CN106265135A - 一种具有抗氧化、保湿活性的盖菜防晒霜 - Google Patents
一种具有抗氧化、保湿活性的盖菜防晒霜 Download PDFInfo
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- CN106265135A CN106265135A CN201610882799.0A CN201610882799A CN106265135A CN 106265135 A CN106265135 A CN 106265135A CN 201610882799 A CN201610882799 A CN 201610882799A CN 106265135 A CN106265135 A CN 106265135A
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- leaf mustard
- sunscreen cream
- polydimethylsiloxane
- antioxidation
- sunscreen
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- 239000000516 sunscreening agent Substances 0.000 title claims abstract description 59
- 230000000475 sunscreen effect Effects 0.000 title claims abstract description 56
- 239000006071 cream Substances 0.000 title claims abstract description 49
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- 235000005855 Brassica juncea var. subintegrifolia Nutrition 0.000 title claims abstract description 44
- 230000003020 moisturizing effect Effects 0.000 title claims abstract description 23
- 230000003064 anti-oxidating effect Effects 0.000 title claims abstract description 17
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- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 21
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 17
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- GJQLBGWSDGMZKM-UHFFFAOYSA-N ethylhexyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(CC)CCCCC GJQLBGWSDGMZKM-UHFFFAOYSA-N 0.000 claims description 7
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
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- A—HUMAN NECESSITIES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
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Abstract
本发明提供了一种具有抗氧化、保湿活性的盖菜防晒霜，该防晒霜由盖菜提取液0.5‑1份、保湿剂20‑25份、润肤剂12‑15份、防晒剂6‑8份、乳化剂5‑6份、乳化稳定剂0.7‑0.8份、防腐剂0.04‑0.07份、着色剂0.08‑0.11份组成，具有多种保湿活性物质，且盖菜提取液有保湿和抗氧化活性，保湿的同时可消除多余的自由基，其含有的多种营养物质还具有修复细胞日晒损伤的功效，可有效保护皮肤。
Description
技术领域
本发明涉及化妆品领域，特别涉及一种具有抗氧化、保湿活性的盖菜防晒霜。
背景技术
盖菜是具有悠久历史的“芥菜”的变种，特指叶子大、叶脉粗、叶面多皱纹的那种南方盖菜。盖菜不是名贵蔬菜，身价微，却因其经霜耐寒，耐贫瘠、不择地而生，易种易得，又便于保存。盖菜(Brass ica juncea(L.)Czerniak.)是十字花科芸薹属一、二年生草本植物，又称包心芥菜、结球芥菜。盖菜含丰富的硫代葡萄糖苷、维生素、膳食纤维、蛋白质、糖类和矿物质，营养丰富，食用价值高。
中国专利CN201510343923.1公开了一种保湿防晒霜，由以下重量份数的原料制成：芦荟凝胶汁6-8份、甘油5-12份、月见草油6-14份、大枣10-16份、杏仁6-11份、芡实5-8份、羊毛脂2-4份、单硬脂酸甘油酯5-7份、十八醇6-9份、豆类5-7份、单硬脂酸甘油酯6-9份、羊毛脂5-8份、维生素E2-4份、二甲基硅油2-5份、绿茶提取物6-12份、透明质酸0.4-0.7份。该保湿防晒霜具有极佳的保湿、防晒效果，赋予肌肤深层滋润，减少细干燥纹，使肌肤全日保湿。
中国专利CN201510928239.X公开了一种海藻保湿防晒霜及其制作方法，包括下述原料：紫苏籽油13-15份、M1乳化剂2.5-3.5份、角沙烷0.5-1.5份、硬脂酸镁0.5-1份、油溶纳米二氧化钛4-6份、氧化锌1.5-3份、铁红0.05-0.1份、1.3丁二醇5-6.5份、食盐0.5-1份、海藻提取液4-6份、去离子水58-62份、天然抗菌剂0.8-1.2份。该防晒霜能够有效隔绝紫外线与皮肤，减少紫外线对皮肤的损害，达到良好的防晒效果，减缓皮肤光老化的产生，也减少紫外线对皮肤的伤害，同时具有美白装饰皮肤的效果。
盖菜在食品领域的应用已广为人知，然而其在其他领域的应用并未有具体的记载。盖菜作为一种廉价而营养丰富的蔬菜，在化妆品中具有广阔的应用前景。
发明内容
本发明目的在于提供一种具有抗氧化、保湿活性的防晒霜，该防晒霜添加了盖菜提取液，赋予防晒霜良好的抗氧化和保湿作用，同时拓宽了盖菜的应用范围。
本发明的具体技术方案如下：
一种具有抗氧化、保湿活性的盖菜防晒霜，相对于0.5-1重量份的盖菜提取液，该防晒霜还含有下述重量份的原料:保湿剂20-25份、防晒剂6-8份、乳化剂5-6份、防腐剂0.04-0.07份、着色剂0.08-0.11份；
所述保湿剂为丙二醇；
所述防晒剂为二氧化钛；
所述乳化剂为环五聚二甲基硅氧烷/PEG/PPG-12/16聚二甲基硅氧烷和聚甘油-2油酸酯/甘油异硬脂酸酯的混合物；
所述防腐剂为羟苯丙酯、双咪唑烷基脲/碘丙炔醇丁基氨甲酸酯、羟苯甲酯的混合物，其中，双咪唑烷基脲/碘丙炔醇丁基氨甲酸酯的用量为0.005-0.008重量份；
所述着色剂为比例为CI 77491和CI 77492的混合物。
进一步地，相对于0.5-1重量份的盖菜提取液，该防晒霜还含有润肤剂12-15份，所述润肤剂为棕榈酸乙基己酯、肉豆蔻酸异丙酯、辛酸/癸酸甘油三酯、聚二甲基硅氧烷和矿油的混合物。
进一步地，相对于0.5-1重量份的盖菜提取液，该防晒霜还含有乳化稳定剂0.7-0.8份，所述乳化稳定剂为硫酸镁。
进一步地，所述防晒霜由下述重量份的原料组成：
盖菜提取液0.8，
丙二醇：25，
二氧化钛：8，
棕榈酸乙基己酯：5，
肉豆蔻酸异丙酯：4，
环五聚二甲基硅氧烷/PEG/PPG-12/16聚二甲基硅氧烷：3，
聚甘油-2油酸酯/甘油异硬脂酸酯：2.5，
辛酸/癸酸甘油三酯：2，
聚二甲基硅氧烷：2，
矿油：2，
硫酸镁：0.8，
羟苯丙酯：0.02，
双咪唑烷基脲/碘丙炔醇丁基氨甲酸酯：0.005，
羟苯甲酯：0.02，
CI 77491：0.071，
CI 77492：0.034，
去离子水：44.75。
本发明还提供了一种具有抗氧化、保湿活性的盖菜防晒霜的制备方法，所述防晒霜的制备方法为：
将A相二氧化钛、棕榈酸乙基己酯、肉豆蔻酸异丙酯、环五聚二甲基硅氧烷/PEG/PPG-12/16聚二甲基硅氧烷、聚甘油-2油酸酯/甘油异硬脂酸酯、聚甘油-2油酸酯/甘油异硬脂酸酯、辛酸/癸酸甘油三酯、聚二甲基硅氧烷、矿油、羟苯丙酯、羟苯甲酯、CI 77491、CI77492投入到乳化锅中，将B相丙二醇、硫酸镁投入到水相锅中，A、B相原料分别加热至85℃，均质5min，冷却至45℃，将B相缓慢抽入乳化锅中，30r/min均质7min，45r/min保温30min抽真空，乳化锅冷却至40℃加入双咪唑烷基脲/碘丙炔醇丁基氨甲酸酯、盖菜提取液，搅拌速度控制在35r/min，搅拌均匀即可。
进一步地，在所述制备方法中，A相抽入乳化锅时搅拌速度为50r/min。
进一步地，在所述制备方法中，二氧化钛需要过胶体磨充分磨匀。
盖菜提取液的制备方法：盖菜洗净冻干，粉碎至30目，加入10倍原料量提取溶液，提取溶液为比例为3:2的45％乙醇溶液和0.15mol/L氢氧化钠溶液的混合溶液,40℃超声波提取30min，分离纯化得盖菜提取液。
本发明的有益效果为：盖菜含有多种多糖类物质和多酚类物质，具有保湿功效，结合防晒霜中另外的保湿成分，在补充表皮层细胞水分的同时可透过皮肤进入到真皮层，给皮肤双重补水。盖菜提取液中还含有多种具有抗氧化功能的活性成分，多酚类化合物、黄酮类化合物以及多糖类物质等共同起到抗氧化作用，消除多余的自由基。盖菜提取液中还含有矿物质、维生素等多种营养物质，具有修复细胞日晒损伤的功效，结合防晒霜中可阻隔紫外线的防晒剂，可在防晒的同时进行着细胞修复，可有效减缓因日晒导致的皮肤衰老，给细胞双重的保护。
文中出现的以下成分名称均为INCI(International Nomenclature CosmeticIngredient，即国际化妆品原料命名)所规定的名称：环五聚二甲基硅氧烷/PEG/PPG-12/16聚二甲基硅氧烷、聚甘油-2油酸酯/甘油异硬脂酸酯、辛酸/癸酸甘油三酯、双咪唑烷基脲/碘丙炔醇丁基氨甲酸酯。
具体实施方式
为了使本技术领域的人员更好地理解本发明的技术方案，下面结合实施例对本发明的技术方案作进一步详细的说明。
实施例1-5
表1盖菜防晒霜配方各组成及其重量百分比
制备方法：将A相二氧化钛、棕榈酸乙基己酯、肉豆蔻酸异丙酯、环五聚二甲基硅氧烷/PEG/PPG-12/16聚二甲基硅氧烷、聚甘油-2油酸酯/甘油异硬脂酸酯、聚甘油-2油酸酯/甘油异硬脂酸酯、辛酸/癸酸甘油三酯、聚二甲基硅氧烷、矿油、羟苯丙酯、羟苯甲酯、CI77491、CI 77492投入到乳化锅中，将B相丙二醇、硫酸镁投入到水相锅中，A、B相原料分别加热至85℃，均质5min，冷却至45℃，将B相缓慢抽入乳化锅中，30r/min均质7min，45r/min保温30min抽真空，乳化锅冷却至40℃加入双咪唑烷基脲/碘丙炔醇丁基氨甲酸酯、盖菜提取液，搅拌速度控制在35r/min，搅拌均匀即可。
实施例6DPPH自由基清除评价试验
1.试验样品
实施例1-5制得的防晒霜以及对比例1-2和空白对照制得的防晒霜、空白样品——去离子水。
2.试验方法
清除DPPH自由基能力测定：取2ml试验样品，加入无水乙醇2mL和0.02％DPPH乙醇溶液0.8ml，振荡混合均匀，室温下避光放置30min，在518nm下测定吸光度，计算清除率。表2为防晒霜的DPPH自由基清除评价试验结果表。
清除率％＝((空白吸光值-样品吸光值)/空白吸光值)×100
表2防晒霜的DPPH自由基清除评价结果
通过表2可以看出，在本发明范围内制得的实施例1-5的防晒霜，其抗氧化能力要强于在本范围以外制得的对比例1、2的防晒霜，能实现防晒霜较强的抗氧化能力，大大提高防晒霜的护肤效果。
实施例6防晒霜使用功效评价试验
对实施例1-5、对比例1-2制得的防晒霜进行功效评价试验，选取20-45岁志愿者140名，分为7组，每组男女各5名，实验组1-5使用实施例1-5制得的盖菜防晒霜，对照组1使用对比例1制得的防晒霜，对照组2使用对比例2制得的防晒霜。使用方法：每日外出前半小时将试验品涂于一边手臂上，另一边手臂不涂抹任何东西，连续使用一个月之后观察并作出评价，评价结果见于表3。
表3防晒霜使用功效评价试验
通过表3可以看出，在本发明范围内制得的实施例1-5的防晒霜，其保湿能力与本范围以外制得的对比例1、2的防晒霜没有明显差别，但其阻碍肤色变黑的能力要强于在本范围以外制得的对比例1、2的防晒霜，能实现防晒霜较强的晒后修复能力，降低皮肤因日晒而促发的自我保护的反应强度，大大提高防晒霜的修复护肤效果。
所有使用本发明盖菜防晒霜的受试者均没有出现任何不良反应。
以上所述实施例仅表达了本发明的几种实施方式，其描述较为具体和详细，但并不能因此而理解为对本发明专利范围的限制。应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进，这些都属于本发明的保护范围。因此，本发明专利的保护范围应以所附权利要求为准。
Claims (9)
1.一种具有抗氧化、保湿活性的盖菜防晒霜，其特征在于，相对于0.5-1重量份的盖菜提取液，该防晒霜还含有下述重量份的原料:保湿剂20-25份、防晒剂6-8份、乳化剂5-6份、防腐剂0.04-0.07份、着色剂0.08-0.11份；
所述保湿剂为丙二醇；
所述防晒剂为二氧化钛；
所述乳化剂为环五聚二甲基硅氧烷/PEG/PPG-12/16聚二甲基硅氧烷和聚甘油-2油酸酯/甘油异硬脂酸酯的混合物；
所述防腐剂为羟苯丙酯、双咪唑烷基脲/碘丙炔醇丁基氨甲酸酯、羟苯甲酯的混合物，其中，双咪唑烷基脲/碘丙炔醇丁基氨甲酸酯的用量为0.005-0.008重量份；
所述着色剂为比例为CI 77491和CI 77492的混合物。
2.根据权利要求1所述的具有抗氧化、保湿活性的盖菜防晒霜，其特征在于，相对于0.5-1重量份的盖菜提取液，该防晒霜还含有润肤剂12-15份。
3.根据权利要求2所述的具有抗氧化、保湿活性的盖菜防晒霜，其特征在于，所述润肤剂为棕榈酸乙基己酯、肉豆蔻酸异丙酯、辛酸/癸酸甘油三酯、聚二甲基硅氧烷和矿油的混合物。
4.根据权利要求1所述的具有抗氧化、保湿活性的盖菜防晒霜，其特征在于，相对于0.5-1重量份的盖菜提取液，该防晒霜还含有乳化稳定剂0.7-0.8份。
5.根据权利要求4所述的具有抗氧化、保湿活性的盖菜防晒霜，
其特征在于，所述乳化稳定剂为硫酸镁。
6.根据权利要求1所述的具有抗氧化、保湿活性的盖菜防晒霜，其特征在于，所述防晒霜由下述重量份的原料组成：
盖菜提取液0.8，
丙二醇：25，
二氧化钛：8，
棕榈酸乙基己酯：5，
肉豆蔻酸异丙酯：4，
环五聚二甲基硅氧烷/PEG/PPG-12/16聚二甲基硅氧烷：3，
聚甘油-2油酸酯/甘油异硬脂酸酯：2.5，
辛酸/癸酸甘油三酯：2，
聚二甲基硅氧烷：2，
矿油：2，
硫酸镁：0.8，
羟苯丙酯：0.02，
双咪唑烷基脲/碘丙炔醇丁基氨甲酸酯：0.005，
羟苯甲酯：0.02，
CI 77491：0.071，
CI 77492：0.034，
去离子水：44.75。
7.根据权利要求6所述的具有抗氧化、保湿活性的盖菜防晒霜，其特征在于，所述防晒霜的制备方法为：
将A相二氧化钛、棕榈酸乙基己酯、肉豆蔻酸异丙酯、环五聚二甲基硅氧烷/PEG/PPG-12/16聚二甲基硅氧烷、聚甘油-2油酸酯/甘油异硬脂酸酯、聚甘油-2油酸酯/甘油异硬脂酸酯、辛酸/癸酸甘油三酯、聚二甲基硅氧烷、矿油、羟苯丙酯、羟苯甲酯、CI 77491、CI 77492投入到乳化锅中，将B相丙二醇、硫酸镁投入到水相锅中，A、B相原料分别加热至85℃，均质5min，冷却至45℃，将B相缓慢抽入乳化锅中，30r/min均质7min，45r/min保温30min抽真空，乳化锅冷却至40℃加入双咪唑烷基脲/碘丙炔醇丁基氨甲酸酯、盖菜提取液，搅拌速度控制在35r/min，搅拌均匀即可。
8.根据权利要求7所述防晒霜的制备方法，其特征在于，A相抽入乳化锅时搅拌速度为50r/min。
9.根据权利要求7所述防晒霜的制备方法，其特征在于，二氧化钛需要过胶体磨充分磨匀。
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| CN115634177A (zh) * | 2022-09-09 | 2023-01-24 | 云南八凯生物科技有限公司 | 一种苦荞芦丁防晒霜及其制备方法 |
| CN115670985A (zh) * | 2022-10-26 | 2023-02-03 | 浙江兰树化妆品有限公司 | 一种草本植物提取物制备护肤品的抗氧化方法 |
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