CN106496916A - A kind of Novel shoe material composite and preparation method thereof - Google Patents
A kind of Novel shoe material composite and preparation method thereof Download PDFInfo
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- CN106496916A CN106496916A CN201610964355.1A CN201610964355A CN106496916A CN 106496916 A CN106496916 A CN 106496916A CN 201610964355 A CN201610964355 A CN 201610964355A CN 106496916 A CN106496916 A CN 106496916A
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- material composite
- novel shoe
- agent
- shoe material
- compatilizer
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- 239000000463 material Substances 0.000 title claims abstract description 63
- 239000002131 composite material Substances 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims description 6
- 238000005299 abrasion Methods 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 20
- 239000003607 modifier Substances 0.000 claims abstract description 18
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 17
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 15
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims abstract description 14
- 239000004088 foaming agent Substances 0.000 claims abstract description 11
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 10
- 239000006229 carbon black Substances 0.000 claims abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 10
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000008117 stearic acid Substances 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004611 light stabiliser Substances 0.000 claims abstract description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004593 Epoxy Substances 0.000 claims abstract description 5
- 238000002347 injection Methods 0.000 claims description 22
- 239000007924 injection Substances 0.000 claims description 22
- 239000002994 raw material Substances 0.000 claims description 14
- -1 Polysiloxane Polymers 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000011236 particulate material Substances 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 230000032683 aging Effects 0.000 abstract description 7
- 230000007062 hydrolysis Effects 0.000 abstract description 2
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- 239000004793 Polystyrene Substances 0.000 description 7
- 229920001971 elastomer Polymers 0.000 description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 3
- 238000009740 moulding (composite fabrication) Methods 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000013536 elastomeric material Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2453/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
A kind of Novel shoe material composite that the present invention is provided, by weight percentage, including：SBS 20%～50%, SEBS 20%～50%, PS 10%～30%, naphthenic oil 10%～30%, Calcium Carbonate 5%～20%, White Carbon black 1%～20%, compatilizer 1%～10%, PE base materials 1%～10%, abrasion resistance modifier 1%～5%, stearic acid 0.1%～1%, antiaging agent 0.1%～1%；Foaming agent 0.05%～1%, cross-linking agent 0.05%～10%, wherein, compatilizer includes that maleic anhydride based compatilizer and epoxy based compatilizer, the abrasion resistance modifier include compounding abrasion resistance modifier, and the antiaging agent includes light stabilizer.The footwear material of the present invention has proportion little, light weight；High intensity, high tenacity, high resilience, high abrasion, high slip preventing；The high premium properties of aging resistance, hydrolysis, dimensional stability.
Description
Technical field
The present invention relates to footwear material technical field, and in particular to a kind of Novel shoe material composite and preparation method thereof.
Background technology
The sole of prior art generally adopts elastomeric material to make to increase the wearability of sole, and is used for making sole
The eventful thermosets of elastomeric material, it is impossible to carry out injection mo(u)lding, the sole of prior art is generally made up of multilayer material, and each
One-shot forming is unable between layer, needs to carry out bonding by glue, and the sole of prior art and upper of a shoe generally adopt bonding or
Person reaches the standard grade plus the mode of bonding is attached, it is impossible to enough one-shot formings.Various rubber manufacture shoe rubber bottoms can so be caused
There is low numerous and diverse operation, high energy consumption, efficiency, poor working environment, big for environment pollution in technique；Manufactured goods are than great, comfortable and easy to wear
Property is poor；Manufactured goods can not be reclaimed, and there is environmental pollution, and endanger the healthy of direct labor.
Content of the invention
The present invention provides a kind of Novel shoe material composite and preparation method thereof, to solve the above problems.
A kind of Novel shoe material composite that the present invention is provided, by weight percentage, including：SBS 20%～50%,
SEBS 20%～50%, PS 10%～30%, naphthenic oil 10%～30%, Calcium Carbonate 5%～20%, White Carbon black 1%～
20%, compatilizer 1%～10%, PE base materials 1%～10%, abrasion resistance modifier 1%～5%, stearic acid 0.1%～1% are prevented old
Agent 0.1%～1%；Foaming agent 0.05%～1%, cross-linking agent 0.05%～10%.
Preferably, by weight percentage, including：SBS 25%～40%, SEBS 25%～40%, PS 10%～
30%, naphthenic oil 10%～30%, Calcium Carbonate 5%～20%, White Carbon black 1%～20%, compatilizer 1%～10%, PE base materials
1%～10%, abrasion resistance modifier 1%～5%, stearic acid 0.1%～1%, antiaging agent 0.1%～1%；Foaming agent 0.05%
～1%, cross-linking agent 0.05%～10%.
Preferably, the Novel shoe material composite also includes pigment 0.05%～0.1%.
Preferably, the compatilizer is maleic anhydride based compatilizer or epoxy based compatilizer.
Preferably, the abrasion resistance modifier is polysiloxane.
Preferably, the antiaging agent is light stabilizer.
Preferably, the cross-linking agent is cumyl peroxide.
Present invention additionally comprises the method for preparing the footwear material composite, specifically includes following steps：
A, banbury banburying after the raw material mix homogeneously, will be added, the pressure of the banbury is 40～100MPa,
Mixing temperature is 150～190 DEG C, and mixing time was 1～8 minute；
B, the raw material for unloading step A banbury add single screw extrusion machine pelletize；
C, by step B particulate material add injection machine, be molded in footwear mould by the injection machine；
D, after step C footwear mould is cooled to, then molded.
SEBS in footwear material composite of the present invention is preferably highly -branched SEBS, and SEBS has excellent ageing-resistant
Performance, can make footwear material that both there is plasticity, there is high resiliency again, and processing by need not vulcanizing is used, and leftover pieces can be used again, extensively
General for producing high-grade elastomer, modifying plastics, adhesive, lubricant tackifier, the inserts of electric wire and protective cover material etc..
SEBS has good weatherability, thermostability, compression resistant morphotropism and excellent mechanical property.
SBS in footwear material composite of the present invention has unrivaled advantage, the present invention in the processed and applied of footwear material
The footwear material composite containing SBS there is excellent thermoplastic property, can realize the injection molding of sole, shaping speed is than tradition
Vulcanite fast, greatly improve production efficiency, saved the energy and cost, can be by sole and footwear by injection mo(u)lding
Face is integrally formed, bonding of need not reaching the standard grade.Injection mo(u)lding it also avoid the pollution produced in traditional rubber soles forming process, will not
The healthy of people is caused damage, sanitation and hygiene.
Naphthenic oil in Novel shoe material composite of the present invention can increase the plasticity of footwear material, and this performance is conducive to footwear material
Injection mo(u)lding.
Foaming agent in Novel shoe material composite of the present invention can cause footwear material composite, foam fine and uniform,
While making material light weight, with excellent structural strength, toughness, elasticity and dimensional stability.
Compatilizer in Novel shoe material composite of the present invention can make footwear material that there is excellent structural strength, high tenacity and excellent
Good adhesive property.
PS in above-mentioned footwear material composite is polystyrene, and have the advantages that lightweight high rigidity, extruded sheet is completely closed
Hole foaming structure forms lightweight, and uniform honeycomb texture causes high hard, but unlike polyurethane foam, phenolic foam
Embrittlement, therefore not cracky are not only carried, install light, and cutting is easily.
The present invention has advantages below compared with prior art：
The Novel shoe material composite of the present invention is made using thermoplastic, can realize the integrated injection molding of sole into
Type, it is not necessary to which sole is made multiple structure carries out bonding by viscose glue by bottom of multilayer shoe structure again, can also be by sole and footwear
Face integrated injection molding and eliminate and sole and vamp reached the standard grade bonding operation.This footwear material composite can simplify production work
Skill, improves work efficiency, using injection mo(u)lding, it is to avoid infringement of the rubber footwear material composite to body, and cleanliness without any pollution is comprehensive
Close low cost.
The sole anti-wear performance that the footwear material composite of the present invention is made is strong, and non-skid property is good, ageing-resistant, and light weight is tough
Property high, the Novel shoe material composite material and technique of the present invention can be used to manufacture sole, can be used as sport shoess, jogging shoes, stop
Not busy footwear, leather shoes, children's footwear, the footwear of slippers.
Specific embodiment
Below in conjunction with the embodiment of the present invention to the embodiment of the present invention in technical scheme be clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiment.In based on the present invention
Embodiment, all other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of Novel shoe material composite, by weight percentage, including：SBS 35%, SEBS 20%, PS10%, ring
Alkane oil 15%, Calcium Carbonate 5%, White Carbon black 5%, compatilizer 5%, PE base materials 2%, abrasion resistance modifier 2%, stearic acid 0.5% are prevented
Aging dose 0.4%；Foaming agent 0.05%, cross-linking agent 0.05%.Wherein, the compatilizer is maleic anhydride based compatilizer, described
Abrasion resistance modifier is polysiloxane, and the antiaging agent is light stabilizer, and cross-linking agent is cumyl peroxide.
Present invention additionally comprises the method for preparing the footwear material composite, specifically includes following steps：
A, banbury banburying after the raw material mix homogeneously, will be added, the pressure of the banbury is 50MPa, banburying temperature
Spend for 150 DEG C, mixing time is 3 minutes；
B, the raw material for unloading step A banbury add single screw extrusion machine pelletize；
C, by step B particulate material add injection machine, be molded in footwear mould by the injection machine.
Embodiment two：
A kind of Novel shoe material composite, by weight percentage, including：SBS 20%, SEBS 35%, PS 10%,
Naphthenic oil 15%, Calcium Carbonate 5%, White Carbon black 5%, compatilizer 5%, PE base materials 2%, abrasion resistance modifier 2%, stearic acid 0.5%,
Antiaging agent 0.4%；Foaming agent 0.05%, cross-linking agent 0.05%.Wherein, the compatilizer is epoxy based compatilizer, described resistance to
Mill modifying agent is polysiloxane, and the antiaging agent is light stabilizer, and cross-linking agent is cumyl peroxide.
Present invention additionally comprises the method for preparing the footwear material composite, specifically includes following steps：
A, banbury banburying after the raw material mix homogeneously, will be added, the pressure of the banbury is 60MPa, banburying temperature
Spend for 170 DEG C, mixing time is 2 minutes；
B, the raw material for unloading step A banbury add single screw extrusion machine pelletize；
C, by step B particulate material add injection machine, be molded in footwear mould by the injection machine.
Embodiment three：
A kind of Novel shoe material composite, by weight percentage, including：SBS 50%, SEBS 20, PS 10%, ring
Alkane oil 10%, Calcium Carbonate 5%, White Carbon black 1%, compatilizer 1%, PE base materials 1%, abrasion resistance modifier 1%, stearic acid 0.4% are prevented
Aging dose 0.3%；Foaming agent 0.1%, cross-linking agent 0.1%, pigment 0.1%.Wherein, the compatilizer is that maleic acid anhydride group is compatible
Agent, the abrasion resistance modifier are polysiloxane, and the antiaging agent is light stabilizer, and cross-linking agent is peroxidating diisopropyl
Benzene.
The method for preparing above-mentioned footwear material composite, specifically includes following steps：
A, banbury banburying after the raw material mix homogeneously, will be added, the pressure of the banbury is 70MPa, banburying temperature
Spend for 160 DEG C, mixing time is 6 minutes；
B, the raw material for unloading banbury add single screw extrusion machine pelletize；
C, by step B particulate material add injection machine, by the injection machine to injection mo(u)lding in footwear mould.
Example IV：
A kind of Novel shoe material composite, by weight percentage, including：SBS 20%, SEBS 50%, PS 10%,
Naphthenic oil 10%, Calcium Carbonate 5%%, White Carbon black 1%, compatilizer 1%, PE base materials 1%, abrasion resistance modifier 1%, stearic acid
0.2%, antiaging agent 0.1%；Foaming agent 0.08%, cross-linking agent 0.62%.Wherein, the compatilizer is epoxy based compatilizer,
The abrasion resistance modifier is polysiloxane, and the antiaging agent is light stabilizer, and cross-linking agent is cumyl peroxide.
The method for preparing above-mentioned footwear material composite, specifically includes following steps：
A, banbury banburying after the raw material mix homogeneously, will be added, the pressure of the banbury is 80MPa, banburying temperature
Spend for 170 DEG C, mixing time is 5 minutes；
B, the raw material for unloading banbury add single screw extrusion machine pelletize；
C, by step B particulate material add injection machine, by the injection machine to injection mo(u)lding in footwear mould.
Embodiment five：
A kind of Novel shoe material composite, by weight percentage, including：SBS 25%, SEBS 25%, PS 15%,
Naphthenic oil 15%, Calcium Carbonate 9%, White Carbon black 3%, compatilizer 2%, PE base materials 1.5%, abrasion resistance modifier 2.5%, stearic acid
0.5%, antiaging agent 0.5%；Foaming agent 0.05%, cross-linking agent 0.95%.Wherein, the compatilizer is that maleic acid anhydride group is compatible
Agent, the abrasion resistance modifier are polysiloxane, and the antiaging agent is light stabilizer, and cross-linking agent is peroxidating diisopropyl
Benzene.
The method for preparing above-mentioned footwear material composite, specifically includes following steps：
A, banbury banburying after the raw material mix homogeneously, will be added, the pressure of the banbury is 100MPa, banburying
Temperature is 190 DEG C, and mixing time is 6 minutes；
B, the raw material for unloading banbury add single screw extrusion machine pelletize；
C, by step B particulate material add injection machine, by the injection machine to injection mo(u)lding in footwear mould.
The detection of the combination property that the sole that following table is the applicant to be made to implementing the footwear material composite in two is carried out：
| Test event | Method of testing | Standard value | Measured value |
| Ooze out test | CT-05 | Without permeability | Without permeability |
| Ageing-resistant test (7 days, 50 DEG C) | FT-07 | 5 | 5 |
| Sun-proof Tachistoscope | FT-11 | 4 | 5 |
| Hardness | GE-09 | 55-60 | 56 |
| Proportion | GE-15 | G/CBCM | 0.825 |
| DIN wear-resisting tests | GE-27 | Max 100 | 53 |
| Abrasion mark is tested | GE-82 | Without vestige | Nothing |
| Albefaction is tested | GE-38 | Without albefaction layer | Nothing |
| Tearing strength | ST-02 | MIN 12 | 17.8 |
| Elongation at break | ST-03 | MIN 350% | 649% |
| 300% stretches pulling force surely | ST-03 | MIN 3.5MPa | 3.69 |
| Tensile strength | ST-03 | MIN 11N | 12.7 |
The footwear that the Novel shoe material composite prepared by embodiment two is made are can be seen that by the detection data of upper table
Bottom has following premium properties：Proportion is little, light weight；High intensity, high tenacity, high resilience, high abrasion, high slip preventing, aging resistance,
Hydrolysis；Dimensional stability is high.
A kind of Novel shoe material composite that above embodiment of the present invention is provided and preparation method thereof has been carried out in detail
Introduce, specific case used herein is set forth to the principle of the present invention and embodiment, the explanation of above example
It is only intended to the core concept for helping understand the present invention；Simultaneously for one of ordinary skill in the art, according to the think of of the present invention
Think and method, will change in specific embodiments and applications, in sum, this specification content should not be managed
Solve as limitation of the present invention.
Claims (8)
1. a kind of Novel shoe material composite, it is characterised in that by weight percentage, including：SBS20%～50%, SEBS
20%～50%, PS 10%～30%, naphthenic oil 10%～30%, Calcium Carbonate 5%～20%, White Carbon black 1%～20%, phase
Hold agent 1%～10%, PE base materials 1%～10%, abrasion resistance modifier 1%～5%, stearic acid 0.1%～1%, antiaging agent
0.1%～1%；Foaming agent 0.05%～1%, cross-linking agent 0.05%～10%.
2. Novel shoe material composite according to claim 1, it is characterised in that：By weight percentage, including：SBS
25%～40%, SEBS 25%～40%, PS 10%～30%, naphthenic oil 10%～30%, Calcium Carbonate 5%～20%, in vain
Carbon black 1%～20%, compatilizer 1%～10%, PE base materials 1%～10%, abrasion resistance modifier 1%～5%, stearic acid 0.1%
～1%, antiaging agent 0.1%～1%；Foaming agent 0.05%～1%, cross-linking agent 0.05%～10%.
3. Novel shoe material composite according to claim 1, it is characterised in that：The Novel shoe material composite is also wrapped
Include pigment 0.05%～0.1%.
4. Novel shoe material composite according to claim 1, it is characterised in that：The compatilizer is maleic acid anhydride group phase
Hold agent or epoxy based compatilizer.
5. according to the Novel shoe material composite of any one of claim 1 or 2, it is characterised in that：The abrasion resistance modifier is
Polysiloxane.
6. Novel shoe material composite according to claim 1, it is characterised in that：The antiaging agent is light stabilizer.
7. Novel shoe material composite according to claim 1, it is characterised in that：The cross-linking agent is peroxidating diisopropyl
Benzene.
8. the preparation method of Novel shoe material composite according to claim 1, it is characterised in that comprise the following steps：
A, banbury banburying after the raw material mix homogeneously, will be added, the pressure of the banbury is 40～100MPa, banburying
Temperature is 150～190 DEG C, and mixing time was 1～8 minute；
B, the raw material for unloading step A banbury add single screw extrusion machine pelletize；
C, by step B particulate material add injection machine, be molded in footwear mould by the injection machine；
D, after step C footwear mould is cooled to, then molded.
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| CN107090171A (en) * | 2017-06-02 | 2017-08-25 | 安徽爱舍家居制品有限公司 | A kind of preparation method of the mosquito-proof cooling slippers of soft |
| CN107629387A (en) * | 2017-04-14 | 2018-01-26 | 莆田市三迪鞋服有限公司 | A kind of improved TPR ultra-light sole materials |
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| CN115011061A (en) * | 2022-05-06 | 2022-09-06 | 茂泰(福建)鞋材有限公司 | A kind of anti-cracking thermoplastic rubber sole and preparation method thereof |
| CN115368684A (en) * | 2022-08-11 | 2022-11-22 | 金发科技股份有限公司 | PS composite material and preparation method and application thereof |
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