CN1064945C - Compound wax for emulsified explosive - Google Patents
Compound wax for emulsified explosive Download PDFInfo
- Publication number
- CN1064945C CN1064945C CN961064439A CN96106443A CN1064945C CN 1064945 C CN1064945 C CN 1064945C CN 961064439 A CN961064439 A CN 961064439A CN 96106443 A CN96106443 A CN 96106443A CN 1064945 C CN1064945 C CN 1064945C
- Authority
- CN
- China
- Prior art keywords
- oil
- wax
- emulsion explosive
- compound wax
- slack
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title claims abstract description 36
- 150000001875 compounds Chemical class 0.000 title claims abstract description 28
- 239000000839 emulsion Substances 0.000 claims abstract description 33
- 239000003208 petroleum Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 9
- 238000004821 distillation Methods 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000010426 asphalt Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- 230000006837 decompression Effects 0.000 claims description 4
- 239000000025 natural resin Substances 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- 239000000057 synthetic resin Substances 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 229920003987 resole Polymers 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 12
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 abstract 2
- 239000003921 oil Substances 0.000 description 62
- 239000001993 wax Substances 0.000 description 35
- 239000003995 emulsifying agent Substances 0.000 description 11
- 239000012188 paraffin wax Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- -1 Vaseline Substances 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- 229940099259 vaseline Drugs 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 229960005215 dichloroacetic acid Drugs 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- LUPNKHXLFSSUGS-UHFFFAOYSA-M sodium;2,2-dichloroacetate Chemical compound [Na+].[O-]C(=O)C(Cl)Cl LUPNKHXLFSSUGS-UHFFFAOYSA-M 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000005474 detonation Methods 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 229940056211 paraffin Drugs 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- FWVCSXWHVOOTFJ-UHFFFAOYSA-N 1-(2-chloroethylsulfanyl)-2-[2-(2-chloroethylsulfanyl)ethoxy]ethane Chemical compound ClCCSCCOCCSCCCl FWVCSXWHVOOTFJ-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 101000809257 Homo sapiens Ubiquitin carboxyl-terminal hydrolase 4 Proteins 0.000 description 1
- 241000233855 Orchidaceae Species 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 102100038463 Ubiquitin carboxyl-terminal hydrolase 4 Human genes 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 229940001516 sodium nitrate Drugs 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Colloid Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The present invention provides a compound wax of an emulsion explosive, which is low in cost and wide in source. Atmosphere 3rd side cut oil, vacuum 1st side cut oil, vacuum 2nd side cut oil, vacuum 3rd side cut oil, vacuum 4th side cut oil, etc. generated in the process of petroleum processing and deoiled cerate and dewaxed oil thereof, residue cerate, light deasphalted oil and heavy deasphalted oil serve as base materials, and an or a plurality of kinds of the base materials are mixed and modulated to obtain the present invention. The cost of the emulsion explosive can be greatly reduced by using the compound wax of an emulsion explosive.
Description
The present invention relates to a kind of compound wax that is used for emulsion explosive.
Emulsion explosive is mainly by as the aqueous inorganic oxidizer salt solution component of disperse phase, form as the hydrocarbon fuel component of external phase, the sensitization gas composition (density adjustment agent) and emulsifying agent four parts that form disperse phase.Oil phase material mainly plays external phase and incendiary material effect in emulsion explosive, the hydrocarbon polymer that the water-fast performance of any different sources is suitable all can be used as oil phase material, the wax, oil and the polymkeric substance that comprise various sources, but consider oil phase material in emulsion process easy emulsifying property and the stability of emulsion, generally all contain long chain hydrocarbon component (as paraffin) and short chain hydrocarbon compound component (as diesel oil, lubricated wet goods).Simultaneously, for adjusting the viscosity of oil phase, generally also add a small amount of superpolymer (as PIB, EVA) owing to the petroleum products aboundresources, great variety of goods and price are lower, so petroleum refinement products such as kerosene, diesel oil, lubricating oil, Vaseline, paraffin, ceresine are used widely in emulsion explosive.
At USP3,445,890 disclose since the emulsion explosive first from H.F.Blume, and people have done a lot of improvement to emulsion explosive.USP4,790, it is oil phase that a kind of emulsion explosive of 890 propositions utilizes mineral oil, 2# oil fuel, vegetables oil, paraffin, Microcrystalline Wax etc., it is the emulsion explosive of oil phase with paraffin, Vaseline, mineral oil, stearic mixture that CN1034336A discloses a kind of, and the emulsion explosive that CN1061213A proposes is an oil phase with paraffin, ceresine, rosin.These patents adopted all based on petroleum wax, Vaseline, lubricating oil.GB2,224,501A has done a little improvement on this basis, proposes to increase aromaticity content with the increase Stability of Emulsion Explosives, but aromatic hydroxy compound volatilization and inflammable easily works the mischief to operative employee's human and environment.The emulsion explosive of all these reports is the oil phase basic raw material with the petroleum refinement product all, petroleum cuts is concocted by a certain percentage more again through oil/wax separation and purification and after making corresponding wax or oil production, not only waste the manpower and materials and the energy but also increased the cost of oil phase, thus the corresponding emulsion explosive cost that increased.
The object of the invention is rationally to utilize refinery's resource, with atmosphere 3rd side cut oil, first vacuum side stream, second line of distillation oil, subtract third fractional oil, subtract four line wet goods fractions oil and corresponding de-oiling slack wax and residue slack wax, frivolous asphalt oil, heavy and light deasphalted oil be basic material, is mixed into a kind of with low cost, emulsion explosive compound wax that stable performance is enriched in the source.Thereby avoided wax/separating of oil refining unnecessary technology of blending again, reduced the oil phase cost, thereby reduced the emulsion explosive cost.
Emulsion explosive compound wax of the present invention, it by atmosphere 3rd side cut oil, first vacuum side stream, second line of distillation oil, subtract third fractional oil, subtract four line wet goods fraction oil and de-oiling slack wax thereof, one or more mixtures of residue slack wax, frivolous asphalt oil, heavy and light diasphaltene wet goods oil intermediate product form.
The main body of emulsion explosive compound wax of the present invention contains (in compound wax weight, w%): the frivolous asphalt oil 0-15% of atmosphere 3rd side cut oil 0-5% vacuum distillate 5-40% decompression slack wax 40-90% residual oil slack wax 0-40% heavy deasphalted oil 0-15%
Wherein vacuum distillate is first vacuum side stream, second line of distillation oil, subtracts third fractional oil, subtracts four line oil and composition thereof.The decompression slack wax is the second line of distillation slack wax, subtracts three-way slack wax, subtracts four line slack waxs and composition thereof.
Emulsion explosive compound wax of the present invention also can contain natural resin or the synthetic resins of 0-5%, the polymkeric substance of 0-5%.
Natural resin or synthetic resins comprise Gum Rosin and derivative thereof, terpine resin, resol, aliphatic petroleum resin, aromatic petroleum resin, hydrogenated petroleum resin.
The polymkeric substance number-average molecular weight is 500-100000, comprises second third glue, PE, PP, PIB, EVA.
The emulsion explosive compound wax advantage that the present invention proposes is rationally to utilize refinery's resource, with the oil middle distillate is the oil phase basic material, abandoned the traditional technology of concocting again behind oil/wax separation and purification, thereby avoided middle unnecessary human and material resources, energy dissipation, thereby reduced the oil phase cost significantly.It is refining that basic material of the present invention does not carry out desulfurization, denitrogenation, deoxidation, demetalization, so sulphur, nitrogen, oxygen, metal, the aromatic hydrocarbons equal size of compound wax of the present invention are higher, the polarity of compound wax is increased, thereby increased the easy milkiness of compound wax of the present invention.With compound wax of the present invention is oil phase and be that oil phase prepares emulsion explosive and compares with petroleum refinement products such as paraffin, ceresine, Vaseline, blast performance and stable storing performance do not reduce, and the oil phase cost reduces significantly, the corresponding emulsion explosive cost that reduced, have good economic benefits, have good use properties simultaneously.
Specify the present invention below by embodiment.
Embodiment of the invention raw material is all adopted white orchid state refinery head factory, and its performance sees Table 1.
Annotate: * is 25 ℃ a penetration degree
| Condensation point (℃) | Oleaginousness (%) | Viscosity (100 ℃ of mm 2/s) | Cone penetration (25 ℃ of 1/10mm) | |
| Atmosphere 3rd side cut oil | 5.0 | / | 3.01 | / |
| First vacuum side stream | 25.0 | 90.0 | 4.98 | / |
| Second line of distillation oil | 35.0 | 88.0 | 5.02 | / |
| Subtract third fractional oil | 37.0 | 85.0 | 5.55 | / |
| Subtract four line oil | 42.0 | 60.0 | 8.58 | 46 |
| Subtract two slack waxs | 50.2 | 7.0 | 4.89 | 21* |
| Subtract three slack waxs and subtract four slack waxs | 53.1 56.5 | 9.5 20.0 | 5.02 6.08 | 19* 25 |
| The residue slack wax | 69.0 | 42.5 | 19.3 | 40 |
| Frivolous asphalt oil | 38.0 | 72.0 | 8.82 | / |
| Heavy deasphalted oil | 40.0 | 69.0 | 12.1 | 65 |
Embodiment of the invention prescription (weight percent composition) and performance thereof see Table 2.
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Atmosphere 3rd side cut oil | 5 | 0 | 0 |
| First vacuum side stream | 0 | 0 | 0 |
| Second line of distillation oil | 0 | 5 | 0 |
| Subtract third fractional oil | 0 | 0 | 0 |
| Subtract four line oil | 15 | 0 | 0 |
| Subtract four slack waxs | 40 | 77 | 95 |
| The residue slack wax | 40 | 0 | 0 |
| Frivolous asphalt oil | 0 | 0 | 0 |
| Heavy deasphalted oil | 0 | 15 | 0 |
| PIB(Mn=5000) | 0 | 3 | 0 |
| Gum Rosin | 0 | 0 | 5 |
| Condensation point (℃) | 55 | 56 | 58 |
| Oil length (%) | 30 | 29 | 19．5 |
| Cone penetration (1/10mm) | 30 | 27 | 21 |
| Viscosity (100 ℃ of mm 2／s) | 10．25 | 14．78 | 8．01 |
As can be seen from Table 2, compound wax of the present invention has indexs such as more suitable condensation point, oil length, penetration degree, viscosity, is comparatively ideal emulsion explosive oil phase material.
Comparative example 1
Adopt USP4, the oil phase prescription (umber) of 790,890 embodiment 1,
Mineral oil 15
58# paraffin 75
Comparative example 2
Adopt GB2,224, the oil phase prescription (umber) of 501A embodiment 8,
Toluene 100
Under 1700 rev/mins condition, carry out the emulsion explosive application test with compound wax of the present invention and comparative example compound wax, its performance sees the following form, by data more as can be seen when emulsifying agent is identical, the critical consumption of the required emulsifying agent of compound wax of the present invention is lower, and the detonation property of preparation emulsion explosive is compared with comparative example with stability and is improved to some extent, and the oil phase cost reduces significantly.Preparation of emulsifying explosive is (with an emulsion explosive, umber):
Ammonium nitrate 66
SODIUMNITRATE 13
Urea 4.5
Water 10.5
Compound wax 4.2
Emulsifying agent 1.8
Perlite 4
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | |
| Emulsifying agent | T-152 | SP-80 | SP-80 | SP-80 | T-152 |
| Induced detonation (mm) | 60 | 60 | 70 | 70 | 60 |
| High cold cycle (individual) | 45 | 15 | 11 | 10 | 43 |
| Oil phase cost (unit/ton) | 1500 | 1500 | 1600 | 3800 | 4000 |
| Emulsifying agent critical amount (w%) | 0．4 | 0．25 | 0．20 | 0．35 | 0．5 |
Emulsifying agent T～152 involved in the present invention, T-153 are succimide family macromolecule emulsifying agent, and Lanzhou refinery head factory additive subsidiary factory produces.P-190 is the reaction product of polyisobutenyl maleic anhydride and glycol ether and trolamine.
Annotate 1: high cold cycle is for estimating the important indicator of emulsion explosive, and the cycle number height represents that then Emulsion Explosive Stability is good.Its testing method is to get 50 gram emulsion explosive samples to place 8 hours in 50 ℃ baking oven, puts into 25 ℃ refrigerator-freezer after the taking-up again and places 16 hours as a circulation, takes out the baking oven circulation of putting into 50 ℃ again and carries out, till emulsion explosive sample conduction.
Annotate 2: the critical consumption of emulsifying agent is the important indicator of the easy milkiness of examination compound wax, and critical consumption represents that greatly then the easy milkiness of this compound wax is good, otherwise then easily milkiness is poor.Testing method reduces emulsifier content for based on preparation of emulsifying explosive, until reducing then not emulsification again.This moment, the emulsifying agent consumption was critical consumption.
Annotate 3: oil phase cost keeping is calculated by the raw material reference price that Lanzhou refinery head factory provides.
Claims (5)
1. compound wax that is used for emulsion explosive is characterized in that in the percentage composition of compound wax weight as follows:
Atmosphere 3rd side cut oil 0-5%
Vacuum distillate 5-40%
Decompression slack wax 40-90%
Residual oil slack wax 0-40%
Frivolous asphalt oil 0-15%
Heavy deasphalted oil 0-15%.
2. according to the described compound wax of claim 1, it is characterized in that said vacuum distillate is first vacuum side stream, second line of distillation oil, subtracts third fractional oil, subtracts four line oil and composition thereof.
3. according to the described compound wax of claim 1, it is characterized in that said decompression slack wax is the second line of distillation slack wax, subtracts three-way slack wax, subtracts four line slack waxs and composition thereof.
4. according to the described compound wax of claim 1, it is characterized in that also containing natural resin or the synthetic resins of 0-5w%, it is 500～100000 second third glue, PE, PP, PIB, EVA that the polymkeric substance of 0-5w%, described polymkeric substance are selected from number-average molecular weight.
5. according to the described compound wax of claim 4, it is characterized in that said natural resin or synthetic resins comprise Gum Rosin and derivative, terpine resin, resol, aliphatic petroleum resin, aromatic petroleum resin or hydrogenated petroleum resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN961064439A CN1064945C (en) | 1996-08-20 | 1996-08-20 | Compound wax for emulsified explosive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN961064439A CN1064945C (en) | 1996-08-20 | 1996-08-20 | Compound wax for emulsified explosive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1174182A CN1174182A (en) | 1998-02-25 |
| CN1064945C true CN1064945C (en) | 2001-04-25 |
Family
ID=5119170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN961064439A Expired - Lifetime CN1064945C (en) | 1996-08-20 | 1996-08-20 | Compound wax for emulsified explosive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1064945C (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101108917B (en) * | 2007-08-23 | 2012-05-23 | 华东理工大学 | A plant-type special wax for emulsion explosives and its preparation method |
| CN102452864B (en) * | 2010-10-14 | 2014-12-10 | 中国石油化工股份有限公司 | Preparation method of powdery emulsion explosive oil phase material |
| CN103113172B (en) * | 2013-03-07 | 2014-12-17 | 辽宁红山化工股份有限公司 | Opencast emulsion explosive and preparation method thereof |
| CN103804921B (en) * | 2013-12-26 | 2016-06-08 | 江西抚州国泰特种化工有限责任公司 | A kind of explosive loading paper web plant blended wax |
| CN105732240A (en) * | 2014-12-08 | 2016-07-06 | 雅化集团旺苍化工有限公司 | Emulsion explosive permissible in grade-three coal mine |
| CN105384587B (en) * | 2015-11-10 | 2017-08-04 | 中国石油化工股份有限公司 | A kind of Special Compound Wax for Emulsion Explosives based on heavy deasphalted oil |
| CN107011104A (en) * | 2017-05-03 | 2017-08-04 | 常州市润星化工有限公司 | Powdery emulsifying explosive composite oil phase and preparation method thereof |
| CN107129421B (en) * | 2017-07-04 | 2018-08-17 | 中国石油化工股份有限公司 | A kind of viscosity grainy emulsified explosive special oil |
| CN107382639A (en) * | 2017-07-28 | 2017-11-24 | 宜兴市阳生化工有限公司 | A kind of high-performance three-level colliery powdery emulsifying explosive and preparation method thereof |
| CN111646871A (en) * | 2020-06-22 | 2020-09-11 | 云南安化有限责任公司 | A kind of high-performance hard emulsion explosive and preparation method thereof |
| CN114621042A (en) * | 2022-03-10 | 2022-06-14 | 安徽理工大学 | Powdery emulsion explosive for explosive welding |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0319324A1 (en) * | 1987-12-03 | 1989-06-07 | Ireco Incorporated | Packaged emulsion explosives and methods of manufacture thereof |
| EP0368495A2 (en) * | 1988-11-07 | 1990-05-16 | C-I-L Inc. | Aromatic hydrocarbon-based emulsion explosive composition |
| CN1061213A (en) * | 1991-06-14 | 1992-05-20 | 华东工学院 | Emulsified powdered nitramon and manufacture method thereof |
-
1996
- 1996-08-20 CN CN961064439A patent/CN1064945C/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0319324A1 (en) * | 1987-12-03 | 1989-06-07 | Ireco Incorporated | Packaged emulsion explosives and methods of manufacture thereof |
| EP0368495A2 (en) * | 1988-11-07 | 1990-05-16 | C-I-L Inc. | Aromatic hydrocarbon-based emulsion explosive composition |
| CN1061213A (en) * | 1991-06-14 | 1992-05-20 | 华东工学院 | Emulsified powdered nitramon and manufacture method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1174182A (en) | 1998-02-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1064945C (en) | Compound wax for emulsified explosive | |
| CA2243054C (en) | Multiple emulsion and method for preparing same | |
| US6461497B1 (en) | Reformulated reduced pollution diesel fuel | |
| EP0757092B1 (en) | Gas oil | |
| EP3165587A2 (en) | Method for reducing hydrogen sulfide evolution from asphalt and heavy fuel oils sulfide evolution from asphalt and heavy fuel oils | |
| US6004361A (en) | Low emissions diesel fuel | |
| CN1049025A (en) | Liquid fuel mixture, method for the production thereof and use thereof in two-stroke engines | |
| KR19980702715A (en) | Fuel oil composition | |
| JPH08157839A (en) | Fuel composition | |
| US4309191A (en) | Coal-oil mixture | |
| CN1064946C (en) | Compound organic component for emulsified explosive | |
| JPH01502122A (en) | Method of upgrading waxy oil into products that can be used as light fuel oil, diesel fuel and other upgrading oils | |
| WO2005028596A1 (en) | Marine fuel | |
| CA2429289A1 (en) | Essentially hydrocarbon compositions to be used as fuels with enhanced lubricating properties | |
| US4299594A (en) | Process for utilizing waste lubricating oils | |
| RU2107084C1 (en) | Method of producing road bitumens | |
| RU2154665C1 (en) | Fuel composition | |
| JP3729211B2 (en) | Diesel diesel oil composition | |
| CN100335597C (en) | Ethyl alcohol gasoline and preparing process thereof | |
| CN1102853A (en) | Multi-effect diesel compound additives and preparation thereof | |
| RU2004578C1 (en) | Method for production of arctic diesel fuel | |
| RU2030445C1 (en) | Method for cleaning secondary gas oil | |
| EP1246893A2 (en) | Diesel fuel composition | |
| RU2704480C1 (en) | Method of producing vacuum distillate fractions with improved low-temperature properties | |
| CN102051237A (en) | Preparation formula of high-cleanliness gasoline |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: CHINA PETROCHEMICAL CORPORATION; CHINA PETROLEUM & Free format text: FORMER NAME OR ADDRESS: CHINA PETRO-CHEMICAL CORP.; FUSHUN PETROCHEMICAL INSTITUTE., CHINA PETROCHEMICAL CORP. |
|
| CP01 | Change in the name or title of a patent holder |
Patentee after: China Petrochemical Group Corp. Patentee after: Sinopec Group Fushun Research Institute of Petroleum and Petrochemicals Patentee before: China Petrochemical Corporation Patentee before: Fushun Research Inst. of Petroleum Processing, China Petro-chem. Corp. |
|
| CX01 | Expiry of patent term |
Granted publication date: 20010425 |
|
| EXPY | Termination of patent right or utility model |