CN106635327A - 用于无拔模角油底壳液压拉延成型的抗挤压介质 - Google Patents
用于无拔模角油底壳液压拉延成型的抗挤压介质 Download PDFInfo
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- 238000001125 extrusion Methods 0.000 title claims abstract description 18
- 239000003921 oil Substances 0.000 claims abstract description 33
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000007942 carboxylates Chemical class 0.000 claims abstract description 12
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004327 boric acid Substances 0.000 claims abstract description 10
- 239000013530 defoamer Substances 0.000 claims abstract description 9
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 9
- 239000000417 fungicide Substances 0.000 claims abstract description 9
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 7
- 239000011734 sodium Substances 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 7
- 238000000465 moulding Methods 0.000 claims description 17
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 235000010338 boric acid Nutrition 0.000 claims description 9
- 150000003891 oxalate salts Chemical class 0.000 claims description 4
- 235000013772 propylene glycol Nutrition 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- AETFVXHERMOZAM-UHFFFAOYSA-N B(O)(O)O.N.N Chemical compound B(O)(O)O.N.N AETFVXHERMOZAM-UHFFFAOYSA-N 0.000 claims description 3
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical class CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 150000004675 formic acid derivatives Chemical class 0.000 claims description 3
- UDGSVBYJWHOHNN-UHFFFAOYSA-N n',n'-diethylethane-1,2-diamine Chemical group CCN(CC)CCN UDGSVBYJWHOHNN-UHFFFAOYSA-N 0.000 claims description 3
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 3
- 239000012279 sodium borohydride Substances 0.000 claims description 3
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical class CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 6
- 239000003208 petroleum Substances 0.000 abstract description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract description 6
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 abstract description 5
- 238000005336 cracking Methods 0.000 abstract description 3
- -1 alkyl alcohol amine Chemical class 0.000 abstract description 2
- 230000007547 defect Effects 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
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- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000005802 Mancozeb Substances 0.000 description 2
- 239000005870 Ziram Substances 0.000 description 2
- 239000011717 all-trans-retinol Substances 0.000 description 2
- 235000019169 all-trans-retinol Nutrition 0.000 description 2
- FROZIYRKKUFAOC-UHFFFAOYSA-N amobam Chemical compound N.N.SC(=S)NCCNC(S)=S FROZIYRKKUFAOC-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 229940043237 diethanolamine Drugs 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 2
- DIOZVWSHACHNRT-UHFFFAOYSA-N 2-(2-prop-2-enoxyethoxy)ethanol Chemical compound OCCOCCOCC=C DIOZVWSHACHNRT-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000003260 anti-sepsis Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
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- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract
本发明提出了用于无拔模角油底壳液压拉延成型的抗挤压介质,按质量百分比,由以下组分组成:29‑31%的矿油,9‑11%的羧酸盐,8‑12%的硼酸或硼酸盐,19‑21%的烷基醇胺,9‑11%的石油磺酸钠,9‑11%的丙烯乙二醇醚,8‑10%的非离子表面活性剂,0.3‑0.7%的消泡剂,0.3‑0.7%的有机硫杀菌剂。采用本发明应用于无拔模角油底壳液压拉延成型中的凹模型腔,替代现有的拉延油,在同样的拉延模具中实现了无拔模角油底壳的拉延成型,产品的合格率达到了98%,零件上擦伤轻微,解决了冷冲压模具对材料的摩擦、材料厚度变化不均的弊端,无极限开裂,尺寸符合图纸要求。
Description
技术领域
本发明属于液压拉延成型技术领域,尤其是用于无拔模角油底壳液压拉延成型的抗挤压介质。
背景技术
针对涡轮增压发动机油底壳,有一些产品类型是无拔模角油底壳,如图1所示,其侧壁A无拔模角的,采用常规的拉延方法无法冲压成型,在拉延模具的凸模表面、凹模型腔表面涂普通的拉延油无法达到目的,成型后,起皱、开裂严重,材料厚度不均。
发明内容
为了实现无拔模角油底壳的拉延成型,本发明提出用于无拔模角油底壳液压拉延成型的抗挤压介质。
为此,本发明的技术方案为:用于无拔模角油底壳液压拉延成型的抗挤压介质,按质量百分比,由以下组分组成:29-31%的矿油,9-11%的羧酸盐,8-12%的硼酸或硼酸盐,19-21%的烷基醇胺,9-11%的石油磺酸钠,9-11%的丙烯乙二醇醚,8-10%的非离子表面活性剂,0.3-0.7%的消泡剂,0.3-0.7%的有机硫杀菌剂。
在上述技术方案中,所述羧酸盐选自甲酸盐、乙酸盐或草酸盐中的一种。
在上述技术方案中,所述硼酸盐选自硼氢化钠或硼酸氢铵中的一种。
在上述技术方案中,所述烷基醇胺选自N,N -二乙基乙醇胺、N,N-二甲基乙醇胺、N-甲基乙醇胺、二乙醇胺或三乙醇胺中的一种。
在上述技术方案中,所述有机硫杀菌剂选自代森铵、福美锌、代森锌或代森锰锌中的一种。
有益效果:本发明与现有技术的拉延油相比,用丙烯甘醇醚替代部分矿油,采用矿油与丙烯甘醇醚的组合配比起到抗挤压作用,丙烯甘醇醚兼有润滑作用,加入羧酸盐及硼酸或硼酸盐强化了润滑作用,采用本发明应用于无拔模角油底壳液压拉延成型中的凹模型腔,替代现有的拉延油,在同样的拉延模具中实现了无拔模角油底壳的拉延成型,产品的合格率达到了98%,零件上擦伤轻微,解决了冷冲压模具对材料的摩擦、材料厚度变化不均的弊端,无极限开裂,尺寸符合图纸要求。
附图说明
图1是一种无拔模角油底壳的结构示意图。
具体实施方式
下面结合实施例,进一步描述本发明。
实施例1
用于无拔模角油底壳液压拉延成型的抗挤压介质,按质量百分比,由以下组分组成:30%的矿油,10%的羧酸盐,10%的硼酸或硼酸盐,20%的烷基醇胺,9%的石油磺酸钠,11%的丙烯乙二醇醚,9%的非离子表面活性剂,0.5%的消泡剂,0.5%的有机硫杀菌剂;把各组分混合均匀,就得到成品。
实施例2
用于无拔模角油底壳液压拉延成型的抗挤压介质,按质量百分比,由以下组分组成:31%的矿油,9%的羧酸盐,8%的硼酸或硼酸盐,21%的烷基醇胺,11%的石油磺酸钠,9%的丙烯乙二醇醚,10%的非离子表面活性剂,0.7%的消泡剂,0.3%的有机硫杀菌剂;把各组分混合均匀,就得到成品。
实施例3
用于无拔模角油底壳液压拉延成型的抗挤压介质,按质量百分比,由以下组分组成:29%的矿油,11%的羧酸盐,9%的硼酸或硼酸盐,19%的烷基醇胺,9%的石油磺酸钠,11%的丙烯乙二醇醚,11%的非离子表面活性剂,0.3%的消泡剂,0.7%的有机硫杀菌剂;把各组分混合均匀,就得到成品。
在本发明中,所述羧酸盐选自甲酸盐、乙酸盐或草酸盐中的一种;优先甲酸的钠盐或钾盐,乙酸的钠盐或钾盐,草酸盐的钠盐或钾盐。
在本发明中,所述硼酸盐选自硼氢化钠或硼酸氢铵中的一种。
在本发明中,选择硼酸或硼酸盐时,优先硼酸。
在本发明中,所述烷基醇胺选自N,N -二乙基乙醇胺、N,N-二甲基乙醇胺、N-甲基乙醇胺、二乙醇胺或三乙醇胺中的一种。
在本发明中,所述非离子表面活性剂是现有技术,是市售产品;例如,非离子表面活性剂为脂肪醇聚氧乙烯醚或脂肪酸聚氧乙烯酯。
在本发明中,消泡剂是现有技术,是市售产品;例如,消泡剂选自有机硅氧烷或聚醚中的任意一种。
在上述技术方案中,所述有机硫杀菌剂是现有技术,是市售产品;所述有机硫杀菌剂选自代森铵、福美锌、代森锌或代森锰锌中的任意一种或两种。
本发明中,各组分具备的作用如下:
抗挤压作用:矿油、丙烯乙二醇醚;
润滑作用:羧酸盐、丙烯乙二醇醚、硼酸或硼酸盐;
缓蚀作用:烷基醇胺;
乳化作用:石油磺酸钠;
防锈作用:非离子表面活性剂;
消泡作用:消泡剂;
防腐杀菌作用:硼酸或硼酸盐、有机硫杀菌剂。
本发明的性能指标见上述的表1。
使用本发明的步骤如下:
(1)把拉延成型模具安装在液压拉延机上,在凹模型腔内的顶料板上注入实施例1的抗挤压介质,保证完全覆盖顶料板;
(2)在充满介质的型腔上放上平板料,在凸模上涂常规的拉延油;(3)合模:启动液压拉延机上,使拉延成型模具的上拉延成型模具、下模拉延成型模具合模;
(4)退料:成型后的发动机油底壳退出拉延成型模具。
Claims (4)
1.用于无拔模角油底壳液压拉延成型的抗挤压介质,按质量百分比,由以下组分组成:29-31%的矿油,9-11%的羧酸盐,8-12%的硼酸或硼酸盐,19-21%的烷基醇胺,9-11%的石油磺酸钠,9-11%的丙烯乙二醇醚,8-10%的非离子表面活性剂,0.3-0.7%的消泡剂,0.3-0.7%的有机硫杀菌剂。
2.根据权利要求1所述的用于无拔模角油底壳液压拉延成型的抗挤压介质,其特征在于:所述羧酸盐选自甲酸盐、乙酸盐或草酸盐中的一种。
3.根据权利要求1所述的用于无拔模角油底壳液压拉延成型的抗挤压介质,其特征在于:所述硼酸盐选自硼氢化钠或硼酸氢铵中的一种。
4.根据权利要求1或2或3所述的用于无拔模角油底壳液压拉延成型的抗挤压介质,其特征在于:所述烷基醇胺选自N,N -二乙基乙醇胺、N,N-二甲基乙醇胺、N-甲基乙醇胺、二乙醇胺或三乙醇胺中的一种。
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