CN106701255A - A kind of multifunctional additive for lubricating oil - Google Patents
A kind of multifunctional additive for lubricating oil Download PDFInfo
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- CN106701255A CN106701255A CN201611149914.XA CN201611149914A CN106701255A CN 106701255 A CN106701255 A CN 106701255A CN 201611149914 A CN201611149914 A CN 201611149914A CN 106701255 A CN106701255 A CN 106701255A
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
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- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2207/287—Partial esters
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/14—Containing carbon-to-nitrogen double bounds, e.g. guanidines, hydrazones, semicarbazones
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- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/026—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrile group
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- C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
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Abstract
本发明涉及一种润滑油多功能添加剂,由以下组分组成:双酚F型环氧树脂、偏苯三甲酸三辛酯、聚‑4‑甲基‑1‑戊烯、乙酸丁酯、丙酸戊酯、二乙二醇乙醚、丙酸异丁酯、甲基苯胺、氰乙基纤维素、硼砂粉末、熊果甘、聚六亚甲基双胍盐酸盐、三氧化钼粉末、石棉粉、石墨粉、四水八硼酸二钠、松烟墨、钛酸钡粉末、碳化钙粉末、碳化硅粉末、六氢化邻苯二甲酸酐、磷酸三甲酯、聚丙烯腈纤维、二盐基性硬脂酸铅、失水山梨醇脂肪酸酯、聚苯乙烯磺酸钠、甘油硬脂酸酯、硬脂酸季戊四醇酯、异辛酸、异佛尔酮二异氰酸酯。本发明产品具有较为优越的性能,改善了产品性能。The present invention relates to a multifunctional lubricating oil additive, which is composed of the following components: bisphenol F type epoxy resin, trioctyl trimellitate, poly-4-methyl-1-pentene, butyl acetate, amyl propionate, diethylene glycol ethyl ether, isobutyl propionate, methylaniline, cyanoethyl cellulose, borax powder, ursolic acid, polyhexamethylene biguanide hydrochloride, molybdenum trioxide powder, asbestos powder, graphite powder, disodium tetrahydrate octaborate, pine smoke ink, barium titanate powder, calcium carbide powder, silicon carbide powder, hexahydrophthalic anhydride, trimethyl phosphate, polyacrylonitrile fiber, dibasic lead stearate, sorbitan fatty acid ester, sodium polystyrene sulfonate, glycerol stearate, stearic acid pentaerythritol ester, isooctanoic acid, isophorone diisocyanate. The product of the present invention has relatively superior performance and improves product performance.
Description
技术领域technical field
本发明涉及一种润滑油多功能添加剂,属于润滑油技术领域。The invention relates to a multifunctional additive for lubricating oil, which belongs to the technical field of lubricating oil.
背景技术Background technique
润滑油是用在各种类型汽车、机械设备上以减少摩擦,保护机械及加工件的液体或半固体润滑剂,主要起润滑、辅助冷却、防锈、清洁、密封和缓冲等作用。只要是应用于两个相对运动的物体之间,而可以减少两物体因接触而产生的磨擦与磨损之功能,即为润滑油。润滑油一般由基础油和添加剂两部分组成。基础油是润滑油的主要成分,决定着润滑油的基本性质,添加剂则可弥补和改善基础油性能方面的不足,赋予某些新的性能,是润滑油的重要组成部分。一般的润滑油添加剂,其性能单一,有必要采用合适的方式予以改进。Lubricating oil is a liquid or semi-solid lubricant used in various types of automobiles and mechanical equipment to reduce friction and protect machinery and processed parts. It mainly plays the roles of lubrication, auxiliary cooling, rust prevention, cleaning, sealing and buffering. As long as it is applied between two relatively moving objects and can reduce the friction and wear of the two objects due to the function of contact, it is a lubricating oil. Lubricating oil generally consists of two parts: base oil and additives. Base oil is the main component of lubricating oil, which determines the basic properties of lubricating oil. Additives can make up for and improve the performance of base oil, endow some new properties, and are an important part of lubricating oil. General lubricating oil additives have single performance, so it is necessary to improve them in an appropriate way.
发明内容Contents of the invention
本发明的目的在于提供一种润滑油多功能添加剂,以便更好地实现润滑油多功能添加剂的使用功能,使产品较好的性能,改善产品使用性能。The purpose of the present invention is to provide a multifunctional additive for lubricating oil, so as to better realize the use function of the multifunctional additive for lubricating oil, improve the performance of the product, and improve the performance of the product.
为了实现上述目的,本发明的技术方案如下。In order to achieve the above object, the technical solution of the present invention is as follows.
一种润滑油多功能添加剂,由以下质量份数的组分组成:双酚F型环氧树脂26~30份、偏苯三甲酸三辛酯24~28份、聚-4-甲基-1-戊烯24~28份、乙酸丁酯22~26份、丙酸戊酯24~28份、二乙二醇乙醚24~28份、丙酸异丁酯22~26份、甲基苯胺24~28份、氰乙基纤维素24~28份、硼砂粉末22~26份、熊果甘22~26份、聚六亚甲基双胍盐酸盐22~26份、三氧化钼粉末24~28份、石棉粉22~26份、石墨粉20~24份、四水八硼酸二钠24~28份、松烟墨22~26份、钛酸钡粉末20~24份、碳化钙粉末22~26份、碳化硅粉末20~24份、六氢化邻苯二甲酸酐20~24份、磷酸三甲酯20~24份、聚丙烯腈纤维18~22份、二盐基性硬脂酸铅14~18份、失水山梨醇脂肪酸酯12~16份、聚苯乙烯磺酸钠12~16份、甘油硬脂酸酯12~16份、硬脂酸季戊四醇酯12~16份、异辛酸12~16份、异佛尔酮二异氰酸酯12~16份。A multifunctional additive for lubricating oil, which consists of the following components in parts by mass: 26-30 parts of bisphenol F epoxy resin, 24-28 parts of trioctyl trimellitate, poly-4-methyl-1 - 24-28 parts of pentene, 22-26 parts of butyl acetate, 24-28 parts of amyl propionate, 24-28 parts of diethylene glycol ethyl ether, 22-26 parts of isobutyl propionate, 24-24 parts of methylaniline 28 parts, 24-28 parts of cyanoethyl cellulose, 22-26 parts of borax powder, 22-26 parts of bearberry, 22-26 parts of polyhexamethylene biguanide hydrochloride, 24-28 parts of molybdenum trioxide powder , 22-26 parts of asbestos powder, 20-24 parts of graphite powder, 24-28 parts of disodium octaborate tetrahydrate, 22-26 parts of pine smoke ink, 20-24 parts of barium titanate powder, 22-26 parts of calcium carbide powder , 20-24 parts of silicon carbide powder, 20-24 parts of hexahydrophthalic anhydride, 20-24 parts of trimethyl phosphate, 18-22 parts of polyacrylonitrile fiber, 14-18 parts of dibasic lead stearate 12-16 parts of sorbitan fatty acid ester, 12-16 parts of sodium polystyrene sulfonate, 12-16 parts of glyceryl stearate, 12-16 parts of pentaerythritol stearate, 12-16 parts of isooctanoic acid 12-16 parts of isophorone diisocyanate.
进一步地,上述润滑油多功能添加剂,由以下质量份数的组分组成:双酚F型环氧树脂26份、偏苯三甲酸三辛酯24份、聚-4-甲基-1-戊烯24份、乙酸丁酯22份、丙酸戊酯24份、二乙二醇乙醚24份、丙酸异丁酯22份、甲基苯胺24份、氰乙基纤维素24份、硼砂粉末22份、熊果甘22份、聚六亚甲基双胍盐酸盐22份、三氧化钼粉末24份、石棉粉22份、石墨粉20份、四水八硼酸二钠24份、松烟墨22份、钛酸钡粉末20份、碳化钙粉末22份、碳化硅粉末20份、六氢化邻苯二甲酸酐20份、磷酸三甲酯20份、聚丙烯腈纤维18份、二盐基性硬脂酸铅14份、失水山梨醇脂肪酸酯12份、聚苯乙烯磺酸钠12份、甘油硬脂酸酯12份、硬脂酸季戊四醇酯12份、异辛酸12份、异佛尔酮二异氰酸酯12份。Further, the above-mentioned multifunctional additive for lubricating oil is composed of the following components in parts by mass: 26 parts of bisphenol F epoxy resin, 24 parts of trioctyl trimellitate, poly-4-methyl-1-pentyl 24 parts of alkene, 22 parts of butyl acetate, 24 parts of amyl propionate, 24 parts of diethylene glycol ether, 22 parts of isobutyl propionate, 24 parts of methyl aniline, 24 parts of cyanoethyl cellulose, 22 parts of borax powder 22 parts of bear fruit, 22 parts of polyhexamethylene biguanide hydrochloride, 24 parts of molybdenum trioxide powder, 22 parts of asbestos powder, 20 parts of graphite powder, 24 parts of disodium octaborate tetrahydrate, 22 parts of pine smoke ink 20 parts, barium titanate powder 20 parts, calcium carbide powder 22 parts, silicon carbide powder 20 parts, hexahydrophthalic anhydride 20 parts, trimethyl phosphate 20 parts, polyacrylonitrile fiber 18 parts, dibasic hard 14 parts of lead fatty acid, 12 parts of sorbitan fatty acid ester, 12 parts of sodium polystyrene sulfonate, 12 parts of glyceryl stearate, 12 parts of pentaerythritol stearate, 12 parts of isooctanoic acid, isophorone 12 parts of diisocyanate.
进一步地,上述润滑油多功能添加剂,由以下质量份数的组分组成:双酚F型环氧树脂28份、偏苯三甲酸三辛酯26份、聚-4-甲基-1-戊烯26份、乙酸丁酯24份、丙酸戊酯26份、二乙二醇乙醚26份、丙酸异丁酯24份、甲基苯胺26份、氰乙基纤维素26份、硼砂粉末24份、熊果甘24份、聚六亚甲基双胍盐酸盐24份、三氧化钼粉末26份、石棉粉24份、石墨粉22份、四水八硼酸二钠26份、松烟墨24份、钛酸钡粉末22份、碳化钙粉末24份、碳化硅粉末22份、六氢化邻苯二甲酸酐22份、磷酸三甲酯22份、聚丙烯腈纤维20份、二盐基性硬脂酸铅16份、失水山梨醇脂肪酸酯14份、聚苯乙烯磺酸钠14份、甘油硬脂酸酯14份、硬脂酸季戊四醇酯14份、异辛酸14份、异佛尔酮二异氰酸酯14份。Further, the above-mentioned multifunctional additive for lubricating oil is composed of the following components in parts by mass: 28 parts of bisphenol F epoxy resin, 26 parts of trioctyl trimellitate, poly-4-methyl-1-pentyl 26 parts of alkene, 24 parts of butyl acetate, 26 parts of amyl propionate, 26 parts of diethylene glycol ether, 24 parts of isobutyl propionate, 26 parts of methyl aniline, 26 parts of cyanoethyl cellulose, 24 parts of borax powder 24 parts of bear fruit, 24 parts of polyhexamethylene biguanide hydrochloride, 26 parts of molybdenum trioxide powder, 24 parts of asbestos powder, 22 parts of graphite powder, 26 parts of disodium octaborate tetrahydrate, 24 parts of pine smoke ink 22 parts, barium titanate powder 22 parts, calcium carbide powder 24 parts, silicon carbide powder 22 parts, hexahydrophthalic anhydride 22 parts, trimethyl phosphate 22 parts, polyacrylonitrile fiber 20 parts, dibasic hard 16 parts of lead fatty acid, 14 parts of sorbitan fatty acid ester, 14 parts of sodium polystyrene sulfonate, 14 parts of glyceryl stearate, 14 parts of pentaerythritol stearate, 14 parts of isooctanoic acid, isophorone 14 parts of diisocyanate.
进一步地,上述润滑油多功能添加剂,由以下质量份数的组分组成:双酚F型环氧树脂30份、偏苯三甲酸三辛酯28份、聚-4-甲基-1-戊烯28份、乙酸丁酯26份、丙酸戊酯28份、二乙二醇乙醚28份、丙酸异丁酯26份、甲基苯胺28份、氰乙基纤维素28份、硼砂粉末26份、熊果甘26份、聚六亚甲基双胍盐酸盐26份、三氧化钼粉末28份、石棉粉26份、石墨粉24份、四水八硼酸二钠28份、松烟墨26份、钛酸钡粉末24份、碳化钙粉末26份、碳化硅粉末24份、六氢化邻苯二甲酸酐24份、磷酸三甲酯24份、聚丙烯腈纤维22份、二盐基性硬脂酸铅18份、失水山梨醇脂肪酸酯16份、聚苯乙烯磺酸钠16份、甘油硬脂酸酯16份、硬脂酸季戊四醇酯16份、异辛酸16份、异佛尔酮二异氰酸酯16份。Further, the above-mentioned multifunctional additive for lubricating oil is composed of the following components in parts by mass: 30 parts of bisphenol F epoxy resin, 28 parts of trioctyl trimellitate, poly-4-methyl-1-pentyl 28 parts of alkene, 26 parts of butyl acetate, 28 parts of pentyl propionate, 28 parts of diethylene glycol ether, 26 parts of isobutyl propionate, 28 parts of methyl aniline, 28 parts of cyanoethyl cellulose, 26 parts of borax powder 26 parts of bear fruit, 26 parts of polyhexamethylene biguanide hydrochloride, 28 parts of molybdenum trioxide powder, 26 parts of asbestos powder, 24 parts of graphite powder, 28 parts of disodium octaborate tetrahydrate, 26 parts of pine smoke ink 24 parts, barium titanate powder 24 parts, calcium carbide powder 26 parts, silicon carbide powder 24 parts, hexahydrophthalic anhydride 24 parts, trimethyl phosphate 24 parts, polyacrylonitrile fiber 22 parts, dibasic hard 18 parts of lead fatty acid, 16 parts of sorbitan fatty acid ester, 16 parts of sodium polystyrene sulfonate, 16 parts of glyceryl stearate, 16 parts of pentaerythritol stearate, 16 parts of isooctanoic acid, isophorone 16 parts of diisocyanate.
进一步地,所述硼砂粉末由三种粒径目数的粉体组成,其粒径目数分别为30~50目、50~80目、80~100目,上述三种粉体的混合质量比例为3~12∶4~8∶1。Further, the borax powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are 30-50 meshes, 50-80 meshes, and 80-100 meshes respectively, and the mixing mass ratio of the above three kinds of powders is 3-12:4-8:1.
进一步地,所述三氧化钼粉末由三种粒径目数的粉体组成,其粒径目数分别为30~50目、50~80目、80~100目,上述三种粉体的混合质量比例为4~12∶2~8∶1。Further, the molybdenum trioxide powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are 30-50 meshes, 50-80 meshes, and 80-100 meshes respectively. The mixing of the above three kinds of powders The mass ratio is 4-12:2-8:1.
进一步地,所述丙酸戊酯的粘度在25℃为120~180mpa.s。Further, the viscosity of the amyl propionate is 120-180 mPa.s at 25°C.
进一步地,所述石棉粉由三种粒径目数的粉体组成,其粒径目数分别为20~50目、50~70目、70~90目,上述三种粉体的混合质量比例为2~4∶3~5∶1。Further, the asbestos powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are 20-50 meshes, 50-70 meshes, and 70-90 meshes respectively, and the mixing mass ratio of the above three kinds of powders is It is 2~4:3~5:1.
进一步地,所述磷酸三甲酯的粘度在25℃为80~100mpa.s。Further, the viscosity of the trimethyl phosphate is 80-100 mPa.s at 25°C.
进一步地,上述润滑油多功能添加剂制备方法步骤如下:Further, the steps of the preparation method of the above-mentioned multifunctional additive for lubricating oil are as follows:
(1)将所述质量份数的双酚F型环氧树脂、偏苯三甲酸三辛酯、聚-4-甲基-1-戊烯、乙酸丁酯、丙酸戊酯、二乙二醇乙醚、丙酸异丁酯、甲基苯胺、氰乙基纤维素、硼砂粉末、熊果甘、聚六亚甲基双胍盐酸盐、三氧化钼粉末、石棉粉、石墨粉、四水八硼酸二钠、松烟墨、钛酸钡粉末、碳化钙粉末、碳化硅粉末予以混合,超声高速分散,超声波频率为20~40KHz,分散速度5000~5400r/min左右,分散时间为30~60min;(1) Bisphenol F type epoxy resin, trioctyl trimellitate, poly-4-methyl-1-pentene, butyl acetate, pentyl propionate, diethylene glycol Alcohol ether, isobutyl propionate, methylaniline, cyanoethyl cellulose, borax powder, bear fruit, polyhexamethylene biguanide hydrochloride, molybdenum trioxide powder, asbestos powder, graphite powder, four water eight Mix disodium borate, pine smoke ink, barium titanate powder, calcium carbide powder, and silicon carbide powder, and disperse at high speed with ultrasonic waves.
(2)加入所述质量份数的六氢化邻苯二甲酸酐、磷酸三甲酯、聚丙烯腈纤维、二盐基性硬脂酸铅、失水山梨醇脂肪酸酯,超声高速分散,超声波频率为20~35KHz,分散速度4800~5200r/min左右,分散时间为30~50min;(2) Add the hexahydrophthalic anhydride, trimethyl phosphate, polyacrylonitrile fiber, dibasic lead stearate, sorbitan fatty acid ester of said mass fraction, ultrasonic high-speed dispersion, ultrasonic The frequency is 20-35KHz, the dispersion speed is about 4800-5200r/min, and the dispersion time is 30-50min;
(3)加入所述质量份数的聚苯乙烯磺酸钠、甘油硬脂酸酯、硬脂酸季戊四醇酯、异辛酸、异佛尔酮二异氰酸酯,超声高速分散,超声波频率为20~30KHz,分散速度4600~4800r/min左右,分散时间为20~40min;混合均匀后制得本品。(3) Adding the sodium polystyrene sulfonate, glyceryl stearate, pentaerythritol stearate, isooctanoic acid, and isophorone diisocyanate in said mass fraction, and ultrasonically disperse at high speed, with an ultrasonic frequency of 20 to 30KHz, The dispersion speed is about 4600~4800r/min, and the dispersion time is 20~40min; the product is obtained after mixing evenly.
该发明的有益效果在于:本发明中的润滑油多功能添加剂,由以下组分组成:双酚F型环氧树脂、偏苯三甲酸三辛酯、聚-4-甲基-1-戊烯、乙酸丁酯、丙酸戊酯、二乙二醇乙醚、丙酸异丁酯、甲基苯胺、氰乙基纤维素、硼砂粉末、熊果甘、聚六亚甲基双胍盐酸盐、三氧化钼粉末、石棉粉、石墨粉、四水八硼酸二钠、松烟墨、钛酸钡粉末、碳化钙粉末、碳化硅粉末、六氢化邻苯二甲酸酐、磷酸三甲酯、聚丙烯腈纤维、二盐基性硬脂酸铅、失水山梨醇脂肪酸酯、聚苯乙烯磺酸钠、甘油硬脂酸酯、硬脂酸季戊四醇酯、异辛酸、异佛尔酮二异氰酸酯。本发明产品具有较为优越的阻燃、耐酸碱、防霉变抗菌性能,改善了产品性能。The beneficial effects of the invention are: the lubricating oil multifunctional additive in the present invention consists of the following components: bisphenol F epoxy resin, trioctyl trimellitate, poly-4-methyl-1-pentene , butyl acetate, amyl propionate, diethylene glycol ethyl ether, isobutyl propionate, methylaniline, cyanoethyl cellulose, borax powder, arbutin, polyhexamethylene biguanide hydrochloride, three Molybdenum oxide powder, asbestos powder, graphite powder, disodium octaborate tetrahydrate, pine smoke ink, barium titanate powder, calcium carbide powder, silicon carbide powder, hexahydrophthalic anhydride, trimethyl phosphate, polyacrylonitrile Fiber, dibasic lead stearate, sorbitan fatty acid ester, sodium polystyrene sulfonate, glyceryl stearate, pentaerythritol stearate, isocaprylic acid, isophorone diisocyanate. The product of the invention has relatively superior flame retardancy, acid and alkali resistance, anti-mildew and antibacterial properties, and improves product performance.
具体实施方式detailed description
本发明中的润滑油多功能添加剂,由以下质量份数的组分组成:双酚F型环氧树脂26~30份、偏苯三甲酸三辛酯24~28份、聚-4-甲基-1-戊烯24~28份、乙酸丁酯22~26份、丙酸戊酯24~28份、二乙二醇乙醚24~28份、丙酸异丁酯22~26份、甲基苯胺24~28份、氰乙基纤维素24~28份、硼砂粉末22~26份、熊果甘22~26份、聚六亚甲基双胍盐酸盐22~26份、三氧化钼粉末24~28份、石棉粉22~26份、石墨粉20~24份、四水八硼酸二钠24~28份、松烟墨22~26份、钛酸钡粉末20~24份、碳化钙粉末22~26份、碳化硅粉末20~24份、六氢化邻苯二甲酸酐20~24份、磷酸三甲酯20~24份、聚丙烯腈纤维18~22份、二盐基性硬脂酸铅14~18份、失水山梨醇脂肪酸酯12~16份、聚苯乙烯磺酸钠12~16份、甘油硬脂酸酯12~16份、硬脂酸季戊四醇酯12~16份、异辛酸12~16份、异佛尔酮二异氰酸酯12~16份。The lubricating oil multifunctional additive in the present invention is composed of the following components in parts by mass: 26-30 parts of bisphenol F epoxy resin, 24-28 parts of trioctyl trimellitate, poly-4-methyl -24-28 parts of 1-pentene, 22-26 parts of butyl acetate, 24-28 parts of pentyl propionate, 24-28 parts of diethylene glycol ethyl ether, 22-26 parts of isobutyl propionate, methylaniline 24-28 parts, 24-28 parts of cyanoethyl cellulose, 22-26 parts of borax powder, 22-26 parts of bearberry, 22-26 parts of polyhexamethylene biguanide hydrochloride, 24-26 parts of molybdenum trioxide powder 28 parts, 22-26 parts of asbestos powder, 20-24 parts of graphite powder, 24-28 parts of disodium octaborate tetrahydrate, 22-26 parts of pine smoke ink, 20-24 parts of barium titanate powder, 22-24 parts of calcium carbide powder 26 parts, 20-24 parts of silicon carbide powder, 20-24 parts of hexahydrophthalic anhydride, 20-24 parts of trimethyl phosphate, 18-22 parts of polyacrylonitrile fiber, 14 parts of dibasic lead stearate ~18 parts, 12~16 parts of sorbitan fatty acid ester, 12~16 parts of sodium polystyrene sulfonate, 12~16 parts of glyceryl stearate, 12~16 parts of pentaerythritol stearate, 12 parts of isooctanoic acid ~16 parts, 12~16 parts of isophorone diisocyanate.
所述硼砂粉末由三种粒径目数的粉体组成,其粒径目数分别为30~50目、50~80目、80~100目,上述三种粉体的混合质量比例为3~12∶4~8∶1。The borax powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are respectively 30-50 meshes, 50-80 meshes, and 80-100 meshes, and the mixing mass ratio of the above three kinds of powders is 3-50 meshes. 12:4~8:1.
所述三氧化钼粉末由三种粒径目数的粉体组成,其粒径目数分别为30~50目、50~80目、80~100目,上述三种粉体的混合质量比例为4~12∶2~8∶1。The molybdenum trioxide powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are respectively 30-50 meshes, 50-80 meshes, and 80-100 meshes, and the mixing mass ratio of the above three kinds of powders is 4~12:2~8:1.
所述丙酸戊酯的粘度在25℃为120~180mpa.s。The viscosity of the amyl propionate is 120-180 mPa.s at 25°C.
所述石棉粉由三种粒径目数的粉体组成,其粒径目数分别为20~50目、50~70目、70~90目,上述三种粉体的混合质量比例为2~4∶3~5∶1。The asbestos powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are 20-50 meshes, 50-70 meshes, and 70-90 meshes respectively, and the mixing mass ratio of the above three kinds of powders is 2-50 mesh. 4:3~5:1.
所述磷酸三甲酯的粘度在25℃为80~100mpa.s。The viscosity of the trimethyl phosphate is 80-100 mPa.s at 25°C.
下面结合实施例对本发明的具体实施方式进行描述,以便更好的理解本发明。Specific embodiments of the present invention will be described below in conjunction with examples, so as to better understand the present invention.
实施例1Example 1
本实施例中的润滑油多功能添加剂,由以下质量份数的组分组成:双酚F型环氧树脂26份、偏苯三甲酸三辛酯24份、聚-4-甲基-1-戊烯24份、乙酸丁酯22份、丙酸戊酯24份、二乙二醇乙醚24份、丙酸异丁酯22份、甲基苯胺24份、氰乙基纤维素24份、硼砂粉末22份、熊果甘22份、聚六亚甲基双胍盐酸盐22份、三氧化钼粉末24份、石棉粉22份、石墨粉20份、四水八硼酸二钠24份、松烟墨22份、钛酸钡粉末20份、碳化钙粉末22份、碳化硅粉末20份、六氢化邻苯二甲酸酐20份、磷酸三甲酯20份、聚丙烯腈纤维18份、二盐基性硬脂酸铅14份、失水山梨醇脂肪酸酯12份、聚苯乙烯磺酸钠12份、甘油硬脂酸酯12份、硬脂酸季戊四醇酯12份、异辛酸12份、异佛尔酮二异氰酸酯12份。The lubricating oil multifunctional additive in the present embodiment is made up of the following components in parts by mass: 26 parts of bisphenol F type epoxy resins, 24 parts of trioctyl trimellitate, poly-4-methyl-1- 24 parts of pentene, 22 parts of butyl acetate, 24 parts of amyl propionate, 24 parts of diethylene glycol ether, 22 parts of isobutyl propionate, 24 parts of methylaniline, 24 parts of cyanoethyl cellulose, borax powder 22 parts, 22 parts of bear fruit, 22 parts of polyhexamethylene biguanide hydrochloride, 24 parts of molybdenum trioxide powder, 22 parts of asbestos powder, 20 parts of graphite powder, 24 parts of disodium octaborate tetrahydrate, pine smoke ink 22 parts, 20 parts of barium titanate powder, 22 parts of calcium carbide powder, 20 parts of silicon carbide powder, 20 parts of hexahydrophthalic anhydride, 20 parts of trimethyl phosphate, 18 parts of polyacrylonitrile fiber, dibasic 14 parts of lead stearate, 12 parts of sorbitan fatty acid ester, 12 parts of sodium polystyrene sulfonate, 12 parts of glyceryl stearate, 12 parts of pentaerythritol stearate, 12 parts of isooctanoic acid, isophor 12 parts of ketone diisocyanate.
所述硼砂粉末由三种粒径目数的粉体组成,其粒径目数分别为30~50目、50~80目、80~100目,上述三种粉体的混合质量比例为3∶4∶1。Described borax powder is made up of the powder body of three kinds of particle size mesh numbers, and its particle size mesh number is respectively 30~50 mesh, 50~80 mesh, 80~100 mesh, and the mixing mass ratio of above-mentioned three kinds of powder bodies is 3: 4:1.
所述三氧化钼粉末由三种粒径目数的粉体组成,其粒径目数分别为30~50目、50~80目、80~100目,上述三种粉体的混合质量比例为4∶2∶1。The molybdenum trioxide powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are respectively 30-50 meshes, 50-80 meshes, and 80-100 meshes, and the mixing mass ratio of the above three kinds of powders is 4:2:1.
所述丙酸戊酯的粘度在25℃为120mpa.s。The viscosity of the amyl propionate is 120mpa.s at 25°C.
所述石棉粉由三种粒径目数的粉体组成,其粒径目数分别为20~50目、50~70目、70~90目,上述三种粉体的混合质量比例为2∶3∶1。The asbestos powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are 20-50 meshes, 50-70 meshes, and 70-90 meshes respectively, and the mixing mass ratio of the above three kinds of powders is 2: 3:1.
所述磷酸三甲酯的粘度在25℃为80mpa.s。The viscosity of the trimethyl phosphate is 80mpa.s at 25°C.
上述润滑油多功能添加剂制备方法步骤如下:The steps of the preparation method of the above-mentioned multifunctional additive for lubricating oil are as follows:
(1)将所述质量份数的双酚F型环氧树脂、偏苯三甲酸三辛酯、聚-4-甲基-1-戊烯、乙酸丁酯、丙酸戊酯、二乙二醇乙醚、丙酸异丁酯、甲基苯胺、氰乙基纤维素、硼砂粉末、熊果甘、聚六亚甲基双胍盐酸盐、三氧化钼粉末、石棉粉、石墨粉、四水八硼酸二钠、松烟墨、钛酸钡粉末、碳化钙粉末、碳化硅粉末予以混合,超声高速分散,超声波频率为20kHz,分散速度5400r/min左右,分散时间为60min;(1) Bisphenol F type epoxy resin, trioctyl trimellitate, poly-4-methyl-1-pentene, butyl acetate, pentyl propionate, diethylene glycol Alcohol ether, isobutyl propionate, methylaniline, cyanoethyl cellulose, borax powder, bear fruit, polyhexamethylene biguanide hydrochloride, molybdenum trioxide powder, asbestos powder, graphite powder, four water eight Mix disodium borate, pine smoke ink, barium titanate powder, calcium carbide powder, and silicon carbide powder, and disperse at high speed with ultrasonic waves. The ultrasonic frequency is 20kHz, the dispersion speed is about 5400r/min, and the dispersion time is 60min;
(2)加入所述质量份数的六氢化邻苯二甲酸酐、磷酸三甲酯、聚丙烯腈纤维、二盐基性硬脂酸铅、失水山梨醇脂肪酸酯,超声高速分散,超声波频率为20kHz,分散速度5200r/min左右,分散时间为50min;(2) Add the hexahydrophthalic anhydride, trimethyl phosphate, polyacrylonitrile fiber, dibasic lead stearate, sorbitan fatty acid ester of said mass fraction, ultrasonic high-speed dispersion, ultrasonic The frequency is 20kHz, the dispersion speed is about 5200r/min, and the dispersion time is 50min;
(3)加入所述质量份数的聚苯乙烯磺酸钠、甘油硬脂酸酯、硬脂酸季戊四醇酯、异辛酸、异佛尔酮二异氰酸酯,超声高速分散,超声波频率为20kHz,分散速度4800r/min左右,分散时间为40min;混合均匀后制得本品。(3) Add the sodium polystyrene sulfonate, glyceryl stearate, pentaerythritol stearate, isooctanoic acid, isophorone diisocyanate of said mass fraction, ultrasonic high-speed dispersion, ultrasonic frequency is 20kHz, dispersion speed About 4800r/min, the dispersion time is 40min; the product is obtained after mixing evenly.
实施例2Example 2
本实施例中的润滑油多功能添加剂,由以下质量份数的组分组成:双酚F型环氧树脂28份、偏苯三甲酸三辛酯26份、聚-4-甲基-1-戊烯26份、乙酸丁酯24份、丙酸戊酯26份、二乙二醇乙醚26份、丙酸异丁酯24份、甲基苯胺26份、氰乙基纤维素26份、硼砂粉末24份、熊果甘24份、聚六亚甲基双胍盐酸盐24份、三氧化钼粉末26份、石棉粉24份、石墨粉22份、四水八硼酸二钠26份、松烟墨24份、钛酸钡粉末22份、碳化钙粉末24份、碳化硅粉末22份、六氢化邻苯二甲酸酐22份、磷酸三甲酯22份、聚丙烯腈纤维20份、二盐基性硬脂酸铅16份、失水山梨醇脂肪酸酯14份、聚苯乙烯磺酸钠14份、甘油硬脂酸酯14份、硬脂酸季戊四醇酯14份、异辛酸14份、异佛尔酮二异氰酸酯14份。The lubricating oil multifunctional additive in the present embodiment is made up of the following components in parts by mass: 28 parts of bisphenol F type epoxy resins, 26 parts of trioctyl trimellitate, poly-4-methyl-1- 26 parts of pentene, 24 parts of butyl acetate, 26 parts of amyl propionate, 26 parts of diethylene glycol ethyl ether, 24 parts of isobutyl propionate, 26 parts of methylaniline, 26 parts of cyanoethyl cellulose, borax powder 24 parts, bear fruit root 24 parts, polyhexamethylene biguanide hydrochloride 24 parts, molybdenum trioxide powder 26 parts, asbestos powder 24 parts, graphite powder 22 parts, disodium octaborate tetrahydrate 26 parts, pine smoke ink 24 parts, 22 parts of barium titanate powder, 24 parts of calcium carbide powder, 22 parts of silicon carbide powder, 22 parts of hexahydrophthalic anhydride, 22 parts of trimethyl phosphate, 20 parts of polyacrylonitrile fiber, dibasic 16 parts of lead stearate, 14 parts of sorbitan fatty acid ester, 14 parts of sodium polystyrene sulfonate, 14 parts of glyceryl stearate, 14 parts of pentaerythritol stearate, 14 parts of isooctanoic acid, isophor 14 parts of ketone diisocyanate.
所述硼砂粉末由三种粒径目数的粉体组成,其粒径目数分别为30~50目、50~80目、80~100目,上述三种粉体的混合质量比例为8∶6∶1。Described borax powder is made up of the powder body of three kinds of particle size mesh numbers, and its particle size mesh number is respectively 30~50 mesh, 50~80 mesh, 80~100 mesh, and the mixing mass ratio of above-mentioned three kinds of powder bodies is 8: 6:1.
所述三氧化钼粉末由三种粒径目数的粉体组成,其粒径目数分别为30~50目、50~80目、80~100目,上述三种粉体的混合质量比例为8∶5∶1。The molybdenum trioxide powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are respectively 30-50 meshes, 50-80 meshes, and 80-100 meshes, and the mixing mass ratio of the above three kinds of powders is 8:5:1.
所述丙酸戊酯的粘度在25℃为150mpa.s。The viscosity of the amyl propionate is 150mpa.s at 25°C.
所述石棉粉由三种粒径目数的粉体组成,其粒径目数分别为20~50目、50~70目、70~90目,上述三种粉体的混合质量比例为3∶4∶1。The asbestos powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are 20-50 meshes, 50-70 meshes, and 70-90 meshes respectively, and the mixing mass ratio of the above three kinds of powders is 3: 4:1.
所述磷酸三甲酯的粘度在25℃为90mpa.s。The viscosity of the trimethyl phosphate is 90mpa.s at 25°C.
上述润滑油多功能添加剂制备方法步骤如下:The steps of the preparation method of the above-mentioned multifunctional additive for lubricating oil are as follows:
(1)将所述质量份数的双酚F型环氧树脂、偏苯三甲酸三辛酯、聚-4-甲基-1-戊烯、乙酸丁酯、丙酸戊酯、二乙二醇乙醚、丙酸异丁酯、甲基苯胺、氰乙基纤维素、硼砂粉末、熊果甘、聚六亚甲基双胍盐酸盐、三氧化钼粉末、石棉粉、石墨粉、四水八硼酸二钠、松烟墨、钛酸钡粉末、碳化钙粉末、碳化硅粉末予以混合,超声高速分散,超声波频率为30kHz,分散速度5200r/min左右,分散时间为45min;(1) Bisphenol F type epoxy resin, trioctyl trimellitate, poly-4-methyl-1-pentene, butyl acetate, pentyl propionate, diethylene glycol Alcohol ether, isobutyl propionate, methylaniline, cyanoethyl cellulose, borax powder, bear fruit, polyhexamethylene biguanide hydrochloride, molybdenum trioxide powder, asbestos powder, graphite powder, four water eight Mix disodium borate, pine smoke ink, barium titanate powder, calcium carbide powder, and silicon carbide powder, and disperse at high speed with ultrasonic waves. The ultrasonic frequency is 30kHz, the dispersion speed is about 5200r/min, and the dispersion time is 45min;
(2)加入所述质量份数的六氢化邻苯二甲酸酐、磷酸三甲酯、聚丙烯腈纤维、二盐基性硬脂酸铅、失水山梨醇脂肪酸酯,超声高速分散,超声波频率为27kHz,分散速度5000r/min左右,分散时间为40min;(2) Add the hexahydrophthalic anhydride, trimethyl phosphate, polyacrylonitrile fiber, dibasic lead stearate, sorbitan fatty acid ester of said mass fraction, ultrasonic high-speed dispersion, ultrasonic The frequency is 27kHz, the dispersion speed is about 5000r/min, and the dispersion time is 40min;
(3)加入所述质量份数的聚苯乙烯磺酸钠、甘油硬脂酸酯、硬脂酸季戊四醇酯、异辛酸、异佛尔酮二异氰酸酯,超声高速分散,超声波频率为25kHz,分散速度4700r/min左右,分散时间为30min;混合均匀后制得本品。(3) Add the sodium polystyrene sulfonate, glyceryl stearate, pentaerythritol stearate, isooctanoic acid, isophorone diisocyanate of said mass fraction, ultrasonic high-speed dispersion, ultrasonic frequency is 25kHz, dispersion speed About 4700r/min, the dispersion time is 30min; after mixing evenly, this product is prepared.
实施例3Example 3
本实施例中的润滑油多功能添加剂,由以下质量份数的组分组成:双酚F型环氧树脂30份、偏苯三甲酸三辛酯28份、聚-4-甲基-1-戊烯28份、乙酸丁酯26份、丙酸戊酯28份、二乙二醇乙醚28份、丙酸异丁酯26份、甲基苯胺28份、氰乙基纤维素28份、硼砂粉末26份、熊果甘26份、聚六亚甲基双胍盐酸盐26份、三氧化钼粉末28份、石棉粉26份、石墨粉24份、四水八硼酸二钠28份、松烟墨26份、钛酸钡粉末24份、碳化钙粉末26份、碳化硅粉末24份、六氢化邻苯二甲酸酐24份、磷酸三甲酯24份、聚丙烯腈纤维22份、二盐基性硬脂酸铅18份、失水山梨醇脂肪酸酯16份、聚苯乙烯磺酸钠16份、甘油硬脂酸酯16份、硬脂酸季戊四醇酯16份、异辛酸16份、异佛尔酮二异氰酸酯16份。The lubricating oil multifunctional additive in the present embodiment is made up of the following components in parts by mass: 30 parts of bisphenol F type epoxy resins, 28 parts of trioctyl trimellitate, poly-4-methyl-1- 28 parts of pentene, 26 parts of butyl acetate, 28 parts of amyl propionate, 28 parts of diethylene glycol ether, 26 parts of isobutyl propionate, 28 parts of methylaniline, 28 parts of cyanoethyl cellulose, borax powder 26 parts, 26 parts of bear fruit, 26 parts of polyhexamethylene biguanide hydrochloride, 28 parts of molybdenum trioxide powder, 26 parts of asbestos powder, 24 parts of graphite powder, 28 parts of disodium octaborate tetrahydrate, pine smoke ink 26 parts, 24 parts of barium titanate powder, 26 parts of calcium carbide powder, 24 parts of silicon carbide powder, 24 parts of hexahydrophthalic anhydride, 24 parts of trimethyl phosphate, 22 parts of polyacrylonitrile fiber, dibasic 18 parts of lead stearate, 16 parts of sorbitan fatty acid ester, 16 parts of sodium polystyrene sulfonate, 16 parts of glyceryl stearate, 16 parts of pentaerythritol stearate, 16 parts of isooctanoic acid, isophor 16 parts of ketone diisocyanate.
所述硼砂粉末由三种粒径目数的粉体组成,其粒径目数分别为30~50目、50~80目、80~100目,上述三种粉体的混合质量比例为12∶8∶1。Described borax powder is made up of the powder body of three kinds of particle size mesh numbers, and its particle size mesh number is respectively 30~50 mesh, 50~80 mesh, 80~100 mesh, and the mixing mass ratio of above-mentioned three kinds of powder bodies is 12: 8:1.
所述三氧化钼粉末由三种粒径目数的粉体组成,其粒径目数分别为30~50目、50~80目、80~100目,上述三种粉体的混合质量比例为12∶8∶1。The molybdenum trioxide powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are respectively 30-50 meshes, 50-80 meshes, and 80-100 meshes, and the mixing mass ratio of the above three kinds of powders is 12:8:1.
所述丙酸戊酯的粘度在25℃为180mpa.s。The viscosity of the amyl propionate is 180mpa.s at 25°C.
所述石棉粉由三种粒径目数的粉体组成,其粒径目数分别为20~50目、50~70目、70~90目,上述三种粉体的混合质量比例为4∶5∶1。The asbestos powder is composed of powders with three particle sizes and meshes, the particle sizes and meshes are 20-50 meshes, 50-70 meshes, and 70-90 meshes respectively, and the mixing mass ratio of the above three kinds of powders is 4: 5:1.
所述磷酸三甲酯的粘度在25℃为100mpa.s。The viscosity of the trimethyl phosphate is 100mpa.s at 25°C.
上述润滑油多功能添加剂制备方法步骤如下:The steps of the preparation method of the above-mentioned multifunctional additive for lubricating oil are as follows:
(1)将所述质量份数的双酚F型环氧树脂、偏苯三甲酸三辛酯、聚-4-甲基-1-戊烯、乙酸丁酯、丙酸戊酯、二乙二醇乙醚、丙酸异丁酯、甲基苯胺、氰乙基纤维素、硼砂粉末、熊果甘、聚六亚甲基双胍盐酸盐、三氧化钼粉末、石棉粉、石墨粉、四水八硼酸二钠、松烟墨、钛酸钡粉末、碳化钙粉末、碳化硅粉末予以混合,超声高速分散,超声波频率为40kHz,分散速度5000r/min,分散时间为30min;(1) Bisphenol F type epoxy resin, trioctyl trimellitate, poly-4-methyl-1-pentene, butyl acetate, pentyl propionate, diethylene glycol Alcohol ether, isobutyl propionate, methylaniline, cyanoethyl cellulose, borax powder, bear fruit, polyhexamethylene biguanide hydrochloride, molybdenum trioxide powder, asbestos powder, graphite powder, four water eight Mix disodium borate, pine smoke ink, barium titanate powder, calcium carbide powder, and silicon carbide powder, and disperse at high speed with ultrasonic waves. The ultrasonic frequency is 40kHz, the dispersion speed is 5000r/min, and the dispersion time is 30 minutes;
(2)加入所述质量份数的六氢化邻苯二甲酸酐、磷酸三甲酯、聚丙烯腈纤维、二盐基性硬脂酸铅、失水山梨醇脂肪酸酯,超声高速分散,超声波频率为35kHz,分散速度4800r/min,分散时间为30min;(2) Add the hexahydrophthalic anhydride, trimethyl phosphate, polyacrylonitrile fiber, dibasic lead stearate, sorbitan fatty acid ester of said mass fraction, ultrasonic high-speed dispersion, ultrasonic The frequency is 35kHz, the dispersion speed is 4800r/min, and the dispersion time is 30min;
(3)加入所述质量份数的聚苯乙烯磺酸钠、甘油硬脂酸酯、硬脂酸季戊四醇酯、异辛酸、异佛尔酮二异氰酸酯,超声高速分散,超声波频率为30kHz,分散速度4600r/min左右,分散时间为20min;混合均匀后制得本品。(3) Add the sodium polystyrene sulfonate, glyceryl stearate, pentaerythritol stearate, isooctanoic acid, isophorone diisocyanate of said mass fraction, ultrasonic high-speed dispersion, ultrasonic frequency is 30kHz, dispersion speed About 4600r/min, the dispersion time is 20min; the product is obtained after mixing evenly.
针对实施例1、实施例2和实施例3中的产品和某市售产品进行性能测量,所测得的数据如表1所示。防火阻燃等级测试采用UL94标准。Performance measurements were performed on the products in Example 1, Example 2 and Example 3 and a commercially available product, and the measured data are shown in Table 1. UL94 standard is adopted for the fire and flame retardant grade test.
表1性能测试结果Table 1 performance test results
可见,本发明产品具有较好的耐腐蚀、防火阻燃、防霉变、抗菌性能。It can be seen that the product of the present invention has better corrosion resistance, fire retardant, mildew resistance and antibacterial properties.
以上所述是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也视为本发明的保护范围。The above description is a preferred embodiment of the present invention, and it should be pointed out that for those skilled in the art, without departing from the principle of the present invention, some improvements and modifications can also be made, and these improvements and modifications are also considered Be the protection scope of the present invention.
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Application publication date: 20170524 |
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| RJ01 | Rejection of invention patent application after publication |