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CN1064098C - Plastic-cement field material and preparing process thereof - Google Patents

Plastic-cement field material and preparing process thereof Download PDF

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Publication number
CN1064098C
CN1064098C CN97100229A CN97100229A CN1064098C CN 1064098 C CN1064098 C CN 1064098C CN 97100229 A CN97100229 A CN 97100229A CN 97100229 A CN97100229 A CN 97100229A CN 1064098 C CN1064098 C CN 1064098C
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China
Prior art keywords
parts
glue
dimethylbenzene
plastic
surface layer
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Expired - Fee Related
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CN97100229A
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Chinese (zh)
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CN1187512A (en
Inventor
程兆礼
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Individual
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Individual
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Abstract

一种塑胶场地材料,主要由底层胶、中间胶和面层胶组成,铺设于运动场地,有利于运动员训练和比赛。A plastic field material, mainly composed of bottom layer glue, intermediate glue and surface layer glue, which is laid on the sports field and is beneficial to athletes' training and competition.

Description

Plastic-cement field material and application thereof
The present invention relates to a kind of plastic-cement field material and application thereof.
At present, though existing both at home and abroad plastic-cement field material from material form, or everyway such as preparation process exists deficiency, for example: Elastoplastic cement of mentioning in the CN1052883 patent application and production method thereof, system is by Corvic, dibutyl phthalate (DBP)s etc. stir in container by a certain percentage and soak certain hour, heat while stirring then to treat that solution is raised to and be cast in the metal pattern after the uniform temperature and keep certain hour promptly to produce the Elastoplastic cement of function admirable.And for example: a kind of method for making of natural fibre reinforced plastic is mentioned in the CN1105045 patent application, and the method is to add in the unsaturated polyester (UP) of per 100 parts of weight: the blowing agent (except the CFCs) of the organic molten system of volatility of 30 to 300 parts of weight: the organic peroxide catalyzer contact agent of 0.5 to 3 part of weight; And Wood flour filled dose of scheduled volume; With the above-mentioned unsaturated polyester (UP) of natural fiber impregnation, form through the heating press quenching, its fabrication steps is as follows: step a. drops into the filler of scheduled volume in the liquid blowing agent, and blowing agent is filled till the agent absorption fully; Step b. drops into the filler of the above-mentioned blowing agent of impregnation in the unsaturated polyester (UP) together with catalyzer contact agent and is mixed into batching; Step c is the unsaturated polyester (UP) of natural fiber silk impregnation step b batching, and in a die cavity, with 30 to 150kg/CM 2, 100 to 160 ℃ temperature heating pressurization, heat time heating time, every millimeter thickness was about 30 to 45 seconds, made that the blowing agent of impregnation evaporates fully in the filler, and made polyester foamed hardened forming.These method activities cost height, the material cost height, the place non-skid property is poor; Engineering time is restricted; The place poor flexibility; Easily aging, the life-span is short etc.
The purpose of this invention is to provide a kind of plastic-cement field material and application thereof.
Plastic material of the present invention is mainly used in places such as basketball, vollyball, shuttlecock, tennis, and the track and field runway.Plastic-cement field material with the inventive method preparation can be got rid of the feared state of mind that the sportsman moves on rough earth, and helps the teenager and often take exercise and avoid the motility bone damage, and the damage of health.
The raw material that is used to prepare plastic-cement field material mainly is selected from thermoplastic butadiene-styrene rubber (Beijing Yanshan Petro-Chemical Industry Corporation provides (SBS-1401)).Dimethylbenzene and neoprene (CR-244) etc.
The main raw material(s) of plastic-cement field material of the present invention has:
1. thermoplastic butadiene-styrene rubber (SBS-1401)
Main effect:, play enhancing elasticity, fusible effect as the main constituent of the material of synthetic court; Thermoplastic butadiene-styrene rubber preferred star-shaped sbs-4402, type SBS-1407.
2. neoprene (CR-244)
Main effect:, play the increased viscosity effect as the main constituent of the material of synthetic court;
3. dimethylbenzene
Main effect: dissolving thermoplastic butadiene-styrene rubber and neoprene;
4. granulated rubber, polyurethane material, particle diameter 3-5mm.
Main effect: play when being used for the track and field runway and increase thickness and flexible effect;
5. 2-hydroxyl-4 oxy-octyl benzophenone
(UV531 or ultra-violet absorber)
6. antioxidizing and antigum agent (age resistor, the German business men product trade mark are 264-1010,264 liang of models)
Main effect: avoid the place aging, life-saving;
7. give birth to tung oil, the place of production: all can in domestic various places.
Main effect: increase the ground surface elastic;
8. castor oil, the place of production: all can in domestic various places.
Main effect: increase the ground surface elastic:
9. quartz sand (place of production: Yanqing granularity: 60-80 order, particle diameter 0.015mm)
Main effect: increase the ground friction;
10. tributyl phosphate (process level) is selected for use as required
Promptly under the moisture conditions of ground, can select tributyl phosphate for use for preventing to bubble;
Play a part to prevent to come off, so general drying normally need not during surface construction;
1. color: red (808 red)
Iron oxide red
Phthalocyanine green
The Chinese is husky yellow
Network green (or chrome green)
Phthalocyanine blue
The phthalein white powder
The preparation method of plastic-cement field material of the present invention is as follows:
Usually plastic floor divides indigo plant, row, tennis court and Track field two classes, and technology is slightly different.
Track field adopts batching back one-shot forming, and indigo plant, row, tennis court divide three layers to lay respectively, bottom, and main rising adhered to basal plane, bonding, waterproof action; Elastic reaction is mainly played in 24 hours Hou Pu middle levels, also is elastic layer; Paving layer after 24 hours, rise anti-skidding, the anti-aging effect; Can enable after 48 hours.
The technology of plastic-cement field material is equipped with process:
For indigo plant, row, tennis court:
1, neoprene (CR-244) is used xylene soluble, and the ratio of neoprene and dimethylbenzene is 1-3: 7-11
2, bottom glue
Thermoplastic butadiene-styrene rubber (SBS-1401) 30-60 part, with 90-120 part xylene soluble, add again and dissolved good 10-40 part neoprene, add ultra-violet absorber (2-hydroxyl-4 oxy-octyl benzophenone) 0.1-0.35 part, antioxidizing and antigum agent (trade mark 264) 0.2-0.55 part adds the color that has prepared in right amount and gets final product.
3, middle level glue
Thermoplastic butadiene-styrene rubber 30-60 part adds the neoprene that 5-12 part has been dissolved with 70-90 part xylene soluble, adds 2-hydroxyl-4 oxy-octyl benzophenone 0.15-0.4 part again.
Antioxidizing and antigum agent (trade mark 264) 0.2-0.5 part.
Give birth to tung oil 1-3.6 part.
Castor oil 1-3.6 part.
Quartz sand 2-5 part.
The color that has been mixed with is an amount of.
4, surface layer glue
Thermoplastic butadiene-styrene rubber 25-50 part
Dimethylbenzene 80-120 part
Neoprene 7-15 part (having used xylene soluble)
Quartz sand 4-15 part
Ultra-violet absorber 0.09-0.335 part
Antioxidizing and antigum agent (264) 0.25-0.5 part
It is an amount of to add color.
The Track field batching prepares in above ratio, once add all needed raw materials, and add granulated rubber in addition, it is polyurethane material, particle diameter 3-5mm, main effect: increase thickness and elasticity when being used for the track and field runway, this granulated rubber and above total material ratio are 1-4: 2.5-10, the once-paving moulding, the granularity 3-5mm of granulated rubber.
Plastic-cement field material of the present invention is compared with domestic and international field material at present, and cost is low, cost of material is low, wear-resisting, withstand voltage, ageing-resistant, water-fast, anti-sunlight, good springiness etc.
The every technical indicator of plastic-cement field material of the present invention all meets the regulation of country to standard blue, row, tennis court and track and field runway.And overcome infringement and the mental handicape that causes to athletes ' body with material-paving places such as cement or pitches.
Plastic-cement field material condition experiment of the present invention:
80 ℃ of 70 hours no changes of high temperature resistant test
Cold test-40 ℃>200 hours no changes
The water resistant test water logging did not have any variation in 1 year
50 circulation no changes of atmospheric exposure test (80 ℃ 9 hours-12 ℃ 15 hours be a circulation)
Bonding force>50kg/cm 2
Table 1 plastic cement motion ground (track and field runway) finished product technical standard
Interventions Requested Technical requirements Measured result
Breaking strength MP a ≥0.8 2.4
Elongation at break % ≥100 170
Hardness (Shao Er A) degree 33-75 58
Impact elasticity % 20-50 36
Compressive stress MP a Distortion 10% 0.2-1.0 0.8
Compressive stress MP a Distortion 50% 1.8-5.5 3.3
Can find out this product through the check breaking strength from table 1, elongation rate, hardness all surpasses technical standard, and the optimum effect of tool.
Table 2 plastic cement motion ground (indigo plant, row, tennis) finished product technical standard
Interventions Requested Technical requirements Measured result
Breaking strength MP a ≥0.8 3.5
Elongation at break % ≥100 160
Hardness (Shao Er A) degree 33-75 72
Impact elasticity % 20-50 27
Compressive stress MP a Distortion 10% 0.2-1.0 0.9
Compressive stress MP a Distortion 50% 1.8-5.5 5.1
Compare from table 1, table 2, Track field is had any different with indigo plant, row, each index of tennis court, and Track field elasticity is bigger, and hardness diminishes, and compressive stress is littler.
Track field disposal molding, gross thickness are 15 millimeters.
It moves on track field mainly due to sportsman's drift bolt footwear thereby a material rubber is arranged, and thickness is bigger about 3 times than tennis court thickness.
Indigo plant, row, tennis court are divided three layers: surface layer (skid resistant course), middle level (elastic layer), bottom (adhesive layer), every layer of effect have difference again, thickness 3-4mm.
Following embodiment further specifies of the present invention, and the unrestricted scope of the invention.
Embodiment 1: eight tennis courts of Beijing Sport University's " international invitational tournament of Beijing 96 tennises "
Concrete pedestal, three section bar material mainly refer to ground basal plane situation:
Activities: a tennis court area is: 39.77 m* 22.97 mThe outfield
23.77m positive of * 10.97m
By 4 tons of tennis court materials
Calculate that a year square metre materials 6-9 kilogram batching deal then provides by a square meter materials quantity:
Neoprene is opened 2:8.5 (dissolving ratio) amount (kg/m with xylene soluble 2) bottom: 1.0 kilograms of (m of thermoplastic butadiene-styrene rubber 2) 1.0
With 1.0 kilograms of xylene soluble 1.0
Add 1.0 kilograms of neoprenes 2.0 of having used xylene soluble
Add ultraviolet ray and receive vapor (2-hydroxyl-4 oxy-octyl benzophenone)
0.01 kilogram 0.01
Age resistor (264 trades mark Germany produces) 0.03
Color: phthalocyanine green reaches with yellow, green 0.03 kilogram of 0.05 middle level of network: 1.0 kilogram 1.0 in thermoplastic butadiene-styrene rubber
With 1.2 kilograms of xylene soluble 1.2
Add 0.25 kilogram and dissolved neoprene 0.25
Ultra-violet absorber (2-hydroxyl-4 oxy-octyl benzophenone)
0.03 kilogram 0.03
0.04 kilogram 0.04 in age resistor (264 trades mark Germany produces)
Give birth to tung oil 0.15 kilogram 0.15
0.15 kilogram 0.15 of castor oil
0.17 kilogram 0.17 of quartz sand (particle diameter 80 orders)
Color: phthalocyanine green reaches with yellow, green 0.05 surface layer of network: 0.75 kilogram 0.75 in thermoplastic butadiene-styrene rubber
0.25 kilogram 0.25 of dimethylbenzene
0.2 kilogram 0.2 of neoprene
0.2 kilogram 0.2 of quartz sand (particle diameter 60 orders)
Ultra-violet absorber (2-hydroxyl-4 oxy-octyl benzophenone)
0.03 kilogram 0.03
0.04 kilogram 0.04 in age resistor (264 trades mark Germany produces)
Color: phthalocyanine green, and with yellow, network green 0.05
The common network court needs materials 6-9 kilogram for average one meter, and thickness 3-4mm prepares burden as above the positive place of color
Be green, the outfield is red materials: red, iron oxide red, all use xylene soluble, ratio 0.1: 1 (comparing) with total amount.
After finishing the place, well through match, training reflection.Embodiment 2: the Peking University tennis court
The pitch basis, technology is prepared burden as example 1.Embodiment 3: the 1500m of Tsing-Hua University 2The tennis court;
6000m 2The track and field runway;
Track field thickness 15mm, average every square meter materials 18-27 kilogram, proportion scale such as example 1, one-shot forming, technology is simpler than the tennis court, only prepares material and color in proportion, directly lays to get final product.Embodiment 4: Physical Culture Institute, Shenyang track and field runway 100M, and 8 roads batching is the same; Embodiment 5: Kunming, Yunnan, eight tennis court proportionings of elder brother's steel are with example 1.

Claims (4)

1. plastic-cement field material is characterized in that comprising following bottom glue material, middle level glue material, surface layer glue material:
The bottom glue material is with 90~120 parts of xylene soluble with 30~60 parts of thermoplastic butadiene-styrene rubber, add 10~40 parts of neoprenes that dissolved with dimethylbenzene, 0.1~0.35 part of Octabenzone, 0.2~0.55 part of antioxidant, an amount of pigment again, mixing
The middle level glue material is with 70~90 parts of xylene soluble with 30~60 parts of thermoplastic butadiene-styrene rubber, add 5~12 parts of neoprenes that dissolved with dimethylbenzene, 0.15~0.4 part of Octabenzone, 0.2~0.5 part of antioxidant, 1~3.6 part of living tung oil, 1~3.6 part of castor oil, 2~5 parts of quartz sand, an amount of pigment again, mixing
The surface layer glue material is with 80~120 parts of xylene soluble with 25~50 parts of thermoplastic fourth rubber, add 7~15 parts of neoprenes that dissolved with dimethylbenzene, 4~15 parts of quartz sand, 0.09~0.335 part of Octabenzone, 0.25~0.5 part of antioxidant, an amount of pigment again, mixing;
Above-mentioned umber all is parts by weight, and the weight proportion of the described neoprene that has dissolved with dimethylbenzene: neoprene: dimethylbenzene is 1-3: 7-11.
2. according to the described plastic-cement field material of claim 1, it is characterized in that also comprising that granularity is the polyurethane material of 3~5mm, its amount is 1-4: 2.5-10 for the weight ratio of polyurethane material and bottom glue, middle level glue, surface layer glue material sum.
3. the described plastic-cement field material of claim 1 is applied to basketball, vollyball, tennis court, it is characterized in that laying successively bottom glue, middle level glue, surface layer glue material, re-lays new layer after interlayer was separated by 24 hours, and every layer thickness is 3~4mm.
4. the described plastic-cement field material of claim 2 is applied to Track field, it is characterized in that with once-paving moulding behind bottom glue, middle level glue, surface layer glue material and the polyurethane material mixing, the laying gross thickness is 15mm.
CN97100229A 1997-01-09 1997-01-09 Plastic-cement field material and preparing process thereof Expired - Fee Related CN1064098C (en)

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Application Number Priority Date Filing Date Title
CN97100229A CN1064098C (en) 1997-01-09 1997-01-09 Plastic-cement field material and preparing process thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN97100229A CN1064098C (en) 1997-01-09 1997-01-09 Plastic-cement field material and preparing process thereof

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CN1064098C true CN1064098C (en) 2001-04-04

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Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1079048C (en) * 1999-05-11 2002-02-13 师永昌 Plastic paving material
CN201216849Y (en) * 2008-03-27 2009-04-08 柳天扬 Novel competitive ball game ground table tennis competition court
CN105713269A (en) * 2014-11-05 2016-06-29 梁意昌 Three-in-one plastic sports ground, and preparation method thereof
CN104532719B (en) * 2014-11-25 2016-07-27 福州皇家地坪有限公司 polyurethane compression resistant floor structure and construction method thereof
CN105755929B (en) * 2016-04-19 2018-05-25 绿茵天地体育产业股份有限公司 A kind of functional compounded rubber racetrack and preparation method thereof
CN108727654B (en) * 2017-04-19 2020-10-30 广州同欣康体设备有限公司 Three-layer prefabricated rubber track and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2406945A1 (en) * 1974-02-14 1975-08-28 Willi Kohl Synthetic surfacing material for play and sports grounds - easily fitted in all weathers without heavy specialised plant
JPS5758705A (en) * 1980-09-22 1982-04-08 Hayakawa Rubber Construction of soil sports cort
JPH01209085A (en) * 1988-02-18 1989-08-22 Idemitsu Petrochem Co Ltd Fence for stadium
EP0419170A2 (en) * 1989-09-21 1991-03-27 En-tout-cas PLC Ground surface material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2406945A1 (en) * 1974-02-14 1975-08-28 Willi Kohl Synthetic surfacing material for play and sports grounds - easily fitted in all weathers without heavy specialised plant
JPS5758705A (en) * 1980-09-22 1982-04-08 Hayakawa Rubber Construction of soil sports cort
JPH01209085A (en) * 1988-02-18 1989-08-22 Idemitsu Petrochem Co Ltd Fence for stadium
EP0419170A2 (en) * 1989-09-21 1991-03-27 En-tout-cas PLC Ground surface material

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