CN106417300A - 一种杀虫剂增效助剂 - Google Patents
一种杀虫剂增效助剂 Download PDFInfo
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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Abstract
本发明公开了一种杀虫剂增效助剂。以β‑细辛醚，胡椒碱，表面活性剂，展着剂，稳定剂和溶剂经混合溶解加工而成。该增效助剂不仅具有较强的润湿、渗透及展着作用，同时还具有绿色、低毒、广谱、高效等特点。该增效助剂不仅可以当助剂应用于杀虫剂配方中，还可以当桶混助剂直接与各类杀虫剂现配现用，稳定性好，增效效果显著。
Description
技术领域
本发明涉及农药增效助剂领域，具体地说是一种含β-细辛醚和胡椒碱的杀虫剂增效助剂。
技术背景
β-细辛醚是一种神经毒剂类杀虫单体，主要通过抑制害虫体内的乙酰胆碱酯酶与谷胱甘S2转移酶的活性，从而使得害虫逐渐停止取食，活力消失，瘫痪，最终死亡。虽然β-细辛醚对害虫有一定的活性，但不足于单独开发成杀虫剂。
胡椒碱是从胡椒中分离提取出来的一类植物源活性成分，在自然中容易降解，对人畜安全，绿色环保，对双翅目、鳞翅目害虫有一定的活性，但不足于单独开发成杀虫剂。
杀虫剂增效剂是指对昆虫没有或者很少有杀虫性能的一类化学品，但添加于某一杀虫剂后，能大大地提升杀虫剂的杀虫效果。添加增效剂的优点在于，能大大增加杀虫效果，减少杀虫剂用量，从而降低成本，减少人类环境的污染，对于环境保护、造福人类有不可忽视的作用，可有效延缓害虫对杀虫剂的抗药性，并且能更加经济、有效地对害虫进行防控。
目前，很多昆虫杀虫剂的增效剂具有一定的专一性，而且稳定性较差。市场上缺乏广谱的稳定性较高的杀虫剂增效助剂。本发明的目的提供一种以β-细辛醚与胡椒碱为主要成分的杀虫剂增效剂，该增效助剂不仅可以当助剂应用于杀虫剂配方中，还可以当桶混助剂直接与各类杀虫剂现配现用，同时该增效助剂具有较强展着渗透性，稳定性好，增效效果显著。
发明内容
本发明的具体技术方案如下：
一种杀虫剂增效助剂，其特征在于：它是以β-细辛醚与胡椒碱为有效成分，加入表面活性剂、稳定剂、展着剂和溶剂水制备而得。
以上所述各组分重量百分比为：
β-细辛醚1-5％；胡椒碱1-5％；表面活性剂5-15％；稳定剂0.1-1.5％；展着剂1-5％；溶剂补足100％。
优选各组分重量百分比为：
β-细辛醚2-3％；胡椒碱2-3％；表面活性剂10-12％；稳定剂0.1-1％；展着剂3-5％；溶剂补足100％。
以上所述的表面活性剂是烷基酚聚氧乙烯醚、壬基酚聚氧乙烯醚、蓖麻油聚氧乙烯醚和苯乙基酚聚氧乙烯醚中一种或一种以上的组合。
以上所述的稳定剂是三苯基亚磷酸酯、丁基羟基茴香醚、二丁基羟基甲苯、特丁基对苯二酚中一种或一种以上的组合。
以上所述的展着剂是有机硅，具体可选择广州多利多化Agrowet 820或西陇化工ES-80中一种或一种以上的组合。
以上所述的溶剂是松脂基植物油、150#溶剂油中一种或一种以上的组合。
本发明的制备方法：预先将上述组份按照重量百分比称取好备用，在常温下先将溶剂投入反应釜中，开启反应釜搅拌器，在搅拌条件下投入β-细辛醚和胡椒碱至完全溶解后，投入表面活性剂后，停止加料，关闭抽料阀门，打开反应釜的放空阀，分别加入稳定剂和展着剂，待物料加完后继续搅拌30分钟即可。
本发明的优点：
1、广谱性。可广泛应用于各类杀虫剂中，不仅可以当助剂应用于杀虫剂配方中，还可以当桶混助剂直接与各类杀虫剂现配现用。
2、绿色、安全、环保。本发明的增效助剂所用到的组分都是绿色，环保材料，加工及使用过程中对人类及环境安全。
3、稳定、高效。本发明的增效助剂具有较强展着渗透性，稳定性好，增效效果显著。
具体实施方式
为了更好的理解本发明的实质，下面用实施例来详细说明发明的技术内容，但本发明并不局限于此。
实施例1增效助剂
按以下重量配比：β-细辛醚3％；胡椒碱2％；烷基酚聚氧乙烯醚12％；三苯基亚磷酸酯0.5％；Agrowet 820 5％；松脂基植物油补至足100％。
实施例1中增效助剂的制备方法是：预先将上述组份按照重量百分比称取好备用，在常温下先将溶剂投入反应釜中，开启反应釜搅拌器，在搅拌条件下投入β-细辛醚和胡椒碱至完全溶解后，投入表面活性剂后，停止加料，关闭抽料阀门，打开反应釜的放空阀，分别加入稳定剂和展着剂，待物料加完后继续搅拌30分钟即可。
实施例2增效助剂在杀虫剂配方中应用
表1增效助剂在杀虫剂配方中应用对甜菜夜蛾防治效果
从表2中可以看出：本发明的增效助剂在5.7％甲维盐微乳剂、5％阿维菌素微乳剂与15％高效氯氟氰菊酯微乳剂3种杀虫剂配方中添加量为5％时，能大幅度提升对甜菜夜蛾的防治效果。
实施例3增效助剂与杀虫剂桶混使用
表2增效助剂与杀虫剂桶混使用对斜纹夜蛾防治效果
从表2中可以看出：本发明的增效助剂与5.7％甲维盐微乳剂、5％阿维菌素微乳剂与15％高效氯氟氰菊酯微乳剂3种杀虫剂桶混使用时，能大幅度提升对斜纹夜蛾的防治效果。
以上对本发明提供的一种杀虫剂增效助剂进行了详细介绍，本文中应用了具体个例对本发明的原理及实施方式进行了详细的阐述，以上实施例的说明只是用于帮助理解本发明的及其核心思想，但不局限于此。
Claims (7)
1.一种杀虫剂增效助剂，其特征在于：该增效助剂由为β-细辛醚，胡椒碱，表面活性剂，稳定剂，展着剂和溶剂六种组分，该增效助剂各组分重量百分比为：β-细辛醚1-5％，胡椒碱1-5％，表面活性剂5-15％，稳定剂0.5-1.5％，展着剂1-5％，余量为溶剂。
2.一种杀虫剂增效助剂，其特征在于：所述各组分重量百分比优选为：β-细辛醚2-3％，胡椒碱2-3％，表面活性剂10-12％，稳定剂0.5-1％，展着剂3-5％，余量为溶剂。
3.根据权利要求1或2所述一杀虫剂增效助剂，其特征在于：所述的表面活性剂是烷基酚聚氧乙烯醚、壬基酚聚氧乙烯醚、蓖麻油聚氧乙烯醚和苯乙基酚聚氧乙烯醚中一种或一种以上的组合。
4.根据权利要求1或2所述一种杀虫剂增效助剂，其特征在于：所述稳定剂是三苯基亚磷酸酯、丁基羟基茴香醚、二丁基羟基甲苯、特丁基对苯二酚中一种或一种以上的组合。
5.根据权利要求1或2所述一种杀虫剂增效助剂，其特征在于：所述展着剂是有机硅，具体可选择广州多利多化学Agrowet 820或西陇化工ES-80中一种或一种以上的组合。
6.根据权利要求1或2所述一种杀虫剂增效助剂，其特征在于：所述的溶剂是松脂基植物油、150#溶剂油中一种或一种以上的组合。
7.根据权利要求1或2所述一种杀虫剂增效助剂，其特征在于：不仅可以当助剂应用于杀虫剂配方中，还可以当桶混助剂直接与各类杀虫剂现配现用。
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