[go: up one dir, main page]

CN106715356A - 挤出的水泥基材料 - Google Patents

挤出的水泥基材料 Download PDF

Info

Publication number
CN106715356A
CN106715356A CN201580033711.1A CN201580033711A CN106715356A CN 106715356 A CN106715356 A CN 106715356A CN 201580033711 A CN201580033711 A CN 201580033711A CN 106715356 A CN106715356 A CN 106715356A
Authority
CN
China
Prior art keywords
range
mixture
starch
cement
wet weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201580033711.1A
Other languages
English (en)
Inventor
E·R·丹尼尔斯
P·J·安德森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INTELLECTUAL GORILLA BV
Original Assignee
INTELLECTUAL GORILLA BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by INTELLECTUAL GORILLA BV filed Critical INTELLECTUAL GORILLA BV
Publication of CN106715356A publication Critical patent/CN106715356A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/14—Apparatus or processes for treating or working the shaped or preshaped articles for dividing shaped articles by cutting
    • B28B11/16—Apparatus or processes for treating or working the shaped or preshaped articles for dividing shaped articles by cutting for extrusion or for materials supplied in long webs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/243—Setting, e.g. drying, dehydrating or firing ceramic articles
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/0048—Fibrous materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04—Portland cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0079—Rheology influencing agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/20—Retarders
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/20—Retarders
    • C04B2103/22—Set retarders
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034—Physico-chemical characteristics of the mixtures
    • C04B2111/00129—Extrudable mixtures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40—Porous or lightweight materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Civil Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)
  • Combustion & Propulsion (AREA)

Abstract

一种由混合物形成的可挤出的水泥基材料，该混合物包含水泥、水、石膏、辅助材料、增强纤维和流变改性剂。可挤出的水泥基材料是轻质材料，其具有约1.4至2.4g/cm3范围内的密度、约5至100MPa范围内的抗压强度以及约5至35MPa范围内的抗弯强度。注意，水泥可以包含石膏，使得石膏不添加到混合物中。

Description

挤出的水泥基材料
发明领域
本发明一般地涉及复合材料领域，更具体地涉及挤出的水泥基材料。
背景技术
一般使用大量的水以形成浆料产生水泥基材料，该浆料太湿不能挤出。
发明概述
本发明提供一种由混合物形成的可挤出的水泥基材料，所述混合物包含水泥、水、石膏、辅助材料、增强纤维和流变改性剂。注意，水泥可包含石膏，使得石膏不添加到混合物中。可挤出的水泥基材料是具有约1.4至2.4g/cm3范围内的密度、约5至100MPa范围内的抗压强度和约5至35MPa范围内的抗弯强度的轻质材料。
另外，本发明提供一种由混合物形成的可挤出的水泥基材料，该混合物包含以湿重百分比计约0.1-90％范围内的水泥、约10-60％范围内的水、以湿重百分比计约0.1-90％范围内的石膏、以湿重百分比计约0.1-50％范围内的辅助材料(例如砂、岩石、飞灰、矿渣、硅粉(silica fume)、碳酸钙等)、以湿重百分比计约1-20％范围内的增强纤维和以湿重百分比计约0.5-10％范围内的流变改性剂。注意，水泥可以包含石膏，使得石膏不添加到混合物中。
另外，本发明提供一种用于通过以下制备可挤出的水泥基材料的方法：将水泥、石膏、辅助材料、增强纤维和流变改性剂与水混合，使用挤出机通过模具挤出混合物，和使挤出的混合物凝固。注意，水泥可以包含石膏，使得石膏不添加至混合物。
另外，本发明提供了一种通过以下步骤制备可挤出的水泥基材料(复合材料)的方法：(1)将约0.1-90％湿重的水泥和0.1-90％湿重的石膏与约10-60％湿重的水混合；(2)将水泥-石膏-水混合物与约0.1-50％湿重的辅助材料(例如砂、岩石、飞灰、矿渣、硅粉、碳酸钙等)和约1-20％湿重的增强纤维共混；和(3)添加约0.5-10％湿重的流变改性剂至混合物。然后可挤出并固化(例如使静置、加热、蒸汽处理等)得到的可挤出的水泥基材料。注意，水泥可以包含石膏，使得石膏不添加至混合物。
附图简述
可通过结合附图参照以下描述更好地理解本发明的上述和其它优点，其中：
无。
发明描述
尽管下文详细讨论了本发明的各种实施方案的制备和使用，但是应当理解，本发明提供了可以在各种各样的具体上下文中体现的许多可应用的发明构思。本文所讨论的具体实施方案仅仅是说明制备和使用本发明的具体方式，而不限制本发明的范围。
以其湿的状态、具有在凝固之前加入的水的普通波特兰水泥(OPC)、铝酸钙水泥(CAC)、Sorel水泥(氧化镁和氯化镁水泥)、CSA水泥(硫铝酸钙水泥)、磷酸盐水泥或现有技术中已知的其它水泥类型，可以流变改性成粘土状材料，这允许使用称为挤出的常规粘土生产方法。
具有水的水泥可以在与多种材料诸如细石灰石、砂、石膏、硅粉、火成二氧化硅(fumed silica)、熟石膏、飞灰、矿渣、岩石、纤维素纤维、玻璃纤维、塑料纤维、PVA纤维、德兰尼特纤维等组合的复合材料组合物中作为粘结剂使用，当流变改性时可如上所述将其挤出。注意，水泥可以包含少量的石膏(例如0.3％等)，因此当所需的石膏含量在该范围的下端时，可以不需要向混合物中添加石膏(见下文)。
通过添加流变改性剂来稳定水泥-石膏-水混合物，典型地以约0.5至10％湿重的量添加。
流变改性剂分为以下类别：(1)多糖及其衍生物，(2)蛋白质及其衍生物，和(3)合成有机材料。多糖流变改性剂可以进一步细分为(a)纤维素基材料及其衍生物，(b)淀粉基材料及其衍生物，和(c)其他多糖。
适合的纤维素基流变改性剂包括例如甲基羟乙基纤维素、羟甲基乙基纤维素、羧甲基纤维素、甲基纤维素、乙基纤维素、羟乙基纤维素、羟乙基丙基纤维素等。
适合的淀粉基材料包括例如小麦淀粉、预胶凝小麦淀粉、马铃薯淀粉、预胶凝马铃薯淀粉、支链淀粉、直链淀粉、海凝胶(seagel)、淀粉乙酸酯、淀粉羟乙基醚、离子淀粉、长链烷基淀粉、糊精、胺淀粉、磷酸盐淀粉和双醛淀粉。
目前优选的流变改性剂是羟丙基甲基纤维素，其实例是Methocel 240和Methocel240S。
对于挤出，使具有总湿材料的约10-60wt.％的水和适合的流变改性混合物的水泥基复合材料感觉和表现与塑性粘土相似。材料触摸起来感觉是塑性的/可变形的，并且可以类似于粘土使用粘土挤出机将其挤出，其中通过螺旋输送机将材料向前输送通过筒并且通过模具连续地形成具有形状稳定性的最终形状。
根据水含量和流变改性混合物的量，挤出的材料可具有或多或少的形状稳定性。
通过向材料中添加增强纤维，在水泥凝固之前将实现增加的稳定性。此外，已经发现纤维添加减少或消除在生产过程的干燥阶段期间的材料收缩和干燥收缩裂纹，并且进一步提供干材料的增加的抗弯强度和韧性。纤维的优选类型是纤维素(硬木或软木)纤维、塑料(基于聚乙烯醇或丙烯酸)纤维和玻璃纤维；纤维素纤维和塑料纤维主要用于目的是低于冻结或环境温度的绝缘，而玻璃纤维主要用于目的是高于环境的温度或需要耐火性的绝缘。此外，可以应用纤维类型的组合。优选的纤维长度对于纤维素纤维为约1至2mm，对于塑料纤维为约4至10mm，对于玻璃纤维为约6至20mm。优选的纤维直径为约10至40微米。
为了增加在凝固(硬化)之前可以挤出水泥基材料的时间，使用少量添加的适合的常规混凝土缓凝剂(例如，来自BASF公司的Delvo)可以将凝固时间延迟最长达数小时。可以通过使用螺旋输送机将混合物输送通过筒，并使用挤出机通过模具连续地将混合物成形为具有形状稳定性的最终形状来挤出水泥基材料。挤出后，材料将在几小时内形成最终产品的初始和最终凝固。
为了形成由OPC水泥制成的产品的最终28天强度，可以使该产品在潮湿的环境中静置约28天，或者可以借助其自身内部(放热)热产生或借助如现有技术中常规的蒸汽固化，通过加热在24-48小时内加速强度形成。
由CAC水泥、Sorel水泥、CSA水泥、磷酸盐水泥或其他水泥类型制成的产品将在24小时内达到其最终强度，并且不必需要额外的固化。
在实现最终强度形成后，将产品干燥以产生成品复合材料。硬化后，可以根据需要(例如，切割成一定尺寸、砂磨、修整、涂漆、密封、纹理化、图像化等)来精加工硬化的材料。
在一个实施方案中，可以通过用水或溶剂基硅烷喷涂产品使成品具有防水性。这种产品Protectosil BHN通常由BASF出售。还可以用抗真菌或抗微生物涂料来喷涂成品。此外，成品可以进行涂漆、染色或纹理化。
制成的轻质水泥基复合材料将具有约1.4至2.4g/cm3范围内的密度、约5至100MPa范围内的抗压强度和约5至35MPa范围内的抗弯强度。
组成范围如下所示：
水泥可以为以重量计0.1％、0.2％、0.3％、0.4％、0.5％、0.6％、0.7％、0.8％、0.9％、1.0％、2％、3％、4％、5％、6％、7％、8％、9％、10％、11％、12％、13％、14％、15％、16％、17％、18％、19％、20％、21％、22％、23％、24％、25％、26％、27％、28％、29％、30％、31％、32％、33％、34％、35％、36％、37％、38％、39％、40％、41％、42％、43％、44％、45％、46％、47％、48％、49％、50％、51％、52％、53％、54％、55％、56％、57％、58％、59％、60％、61％、62％、63％、64％、65％、66％、67％、68％、69％、70％、71％、72％、73％、74％、75％、76％、77％、78％、79％、80％、81％、82％、83％、84％、85％、86％、87％、88％、89％或90％或之间的其它增量百分比。
水可以为以重量计10％、11％、12％、13％、14％、15％、16％、17％、18％、19％、20％、21％、22％、23％、24％、25％、26％、27％、28％、29％、30％、31％、32％、33％、34％、35％、36％、37％、38％、39％、40％、41％、42％、43％、44％、45％、46％、47％、48％、49％、50％、51％、52％、53％、54％、55％、56％、57％、58％、59％或60％或之间的其它增量百分比。
石膏可以为以重量计0.1％、0.2％、0.3％、0.4％、0.5％、0.6％、0.7％、0.8％、0.9％、1.0％、2％、3％、4％、5％、6％、7％、8％、9％、10％、11％、12％、13％、14％、15％、16％、17％、18％、19％、20％、21％、22％、23％、24％、25％、26％、27％、28％、29％、30％、31％、32％、33％、34％、35％、36％、37％、38％、39％、40％、41％、42％、43％、44％、45％、46％、47％、48％、49％、50％、51％、52％、53％、54％、55％、56％、57％、58％、59％、60％、61％、62％、63％、64％、65％、66％、67％、68％、69％、70％、71％、72％、73％、74％、75％、76％、77％、78％、79％、80％、81％、82％、83％、84％、85％、86％、87％、88％、89％或90％或之间的其它增量百分比。
辅助材料可以为以重量计0.1％、0.2％、0.3％、0.4％、0.5％、0.6％、0.7％、0.8％、0.9％、1.0％、2％、3％、4％、5％、6％、7％、8％、9％、10％、11％、12％、13％、14％、15％、16％、17％、18％、19％、20％、21％、22％、23％、24％、25％、26％、27％、28％、29％、30％、31％、32％、33％、34％、35％、36％、37％、38％、39％、40％、41％、42％、43％、44％、45％、46％、47％、48％、49％或50％或之间的其它增量百分比。
增强纤维可以为以重量计0.5％、0.6％、0.7％、0.8％、0.9％、1.0％、2％、3％、4％、5％、6％、7％、8％、9％、10％、11％、12％、13％、14％、15％、16％、17％、18％、19％或20％或之间的其它增量百分比。
流变改性剂可以为以重量计0.5％、0.6％、0.7％、0.8％、0.9％、1.0％、1.1％、1.2％、1.3％、1.4％、1.5％、1.6％、1.7％、1.8％、1.9％、2.0％、2.1％、2.2％、2.3％、2.4％、2.5％、2.6％、2.7％、2.8％、2.9％、3.0％、3.1％、3.2％、3.3％、3.4％、3.5％、3.6％、3.7％、3.8％、3.9％、4.0％、4.1％、4.2％、4.3％、4.4％、4.5％、4.6％、4.7％、4.8％、4.9％、5.0％、5.1％、5.2％、5.3％、5.4％、5.5％、5.6％、5.7％、5.8％、5.9％、6.0％、6.1％、6.2％、6.3％、6.4％、6.5％、6.6％、6.7％、6.8％、6.9％、7.0％、7.1％、7.2％、7.3％、7.4％、7.5％、7.6％、7.7％、7.8％、7.9％、8.0％、8.1％、8.2％、8.3％、8.4％、8.5％、8.6％、8.7％、8.8％、8.9％、9.0％、9.1％、9.2％、9.3％、9.4％、9.5％、9.6％、9.7％、9.8％、9.9％或10％或之间的其它增量百分比。
缓凝剂可以为以重量计0.1％、0.2％、0.3％、0.4％、0.5％、0.6％、0.7％、0.8％、0.9％、1.0％、1.1％、1.2％、1.3％、1.4％、1.5％、1.6％、1.7％、1.8％、1.9％、2.0％、2.1％、2.2％、2.3％、2.4％、2.5％、2.6％、2.7％、2.8％、2.9％、3.0％、3.1％、3.2％、3.3％、3.4％、3.5％、3.6％、3.7％、3.8％、3.9％、4.0％、4.1％、4.2％、4.3％、4.4％、4.5％、4.6％、4.7％、4.8％、4.9％、5.0％、5.1％、5.2％、5.3％、5.4％、5.5％、5.6％、5.7％、5.8％、5.9％、6.0％、6.1％、6.2％、6.3％、6.4％、6.5％、6.6％、6.7％、6.8％、6.9％、7.0％、7.1％、7.2％、7.3％、7.4％、7.5％、7.6％、7.7％、7.8％、7.9％、或8.0％或之间的其它增量百分比。
因此，本发明提供了由包含水泥、水、石膏、辅助材料、增强纤维和流变改性剂的混合物形成的可挤出的水泥基材料。可挤出的水泥基材料是轻质材料，其具有约1.4至2.4g/cm3范围内的密度、约5至100MPa范围内的抗压强度以及约5至约35MPa范围内的抗弯强度。注意，水泥可以包含石膏，使得石膏不添加到混合物中。在一些实施方案中，可以向混合物中添加缓凝剂。
另外，本发明提供了一种可挤出的水泥基材料，其由混合物形成，该混合物包含以湿重量百分比计约0.1至90％范围内的水泥、约10至60％范围内的水、以湿重百分比计约0.1至90％范围内的石膏、以湿重百分比计约0.1至50％范围内的辅助材料(例如砂、岩石、飞灰、矿渣、硅粉、碳酸钙等)、以湿重量百分比计约0.5至20％范围内的增强纤维和以湿重百分比计约0.5至10％范围内的流变改性剂。注意，水泥可以包含石膏，使得石膏不添加到混合物中。在一些实施方案中，约0.1至8％湿重范围内的缓凝剂可以加入到混合物中。
此外，本发明提供一种通过以下制造可挤出的水泥基材料的方法：将水泥、辅助材料、增强纤维和流变改性剂与水混合，使用挤出机通过模具挤出混合物，并使挤出的混合物凝固。注意，水泥可以包含石膏，使得石膏不添加到混合物中，或者石膏与水混合，或两者。在一些实施方案中，可以向混合物中加入缓凝剂。
此外，本发明提供了通过以下步骤制备可挤出的水泥基材料(复合材料)的方法：(1)混合约0.1-90％湿重的水泥和0.1-90％湿重的石膏与约10至60％湿重的水，其中水泥包含石膏，或石膏与水泥和水混合，或两者；(2)将所述水泥-石膏-水混合物与约0.1至50％湿重的辅助材料(例如砂、岩石、飞灰、矿渣、硅粉、碳酸钙等)和约0.5至20％湿重的增强纤维共混；和(3)加入约0.5至10％湿重的流变改性剂至混合物。然后可将得到的可挤出的水泥基材料挤出并固化(例如，使静置、加热、蒸汽处理等)。在一些实施方案中，可以将约0.1至8％的湿重范围内的缓凝剂添加到混合物中。
在另一个实施方案中，可挤出的水泥基材料(复合材料)可以通过以下步骤制备：(1)将批料的所有成分同时计量加入混合器(例如，Eirich强力混合器等)中并混合这些成分；(2)将混合物倒入料斗中并通过模具挤出混合物以形成细长片材；(3)将细长片材通过一组或多组(例如两组等)压延机轧制到最终厚度；(4)将细长片材切割成具有特定长度的一组单独片材；(5)拾取单独片材中的一个或多个并将它们堆放在托盘上；(6)用塑料和绝缘覆盖物覆盖堆叠物，并将堆叠物放置在固化室中保持特定的一段时间(例如24至48小时或固化各片材所需的其它时间段)；(7)精加工每个单独的片材(例如，弄方正边缘，砂磨以使表面平滑和使尺寸精确(exact)；以及(8)将一种或多种涂料或油墨施加到每个单独的片材(例如借助涂布或印刷工艺施加UV涂料、防火涂料、颜料、图像、纹理化或其组合)。
尽管已经详细描述了本发明的优选实施方案，但是本领域技术人员将理解，在不脱离如所附权利要求中阐述的本发明的精神和范围的情况下，可以在其中进行各种修改。

Claims (40)

1.一种由混合物形成的可挤出的水泥基材料，所述混合物包含：
以湿重百分比计约0.1-90％范围内的水泥；
以湿重百分比计约0.1-90％范围内的石膏；
以湿重百分比计约0.1-50％范围内的辅助材料；
以湿重百分比计约0.5-20％范围内的增强纤维；
以湿重百分比计约0.5-10％范围内的流变改性剂；
总湿材料重量的10-60％范围内的水；和
所述混合物是可挤出的。
2.根据权利要求1所述的可挤出的水泥基材料，其中所述水泥包含石膏，并且石膏不添加至混合物。
3.根据权利要求1所述的可挤出的水泥基材料，所述混合物具有粘土状稠度。
4.根据权利要求1所述的可挤出的水泥基材料，所述辅助材料包括砂、硅粉、火成二氧化硅、飞灰、矿渣、岩石、纤维素纤维、玻璃纤维、塑料纤维、聚乙烯醇(PVA)纤维或其组合。
5.根据权利要求1所述的可挤出的水泥基材料，所述增强纤维包括纤维素纤维、玻璃纤维、聚丙烯纤维、聚乙烯醇(PVA)纤维、德兰尼特纤维或其组合。
6.根据权利要求1所述的可挤出的水泥基材料，所述流变改性剂包括多糖、多糖衍生物、蛋白质、蛋白质衍生物、合成有机材料、合成有机材料衍生物或其组合。
7.根据权利要求6所述的可挤出的水泥基材料，所述多糖包括纤维素基材料、纤维素基材料衍生物、淀粉基材料、淀粉基材料衍生物或其组合。
8.根据权利要求7所述的可挤出的水泥基材料，所述纤维素基材料选自主要由以下组成的组：甲基羟乙基纤维素(MHEC)、羟甲基乙基纤维素(HMEC)、羧甲基纤维素(CMC)、甲基纤维素(MC)、乙基纤维素(EC)、羟乙基纤维素(HEC)、羟乙基丙基纤维素(HEPC)和羟丙基甲基纤维素(HPMC)。
9.根据权利要求7所述的可挤出的水泥基材料，所述淀粉基材料选自主要由以下组成的组：小麦淀粉、预胶凝小麦淀粉、马铃薯淀粉、预胶凝马铃薯淀粉、支链淀粉、直链淀粉、海凝胶、淀粉乙酸酯、淀粉羟乙基醚、离子淀粉、长链烷基淀粉、糊精、胺淀粉、磷酸盐淀粉或双醛淀粉。
10.根据权利要求1所述的可挤出的水泥基材料，进一步包含以湿重百分比计约0.1-8％范围内的缓凝剂。
11.根据权利要求10所述的可挤出的水泥基材料，所述缓凝剂包括柠檬酸钠，或者熟石膏、柠檬酸钠和结晶二氧化硅的混合物。
12.根据权利要求1所述的可挤出的水泥基材料，所述可挤出的水泥基材料具有约1.4至2.4g/cm3范围内的密度、约5MPa至100MPa范围内的抗压强度和约5至35MPa范围内的抗弯强度。
13.一种由混合物形成的可挤出的水泥基材料，所述混合物主要由以下组成：
以湿重百分比计约0.1-90％范围内的水泥；
以湿重百分比计约0.1-90％范围内的石膏；
以湿重百分比计约0.1-50％范围内的辅助材料；
以湿重百分比计约0.5-20％范围内的增强纤维；
以湿重百分比计约0.5-10％范围内的流变改性剂；
总湿材料重量的10-60％范围内的水；和
所述混合物是可挤出的。
14.可挤出的水泥基材料，其中所述水泥包含石膏，并且石膏不添加至混合物。
15.一种用于制备可挤出的水泥基材料的方法，所述方法包括以下步骤：
将水泥、辅助材料、增强纤维和流变改性剂与水混合，其中水泥包含石膏，或者石膏与水混合，或两者；
使用挤出机通过模具挤出混合物；和
使挤出的混合物凝固。
16.根据权利要求15所述的方法，所述混合物包含：
以湿重百分比计约0.1-90％范围内的水泥；
以湿重百分比计约0.1-90％范围内的石膏；
以湿重百分比计约0.1-50％范围内的辅助材料；
以湿重百分比计约0.5-20％范围内的增强纤维；
以湿重百分比计约0.5-10％范围内的流变改性剂；和
总湿材料重量的10-60％范围内的水。
17.根据权利要求15所述的方法，所述混合物主要由以下组成：
以湿重百分比计约40-90％范围内的水泥；
以湿重百分比计约0.1-90％范围内的石膏；
以湿重百分比计约0.1-50％范围内的辅助材料；
以湿重百分比计约0.5-20％范围内的增强纤维；
以湿重百分比计约0.5-10％范围内的流变改性剂；和
总湿材料重量的10-60％范围内的水。
18.根据权利要求15所述的方法，其中将水泥、辅助材料、增强纤维和流变改性剂与水混合的步骤包括以下步骤：
将水泥与水混合，其中水泥包含石膏；
将水泥-石膏-水混合物与辅助材料和增强纤维共混；和
将流变改性剂添加至混合物。
19.根据权利要求15所述的方法，其中将水泥、辅助材料、增强纤维和流变改性剂与水混合的步骤包括以下步骤：
将水泥和石膏与水混合；
将水泥-石膏-水混合物与辅助材料和增强纤维共混；和
将流变改性剂添加至混合物。
20.根据权利要求15所述的方法，所述混合物具有粘土状稠度。
21.根据权利要求15所述的方法，使用挤出机通过模具挤出混合物的步骤包括以下步骤：
使用螺旋输送机输送所述混合物通过筒；和
使用挤出机通过模具连续地将所述混合物成形为具有形状稳定性的最终形状。
22.根据权利要求15所述的方法，所述辅助材料包括砂、硅粉、火成二氧化硅、飞灰、矿渣、岩石、纤维素纤维、玻璃纤维、塑料纤维、聚乙烯醇(PVA)纤维或其组合。
23.根据权利要求15所述的方法，所述增强纤维包括纤维素纤维、玻璃纤维、聚丙烯纤维、聚乙烯醇(PVA)纤维、德兰尼特纤维或其组合。
24.根据权利要求15所述的方法，所述流变改性剂包括多糖、多糖衍生物、蛋白质、蛋白质衍生物、合成有机材料、合成有机材料衍生物或其组合。
25.根据权利要求24所述的方法，所述多糖包括纤维素基材料、纤维素基材料衍生物、淀粉基材料、淀粉基材料衍生物或其组合。
26.根据权利要求25所述的方法，所述纤维素基材料选自主要由以下组成的组：甲基羟乙基纤维素(MHEC)、羟甲基乙基纤维素(HMEC)、羧甲基纤维素(CMC)、甲基纤维素(MC)、乙基纤维素(EC)、羟乙基纤维素(HEC)、羟乙基丙基纤维素(HEPC)和羟丙基甲基纤维素(HPMC)。
27.根据权利要求25所述的方法，所述淀粉基材料选自主要由以下组成的组：小麦淀粉、预胶凝小麦淀粉、马铃薯淀粉、预胶凝马铃薯淀粉、支链淀粉、直链淀粉、海凝胶、淀粉乙酸酯、淀粉羟乙基醚、离子淀粉、长链烷基淀粉、糊精、胺淀粉、磷酸盐淀粉或双醛淀粉。
28.根据权利要求15所述的方法，其中所述混合步骤进一步包括将以湿重百分比计约0.1-8％范围内的缓凝剂与水混合。
29.根据权利要求28所述的方法，所述缓凝剂包括柠檬酸钠，或者熟石膏、柠檬酸钠和结晶二氧化硅的混合物。
30.根据权利要求15所述的方法，所述可挤出的水泥基材料在凝固、固化或干燥之后具有约1.4至2.4g/cm3范围内的密度、约5MPa至100MPa范围内的抗压强度和约5至35MPa范围内的抗弯强度。
31.根据权利要求15所述的方法，其中挤出的混合物包括细长片材，并且进一步包括通过一组或多组压延机轧制细长片材的步骤。
32.根据权利要求31所述的方法，进一步包括以下步骤：
将所述细长片材切割成具有指定长度的一组单独片材；
将所述一组单独的片材堆叠到托盘上；
用塑料和绝缘材料覆盖堆叠物；
通过使被覆盖的堆叠物静置指定的时间段来固化所述堆叠物；和
弄方正和砂磨每个单独片材。
33.根据权利要求32所述的方法，其中所述指定的时间段为约24至48小时。
34.根据权利要求15所述的方法，其中使挤出的混合物凝固最长达2至3小时。
35.根据权利要求15所述的方法，进一步包括固化挤出的混合物的步骤。
36.根据权利要求15所述的方法，进一步包括干燥挤出的混合物的步骤。
37.根据权利要求15所述的方法，进一步包括将挤出的混合物模制、切割、修整、砂磨或者特形铣成指定形状的步骤。
38.根据权利要求15所述的方法，进一步包括用防水剂喷涂挤出的混合物的步骤。
39.根据权利要求15所述的方法，进一步包括将一种或多种涂料或油墨施加至挤出的混合物的步骤。
40.根据权利要求39所述的方法，其中所述一种或多种涂料或油墨包括UV涂料、防火涂料、颜料、图像、纹理或其组合。
CN201580033711.1A 2014-06-05 2015-06-05 挤出的水泥基材料 Pending CN106715356A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462007984P 2014-06-05 2014-06-05
US62/007984 2014-06-05
PCT/US2015/034397 WO2015188054A1 (en) 2014-06-05 2015-06-05 Extruded cement based materials

Publications (1)

Publication Number Publication Date
CN106715356A true CN106715356A (zh) 2017-05-24

Family

ID=54767423

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201580033711.1A Pending CN106715356A (zh) 2014-06-05 2015-06-05 挤出的水泥基材料

Country Status (7)

Country Link
US (1) US10538459B2 (zh)
EP (1) EP3157884A4 (zh)
CN (1) CN106715356A (zh)
AU (4) AU2015269315A1 (zh)
BR (1) BR112016028409B1 (zh)
CA (1) CA2985505C (zh)
WO (1) WO2015188054A1 (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115636649A (zh) * 2022-10-24 2023-01-24 上海镎素工业技术有限公司 可挤出加工水泥基材料及其制备方法
CN116589232A (zh) * 2023-05-16 2023-08-15 王柏泉 胶体挤出压延板用组合物、胶体挤出压延板及其制造方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105473529A (zh) * 2013-04-24 2016-04-06 知识产权古里亚有限责任公司 挤出的轻质热绝缘水泥基材料
US11072562B2 (en) * 2014-06-05 2021-07-27 The Intellectual Gorilla Gmbh Cement-based tile
GB201420676D0 (en) 2014-11-20 2015-01-07 Bpb Ltd Construction panel having improved fixing strength
WO2018209444A1 (en) * 2017-05-19 2018-11-22 Fpinnovations Cellulose filaments reinforced cement composite board and method for the manufacture of the same
EP3539938A1 (en) * 2018-03-17 2019-09-18 Hindustan Zinc Limited Method for manufacturing of paver blocks and bricks from industrial waste
CN110041011A (zh) * 2019-05-28 2019-07-23 四川益好优科环保科技有限公司 一种高无机物填充的辐射交联聚乙烯醇材料及制备方法
US20250361183A1 (en) * 2024-05-24 2025-11-27 Onx, Inc. Plaster material composition for use in construction and methods of preparing the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4416695A (en) * 1979-08-22 1983-11-22 National Research Development Corporation Hydraulic cements
US6030446A (en) * 1996-05-29 2000-02-29 Peerless Block & Brick Co. Cementitious compositions and lightweight structural units
US20040258901A1 (en) * 1998-04-20 2004-12-23 Bpb Plc. Gypsum plaster
CN101351418A (zh) * 2005-12-27 2009-01-21 日本油脂株式会社 用于挤出模塑的胶合剂基组合物、其制造方法和胶合剂产品
CN102712531A (zh) * 2009-11-24 2012-10-03 E·喀硕吉工业有限责任公司 具有类似木材的特性和超高强度的挤压成型的纤维增强水泥制品以及制造该制品的方法

Family Cites Families (276)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US570391A (en) 1896-10-27 Fireproof door
US1048923A (en) 1911-06-09 1912-12-31 James A Wheeler Fireproof door.
GB1265471A (zh) 1967-11-23 1972-03-01
US3517468A (en) 1968-07-22 1970-06-30 John Thomas Woods Audiometric enclosure
US3852083A (en) 1972-03-30 1974-12-03 J Yang Manufacture of plaster of paris products containing latex
GB1478964A (en) 1973-06-21 1977-07-06 Credelca Ag Buildings
US3908062A (en) 1974-01-21 1975-09-23 United States Gypsum Co Fire-resistant, composite panel and method of making same
CA1030705A (en) 1974-01-30 1978-05-09 Champion International Corporation Asbestos-free fire resistant compositions and products therefrom
JPS514216A (ja) 1974-07-01 1976-01-14 Mitsubishi Petrochemical Co Setsukoseikeihinseizoyososeibutsu
JPS5433722Y2 (zh) 1974-10-11 1979-10-17
US3994110A (en) 1975-04-10 1976-11-30 Champion International Corporation Three hour fire resistant door, panel or building element, and method of manufacturing the same
US4159302A (en) 1975-10-14 1979-06-26 Georgia-Pacific Corporation Fire door core
US3987600A (en) 1975-12-10 1976-10-26 United States Gypsum Company Fire resistant doors
US4084571A (en) 1976-09-20 1978-04-18 The Tappan Company See-through oven door with reticulated heat shield
JPS5376458A (en) 1976-12-17 1978-07-06 Shikoku Kaken Kogyo Kk Heat retaining and insulating plate
MX147334A (es) 1977-09-30 1982-11-17 Walls Mycelo Jose Composicion mejorada de arido ligero de particulas discretas porosas y expandidas
US4343127A (en) 1979-02-07 1982-08-10 Georgia-Pacific Corporation Fire door
US4225357A (en) 1979-03-09 1980-09-30 Harry Hodson Method of producing and distributing a pervious concrete product
US4225247A (en) 1979-03-09 1980-09-30 Harry Hodson Mixing and agitating device
US4339487A (en) 1979-05-16 1982-07-13 Mullet Willis J Door panel and manner of making same
US4284119A (en) 1979-07-23 1981-08-18 Martin Overhead Door And Electronics Co. Overhead door and overhead door section system and method
US4347653A (en) 1979-07-23 1982-09-07 Martin Overhead Door And Electronics Company Method of preparing a section for an overhead door
US4302127A (en) 1979-11-13 1981-11-24 Harry Hodson Applicator and distributor assembly
IL61258A (en) 1980-10-13 1983-12-30 Mordechai Shechter Method of prefabricated construction and building structure constructed in accordance with such method
US4434899A (en) 1980-11-17 1984-03-06 Liberty Carton Co. Adjustable wire tote for printed circuit boards
US4398842A (en) 1980-12-29 1983-08-16 Harry Hodson Method of overlay and sandwich formation of pervious concrete
US4428775A (en) 1981-02-11 1984-01-31 National Gypsum Company Reinforced cement sheet product containing no asbestos for fabricating on hatschek machine
CA1176024A (en) 1981-09-28 1984-10-16 J. Douglas Dickson Edge-to-edge panel connection
CA1217680A (en) 1983-01-13 1987-02-10 John S. Luckanuck Fire-resistant sandwich core assembly
US4552463A (en) 1984-03-15 1985-11-12 Harry Hodson Method and apparatus for producing a colloidal mixture
AT380292B (de) 1984-05-17 1986-05-12 Atlas Blech Center Gmbh Dichtung fuer gebaeudeteile
US4664707A (en) 1985-04-09 1987-05-12 Georgia-Pacific Corporation Fire resistant gypsum composition
US4630420A (en) 1985-05-13 1986-12-23 Rolscreen Company Door
US4889428A (en) 1985-07-29 1989-12-26 Concrete Technology Corporation Rotary mill
US4800538A (en) 1986-03-31 1989-01-24 Refraction Technology, Inc. Method of and systems for seismic exploration
US4704834A (en) 1986-11-24 1987-11-10 Turner Terry A Raised panel-style door
US4695494A (en) 1986-11-25 1987-09-22 Georgia-Pacific Corporation Fire-resistant article and method of manufacture
US4811538A (en) 1987-10-20 1989-03-14 Georgia-Pacific Corporation Fire-resistant door
US4864789A (en) 1988-06-02 1989-09-12 Therma-Tru Corp. Compression molded door assembly
US4922674A (en) 1988-06-15 1990-05-08 Therma-Tru Corp. Compression molded door assembly
US5061319A (en) 1988-08-19 1991-10-29 Concrete Technology Corporation Process for producing cement building material
US4946504A (en) 1988-08-19 1990-08-07 Concrete Technology Corporation Cement building material
US5232496A (en) 1988-08-19 1993-08-03 E. Khashoggi Industries Process for producing improved building material and product thereof
US4944595A (en) 1988-08-19 1990-07-31 Simon Hodson Apparatus for producing cement building material
US5108677A (en) 1988-10-17 1992-04-28 John Ayres Method of forming a sand base article using a decomposable binder and the article formed thereby
US5317119A (en) 1988-10-17 1994-05-31 Nu-Tech & Engineering, Inc. Oven safe disposable food container
US5066080A (en) 1988-11-14 1991-11-19 National Products, Inc. Tambour door and method of making
US4896471A (en) 1989-01-23 1990-01-30 Truline Manufacturing Inc. Fire roof panel door
US4998598A (en) 1989-05-30 1991-03-12 The Ceco Corporation Acoustical door
US5505987A (en) 1989-10-10 1996-04-09 Jennings; Hamlin M. Processes for improving the bond between hydrating cement-based materials and existing cement-based substrates
US5695811A (en) 1989-10-10 1997-12-09 E. Khashoggi Industries Methods and compositions for bonding a cement-based overlay on a cement-based substrate
US5155959A (en) 1989-10-12 1992-10-20 Georgia-Pacific Corporation Firedoor constructions including gypsum building product
US5171366A (en) 1989-10-12 1992-12-15 Georgia-Pacific Corporation Gypsum building product
US5347780A (en) 1989-10-12 1994-09-20 Georgia-Pacific Corporation Gypsum fiberboard door frame
US5305577A (en) 1989-10-12 1994-04-26 Georgia-Pacific Corporation Fire-resistant structure containing gypsum fiberboard
JP2539125B2 (ja) 1990-02-06 1996-10-02 ビオパック・ビオロギッシェ・フエルパックングス ジステメ・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング 澱粉を基礎とする腐食性の肉薄成形体の製造方法
US5637412A (en) 1990-05-18 1997-06-10 E. Khashoggi Industries Compressed hydraulically bonded composite articles
AU7962291A (en) 1990-05-18 1991-12-10 E. Khashoggi Industries Hydraulically bonded cement compositions and their methods of manufacture and use
US5169566A (en) 1990-05-18 1992-12-08 E. Khashoggi Industries Engineered cementitious contaminant barriers and their method of manufacture
US5356579A (en) 1990-05-18 1994-10-18 E. Khashoggi Industries Methods of manufacture and use for low density hydraulically bonded cement compositions
US5100586A (en) 1990-07-20 1992-03-31 E. Khashoggi Industries Cementitious hazardous waste containers and their method of manufacture
JPH0489339A (ja) * 1990-07-31 1992-03-23 Sekisui Chem Co Ltd 押出成形用セメント組成物
US5074087A (en) 1990-10-10 1991-12-24 Pease Industries, Inc. Doors of composite construction
KR930001645B1 (ko) 1991-02-13 1993-03-08 삼성전자주식회사 자동 트랙킹 방법
US5154358A (en) 1991-03-05 1992-10-13 Nordson Corporation Repulsion device for low capacitance electrostatic painting systems
US5339522A (en) 1991-06-10 1994-08-23 Groupe Herve Pomerleau Inc. Method for constructing modular doors
US5250578A (en) 1991-07-05 1993-10-05 Cornwell Charles E Foamed cementitious composition and method of making
JP3131701B2 (ja) 1991-08-26 2001-02-05 リグナイト株式会社 耐火性ドア
US5239799A (en) 1991-08-28 1993-08-31 The Stanley Works Insulated door with synthetic resin skins
ZA926178B (en) 1991-08-30 1993-04-26 Plascon Tech Method of making a building board.
US5242078A (en) 1991-10-01 1993-09-07 Franz Haas Waffelmaschinen Industriegesellschaft M.B.H. Biodegradable ribbed dish
JP2986986B2 (ja) 1991-10-09 1999-12-06 浅野スレート株式会社 高強度石膏板の製造方法
AU3903793A (en) 1992-04-23 1993-11-29 Rivdal Developments Limited A panel and a method for producing the panel
CA2084494C (en) 1992-04-28 1997-06-24 Peter Paul Roosen Plasticised gypsum composition
US5665439A (en) 1992-08-11 1997-09-09 E. Khashoggi Industries Articles of manufacture fashioned from hydraulically settable sheets
US5631097A (en) * 1992-08-11 1997-05-20 E. Khashoggi Industries Laminate insulation barriers having a cementitious structural matrix and methods for their manufacture
US5506046A (en) 1992-08-11 1996-04-09 E. Khashoggi Industries Articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix
US5662731A (en) 1992-08-11 1997-09-02 E. Khashoggi Industries Compositions for manufacturing fiber-reinforced, starch-bound articles having a foamed cellular matrix
US5549859A (en) 1992-08-11 1996-08-27 E. Khashoggi Industries Methods for the extrusion of novel, highly plastic and moldable hydraulically settable compositions
WO1994004330A1 (en) 1992-08-11 1994-03-03 E. Khashoggi Industries Hydraulically settable containers
US5679145A (en) 1992-08-11 1997-10-21 E. Khashoggi Industries Starch-based compositions having uniformly dispersed fibers used to manufacture high strength articles having a fiber-reinforced, starch-bound cellular matrix
US5618341A (en) 1992-08-11 1997-04-08 E. Khashoggi Industries Methods for uniformly dispersing fibers within starch-based compositions
US5453310A (en) 1992-08-11 1995-09-26 E. Khashoggi Industries Cementitious materials for use in packaging containers and their methods of manufacture
US5800647A (en) 1992-08-11 1998-09-01 E. Khashoggi Industries, Llc Methods for manufacturing articles from sheets having a highly inorganically filled organic polymer matrix
US5783126A (en) 1992-08-11 1998-07-21 E. Khashoggi Industries Method for manufacturing articles having inorganically filled, starch-bound cellular matrix
US5545297A (en) 1992-08-11 1996-08-13 E. Khashoggi Industries Methods for continuously placing filaments within hydraulically settable compositions being extruded into articles of manufacture
US5851634A (en) 1992-08-11 1998-12-22 E. Khashoggi Industries Hinges for highly inorganically filled composite materials
US5928741A (en) 1992-08-11 1999-07-27 E. Khashoggi Industries, Llc Laminated articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix
US5580409A (en) 1992-08-11 1996-12-03 E. Khashoggi Industries Methods for manufacturing articles of manufacture from hydraulically settable sheets
US5508072A (en) 1992-08-11 1996-04-16 E. Khashoggi Industries Sheets having a highly inorganically filled organic polymer matrix
US5658603A (en) 1992-08-11 1997-08-19 E. Khashoggi Industries Systems for molding articles having an inorganically filled organic polymer matrix
US5830305A (en) 1992-08-11 1998-11-03 E. Khashoggi Industries, Llc Methods of molding articles having an inorganically filled organic polymer matrix
US5810961A (en) 1993-11-19 1998-09-22 E. Khashoggi Industries, Llc Methods for manufacturing molded sheets having a high starch content
US5683772A (en) 1992-08-11 1997-11-04 E. Khashoggi Industries Articles having a starch-bound cellular matrix reinforced with uniformly dispersed fibers
US5830548A (en) 1992-08-11 1998-11-03 E. Khashoggi Industries, Llc Articles of manufacture and methods for manufacturing laminate structures including inorganically filled sheets
US5709827A (en) 1992-08-11 1998-01-20 E. Khashoggi Industries Methods for manufacturing articles having a starch-bound cellular matrix
US5545450A (en) 1992-08-11 1996-08-13 E. Khashoggi Industries Molded articles having an inorganically filled organic polymer matrix
US5641584A (en) 1992-08-11 1997-06-24 E. Khashoggi Industries Highly insulative cementitious matrices and methods for their manufacture
US5660903A (en) 1992-08-11 1997-08-26 E. Khashoggi Industries Sheets having a highly inorganically filled organic polymer matrix
US5720913A (en) 1992-08-11 1998-02-24 E. Khashoggi Industries Methods for manufacturing sheets from hydraulically settable compositions
US5580624A (en) 1992-08-11 1996-12-03 E. Khashoggi Industries Food and beverage containers made from inorganic aggregates and polysaccharide, protein, or synthetic organic binders, and the methods of manufacturing such containers
US5582670A (en) 1992-08-11 1996-12-10 E. Khashoggi Industries Methods for the manufacture of sheets having a highly inorganically filled organic polymer matrix
US5527387A (en) 1992-08-11 1996-06-18 E. Khashoggi Industries Computer implemented processes for microstructurally engineering cementious mixtures
JPH0656497A (ja) 1992-08-13 1994-03-01 Sansou:Kk アルミナセメント複合材料
US5716675A (en) 1992-11-25 1998-02-10 E. Khashoggi Industries Methods for treating the surface of starch-based articles with glycerin
US5401588A (en) 1992-12-23 1995-03-28 Georgia-Pacific Resins Inc. Gypsum microfiber sheet material
DE4244578C2 (de) 1992-12-31 1996-05-09 Langenhorst Eva Revisionsabdeckung
DK169728B1 (da) 1993-02-02 1995-01-23 Stein Gaasland Fremgangsmåde til frigørelse af cellulosebaserede fibre fra hinanden i vand og støbemasse til plastisk formning af celluloseholdige fiberprodukter
US5543186A (en) 1993-02-17 1996-08-06 E. Khashoggi Industries Sealable liquid-tight, thin-walled containers made from hydraulically settable materials
US5738921A (en) 1993-08-10 1998-04-14 E. Khashoggi Industries, Llc Compositions and methods for manufacturing sealable, liquid-tight containers comprising an inorganically filled matrix
US5482551A (en) 1993-09-20 1996-01-09 Armstrong World Industries, Inc. Extruded fire resistant construction and building products
US5417024A (en) 1993-10-23 1995-05-23 The Maiman Company Fire resistant panel door
US5522195A (en) 1993-11-15 1996-06-04 Bargen; Theodore J. Energy-efficient fire door
US6083586A (en) 1993-11-19 2000-07-04 E. Khashoggi Industries, Llc Sheets having a starch-based binding matrix
US5736209A (en) 1993-11-19 1998-04-07 E. Kashoggi, Industries, Llc Compositions having a high ungelatinized starch content and sheets molded therefrom
ES2123942T3 (es) 1993-12-06 1999-01-16 Khashoggi E Ind Procedimiento para la obtencion de cuerpos moldeables degradables de pared delgada, a base de almidon.
CA2182014A1 (en) 1994-02-01 1995-08-10 Surendra P. Shah Extruded fiber-reinforced cement matrix composites and method of making same
US5705203A (en) 1994-02-07 1998-01-06 E. Khashoggi Industries Systems for molding articles which include a hinged starch-bound cellular matrix
US5776388A (en) 1994-02-07 1998-07-07 E. Khashoggi Industries, Llc Methods for molding articles which include a hinged starch-bound cellular matrix
US5843544A (en) 1994-02-07 1998-12-01 E. Khashoggi Industries Articles which include a hinged starch-bound cellular matrix
US5433189A (en) 1994-02-17 1995-07-18 Maytag Corporation Oven door heat dissipation system
CA2139373C (en) 1994-05-12 2002-06-25 Therese A. Espinoza Ready-mixed, setting type joint compound
CA2140162A1 (en) 1995-01-13 1996-07-14 Materiaux De Construction 2 Plus 2 Inc. Modular anti-warping door structure
US5740635A (en) 1995-01-24 1998-04-21 Gil; Maria Desamparados Mateu Enclosure fire-resistive for a predetermined time
US5601888A (en) 1995-02-14 1997-02-11 Georgia-Pacific Corporation Fire-resistant members containing gypsum fiberboard
US6067699A (en) 1995-04-19 2000-05-30 Jeld-Wen, Inc. Method for assembling a multi-panel door
US6161363A (en) 1995-06-07 2000-12-19 Herbst; Walter B. Molded door frame and method
US5887402A (en) 1995-06-07 1999-03-30 Masonite Corporation Method of producing core component, and product thereof
US5644870A (en) 1995-06-14 1997-07-08 Nan Ya Plastics Corporation Compression molded door assembly
US5720142A (en) 1995-12-29 1998-02-24 Wayne-Dalton Corp. Foam-filled door and method of manufacture
US5792427A (en) 1996-02-09 1998-08-11 Forma Scientific, Inc. Controlled atmosphere incubator
US5653075A (en) 1996-02-26 1997-08-05 Smartdoor Fiberglass Systems, Inc. Field alterable, glass reinforced plastic door panel
US5786080A (en) 1996-04-03 1998-07-28 E. Khashoggi Industries Compositions and methods for manufacturing ettringite coated fibers and aggregates
US6168857B1 (en) 1996-04-09 2001-01-02 E. Khashoggi Industries, Llc Compositions and methods for manufacturing starch-based compositions
US5749178A (en) 1996-08-06 1998-05-12 Garmong; Victor H. Shielded enclosure
US5782055A (en) 1996-11-22 1998-07-21 Crittenden; Jerry G. Door Apparatus and method of making door
US5916077A (en) 1997-02-20 1999-06-29 Chuan Mau Products, Ltd. Composite fire-proof, heat-barrier door
RU2132829C1 (ru) 1997-09-25 1999-07-10 Александров Юрий Юрьевич Способ получения листового теплоизоляционного материала на основе волластонита
JPH11147777A (ja) 1997-11-14 1999-06-02 Kanegafuchi Chem Ind Co Ltd 軽量硬化物及びその製造方法
GB2336585B (en) * 1998-04-20 2002-06-26 Bpb Plc Gypsum plaster
US6119411A (en) 1998-09-08 2000-09-19 Mateu Gil; Maria Desamparados Enclosure which is fire-resistive for a predetermined period of time
US6311454B1 (en) 1999-02-18 2001-11-06 Globe Door, L.L.C. Door construction
DE19933410B4 (de) 1999-07-21 2005-12-15 Dorma Gmbh + Co. Kg Brandschutztür oder -fenster
DE19933406A1 (de) 1999-07-21 2001-03-01 Dorma Gmbh & Co Kg Brandschutztür mit einem diese umfassenden Türstock
US6268022B1 (en) 1999-09-03 2001-07-31 Morton International, Inc. Process for coating cabinet doors
US6115976A (en) 1999-09-20 2000-09-12 Wood Door Products, Inc. Door edge assembly for creating a smoke seal about a closed door mounted within a door frame
US6475275B1 (en) 1999-10-21 2002-11-05 Isolatek International Cement composition
US6231970B1 (en) 2000-01-11 2001-05-15 E. Khashoggi Industries, Llc Thermoplastic starch compositions incorporating a particulate filler component
US20020078659A1 (en) 2000-12-21 2002-06-27 Hunt Christopher M. Methods of manufacturing and constructing a habitable, cementitious structure
US6485561B1 (en) 2000-03-03 2002-11-26 Clinton D. Dattel Low density cellular concrete with accelerators for rapid hardening
CA2402886C (en) 2000-03-14 2012-02-14 James Hardie Research Pty Limited Fiber cement building materials with low density additives
JP4407779B2 (ja) 2000-03-27 2010-02-03 信越化学工業株式会社 押出成形用の水硬性組成物用バインダー及び水硬性組成物並びに押出成形品の製造方法
US6494704B1 (en) 2000-03-31 2002-12-17 E. Khashoggi Industries, Llc Mold apparatus
US6379446B1 (en) 2000-04-03 2002-04-30 E. Khashoggi Industries, Llc. Methods for dispersing fibers within aqueous compositions
US6327821B1 (en) 2000-04-14 2001-12-11 Wen Fu Chang Structure of a fire-proof refuge shelter
US6347934B1 (en) 2000-05-10 2002-02-19 E. Khashoggi Industries, Llc. System for metering and delivering a moldable composition into a mold
US6773500B1 (en) 2000-05-31 2004-08-10 Isg Resources, Inc. Fiber reinforced aerated concrete and methods of making same
US20030115817A1 (en) 2000-06-22 2003-06-26 New Horizons Shutters, Inc. Reinforced window shutter
DE10036030B4 (de) 2000-07-24 2004-05-13 Rational Ag Garraum-Isolierglastür für ein Gargerät
US6584667B1 (en) 2000-07-25 2003-07-01 Gregory Frumkin Panel door construction and method of making same
US6688063B1 (en) 2000-07-25 2004-02-10 Larson Manufacturing Company Wood core exterior door with mortise lock
KR20030068125A (ko) 2000-08-07 2003-08-19 라파르쥐 쁠라뜨르 경량 석고 보드 제품 및 제조 방법
DE10042071C1 (de) 2000-08-16 2002-03-21 Mattig & Lindner Gmbh Poröses silikatisches Granulat und Verfahren zu dessen Herstellung
US6573340B1 (en) 2000-08-23 2003-06-03 Biotec Biologische Naturverpackungen Gmbh & Co. Kg Biodegradable polymer films and sheets suitable for use as laminate coatings as well as wraps and other packaging materials
JP2004510585A (ja) 2000-09-29 2004-04-08 ザルツギッター・アントリープシュテヒニーク・ゲーエムベーハー・ウント・コンパニー・カーゲー ホローシャフト、特にカムシャフトを製造する方法及びこの方法によって製造されたホローシャフト
US6572355B1 (en) 2000-10-03 2003-06-03 Libbey-Owens-Ford Co. Window sash construction and method and apparatus for manufacture thereof
WO2002031306A1 (en) 2000-10-12 2002-04-18 Mdf, Inc. Fire door and method of assembly
GB2368364B (en) 2000-10-12 2004-06-02 Mdf Inc Fire door and method of assembly
US6643991B1 (en) 2000-10-12 2003-11-11 Premdor International, Inc. Fire door and method of assembly
US6402830B1 (en) 2000-11-20 2002-06-11 Randy C. Schaffer Lightweight concrete composition
US20020053757A1 (en) 2001-01-11 2002-05-09 Andersen Per Just Methods and systems for removing flashing and other irregularities from molded starch-bound articles
BR0207808A (pt) 2001-03-02 2004-03-09 James Hardie Res Pty Ltd Aparelho de salpicamento
KR20040030525A (ko) 2001-03-05 2004-04-09 제임스 하디 리서치 피티와이 리미티드 시멘트 제품용 저밀도 규산칼슘 수화물 강도 촉진 첨가제
US6743830B2 (en) 2001-03-07 2004-06-01 Innovative Construction And Building Materials Construction board materials with engineered microstructures
US6866081B1 (en) 2001-03-09 2005-03-15 Larson Manufacturing Company Of South Dakota, Inc. Exterior door or window having extruded composite frame
US6434899B1 (en) 2001-03-12 2002-08-20 Skamol A/S Fire resistant door edge construction comprising a stile with groove, high density strip in the groove, an intumescent strip seal, covered by an edge lipping
US7241832B2 (en) 2002-03-01 2007-07-10 bio-tec Biologische Naturverpackungen GmbH & Co., KG Biodegradable polymer blends for use in making films, sheets and other articles of manufacture
US7297394B2 (en) 2002-03-01 2007-11-20 Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg Biodegradable films and sheets suitable for use as coatings, wraps and packaging materials
US6886306B2 (en) 2001-05-04 2005-05-03 Greencor Composites, Llc Fire-resistant material and method of manufacture
JP3891256B2 (ja) 2001-06-13 2007-03-14 信越化学工業株式会社 押出成形用水硬性組成物及びその硬化体
US6843543B2 (en) 2001-06-22 2005-01-18 Roahan Ramesh Weatherproof enclosure with a modular structure
US6648965B2 (en) 2001-07-06 2003-11-18 G-P Gypsum Corporation Fire door components and fire doors comprising the components
US20030033786A1 (en) 2001-08-17 2003-02-20 Leon Yulkowski Fire door assembly
US20030084980A1 (en) 2001-11-06 2003-05-08 Seufert James F Lightweight gypsum wallboard and method of making same
US6665997B2 (en) 2002-02-05 2003-12-23 Kuei Yung Wang Chen Edge inserts for stiles of molded doors
US7059092B2 (en) 2002-02-26 2006-06-13 Washington Hardwoods Co., Llc Fire-resistant wood assemblies for building
US6696979B2 (en) 2002-03-06 2004-02-24 Howard Manten Double door security system for aircraft and the like
US6764625B2 (en) 2002-03-06 2004-07-20 Masonite Corporation Method of producing core component, and product thereof
US6779859B2 (en) 2002-03-15 2004-08-24 Maytag Corporation Freezer door assembly
US8163081B2 (en) 2002-04-04 2012-04-24 Kirby Wayne Beard Composite materials using novel reinforcements
US6619005B1 (en) 2002-04-16 2003-09-16 Kuei Yung Wang Chen Molded doors with large glass insert
US6823810B2 (en) 2002-05-01 2004-11-30 Harris Acoustic Products Corporation Wireless ballast water monitoring and reporting system and marine voyage data recorder system
US6766621B2 (en) 2002-05-13 2004-07-27 Snavely Forest Products Reinforced door stile
US20030211252A1 (en) 2002-05-13 2003-11-13 Daniels Evan R. Method and apparatus for horizontal powder coating
US20030209403A1 (en) 2002-05-13 2003-11-13 Daniels Evan R. Method and process for loading and unloading parts
US20030211251A1 (en) 2002-05-13 2003-11-13 Daniels Evan R. Method and process for powder coating molding
US6890604B2 (en) 2002-05-13 2005-05-10 Trio Industries Holdings, Llc Method and system for powder coating passage doors
US7311964B2 (en) 2002-07-30 2007-12-25 Saint-Gobain Technical Fabrics Canada, Ltd. Inorganic matrix-fabric system and method
US6964722B2 (en) 2002-08-07 2005-11-15 Trio Industries Holdings, L.L.C. Method for producing a wood substrate having an image on at least one surface
US7185468B2 (en) 2002-10-31 2007-03-06 Jeld-Wen, Inc. Multi-layered fire door and method for making the same
AU2003298624A1 (en) 2002-11-12 2004-06-03 Masonite Corporation A door skin, method of manufacturing a door produced therewith, and door produced therefrom
US6745526B1 (en) 2003-04-16 2004-06-08 Enrico Autovino Fire retardant wooden door with intumescent materials
JP2004332401A (ja) 2003-05-08 2004-11-25 Sekisui Chem Co Ltd 防・耐火パネル及び木製防火戸
US7328539B2 (en) 2003-05-22 2008-02-12 Jeld-Wen, Inc. Door and method of making same
US20070157537A1 (en) 2003-07-28 2007-07-12 Dave Nicolson Molded stone architectural product having a foam core
US7617606B2 (en) 2003-08-21 2009-11-17 Inno-Tech Plastics, Inc. Composite door, door core and method of manufacture
US7090897B2 (en) 2003-10-10 2006-08-15 Hardesty Jon H Electrically conductive MDF surface
US7621102B2 (en) 2003-10-14 2009-11-24 E.M.E.H., Inc. Door edge construction
US7886501B2 (en) 2003-10-14 2011-02-15 Construction Specialties, Inc. Door edge construction
US20050227006A1 (en) 2004-04-08 2005-10-13 Segall Ronald H Methods for preparing an imaged composite
JP2007534606A (ja) 2004-04-27 2007-11-29 ハーキュリーズ・インコーポレーテッド 未加工コットンリンターから製造された水分保持剤を用いた石膏ベースのモルタル
US20050241543A1 (en) * 2004-04-27 2005-11-03 Wolfgang Hagen Cement-based systems using plastification/extrusion auxiliaries prepared from raw cotton linters
US20050284030A1 (en) 2004-06-14 2005-12-29 Enrico Autovino Fire retardant panel door and door frame having intumescent materials therein
US20060070321A1 (en) 2004-09-29 2006-04-06 R E P Technologies Ltd. Fire-resistant panel and method of manufacture
US20060096240A1 (en) 2004-10-26 2006-05-11 Industries 3F, Inc. Fire door core assembly
US7279437B2 (en) 2004-12-02 2007-10-09 Richard H Kai Rated fire door core and method of making
US7849650B2 (en) 2005-01-27 2010-12-14 United States Gypsum Company Non-combustible reinforced cementitious lightweight panels and metal frame system for a fire wall and other fire resistive assemblies
US7669383B2 (en) 2005-02-15 2010-03-02 Warm Springs Composite Products Fire door
CN101132999A (zh) 2005-03-01 2008-02-27 登纳特波拉沃有限公司 制备泡沫玻璃颗粒的方法
AU2006226916B2 (en) 2005-03-22 2011-06-09 Nova Chemicals Inc. Lightweight concrete compositions
CA2607732A1 (en) 2005-06-17 2006-12-28 Icrete, Llc Methods and systems for redesigning pre-existing concrete mix designs and manufacturing plants and design-optimizing and manufacturing concrete
US20070021515A1 (en) 2005-07-19 2007-01-25 United States (as represented by the Secretary of Agriculture) Expandable starch-based beads and method of manufacturing molded articles therefrom
JP4861416B2 (ja) 2005-07-27 2012-01-25 ミルウォーキー・コンポジッツ・インコーポレーテッド 難燃性パネル装置並びにその製造及び使用方法
US20070092712A1 (en) 2005-10-25 2007-04-26 Hodson Simon K Articles having a moisture-resistant protective coating and methods of manufacturing such articles
US7598460B2 (en) 2005-10-28 2009-10-06 Roberts Iv Leonard Pascal Radiation shielding wood or laminate faced door having a high fire rating and method for making same
WO2007053852A2 (en) 2005-11-01 2007-05-10 E. Khashoggi Industries, Llc Cementitious composites having wood-like properties and methods of manufacture
US20080099122A1 (en) 2006-11-01 2008-05-01 E. Khashoggi Industries Llc Cementitious composites having wood-like properties and methods of manufacture
WO2007081685A2 (en) 2006-01-04 2007-07-19 Masonite Corporation Method of forming a core component
MX2008010766A (es) 2006-02-21 2009-03-06 Polymer Wood Technologies Inc Sistema metodo y aparato para producir puertas clasificadas contra fuego.
DE102006015644A1 (de) 2006-03-27 2007-10-04 Frank Ripplinger Mineralschaumgranulat, Verfahren und Anlage zu dessen Herstellung
US8037820B2 (en) 2006-03-30 2011-10-18 William Daniels Decorative, wood fire-rated door and method
US8011165B2 (en) 2006-06-07 2011-09-06 Integritect Consulting, Inc. Composite assembly with saturated bonding mass and process of reinforced attachment
JP2008036549A (ja) 2006-08-08 2008-02-21 Hitachi Plant Technologies Ltd 建築板の塗装方法
US20080086982A1 (en) 2006-09-19 2008-04-17 Martin Parenteau Insulating panel and process of making same
US20080145580A1 (en) 2006-11-07 2008-06-19 Insulastics Inc. Recycled material insulation
US8394191B2 (en) 2006-12-06 2013-03-12 Construction Research & Technology Gmbh Rheology modifying additive for cementitious compositions
US20080152945A1 (en) 2006-12-20 2008-06-26 David Paul Miller Fiber reinforced gypsum panel
DE102007035851A1 (de) 2007-01-13 2008-08-14 Vacuum Walls Ag Vakuum-Isolationspaneel und Herstellungsverfahren dafür
CN101239838B (zh) 2007-02-05 2011-05-04 山东理工大学 粉煤灰陶瓷水洗球的制备方法
JP5223205B2 (ja) 2007-02-19 2013-06-26 信越化学工業株式会社 押出成形用水硬性組成物
US20080286519A1 (en) 2007-05-18 2008-11-20 E. Khashoggi Industries, Llc Molded cementitious architectural products having a polished stone-like surface finish
US8070878B2 (en) * 2007-07-05 2011-12-06 United States Gypsum Company Lightweight cementitious compositions and building products and methods for making same
CN101113077B (zh) 2007-07-20 2010-09-01 内蒙古自治区建筑材料工业科学研究设计院 一种泡沫玻璃的制备方法
CN101778805A (zh) 2007-08-10 2010-07-14 建筑研究和技术有限公司 用于干铸胶凝组合物的流变改性添加剂
US8221542B2 (en) 2007-12-13 2012-07-17 Georgia-Pacific Gypsum Llc Non-cement fire door core
US7927420B2 (en) 2007-12-13 2011-04-19 Georgia-Pacific Gypsum Llc Light weight metal fire door core
US20130008115A1 (en) 2007-12-28 2013-01-10 Timm Bierman Building construction sheathing composites, structures and related methods of use
US8097544B2 (en) 2008-04-01 2012-01-17 Kenneth Majors Rated fire frame and door frame / jamb
US8366823B2 (en) 2008-09-25 2013-02-05 United States Gypsum Company Fly ash based lightweight cementitious composition with high compressive strength and fast set
GB2465430B8 (en) 2008-11-24 2014-01-29 Nanya Plastics Corp A fireproof door panel structure
US7803723B2 (en) 2008-12-16 2010-09-28 Saint-Gobain Technical Fabrics America, Inc. Polyolefin coated fabric reinforcement and cementitious boards reinforced with same
EP2230075A1 (en) 2009-03-17 2010-09-22 Lafarge Gypsum International Surface-treated nonwoven facer for gypsum wallboard
KR101705388B1 (ko) * 2009-04-03 2017-02-09 제임스 하디 테크놀로지 리미티드 시멘트질 물품, 제제, 제조 및 사용 방법
US8277556B2 (en) 2009-06-05 2012-10-02 W. R. Grace & Co.-Conn. Articles made from cementitious foam and slurry
PL2314462T3 (pl) 2009-10-21 2013-04-30 Falquon Gmbh Sposób wytwarzania spajanej cementem płyty, wyposażonej w nadrukowaną warstwę dekoracyjną
US20110120349A1 (en) 2009-11-24 2011-05-26 E. Khashoggi Industries, Llc Extruded fiber reinforced cementitious products having stone-like properties and methods of making the same
US20110131921A1 (en) 2009-12-08 2011-06-09 Kuei Yung Wang Chen Synthetic door with improved fire resistance
RU2411218C1 (ru) 2010-01-11 2011-02-10 Государственное образовательное учреждение высшего профессионального образования "Астраханский государственный университет" (АГУ) Сырьевая смесь для изготовления газобетона
US8528212B2 (en) 2010-01-13 2013-09-10 Quanex Corporation Method of manufacturing a frame assembly having stile and rail tabs for coupling stile and rail members together
CN102510848A (zh) 2010-04-27 2012-06-20 世联株式会社 装饰混凝土砌块和装饰混凝土砌块的制造方法
DE102010021532A1 (de) 2010-05-26 2011-12-01 Evonik Goldschmidt Gmbh Granularer Bims sowie Verfahren zur Herstellung von granularem Bims
CH703868B1 (de) 2010-09-16 2016-06-15 Creabeton Matériaux Sa Baustoff und Bausystem-Element sowie Verfahren zur Herstellung derselben.
CN102001832B (zh) 2010-11-18 2012-01-25 陕西科技大学 一种泡沫玻璃颗粒的制备方法
EP2468695A1 (en) 2010-12-21 2012-06-27 Mapei S.p.A. Method for recycling concrete
CN102167619B (zh) 2011-01-25 2013-05-08 河海大学 低导热加气混凝土及其制备方法
CN102220829A (zh) 2011-06-09 2011-10-19 支亮 一种防火门
WO2013055603A1 (en) 2011-10-11 2013-04-18 820 Industrial Loop Partners Llc Fire rated door core
PT105937A (pt) 2011-10-17 2013-04-17 Secil Martinganca Aglomerantes E Novos Materiais Para A Construcao S A Argamassa leve preparada com granulado de cortiça
EP2785502A4 (en) * 2011-11-30 2015-11-25 Hardie James Technology Ltd LIGHT EXTRUDED CEMENTITIOUS MATERIAL AND MANUFACTURING METHOD THEREOF
US9249053B2 (en) 2012-02-21 2016-02-02 Nano And Advanced Materials Institute Limited Composite wall panel with low thermal conductivity and sufficient strength for structural use
CN102643013B (zh) 2012-04-28 2014-01-29 浙江德和绝热科技有限公司 一种利用废弃玻纤增强酚醛树脂模塑料生产泡沫玻璃的方法
US9375899B2 (en) 2012-06-29 2016-06-28 The Intellectual Gorilla Gmbh Gypsum composites used in fire resistant building components
US9243444B2 (en) * 2012-06-29 2016-01-26 The Intellectual Gorilla Gmbh Fire rated door
US8915033B2 (en) 2012-06-29 2014-12-23 Intellectual Gorilla B.V. Gypsum composites used in fire resistant building components
AU2014225765B2 (en) 2013-03-05 2017-10-26 The Intellectual Gorilla Gmbh Extruded gypsum-based materials
CN105392753A (zh) 2013-04-24 2016-03-09 知识产权古里亚有限责任公司 由玻璃或浮石制备的膨胀轻质骨料

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4416695A (en) * 1979-08-22 1983-11-22 National Research Development Corporation Hydraulic cements
US6030446A (en) * 1996-05-29 2000-02-29 Peerless Block & Brick Co. Cementitious compositions and lightweight structural units
US20040258901A1 (en) * 1998-04-20 2004-12-23 Bpb Plc. Gypsum plaster
CN101351418A (zh) * 2005-12-27 2009-01-21 日本油脂株式会社 用于挤出模塑的胶合剂基组合物、其制造方法和胶合剂产品
CN102712531A (zh) * 2009-11-24 2012-10-03 E·喀硕吉工业有限责任公司 具有类似木材的特性和超高强度的挤压成型的纤维增强水泥制品以及制造该制品的方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115636649A (zh) * 2022-10-24 2023-01-24 上海镎素工业技术有限公司 可挤出加工水泥基材料及其制备方法
CN116589232A (zh) * 2023-05-16 2023-08-15 王柏泉 胶体挤出压延板用组合物、胶体挤出压延板及其制造方法

Also Published As

Publication number Publication date
WO2015188054A1 (en) 2015-12-10
US10538459B2 (en) 2020-01-21
AU2019202740A1 (en) 2019-05-16
AU2015269315A1 (en) 2017-01-19
AU2021203346B2 (en) 2023-08-03
EP3157884A4 (en) 2018-02-28
EP3157884A1 (en) 2017-04-26
CA2985505A1 (en) 2015-12-10
US20170113971A1 (en) 2017-04-27
CA2985505C (en) 2021-05-25
BR112016028409A2 (pt) 2018-07-03
AU2023204681A1 (en) 2023-08-10
AU2021203346A1 (en) 2021-06-24
AU2023204681B2 (en) 2024-08-22
BR112016028409B1 (pt) 2022-09-20

Similar Documents

Publication Publication Date Title
AU2023204681B2 (en) Extruded cement based materials
CN105026142B (zh) 挤出的石膏基材料
CA2909983C (en) Extruded lightweight thermal insulating cement-based materials
US11155499B2 (en) Lightweight thermal insulating cement based materials
US11072562B2 (en) Cement-based tile
HK1235387A1 (zh) 挤出的水泥基材料
US20250236558A1 (en) Cement-based tile
HK40027436A (zh) 挤出的轻质热绝缘水泥基材料
HK1216731B (zh) 挤出的石膏基材料
HK1236506A1 (zh) 基於轻质隔热水泥的材料

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1235387

Country of ref document: HK

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170524

REG Reference to a national code

Ref country code: HK

Ref legal event code: WD

Ref document number: 1235387

Country of ref document: HK