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CN1066497C - Preparation method and application of polyester mixed fiber - Google Patents

Preparation method and application of polyester mixed fiber Download PDF

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Publication number
CN1066497C
CN1066497C CN98117617A CN98117617A CN1066497C CN 1066497 C CN1066497 C CN 1066497C CN 98117617 A CN98117617 A CN 98117617A CN 98117617 A CN98117617 A CN 98117617A CN 1066497 C CN1066497 C CN 1066497C
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flat filament
yarn
filament yarn
wheel
shrinkage
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CN98117617A
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CN1208780A (en
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简日春
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Nan Ya Plastics Corp
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Nan Ya Plastics Corp
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Abstract

The invention relates to a method for preparing polyester mixed fiber and its use, mainly through melting polyester polymer different to the alkali dissolution rate, adjust the mixing proportion, through different mixing spinning, make the filament as the spinning cake of the cross section shown in figure 1, and then through the processing procedure such as draw twisting, false twisting or direct spinning extension to make the flat filament yarn or textured yarn, with this flat filament yarn or textured yarn, through reducing with alkali liquor after the weaving, the range of single filament denier is 0.02-1.2d, the average denier is about 0.2d and the fabric with abundant change of cross section shape.

Description

Method for making of polyester blended fiber and uses thereof
The present invention relates to method for making of a kind of polyester blended fiber and uses thereof.The made iso-fineness of polyester blended fiber, gloss and the peach skin shape sense of touch of sense of touch or similar tencel fiber (TENCEL) and the gloss of special shade sense that different section fabric has similar silk thus.
Synthetic fiber (comprising polyester fiber) are used to prepare dress material, are of long duration.Because the consumer improves constantly the feel and the dynamopathic requirement of synthetic fibre, recently the fiber industry actively drops into research invariably for this reason, manage to develop the similar natural silk of iso-fineness, different section or the synthetic fabrics of similar tencel fiber, to satisfy consumer demand.
Desire was produced iso-fineness, different cross-section fiber in the past, or with same spinnerets direct fabrics, or after producing spinning cake with different spinneretss in the Split Down mode, through stretching sth. made by twisting, false twisting or make iso-fineness, different section flat yarn or textured filament through procedures such as direct fabrics extensions, and flat yarn that iso-fineness, different section MULTIPLE COMPOSITE structure fabric can utilize aforesaid iso-fineness, different section flat yarn or textured filament to weave to form or utilize different fiber numbers, different section or textured filament are with the interleaving mode manufacturing.No matter but make in which way, according to known spinning production technology, when production single fiber DENIER was the spinning cake of 0.2dpf, its productivity and special-shaped section shape were neither easy to control; In addition, when section configuration is too many in the same spinnerets, then the manufacturing cost of spinnerets is too high, and the working condition scope also can be restricted, so consider manufacturing cost and productivity, the intensity of variation of its fiber number and section configuration will be restricted, and therefore can have influence on the effect of final fabric, comprises the effect of vision and sense of touch.
The present invention promptly is at above-mentioned cited shortcoming, studies through constantly making great efforts, and the method for making of inventing out polyester blended fiber and converted goods thereof.Main by after the polyester polymers difference fusion different to alkali dissolution speed, adjust mixed proportion, through the difference device spinning of mixing, make the single fiber section configuration for as shown in Figure 1, upgrading polyester polymers and be sweep strip stratiform by polyalcohol or polyacid copolymerization upgrading and upgrading polyester polymers that alkali dissolution speed is accelerated and pile up alternately not wherein, the opening of this curved bars is all towards its central point, and the position of this central point can filamentary central authorities or on every side and quantity greater than more than one spinning cake, again through stretching sth. made by twisting, false twisting or make flat yarn or textured filament through procedures such as direct fabrics extensions.With this flat yarn or textured filament, when dyeing and finishing, can control the decrement ratio behind the warp-knit cloth, and obtain having the fabric of the gloss of similar natural silk and sense of touch or produce the gloss of the peach shadow sense of similar tencell fabric because of the fibrillation effect.
Not upgrading polyester polymers and upgrading polyester polymers that the used raw material of the present invention is moored for viscosity 1500-4000.For the benefit of decrement generally can add the 3rd composition such as diethylene glycol (DEG), propylene glycol, cyclohexanediol, polyethylene glycol, phthalic acid, M-phthalic acid, sulfoisophthalic acid, adipic acid, azelaic acid, decanedioic acid etc. and carry out combined polymerization in the upgrading polyester polymers.
The present invention is a raw material with above-mentioned not upgrading polyester polymers and by polyalcohol or polyacid copolymerization upgrading and upgrading polyester polymers that alkali dissolution speed is accelerated, after the fusion, adjusts its mixed proportion respectively; Upgrading polyester polymers/not by polyalcohol or polyacid copolymerization upgrading and upgrading polyester polymers=85/15-50/50 that alkali dissolution speed is accelerated, through spinning equipment shown in Figure 2, produce the single fiber section for upgrading polyester polymers not and be sweep strip stratiform by polyalcohol or polyacid copolymerization upgrading and upgrading polyester polymers that alkali dissolution speed is accelerated and pile up alternately, the opening of this curved bars is all towards its central point, and the position of this central point can filamentary central authorities or on every side and quantity greater than more than one polyester blended fiber; And when passing through polyalcohol or polyacid copolymerization upgrading and making the upgrading polyester raw material proportion that alkali dissolution speed accelerates<15% in the polyester blended fiber, then the section of fiber is because of by polyalcohol or polyacid copolymerization upgrading and make the shared one-tenth number of upgrading polyester polymers that alkali dissolution speed accelerates very little, can't obtain careful feel after the decrement, and when by polyalcohol or polyacid copolymerization upgrading and when making the upgrading polyester raw material proportion that alkali dissolution speed accelerates>50%, then will be meticulous because of the single fiber fiber number after the decrement, and can't obtain appropriate different fibre, different section effect, and the decrement ratio is excessive, the tearing strength that will increase manufacturing cost and fabric reduces, so general not upgrading polyester polymers/by polyalcohol or polyacid copolymerization upgrading and make the mixed proportion of upgrading polyester polymers of alkali dissolution speed quickening comparatively suitable with 85/15-50/50.
Polyester blended fiber of the present invention is via the parallel cutting unit 22 among Fig. 2, static mixer 23 and distribution plate 24 etc. mix device will be not upgrading polyester polymers 21 and fully mix by polyalcohol or polyacid copolymerization upgrading and upgrading polyester polymers (21-1) that alkali dissolution speed is accelerated after, spue through the hole of spinnerets 25 again.The pore cross section of this spinnerets can carry out spinning in any section mode, and is to obtain the suitable effect of mixing, and the number of unit of mixing of static mixer 23 is generally 4-8 the unit that mixes.
Through the polyester blended fiber of spinning gained, stretch the twisting journey through Fig. 3 again.The partially oriented yarn (POY) or medium oriented yarn (MOY) (MOY) spinning cake 31 that make by spinning, organizine leads 32, silk pressing wheel 33, then through heated wheel 34, heater via 35 typings again, lead 37 through extension wheel 36, silk, and be wound into traditional flat yarn 38, the heating-up temperature of heated wheel 34 is 40-120 ℃, the ratio of elongation that heated wheel 34 and extension wheel are 36 is 1.3-3.0, and the setting temperature of heater 35 is 100-200 ℃.
As for making fabric increase backwash elasticity and generous sense, this moment can be in another the high contraction POY (39) of feeding in the twisting journey that stretches of Fig. 3, organizine is led (3C), silk pressing wheel 33, then through heated wheel 34, again through separating wheel 3A, extend wheel 36, produce the fine effect that mixes by air nozzle 3B with general flat yarn, organizine leads 37, and be wound into the different contraction flat yarn 38 that shrinks poor>10%, behind the different contraction flat yarn warp-knit cloth of poor>10% of this contraction, when dyeing and finishing, shrink poor, so can make fabric have good backwash elasticity and generous sense owing to thermal processes act produces.
Direct fabrics extend processing procedure as shown in Figure 4, the tow 41 that is spued by spinnerets is after oil tanker or oil nozzle 42 oil, after heated wheel 43 is directly extended, finalize the design through heated wheel 44 again, be rolled into flat yarn cake 46 through coiling machine 45, the heating-up temperature of heated wheel 43 is 50-150 ℃, speed be 500-6000 rice/minute, the heating-up temperature of heated wheel 44 is 80-250 ℃, speed be 3000-7000 rice/minute.
The false twisting procedure for processing as shown in Figure 5.The raw material of feeding can be used spun MOY of Fig. 2 processing procedure or POY spinning cake, or Fig. 3 processing procedure traditional flat yarn or the spun flat yarn cake of Fig. 4 processing procedure produced.Above-mentioned a kind of raw material thread 5A is separated the Shu Houjing silk rolling lead 51, enter the 1st axletree 52, promptly begin with heater 53 heating, coldplate 54 coolings, and friction ingot group 55 adds/untwisting 57 extensions of the 2nd axletree, coil into textured filament 5C after the effects such as the 3rd axletree 59 adjustment hello rates, the temperature of heater 53 is 120-240 ℃, uses MOY or POY spinning cake, and the ratio of elongation that the 1st axletree 52 when extending false twisting and the 2nd axletree are 57 is 1.3-3.0.
As for making fabric increase backwash elasticity and generous sense, can in the false twisting procedure for processing of Fig. 5, feed another boiling water shrinkage this moment and be higher than 10% height contraction flat yarn 5B, lead 56 by silk and incorporate the 2nd axletree 57 into, enter air nozzle 58 jointly with stretch textured yarn, produce the fine effect that mixes, again through the 3rd axletree 59, and coil into different contraction distortion silk 5C, behind this different contraction distortion silk warp-knit cloth, when dyeing and finishing, shrink poor, so can make fabric have good backwash elasticity and generous sense owing to thermal processes act produces.
Textured filament that the flat yarn cake that traditional flat yarn that Fig. 3 processing procedure makes or different contraction flat yarn, Fig. 4 processing procedure make and Fig. 5 processing procedure make or different contraction distortion silk can be applicable to woven and knitting purposes.
Polyester blended fiber of the present invention is after being woven or knitted into cloth, in dyeing and finishing process, need through the alkali lye decrement, make fiber produce iso-fineness, different section effect, reduction rate generally is controlled between the 5-40%, the reduction rate of similar natural silk fabric is about 5-20%, and the reduction rate of similar tencell fabric then is about 15-40%.Single fiber DENIER scope after the decrement is 0.02-1.2d, the average about 0.2d of DENIER, and fabric can be used for lady's blouse, suit, divided skirt material etc.
The simple declaration of accompanying drawing
Fig. 1: polyester blended fiber single fiber section configuration figure of the present invention;
Fig. 2: spinning of the present invention is with the mix constitutional diagram of device of spinning head;
Fig. 3: traditional flat yarn of polyester blended fiber of the present invention and different contraction flat yarn are stretched twisting journey figure;
Fig. 4: the flat yarn cake direct fabrics of polyester blended fiber of the present invention extend processing procedure figure;
Fig. 5: the textured filament of polyester blended fiber of the present invention and different contraction distortion silk false twisting procedure for processing figure.The conventional letter of main subdivision in the accompanying drawing:
(21): upgrading polyester polymers not;
(21-1): the upgrading polyester polymers;
(22): parallel cutting unit;
(23): static mixer;
(24): distribution plate;
(25): spinnerets;
(31): POY or MOY spinning cake;
(32): silk is led;
(33): the silk pressing wheel;
(34): heated wheel;
(35): heater;
(36): extend wheel;
(37): silk is led;
(38): traditional flat yarn or different contraction flat yarn;
(39): the high POY that shrinks;
(3A): separate wheel;
(3B): air nozzle;
(3C): silk is led;
(41): tow;
(42): oil tanker or oil nozzle;
(43): heated wheel;
(44): heated wheel;
(45): coiling machine;
(46): the flat yarn cake;
(5A): MOY or POY or traditional flat yarn or flat yarn cake;
(5B): the high flat yarn that shrinks;
(5C): textured filament or different contraction distortion silk;
(51): silk is led;
(52): the 1st axletree;
(53): heater;
(54): coldplate;
(55): friction ingot group;
(56): silk is led;
(57): the 2nd axletree;
(58): air nozzle;
(59): the 3rd axletree.
For making your auditor can further understand the technology contents of this case; Now also in conjunction with the accompanying drawings the present invention is done an explanation with embodiment 1,2.
Embodiment 1
With upgrading polyester polymers not and by polyalcohol or polyacid copolymerization upgrading and upgrading polyester polymers that alkali dissolution speed is accelerated is raw material, mixed proportion is 65/35, the temperature of spinning with 285 ℃, 32 hole spinneretss carry out spinning, the device that mixes of spinning head has parallel cutting unit, static mixer and distribution plate, and the unit number of mixing on the static mixer is 4; Discharge-amount is 1.5 Grams Per Minute holes, volume speed is 3000 meters/minute, upgrading polyester polymers viscosity is not 3000 pools, by polyalcohol or polyacid copolymerization upgrading and upgrading polyester polymers viscosity that alkali dissolution speed is accelerated is 3500 pools, spinning product condition is normal, spun spinning cake fiber number is 140d, and intensity is 1.7g/d, and degree of stretching is 159%, with it through false twisting procedure for processing shown in Figure 5, ratio of elongation is 1.9, and heter temperature is 180 ℃, and the false twisting process velocity is 500 meters/minute, incorporate the high flat yarn that shrinks of a 30D/12F during production into, the different contraction distortion silk size of making is 107d, and intensity is 3.4g/d, and degree of stretching is 27.7%.Make warp thread with above-mentioned different contraction distortion silk, make weft yarn with 75/36 textured filament, through close be 130/inch, filling density is 74/inch, with 1/1 plain weave; This fabric is through lax (120 ℃, 30 minutes), decrement (3%, 95 ℃ of NaOH, 40 minutes) and dyeing (130 ℃, 30 minutes) after, reduction rate about 18%, soft as the cloth mask peach skin, careful feel and the distinctive shade sense of the similar tencel fiber of tool, splendid backwash elasticity and the generous sense of fabric tool in addition.
Embodiment 2
With upgrading polyester polymers not and by polyalcohol or polyacid copolymerization upgrading and upgrading polyester polymers that alkali dissolution speed is accelerated is raw material, mixed proportion is 75/25, the temperature of spinning with 288 ℃, 36 hole spinneretss carry out spinning, the device that mixes of spinning head is in respect of parallel cutting unit, static mixer and distribution plate, and the unit number of mixing on the static mixer is 6; Discharge-amount is 1.29 Grams Per Minute holes, volume speed is 2400 meters/minute, upgrading polyester polymers viscosity is not 3000 pools, by polyalcohol or polyacid copolymerization upgrading and upgrading polyester polymers viscosity that alkali dissolution speed is accelerated is 3500 pools, spinning product condition is normal, spun spinning cake fiber number is 174d, and intensity is 1.6g/d, and degree of stretching is 197%, with it through the sth. made by twisting procedure for processing of stretching shown in Figure 3, ratio of elongation is 2.0, and the heated wheel temperature is 90 ℃, and stretching the sth. made by twisting process velocity is 690 meters/minute, make general traditional flat yarn, its fiber number is 87d, and intensity is 3.8g/d, and degree of stretching is 30%.Make warp thread with above-mentioned flat yarn, make weft yarn with 75/36 textured filament, through close be 175/inch, filling density is 86/inch, with 1/4 satin weave; This fabric is after lax (125 ℃, 30 minutes), decrement (2.5%, 95 ℃ of NaOH, 40 minutes) and dyeing (130 ℃, 30 minutes), and reduction rate is about 14%, and cloth cover has the gloss and the sense of touch of similar silk.

Claims (6)

1.一种聚酯混练纤维的制法,其特征在于通过对碱溶解速率不同的未改质聚酯聚合物及通过多元醇或多元酸共聚改质并使碱溶解速率加快的改质聚酯聚合物,分别调整其混合比例为85/15-50/50,经由平行分割单元(22)、静态混合器(23)及分配板(24)混练装置将未改质聚酯聚合物及通过多元醇或多元酸共聚改质并使碱溶解速率加快的改质聚酯聚合物进行充分混练后,再经喷丝板(25)的孔吐出,该喷丝板的孔断面可以以任何断面方式进行纺丝,经卷丝机卷取,制成单纤断面为未改质聚酯聚合物及通过多元醇或多元酸共聚改质并使碱溶解速率加快的改质聚酯聚合物呈弯曲线条状层状交互堆叠,此弯曲线条的开口均朝向其中心点,而此中心点的位置可在单纤维的中央或周围且数量大于一个以上的MOY或POY。1. A method for preparing polyester mixed fibers, which is characterized in that it is polymerized by unmodified polyester polymers with different alkali dissolution rates and modified polyesters modified by copolymerization of polyhydric alcohols or polyacids to accelerate the alkali dissolution rate. Material, adjust its mixing ratio to be 85/15-50/50 respectively, through parallel division unit (22), static mixer (23) and distribution plate (24) kneading device will unmodified polyester polymer and pass Alcohol or polybasic acid copolymerization modification and the modified polyester polymer that makes the alkali dissolution rate accelerated are fully mixed, and then spit out through the hole of the spinneret (25), and the hole section of the spinneret can be in any cross section Spinning, coiled by a coiling machine, the cross-section of the single fiber is made of unmodified polyester polymer and the modified polyester polymer modified by polyol or polyacid copolymerization and the alkali dissolution rate is accelerated to form a curved line The openings of the curved lines are all towards the center point, and the position of the center point can be in the center or around the single fiber and the number is more than one MOY or POY. 2.权利要求1所述的制法,其中由喷丝板(25)吐出的丝束(41)经油轮或油嘴(42)上油,经加热轮(43)直接延伸,经加热轮(44)进行定型,再经卷取机(45)的直接纺丝延伸制程卷成扁平长丝纱饼(46)。2. The method according to claim 1, wherein the tow (41) ejected from the spinneret (25) is oiled through an oil tanker or an oil nozzle (42), directly extended through a heating wheel (43), and carried out through a heating wheel (44). Sizing, then roll into a flat filament yarn cake (46) through the direct spinning extension process of the coiler (45). 3.权利要求1所述的制法,其中所制成的MOY或POY丝饼(31),经丝导(32)、压丝轮(33)、加热轮(34)、再经加热器(35)定型、经延伸轮(36)、丝导(37)的伸捻制程,而卷绕成传统扁平长丝纱(38);或于伸捻制程中并行喂入另一条高收缩POY(39),经丝导(3C)、压丝轮(33),然后经加热轮(34),再经分离轮(3A)、延伸轮(36),借由空气喷嘴(3B)与一般扁平长丝纱产生混纤作用,经丝导(37)而卷绕成收缩差>10%的异收缩扁平长丝纱(38)。3. The method for making according to claim 1, wherein the MOY or POY silk cake (31) made is passed through a wire guide (32), a pressing wheel (33), a heating wheel (34), and then through a heater (35) Shaped, stretched and twisted through the stretching wheel (36) and wire guide (37), and wound into a traditional flat filament yarn (38); or fed into another high-shrinkage POY (39) in parallel during the stretching and twisting process, Through the wire guide (3C), the pressing wheel (33), then the heating wheel (34), then the separation wheel (3A), the stretching wheel (36), and the air nozzle (3B) and the general flat filament yarn to produce Fiber blending effect, through the wire guide (37) and winding into different shrinkage flat filament yarn (38) with shrinkage difference > 10%. 4.权利要求1所述的制法,其中所制成的MOY或POY,权利要求2所述的制法,其中所制成的扁平长丝纱饼,权利要求3所述的制法,其中所制成的传统扁平长丝纱,使上述的一种原料丝(5A)解舒后经过丝导(51),进入第1车轴(52),即开始以加热器(53)加热,冷却板(54)冷却,及磨擦锭组(55)加/退捻,第2车轴(57)延伸,第3车轴(59)调整喂率的假捻加工制程后卷取成变形丝(5C);或于假捻加工制程中喂入另一沸水收缩率高于10%的高收缩扁平长丝纱(5B),由丝导(56)并入第2车轴(57),与假捻变形丝共同进入空气喷嘴(58),产生混纤作用,再经第3车轴(59),而卷取成异收缩变形丝(5C)。4. The preparation method described in claim 1, wherein the MOY or POY made, the preparation method described in claim 2, wherein the flat filament yarn cake made, the preparation method described in claim 3, wherein the made The traditional flat filament yarn that makes above-mentioned a kind of raw material silk (5A) unwinds and passes through silk guide (51), enters the 1st axle (52), promptly begins to heat with heater (53), cooling plate (54) ) cooling, and the addition/untwisting of the friction spindle group (55), the second axle (57) is extended, and the third axle (59) adjusts the false twist processing process of the feed rate, and then coils it into a textured yarn (5C); or in a fake In the twisting process, another high-shrinkage flat filament yarn (5B) with a boiling water shrinkage rate higher than 10% is fed into the second axle (57) from the wire guide (56), and enters the air nozzle together with the false-twisted textured yarn (58), produce the mixed fiber effect, then through the 3rd axle shaft (59), and coiling becomes different shrinkage textured yarn (5C). 5.权利要求2所述方法制成的扁平长丝纱饼、权利要求3所述方法制成的传统扁平长丝纱或异收缩扁平长丝纱、权利要求4所述方法制成的变形丝或异收缩变形丝用于织造织物的用途。5. The flat filament yarn cake made by the method of claim 2, the traditional flat filament yarn or different shrinkage flat filament yarn made by the method of claim 3, the textured yarn or different shrinkage yarn made by the method of claim 4 Use of shrink textured yarns for weaving fabrics. 6.按权利要求5所述的用途,其特征在于所织造的织物经碱液减量,其减量率为5-40%,减量后其单纤旦尼尔范围为0.02-1.2d,平均旦尼尔为0.2d。6. Use according to claim 5, characterized in that the woven fabric is reduced in weight by lye, and its weight reduction rate is 5-40%. After weight reduction, its single fiber denier range is 0.02-1.2d, and the average denier Neil is 0.2d.
CN98117617A 1998-08-20 1998-08-20 Preparation method and application of polyester mixed fiber Expired - Fee Related CN1066497C (en)

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6787081B2 (en) * 2001-12-14 2004-09-07 Nan Ya Plastics Corporation Manufacturing method for differential denier and differential cross section fiber and fabric
CN100424241C (en) * 2002-07-29 2008-10-08 济南正昊化纤新材料有限公司 Method for preparing hollow functional micropore polyester fibre
CN100360730C (en) * 2003-03-12 2008-01-09 厦门翔鹭化纤股份有限公司 Producing method for superfine bi-shrinkable fibre false twist composite yarn
US7892993B2 (en) * 2003-06-19 2011-02-22 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
CN105420865A (en) * 2015-12-31 2016-03-23 江南大学 Elastic filament production method
CN116446085B (en) * 2023-04-26 2024-05-28 浙江佳宝聚酯有限公司 Production method of polyester FDY filament yarn composite wool-like yarn

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CN88210834U (en) * 1988-02-21 1988-08-31 青岛纺织电器厂 Full-automatic roving tensometer
JPH02218A (en) * 1987-11-27 1990-01-05 Schering Ag 2,2-difluorocyclopropylethane derivatives, their intermediates, their production methods, and pest control agents containing them
CN1178845A (en) * 1996-09-23 1998-04-15 鲜京工业股份有限公司 Abnormal contraction composite filament and its producing method
CN1202541A (en) * 1997-06-18 1998-12-23 延俊生 Method for producing inhomogeneously contracting blended yarn and other two kinds of yarns on one identical set of production apparatus

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02218A (en) * 1987-11-27 1990-01-05 Schering Ag 2,2-difluorocyclopropylethane derivatives, their intermediates, their production methods, and pest control agents containing them
CN88210834U (en) * 1988-02-21 1988-08-31 青岛纺织电器厂 Full-automatic roving tensometer
CN1178845A (en) * 1996-09-23 1998-04-15 鲜京工业股份有限公司 Abnormal contraction composite filament and its producing method
CN1202541A (en) * 1997-06-18 1998-12-23 延俊生 Method for producing inhomogeneously contracting blended yarn and other two kinds of yarns on one identical set of production apparatus

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