CN1064098C - Plastic-cement field material and preparing process thereof - Google Patents
Plastic-cement field material and preparing process thereof Download PDFInfo
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- CN1064098C CN1064098C CN97100229A CN97100229A CN1064098C CN 1064098 C CN1064098 C CN 1064098C CN 97100229 A CN97100229 A CN 97100229A CN 97100229 A CN97100229 A CN 97100229A CN 1064098 C CN1064098 C CN 1064098C
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- dimethylbenzene
- plastic
- surface layer
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- 239000000463 material Substances 0.000 title claims abstract description 49
- 239000004568 cement Substances 0.000 title claims description 22
- 238000000034 method Methods 0.000 title description 7
- 239000003292 glue Substances 0.000 claims abstract description 21
- 239000010410 layer Substances 0.000 claims abstract description 9
- 239000002344 surface layer Substances 0.000 claims abstract description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 32
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 17
- 229920001169 thermoplastic Polymers 0.000 claims description 13
- 239000004416 thermosoftening plastic Substances 0.000 claims description 13
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 12
- 239000008096 xylene Substances 0.000 claims description 12
- 239000006004 Quartz sand Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 229920001971 elastomer Polymers 0.000 claims description 6
- 239000005060 rubber Substances 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- 239000002383 tung oil Substances 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 3
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims 6
- 239000003963 antioxidant agent Substances 0.000 claims 3
- 230000003078 antioxidant effect Effects 0.000 claims 3
- 229950002083 octabenzone Drugs 0.000 claims 3
- 239000000049 pigment Substances 0.000 claims 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000011229 interlayer Substances 0.000 claims 1
- 229920003023 plastic Polymers 0.000 abstract description 5
- 239000004033 plastic Substances 0.000 abstract description 5
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 15
- 229920006305 unsaturated polyester Polymers 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 241001062009 Indigofera Species 0.000 description 6
- 239000012965 benzophenone Substances 0.000 description 6
- 239000004604 Blowing Agent Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 230000035882 stress Effects 0.000 description 5
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 230000003064 anti-oxidating effect Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000011295 pitch Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 230000009975 flexible effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 230000004899 motility Effects 0.000 description 1
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Road Paving Structures (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
一种塑胶场地材料,主要由底层胶、中间胶和面层胶组成,铺设于运动场地,有利于运动员训练和比赛。A plastic field material, mainly composed of bottom layer glue, intermediate glue and surface layer glue, which is laid on the sports field and is beneficial to athletes' training and competition.
Description
The present invention relates to a kind of plastic-cement field material and application thereof.
At present, though existing both at home and abroad plastic-cement field material from material form, or everyway such as preparation process exists deficiency, for example: Elastoplastic cement of mentioning in the CN1052883 patent application and production method thereof, system is by Corvic, dibutyl phthalate (DBP)s etc. stir in container by a certain percentage and soak certain hour, heat while stirring then to treat that solution is raised to and be cast in the metal pattern after the uniform temperature and keep certain hour promptly to produce the Elastoplastic cement of function admirable.And for example: a kind of method for making of natural fibre reinforced plastic is mentioned in the CN1105045 patent application, and the method is to add in the unsaturated polyester (UP) of per 100 parts of weight: the blowing agent (except the CFCs) of the organic molten system of volatility of 30 to 300 parts of weight: the organic peroxide catalyzer contact agent of 0.5 to 3 part of weight; And Wood flour filled dose of scheduled volume; With the above-mentioned unsaturated polyester (UP) of natural fiber impregnation, form through the heating press quenching, its fabrication steps is as follows: step a. drops into the filler of scheduled volume in the liquid blowing agent, and blowing agent is filled till the agent absorption fully; Step b. drops into the filler of the above-mentioned blowing agent of impregnation in the unsaturated polyester (UP) together with catalyzer contact agent and is mixed into batching; Step c is the unsaturated polyester (UP) of natural fiber silk impregnation step b batching, and in a die cavity, with 30 to 150kg/CM
2, 100 to 160 ℃ temperature heating pressurization, heat time heating time, every millimeter thickness was about 30 to 45 seconds, made that the blowing agent of impregnation evaporates fully in the filler, and made polyester foamed hardened forming.These method activities cost height, the material cost height, the place non-skid property is poor; Engineering time is restricted; The place poor flexibility; Easily aging, the life-span is short etc.
The purpose of this invention is to provide a kind of plastic-cement field material and application thereof.
Plastic material of the present invention is mainly used in places such as basketball, vollyball, shuttlecock, tennis, and the track and field runway.Plastic-cement field material with the inventive method preparation can be got rid of the feared state of mind that the sportsman moves on rough earth, and helps the teenager and often take exercise and avoid the motility bone damage, and the damage of health.
The raw material that is used to prepare plastic-cement field material mainly is selected from thermoplastic butadiene-styrene rubber (Beijing Yanshan Petro-Chemical Industry Corporation provides (SBS-1401)).Dimethylbenzene and neoprene (CR-244) etc.
The main raw material(s) of plastic-cement field material of the present invention has:
1. thermoplastic butadiene-styrene rubber (SBS-1401)
Main effect:, play enhancing elasticity, fusible effect as the main constituent of the material of synthetic court; Thermoplastic butadiene-styrene rubber preferred star-shaped sbs-4402, type SBS-1407.
2. neoprene (CR-244)
Main effect:, play the increased viscosity effect as the main constituent of the material of synthetic court;
3. dimethylbenzene
Main effect: dissolving thermoplastic butadiene-styrene rubber and neoprene;
4. granulated rubber, polyurethane material, particle diameter 3-5mm.
Main effect: play when being used for the track and field runway and increase thickness and flexible effect;
5. 2-hydroxyl-4 oxy-octyl benzophenone
(UV531 or ultra-violet absorber)
6. antioxidizing and antigum agent (age resistor, the German business men product trade mark are 264-1010,264 liang of models)
Main effect: avoid the place aging, life-saving;
7. give birth to tung oil, the place of production: all can in domestic various places.
Main effect: increase the ground surface elastic;
8. castor oil, the place of production: all can in domestic various places.
Main effect: increase the ground surface elastic:
9. quartz sand (place of production: Yanqing granularity: 60-80 order, particle diameter 0.015mm)
Main effect: increase the ground friction;
10. tributyl phosphate (process level) is selected for use as required
Promptly under the moisture conditions of ground, can select tributyl phosphate for use for preventing to bubble;
Play a part to prevent to come off, so general drying normally need not during surface construction;
1. color: red (808 red)
Iron oxide red
Phthalocyanine green
The Chinese is husky yellow
Network green (or chrome green)
Phthalocyanine blue
The phthalein white powder
The preparation method of plastic-cement field material of the present invention is as follows:
Usually plastic floor divides indigo plant, row, tennis court and Track field two classes, and technology is slightly different.
Track field adopts batching back one-shot forming, and indigo plant, row, tennis court divide three layers to lay respectively, bottom, and main rising adhered to basal plane, bonding, waterproof action; Elastic reaction is mainly played in 24 hours Hou Pu middle levels, also is elastic layer; Paving layer after 24 hours, rise anti-skidding, the anti-aging effect; Can enable after 48 hours.
The technology of plastic-cement field material is equipped with process:
For indigo plant, row, tennis court:
1, neoprene (CR-244) is used xylene soluble, and the ratio of neoprene and dimethylbenzene is 1-3: 7-11
2, bottom glue
Thermoplastic butadiene-styrene rubber (SBS-1401) 30-60 part, with 90-120 part xylene soluble, add again and dissolved good 10-40 part neoprene, add ultra-violet absorber (2-hydroxyl-4 oxy-octyl benzophenone) 0.1-0.35 part, antioxidizing and antigum agent (trade mark 264) 0.2-0.55 part adds the color that has prepared in right amount and gets final product.
3, middle level glue
Thermoplastic butadiene-styrene rubber 30-60 part adds the neoprene that 5-12 part has been dissolved with 70-90 part xylene soluble, adds 2-hydroxyl-4 oxy-octyl benzophenone 0.15-0.4 part again.
Antioxidizing and antigum agent (trade mark 264) 0.2-0.5 part.
Give birth to tung oil 1-3.6 part.
Castor oil 1-3.6 part.
Quartz sand 2-5 part.
The color that has been mixed with is an amount of.
4, surface layer glue
Thermoplastic butadiene-styrene rubber 25-50 part
Dimethylbenzene 80-120 part
Neoprene 7-15 part (having used xylene soluble)
Quartz sand 4-15 part
Ultra-violet absorber 0.09-0.335 part
Antioxidizing and antigum agent (264) 0.25-0.5 part
It is an amount of to add color.
The Track field batching prepares in above ratio, once add all needed raw materials, and add granulated rubber in addition, it is polyurethane material, particle diameter 3-5mm, main effect: increase thickness and elasticity when being used for the track and field runway, this granulated rubber and above total material ratio are 1-4: 2.5-10, the once-paving moulding, the granularity 3-5mm of granulated rubber.
Plastic-cement field material of the present invention is compared with domestic and international field material at present, and cost is low, cost of material is low, wear-resisting, withstand voltage, ageing-resistant, water-fast, anti-sunlight, good springiness etc.
The every technical indicator of plastic-cement field material of the present invention all meets the regulation of country to standard blue, row, tennis court and track and field runway.And overcome infringement and the mental handicape that causes to athletes ' body with material-paving places such as cement or pitches.
Plastic-cement field material condition experiment of the present invention:
80 ℃ of 70 hours no changes of high temperature resistant test
Cold test-40 ℃>200 hours no changes
The water resistant test water logging did not have any variation in 1 year
50 circulation no changes of atmospheric exposure test (80 ℃ 9 hours-12 ℃ 15 hours be a circulation)
Bonding force>50kg/cm
2
Table 1 plastic cement motion ground (track and field runway) finished product technical standard
| Interventions Requested | Technical requirements | Measured result | |
| Breaking strength MP a | ≥0.8 | 2.4 | |
| Elongation at break % | ≥100 | 170 | |
| Hardness (Shao Er A) degree | 33-75 | 58 | |
| Impact elasticity % | 20-50 | 36 | |
| Compressive stress MP a | Distortion 10% | 0.2-1.0 | 0.8 |
| Compressive stress MP a | Distortion 50% | 1.8-5.5 | 3.3 |
Can find out this product through the check breaking strength from table 1, elongation rate, hardness all surpasses technical standard, and the optimum effect of tool.
Table 2 plastic cement motion ground (indigo plant, row, tennis) finished product technical standard
| Interventions Requested | Technical requirements | Measured result | |
| Breaking strength MP a | ≥0.8 | 3.5 | |
| Elongation at break % | ≥100 | 160 | |
| Hardness (Shao Er A) degree | 33-75 | 72 | |
| Impact elasticity % | 20-50 | 27 | |
| Compressive stress MP a | Distortion 10% | 0.2-1.0 | 0.9 |
| Compressive stress MP a | Distortion 50% | 1.8-5.5 | 5.1 |
Compare from table 1, table 2, Track field is had any different with indigo plant, row, each index of tennis court, and Track field elasticity is bigger, and hardness diminishes, and compressive stress is littler.
Track field disposal molding, gross thickness are 15 millimeters.
It moves on track field mainly due to sportsman's drift bolt footwear thereby a material rubber is arranged, and thickness is bigger about 3 times than tennis court thickness.
Indigo plant, row, tennis court are divided three layers: surface layer (skid resistant course), middle level (elastic layer), bottom (adhesive layer), every layer of effect have difference again, thickness 3-4mm.
Following embodiment further specifies of the present invention, and the unrestricted scope of the invention.
Embodiment 1: eight tennis courts of Beijing Sport University's " international invitational tournament of Beijing 96 tennises "
Concrete pedestal, three section bar material mainly refer to ground basal plane situation:
Activities: a tennis court area is: 39.77
m* 22.97
mThe outfield
23.77m positive of * 10.97m
By 4 tons of tennis court materials
Calculate that a year square metre materials 6-9 kilogram batching deal then provides by a square meter materials quantity:
Neoprene is opened 2:8.5 (dissolving ratio) amount (kg/m with xylene soluble
2) bottom: 1.0 kilograms of (m of thermoplastic butadiene-styrene rubber
2) 1.0
With 1.0 kilograms of xylene soluble 1.0
Add 1.0 kilograms of neoprenes 2.0 of having used xylene soluble
Add ultraviolet ray and receive vapor (2-hydroxyl-4 oxy-octyl benzophenone)
0.01 kilogram 0.01
Age resistor (264 trades mark Germany produces) 0.03
Color: phthalocyanine green reaches with yellow, green 0.03 kilogram of 0.05 middle level of network: 1.0 kilogram 1.0 in thermoplastic butadiene-styrene rubber
With 1.2 kilograms of xylene soluble 1.2
Add 0.25 kilogram and dissolved neoprene 0.25
Ultra-violet absorber (2-hydroxyl-4 oxy-octyl benzophenone)
0.03 kilogram 0.03
0.04 kilogram 0.04 in age resistor (264 trades mark Germany produces)
Give birth to tung oil 0.15 kilogram 0.15
0.15 kilogram 0.15 of castor oil
0.17 kilogram 0.17 of quartz sand (particle diameter 80 orders)
Color: phthalocyanine green reaches with yellow, green 0.05 surface layer of network: 0.75 kilogram 0.75 in thermoplastic butadiene-styrene rubber
0.25 kilogram 0.25 of dimethylbenzene
0.2 kilogram 0.2 of neoprene
0.2 kilogram 0.2 of quartz sand (particle diameter 60 orders)
Ultra-violet absorber (2-hydroxyl-4 oxy-octyl benzophenone)
0.03 kilogram 0.03
0.04 kilogram 0.04 in age resistor (264 trades mark Germany produces)
Color: phthalocyanine green, and with yellow, network green 0.05
The common network court needs materials 6-9 kilogram for average one meter, and thickness 3-4mm prepares burden as above the positive place of color
Be green, the outfield is red materials: red, iron oxide red, all use xylene soluble, ratio 0.1: 1 (comparing) with total amount.
After finishing the place, well through match, training reflection.Embodiment 2: the Peking University tennis court
The pitch basis, technology is prepared burden as example 1.Embodiment 3: the 1500m of Tsing-Hua University
2The tennis court;
6000m
2The track and field runway;
Track field thickness 15mm, average every square meter materials 18-27 kilogram, proportion scale such as example 1, one-shot forming, technology is simpler than the tennis court, only prepares material and color in proportion, directly lays to get final product.Embodiment 4: Physical Culture Institute, Shenyang track and field runway 100M, and 8 roads batching is the same; Embodiment 5: Kunming, Yunnan, eight tennis court proportionings of elder brother's steel are with example 1.
Claims (4)
1. plastic-cement field material is characterized in that comprising following bottom glue material, middle level glue material, surface layer glue material:
The bottom glue material is with 90~120 parts of xylene soluble with 30~60 parts of thermoplastic butadiene-styrene rubber, add 10~40 parts of neoprenes that dissolved with dimethylbenzene, 0.1~0.35 part of Octabenzone, 0.2~0.55 part of antioxidant, an amount of pigment again, mixing
The middle level glue material is with 70~90 parts of xylene soluble with 30~60 parts of thermoplastic butadiene-styrene rubber, add 5~12 parts of neoprenes that dissolved with dimethylbenzene, 0.15~0.4 part of Octabenzone, 0.2~0.5 part of antioxidant, 1~3.6 part of living tung oil, 1~3.6 part of castor oil, 2~5 parts of quartz sand, an amount of pigment again, mixing
The surface layer glue material is with 80~120 parts of xylene soluble with 25~50 parts of thermoplastic fourth rubber, add 7~15 parts of neoprenes that dissolved with dimethylbenzene, 4~15 parts of quartz sand, 0.09~0.335 part of Octabenzone, 0.25~0.5 part of antioxidant, an amount of pigment again, mixing;
Above-mentioned umber all is parts by weight, and the weight proportion of the described neoprene that has dissolved with dimethylbenzene: neoprene: dimethylbenzene is 1-3: 7-11.
2. according to the described plastic-cement field material of claim 1, it is characterized in that also comprising that granularity is the polyurethane material of 3~5mm, its amount is 1-4: 2.5-10 for the weight ratio of polyurethane material and bottom glue, middle level glue, surface layer glue material sum.
3. the described plastic-cement field material of claim 1 is applied to basketball, vollyball, tennis court, it is characterized in that laying successively bottom glue, middle level glue, surface layer glue material, re-lays new layer after interlayer was separated by 24 hours, and every layer thickness is 3~4mm.
4. the described plastic-cement field material of claim 2 is applied to Track field, it is characterized in that with once-paving moulding behind bottom glue, middle level glue, surface layer glue material and the polyurethane material mixing, the laying gross thickness is 15mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97100229A CN1064098C (en) | 1997-01-09 | 1997-01-09 | Plastic-cement field material and preparing process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97100229A CN1064098C (en) | 1997-01-09 | 1997-01-09 | Plastic-cement field material and preparing process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1187512A CN1187512A (en) | 1998-07-15 |
| CN1064098C true CN1064098C (en) | 2001-04-04 |
Family
ID=5164890
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97100229A Expired - Fee Related CN1064098C (en) | 1997-01-09 | 1997-01-09 | Plastic-cement field material and preparing process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1064098C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079048C (en) * | 1999-05-11 | 2002-02-13 | 师永昌 | Plastic paving material |
| CN201216849Y (en) * | 2008-03-27 | 2009-04-08 | 柳天扬 | Novel competitive ball game ground table tennis competition court |
| CN105713269A (en) * | 2014-11-05 | 2016-06-29 | 梁意昌 | Three-in-one plastic sports ground, and preparation method thereof |
| CN104532719B (en) * | 2014-11-25 | 2016-07-27 | 福州皇家地坪有限公司 | polyurethane compression resistant floor structure and construction method thereof |
| CN105755929B (en) * | 2016-04-19 | 2018-05-25 | 绿茵天地体育产业股份有限公司 | A kind of functional compounded rubber racetrack and preparation method thereof |
| CN108727654B (en) * | 2017-04-19 | 2020-10-30 | 广州同欣康体设备有限公司 | Three-layer prefabricated rubber track and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2406945A1 (en) * | 1974-02-14 | 1975-08-28 | Willi Kohl | Synthetic surfacing material for play and sports grounds - easily fitted in all weathers without heavy specialised plant |
| JPS5758705A (en) * | 1980-09-22 | 1982-04-08 | Hayakawa Rubber | Construction of soil sports cort |
| JPH01209085A (en) * | 1988-02-18 | 1989-08-22 | Idemitsu Petrochem Co Ltd | Fence for stadium |
| EP0419170A2 (en) * | 1989-09-21 | 1991-03-27 | En-tout-cas PLC | Ground surface material |
-
1997
- 1997-01-09 CN CN97100229A patent/CN1064098C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2406945A1 (en) * | 1974-02-14 | 1975-08-28 | Willi Kohl | Synthetic surfacing material for play and sports grounds - easily fitted in all weathers without heavy specialised plant |
| JPS5758705A (en) * | 1980-09-22 | 1982-04-08 | Hayakawa Rubber | Construction of soil sports cort |
| JPH01209085A (en) * | 1988-02-18 | 1989-08-22 | Idemitsu Petrochem Co Ltd | Fence for stadium |
| EP0419170A2 (en) * | 1989-09-21 | 1991-03-27 | En-tout-cas PLC | Ground surface material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1187512A (en) | 1998-07-15 |
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