CN106221879A - 一种加强型润滑油 - Google Patents
一种加强型润滑油 Download PDFInfo
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- CN106221879A CN106221879A CN201610603759.8A CN201610603759A CN106221879A CN 106221879 A CN106221879 A CN 106221879A CN 201610603759 A CN201610603759 A CN 201610603759A CN 106221879 A CN106221879 A CN 106221879A
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- 239000010687 lubricating oil Substances 0.000 title claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 19
- 239000010439 graphite Substances 0.000 claims abstract description 19
- 239000002199 base oil Substances 0.000 claims abstract description 9
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 9
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 9
- 239000006185 dispersion Substances 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 239000002131 composite material Substances 0.000 claims abstract description 6
- 230000007935 neutral effect Effects 0.000 claims abstract description 6
- 239000003607 modifier Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 4
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims description 3
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000003599 detergent Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 238000013016 damping Methods 0.000 abstract description 3
- 229920001577 copolymer Polymers 0.000 description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 3
- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical compound CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 3
- 239000004575 stone Substances 0.000 description 2
- 238000005829 trimerization reaction Methods 0.000 description 2
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940068939 glyceryl monolaurate Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明公开了一种加强型润滑油，按质量份计，包括100~200份的中性基础油，0.1~1份10~20nm的改性石墨，1~3份表面改性剂，3~7份粘度指数改进剂，1~5份抗氧化剂，1~3份助分散剂，其中所述改性石墨为使用氰基丙烯酸乙酯改性石墨得到的聚甲基丙烯酸甲酯/石墨复合物。本发明的润滑油中添加有适量的改性过的石墨，石墨与基础油的相连性好，在基础油内的分散性好，不出现团聚的现象，极大地提高了润滑油的强度、润滑性、耐磨性、减震性及使用寿命。
Description
技术领域
本发明涉及润滑油的技术领域。
背景技术
润滑油是用在各种类型汽车、机械设备上以减少摩擦，保护机械及加工件的液体或半固体润滑剂，主要起润滑、辅助冷却、防锈、清洁、密封和缓冲等作用。
发明内容
本发明的目的在于提供一种润滑性能优异、减震、耐磨、使用寿命长的润滑油。
本发明的技术方案如下：
一种加强型润滑油，按质量份计，包括100~200份的中性基础油， 0.1~1份10~20nm的改性石墨，1~3份表面改性剂，3~7份粘度指数改进剂，1~5份抗氧化剂，1~3份助分散剂，其中所述改性石墨为使用氰基丙烯酸乙酯改性石墨得到的聚甲基丙烯酸甲酯/石墨复合物。优选的是：所述表面改性剂为十二烷基苯磺酸钠、十六烷基三甲基溴化铵、硅烷偶联剂中的一种或多种。
另外优选的是：所述助分散剂为油酸、三聚甘油单月桂酸酯、硬脂酸单甘油酯中的一种或多种。
另外优选的是：所述粘度指数改进剂为乙丙共聚物，其平均分子量为30000~50000。
另外优选的是：所述石墨为膨胀石墨。
本发明的润滑油中添加有适量的改性过的石墨，石墨与基础油的相连性好，在基础油内的分散性好，不出现团聚的现象，极大地提高了润滑油的强度、润滑性、耐磨性、减震性及使用寿命。
具体实施方式
实施例1
一种加强型润滑油，包括200份的中性基础油；1份20nm的改性膨胀石墨，所述改性石墨为使用氰基丙烯酸乙酯改性石墨得到的聚甲基丙烯酸甲酯/石墨复合物，复合物中聚甲基丙烯酸甲酯的平均分子量为10000，聚甲基丙烯酸甲酯与石墨的物质的量为0.1:1； 3份十二烷基苯磺酸钠；7份作为粘度指数改进剂的乙丙共聚物，该乙丙共聚物的平均分子量为30000；5份抗氧化剂； 3份油酸。
实施例2
一种加强型润滑油，包括100份的中性基础油；0.5份10nm的改性膨胀石墨，所述改性石墨为使用氰基丙烯酸乙酯改性石墨得到的聚甲基丙烯酸甲酯/石墨复合物，复合物中聚甲基丙烯酸甲酯的平均分子量为20000，聚甲基丙烯酸甲酯与石墨的物质的量为0.05:1；2份十六烷基三甲基溴化铵，3份作为粘度指数改进剂的乙丙共聚物，该乙丙共聚物的平均分子量为50000，3份抗氧化剂，2份三聚甘油单月桂酸酯。
实施例3
一种加强型润滑油，包括150份的中性基础油；0.2份10nm的改性膨胀石墨，所述改性石墨为使用氰基丙烯酸乙酯改性石墨得到的聚甲基丙烯酸甲酯/石墨复合物，复合物中聚甲基丙烯酸甲酯的平均分子量为22000，聚甲基丙烯酸甲酯与石墨的物质的量为0.07:1；1份硅烷偶联剂；3份作为粘度指数改进剂的乙丙共聚物，该乙丙共聚物的平均分子量为40000；1份抗氧化剂；2份硬脂酸单甘油酯。
Claims (5)
1. 一种加强型润滑油，其特征在于：按质量份计，包括100~200份的中性基础油， 0.1~1份10~20nm的改性石墨，1~3份表面改性剂，3~7份粘度指数改进剂，1~5份抗氧化剂，1~3份助分散剂，其中所述改性石墨为使用氰基丙烯酸乙酯改性石墨得到的聚甲基丙烯酸甲酯/石墨复合物。
2.根据权利要求1所述的加强型润滑油，其特征在于：所述表面改性剂为十二烷基苯磺酸钠、十六烷基三甲基溴化铵、硅烷偶联剂中的一种或多种。
3.根据权利要求1所述的加强型润滑油，其特征在于：所述助分散剂为油酸、三聚甘油单月桂酸酯、硬脂酸单甘油酯中的一种或多种。
4.根据权利要求1所述的加强型润滑油，其特征在于：所述粘度指数改进剂为乙丙共聚物，其平均分子量为30000~50000。
5.根据权利要求1所述的加强型润滑油，其特征在于：所述石墨为膨胀石墨。
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107267266A (zh) * | 2017-07-04 | 2017-10-20 | 合肥择浚电气设备有限公司 | 一种润滑油及其制备方法 |
| CN107446682A (zh) * | 2017-09-20 | 2017-12-08 | 太仓宝达齿条有限公司 | 一种齿条用高性能水溶性润滑油 |
| CN107523394A (zh) * | 2017-09-20 | 2017-12-29 | 太仓宝达齿条有限公司 | 一种齿条用生物润滑油 |
| CN107686767A (zh) * | 2017-09-20 | 2018-02-13 | 太仓宝达齿条有限公司 | 一种齿条用耐磨润滑油 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312701A (zh) * | 2014-11-14 | 2015-01-28 | 柳州聚龙科技有限公司 | 润滑油 |
| CN105385487A (zh) * | 2015-11-26 | 2016-03-09 | 杨桂望 | 一种低成本长寿命润滑油 |
-
2016
- 2016-07-28 CN CN201610603759.8A patent/CN106221879A/zh active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312701A (zh) * | 2014-11-14 | 2015-01-28 | 柳州聚龙科技有限公司 | 润滑油 |
| CN105385487A (zh) * | 2015-11-26 | 2016-03-09 | 杨桂望 | 一种低成本长寿命润滑油 |
Non-Patent Citations (1)
| Title |
|---|
| 李春风等: "膨胀石墨的表面改性及作为润滑油添加剂的摩擦学性能", 《润滑与密封》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107267266A (zh) * | 2017-07-04 | 2017-10-20 | 合肥择浚电气设备有限公司 | 一种润滑油及其制备方法 |
| CN107446682A (zh) * | 2017-09-20 | 2017-12-08 | 太仓宝达齿条有限公司 | 一种齿条用高性能水溶性润滑油 |
| CN107523394A (zh) * | 2017-09-20 | 2017-12-29 | 太仓宝达齿条有限公司 | 一种齿条用生物润滑油 |
| CN107686767A (zh) * | 2017-09-20 | 2018-02-13 | 太仓宝达齿条有限公司 | 一种齿条用耐磨润滑油 |
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