CN106167606A - A kind of PVC base modification 3D printing consumables - Google Patents
A kind of PVC base modification 3D printing consumables Download PDFInfo
- Publication number
- CN106167606A CN106167606A CN201610608645.2A CN201610608645A CN106167606A CN 106167606 A CN106167606 A CN 106167606A CN 201610608645 A CN201610608645 A CN 201610608645A CN 106167606 A CN106167606 A CN 106167606A
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- CN
- China
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- parts
- printing consumables
- base modification
- pvc base
- light trigger
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
Abstract
The present invention provides a kind of PVC base modification 3D printing consumables, it is characterised in that: include the raw material of following parts by weight,
Description
Technical field
The invention belongs to 3D printing consumables technical field, be specifically related to a kind of PVC base modification 3D printing consumables.
Background technology
It is a kind of rapid shaping technique that 3D prints, and is described as the core technology of " industrial revolution for the third time ", with conventionally manufactured
Technology is compared, and 3D prints need not previously fabricated mould, it is not necessary to remove substantial amounts of material in the fabrication process, also without going through complexity
Forging Technology can be obtained by final products, produce on can realize structure optimization, save material and save the energy.
Material is the material base that 3D prints, and is also that restricting current 3D prints the bottleneck developed.PVC (polrvinyl chloride) has
Well attribute, extremely durable, cheap, there is good chemical resistance and fire protection flame retarding characteristic, but, it is known as the world the at present
Three big common plastics PVC are but absent in 3D printed material list.
Summary of the invention
For solving above-mentioned technical problem, the invention provides a kind of PVC base modification 3D printing consumables, replicate the institute of PVC
There is determinant attribute, simultaneously good mechanical performance, there is good heat stability and antistatic property simultaneously, 3D can be solved and print
There is warpage or prints the problems such as bed adhesive capacity difference in product.
For reaching above-mentioned purpose, technical scheme is as follows: a kind of PVC base modification 3D printing consumables, its feature exists
In: include the raw material of following parts by weight,
Glass fibre polylactic resin 60～80 parts
Lubricant 6～8 parts
Heat stabilizer 12～14 parts
Antioxidant 8～12 parts
Plasticizer 10～15 parts
PAEK 14～18 parts
Light trigger 1～3 parts
Antistatic additive 0.5～1.5 parts.
In one preferred embodiment of the present invention, farther including described lubricant is stearic acid, butyl stearate, oleoyl
One in amine, ethylene bis stearamide.
In one preferred embodiment of the present invention, farther including described heat stabilizer is tribasic ceruse, dibasic
One in lead phosphate, dioctyltin.
In one preferred embodiment of the present invention, farther including described antioxidant is according to percentage by weight combination
75% (3,5 di-t-butyl 4 hydroxy phenyl) propanoic acid octadecyl and 25% dilauryl thiodipropionate.
In one preferred embodiment of the present invention, farther including described plasticizer is fatty group dibasic acid, phosphate ester
With the one in chlorinated paraffin.
In one preferred embodiment of the present invention, farther including described light trigger is light trigger 184, light trigger
369, the one in light trigger 1700.
In one preferred embodiment of the present invention, farther including described antistatic additive is quarternary ammonium salt, ethoxyquin ammonium, fat
One in fat acid esters.
The invention has the beneficial effects as follows:
The 3D printing consumables that one, the present invention obtain, replicates all determinant attributes of PVC, good mechanical performance simultaneously,
There is good heat stability and antistatic property simultaneously, 3D printed product can be solved and warpage occurs or prints bed adhesion energy
The problems such as power difference；
Two, forming the overall component of printed material, especially adding PAEK in component can improve further
The mechanical property of material, it is 5-10MPa that material stretches slight after tested, and bending strength is 2-6MPa.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described embodiment
It is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, ordinary skill
The every other embodiment that personnel are obtained under not making creative work premise, broadly falls into the scope of protection of the invention.
Embodiment one
The present embodiment discloses a kind of PVC base modification 3D printing consumables, including the raw material of following parts by weight,
Glass fibre polylactic resin 60 parts
Lubricant 6 parts
Heat stabilizer 12 parts
Antioxidant 8 parts
Plasticizer 10 parts
PAEK 14 parts
Light trigger 1 part
0.5 part of antistatic additive.
Wherein, the concrete composition of each auxiliary agent is as follows:
Described lubricant: the one in stearic acid, butyl stearate, oleamide, ethylene bis stearamide；
Described heat stabilizer: the one in tribasic ceruse, dibasic lead phosphate, dioctyltin；
Described antioxidant: according to 75% (3,5 di-t-butyl 4 hydroxy phenyl) propanoic acid ten of percentage by weight combination
Eight alcohol esters and 25% dilauryl thiodipropionate；
Described plasticizer: the one in fatty group dibasic acid, phosphate ester and chlorinated paraffin；
Described light trigger: the one in light trigger 184, light trigger 369, light trigger 1700；
Described antistatic additive: the one in quarternary ammonium salt, ethoxyquin ammonium, fatty acid ester.
Embodiment two
The present embodiment discloses a kind of PVC base modification 3D printing consumables, including the raw material of following parts by weight,
Glass fibre polylactic resin 70 parts
Lubricant 7 parts
Heat stabilizer 13 parts
Antioxidant 10 parts
Plasticizer 13 parts
PAEK 16 parts
Light trigger 2 parts
1 part of antistatic additive.
Wherein, the concrete composition of each auxiliary agent is as follows:
Described lubricant: the one in stearic acid, butyl stearate, oleamide, ethylene bis stearamide；
Described heat stabilizer: the one in tribasic ceruse, dibasic lead phosphate, dioctyltin；
Described antioxidant: according to 75% (3,5 di-t-butyl 4 hydroxy phenyl) propanoic acid ten of percentage by weight combination
Eight alcohol esters and 25% dilauryl thiodipropionate；
Described plasticizer: the one in fatty group dibasic acid, phosphate ester and chlorinated paraffin；
Described light trigger: the one in light trigger 184, light trigger 369, light trigger 1700；
Described antistatic additive: the one in quarternary ammonium salt, ethoxyquin ammonium, fatty acid ester.
Embodiment two
The present embodiment discloses a kind of PVC base modification 3D printing consumables, including the raw material of following parts by weight,
Glass fibre polylactic resin 80 parts
Lubricant 8 parts
Heat stabilizer 14 parts
Antioxidant 12 parts
Plasticizer 15 parts
PAEK 18 parts
Light trigger 3 parts
1.5 parts of antistatic additive.
Wherein, the concrete composition of each auxiliary agent is as follows:
Described lubricant: the one in stearic acid, butyl stearate, oleamide, ethylene bis stearamide；
Described heat stabilizer: the one in tribasic ceruse, dibasic lead phosphate, dioctyltin；
Described antioxidant: according to 75% (3,5 di-t-butyl 4 hydroxy phenyl) propanoic acid ten of percentage by weight combination
Eight alcohol esters and 25% dilauryl thiodipropionate；
Described plasticizer: the one in fatty group dibasic acid, phosphate ester and chlorinated paraffin；
Described light trigger: the one in light trigger 184, light trigger 369, light trigger 1700；
Described antistatic additive: the one in quarternary ammonium salt, ethoxyquin ammonium, fatty acid ester.
Described above to the disclosed embodiments, makes professional and technical personnel in the field be capable of or uses the present invention.
Multiple amendment to these embodiments will be apparent from for those skilled in the art, as defined herein
General Principle can realize without departing from the spirit or scope of the present invention in other embodiments.Therefore, the present invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and principles disclosed herein and features of novelty phase one
The widest scope caused.
Claims (7)
1. a PVC base modification 3D printing consumables, it is characterised in that: include the raw material of following parts by weight,
Glass fibre polylactic resin 60～80 parts
Lubricant 6～8 parts
Heat stabilizer 12～14 parts
Antioxidant 8～12 parts
Plasticizer 10～15 parts
PAEK 14～18 parts
Light trigger 1～3 parts
Antistatic additive 0.5～1.5 parts.
A kind of PVC base modification 3D printing consumables the most according to claim 1, it is characterised in that: described lubricant is stearic
One in acid, butyl stearate, oleamide, ethylene bis stearamide.
A kind of PVC base modification 3D printing consumables the most according to claim 1, it is characterised in that: described heat stabilizer is three
One in alkali ceruse, dibasic lead phosphate, dioctyltin.
A kind of PVC base modification 3D printing consumables the most according to claim 1, it is characterised in that: described antioxidant is for pressing
75% (3,5 di-t-butyl 4 hydroxy phenyl) propanoic acid octadecyl and 25% thio-2 acid according to percentage by weight combination
Dilauryl.
A kind of PVC base modification 3D printing consumables the most according to claim 1, it is characterised in that: described plasticizer is fat
One in race's dibasic acid ester, phosphate ester and chlorinated paraffin.
A kind of PVC base modification 3D printing consumables the most according to claim 1, it is characterised in that: described light trigger is light
One in initiator 184, light trigger 369, light trigger 1700.
A kind of PVC base modification 3D printing consumables the most according to claim 1, it is characterised in that described antistatic additive is four
One in level ammonium salt, ethoxyquin ammonium, fatty acid ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610608645.2A CN106167606A (en) | 2016-07-29 | 2016-07-29 | A kind of PVC base modification 3D printing consumables |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610608645.2A CN106167606A (en) | 2016-07-29 | 2016-07-29 | A kind of PVC base modification 3D printing consumables |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106167606A true CN106167606A (en) | 2016-11-30 |
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| CN201610608645.2A Pending CN106167606A (en) | 2016-07-29 | 2016-07-29 | A kind of PVC base modification 3D printing consumables |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109354793A (en) * | 2018-09-04 | 2019-02-19 | 浙江天原医用材料有限公司 | A kind of high-strength PVC medical material and preparation method thereof |
| CN113150330A (en) * | 2021-05-25 | 2021-07-23 | 九江市磐泰复合材料有限公司 | Preparation method of glass fiber reinforced polyvinyl chloride material |
| US12179424B2 (en) | 2020-01-09 | 2024-12-31 | Hewlett-Packard Development Company, L.P. | Three-dimensional printing with secondary antioxidants |
Citations (7)
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|---|---|---|---|---|
| JP2009062410A (en) * | 2007-09-04 | 2009-03-26 | Sekisui Seikei Ltd | Production method of polylactic acid resin sheet and production apparatus used therefor |
| US20090209695A1 (en) * | 2008-02-20 | 2009-08-20 | Ren Yu | Thermoplastic polycarbonate/polyester blend compositions with improved mechanical properties |
| CN103804863A (en) * | 2013-09-02 | 2014-05-21 | 芜湖瀚博电子科技有限公司 | A biodegradable plastic thread for 3D printing |
| CN104031304A (en) * | 2014-04-30 | 2014-09-10 | 中国科学院化学研究所 | Ultraviolet light crosslinked polymer material used for 3D printing, and preparation method and application thereof |
| CN105599302A (en) * | 2016-01-20 | 2016-05-25 | 鑫烯三维科技（上海）有限公司 | Continuous fiber fused deposition 3D (three-dimensional) printing method and application thereof |
| CN105665697A (en) * | 2016-03-11 | 2016-06-15 | 中山大学惠州研究院 | Metal or ceramic consumable item for FDM 3D printing, preparation method for metal or ceramic consumable item and finished product printing method |
| CN105670254A (en) * | 2016-02-24 | 2016-06-15 | 北京石油化工学院 | Preparation method of polylactic acid composite material used for hot-melt 3D printing |
-
2016
- 2016-07-29 CN CN201610608645.2A patent/CN106167606A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009062410A (en) * | 2007-09-04 | 2009-03-26 | Sekisui Seikei Ltd | Production method of polylactic acid resin sheet and production apparatus used therefor |
| US20090209695A1 (en) * | 2008-02-20 | 2009-08-20 | Ren Yu | Thermoplastic polycarbonate/polyester blend compositions with improved mechanical properties |
| CN103804863A (en) * | 2013-09-02 | 2014-05-21 | 芜湖瀚博电子科技有限公司 | A biodegradable plastic thread for 3D printing |
| CN104031304A (en) * | 2014-04-30 | 2014-09-10 | 中国科学院化学研究所 | Ultraviolet light crosslinked polymer material used for 3D printing, and preparation method and application thereof |
| CN105599302A (en) * | 2016-01-20 | 2016-05-25 | 鑫烯三维科技（上海）有限公司 | Continuous fiber fused deposition 3D (three-dimensional) printing method and application thereof |
| CN105670254A (en) * | 2016-02-24 | 2016-06-15 | 北京石油化工学院 | Preparation method of polylactic acid composite material used for hot-melt 3D printing |
| CN105665697A (en) * | 2016-03-11 | 2016-06-15 | 中山大学惠州研究院 | Metal or ceramic consumable item for FDM 3D printing, preparation method for metal or ceramic consumable item and finished product printing method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109354793A (en) * | 2018-09-04 | 2019-02-19 | 浙江天原医用材料有限公司 | A kind of high-strength PVC medical material and preparation method thereof |
| US12179424B2 (en) | 2020-01-09 | 2024-12-31 | Hewlett-Packard Development Company, L.P. | Three-dimensional printing with secondary antioxidants |
| CN113150330A (en) * | 2021-05-25 | 2021-07-23 | 九江市磐泰复合材料有限公司 | Preparation method of glass fiber reinforced polyvinyl chloride material |
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161130 |