CN106280089A - A kind of ivory board and application thereof - Google Patents
A kind of ivory board and application thereof Download PDFInfo
- Publication number
- CN106280089A CN106280089A CN201610654955.8A CN201610654955A CN106280089A CN 106280089 A CN106280089 A CN 106280089A CN 201610654955 A CN201610654955 A CN 201610654955A CN 106280089 A CN106280089 A CN 106280089A
- Authority
- CN
- China
- Prior art keywords
- ivory board
- application
- card
- ivory
- board
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000002671 adjuvant Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 4
- 238000005282 brightening Methods 0.000 claims abstract description 4
- 239000003381 stabilizer Substances 0.000 claims abstract description 4
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 5
- 230000003000 nontoxic effect Effects 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 230000007774 longterm Effects 0.000 abstract description 2
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 20
- 238000001514 detection method Methods 0.000 description 9
- -1 2-ethylhexyl Chemical group 0.000 description 8
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 6
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 6
- 235000010290 biphenyl Nutrition 0.000 description 5
- 230000001473 noxious effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- KTADSLDAUJLZGL-UHFFFAOYSA-N 1-bromo-2-phenylbenzene Chemical group BrC1=CC=CC=C1C1=CC=CC=C1 KTADSLDAUJLZGL-UHFFFAOYSA-N 0.000 description 2
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 2
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000010215 titanium dioxide Nutrition 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
This application discloses a kind of ivory board and application thereof.The ivory board of the application is with PVC as main raw material(s), wherein be added with additional adjuvants, additional adjuvants include accounting for the MBS of ivory board total weight parts 3.5%, 181 stabilizers of 1.2%, P 201 auxiliary agent of 1%, the brightening agent of 0.012%, the V709 Rhizoma Bletillae of 0.0028%, 0.0004% 707 purplish red, the G16 of 0.06% in cunning, the outer cunning of 0.018%, the anti ultraviolet agent of 0.028% and the titanium dioxide of 6%.The ivory board toughness of the application is strong, the most pliable deformation；Further, it is not easy to turn yellow under long-term shining upon, more durable.The ivory board of the application, provides a kind of nontoxic, card stock of Environmental Safety for preparing various member card, mass transit card etc..
Description
Technical field
The application relates to ivory board field, particularly to a kind of ivory board and application thereof.
Background technology
Ivory board be a kind of be wear-resisting durable card stock prepared by main raw material(s) with polrvinyl chloride (abbreviation PCV),
It is mainly used in various member card, bank card, social security card, mass transit card, identity card etc..Along with the development of society, our life
Also being full of by various cards, ivory board have also been obtained application greatly.
Although the main raw material(s) of ivory board is PVC, but, ivory board prepared by different formulations, its function and application is also
It is not quite similar.Ivory board the most on the market, in long-term transportation, is the most all that multiple ivory boards are superimposed
, it is easily deformed, and, the most easily turn yellow.For businessman especially for some outlet ivory boards, ivory board warp
Sea-freight outlet, it is easier to deform the problem turned yellow.
Summary of the invention
The purpose of the application is to provide ivory board and the application thereof of a kind of compositional refinements.
To achieve these goals, this application provides a kind of ivory board, this ivory board with PVC as main raw material(s), its
In be added with additional adjuvants, additional adjuvants includes accounting for the MBS of ivory board total weight parts 3.5%, 181 stabilizers of 1.2%, the P-of 1%
201 auxiliary agents, the brightening agent of 0.012%, the V709 Rhizoma Bletillae of 0.0028%, 0.0004% 707 purplish red, the G16 of 0.06% in sliding,
Outer cunning, the anti ultraviolet agent of 0.028% and the titanium dioxide of 6% of 0.018%.
The application is by being optimized each component, combining, and tests its optimum amount, finally obtains the application
Ivory board formula；The formula of the application gives full play to function and the effect of each component so that the ivory board of preparation has higher
Toughness, and, be at high temperature exposed to the sun and will not turn yellow.What is more important, the ivory board of the application confirms after tested, nontoxic,
Environmental protection, can the various member cards being applied in life of safety, bank card etc..
The another side of the application provides the ivory board of the application in member card, bank card, social security card, mass transit card, identity
Application in card or name card.
It is appreciated that the ivory board of the application, compared with existing ivory board, first, toughness is higher；Second, the most variable
Color, more robust；3rd, safe and nontoxic.Therefore, it can substitute existing ivory board, be applied to member card, bank card, social security
The fields such as card, mass transit card, identity card, name card.
Therefore, the application has the beneficial effects that: the ivory board toughness of the application is strong, the most pliable deformation；Further, growing
It is not easy under the shining upon of phase turn yellow, more durable.The ivory board of the application, carries for preparing various member card, mass transit card etc.
Supply a kind of nontoxic, card stock of Environmental Safety.
Detailed description of the invention
In order to enable auditor to further appreciate that the purpose of the application, existing attached preferred embodiment is as follows to describe in detail,
The present embodiment is merely to illustrate the technical scheme of the application, and non-limiting the application.
Embodiment
The ivory board of this example, with PVC as main raw material(s), is additionally supplemented with additional adjuvants, and additional adjuvants is by accounting for ivory board
The MBS of total weight parts 3.5%, 181 stabilizers of 1.2%, the P-201 auxiliary agent of 1%, the brightening agent of 0.012%, the V709 of 0.0028%
Rhizoma Bletillae, 0.0004% 707 purplish red, the G16 of 0.06% in cunning, the outer cunning of 0.018%, the anti ultraviolet agent of 0.028% and the titanium white of 6%
Powder forms；Surplus is PVC.Each component is weighed according to weight ratio, mixes, through 100 degree of blender stirring mixing, then extrude
Machine is extruded, then by calendering compression molding, finally cuts into suitable size, to facilitate transport or to use.
The ivory board preparing this example carries out toughness detection, high temperature detection and noxious substance detection.Specific as follows:
Toughness detection uses UV machine, and the ivory board of preparation is bent 80 degree, and result shows, the ivory board of this example bends 80 degree not to be had yet
Have and rupture, there is the strongest toughness.Current existing ivory board is typically not capable of the strongest toughness.
High temperature detects, and the ivory board this example prepared irradiates 24 hours at 80 degrees celsius, and the color observing ivory board becomes
Change.Result shows, ivory board prepared by this example does not occur variable color, it is seen that even if the ivory board of this example is not easy to become through high temperature
Color.Meanwhile, in order to observe the ivory board of this example situation at low temperatures, by the ivory board of this example as subzero 30 degrees Celsius
Irradiating 24 hours, result shows, the ivory board of this example, also without there is color change, has the strongest thermal adaptability.
Noxious substance detection entrusts UEFA Champions League detection technique Services Co., Ltd (CPST) to carry out, the ivory board preparing this example
Lead, hydrargyrum, cadmium, Cr VI, PBBs, PBDE, phthalic acid two (2-ethylhexyl) ester (DEHP), adjacent benzene two
The content of formic acid butyloxy phenyl (BBP), dibutyl phthalate (DBP) and diisobutyl phthalate (DIBP) is surveyed
Examination.IEC publication referenced by testing result and detection is as shown in table 1.
Table 1 noxious substance testing result
| Test event | Unit | Method of testing | Result | Detection value | Limit value |
| Lead | mg/kg | IEC 62321-5:2013, ICP-OES | N.D. | 2 | 1000 |
| Hydrargyrum | mg/kg | IEC 62321-4:2013, ICP-OES | N.D. | 2 | 1000 |
| Cadmium | mg/kg | IEC 62321-5:2013, ICP-OES | N.D. | 2 | 100 |
| Cr VI | mg/kg | IEC 62321:2008, UV-VIS | N.D. | 2 | 1000 |
| One bromo biphenyl | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| '-dibromobiphenyl | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Three bromo biphenyls | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Four bromo biphenyls | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Five bromo biphenyls | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Hexabromobiphenyl | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Seven bromo biphenyls | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Octabromo-diphenyl | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Nine bromo biphenyls | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Decabromodiphenyl | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| PBBs summation | mg/kg | - | N.D. | - | 1000 |
| Monobromo Biphenyl Ether | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| '-dibromobiphenyl ether | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Tribromo Biphenyl Ether | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Tetrabromo Biphenyl Ether | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Pentabromo-Biphenyl Ether | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Hexabromobiphenyl ether | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Seven bromo biphenyl ethers | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Octa-BDE | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Nine bromo biphenyl ethers | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| Decabromodiphenyl oxide | mg/kg | IEC 62321-6: 2015, GC-MS | N.D. | 5 | - |
| PBDE summation | mg/kg | - | N.D. | - | 1000 |
| DEHP | mg/kg | EN 14372:2004 | N.D. | 50 | 1000 |
| BBP | mg/kg | EN 14372:2004 | N.D. | 50 | 1000 |
| DBP | mg/kg | EN 14372:2004 | N.D. | 50 | 1000 |
| DIBP | mg/kg | EN 14372:2004 | N.D. | 50 | 1000 |
The result of table 1 shows, the content of the various noxious substance of ivory board prepared by this example is much smaller than regulation and limits, and, this
Example has been also carried out detection to other several noxious substances being not specified by, and result shows, its content is all in allowed band.Cause
This, ivory board prepared by this example is nontoxic, Environmental Safety, it is possible to meet various member card, bank card, social security card, mass transit card, identity
Card or the use demand of name card.
It is to be understood that, foregoing and detailed description of the invention are intended to prove the reality of technical scheme provided herein
Application, should not be construed as the restriction to the application protection domain.Those skilled in the art in spirit herein and principle, when
Can various modifications may be made, equivalent or improvement.The protection domain of the application is as the criterion with appended claims.
Claims (2)
1. an ivory board, it is characterised in that: described ivory board, with PVC as main raw material(s), is wherein added with additional adjuvants, institute
State additional adjuvants include accounting for the MBS of ivory board total weight parts 3.5%, 181 stabilizers of 1.2%, the P-201 auxiliary agent of 1%, 0.012%
Brightening agent, the V709 Rhizoma Bletillae of 0.0028%, 0.0004% 707 purplish red, the G16 of 0.06% in cunning, the outer cunning of 0.018%,
The anti ultraviolet agent of 0.028% and the titanium dioxide of 6%.
Ivory board the most according to claim 1 is in member card, bank card, social security card, mass transit card, identity card or name card
Application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610654955.8A CN106280089A (en) | 2016-08-11 | 2016-08-11 | A kind of ivory board and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610654955.8A CN106280089A (en) | 2016-08-11 | 2016-08-11 | A kind of ivory board and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106280089A true CN106280089A (en) | 2017-01-04 |
Family
ID=57670054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610654955.8A Pending CN106280089A (en) | 2016-08-11 | 2016-08-11 | A kind of ivory board and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106280089A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106967263A (en) * | 2017-05-11 | 2017-07-21 | 温州市隆昌塑料有限公司 | Water drilling piece and preparation method thereof |
| CN107663349A (en) * | 2017-10-16 | 2018-02-06 | 河北凯成包装股份有限公司 | Polymer Synthesizing paper |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101348591A (en) * | 2008-07-08 | 2009-01-21 | 常州百佳磁卡有限公司 | PVC card matrix material |
| CN104487988A (en) * | 2012-04-03 | 2015-04-01 | X卡控股有限公司 | Information bearing card comprising cross-linked polymer composition and method of manufacturing the same |
| CN105524298A (en) * | 2015-12-22 | 2016-04-27 | 成都新柯力化工科技有限公司 | Preparation method of composite ivory board dedicated inorganic powder |
-
2016
- 2016-08-11 CN CN201610654955.8A patent/CN106280089A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101348591A (en) * | 2008-07-08 | 2009-01-21 | 常州百佳磁卡有限公司 | PVC card matrix material |
| CN104487988A (en) * | 2012-04-03 | 2015-04-01 | X卡控股有限公司 | Information bearing card comprising cross-linked polymer composition and method of manufacturing the same |
| CN105524298A (en) * | 2015-12-22 | 2016-04-27 | 成都新柯力化工科技有限公司 | Preparation method of composite ivory board dedicated inorganic powder |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106967263A (en) * | 2017-05-11 | 2017-07-21 | 温州市隆昌塑料有限公司 | Water drilling piece and preparation method thereof |
| CN107663349A (en) * | 2017-10-16 | 2018-02-06 | 河北凯成包装股份有限公司 | Polymer Synthesizing paper |
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| WD01 | Invention patent application deemed withdrawn after publication |
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