CN106148006A - A kind of antidepressant joyful type liquid detergent microcapsule essence - Google Patents
A kind of antidepressant joyful type liquid detergent microcapsule essence Download PDFInfo
- Publication number
- CN106148006A CN106148006A CN201610628569.1A CN201610628569A CN106148006A CN 106148006 A CN106148006 A CN 106148006A CN 201610628569 A CN201610628569 A CN 201610628569A CN 106148006 A CN106148006 A CN 106148006A
- Authority
- CN
- China
- Prior art keywords
- essence
- fructus citri
- joyful
- liquid detergent
- microcapsule
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003094 microcapsule Substances 0.000 title claims abstract description 30
- 239000003599 detergent Substances 0.000 title claims abstract description 21
- 239000007788 liquid Substances 0.000 title claims abstract description 20
- 230000001430 anti-depressive effect Effects 0.000 title claims abstract description 11
- 239000000935 antidepressant agent Substances 0.000 title claims abstract description 11
- 229940005513 antidepressants Drugs 0.000 title claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 9
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims abstract description 9
- 239000001111 citrus aurantium l. leaf oil Substances 0.000 claims abstract description 9
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 7
- 239000012153 distilled water Substances 0.000 claims abstract description 7
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 7
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 7
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims abstract description 6
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims abstract description 6
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims abstract description 6
- 235000010262 sodium metabisulphite Nutrition 0.000 claims abstract description 6
- 240000000560 Citrus x paradisi Species 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims description 13
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- -1 Alcohol ester Chemical class 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- 238000005352 clarification Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 239000002893 slag Substances 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 12
- 239000003205 fragrance Substances 0.000 abstract description 9
- 230000002045 lasting effect Effects 0.000 abstract description 7
- 239000004744 fabric Substances 0.000 abstract description 6
- 238000005406 washing Methods 0.000 abstract description 4
- 206010006326 Breath odour Diseases 0.000 abstract description 2
- 241000207199 Citrus Species 0.000 abstract description 2
- 235000018958 Gardenia augusta Nutrition 0.000 abstract description 2
- 235000020971 citrus fruits Nutrition 0.000 abstract description 2
- 235000009508 confectionery Nutrition 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 239000000341 volatile oil Substances 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 1
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of antidepressant joyful type liquid detergent microcapsule essence, be prepared by the raw materials in: pomelo peel 50 60, Fericarpium Citri Limoniae 45 50, distilled water are appropriate, petitgrain oil 23, MDJ 1 1.2, ambrotone 3.5 4, arabic gum 0.3 0.4, deionized water are appropriate, Ethylene glycol dimethacrylate 2.5 3, Ammonium persulfate. 0.1 0.11, sodium pyrosulfite 0.13 0.14, sodium carboxymethyl cellulose 1 1.2.The present invention, by extracting Fructus Citri Limoniae and Fructus Citri grandis mixed essential oil, then mixes with petitgrain oil, MDJ, has fragrant and sweet Citrus fruital and mix with similar jasmin, coordinates the interpolation of ambrotone, and fragrance is lively, harmonious, pure and fresh, lasting；The present invention can effectively cover the bad breath distributed after base material is dissolved in water and lasting at fabric face lasting in washing process, brings pure and fresh joyful impression to people.
Description
Technical field
The present invention relates to essence technical field, particularly relate to a kind of antidepressant joyful type liquid detergent microcapsule essence.
Background technology
Daily chemical essence occupies the market share of about half as the pillar of fragrance industry, and along with economic development and society
Progressive, this ratio may proceed to rise, and along with the raising of living standards of the people, consumer is more and more higher to the requirement of detergent,
Not only want to the medicated clothing after washing and can leave lasting pure and fresh joyful fragrance, but also wish that the products such as liquid detergent have
Other additional benefit such as antibacterial, sterilization, skin protection.This is accomplished by the essence adding in detergent carrying out constantly modification and grinding
Send out.Typically essence high volatility, rate of release is too fast, easily occurs waste during storing, transporting and use,
Or the odor type caused that goes bad changes and becomes sour, it is impossible to meet the requirement of consumer, restrict its development.Microcapsule technology is can be effective
Improve these problems so that spice has longer fragrance remaining time, more preferable washing fastness and stability etc..But traditional conjunction
Become macromolecule wall material to have polyureas, polyester, melamine resin and polyacrylic etc., form microcapsule wall material utilizing synthesis macromolecule
During the monomer that often uses, cross-linking agent etc. such as toluene di-isocyanate(TDI), glutaraldehyde, formaldehyde etc., all there is certain toxicity, these
Poisonous reaction residue makes to synthesize the macromolecule microcapsule for wall material
Use be restricted.Therefore, take nontoxic and to have functional monomer synthetic environment-friendly wall material be microcapsule science
The target that worker pursues always.
" preparation of polymethyl methacrylate glycol ester wall material microcapsule and sign thereof " literary composition uses radical polymerization
Method high polymer polymethyl methacrylate that Ethylene glycol dimethacrylate monomer is formed by interface radical polymerization
Glycol ester is the microcapsule of wall material, has good heat stability, and wall material is nontoxic, is suitable for personal care articles and field of medicaments
It is with a wide range of applications.But the microcapsule essence liquid detergent to be added to made as the wall material of essence due to microcapsule
Preparation in, the density of microcapsule essence and liquid detergent matrix have difference, cause product to be layered, suspended uneven.This is accomplished by
Microcapsule wall material is modified, enables to meet the demand of liquid detergent flavouring.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of antidepressant joyful type micro-glue of liquid detergent
Capsule essence.
The present invention is achieved by the following technical solutions:
A kind of antidepressant joyful type liquid detergent microcapsule essence, is prepared by the raw materials in: pomelo peel 50-60, lemon
Lemon skin 45-50, distilled water are appropriate, petitgrain oil 2-3, MDJ 1-1.2, ambrotone 3.5-4, arabic gum 0.3-
0.4, deionized water is appropriate, Ethylene glycol dimethacrylate 2.5-3, Ammonium persulfate. 0.1-0.11, sodium pyrosulfite 0.13-
0.14, sodium carboxymethyl cellulose 1-1.2.
Described a kind of antidepressant joyful type liquid detergent microcapsule essence, is made up of step in detail below:
(1) white of pomelo peel, Fericarpium Citri Limoniae is removed, then become the fritter of 4-5mm by crusher in crushing after, put into screw press
Machine squeezes, after making squeezing with appropriate distilled water spray peel juice flow out, peel juice is filtered, removes residual
Slag, then will filter after peel juice put in subsider stand, after layering will clarification after quintessence oil overflow, overflow is gone out
Coarse-fine oil stands 2-3 days at 3-5 DEG C, removes precipitate and the moisture of bottom, and upper strata quintessence oil anhydrous calcium chloride removes further
Remove the moisture of residual, obtain Fructus Citri Limoniae Fructus Citri grandis quintessence oil；
(2) the Fructus Citri Limoniae Fructus Citri grandis quintessence oil that step (1) prepares is mixed to form mixed with petitgrain oil, MDJ, ambrotone
Blending essence is stand-by；Then will add the deionized water of 100-120 times amount in arabic gum, warming while stirring is straight to 50-60 DEG C
It is completely dissolved to arabic gum, forms solution；Mixing essence is mixed with above-mentioned solution, puts in effective dispersing machine with 6000-
VELOCITY SHEAR 3-5 minute of 7000 revs/min, forms mixing essence emulsion；
(3) the mixing essence emulsion of step (2) put in reactor and be passed through nitrogen protection, adding dimethacrylate second two
Alcohol ester, is stirring evenly and then adding into the sodium pyrosulfite being dissolved in 10-12 times amount deionized water, and under room temperature, dropping is dissolved in 8-10 times amount
The Ammonium persulfate. of ionized water, controlling time for adding is 30 minutes, is warming up to 50-60 DEG C, and insulation reaction 1.5-2 hour is cooled to
Room temperature, obtains microcapsule essence；
(4) by the deionized water adding 3-5 times amount in sodium carboxymethyl cellulose, stir to being completely dissolved formation clear solution,
By the surface of the microcapsule essence that spray solution obtains in step (3), finally it is dried at 50-60 DEG C in vacuum drying oven,
Obtain the present invention.
The invention have the advantage that Ethylene glycol dimethacrylate self-crosslinking is formed the three of densification by the present invention by reaction
Dimension net polymer is coated on mixing essence top layer and forms microcapsule essence, and the microcapsule essence size dimension made distribution is all
Even, form is full, few gathering, has good heat stability and slow-releasing so that fragrance persistently discharges；By at microcapsule
One layer of carboxymethylcellulose sodium solution of essence surface sprinkling, it is possible to the microcapsule essence made is suspended all in liquid detergent
Even, moreover it is possible to act on fabric face be prevented from fabric repeat absorb dust.Product safety environment-protecting asepsis of the present invention, adds to and washes
In clothing liquid, laundry processes enter fabric and remains, then slowly discharging fragrance by rubbing, make fabric have and hold
Long fragrance.
The present invention, by extracting Fructus Citri Limoniae and Fructus Citri grandis mixed essential oil, then mixes with petitgrain oil, MDJ, tool
Having fragrant and sweet Citrus fruital to mix with similar jasmin, coordinate the interpolation of ambrotone, fragrance is lively, harmonious, pure and fresh, lasting；
The base material feature breath of essence of the present invention and liquid detergent is coordinated easily, and can effectively cover after base material is dissolved in water in washing process
The bad breath that distributes and lasting at fabric face lasting, brings pure and fresh joyful impression to people.
Detailed description of the invention
A kind of antidepressant joyful type liquid detergent microcapsule essence, is made up of the raw material of following weight portion (kilogram): Fructus Citri grandis
Skin 50, Fericarpium Citri Limoniae 45, distilled water are appropriate, petitgrain oil 2, MDJ 1, ambrotone 3.5, arabic gum 0.3, go from
Sub-water is appropriate, Ethylene glycol dimethacrylate 2.5, Ammonium persulfate. 0.1, sodium pyrosulfite 0.13, sodium carboxymethyl cellulose 1.
Described a kind of antidepressant joyful type liquid detergent microcapsule essence, is made up of step in detail below:
(1) white of pomelo peel, Fericarpium Citri Limoniae is removed, then become the fritter of 4mm by crusher in crushing after, put into pressafiner
In squeeze, after making squeezing with appropriate distilled water spray peel juice flow out, peel juice is filtered, removes residue,
Peel juice after filtering again is put in subsider and is stood, and is overflowed by the quintessence oil after clarification after layering, and overflow gone out is thick
Quintessence oil stands 2 days at 3 DEG C, removes precipitate and the moisture of bottom, and upper strata quintessence oil anhydrous calcium chloride removes residual further
Moisture, obtain Fructus Citri Limoniae Fructus Citri grandis quintessence oil；
(2) the Fructus Citri Limoniae Fructus Citri grandis quintessence oil that step (1) prepares is mixed to form mixed with petitgrain oil, MDJ, ambrotone
Blending essence is stand-by；Then will add the deionized water of 100 times amount in arabic gum, warming while stirring to 50 DEG C is until Arab
Glue is completely dissolved, and forms solution；Mixing essence is mixed with above-mentioned solution, puts into the speed with 6000 revs/min in effective dispersing machine
Degree is sheared 3 minutes, forms mixing essence emulsion；
(3) the mixing essence emulsion of step (2) put in reactor and be passed through nitrogen protection, adding dimethacrylate second two
Alcohol ester, is stirring evenly and then adding into the sodium pyrosulfite being dissolved in 10 times amount deionized waters, and under room temperature, dropping is dissolved in 8 times amount deionized waters
Ammonium persulfate., control time for adding be 30 minutes, be warming up to 50 DEG C, insulation reaction 1.5 hours, be cooled to room temperature, obtain micro-
Capsule essence；
(4) by the deionized water adding 3 times amount in sodium carboxymethyl cellulose, stirring, will to being completely dissolved formation clear solution
The surface of the microcapsule essence that spray solution obtains in step (3), is finally dried in vacuum drying oven at 50 DEG C, obtains this
Invention.
Adding in liquid detergent by product of the present invention, consumption is 0.5%, still has after test liquid detergent is placed 12 months
Fragrance, and essence residual quantity is still greater than 10%.
Claims (2)
1. an antidepressant joyful type liquid detergent microcapsule essence, it is characterised in that be prepared by the raw materials in: Fructus Citri grandis
Sub-skin 50-60, Fericarpium Citri Limoniae 45-50, distilled water are appropriate, petitgrain oil 2-3, MDJ 1-1.2, ambrotone 3.5-4,
Arabic gum 0.3-0.4, deionized water are appropriate, Ethylene glycol dimethacrylate 2.5-3, Ammonium persulfate. 0.1-0.11, Jiao Ya
Sodium sulfate 0.13-0.14, sodium carboxymethyl cellulose 1-1.2.
A kind of antidepressant joyful type liquid detergent microcapsule essence, it is characterised in that by following tool
Body step is made:
(1) white of pomelo peel, Fericarpium Citri Limoniae is removed, then become the fritter of 4-5mm by crusher in crushing after, put into screw press
Machine squeezes, after making squeezing with appropriate distilled water spray peel juice flow out, peel juice is filtered, removes residual
Slag, then will filter after peel juice put in subsider stand, after layering will clarification after quintessence oil overflow, overflow is gone out
Coarse-fine oil stands 2-3 days at 3-5 DEG C, removes precipitate and the moisture of bottom, and upper strata quintessence oil anhydrous calcium chloride removes further
Remove the moisture of residual, obtain Fructus Citri Limoniae Fructus Citri grandis quintessence oil；
(2) the Fructus Citri Limoniae Fructus Citri grandis quintessence oil that step (1) prepares is mixed to form mixed with petitgrain oil, MDJ, ambrotone
Blending essence is stand-by；Then will add the deionized water of 100-120 times amount in arabic gum, warming while stirring is straight to 50-60 DEG C
It is completely dissolved to arabic gum, forms solution；Mixing essence is mixed with above-mentioned solution, puts in effective dispersing machine with 6000-
VELOCITY SHEAR 3-5 minute of 7000 revs/min, forms mixing essence emulsion；
(3) the mixing essence emulsion of step (2) put in reactor and be passed through nitrogen protection, adding dimethacrylate second two
Alcohol ester, is stirring evenly and then adding into the sodium pyrosulfite being dissolved in 10-12 times amount deionized water, and under room temperature, dropping is dissolved in 8-10 times amount
The Ammonium persulfate. of ionized water, controlling time for adding is 30 minutes, is warming up to 50-60 DEG C, and insulation reaction 1.5-2 hour is cooled to
Room temperature, obtains microcapsule essence；
(4) by the deionized water adding 3-5 times amount in sodium carboxymethyl cellulose, stir to being completely dissolved formation clear solution,
By the surface of the microcapsule essence that spray solution obtains in step (3), finally it is dried at 50-60 DEG C in vacuum drying oven,
Obtain the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610628569.1A CN106148006A (en) | 2016-08-03 | 2016-08-03 | A kind of antidepressant joyful type liquid detergent microcapsule essence |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610628569.1A CN106148006A (en) | 2016-08-03 | 2016-08-03 | A kind of antidepressant joyful type liquid detergent microcapsule essence |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106148006A true CN106148006A (en) | 2016-11-23 |
Family
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| CN201610628569.1A Pending CN106148006A (en) | 2016-08-03 | 2016-08-03 | A kind of antidepressant joyful type liquid detergent microcapsule essence |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108589279A (en) * | 2018-04-30 | 2018-09-28 | 安徽恒益纺织科技有限公司 | A kind of fumet for textile fabric |
| CN108755113A (en) * | 2018-04-30 | 2018-11-06 | 安徽恒益纺织科技有限公司 | A kind of fragrant care agent for textile fabric |
| CN110291180A (en) * | 2017-02-13 | 2019-09-27 | 荷兰联合利华有限公司 | laundry composition |
| CN110903904A (en) * | 2019-12-20 | 2020-03-24 | 厦门琥珀日化科技股份有限公司 | Composite flower fragrance microcapsule essence and preparation method thereof |
| US11180721B2 (en) | 2017-02-13 | 2021-11-23 | Conopco, Inc. | Ancillary laundry composition |
| US11208617B2 (en) | 2017-02-13 | 2021-12-28 | Conopco, Inc. | Laundry composition additive |
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| CN102776071A (en) * | 2012-08-15 | 2012-11-14 | 上海应用技术学院 | Transparent microcapsule flavoring jasmine essence and preparation method thereof |
| CN102776069A (en) * | 2012-08-15 | 2012-11-14 | 上海应用技术学院 | Paste microcapsule jasmine essence and preparation method thereof |
| CN105062713A (en) * | 2015-07-23 | 2015-11-18 | 安徽省三环纸业集团香料科技发展有限公司 | Spice used for mosquito repellent detergent powder and preparation method for spice |
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| CN102776071A (en) * | 2012-08-15 | 2012-11-14 | 上海应用技术学院 | Transparent microcapsule flavoring jasmine essence and preparation method thereof |
| CN102776069A (en) * | 2012-08-15 | 2012-11-14 | 上海应用技术学院 | Paste microcapsule jasmine essence and preparation method thereof |
| CN105062713A (en) * | 2015-07-23 | 2015-11-18 | 安徽省三环纸业集团香料科技发展有限公司 | Spice used for mosquito repellent detergent powder and preparation method for spice |
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| US11180721B2 (en) | 2017-02-13 | 2021-11-23 | Conopco, Inc. | Ancillary laundry composition |
| US11208617B2 (en) | 2017-02-13 | 2021-12-28 | Conopco, Inc. | Laundry composition additive |
| CN108589279A (en) * | 2018-04-30 | 2018-09-28 | 安徽恒益纺织科技有限公司 | A kind of fumet for textile fabric |
| CN108755113A (en) * | 2018-04-30 | 2018-11-06 | 安徽恒益纺织科技有限公司 | A kind of fragrant care agent for textile fabric |
| CN110903904A (en) * | 2019-12-20 | 2020-03-24 | 厦门琥珀日化科技股份有限公司 | Composite flower fragrance microcapsule essence and preparation method thereof |
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