CN1063674A - Granular compound fertilizer and technology thereof that the part acidic phosphorus mine single stage method is made - Google Patents
Granular compound fertilizer and technology thereof that the part acidic phosphorus mine single stage method is made Download PDFInfo
- Publication number
- CN1063674A CN1063674A CN 91112622 CN91112622A CN1063674A CN 1063674 A CN1063674 A CN 1063674A CN 91112622 CN91112622 CN 91112622 CN 91112622 A CN91112622 A CN 91112622A CN 1063674 A CN1063674 A CN 1063674A
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- single stage
- stage method
- repone
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 29
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000011574 phosphorus Substances 0.000 title claims abstract description 26
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 26
- 150000001875 compounds Chemical class 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 13
- 230000002378 acidificating effect Effects 0.000 title claims abstract description 11
- 238000005516 engineering process Methods 0.000 title abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002367 phosphate rock Substances 0.000 claims abstract description 22
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 17
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 12
- 210000003608 fece Anatomy 0.000 claims abstract description 12
- 239000010871 livestock manure Substances 0.000 claims abstract description 12
- 239000004202 carbamide Substances 0.000 claims abstract description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 208000006558 Dental Calculus Diseases 0.000 claims abstract description 7
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims abstract description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 239000011573 trace mineral Substances 0.000 claims description 2
- 235000013619 trace mineral Nutrition 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 5
- 239000000618 nitrogen fertilizer Substances 0.000 abstract description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 3
- 239000002686 phosphate fertilizer Substances 0.000 abstract description 3
- 229940072033 potash Drugs 0.000 abstract description 3
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 3
- 235000015320 potassium carbonate Nutrition 0.000 abstract description 3
- 239000002253 acid Substances 0.000 description 10
- 239000002689 soil Substances 0.000 description 7
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 6
- 229910000389 calcium phosphate Inorganic materials 0.000 description 6
- 235000019691 monocalcium phosphate Nutrition 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 235000015097 nutrients Nutrition 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 1
- QLULGSLAHXLKSR-UHFFFAOYSA-N azane;phosphane Chemical compound N.P QLULGSLAHXLKSR-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The granular compound fertilizer of part acidic phosphorus mine single stage method manufacturing be a kind of be raw material with nitrogenous fertilizer (urea, ammonium nitrate etc.), potash fertilizer (Repone K or vitriolate of tartar), ground phosphate rock and sulfuric acid (or phosphoric acid or mixture of sulfuric phosphoric acid), the compound manure that makes of step in the reaction tablets press.
Part acidic phosphorus mine single stage method system composite fertilizer is directly to be the phosphorus source with ground phosphate rock, combine together with the manufacturing of phosphate fertilizer and with the compound of nitrogenous fertilizer, potash fertilizer, save the production process of phosphate fertilizer, had less investment, characteristics such as raw material is cheap and easy to get, technology is simple, cost is low, fertilizer efficiency height.
Description
The invention belongs to the chemical industry class, is a kind of manufacture method of new particulate compound manure.
Part acidic phosphorus mine (claiming partially acidulated rock phosphate again) is to handle phosphorus ore with producing calcium superphosphate with the part of acid amount, makes in the phosphorus ore a part of phosphorus be converted into water-soluble a, part and is converted into solubility in citric acid, some unconverted phosphorus slowly conversion in soil still.By regulating sour consumption (acescency), can change the ratio of above-mentioned three kinds of form phosphorus.
Partially acidulated rock phosphate is particularly used wider on the torrid zone, subtropical zone acid soil abroad.The research and extension of partially acidulated rock phosphate just is being devoted at international fertilizer center (IFDC).And plan to promote this fertilizer on South East Asia and other places.The cross-country positive legendary ruler of great antiquity, the first of the Three August Ones of Japan has delivered " the up-to-date problem of fertilizer research " literary composition on " fertilizer " magazine in 1991, discussed seven directions of current fertilizer research, and wherein partially acidulated rock phosphate ranks second.
After calcium superphosphate is manured into soil, form acid stronger solution, when it spreads towards periphery, can dissolve iron in the soil, aluminium etc. and form insoluble phosphate, make degenerate useful phosphorus; And the acidic solution that partially acidulated rock phosphate forms in soil with unreacted breeze effect, is translated into available phosphorus when spreading towards periphery.The fertilizer efficiency and the calcium superphosphate of partially acidulated rock phosphate are suitable in the high soil of phosphate fixation ability, even are better than calcium superphosphate.A large amount of both at home and abroad experimental studies show, in acid, slightly acidic and calcareous soil, the fertilizer efficiency of partially acidulated rock phosphate such as is at the 80-110% of weight calcium superphosphate.
The deficiency of partially acidulated rock phosphate is that nutrient is low, nutrient is single, and fertilising inconvenience.In view of the above, we have developed the novel process of part acidic phosphorus mine single stage method preparing granular compound manure.Carried out international online retrieval at the Ministry of Chemical Industry's Office for Scientific and Technical Information in October, 1991, the relevant report of Shang Weijian.English Patent (UK1106104) has only been introduced a kind of technology of acidic phosphorus mine compound fertilizer making.This method is handled phosphorus ore with excess acid, P in acid and the phosphorus ore
2O
5Mol ratio 〉=4.7: 1, temperature of reaction 〉=70 ℃ are in order to avoid phosphorus ore is by CaSO
4Parcel, reacted slip makes product with ammonia neutralization, granulation, slaking.Unnecessary acid and ammonia react are converted into phosphorus ammonium or sulphur ammonium.It is not the joint acid type, the compound manure that neither single stage method makes.
The purpose of part acidic phosphorus mine single stage method compound fertilizer making is to make a kind of inexpensive polyelement composite fertilizer.Compare with common mixed fertilizers, its technology is simple, directly is the phosphorus source with ground phosphate rock; A step is made compound manure, balling ratio height in the reaction tablets press; Product utilization reaction heat self drying, cost is low.And the ordinary compound fertilizer height of nutrients such as the fertilizer efficiency of this fertilizer ratio.
The technology of part acidic phosphorus mine single stage method compound fertilizer making is as follows:
Raw material: nitrogenous source-urea (or ammonium nitrate, ammonium chloride etc.) is granular; Potassium source-Repone K or vitriolate of tartar ,-80 orders; Phosphorus source-ground phosphate rock, phosphorus pentoxide content 20-40% ,-90 orders; Souring agent-sulfuric acid (phosphoric acid or mixture of sulfuric phosphoric acid), concentration 20-98%.
Add urea (or ammonium nitrate, ammonium chloride in the tablets press in reaction; down together); evenly spray into small amount of acid; rotated about one minute; make urea surface fully moistening, add uniform ground phosphate rock of mixed with little amount and Repone K (or vitriolate of tartar), make it be coated on granular nitrogenous fertilizer surface; alternately spray mixture sour, that be sprinkled into breeze and Repone K (or vitriolate of tartar) again, until the multiple fertile granularity that reaches regulation.In the successive reaction tablets press, also can realize continuous production.Also can add various trace elements, make the compound manure that contains little fertilizer.Repone K in the raw material (or vitriolate of tartar, or other villaumite, or tensio-active agent) is the potassium source, is again the reactive behavior agent, can prevent that ground phosphate rock from being reacted the crystal of calcium sulfate parcel of generation and hinder reaction and carry out.Emit a large amount of heat during the ground phosphate rock acidifying, make temperature of reaction greater than 70 ℃.Product in tablets press and process of cooling, evaporation section moisture, thus realize self drying of product.Product is stored up slaking and can be packed after several days and dispatch from the factory in the warehouse.
Change the add-on of proportion scale and sulfuric acid or phosphoric acid, can be made into the special-purpose fertilizer of various crops.
Embodiment one: it is heavy to take by weighing KCl82 part, 500 parts of breezes (containing Vanadium Pentoxide in FLAKES 27%), 305 parts in urea, 105 parts in 93% sulfuric acid.Earlier urea is added in the reaction tablets press, evenly spray into a small amount of sulfuric acid, rotated about 1 minute, add mixed breeze and Repone K.Alternately spray is sour again, adds the ground phosphate rock and the Repone K of mixing, all adds until ground phosphate rock, Repone K and sulfuric acid.Take out product.Seasoning, and in the warehouse, store up slaking and adorn after several days and contract out factory, the fertilizer specially for wheat of 14-7-4.2 promptly got.
Embodiment two: get 218 parts of weights of urea, 196 parts in Repone K, 480 parts in ground phosphate rock, 100 parts of mixture of sulfuric phosphoric acid (wherein sulfuric acid is pure 40 parts, pure 50 parts of phosphoric acid).Earlier urea is added in the reaction tablets press, evenly spray into a small amount of mixture of sulfuric phosphoric acid, rotated about 1 minute, add mixed breeze and Repone K.Alternately spray acid again, add breeze and Repone K behind the mixing, after treating that breeze and Repone K add about 1/5, breeze, Repone K and the mixture of sulfuric phosphoric acid (spraying into) that can add mixing continuously, until all add (after, can add urea, ground phosphate rock, Repone K and mixture of sulfuric phosphoric acid continuously by proportioning, realize continuous production).Take out product, seasoning, and in the warehouse, store up slaking after several days, packing is dispatched from the factory, and can make the 10-10-10 fruit-specific fertilizer.
Also available common garden dish tablets press surrogate response tablets press is made this compound manure.
The present invention directly is the phosphorus source with ground phosphate rock, combines together with the production of phosphate fertilizer and with the compound of nitrogenous fertilizer, potash fertilizer.Raw material does not need pre-treatment, product utilization reaction heat self drying; The balling ratio height, no returning charge.Thereby energy consumption and cost are low, than the common compound fertilizer 10-20 unit/ton that reduces cost.The effective Vanadium Pentoxide in FLAKES of per kilogram is saved 0.3-0.5 kilogram sulfuric acid.The fertilizer efficiency of equivalent available phosphorus is more than 110% of calcium superphosphate or double superhosphate.And aftereffect is good.
Claims (4)
1, a kind of compound manure made from the part acidic phosphorus mine single stage method, it is characterized in that directly with ground phosphate rock as the phosphorus source of compound manure, be souring agent, be nitrogenous source, be the potassium source with Repone K (or vitriolate of tartar) with urea (or ammonium nitrate or ammonium chloride) with sulfuric acid (or phosphoric acid or mixture of sulfuric phosphoric acid), and add needed trace element, one goes on foot the polyelement composite fertilizer that makes.
2, by the compound manure of claim 1, it is characterized in that said ground phosphate rock, its P
2O
5Content is 20-40%.
3, by the compound manure of claim 1, it is characterized in that said Repone K (or vitriolate of tartar), be not only the potassium source, but also be a kind of reactive activity agent.
4,, it is characterized in that said product is to utilize the heat that produces in the reaction process to realize self drying by the compound manure of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91112622 CN1032914C (en) | 1991-12-30 | 1991-12-30 | Granular compound fertilizer and tech. made by part acidic phosphorus mine one step method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91112622 CN1032914C (en) | 1991-12-30 | 1991-12-30 | Granular compound fertilizer and tech. made by part acidic phosphorus mine one step method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1063674A true CN1063674A (en) | 1992-08-19 |
| CN1032914C CN1032914C (en) | 1996-10-02 |
Family
ID=4910969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91112622 Expired - Fee Related CN1032914C (en) | 1991-12-30 | 1991-12-30 | Granular compound fertilizer and tech. made by part acidic phosphorus mine one step method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1032914C (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001042172A1 (en) * | 1999-12-09 | 2001-06-14 | Rotem Amfert Negev Ltd. | Process for the preparation of urea superphosphate fertilizers |
| CN1094918C (en) * | 1998-07-02 | 2002-11-27 | 化学工业部上海化工研究院 | Method for prodn. of high efficiency composite fertilizer contg. nitrogen, phosphorous and potassium |
| KR100382832B1 (en) * | 2000-09-14 | 2003-05-09 | (주)에코바이오 | Rock powder-based fertilizer composition and preparation thereof |
| CN102557802A (en) * | 2012-02-20 | 2012-07-11 | 中国农业大学 | Special fertilizer for rice and preparation method for fertilizer |
| CN102731214A (en) * | 2012-07-12 | 2012-10-17 | 个旧市绿保复合肥有限责任公司 | Production process of sugarcane slow release fertilizer |
| CN101508607B (en) * | 2009-03-20 | 2012-11-21 | 辽宁华锦化工（集团）有限责任公司 | Process for producing long-acting sustained-release complex fertilizer of urea sulfuric acid |
| CN106748017A (en) * | 2016-12-02 | 2017-05-31 | 锦西天然气化工有限责任公司 | A kind of production method of urea general calcium composite fertilizer |
-
1991
- 1991-12-30 CN CN 91112622 patent/CN1032914C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094918C (en) * | 1998-07-02 | 2002-11-27 | 化学工业部上海化工研究院 | Method for prodn. of high efficiency composite fertilizer contg. nitrogen, phosphorous and potassium |
| WO2001042172A1 (en) * | 1999-12-09 | 2001-06-14 | Rotem Amfert Negev Ltd. | Process for the preparation of urea superphosphate fertilizers |
| KR100382832B1 (en) * | 2000-09-14 | 2003-05-09 | (주)에코바이오 | Rock powder-based fertilizer composition and preparation thereof |
| CN101508607B (en) * | 2009-03-20 | 2012-11-21 | 辽宁华锦化工（集团）有限责任公司 | Process for producing long-acting sustained-release complex fertilizer of urea sulfuric acid |
| CN102557802A (en) * | 2012-02-20 | 2012-07-11 | 中国农业大学 | Special fertilizer for rice and preparation method for fertilizer |
| CN102731214A (en) * | 2012-07-12 | 2012-10-17 | 个旧市绿保复合肥有限责任公司 | Production process of sugarcane slow release fertilizer |
| CN102731214B (en) * | 2012-07-12 | 2014-05-07 | 个旧市绿保复合肥有限责任公司 | Production process of sugarcane slow release fertilizer |
| CN106748017A (en) * | 2016-12-02 | 2017-05-31 | 锦西天然气化工有限责任公司 | A kind of production method of urea general calcium composite fertilizer |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1032914C (en) | 1996-10-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C15 | Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993) | ||
| OR01 | Other related matters | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |