CN1067175A - Cosmetics - Google Patents
Cosmetics Download PDFInfo
- Publication number
- CN1067175A CN1067175A CN92102479.7A CN92102479A CN1067175A CN 1067175 A CN1067175 A CN 1067175A CN 92102479 A CN92102479 A CN 92102479A CN 1067175 A CN1067175 A CN 1067175A
- Authority
- CN
- China
- Prior art keywords
- cosmetics
- absorbent
- oxide
- macromolecule resin
- effect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Images
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0254—Platelets; Flakes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/28—Zirconium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
It is good to the invention provides a kind of preventing ultraviolet effect (sun-proof result), both the cosmetics of the texture nature of safety and cosmetic.This cosmetics contain average thickness 0.01～3 μ m, the laminar metal-oxide of mean size 1-100 μ m and in be surrounded by the macromolecule resin powder of UV absorbent.
Description
The present invention relates to a kind of anti-sunlight and burn the cosmetics of usefulness, particularly a kind of by the thin sheet of metal oxide and in be surrounded by that the macromolecule resin of ultra-violet absorption forms can play the cosmetics that prevent serious daylight cauterization effect.
Known in the ultraviolet that arrives the face of land have excessive shower meeting to cause erythema on skin, cause the melanism after inflammation and become the middle-ultraviolet lamp (290～320nm:(UV-B) of one of reason of causing skin carcinoma, though and have and be difficult for causing skin erythema, under daylight, cause skin to shift to an earlier date the nearultraviolet rays (320～400nm:UV-A) of senile cause because of making oxidized melanin pigmentation and the skin long term exposure of causing of the reductive melanin of epidermis.
Therefore, along with ultraviolet is more and more clearer to the adverse effect of skin, the requirement that the anti-Exposure to Sunlight of cosmetics is burnt has also improved.Index S PF(Sun.Protector Factor at ultraviolet protection skin has been proposed) value; spf value is high more; anti-sunlight cauterization effect is good more, as, with reference to [SPF of daylight shielding] fragrant magazine 8(4 of association that makes up of Feitian Fu Shi) .315～323 pages 1984.
In general, in the cosmetics that anti-daylight burns, realize the purpose of anti-ultraviolet, be furnished with UV absorbent and ultraviolet scattering diluent for reaching high spf value.
In UV absorbent, known have benzophenone (benzophenon) family, cinnamic acid family, a benzoic acid family etc.For obtaining effectively anti-sunlight cauterization effect, to be equipped with a large amount of relatively UV absorbent in the cosmetic composition, under the more situation of dosage, can produce variety of issue.For example, produced the consistency problem of itself and other ingredients; Because the existence of UV absorbent makes other ingredients produce serious rotten harmful effect problem; Because of the decomposition of UV absorbent, UV absorbing properties is descended and painted etc. and to the safety issues such as zest increase of skin.Thereby UV absorbent like this has many problems as cosmetic material, uses the cosmetics of such raw material in a large number, and it just has the problem that does not have as the value of cosmetics.
On the one hand, in the ultraviolet scattering diluent zinc oxide is arranged, titanium oxide, zirconium oxide, Kaolin etc.These inorganic pigments have shown large-scale ultraviolet dispersion effect, lack by UV-induced going bad, and not by skin absorbs, so the problem of skin irritation seldom occurs.But owing to the covering power height, be coated in the vestiges of meeting adularescent on the skin, have a strong impact on appearance.
For improving above-mentioned shortage, use microgranular zinc oxide, titanium oxide, zirconium oxide etc. though disclose.But when in cosmetics, being furnished with this raw material, can cause that secondary condenses, can not expect that it plays anti-preferably daylight cauterization effect as cosmetics, on usability because its coating deleterious also is unsuitable for doing cosmetics.
For present this present situation, the spy open clear 61-161212 number, 62-4212 number, 63-166819 number and the spy open disclose on the flat 1-175921 communique safe, the sense of making up is good, the plate-shape metal oxide as cosmetic material that the ultraviolet scattering property is high.
Yet, this raw material, though safety and cosmetic in the sense better effects is arranged naturally, no matter use this raw material separately or be used, all do not have very good anti-daylight cauterization effect with the UV absorbent of the appropriate amount that on safety, does not have problems.
Thereby now people still expect to develop not only safety but also the cosmetics of higher anti-daylight cauterization effect can be arranged.
The object of the invention is to address the above problem, and a kind of higher retaining ultraviolet effect (sun-proof result) that has is provided, and safety is more excellent, the more natural cosmetics of effect that base material of cosmetics middle-ultraviolet lamp absorbent is stablized and made up.
Among the present invention, the inventor addresses the above problem that to have done to contain average thickness in the cosmetics that the result after the research with keen determination obtains be 0.01～3 μ m, mean size is the laminar metal-oxide of 1～100 μ m and by UV absorbent and macromolecule resin list aggressiveness uniform mixing are obtained, in be surrounded by the macromolecule resin powder of UV absorbent; Such cosmetics retaining ultraviolet effect (anti-Exposure to Sunlight effect) height.Safety is more excellent, and the UV absorbent in the base material of cosmetics is stable and can obtain the dressing effect that seems more natural in the use, has finished the present invention.
That is, laminar metal-oxide with in be surrounded by under the occasion of the macromolecule resin of UV absorbent and usefulness, even total the proportional quantity of two kinds of compositions in cosmetics relatively more after a little while, also can demonstrate significant high spf value.And, at secure context; Because the gain effect effect of last two kinds of compositions can relatively add UV absorbent less, UV absorbent is coated by macromolecule resin like this, can directly not contact with skin, so needn't consider safety issue again.Secondly, make up sensuously smear the time even opening etc. on the usability, the cosmetics of two kinds of compositions and usefulness have shown superior performance.
Employed plate-shape metal oxide among the present invention, its flat field thickness are 0.01～3 μ m, and mean size is 1～100 μ m.Here, described average thickness be meansigma methods with 100 thin slices as average thickness, with the meansigma methods of (thin slice longest diameter+its shortest diameter)/2 of 100 thin slices as the mean size size.If use as cosmetics, the metal-oxide of any kind as long as in above-mentioned shape and size scope, all is good.The kind of metal-oxide for example has, inorganic pigments such as zinc oxide, titanium oxide, zirconium oxide.
The metal-oxide that can use among the present invention can be used as following method manufacturing.At first with method as putting down in writing in No. 2941895 description of United States Patent (USP), after smearing organic solvent soln of metal-oxide on the even surface, under the effect of water vapour, lip-deep film peels off and obtains the tabular thin sheet of metal oxide of desired thickness; The spy opens that disclosed method is that metal oxide solution is coated on the gelatin film on the clear 30-473 communique, then gelatin film is dissolved; The spy opens clear 39-25280 communique and discloses the method for using vacuum evaporation; The spy opens the fiber that clear 58-88121 communique only discloses metal-oxide and adds acid, and methods of heating treatment produces metal-oxide then.Next, can go up resulting tabular thin sheet of metal oxide through dry ball, wet ball mill, vibrating mill, Z grinding machine etc. and pulverize, pass through oscillatory spin mobile device and electromagnetism porpoising again, and by spiral classifier and the such wet classification of hydroseparator, the dry classification method of dynamic formula or centrifugal wind clasfficiator, or a kind of the classification engineering in the floation or two or more combined method are made specific size.Laminar titanium oxide within the scope of the present invention, the product of the sale of available Sumitomo Chemical Le Network ヤ レ Application (registered trade mark) by name.
Among the present invention the structure of the macromolecule resin of used interior bag UV absorbent be with the ultra-violet absorption agent material as core, be that outer wall coats it by macromolecule resin.Be surrounded by the macromolecule resin of UV absorbent structure in this, to open the disclosed toner that contains UV absorbent that UV absorbent and macromolecule resin is only carried out uniform mixing and form of clear 62-22710 communique different with the spy.Promptly, resin raw material only has slow-releasing in the latter's the toner, after after a while, UV absorbent is emitted from base material of cosmetics, the stability problem that resin therefore can occur, and the macromolecule resin of used interior bag UV absorbent among the present invention because of it has above-mentioned structure, can not produce such problem.
In be surrounded by UV absorbent macromolecule resin can be: vinyl polymer resin, alkene-vinyl polymer resin, alkene-allyl resin polymer, polyamide, acrylic resin, polystyrene, polyester etc., but be not limited to this.
Among the present invention, the UV absorbent that coats in macromolecule resin material can be: amino benzoate and/or its derivant, salicylate and/or its derivant, cinnamate and/or its derivant, benzophenone derivative, urocanic acid ester and/its derivant but be not limited to this.Example is more specifically: 2-hydroxyl-4-methoxy benzophenone, 2-hydroxyl-4-methoxy benzophenone-5-sulphonic acid ester, 2,2 '-dihydroxy-4-methoxy benzophenone, to methoxy hydrogen cinnamic acid diethanolamine, para-amino benzoic acid ethyl dihydroxy propyl ester, para-amino benzoic acid glyceride, salicylic acid
Ester complex, ortho-aminobenzoic acid
Ester, 2-ethylhexyl-2-cyano group-3,3-diphenylacrylate ester, para-amino benzoic acid octyldimethyl ester, the 2-ethylhexyl-to the methoxy cinnamate, the 2-Ethylhexyl salicylate, para-amino benzoic acid, 2-Phenylbenzimidazole-5-sulphonic acid ester, trolamine salicylate, 3-(4-methyl benzal)-Camphora, 2, the 4-dihydroxy benaophenonel, 2,2 ', 4,4 '-tetrahydroxybenzophenone, 2,2 '-dihydroxy-4,4 '-dimethoxy-benzophenone, octabenzone, 4-isopropyl diphenyl formyl methane, 4-tert-butyl-4 '-the methoxy dibenzoyl methane, 2-ethyl-2-cyano group-3,3 '-diphenylacrylate ester, the urocanic acid ester, urocanic acid ethyl ester etc.Also can use a kind of of these UV absorbent and mix use more than two kinds.Can at random add spendable oils, esters, hydrocarbon, liquid senior ethanol class etc. in cosmetics uses together as additive.
The method for making that is surrounded by the macromolecule resin of UV absorbent in employed in the present invention is: for example, on-site polymerization, according to occasion, UV absorbent and oils etc. other arbitrarily additive and macromolecule resin monomer mixed dissolution, with inorganic dispersion stabilizer and after being emulsified into O/W type emulsion state, polymerization is the method for Powdered taking-up.
The amount of the UV absorbent of bag will be according to coating with the proportional quantity of macromolecule resin in cosmetics in the macromolecule resin that uses among the present invention, and the kind of used UV absorbent is decided with reaching the preventing degree of sun-proof purpose, usually, weight resin with respect to 100%, its scope of application are 1.0～50% percentage by weights preferably more than 0.01.Use amount is as being lower than 0.01 percentage by weight, and the amount of UV absorbent very little.With can not fully play sun-proof result after relative a large amount of cosmetic material cooperates.And usability such as tack, the even property opened, persistence are all bad.Be not suitable for as cosmetic material.On the other hand, 50% of its use amount overweight percentage ratio, the wall of macromolecule resin that coats UV absorbent is too thin, behind the certain hour because it is unstable in cosmetics.The resin wall of institute's adapted easily has disruptive tendency in the cosmetics, according to the kind of the UV absorbent of using; Produced the situation that macromolecule resin can not coat UV absorbent.
The size of macromolecule resin that is surrounded by UV absorbent among the present invention in employed is normally in 5～20 mu m ranges.
Among the present invention the proportional quantity of the laminar metal-oxide of employed adding cosmetics will be according to the sun-proof effect that will reach and the proportional quantity of the macromolecule resin powder of the interior bag UV absorbent used together change.But it is in the 1-70% weight range of total cosmetics weight.Percentage by weight is lower than at 1% o'clock, can not play fully anti-Exposure to Sunlight effect, is higher than 70% the situation that then has cosmetics not smoothen.Producing the problem of usability (even open, persistence color emissivity), is not very good sun care preparations.
Coated UV absorbent among the present invention and add the proportional quantity of the macromolecule resin powder of cosmetics will be according to desired anti-Exposure to Sunlight effect, and and the proportional quantity of the laminar metal-oxide of usefulness and changing, in the 0.1-70% of cosmetics gross weight scope.If content is lower than percentage by weight 0.1% and just can not fully plays sun-proof result, then smearing of cosmetics just can not be even if be higher than 70% percentage by weight, and the problem of generation usability (spare open, persistence, color emissivity) is not very good sun care preparations.
In cosmetics of the present invention; add above-mentioned laminar metal-oxide composition and in be surrounded by outside the macromolecule resin powder composition of UV absorbent, can be equipped with additives such as the employed surfactant of common cosmetics, oiliness composition, heat preserving agent, pigment, antiseptic on request.
Because the used structure of the present invention, though can not improve the ultraviolet occlusion effect significantly, but because of in be surrounded by UV absorbent the macromolecule resin powder be evenly dispersed in the interlayer of laminar metal-oxide, and laminar metal-oxide has absorbed the ultraviolet that can't stop, and has replenished desired effect.
Below, according to embodiment in the scope that the present invention elaborates, the present invention is not limited to these embodiment.
Material
(1) laminar metal-oxide
Le Network セ レ Application (registered trade mark) for titanium oxide, use Sumitomo Chemical (strain) system.This oxide, average thickness are 0.2 μ m, and mean size is 3-20 μ m, and other characteristic is refractive index 2.7, reflectance 7-15%.
To zinc oxide and zirconic use also within the average thickness and mean size of the scope of the invention.
(2) be surrounded by the macromolecule resin powder of UV absorbent in
Use plexiglass (PMMA) particle, in be surrounded by as UV absorbent, press the para-amino benzoic acid octyldimethyl ester (UV-A) and 4 tert-butyl-the 4 '-methoxy dibenzoyl methane (UA-B) of the ratio proportioning in the tabulation 1.
Contained UV absorbent is formed in the table 1 ［ UV-powder ］
| Title | UV-internal rate 1. | UV-internal rate 2. |
| UV-powder 0000 | 0％ | 0％ |
| UV-powder 0703 | 7％ | 3％ |
| UV-powder 1010 | 10％ | 10％ |
| UV- |
20％ | 0％ |
Fig. 1 represented with mobile paraffin as dispersive medium, make 2% in be surrounded by UV absorbent shown in the table 1 the PMMA toner be dispersed into paste equably, the ultra-violet absorption characteristic when thickness is 7 μ m.UV-powder 0000 does not have the ultra-violet absorption characteristic in addition, absorbs figure shown in baseline among Fig. 1.
The assay method of spf value
Using the Tim Hartley of 10 above body weight 250～350g is that female Cavia porcellus is measured.Before the solar radiation experiment, shave off, then with the depilation of depilation butterfat with the hair of electric razor with guinea pig back.After Cavia porcellus is fixed on holder, be that the boundary is divided into the left and right sides, a side (left side or right) is coated with equably and spreads test material (2mg/cm with the spine portion at depilation back
2), opposite side (right or a left side) is not coated with any material and exposing.Then, the photo-shield strip with 2 * 10cm of a peristome that is provided with 71 * 1cm that vertically give out vertically is attached to the part that scribbles test portion and be not coated with respectively.Be coated with the back at test portion and placed 15 minutes, begin irradiation in the sun.With silk card (ス ガ) test system radiometer ultraviolet integrating instrument the ultraviolet irradiation amount is measured, when each peristome the fixed ultraviolet amount stage block peristome with the band that is in the light when reaching and block solar light irradiation.Up to whole openings be covered and finish the irradiation.Peel off belt after the irradiation, place after 24 hours, judge.
Judging by the visual effect to the dermoreaction of each peristome appropriate section, is the irradiation integrating amount on the part that produces the most weak erythema MED(Minimum Erythema Dose).
The spf value of underproof material is calculated by following formula.
SPF=(being tested the MED of applying material part)/(the not MED of spreader portion)
Fleet testing
Carry out the performance test of [cosmetic appearance sensation] and [the even property opened when smearing].In women's group (15-20 name), allow they with usual way with the test cosmetic makeup, for [cosmetic appearance sensation] and [when smearing even the property opened], have: 5 estimate very good, 4 well, 3 generally, 2 relatively poor, 15 kinds of very poor stages are estimated.PTS after estimating is divided as estimating divided by the group number.Below with judging mark.
| Estimate and divide | 5～4.5 | 4.5～3.5 | 3.5～2.5 | 2.5 below |
| Judge |
|
○ | △ | × |
Example 1
Prescription, spf value and the usability of having represented the cosmetics (solid shape) of test in the table 2.
From table 2, use titanium oxide (comparative example 1～5 separately, comparative example 7: used the macromolecule resin that does not coat UV absorbent), use laminar titanium oxide (comparative example 6 separately, 11), be surrounded by the macromolecule resin monomer (comparative example 8-10) of UV absorbent in using separately, the situation (comparative example 12) that titanium oxide uses with UV absorbent (para-amino benzoic acid octyl group dihydroxy propyl ester), and the situation of titanium oxide and laminar titanium oxide and usefulness is compared, laminar titanium oxide of the present invention and in be surrounded by the macromolecule resin of UV absorbent and the situation of usefulness (embodiment 1～7), it is significantly superior to demonstrate superior spf value and usability, particularly spf value.
Example 2
Table 3 has been represented prescription, spf value and the usability of the cosmetics (when leaving standstill, as separative 2～3 layers, vibration makes its cosmetics that become the uniform mixing state to use during use) of the multi-layered type of test.
Table 3, the prescription of multi-layered type cosmetics and result of the test
| Formula material | Embodiment 8 | Comparative example 15 |
| Different n-nonanoic acid octyl group ester | 3.00（％） | ← |
| (POE40) four oil base Sorbitols | 0.05 | ← |
| Para-amino benzoic acid octyldimethyl ester | 0.50 | ← |
| Uncle 4--butyl-4 '-methoxy DBM | 0.50 | ← |
| Purified Water | 72.95 | 78.95％ |
| 1,3 butylene glycol | 3.00 | 3.00 |
| Ethanol | 14.00 | 14.00 |
| Laminar zirconium oxide | 5.00 | |
| UV-powder 1010 | 1.00 | |
| Spf value | 16.3 | 6.2 |
| Cosmetic appearance is felt naturally |
|
|
| Usability (smooth sense) |
|
△ |
As shown in table 3, the cosmetics of the embodiment of the invention 8 are compared with the cosmetics of comparative example 15, and spf value is significantly superior, and usability is also superior, are the good cosmetics of a kind of sun-proof result.In addition, the cosmetics of embodiment 8, as shown in Figure 2, it is also fine to ultrared occlusion effect.
Example 3
Spf value and usability to the various cosmetics in the scope of the invention of following method manufacturing are tested.The percentage by weight that is depicted as prescription is below formed.
Embodiment 9
Sun-proof emulsifiable paste
Prescription
One-tenth is grouped into
Hard ester acid 4.0
Self-emulsifying type glyceryl monostearate 3.0
Spermol 2.0
White beeswax 3.0
Olive oil 5.0
Squalane 10.0
Antioxidant is an amount of
Triethanolamine 2.0
Propylene glycol 7.0
Bentonite 0.5
Sterilization antiseptic is an amount of
Laminar titanium oxide (Le Network セ レ Application) 10.0
UV-powder 0,703 1.0
Spice is an amount of
Purified Water total amount to 100.0
The sun-proof butterfat of above-mentioned prescription, its spf value is 17.2, on its usability the sense of cosmetic nature and when smearing the even property opened all good.
Embodiment 10
Ultra light sun block lotion
Prescription
One-tenth is grouped into
(POE20) oily ether 1.2
Sesquialter oleic acid sorbitan 0.8
White beeswax 0.5
Vaseline 2.0
Squalane 5.0
Propylene glycol 5.0
Ethanol (ethanol) 3.0
Anticorrosion and bactericidal agent is an amount of
Xanthene glue 0.2
Laminar zinc oxide 7.0
UV-powder 2,000 3.0
Spice is an amount of
Purified Water total amount to 100.0
The spf value of the ultra light sun block lotion of above-mentioned prescription is 16.7, goes up the nature sense and be coated with the applied property opened good with regard to its cosmetic on its usability.
Embodiment 11
Substrate (0/W type)
Prescription
One-tenth is grouped into
Stearate 4.0
Glyceryl monostearate 2.0
Cetostearyl alcohol 1.5
Tetradecanoic acid isopropyl esters 7.0
Mobile paraffin 10.0
Silicone oil 5.0
Triethanolamine 1.5
Glycerol (glycerol) 4.0
Bentonite (Bentonite) 1.0
Sterilization antiseptic is an amount of
Titanium oxide 8.0
Kaolin 3.0
Talcum 3.0
Laminar titanium oxide 5.0
UV-powder 1,010 1.0
Coloring pigment 2.0
Spice is an amount of
Purified Water total amount to 100.0
The spf value of the creaminess substrate of above-mentioned prescription is 16.2, with regard to its cosmetic nature sense of usability with to be coated with the applied property opened good.
Embodiment 12
Substrate (w/o type)
Prescription
One-tenth is grouped into
Span-83 3.0
Self-emulsifying type glyceryl monostearate 2.0
Aluminium stearate 0.5
Ceresin 5.0
Squalane 10.0
Oleum sesami 15.0
Vaseline 5.0
Urocanic acid ethyl ester 2.0
Propylene glycol 5.0
Sterilization antiseptic is an amount of
Magnesium oxide 0.5
Titanium oxide 4.0
Zirconium oxide 4.0
Talcum 4.0
Laminar titanium oxide 6.0
UV-powder 0,703 2.0
Spice is an amount of
Purified Water total amount to 100.0
The spf value of the creaminess substrate of above-mentioned prescription is 18.7, the cosmetic nature sense on its usability and when smearing the even property opened good.Persistence after the cosmetic is superior.
Embodiment 13
Astringent
Prescription
One-tenth is grouped into
Ethanol 10.0
(P0E-20) sorbitan acid monolaurate 1.0
Sterilization antiseptic 0.2
Spice 0.2
1,3 butylene glycol 8.0
Laminar titanium oxide 5.0
UV-powder 2,000 2.0
Dry oxidation silicon 0.2
Purified Water total amount to 100.0
The spf value of the astringent of above-mentioned prescription is 14.7, has anti-Exposure to Sunlight effect, the cosmetic that it uses feel naturally and to be coated with the applied property opened good.
Embodiment 14
Suntan lotion
Prescription
One-tenth is grouped into
Para-amino benzoic acid octyldimethyl ester 4.0
4-tert-butyl-4 '-methoxy dibenzoyl methane 1.0
Tocopheryl acetate 0.1
Laminar titanium oxide 10.0
UV-powder 1,010 1.0
Spice is an amount of
Volatile silicone total amount to 100.0
The suntan lotion spf value of above-mentioned prescription is 17.5, has anti-Exposure to Sunlight effect, with regard to its usability at feeling naturally of making up with to be coated with the applied property opened good.
Embodiment 15
Lip pomade
Prescription
One-tenth is grouped into
Brazil wax 4.5
Candelilla wax 9.0
Ceresin(e) 2.5
White beeswax 1.5
Cocoa butter 4.0
Sucrose fatty acid ester 2.0
Lanoline 20.0
Antioxidant is an amount of
Allantoin is an amount of
Laminar titanium oxide 5.0
UV-powder 2,000 5.0
Red No. 3 aluminum precipitation colorants are an amount of
Spice is an amount of
Fluidised form white beeswax total amount to 100.0
The disgrace cream of above-mentioned prescription, spf value is 15.6, has sun-proof result, the cosmetic nature sense that it uses and to be coated with the applied property opened good.
Cosmetics of the present invention; spf value data as shown in the Examples not only have the effect of better protect skin to deleterious ultraviolet; its safety, usability, the sense of cosmetic nature are all good; no matter and it has very high preventing ultraviolet effect, when making up, also be the valuable cosmetics that can obtain the effect of nature in appearance with regard to it.
Fig. 1 is the ultra-violet absorption performance plot that is surrounded by the macromolecule resin powder (UV-powder) of used UV absorbent in of the present invention.
Fig. 2 represents the infrared ray occlusion effect figure of multi-layered type cosmetics.
Claims (1)
1, a kind of cosmetics, contain average thickness and be 0.01～3 μ m, mean size and be 1-100 μ m laminar metal-oxide and by UV absorbent and macromolecule resin monomer mix equably obtain in be surrounded by the macromolecule resin powder of UV absorbent.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3051591A JPH04288010A (en) | 1991-03-15 | 1991-03-15 | Cosmetic |
| JP51591/91 | 1991-03-15 | ||
| US08/199,867 US5585090A (en) | 1991-03-15 | 1994-02-22 | Cosmetics having sunscreen properties |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1067175A true CN1067175A (en) | 1992-12-23 |
Family
ID=26392134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN92102479.7A Pending CN1067175A (en) | 1991-03-15 | 1992-03-14 | Cosmetics |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5585090A (en) |
| EP (1) | EP0503922B1 (en) |
| JP (1) | JPH04288010A (en) |
| CN (1) | CN1067175A (en) |
| AU (1) | AU663697B2 (en) |
| CA (1) | CA2062651C (en) |
| CS (1) | CS76392A3 (en) |
| DE (1) | DE69206853T2 (en) |
| ES (1) | ES2083082T3 (en) |
| TR (1) | TR25814A (en) |
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|---|---|---|---|---|
| CN105228578A (en) * | 2013-05-14 | 2016-01-06 | 大赛璐赢创株式会社 | Resin powder body containing ultraviolet scattering diluent and manufacture method thereof and cosmetic |
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| DE102004012576A1 (en) * | 2004-03-12 | 2005-09-29 | Basf Ag | Aqueous polymer dispersions containing effect substances, process for their preparation and their use |
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| KR20100017328A (en) | 2007-05-01 | 2010-02-16 | 가부시키가이샤 엔티티 도코모 | User device, base station device, and communicaion control method in mobile communication system |
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| DE102009019411A1 (en) | 2009-04-29 | 2010-11-04 | Bayer Technology Services Gmbh | Process for the UV stabilization of organic substances |
| JP2011051913A (en) * | 2009-08-31 | 2011-03-17 | Miyoshi Kasei Inc | Composition for cosmetic preparation having ultraviolet-shielding effect and sebum solidifying ability |
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| US20140004057A1 (en) | 2012-06-28 | 2014-01-02 | Johnson & Johnson Consumer Companies, Inc. | Sunscreen compositions containing an ultraviolet radiation-absorbing polyester |
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| US20160143824A1 (en) * | 2013-07-09 | 2016-05-26 | L'oreal | Long-wear cosmetic composition |
| DE102014206156A1 (en) * | 2014-04-01 | 2015-10-01 | Beiersdorf Ag | Sunscreens with encapsulated UV filters III |
| DE102014206152A1 (en) * | 2014-04-01 | 2015-10-01 | Beiersdorf Ag | Sunscreens with encapsulated UV filters I |
| US10874603B2 (en) | 2014-05-12 | 2020-12-29 | Johnson & Johnson Consumer Inc. | Sunscreen compositions containing a UV-absorbing polyglycerol and a non-UV-absorbing polyglycerol |
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| US10596087B2 (en) | 2016-10-05 | 2020-03-24 | Johnson & Johnson Consumer Inc. | Ultraviolet radiation absorbing polymer composition |
| FR3091652B1 (en) * | 2019-01-11 | 2021-05-28 | Thorel Jean Noel | TOPICAL SOLAR COMPOSITION PROTECTING SKIN EXPOSED TO IRRADIATION OF HIGH ENERGY VISIBLE LIGHT |
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| MX2022009293A (en) * | 2020-01-30 | 2022-08-17 | Amyris Inc | SUNSCREEN FORMULATIONS WITH METAL OXIDE. |
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| CN117045543B (en) * | 2023-08-30 | 2026-01-02 | 上海应用技术大学 | A sunscreen composition based on *Sapindus mukorossi* oil and an oil-soluble UV absorber and its application. |
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| JPS57120514A (en) * | 1981-01-20 | 1982-07-27 | Pola Chem Ind Inc | Cosmetic having ultraviolet light shielding effect |
| JPH0662387B2 (en) * | 1985-01-11 | 1994-08-17 | 住友化学工業株式会社 | Cosmetics |
| JPS624212A (en) * | 1985-06-28 | 1987-01-10 | Catalysts & Chem Ind Co Ltd | Cosmetic composition |
| JPS6222710A (en) * | 1985-07-19 | 1987-01-30 | Seitetsu Kagaku Co Ltd | Anti-sunburn cosmetic |
| MY100306A (en) * | 1985-12-18 | 1990-08-11 | Kao Corp | Anti-suntan cosmetic composition |
| US5026540A (en) * | 1987-06-04 | 1991-06-25 | Chesebrough-Pond's Usa Co. | Sunscreen composition |
| US5028417A (en) * | 1987-07-20 | 1991-07-02 | Johnson & Johnson Consumer Products, Inc. | Sunscreen compositions |
| LU87030A1 (en) * | 1987-10-28 | 1989-05-08 | Oreal | USE IN COSMETICS OF NEW SUBSTANCES AS INFRARED RADIATION REFLECTORS, COSMETIC COMPOSITIONS CONTAINING THEM AND THEIR USE FOR THE PROTECTION OF THE HUMAN SKIN AGAINST INFRARED RADIATION |
| US5093099A (en) * | 1987-11-16 | 1992-03-03 | Kao Corporation | Flaky powder of zinc oxide and its composition for external use |
| GB8906258D0 (en) * | 1989-03-18 | 1989-05-04 | Boots Co Plc | Sunscreen compositions |
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| FR2680684B1 (en) * | 1991-08-29 | 1993-11-12 | Oreal | COSMETIC FILTERING COMPOSITION COMPRISING A METAL OXIDE NANOPIGMENT AND A FILTERED POLYMER. |
| GB9211708D0 (en) * | 1992-06-03 | 1992-07-15 | Unilever Plc | Cosmetic composition |
-
1991
- 1991-03-15 JP JP3051591A patent/JPH04288010A/en active Pending
-
1992
- 1992-03-11 DE DE69206853T patent/DE69206853T2/en not_active Expired - Fee Related
- 1992-03-11 ES ES92302075T patent/ES2083082T3/en not_active Expired - Lifetime
- 1992-03-11 CA CA002062651A patent/CA2062651C/en not_active Expired - Fee Related
- 1992-03-11 EP EP92302075A patent/EP0503922B1/en not_active Expired - Lifetime
- 1992-03-13 AU AU12837/92A patent/AU663697B2/en not_active Ceased
- 1992-03-13 CS CS92763A patent/CS76392A3/en unknown
- 1992-03-14 CN CN92102479.7A patent/CN1067175A/en active Pending
- 1992-03-16 TR TR92/0214A patent/TR25814A/en unknown
-
1994
- 1994-02-22 US US08/199,867 patent/US5585090A/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105228578A (en) * | 2013-05-14 | 2016-01-06 | 大赛璐赢创株式会社 | Resin powder body containing ultraviolet scattering diluent and manufacture method thereof and cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| TR25814A (en) | 1993-09-01 |
| EP0503922A2 (en) | 1992-09-16 |
| AU1283792A (en) | 1992-09-17 |
| CA2062651C (en) | 1997-05-27 |
| DE69206853D1 (en) | 1996-02-01 |
| CA2062651A1 (en) | 1992-09-16 |
| AU663697B2 (en) | 1995-10-19 |
| US5585090A (en) | 1996-12-17 |
| CS76392A3 (en) | 1992-11-18 |
| DE69206853T2 (en) | 1996-07-25 |
| EP0503922B1 (en) | 1995-12-20 |
| EP0503922A3 (en) | 1993-04-07 |
| JPH04288010A (en) | 1992-10-13 |
| ES2083082T3 (en) | 1996-04-01 |
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| C06 | Publication | ||
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| AD01 | Patent right deemed abandoned | ||
| C20 | Patent right or utility model deemed to be abandoned or is abandoned |