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CN1066015C - Compounded prepn of Bichonglin - Google Patents

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Publication number
CN1066015C
CN1066015C CN95116465A CN95116465A CN1066015C CN 1066015 C CN1066015 C CN 1066015C CN 95116465 A CN95116465 A CN 95116465A CN 95116465 A CN95116465 A CN 95116465A CN 1066015 C CN1066015 C CN 1066015C
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preparation
pesticide
imidacloprid
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pests
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CN1147335A (en
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郭武棣
周惠中
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Shenyang Research Institute of Chemical Industry Co Ltd
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Shenyang Research Institute of Chemical Industry Co Ltd
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Abstract

The present invention relates to a pesticide preparation with high efficiency, low toxicity and strong systemic translocation, which has a special good effect on piercing-sucking pests and pests with scratching mouthparts, such as aphids, leafhoppers, plant hoppers, thrips, white flies and resistant strains. The compounded preparation provided by the present invention is a compounded preparation by compounding imidacloprid, sand worm toxin pesticide, pyrethrin pesticide, organic phosphide pesticide, carbamate pesticide and heterocyclic pesticide.

Description

吡虫啉的复配制剂Compound preparation of imidacloprid

吡虫啉的英文名:ImidaclopridThe English name of imidacloprid: Imidacloprid

结构式:

Figure 9511646500031
Structural formula:
Figure 9511646500031

吡虫啉是由日本特殊农药公司和Bayer A.G.开发的高效、低毒、具有内吸性的杀虫剂,对刺吸式、吮吸式口器害虫,如蚜虫、叶蝉、飞虱、蓟马、粉虱及其抗性品系有特效;对鞘翅目、双翅目、鳞翅目也有一定的防效。由于它有内吸作用,它的各种剂型都有良好的防效。Imidacloprid is a high-efficiency, low-toxicity, and systemic insecticide developed by Japan Special Pesticide Company and Bayer A.G. It is effective against piercing and sucking mouthpart pests, such as aphids, leafhoppers, planthoppers, thrips, powder Lice and its resistant strains have special effects; it also has certain control effects on Coleoptera, Diptera and Lepidoptera. Because of its systemic effect, its various dosage forms have good preventive effects.

吡虫啉与多种农药复配可提高药效、扩大杀虫谱,降低使用成本。The combination of imidacloprid and a variety of pesticides can improve the efficacy, expand the insecticidal spectrum and reduce the cost of use.

J.P.63 126804曾报道吡虫啉与杀螟丹的复配制剂,对防治稻纵卷叶螟有明显增效作用。J.P.63 126804 has reported that the compound preparation of imidacloprid and cartap has obvious synergistic effect on the control of rice leaf roller.

杀螟丹: Cartap:

本发明提出了吡虫啉与杀蚕毒类农药杀虫丹、杀虫双、杀虫环、硫氰酯;与菊酯类农药氯氟氰菊酯、氰戊菊酯、氯氰菊酯、溴氰菊酯;与有机磷类农药辛硫磷、毒死蜱、三唑磷、甲胺磷;与氨基甲酯类农药乐果、氧化乐果、速灭威、抗蚜威及杂环类农药噻嗪酮(扑虱灵)等农药复配成二元以上杀虫制剂,以提高药效、扩大杀菌谱、降低农用成本。The present invention proposes imidacloprid and silkworm-killing poisonous pesticides chlorchondan, dimehypo, dimetap, and thiocyanate; and pyrethroid pesticides cyhalothrin, fenvalerate, cypermethrin, and deltamethrin; With organophosphorus pesticides phoxim, chlorpyrifos, triazophos, methamidophos; with carbamate pesticides dimethoate, omethoate, memecarb, pirimicarb and heterocyclic pesticide buprofezin ( Ling) and other pesticides are compounded into more than binary insecticide preparations to improve efficacy, expand bactericidal spectrum, and reduce agricultural costs.

本发明提出了吡虫啉与杀蚕毒类农药杀虫双等的复配制剂对刺吸式、吮吸式口器害虫有增效作用,而且对咀嚼式害虫的防效也非常突出。

Figure 9511646500033
The invention proposes that the compound preparation of imidacloprid and silkworm poisonous pesticide dimehypo has synergistic effect on piercing and sucking mouthparts pests, and the control effect on chewing pests is also very prominent.
Figure 9511646500033

本发明提出的吡虫啉与其它杀虫剂可制成粉剂、可湿性粉剂、水分散粒剂、悬浮剂、乳剂等。The imidacloprid and other insecticides proposed by the present invention can be made into powder, wettable powder, water dispersible granule, suspension, emulsion and the like.

制剂的有效成分:吡虫啉在制剂中占1-90%(重量百分数),其它有效成分在制剂中占90-1%(重量百分数)。Active ingredients of the preparation: imidacloprid accounts for 1-90% (weight percentage) in the preparation, and other active ingredients account for 90-1% (weight percentage) in the preparation.

制剂中所用的稳定剂有:柠檬酸、硼酸、HAC、H3PO4、NH4Cl、(NH4)2SO4The stabilizers used in the formulation are: citric acid, boric acid, HAC, H 3 PO 4 , NH 4 Cl, (NH 4 ) 2 SO 4 .

所采用的助剂有:木质素磺酸钠、十二烷基硫酸钠、分散剂NNO、渗透剂T、农乳500#、农乳600#、农乳100#、CMC、1656H、1656L9。The additives used are: sodium lignosulfonate, sodium lauryl sulfate, dispersant NNO, penetrant T, agricultural milk 500 # , agricultural milk 600 # , agricultural milk 100 # , CMC, 1656H, 1656L9.

制剂中所采用的填料有:硅藻土、凹凸棒土、高岭土、膨润土、CaCO3 NaHCO3The fillers used in the preparation include: diatomite, attapulgite, kaolin, bentonite, CaCO 3 NaHCO 3 .

例1:example 1:

吡虫啉25%、杀虫丹25%、木质素磺酸钠6%、NNO4%、硼酸5%、加硅藻土补至100%,得50%可湿性粉剂。25% of imidacloprid, 25% of insecticide, 6% of sodium lignosulfonate, 4% of NNO, 5% of boric acid, adding diatomaceous earth to make up to 100%, to obtain 50% wettable powder.

例2:Example 2:

吡虫啉10%、杀虫丹10%、农乳500#或600#5%、NNO4%、硼酸10%、CMC55、补加NaHCO3至100%得20%水分散粒剂。10% of imidacloprid, 10% of insecticide, Nongru 500 # or 600 # 5%, NNO4%, boric acid 10%, CMC55, add NaHCO 3 to 100% to get 20% water dispersible granules.

例3:Example 3:

吡虫啉10%、氯氟氰菊酯10%、木质素磺酸钠6%、1656H5%、NNO5%、乙二醇10%,加水补至100%,制得20%悬浮剂。10% of imidacloprid, 10% of cyhalothrin, 6% of sodium lignosulfonate, 5% of 1656H, 5% of NNO, and 10% of ethylene glycol were added to make up to 100% with water to prepare a 20% suspension concentrate.

例4:Example 4:

吡虫啉5%、辛硫磷35%、1656L9或1656H6%、加二甲苯补至100%,制得40%乳剂。Imidacloprid 5%, phoxim 35%, 1656L9 or 1656H6%, add xylene to make up to 100%, and make 40% emulsion.

例5:Example 5:

吡虫啉5%、速灭威35%、木质素磺酸钠6%、NNO4%、加高岭土补至100%,制得40%可湿粉。Imidacloprid 5%, Memocarb 35%, Sodium Lignosulfonate 6%, NNO 4%, add kaolin to make up to 100%, and make 40% wettable powder.

例6:Example 6:

吡虫啉10%、噻嗪酮30%、木质素磺酸钠6%、NNO4%、加高岭土补至100%,制得40%可湿粉剂。10% of imidacloprid, 30% of buprofezin, 6% of sodium lignosulfonate, 4% of NNO, added kaolin to make up to 100%, and a 40% wettable powder was prepared.

例7:Example 7:

吡虫啉20%、硫氰酯20%、木质素磺酸钠6%、NNO4%、硼酸5%、加硅藻土补至100%,制得50%可湿性粉剂。20% imidacloprid, 20% thiocyanate, 6% sodium lignosulfonate, 4% NNO, 5% boric acid, add diatomaceous earth to make up to 100%, and make 50% wettable powder.

本发明的复配制剂对防治刺吸式、吮吸式口器害虫有增效作用,如对叶蝉、飞虱、蓟马、粉虱以及鞘翅目、双翅目、鳞翅目有特效。The compound preparation of the present invention has a synergistic effect on the prevention and control of sucking and sucking mouthpart pests, such as special effects on leafhoppers, planthoppers, thrips, whiteflies, Coleoptera, Diptera and Lepidoptera.

例8:Example 8:

吡虫啉与杀虫丹以不同比例(1∶1,1∶2,1∶3,1∶4,1∶5)进行毒力筛选试验,若采用1∶1的比例时,使用浓度在1ppm,2ppm,4ppm对蚕豆蚜的防效分别为31.5%,59.5%,82.3%,说明活性物质大于4ppm时就有明显的防效。Imidacloprid and chlorchongdan are used in different ratios (1:1, 1:2, 1:3, 1:4, 1:5) for toxicity screening tests. If the ratio of 1:1 is used, the concentration used is 1ppm, 2ppm The control effects of 4ppm on broad bean aphid were 31.5%, 59.5%, and 82.3%, respectively, indicating that when the active substance is greater than 4ppm, there is an obvious control effect.

Claims (4)

1、一种吡虫啉与杀虫丹复配制成的杀虫制剂,吡虫啉在制剂中占重量的10-25%,杀虫丹在制剂中占重量的10-25%,制剂中还加入稳定剂、助剂和填料。1. An insecticidal preparation compounded by imidacloprid and chlorchongdan, imidacloprid accounts for 10-25% by weight in the preparation, chlorchondan accounts for 10-25% by weight in the preparation, stabilizer, Auxiliaries and fillers. 2、根据权利要求1所述的杀虫制剂,其特征在于:该复配制剂的剂型有粉剂、可湿粉剂、水分散剂、悬浮剂、乳剂。2. The insecticide preparation according to claim 1, characterized in that: the formulations of the compound preparation include powder, wettable powder, water dispersion, suspension and emulsion. 3、根据权利要求1或2所述的杀虫制剂,其特征在于:该复配制剂中所用的稳定剂有柠檬酸、硼酸、HAC、H3PO4、NH4Cl、(NH4)2SO4,所用的助剂有木质素磺酸钠、十二烷基硫酸钠、分散剂NNO、渗透剂T、农乳500#、农乳600#、农乳100#、CMC、1656H、1656L9;所用的填料有硅藻土、凹凸棒土、高岭土、膨润土、CaCO3、NaHCO33. The insecticide preparation according to claim 1 or 2, characterized in that: the stabilizers used in the compound preparation include citric acid, boric acid, HAC, H 3 PO 4 , NH 4 Cl, (NH 4 ) 2 SO 4 , the additives used are sodium lignosulfonate, sodium lauryl sulfate, dispersant NNO, penetrant T, agricultural milk 500 # , agricultural milk 600 # , agricultural milk 100 # , CMC, 1656H, 1656L9; The fillers used are diatomite, attapulgite, kaolin, bentonite, CaCO 3 , NaHCO 3 . 4、本发明所提出的杀虫制剂在防治刺吸式、咀嚼式害虫中的应用。4. The application of the insecticidal preparation proposed by the present invention in the control of piercing-sucking and chewing pests.
CN95116465A 1995-10-06 1995-10-06 Compounded prepn of Bichonglin Expired - Fee Related CN1066015C (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
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CN103222473A (en) * 2013-05-06 2013-07-31 南通金陵农化有限公司 Imidacloprid and buprofezin compound pesticide

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US6048542A (en) * 1999-03-08 2000-04-11 Bayer Corporation Inhibiting growth of microorganisms in water-based pesticide suspensions
AU2010215126B2 (en) * 2009-02-20 2013-12-19 Deepak Pranjivandas Shah A novel water dispersible granular composition
KR101747922B1 (en) * 2009-05-06 2017-06-15 바이엘 크롭사이언스 엘피 A method for increasing the vigor and/or crop yield of agricultural plants under essentially non-existent pathogen pressure
CN102090415A (en) * 2009-12-14 2011-06-15 联合国南通农药剂型开发中心 Insecticide composition for preventing and controlling termites, and product preparation method and application thereof
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CN102017988A (en) * 2010-12-15 2011-04-20 广西安泰化工有限责任公司 Deltamethrin and imidacloprid composition and preparations thereof
CN102204530B (en) * 2011-04-07 2013-11-27 德强生物股份有限公司 Imidacloprid suspension
CN102265900A (en) * 2011-08-31 2011-12-07 甘肃省农业科学院植物保护研究所 Formula and preparation method of granular pesticide
CN103651342A (en) * 2012-08-31 2014-03-26 江苏长青农化股份有限公司 Wettable powder with buprofezin content being 25 percent
CN103651547B (en) * 2013-12-27 2015-11-25 贵州交勘生态园林有限责任公司 The seed dressing of karst shrub slope protection seed and using method
CN104322548A (en) * 2014-10-24 2015-02-04 柳州市天姿园艺有限公司 Insecticide for controlling aphid pests of pomegranate trees
CN105794833A (en) * 2014-12-31 2016-07-27 殷瑞嶺 Compound pesticide of imidacloprid and deltamethrin
CN104813872A (en) * 2015-03-10 2015-08-05 安徽省农业科学院农业工程研究所 Method for preventing harm from North-America red-maple long-horned beetles
CN106386826A (en) * 2016-08-31 2017-02-15 江苏天容集团股份有限公司 Insecticide composition containing cycloxaprid and dimehypo
CN109156473A (en) * 2018-11-09 2019-01-08 华南农业大学 Prevent and treat large small moth note dry medicament and preparation method
CN111011073A (en) * 2020-01-08 2020-04-17 浙江人文园林股份有限公司 Method for preventing and treating Chinese wistaria weevil

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Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63126804A (en) * 1986-11-14 1988-05-30 Nippon Tokushu Noyaku Seizo Kk Agricultural and horticultural insecticidal composition
CN1067781A (en) * 1991-06-26 1993-01-13 先灵公司 Insecticides
CN1108043A (en) * 1993-11-04 1995-09-13 罗纳-普朗克农业化学公司 Combinations of a fungicide containing an azole group with an insecticide containing a pyrazole, pyrrole or phenylimidazole group

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103222473A (en) * 2013-05-06 2013-07-31 南通金陵农化有限公司 Imidacloprid and buprofezin compound pesticide

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