CN106280700A - Gravure water-based metal ink and production method thereof - Google Patents
Gravure water-based metal ink and production method thereof Download PDFInfo
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- CN106280700A CN106280700A CN201610636014.1A CN201610636014A CN106280700A CN 106280700 A CN106280700 A CN 106280700A CN 201610636014 A CN201610636014 A CN 201610636014A CN 106280700 A CN106280700 A CN 106280700A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 64
- 239000002184 metal Substances 0.000 title claims abstract description 64
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000006185 dispersion Substances 0.000 claims abstract description 17
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 11
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims abstract description 11
- 239000013556 antirust agent Substances 0.000 claims abstract description 9
- 239000007822 coupling agent Substances 0.000 claims abstract description 9
- 239000003381 stabilizer Substances 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 8
- 238000009736 wetting Methods 0.000 claims abstract description 8
- 239000000084 colloidal system Substances 0.000 claims abstract description 7
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims abstract description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 229910017518 Cu Zn Inorganic materials 0.000 claims description 4
- 229910017752 Cu-Zn Inorganic materials 0.000 claims description 4
- 229910017943 Cu—Zn Inorganic materials 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical group [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- QRJOYPHTNNOAOJ-UHFFFAOYSA-N copper gold Chemical compound [Cu].[Au] QRJOYPHTNNOAOJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 239000002904 solvent Substances 0.000 abstract description 13
- 238000007639 printing Methods 0.000 abstract description 9
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 238000001035 drying Methods 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 1
- -1 standby Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Developing Agents For Electrophotography (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Gravure water-based metal ink and production method thereof, gravure water-based metal ink forms with two kinds of systems of resin dispersion system and metal toner predispersion system, and resin dispersion system includes the water-borne acrylic resin of 19 ~ 21 parts, the isopropanol of 2 ~ 3 parts, the water soluble acrylic acid of 6 ~ 7 parts, the water of 6 ~ 7 parts, the PH stabilizer of 0.5 ~ 1 part, the wetting dispersing agent of 3 ~ 4 parts；Metal toner predispersion system includes the metal toner of 35 ~ 37 parts, the ethanol of 17 ~ 19 parts, the water soluble colloid of the water-borne acrylic resin of 5 ~ 6 parts, the coupling agent of 0.05 ~ 0.07 part, the modified polycarboxylic acid potassium salt of 0.1 ~ 0.3 part, the antirust agent of 0.1 ~ 0.3 part, the passivator of 0.3 ~ 0.5 part；Having the beneficial effects that, gravure water-based metal ink does not contains volatility toxic solvent, compares environmental protection, low cost；Adhesive force and double exposure better performances, can realize clear, complete printing on gloss oil；Rate of drying is easy to control, is not susceptible to stifled version problem；Stable performance, does not haves blackout, a problem that glossiness is low；There is higher wearability and chemical-resistant；Printing does not haves the paste back of the body, flies ink, bracing wire, apprehensive problem.
Description
Technical field
The invention belongs to printing-ink technical field, relate to a kind of gravure water-based metal ink and production method thereof.
Background technology
Intaglio printing is called for short gravure, is to be imprinted directly on stock by ink contained in intaglio plate pit.It is presently used for
The ink type of intaglio printing is roughly divided into solvent type ink and water color ink two kinds.In existing technology, intaglio printing institute
Ink mostly use solvent type ink, it has formula comparative maturity, and adhesive force is excellent, levelability, gloss, light sense non-
The best advantage.But, containing the substantial amounts of organic solvent such as alcohols, ethers, benzene class, ketone in solvent type ink, manufacturing and
During using this kind of ink, the discharge of a large amount of volatile organic gas, pollute the environment；Meanwhile, solvent type ink is in printing
During easily there is sticking with paste the back of the body, rub the back of the body, the phenomenon such as apprehensive.Water color ink is mainly by water-soluble resin, organic pigment, solvent and phase
Closing auxiliary agent to form through abrasive machining, it is with the maximum difference of solvent type ink, and the solvent that water color ink uses is water
Or alcohols, it will be apparent that decrease the discharge of volatile organic gas, free from environmental pollution.
But, no matter the water color ink of present stage is import or domestic all there is poor adhesive force, at many plastic cement
It is difficult to moistening well and printing on material, rubber mass and all kinds of leather material that changes colour；Water color ink granule is relatively thick, and drying time is difficult to
Control, cross net poor performance, it is easy to stifled version, seriously limit large batch of production；In water color ink preparation process, acid-base value is not
Stable, be difficult to regulation, be easily caused that water color ink quality is low, the problem of product rejection；Resin in water color ink preparation process, molten
Agent, metal toner are susceptible to reaction, the problem that can cause water color ink unstable properties.
Summary of the invention
The present invention is directed in prior art, there is poor adhesive force in water color ink, and drying time is wayward, acid-base value and property
The problem that shape is unstable, it is provided that a kind of gravure water-based metal ink and production method, its technical scheme is:
A kind of gravure water-based metal ink, this gravure water-based metal ink is by resin dispersion system and two kinds of metal toner predispersion system
System coordinates composition, and resin dispersion system includes the water-borne acrylic resin of 19 ~ 21 parts, the isopropanol of 2 ~ 3 parts, the water of 6 ~ 7 parts
Property acrylic acid, the water of 6 ~ 7 parts, the PH stabilizer of 0.5 ~ 1 part, the wetting dispersing agent of 3 ~ 4 parts；Metal toner predispersion system includes
The metal toner of 35 ~ 37 parts, the ethanol of 17 ~ 19 parts, the water soluble colloid of the water-borne acrylic resin of 5 ~ 6 parts, 0.05 ~ 0.07 part
Coupling agent, the modified polycarboxylic acid potassium salt of 0.1 ~ 0.3 part, the antirust agent of 0.1 ~ 0.3 part, the passivator of 0.3 ~ 0.5 part；
The production method of gravure water-based metal ink includes following procedure of processing:
The preparation of (a) resin dispersion system
The water-borne acrylic resin of 19 ~ 21 parts, the isopropanol of 2 ~ 3 parts, the aqueous acrylamide of 6 ~ 7 parts it is sequentially added in reactor I
Acid, the water of 6 ~ 7 parts, the PH stabilizer of 0.5 ~ 1 part, the wetting dispersing agent of 3 ~ 4 parts, be placed on reactor I on centrifuge, 60
DEG C, under conditions of rotating speed is 450 turns per minute, disperses 20min, the mixed liquor in reactor I transferred to, in container I, carry out
Sealing and standing 7d, in mixed liquor, bubble-free produces, and viscosity reaches 45S ~ 52S, and pH value reaches 7.5 ~ 8.0, makes resin dispersion
System, standby；
The preparation of (b) metal toner predispersion system
In reactor II, add the metal toner of 35 ~ 37 parts and the ethanol of 17 ~ 19 parts, reactor II be placed on centrifuge,
25 DEG C, under conditions of rotating speed is 100 turns per minute, disperse 5min, then toward reactor II is sequentially added into the aqueous third of 5 ~ 6 parts
The water soluble colloid of olefin(e) acid resin, the coupling agent of 0.05 ~ 0.07 part, the modified polycarboxylic acid potassium salt of 0.1 ~ 0.3 part, 0.1 ~ 0.3 part
Antirust agent, the passivator of 0.3 ~ 0.5 part, after mix homogeneously, transfer to the mixed liquor in reactor II in container II, stands
2h, without Precipitation, prepares metal toner predispersion system, standby；
The preparation of (c) gravure water-based metal ink
Resin dispersion system in container I is poured in reactor III, then by the metal toner predispersion system in container II with
And the anti-settling agent of 0.07 ~ 0.09 part adds in reactor III together, after addition, reactor III is placed on centrifuge,
25 DEG C, under conditions of rotating speed is 400 turns per minute, disperse 20min, viscosity of mixed liquid reaches 100S ~ 140S, pH value reaches 8 ~
8.5, make gravure water-based metal ink；
Metal toner is Cu-Zn alloy powder, or aluminum argentum powder, or copper gold bar, or aluminum Rhizoma Humatae Tyermanni, or aluminum paste, metal toner big
Little between 1000 ~ 1500 mesh；
PH stabilizer be carbon number be less than or equal to 6 primary amine or carbon number less than or equal to 6 secondary amine in one or two
Kind；
Wetting dispersing agent is made up of water, isopropanol, the mixed solution of propylene glycol；
Coupling agent is the one in silane coupling agent or titante coupling agent；
Antirust agent is zinc salt antirust agent；
Passivator be the one or two kinds of in the coordination compound of chromate, petroleum sulfonate, organic nitrogen(ous) base or acid phosphoric acid and
Above；
Anti-settling agent is the aqueous solution of acrylates.
The beneficial effects of the present invention is:
1, gravure water-based metal ink is using water and ethanol as solvent, without volatility toxic solvent, and not volatilization in production process
Property organic gas discharge, compare environmental protection, meanwhile, gravure water-based metal ink is using water and ethanol as solvent, and compare solvent-borne type
Ink is using n-propyl, ethyl ester as solvent, and price is low, greatly reduces production cost.
2, gravure water-based metal ink adhesive force is relatively good, can be very well on plastic rubber material, rubber mass and many change colour leather material
Ground moistening and printing, meanwhile, the double exposure better performances of this gravure water-based metal ink, gloss oil can also realize clear, complete
Print.
3, gravure water-based metal ink granule is less, and rate of drying is easily controlled, and crosses net better performances, is not susceptible to stifled version print
Brush is asked.
4, in gravure water-based metal ink production process, with the addition of pH value stabilizer, the resin dispersion system pH value made reaches
To 7.5-8.0, gravure water-based metal ink pH value reaches 8-8.5, meta-alkalescence, resin, solvent, metal toner in alkaline environment
Relatively stable, metal toner will not be with the reaction of Salmon-Saxl in resin and solvent, and gravure water-based metal ink is relatively stable, does not haves and sends out
The problem that black, glossiness is low.
5, gravure water-based metal ink with the addition of in Cu-Zn alloy powder, aluminum argentum powder, copper gold bar, aluminum Rhizoma Humatae Tyermanni, aluminum paste metal toner
One or two kinds of and more than, the glossiness of gravure water-based metal ink, wearability, chemical-resistant are greatly improved.
6, gravure water-based metal ink production process can regulate the ratio of ethanol and water, improve product quality, reduce
In printing process, easily there is sticking with paste the back of the body, rub the back of the body, fly ink, bracing wire, apprehensive problem.
Detailed description of the invention:
Embodiment one: a kind of gravure water-based metal ink, it is by two kinds of systems of resin dispersion system and metal toner predispersion system
Coordinating composition, resin dispersion system includes the water-borne acrylic resin of 20 parts, the isopropanol of 2.5 parts, the aqueous acrylamide of 6.5 parts
Acid, the water of 6.5 parts, the PH stabilizer of 0.7 part, the wetting dispersing agent of 3.5 parts；Metal toner predispersion system includes the gold of 36 parts
Belong to toner, the ethanol of 18 parts, the water soluble colloid of the water-borne acrylic resin of 5.5 parts, the coupling agent of 0.06 part, the modification of 0.2 part
Polycarboxylic acids potassium salt, the antirust agent of 0.2 part, the passivator of 0.4 part.
Embodiment two: the production method of a kind of gravure water-based metal ink, including following procedure of processing:
The preparation of (a) resin dispersion system
Reactor I is sequentially added into the water-borne acrylic resin of 20 parts, the isopropanol of 2.5 parts, the water soluble acrylic acid of 6.5 parts,
The water of 6.5 parts, the PH stabilizer of 0.7 part, the wetting dispersing agent of 3.5 parts, be placed on reactor I on centrifuge, at 60 DEG C, rotating speed
Under conditions of 450 turns per minute, disperse 20min, the mixed liquor in reactor I is transferred to, in container I, carry out sealing and standing
7d, in mixed liquor, bubble-free produces, and viscosity reaches 48S, and pH value reaches 7. 8, makes resin dispersion system, standby；
The preparation of (b) metal toner predispersion system
In reactor II, add the metal toner of 36 parts and the ethanol of 18 parts, reactor II be placed on centrifuge, 25 DEG C,
Under conditions of rotating speed is 100 turns per minute, disperse 5min, then toward reactor II is sequentially added into the water soluble acrylic acid tree of 5.5 parts
The water soluble colloid of fat, the coupling agent of 0.06 part, the modified polycarboxylic acid potassium salt of 0.2 part, the antirust agent of 0.2 part, the passivation of 0.4 part
Agent, after mix homogeneously, transfers to the mixed liquor in reactor II in container II, stands 2h, without Precipitation, prepares metallochrome
The pre-dispersed system of powder, standby, metal toner is Cu-Zn alloy powder, and granule size is at 1300 mesh；
The preparation of (c) gravure water-based metal ink
Resin dispersion system in container I is poured in reactor III, then by the metal toner predispersion system in container II with
And the anti-settling agent of 0.08 part adds in reactor III together, after addition, reactor III is placed on centrifuge, 25 DEG C,
Under conditions of rotating speed is 400 turns per minute, disperseing 20min, viscosity of mixed liquid reaches 120S, and pH value reaches 8.3, makes gravure
Water-based metal ink.
Claims (3)
1. gravure water-based metal ink, it is characterised in that this gravure water-based metal ink is divided in advance by resin dispersion system and metal toner
Two kinds of systems of prose style free from parallelism system coordinate composition, resin dispersion system include the water-borne acrylic resin of 19 ~ 21 parts, the isopropanol of 2 ~ 3 parts,
The water soluble acrylic acid of 6 ~ 7 parts, the water of 6 ~ 7 parts, the PH stabilizer of 0.5 ~ 1 part, the wetting dispersing agent of 3 ~ 4 parts；Metal toner divides in advance
Prose style free from parallelism system includes the metal toner of 35 ~ 37 parts, the ethanol of 17 ~ 19 parts, the water soluble colloid of the water-borne acrylic resin of 5 ~ 6 parts,
The coupling agent of 0.05 ~ 0.07 part, the modified polycarboxylic acid potassium salt of 0.1 ~ 0.3 part, the antirust agent of 0.1 ~ 0.3 part, 0.3 ~ 0.5 part blunt
Agent.
2. the production method of gravure water-based metal ink as claimed in claim 1, it is characterised in that include following procedure of processing:
The preparation of (a) resin dispersion system
The water-borne acrylic resin of 19 ~ 21 parts, the isopropanol of 2 ~ 3 parts, the aqueous acrylamide of 6 ~ 7 parts it is sequentially added in reactor I
Acid, the water of 6 ~ 7 parts, the PH stabilizer of 0.5 ~ 1 part, the wetting dispersing agent of 3 ~ 4 parts, be placed on reactor I on centrifuge, 60
DEG C, under conditions of rotating speed is 450 turns per minute, disperses 20min, the mixed liquor in reactor I transferred to, in container I, carry out
Sealing and standing 7d, in mixed liquor, bubble-free produces, and saybolt viscosity reaches 45s ~ 52s, and pH value reaches 7.5 ~ 8.0, makes resin and divides
Prose style free from parallelism system, standby；
The preparation of (b) metal toner predispersion system
In reactor II, add the metal toner of 35 ~ 37 parts and the ethanol of 17 ~ 19 parts, reactor II be placed on centrifuge,
25 DEG C, under conditions of rotating speed is 100 turns per minute, disperse 5min, then toward reactor II is sequentially added into the aqueous third of 5 ~ 6 parts
The water soluble colloid of olefin(e) acid resin, the coupling agent of 0.05 ~ 0.07 part, the modified polycarboxylic acid potassium salt of 0.1 ~ 0.3 part, 0.1 ~ 0.3 part
Antirust agent, the passivator of 0.3 ~ 0.5 part, after mix homogeneously, transfer to the mixed liquor in reactor II in container II, stands
2h, without Precipitation, prepares metal toner predispersion system, standby；
The preparation of (c) gravure water-based metal ink
Resin dispersion system in container I is poured in reactor III, then by the metal toner predispersion system in container II with
And the anti-settling agent of 0.07 ~ 0.09 part adds in reactor III together, after addition, reactor III is placed on centrifuge,
25 DEG C, under conditions of rotating speed is 400 turns per minute, disperse 20min, mixed liquor saybolt viscosity reaches 100s ~ 140s, and pH value reaches
To 8 ~ 8.5, make gravure water-based metal ink.
3. the production method of gravure water-based metal ink as claimed in claim 2, it is characterised in that metal toner is Cu-Zn alloy powder,
Or aluminum argentum powder, or copper gold bar, or aluminum Rhizoma Humatae Tyermanni, or aluminum paste, the size of metal toner is between 1000 ~ 1500 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610636014.1A CN106280700A (en) | 2016-08-05 | 2016-08-05 | Gravure water-based metal ink and production method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610636014.1A CN106280700A (en) | 2016-08-05 | 2016-08-05 | Gravure water-based metal ink and production method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106280700A true CN106280700A (en) | 2017-01-04 |
Family
ID=57665396
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610636014.1A Pending CN106280700A (en) | 2016-08-05 | 2016-08-05 | Gravure water-based metal ink and production method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106280700A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107760095A (en) * | 2017-12-01 | 2018-03-06 | 云南红塔油墨有限公司 | Water-based gravure gold ink and preparation method thereof |
| CN109054499A (en) * | 2018-08-07 | 2018-12-21 | 长春吉星印务有限责任公司 | A kind of environment-friendly water-based silver inks and preparation method thereof for intaglio plate green printing |
| CN109572156A (en) * | 2019-01-31 | 2019-04-05 | 上海运城制版有限公司 | A kind of intaglio printing method of quality control |
| CN117363095A (en) * | 2023-11-03 | 2024-01-09 | 常德市金鹰印刷材料有限公司 | High-adhesion gravure metal ink capable of being printed at high speed and preparation method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1446865A (en) * | 2002-10-31 | 2003-10-08 | 汕头市金园区东风包装印刷厂有限公司 | Aquosity intaglio printing ink and its preparation method |
| CN1916091A (en) * | 2006-09-06 | 2007-02-21 | 深圳市永仁包装印刷材料有限公司 | Water-soluble gold and silver inks, and preparation method |
| CN101054489A (en) * | 2006-04-13 | 2007-10-17 | 楼永财 | Water high light wearable intaglio ink and preparing method thereof |
| CN101134862A (en) * | 2006-08-30 | 2008-03-05 | 东莞市佳景印刷材料有限公司 | Aqueous gold aluminium ink resin and method for synthesizing the same |
| CN102485813A (en) * | 2010-12-01 | 2012-06-06 | 成都市新津托展油墨有限公司 | Preparation method of alcohol water-soluble plastic intaglio plate golden oil |
| CN103421386A (en) * | 2013-08-02 | 2013-12-04 | 上海烟草集团有限责任公司 | Water-based gold ink for tipping paper and preparation method thereof |
| CN103788768A (en) * | 2013-12-23 | 2014-05-14 | 深圳市深赛尔股份有限公司 | Water-based golden ink produced by using ordinary bronze powder and preparation method thereof |
| CN103923524A (en) * | 2013-01-15 | 2014-07-16 | 永发印务(东莞)有限公司 | A water-based pearlescent ink for web gravure printing |
| CN105038403A (en) * | 2015-08-26 | 2015-11-11 | 云南彩丰油墨有限公司 | Water-based gravure pearly luster varnish and preparation method thereof |
| CN105038402A (en) * | 2015-08-26 | 2015-11-11 | 云南彩丰油墨有限公司 | Water-based gravure metal gold varnish and preparation method thereof |
-
2016
- 2016-08-05 CN CN201610636014.1A patent/CN106280700A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1446865A (en) * | 2002-10-31 | 2003-10-08 | 汕头市金园区东风包装印刷厂有限公司 | Aquosity intaglio printing ink and its preparation method |
| CN101054489A (en) * | 2006-04-13 | 2007-10-17 | 楼永财 | Water high light wearable intaglio ink and preparing method thereof |
| CN101134862A (en) * | 2006-08-30 | 2008-03-05 | 东莞市佳景印刷材料有限公司 | Aqueous gold aluminium ink resin and method for synthesizing the same |
| CN1916091A (en) * | 2006-09-06 | 2007-02-21 | 深圳市永仁包装印刷材料有限公司 | Water-soluble gold and silver inks, and preparation method |
| CN102485813A (en) * | 2010-12-01 | 2012-06-06 | 成都市新津托展油墨有限公司 | Preparation method of alcohol water-soluble plastic intaglio plate golden oil |
| CN103923524A (en) * | 2013-01-15 | 2014-07-16 | 永发印务(东莞)有限公司 | A water-based pearlescent ink for web gravure printing |
| CN103421386A (en) * | 2013-08-02 | 2013-12-04 | 上海烟草集团有限责任公司 | Water-based gold ink for tipping paper and preparation method thereof |
| CN103788768A (en) * | 2013-12-23 | 2014-05-14 | 深圳市深赛尔股份有限公司 | Water-based golden ink produced by using ordinary bronze powder and preparation method thereof |
| CN105038403A (en) * | 2015-08-26 | 2015-11-11 | 云南彩丰油墨有限公司 | Water-based gravure pearly luster varnish and preparation method thereof |
| CN105038402A (en) * | 2015-08-26 | 2015-11-11 | 云南彩丰油墨有限公司 | Water-based gravure metal gold varnish and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107760095A (en) * | 2017-12-01 | 2018-03-06 | 云南红塔油墨有限公司 | Water-based gravure gold ink and preparation method thereof |
| CN109054499A (en) * | 2018-08-07 | 2018-12-21 | 长春吉星印务有限责任公司 | A kind of environment-friendly water-based silver inks and preparation method thereof for intaglio plate green printing |
| CN109572156A (en) * | 2019-01-31 | 2019-04-05 | 上海运城制版有限公司 | A kind of intaglio printing method of quality control |
| CN117363095A (en) * | 2023-11-03 | 2024-01-09 | 常德市金鹰印刷材料有限公司 | High-adhesion gravure metal ink capable of being printed at high speed and preparation method thereof |
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