternary ammonium salt cationic surfactant.
8. the blend polyester dyeing fabric liquid and preparation method thereof according to any one claim in claim 1 ~ 7, it is special
Levy and be：Any one in described blend polyester fabric is terylene, spandex fine with wool, silk, vinegar or several compositions
Mixed goods.
9. blend polyester dyeing fabric liquid and preparation method thereof according to claim 8, it is characterised in that：Described mixed goods
In, the weight ratio of terylene is 40% ~ 90%.
10. prepared by the blend polyester dyeing fabric liquid and preparation method thereof according to any one claim in claim 1 ~ 7
The dyeing liquor for obtaining, it is characterised in that described dyeing liquor is composed of the following components by weight：0.5 ~ 1.5 part of cobaltous sulfate,
1 ~ 2 part of ferrous sulfate, 0.5 ~ 1 part of glauber salt, 3 ~ 5 parts of glycerine, 3 ~ 5 parts of oxydiphthalic, AEO 2 ~
4 parts, 2 ~ 6 parts of trimethylolpropane, 1 ~ 5 part of antifebrin, ethylenediamine tetra-acetic acid two receives 2 ~ 4 parts, 0.5 ~ 2 part of catalyst, is modified
3 ~ 6 parts of agent, 2 ~ 3 parts of diffusant, 2 ~ 6 parts of surfactant.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107503183A (en) * | 2017-09-19 | 2017-12-22 | 澳洋集团有限公司 | A kind of dyeing of wear-resisting color blend polyester cloth |
| CN107956145A (en) * | 2017-12-13 | 2018-04-24 | 海宁星皓进出口有限公司 | A kind of colouring method of polyester fabric |
| CN110863376A (en) * | 2019-11-12 | 2020-03-06 | 江苏宇道生物科技有限公司 | Polyamide and spandex fiber coloring synchronism improver and use method thereof |
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| CN104846667A (en) * | 2015-05-18 | 2015-08-19 | 青岛德翕拓创高新技术有限公司 | Textile fabric coloring agent |
| CN104988711A (en) * | 2015-07-28 | 2015-10-21 | 太仓市双宇化纤有限公司 | Aramid fabric high-efficiency dyeing and finishing process |
| CN105735006A (en) * | 2016-02-26 | 2016-07-06 | 苏州三和开泰花线织造有限公司 | Multifunctional environment-friendly dyeing deepening agent and preparation method thereof |
| CN106120398A (en) * | 2016-07-18 | 2016-11-16 | 南通富之岛寝具发展有限公司 | Dyeing agent for textile fabrics |
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2016
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104846667A (en) * | 2015-05-18 | 2015-08-19 | 青岛德翕拓创高新技术有限公司 | Textile fabric coloring agent |
| CN104988711A (en) * | 2015-07-28 | 2015-10-21 | 太仓市双宇化纤有限公司 | Aramid fabric high-efficiency dyeing and finishing process |
| CN105735006A (en) * | 2016-02-26 | 2016-07-06 | 苏州三和开泰花线织造有限公司 | Multifunctional environment-friendly dyeing deepening agent and preparation method thereof |
| CN106120398A (en) * | 2016-07-18 | 2016-11-16 | 南通富之岛寝具发展有限公司 | Dyeing agent for textile fabrics |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107503183A (en) * | 2017-09-19 | 2017-12-22 | 澳洋集团有限公司 | A kind of dyeing of wear-resisting color blend polyester cloth |
| CN107956145A (en) * | 2017-12-13 | 2018-04-24 | 海宁星皓进出口有限公司 | A kind of colouring method of polyester fabric |
| CN110863376A (en) * | 2019-11-12 | 2020-03-06 | 江苏宇道生物科技有限公司 | Polyamide and spandex fiber coloring synchronism improver and use method thereof |
| CN110863376B (en) * | 2019-11-12 | 2022-02-18 | 多恩生物科技有限公司 | Polyamide and spandex fiber coloring synchronism improver and use method thereof |
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