CN106137826A - A kind of cleaning skin care makeup removing liquid - Google Patents
A kind of cleaning skin care makeup removing liquid Download PDFInfo
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- CN106137826A CN106137826A CN201610508263.2A CN201610508263A CN106137826A CN 106137826 A CN106137826 A CN 106137826A CN 201610508263 A CN201610508263 A CN 201610508263A CN 106137826 A CN106137826 A CN 106137826A
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- China
- Prior art keywords
- makeup removing
- removing liquid
- ester
- poly
- skin care
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- 239000007788 liquid Substances 0.000 title claims abstract description 41
- 238000004140 cleaning Methods 0.000 title claims abstract description 27
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims abstract description 12
- 229920000903 polyhydroxyalkanoate Polymers 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000008495 Chrysanthemum leucanthemum Nutrition 0.000 claims abstract description 8
- 235000000604 Chrysanthemum parthenium Nutrition 0.000 claims abstract description 8
- 102000008186 Collagen Human genes 0.000 claims abstract description 8
- 108010035532 Collagen Proteins 0.000 claims abstract description 8
- 229920001436 collagen Polymers 0.000 claims abstract description 8
- 235000008384 feverfew Nutrition 0.000 claims abstract description 8
- 239000003921 oil Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000000341 volatile oil Substances 0.000 claims abstract description 8
- 229920002385 Sodium hyaluronate Polymers 0.000 claims abstract description 7
- 229930003427 Vitamin E Natural products 0.000 claims abstract description 7
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims abstract description 7
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims abstract description 7
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims abstract description 7
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940010747 sodium hyaluronate Drugs 0.000 claims abstract description 7
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 claims abstract description 7
- 229940046009 vitamin E Drugs 0.000 claims abstract description 7
- 235000019165 vitamin E Nutrition 0.000 claims abstract description 7
- 239000011709 vitamin E Substances 0.000 claims abstract description 7
- 239000000811 xylitol Substances 0.000 claims abstract description 7
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims abstract description 7
- 229960002675 xylitol Drugs 0.000 claims abstract description 7
- 235000010447 xylitol Nutrition 0.000 claims abstract description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 5
- 239000010696 ester oil Substances 0.000 claims abstract description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 3
- -1 Hydroxy sulfo lycine Chemical compound 0.000 claims description 17
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 14
- 229920000070 poly-3-hydroxybutyrate Polymers 0.000 claims description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- 239000000194 fatty acid Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 7
- 229940070710 valerate Drugs 0.000 claims description 7
- OBNCKNCVKJNDBV-UHFFFAOYSA-N ethyl butyrate Chemical compound CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 claims description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000008118 PEG 6000 Substances 0.000 claims description 4
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 claims description 4
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 229960003237 betaine Drugs 0.000 claims description 3
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 240000004460 Tanacetum coccineum Species 0.000 claims 1
- QCCKPZOPTXCJPL-UHFFFAOYSA-N dodecyl(dimethyl)azanium;hydroxide Chemical compound [OH-].CCCCCCCCCCCC[NH+](C)C QCCKPZOPTXCJPL-UHFFFAOYSA-N 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 244000192528 Chrysanthemum parthenium Species 0.000 abstract description 7
- 239000002537 cosmetic Substances 0.000 abstract description 6
- 239000011148 porous material Substances 0.000 abstract description 3
- 235000020737 peppermint extract Nutrition 0.000 abstract description 2
- 230000001835 salubrious effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 6
- 230000003020 moisturizing effect Effects 0.000 description 3
- 239000004006 olive oil Substances 0.000 description 3
- 235000008390 olive oil Nutrition 0.000 description 3
- 235000019486 Sunflower oil Nutrition 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000037394 skin elasticity Effects 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000002600 sunflower oil Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 206010020649 Hyperkeratosis Diseases 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 208000001126 Keratosis Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 208000030961 allergic reaction Diseases 0.000 description 1
- 230000037336 dry skin Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229940094952 green tea extract Drugs 0.000 description 1
- 235000020688 green tea extract Nutrition 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/591—Mixtures of compounds not provided for by any of the codes A61K2800/592 - A61K2800/596
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Engineering & Computer Science (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Biotechnology (AREA)
- Gerontology & Geriatric Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
Abstract
A kind of cleaning skin care makeup removing liquid, belongs to cosmetic field.The makeup removing raw material of liquid and mass percent thereof be: betaines surfactant: 1 ~ 3%, ester oil: 3 ~ 10%, grape-kernel oil: 10 ~ 15%, propane diols: 5 ~ 8%, polyethylene glycol: 0.5 ~ 1.0%, polyhydroxyalkanoate: 20 ~ 30%, Sodium Hyaluronate: 0.05 ~ 2.0%, Hydrolyzed Collagen: 2 ~ 5%, feverfew essential oil: 0.2 ~ 0.6%, palma extract: 1 ~ 2%, xylitol: 10 ~ 15%, vitamin E: 2 ~ 3%, balance of water.This makeup removing liquid can effectively in removal color make-up Peppermint Extract residue, after makeup removing, face non-greasy not tight, salubrious, can deep layer cleaning, disintegrate pore bottom dirt.
Description
Technical field
The invention belongs to cosmetic field, be specifically related to a kind of cleaning skin care makeup removing liquid.
Background technology
Make up particularly significant to each Ms, and prior thing is removed ornaments and formal dress exactly, only correct makeup removing, Cai Nengrang
The state that skin is kept fit, if it is improper to remove ornaments and formal dress, remains in the cosmetics on skin and will injure skin, cause skin dark
Huang, is dried and pore is thick, and the makeup removing liquid of a practicality becomes the indispensable emperorship of each beautiful woman.
At present, existing makeup removing species has: makeup removing liquid, makeup removing breast, makeup remover, makeup removing paper etc., and color make-up is unloaded by makeup remover
Adornment effect is very excellent, but after makeup removing, the oily matter of face residual allows people feel clouding, it is necessary to secondary cleans；Makeup removing
Breast is also a kind of makeup removing kind popular at present, but it is general to the removal effectiveness comparison of color make-up.Also have some makeup removings
Liquid, after remove ornaments and formal dress DeGrain, or makeup removing, sensation face is tight, feels clouding, have sticky after lacking moisture or makeup removing
Sense.This all illustrates to provide a kind of cleaning skin care makeup removing liquid very urgent.
Content of the invention
The present invention provides a kind of cleaning skin care makeup removing liquid, residue that can effectively in removal color make-up Peppermint Extract,
After makeup removing, face non-greasy not tight, salubrious, can deep layer cleaning, disintegrate pore bottom dirt.
A kind of cleaning skin care makeup removing liquid, raw material and mass percent thereof are as follows:
Betaines surfactant: 1 ~ 3%
Ester oil: 3 ~ 10%
Grape-kernel oil: 10 ~ 15%
Propane diols: 5 ~ 8%
Polyethylene glycol: 0.5 ~ 1.0%
Polyhydroxyalkanoate: 20 ~ 30%
Sodium Hyaluronate: 0.05 ~ 2.0%
Hydrolyzed Collagen: 2 ~ 5%
Feverfew essential oil: 0.2 ~ 0.6%
Palma extract: 1 ~ 2%
Xylitol: 10 ~ 15%
Vitamin E: 2 ~ 3%
Balance of water.Grape-kernel oil in formula serves the effect of moisturizing skin care, it is to avoid the makeup removing wound to keratoderma for the liquid
Evil, Hydrolyzed Collagen is conducive to recovering skin elasticity and cytothesis, and feverfew essential oil and palma extract are to skin table
Face cosmetics and the thorough cleaning of greasy dirt, dirt etc..The makeup removing liquid of the present invention takes when using and in the centre of the palm gently rubs a little, then be applied to face
Upper massage 1-2 minute, then add little water continuation massage, can realize to facial makeup removing cleaning.
As preferably, described glycine betaine is cocamidopropyl propyl amide hydroxy sulfo lycine, empgen BB, dodecane
Base dimethyl betaine, lauroyl amido CAB.
As preferably, ester oil is containing the one in the fatty acid ester that carbon number is 20 ~ 25 or fatty acid triglycercide,
It is preferably soybean oil, sunflower oil, the one in olive oil.
As preferably, polyethylene glycol is PEG-4000 or PEG-6000；
As preferably, described polyhydroxyalkanoate is the poly-carboxylic fatty acid esters using modifying agent to be modified, modifying agent
Mass ratio with poly-carboxylic fatty acid esters is 0.01 ~ 0.6:1, and described modifying agent is maleic anhydride, acrylic acid or acrylic acid first
One in ester.
As preferably, described polyhydroxyalkanoate is poly butyric ester, poly-hydroxyl valerate, poly-hydroxycaproic acid
Ester, poly-(3-hydroxybutyrate ester-co-3-hydroxyl valerate) (PHBV), poly-(3-hydroxybutyrate ester-co-4-butyric ester) (P
(3HB-co-4HB) one) or in the copolymer of poly-3-hydroxybutyrate ester-co-3-hydroxycaproic ester.
As preferably, the modification procedure of described polyhydroxyalkanoate is: protect reactor inflated with nitrogen, by poly-hydroxyl
Fatty acid ester is put in reactor, adds ethanol, at 30 ~ 60 DEG C, adds in maleic anhydride, acrylic acid or methyl acrylate
Kind, radiate with gamma rays, stir 5 ~ 12h, after reaction terminates, product is separated, after being dried, obtain the poly-hydroxyl of modification
Fatty acid ester.Amount of radiation is generally 5～200kGy.Use the makeup removing liquid that modified polyhydroxyalkanoate is made, quality
Fine and smooth uniform, mix more preferably uniform with water, clean-up performance is preferable, additionally, hydrophobic performance strengthens, draws facial oiliness color make-up effect
Substantially.
A kind of cleaning skin care makeup removing liquid of the present invention, compared to prior art, has the advantage that
1. after in order to prevent makeup removing, the grease removal that skin is originally had, cause dry skin tight, the makeup removing liquid of the present invention has
Moisturizing, the function of lock water, can effectively prevent moisture loss；
2. the makeup removing liquid of the present invention can promote fibrous bud cell disintegration, protects skin skin corium；
3. the makeup removing liquid not harmful components such as spirituosity, preservative of the present invention, fool proof to skin；
4. the makeup removing liquid of the present invention can play moisturizing, strengthens skin elasticity, the effect to Green Tea Extract, thus reaches to strengthen skin
The effect of defence capability.
5. the makeup removing liquid of the present invention can effectively absorb the grease of skin secretion, after makeup removing, skin refreshing, non-greasy.
Specific implementation method
In conjunction with embodiment, the present invention is described further, but is not the restriction to protection domain.
In the present invention, if not refering in particular to, all of part, percentage are unit of weight, the equipment being used and raw material etc.
It is all commercially available or commonly used in the art.Method in following embodiment, if no special instructions, is the normal of this area
Rule method.
Embodiment 1
A kind of cleaning skin care makeup removing liquid, raw material and mass percent thereof are as follows:
Cocamidopropyl propyl amide hydroxy sulfo lycine: 2%
Soybean oil: 10%
Grape-kernel oil: 12%
Propane diols: 8%
PEG-6000:0.8%
Modifying poly butyric ester: 20%
Sodium Hyaluronate: 1.0%
Hydrolyzed Collagen: 3%
Feverfew essential oil: 0.5%
Palma extract: 2%
Xylitol: 10%
Vitamin E: 3%
Balance of water.
Wherein, modifying poly butyric ester is to use following method modification to obtain: protect reactor inflated with nitrogen, by poly-hydroxyl
Base butyrate is put in reactor, adds ethanol, makes system temperature rise to 60 DEG C, adds maleic anhydride, maleic anhydride with poly-
The mass ratio of butyric ester is 0.6:1, radiates with gamma rays, stirs 10h, after reaction terminates, separates product, dry
Obtaining modifying agent after dry is maleic anhydride modified poly butyric ester.
Embodiment 2
A kind of cleaning skin care makeup removing liquid, raw material and mass percent thereof are as follows:
Lauroyl amido CAB: 1%
Olive oil: 10%
Grape-kernel oil: 15%
Propane diols: 8%
PEG-4000:0.5%
Acrylic acid modified poly-(3-hydroxybutyrate ester-co-3-hydroxyl valerate) (PHBV): 30%
Sodium Hyaluronate: 0.05%
Hydrolyzed Collagen: 5%
Feverfew essential oil: 0.6%
Palma extract: 2%
Xylitol: 10%
Vitamin E: 3%
Balance of water.
The method of modifying of acrylic acid modified poly-(3-hydroxybutyrate ester-co-3-hydroxyl valerate) is: by reactor nitrogen charging
PHBV is put in reactor by gas shielded, adds ethanol, and system adds acrylic acid after being warming up to 60 DEG C, acrylic acid is with PHBV's
Mass ratio is 0.01:1, radiates with gamma rays, stirs 10h, after reaction terminates, separates product, obtains third after being dried
Olefin(e) acid modified poly-(3-hydroxybutyrate ester-co-3-hydroxyl valerate).
Embodiment 3
A kind of cleaning skin care makeup removing liquid, raw material and mass percent thereof are as follows:
Empgen BB: 3%
Sunflower oil: 3%
Grape-kernel oil: 12%
Propane diols: 8%
PEG-6000:0.5%
Methyl acrylate modified poly-(3-hydroxybutyrate ester-co-4-butyric ester) (P (3HB-co-4HB)): 20%
Sodium Hyaluronate: 2.0%
Hydrolyzed Collagen: 5%
Feverfew essential oil: 0.2%
Palma extract: 1%
Xylitol: 15%
Vitamin E: 2%
Balance of water.
The method of modifying of methyl acrylate modified poly-(3-hydroxybutyrate ester-co-4-butyric ester) is: by reactor
Inflated with nitrogen is protected, and puts in reactor by P (3HB-co-4HB), adds ethanol, and system adds acrylic acid first after being warming up to 60 DEG C
Ester, methyl acrylate is 0.5:1 with the mass ratio of P (3HB-co-4HB), radiates with gamma rays, stirs 10h, reaction knot
Product is separated by Shu Hou, obtains methyl acrylate modified poly-(3-hydroxybutyrate ester-co-4-butyric ester) after being dried.
Embodiment 4
A kind of cleaning skin care makeup removing liquid, raw material and mass percent thereof are as follows:
Lauroyl amido CAB: 1%
Olive oil: 10%
Grape-kernel oil: 15%
Propane diols: 8%
PEG-4000:0.5%
PHBV:30%
Sodium Hyaluronate: 0.05%
Hydrolyzed Collagen: 5%
Feverfew essential oil: 0.6%
Palma extract: 2%
Xylitol: 10%
Vitamin E: 3%
Balance of water.
After tested, with the makeup removing liquid of the present embodiment, after makeup removing, skin is not tight, flexible.
For verification the verifying results, the makeup removing liquid preparing above-described embodiment carries out effect assessment, and the method for employing is: right after cosmetic
The cleaning effect evaluation of color make-up and skin-tolerant and sensitizability are studied.
Study at 50 Ms volunteer's faces, by cotton pads, dip makeup removing liquid, gently smear in cosmetic part, stop
After 5s, carry out wiping gently.
1. according to evaluation to the makeup removing cleaning effect evaluation to color make-up for the liquid
Excellent: in 50, more than 40 evaluation makeup removing liquid are good to the cleaning effect of color make-up
Good: in 50,30 ~ 39 evaluation makeup removing liquid are good to the cleaning effect of color make-up
Can: in 50,20 ~ 29 evaluation makeup removing liquid are good to the cleaning effect of color make-up
Difference: in 50,20 ~ 29 evaluation makeup removing liquid are good to the cleaning effect of color make-up
2. skin-tolerant and sensitizability research
By Marzulli-Maibach method, studying at 50 Ms volunteer's faces, obtaining SI, data are shown in
Table 1.
Table 1
The above results proves, the makeup removing liquid temperature of the present invention and non-stimulated, and makeup removing cleannes are higher, are not likely to produce allergic reaction.
Embodiment described above is the one preferably scheme of the present invention, not makees the present invention any pro forma
Limit, on the premise of without departing from technical scheme described in claim, also have other variant and remodeling.
Claims (7)
1. a cleaning skin care makeup removing liquid, it is characterised in that raw material and mass percent thereof are as follows:
Betaines surfactant: 1 ~ 3%
Ester oil: 3 ~ 10%
Grape-kernel oil: 10 ~ 15%
Propane diols: 5 ~ 8%
Polyethylene glycol: 0.5 ~ 1.0%
Polyhydroxyalkanoate: 20 ~ 30%
Sodium Hyaluronate: 0.05 ~ 2.0%
Hydrolyzed Collagen: 2 ~ 5%
Feverfew essential oil: 0.2 ~ 0.6%
Palma extract: 1 ~ 2%
Xylitol: 10 ~ 15%
Vitamin E: 2 ~ 3%
Balance of water.
2. cleaning skin care makeup removing liquid according to claim 1, it is characterised in that described glycine betaine is cocamidopropyl propyl amide
Hydroxy sulfo lycine, empgen BB, dodecyldimethylammonium hydroxide inner salt, lauroyl amido CAB.
3. cleaning skin care makeup removing liquid according to claim 1, it is characterised in that ester oil is for being 20 ~ 25 containing carbon number
Fatty acid ester or fatty acid triglycercide in one.
4. cleaning skin care makeup removing liquid according to claim 1, it is characterised in that polyethylene glycol is PEG-4000 or PEG-
6000。
5. cleaning skin care makeup removing liquid according to claim 1, it is characterised in that described polyhydroxyalkanoate is to use
The poly-carboxylic fatty acid esters that modifying agent is modified, modifying agent is 0.01 ~ 0.6:1 with the mass ratio of poly-carboxylic fatty acid esters, institute
The modifying agent stated is the one in maleic anhydride, acrylic acid or methyl acrylate.
6. clean skin care makeup removing liquid according to claim 1 or 5, it is characterised in that described polyhydroxyalkanoate is
Poly butyric ester, poly-hydroxyl valerate, poly-hydroxycaproic ester, poly-(3-hydroxybutyrate ester-co-3-hydroxyl valerate)
(PHBV), poly-(3-hydroxybutyrate ester-co-4-butyric ester) (P (3HB-co-4HB)) or poly-3-hydroxybutyrate ester-co-
One in the copolymer of 3-hydroxycaproic ester.
7. clean skin care makeup removing liquid according to claim 1 or 5, it is characterised in that described polyhydroxyalkanoate
Modification procedure is: protects reactor inflated with nitrogen, puts into polyhydroxyalkanoate in reactor, adds ethanol, 30 ~ 60
DEG C, add the one in maleic anhydride, acrylic acid or methyl acrylate, radiate with gamma rays, stir 5 ~ 12h, reaction
After end, product is separated, after being dried, obtain the polyhydroxyalkanoate of modification.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610508263.2A CN106137826A (en) | 2016-07-01 | 2016-07-01 | A kind of cleaning skin care makeup removing liquid |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610508263.2A CN106137826A (en) | 2016-07-01 | 2016-07-01 | A kind of cleaning skin care makeup removing liquid |
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| CN106137826A true CN106137826A (en) | 2016-11-23 |
Family
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| CN114501993A (en) * | 2019-08-31 | 2022-05-13 | 尤尼菲尔克斯国际有限公司 | Biostimulants for treating plants and/or plant seeds |
| CN117257690A (en) * | 2023-11-10 | 2023-12-22 | 浙江百姿化妆品股份有限公司 | Skin-friendly cleansing water and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106580748A (en) * | 2016-12-24 | 2017-04-26 | 叶宗瑞 | Skincare makeup remover and preparation method thereof |
| CN107149565A (en) * | 2017-05-23 | 2017-09-12 | 邓子坚 | A kind of foam make up remover |
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| CN117257690A (en) * | 2023-11-10 | 2023-12-22 | 浙江百姿化妆品股份有限公司 | Skin-friendly cleansing water and preparation method thereof |
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