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CN106398876A - Detergent for plastics and preparation method thereof - Google Patents

Detergent for plastics and preparation method thereof Download PDF

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Publication number
CN106398876A
CN106398876A CN201610805592.3A CN201610805592A CN106398876A CN 106398876 A CN106398876 A CN 106398876A CN 201610805592 A CN201610805592 A CN 201610805592A CN 106398876 A CN106398876 A CN 106398876A
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Prior art keywords
parts
plastic
detergent
content
preparation
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Inventor
杜红华
王仁俊
汪玲玲
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Wuhu Dexin Automotive Parts Co Ltd
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Wuhu Dexin Automotive Parts Co Ltd
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Priority to CN201610805592.3A priority Critical patent/CN106398876A/en
Publication of CN106398876A publication Critical patent/CN106398876A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3749Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753Polyvinylalcohol; Ethers or esters thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776Heterocyclic compounds, e.g. lactam
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/18Glass; Plastics

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a detergent for plastics and a preparation method thereof. The detergent for plastics comprises the following raw materials by weight: on the basis of 30 parts of sodium alkyl sulfonate, 150 to 200 parts of deionized water, 5 to 15 parts of an antifoaming agent, 10 to 20 parts of an antiseptic, 15 to 35 parts of a thickening agent and 10 to 20 parts of a dispersing agent. The detergent for plastics has highly efficient detergency.

Description

塑料去污剂及其制备方法Plastic stain remover and preparation method thereof

技术领域technical field

本发明涉及去污剂,具体涉及塑料去污剂及其制备方法。The invention relates to a detergent, in particular to a plastic detergent and a preparation method thereof.

背景技术Background technique

去污剂通常是指在一般的洗涤条件下能将污垢洗净的物质。市售的去污剂常含有表面活性剂,表面活性剂与污垢发生亲合作用,通过改变水的表面活性、降低水的表面张力,使污垢脱离出来。根据亲水基团的不同,去污剂可分为:离子型去污剂和非离子型去污剂,其中离子型去污剂又可分为阴离子型去污剂和阳离子型去污剂。Detergents generally refer to substances that can clean dirt under normal washing conditions. Commercially available detergents often contain surfactants, which have an affinity with dirt, change the surface activity of water, reduce the surface tension of water, and make dirt come out. According to the different hydrophilic groups, detergents can be divided into: ionic detergents and nonionic detergents, and ionic detergents can be further divided into anionic detergents and cationic detergents.

当前,塑料制品由于表面粗糙易结合污垢且结合力强,给其表面清洗带来难度。At present, due to the rough surface of plastic products, it is easy to bind dirt and has strong binding force, which makes it difficult to clean the surface.

发明内容Contents of the invention

本发明的目的之一是提供具有高效去污能力的塑料去污剂。One of the objects of the present invention is to provide a plastic stain remover with high detergency.

本发明的另一目的是提供条件温和、操作简单的塑料去污剂的制备方法。Another object of the present invention is to provide a method for preparing a plastic detergent with mild conditions and simple operation.

本发明提供的塑料去污剂由以下重量份的原料组成,相对于30份的烷基磺酸钠,去离子水的含量为150-200份,消泡剂的含量为5-15份,防腐剂的含量为10-20份,增稠剂的含量为15-35份,分散剂的含量为10-20份。The plastic detergent provided by the present invention is composed of the following raw materials in parts by weight, with respect to 30 parts of sodium alkylsulfonate, the content of deionized water is 150-200 parts, the content of defoamer is 5-15 parts, anti-corrosion The content of the agent is 10-20 parts, the content of the thickener is 15-35 parts, and the content of the dispersant is 10-20 parts.

在上述塑料去污剂中,消泡剂的具体种类可以在宽的范围内选择,但是为提高该塑料去污剂的去污能力,优选地,消泡剂选自乳化硅油、高碳醇脂肪酸酯复合物和聚二甲基硅氧烷中的一种或多种。In the above-mentioned plastic detergent, the specific type of defoamer can be selected in a wide range, but in order to improve the decontamination ability of this plastic detergent, preferably, the defoamer is selected from emulsified silicone oil, high-carbon alcohol fat One or more of acid ester complex and polydimethylsiloxane.

在上述塑料去污剂中,防腐剂的具体种类可以在宽的范围内选择,但是为提高该塑料去污剂的保质期,优选地,防腐剂选自乙酯、丙酯、丁酯和双乙酸钠中的一种或多种。In the above-mentioned plastic detergent, the specific type of preservative can be selected in a wide range, but in order to improve the shelf life of the plastic detergent, preferably, the preservative is selected from ethyl ester, propyl ester, butyl ester and diacetic acid One or more of sodium.

在上述塑料去污剂中,增稠剂的具体种类可以在宽的范围内选择,从成本上考虑,优选地,增稠剂选自聚丙烯酰胺、聚乙烯醇和聚乙烯吡咯烷酮中的一种或多种。In the above-mentioned plastic detergent, the specific type of thickener can be selected in a wide range. From the perspective of cost, preferably, the thickener is selected from one or more of polyacrylamide, polyvinyl alcohol and polyvinylpyrrolidone. Various.

在上述塑料去污剂中,分散剂的具体种类可以在宽的范围内选择,同样从成本上考虑,优选地,分散剂选自石蜡油、聚乙烯蜡和氧化聚乙烯蜡中的一种或多种。In the above-mentioned plastic detergent, the specific type of dispersant can be selected in a wide range, also considering the cost, preferably, the dispersant is selected from one or more of paraffin oil, polyethylene wax and oxidized polyethylene wax. Various.

本发明提供的上述塑料去污剂的制备方法,该方法包括:将所述烷基磺酸钠、消泡剂、防腐剂、增稠剂、分散剂和去离子水混合制得所述塑料去污剂。其中,以重量份计,相对于30份的烷基磺酸钠,去离子水的含量为150-200份,消泡剂的含量为5-15份,防腐剂的含量为10-20份,增稠剂的含量为15-35份,分散剂的含量为10-20份。The preparation method of the above-mentioned plastic detergent provided by the present invention comprises: mixing the sodium alkylsulfonate, defoamer, preservative, thickener, dispersant and deionized water to prepare the plastic detergent Stain agent. Wherein, in parts by weight, relative to 30 parts of sodium alkylsulfonate, the content of deionized water is 150-200 parts, the content of defoaming agent is 5-15 parts, and the content of antiseptic is 10-20 parts, The content of the thickener is 15-35 parts, and the content of the dispersant is 10-20 parts.

在上述制备方法中,混合的方式可以在宽的范围内选择,但是为了进一步提高该塑料去污剂的制备效率,优选地,混合的方式为超声混合,超声混合的功率为60-80w,超声混合的时间为20-60min。In the above preparation method, the way of mixing can be selected in a wide range, but in order to further improve the preparation efficiency of the plastic detergent, preferably, the way of mixing is ultrasonic mixing, and the power of ultrasonic mixing is 60-80w. The mixing time is 20-60min.

通过上述技术方案,本发明通过将各重量份的原料混合,物料之间紧密接触,相互间产生协同作用,从而制得塑料去污剂。该方法为一种成本低廉、条件温和、绿色环保和操作简单的方法,制得的塑料去污剂具有高效去污能力。Through the above technical scheme, the present invention mixes the raw materials in different parts by weight, and the materials are in close contact with each other to produce a synergistic effect, thereby preparing the plastic detergent. The method is a method with low cost, mild conditions, environmental protection and simple operation, and the prepared plastic decontamination agent has high decontamination ability.

本发明的其他特征和优点将在随后的具体实施方式部分予以详细说明。Other features and advantages of the present invention will be described in detail in the following detailed description.

具体实施方式detailed description

以下对本发明的具体实施方式进行详细说明。应当理解的是,此处所描述的具体实施方式仅用于说明和解释本发明,并不用于限制本发明。Specific embodiments of the present invention will be described in detail below. It should be understood that the specific embodiments described here are only used to illustrate and explain the present invention, and are not intended to limit the present invention.

实施例1Example 1

以重量份计,将30份烷基磺酸钠、6份乳化硅油、11份乙酯、16份聚丙烯酰胺、12份石蜡油和155份去离子水以62w的功率超声混合25min制得塑料去污剂A1。In parts by weight, 30 parts of sodium alkyl sulfonate, 6 parts of emulsified silicone oil, 11 parts of ethyl ester, 16 parts of polyacrylamide, 12 parts of paraffin oil and 155 parts of deionized water were ultrasonically mixed at 62w for 25 minutes to obtain a plastic Detergent A1.

实施例2Example 2

以重量份计,将30份烷基磺酸钠、13份高碳醇脂肪酸酯复合物、18份丙酯、32份聚乙烯醇、18份聚乙烯蜡和195份去离子水以75w的功率超声混合55min制得塑料去污剂A2。In parts by weight, 30 parts of sodium alkylsulfonate, 13 parts of high-carbon alcohol fatty acid ester complex, 18 parts of propyl ester, 32 parts of polyvinyl alcohol, 18 parts of polyethylene wax and 195 parts of deionized water are used in a 75w Power ultrasonic mixing for 55 minutes to prepare plastic detergent A2.

实施例3Example 3

以重量份计,将30份烷基磺酸钠、10份聚二甲基硅氧烷、15份双乙酸钠、25份聚乙烯吡咯烷酮、15份氧化聚乙烯蜡和175份去离子水以75w的功率超声混合40min制得塑料去污剂A3。In parts by weight, 30 parts of sodium alkyl sulfonate, 10 parts of polydimethylsiloxane, 15 parts of sodium diacetate, 25 parts of polyvinylpyrrolidone, 15 parts of oxidized polyethylene wax and 175 parts of deionized water were mixed in 75w The power of ultrasonic mixing for 40min to prepare the plastic detergent A3.

对比例1Comparative example 1

相对于实施例1制得去污剂B1,所不同的是,加入乳化硅油的用量为0.5重量份。Compared with the detergent B1 prepared in Example 1, the difference is that the amount of emulsified silicone oil added is 0.5 parts by weight.

对比例2Comparative example 2

相对于实施例1制得去污剂B2,所不同的是,加入石蜡油的用量为5重量份,聚丙烯酰胺的用量为0.5重量份。Compared with the detergent B2 prepared in Example 1, the difference is that the amount of paraffin oil added is 5 parts by weight, and the amount of polyacrylamide is 0.5 parts by weight.

将上述实施例和对比例制得的去污剂A1-B2用来清洗有污渍的塑料,观察洗涤效果,结果显示上述实施例所制备的去污剂能够快速去污。从上述结果得知,本发明提供的塑料去污剂具有高效去污能力。此外,从本发明所提供的制备方法可以看出,本发明提供的塑料去污剂的制备方法条件温和、绿色环保,制备简单。The detergents A1-B2 prepared in the above examples and comparative examples were used to clean stained plastics, and the washing effect was observed. The results showed that the detergents prepared in the above examples could quickly decontaminate. Known from above-mentioned result, the plastic decontamination agent provided by the present invention has efficient decontamination ability. In addition, it can be seen from the preparation method provided by the present invention that the preparation method of the plastic detergent provided by the present invention has mild conditions, environmental protection and simple preparation.

以上详细描述了本发明的优选实施方式,但是,本发明并不限于上述实施方式中的具体细节,在本发明的技术构思范围内,可以对本发明的技术方案进行多种简单变型,这些简单变型均属于本发明的保护范围。The preferred embodiments of the present invention have been described in detail above, but the present invention is not limited to the specific details in the above embodiments. Within the scope of the technical concept of the present invention, various simple modifications can be made to the technical solutions of the present invention. These simple modifications All belong to the protection scope of the present invention.

另外需要说明的是,在上述具体实施方式中所描述的各个具体技术特征,在不矛盾的情况下,可以通过任何合适的方式进行组合,为了避免不必要的重复,本发明对各种可能的组合方式不再另行说明。In addition, it should be noted that the various specific technical features described in the above specific embodiments can be combined in any suitable way if there is no contradiction. The combination method will not be described separately.

此外,本发明的各种不同的实施方式之间也可以进行任意组合,只要其不违背本发明的思想,通过将各重量份的原料在容器中进行混合,接触,相互间产生协同作用,从而得到塑料去污剂,其同样应当视为本发明所公开的内容。In addition, various combinations of different embodiments of the present invention can also be combined arbitrarily, as long as they do not violate the idea of the present invention, by mixing and contacting the raw materials of each weight part in the container, a synergistic effect is produced between them, thereby A plastic stain remover is obtained, which should also be considered as disclosed in the present invention.

Claims (7)

1.一种塑料去污剂,其特征在于,所述塑料去污剂由以下重量份的原料组成,相对于30份的烷基磺酸钠,去离子水的含量为150-200份,消泡剂的含量为5-15份,防腐剂的含量为10-20份,增稠剂的含量为15-35份,分散剂的含量为10-20份。1. a plastic detergent, is characterized in that, described plastic detergent is made up of the raw material of following weight part, with respect to the sodium alkylsulfonate of 30 parts, the content of deionized water is 150-200 part, eliminates The content of the foaming agent is 5-15 parts, the content of the preservative is 10-20 parts, the content of the thickener is 15-35 parts, and the content of the dispersant is 10-20 parts. 2.根据权利要求1所述的塑料去污剂,其中,所述消泡剂选自乳化硅油、高碳醇脂肪酸酯复合物和聚二甲基硅氧烷中的一种或多种。2. The plastic detergent according to claim 1, wherein the defoamer is selected from one or more of emulsified silicone oil, higher alcohol fatty acid ester complex and polydimethylsiloxane. 3.根据权利要求1或2所述的塑料去污剂,其中,所述防腐剂选自乙酯、丙酯、丁酯和双乙酸钠中的一种或多种。3. The plastic stain remover according to claim 1 or 2, wherein the preservative is selected from one or more of ethyl ester, propyl ester, butyl ester and sodium diacetate. 4.根据权利要求3所述的塑料去污剂,其中,所述增稠剂选自聚丙烯酰胺、聚乙烯醇和聚乙烯吡咯烷酮中的一种或多种。4. The plastic stain remover according to claim 3, wherein the thickener is selected from one or more of polyacrylamide, polyvinyl alcohol and polyvinylpyrrolidone. 5.根据权利要求1或4所述的塑料去污剂,其中,所述分散剂选自石蜡油、聚乙烯蜡和氧化聚乙烯蜡中的一种或多种。5. The plastic stain remover according to claim 1 or 4, wherein the dispersant is selected from one or more of paraffin oil, polyethylene wax and oxidized polyethylene wax. 6.一种如权利要求1-5中任意一项所述的塑料去污剂的制备方法,其特征在于:所述制备方法为将所述烷基磺酸钠、消泡剂、防腐剂、增稠剂、分散剂和去离子水混合制得所述塑料去污剂。6. a kind of preparation method of plastic stain remover as described in any one in claim 1-5, it is characterized in that: described preparation method is with described sodium alkylsulfonate, defoamer, preservative, Thickener, dispersant and deionized water are mixed to prepare the plastic detergent. 7.根据权利要求6所述的塑料去污剂的制备方法,其中,所述混合的方式为超声混合,所述超声混合的功率为60-80w,超声混合的时间为20-60min。7. The preparation method of plastic detergent according to claim 6, wherein the mixing method is ultrasonic mixing, the power of the ultrasonic mixing is 60-80w, and the time of ultrasonic mixing is 20-60min.
CN201610805592.3A 2016-09-07 2016-09-07 Detergent for plastics and preparation method thereof Pending CN106398876A (en)

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Application publication date: 20170215