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CN106115813A - A kind of chemical engineering sewage intensive treatment agent and its preparation method and application - Google Patents

A kind of chemical engineering sewage intensive treatment agent and its preparation method and application Download PDF

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Publication number
CN106115813A
CN106115813A CN201610619053.0A CN201610619053A CN106115813A CN 106115813 A CN106115813 A CN 106115813A CN 201610619053 A CN201610619053 A CN 201610619053A CN 106115813 A CN106115813 A CN 106115813A
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CN
China
Prior art keywords
parts
triterpene saponin
chemical engineering
metakaolin
engineering sewage
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Pending
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CN201610619053.0A
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Chinese (zh)
Inventor
周圣聪
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Hefei Wisdom Longtuteng Intellectual Property Co Ltd
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Individual
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Priority to CN201610619053.0A priority Critical patent/CN106115813A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Biological Wastes In General (AREA)
  • Activated Sludge Processes (AREA)

Abstract

The invention discloses a kind of chemical engineering sewage intensive treatment agent and its preparation method and application, this inorganic agent is made up of according to the raw material of weight portion following: Methyl Hydrogen Polysiloxane Fluid 10 18 parts, dioctyl phthalate 15 parts, cellulose ether 15 parts, metakaolin 22 30 parts, triterpene saponin 5 12 parts.Being processed with metakaolin Hybrid Heating by the triterpene saponin solution of preparation, heat treated obtains pretreatment material the most under nitrogen atmosphere;By Methyl Hydrogen Polysiloxane Fluid and cellulose ether Hybrid Heating, then inserting in pretreatment material, heated and stirred processes under nitrogen atmosphere, adds dioctyl phthalate stir process and get final product.The present invention is used for processing chemical engineering sewage, processing speed is fast, usage amount is few, can efficiently remove the float in sewage, the turbid descending, decolouring, limpid water quality, effectively remove COD, the BOD in sewage and Organic substance, the inorganic agent after process is prone to remove, do not result in secondary pollution, energy recycling, production cost is low, is suitable to large-scale production.

Description

A kind of chemical engineering sewage intensive treatment agent and its preparation method and application
Technical field
The present invention relates to technical field of sewage, specifically a kind of chemical engineering sewage intensive treatment agent and preparation method thereof and Application.
Background technology
Chemical plant as using water rich and influential family, year fresh water consumption be generally millions of cubic meter, the recycling rate of waterused of water is low, with Time the millions of cubic meter of externally discharged waste water, not only waste great lot of water resources, also result in environmental pollution, and the shortage of water resource is the most right The production of these water for industrial uses rich and influential family threatens.The waste water produced in chemical products production process shows themselves in that discharge capacity is big, malicious Property big, organic concentration is high, salinity is high, colourity is high, difficult degradation compounds content is high, difficulty of governance is big, but simultaneously in waste water Also contain many available resources, and membrane technology as new and high technology in the production and processing, energy-saving and cost-reducing and clear of chemical field The aspects such as clean production play important.The topmost feature of chemical engineering sewage is: water quality and quantity changes greatly, and B/C ratio is low, biodegradability Difference.PH value mostly is highly acid or strong basicity, therefore intractability is relatively big, processes chemical engineering sewage own through becoming global problem.A lot After chemical engineering sewage treatment facility builds up, operating cost is high, has been even more than blowdown sustainability of enterprises, and effluent quality can not reach Mark or blowdown water quality are unstable, it is impossible to reach the requirement of environmental administration, thus bring huge loss to enterprise.
Summary of the invention
It is an object of the invention to provide the float in a kind of usage amount removal sewage few, efficient, the turbid descending, decolouring, clear COD, BOD in clear water quality, effectively removal sewage and Organic substance, the chemical engineering sewage intensive treatment agent of energy recycling and system thereof Preparation Method and application, with the problem solving to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of chemical engineering sewage intensive treatment agent, is made up of according to the raw material of weight portion following: Methyl Hydrogen Polysiloxane Fluid 10-18 Part, dioctyl phthalate 1-5 part, cellulose ether 1-5 part, metakaolin 22-30 part, triterpene saponin 5-12 part.
As the further scheme of the present invention: described chemical engineering sewage intensive treatment agent, by the following raw material according to weight portion Composition: Methyl Hydrogen Polysiloxane Fluid 12-16 part, dioctyl phthalate 2-4 part, cellulose ether 2-4 part, metakaolin 24-28 part, Triterpene saponin 7-10 part.
As the further scheme of the present invention: described chemical engineering sewage intensive treatment agent, by the following raw material according to weight portion Composition: Methyl Hydrogen Polysiloxane Fluid 14 parts, dioctyl phthalate 3 parts, cellulose ether 3 parts, metakaolin 268 parts, triterpene saponin 8 Part.
Another object of the present invention is to provide the preparation method of a kind of chemical engineering sewage intensive treatment agent, comprises the steps of:
1) triterpene saponin is mixed with ethanol solution, prepare the quality of triterpene saponin solution, triterpene saponin and ethanol solution Ratio is 1:5-10, and in ethanol solution, ethanol is 3:1-4 with the volume ratio of deionized water;Triterpene saponin solution is mixed with metakaolin Closing, when 68 DEG C, heated and stirred processes 20-25min, logical nitrogen, is heated to 85 DEG C under nitrogen atmosphere, stir process 30- 35min, prepares pretreatment material;
2) Methyl Hydrogen Polysiloxane Fluid is mixed with cellulose ether, heated and stirred 40min at 62 DEG C, then insert pretreatment material In, it is heated to 72 DEG C under nitrogen atmosphere, stir process 50-60min, then it is down to 50 DEG C, adds dioctyl phthalate Stirring 40-50min, then heats to 250 DEG C, and stir process 2.5-3h at such a temperature, obtains inorganic agent.
Another object of the present invention is to provide the application in processing chemical engineering sewage of the described inorganic agent.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention utilizes triterpene saponin to be modified metakaolin, then with cellulose ether, Methyl Hydrogen Polysiloxane Fluid crosslinking instead Should, the inorganic agent prepared after then reacting with dioctyl phthalate is used for processing chemical engineering sewage, and processing speed is fast, usage amount Few, can efficiently remove the float in sewage, the turbid descending, decolouring, limpid water quality, effectively remove COD, BOD in sewage and organic Thing, processes the inorganic agent after sewage and is prone to remove, water quality will not be caused secondary pollution, moreover it is possible to recycling, expand it and make By value.Preparation process of the present invention is simple, and parameter is easy to control, the inorganic agent stable performance prepared, and production cost is extremely low, is suitable to big Large-scale production.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under not making creative work premise, all Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of chemical engineering sewage intensive treatment agent, it is made up of according to the raw material of weight portion following: methyl Containing hydrogen silicone oil 10 parts, dioctyl phthalate 1 part, cellulose ether 1 part, metakaolin 22 parts, triterpene saponin 5 parts.
Triterpene saponin is mixed with ethanol solution, prepares the mass ratio of triterpene saponin solution, triterpene saponin and ethanol solution For 1:5, in ethanol solution, ethanol is 3:1 with the volume ratio of deionized water;Triterpene saponin solution is mixed with metakaolin, 68 DEG C time heated and stirred process 20min, logical nitrogen, be heated to 85 DEG C under nitrogen atmosphere, stir process 30min, prepare pretreatment Material.Methyl Hydrogen Polysiloxane Fluid is mixed with cellulose ether, heated and stirred 40min at 62 DEG C, then insert in pretreatment material, at nitrogen Atmosphere is heated to 72 DEG C under enclosing, stir process 50min, is then down to 50 DEG C, adds dioctyl phthalate stirring 40min, Then heat to 250 DEG C, and stir process 2.5h at such a temperature, obtain inorganic agent.
Embodiment 2
In the embodiment of the present invention, a kind of chemical engineering sewage intensive treatment agent, it is made up of according to the raw material of weight portion following: methyl Containing hydrogen silicone oil 18 parts, dioctyl phthalate 5 parts, cellulose ether 5 parts, metakaolin 30 parts, triterpene saponin 12 parts.
Triterpene saponin is mixed with ethanol solution, prepares the mass ratio of triterpene saponin solution, triterpene saponin and ethanol solution For 1:10, in ethanol solution, ethanol is 3:4 with the volume ratio of deionized water;Triterpene saponin solution is mixed with metakaolin, When 68 DEG C, heated and stirred processes 25min, logical nitrogen, is heated to 85 DEG C under nitrogen atmosphere, and stir process 35min prepares pre-place Reason material.Methyl Hydrogen Polysiloxane Fluid is mixed with cellulose ether, heated and stirred 40min at 62 DEG C, then insert in pretreatment material, 72 DEG C it are heated under nitrogen atmosphere, stir process 60min, then it is down to 50 DEG C, adds dioctyl phthalate stirring 50min, then heats to 250 DEG C, and stir process 3h at such a temperature, obtains inorganic agent.
Embodiment 3
In the embodiment of the present invention, a kind of chemical engineering sewage intensive treatment agent, it is made up of according to the raw material of weight portion following: methyl Containing hydrogen silicone oil 12 parts, dioctyl phthalate 2 parts, cellulose ether 2 parts, metakaolin 24 parts, triterpene saponin 7 parts.
Triterpene saponin is mixed with ethanol solution, prepares the mass ratio of triterpene saponin solution, triterpene saponin and ethanol solution For 1:8, in ethanol solution, ethanol is 3:2 with the volume ratio of deionized water;Triterpene saponin solution is mixed with metakaolin, 68 DEG C time heated and stirred process 22min, logical nitrogen, be heated to 85 DEG C under nitrogen atmosphere, stir process 32min, prepare pretreatment Material.Methyl Hydrogen Polysiloxane Fluid is mixed with cellulose ether, heated and stirred 40min at 62 DEG C, then insert in pretreatment material, at nitrogen Atmosphere is heated to 72 DEG C under enclosing, stir process 55min, is then down to 50 DEG C, adds dioctyl phthalate stirring 45min, Then heat to 250 DEG C, and stir process 2.8h at such a temperature, obtain inorganic agent.
Embodiment 4
In the embodiment of the present invention, a kind of chemical engineering sewage intensive treatment agent, it is made up of according to the raw material of weight portion following: methyl Containing hydrogen silicone oil 16 parts, dioctyl phthalate 4 parts, cellulose ether 4 parts, metakaolin 28 parts, triterpene saponin 10 parts.
Triterpene saponin is mixed with ethanol solution, prepares the mass ratio of triterpene saponin solution, triterpene saponin and ethanol solution For 1:8, in ethanol solution, ethanol is 3:2 with the volume ratio of deionized water;Triterpene saponin solution is mixed with metakaolin, 68 DEG C time heated and stirred process 22min, logical nitrogen, be heated to 85 DEG C under nitrogen atmosphere, stir process 32min, prepare pretreatment Material.Methyl Hydrogen Polysiloxane Fluid is mixed with cellulose ether, heated and stirred 40min at 62 DEG C, then insert in pretreatment material, at nitrogen Atmosphere is heated to 72 DEG C under enclosing, stir process 55min, is then down to 50 DEG C, adds dioctyl phthalate stirring 45min, Then heat to 250 DEG C, and stir process 2.8h at such a temperature, obtain inorganic agent.
Embodiment 5
In the embodiment of the present invention, a kind of chemical engineering sewage intensive treatment agent, it is made up of according to the raw material of weight portion following: methyl Containing hydrogen silicone oil 14 parts, dioctyl phthalate 3 parts, cellulose ether 3 parts, metakaolin 268 parts, triterpene saponin 8 parts.
Triterpene saponin is mixed with ethanol solution, prepares the mass ratio of triterpene saponin solution, triterpene saponin and ethanol solution For 1:8, in ethanol solution, ethanol is 3:2 with the volume ratio of deionized water;Triterpene saponin solution is mixed with metakaolin, 68 DEG C time heated and stirred process 22min, logical nitrogen, be heated to 85 DEG C under nitrogen atmosphere, stir process 32min, prepare pretreatment Material.Methyl Hydrogen Polysiloxane Fluid is mixed with cellulose ether, heated and stirred 40min at 62 DEG C, then insert in pretreatment material, at nitrogen Atmosphere is heated to 72 DEG C under enclosing, stir process 55min, is then down to 50 DEG C, adds dioctyl phthalate stirring 45min, Then heat to 250 DEG C, and stir process 2.8h at such a temperature, obtain inorganic agent.
Comparative example 1
In addition to not containing triterpene saponin, its formula and preparation process are consistent with embodiment 5.
Comparative example 2
Containing only metakaolin, triterpene saponin, its formula and preparation process are consistent with embodiment 5.
The sewage of a certain chemical fertilizer factory is entered by inorganic agent that embodiment 1-5 prepares with comparative example 1-2 the most in accordance with the following steps Capable process: by need sewage to be processed in sewage pump is injected into the dispensing kit of magnetic force usefulness integrated machine for sewage treatment, so Rear addition inorganic agent, the addition of inorganic agent is the 0.5% of sewage quality, in order to the process of 1000L sewage.Dirty through magnetic force usefulness Clear water is obtained after a series of process of water process all-in-one.
Chemical fertilizer factory's wastewater influent when embodiment 1-5 is implemented with comparative example 1-2 is as shown in table 1 with the water quality index of water outlet:
Water inlet when table 1 embodiment 1-5 is implemented with comparative example 1-2 and the water quality index of water outlet
As can be seen from Table 1, the present invention utilizes the inorganic agent in embodiment 1-5, in conjunction with magnetic force usefulness sewage disposal one Chemical fertilizer factory's sewage is processed by machine, can effectively remove SS, COD, the BOD in sewage and Organic substance.Furthermore it is possible to observe dirt Float in water is efficiently removed, and turbidity substantially reduces, and water quality becomes clear.Compared with comparative example 1-2, it is known that, the present invention exists Play a role under the reacting to each other of each raw material, there is the progress of significance.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of the spirit or essential attributes of the present invention, it is possible to realize the present invention in other specific forms.Therefore, no matter From the point of view of which point, all should regard embodiment as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all by fall in the implication of equivalency and scope of claim Change is included in the present invention.
Although moreover, it will be appreciated that this specification is been described by according to embodiment, but the most each embodiment only wraps Containing an independent technical scheme, this narrating mode of description is only that for clarity sake those skilled in the art should Description can also be formed those skilled in the art through appropriately combined as an entirety, the technical scheme in each embodiment May be appreciated other embodiments.

Claims (5)

1. a chemical engineering sewage intensive treatment agent, it is characterised in that be made up of according to the raw material of weight portion following: methyl hydrogen silicon Oil 10-18 part, dioctyl phthalate 1-5 part, cellulose ether 1-5 part, metakaolin 22-30 part, triterpene saponin 5-12 part.
Chemical engineering sewage intensive treatment agent the most according to claim 1, it is characterised in that by the following raw material according to weight portion Composition: Methyl Hydrogen Polysiloxane Fluid 12-16 part, dioctyl phthalate 2-4 part, cellulose ether 2-4 part, metakaolin 24-28 part, Triterpene saponin 7-10 part.
Chemical engineering sewage intensive treatment agent the most according to claim 1, it is characterised in that by the following raw material according to weight portion Composition: Methyl Hydrogen Polysiloxane Fluid 14 parts, dioctyl phthalate 3 parts, cellulose ether 3 parts, metakaolin 268 parts, triterpene saponin 8 Part.
4. the preparation method of the chemical engineering sewage intensive treatment agent as described in claim 1-3 is arbitrary, it is characterised in that by with Lower step forms:
1) being mixed with ethanol solution by triterpene saponin, prepare triterpene saponin solution, triterpene saponin with the mass ratio of ethanol solution is 1:5-10, in ethanol solution, ethanol is 3:1-4 with the volume ratio of deionized water;Triterpene saponin solution is mixed with metakaolin, When 68 DEG C, heated and stirred processes 20-25min, logical nitrogen, is heated to 85 DEG C under nitrogen atmosphere, stir process 30-35min, Prepare pretreatment material;
2) Methyl Hydrogen Polysiloxane Fluid is mixed with cellulose ether, heated and stirred 40min at 62 DEG C, then inserts in pretreatment material, It is heated to 72 DEG C under nitrogen atmosphere, stir process 50-60min, then it is down to 50 DEG C, adds dioctyl phthalate stirring 40-50min, then heats to 250 DEG C, and stir process 2.5-3h at such a temperature, obtains inorganic agent.
5. the application in processing chemical engineering sewage of the inorganic agent as described in claim 1-3 is arbitrary.
CN201610619053.0A 2016-07-29 2016-07-29 A kind of chemical engineering sewage intensive treatment agent and its preparation method and application Pending CN106115813A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63205193A (en) * 1987-02-20 1988-08-24 Toyomichi Nagasaka Waste liquid discarding agent
CN1297667A (en) * 1998-04-20 2001-05-30 艾利森公司 System and method for use of override keys for location services
CN1853770A (en) * 2005-04-27 2006-11-01 李兆辉 Modified adsorbent for oil component in water, its production and adsorber
CN104261529A (en) * 2014-09-19 2015-01-07 句容亿格纳米材料厂 Nano titanium dioxide coating flocculant and preparation method thereof
CN104445790A (en) * 2014-10-27 2015-03-25 乔世琴 Method and device for comprehensively purifying wastewater containing heavy metal ions and organics

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63205193A (en) * 1987-02-20 1988-08-24 Toyomichi Nagasaka Waste liquid discarding agent
CN1297667A (en) * 1998-04-20 2001-05-30 艾利森公司 System and method for use of override keys for location services
CN1853770A (en) * 2005-04-27 2006-11-01 李兆辉 Modified adsorbent for oil component in water, its production and adsorber
CN104261529A (en) * 2014-09-19 2015-01-07 句容亿格纳米材料厂 Nano titanium dioxide coating flocculant and preparation method thereof
CN104445790A (en) * 2014-10-27 2015-03-25 乔世琴 Method and device for comprehensively purifying wastewater containing heavy metal ions and organics

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
丁浩: "《粉体表面改性与应用》", 31 August 2013, 清华大学出版社 *
阮承祥: "《混凝土外加剂及其工程应用》", 31 December 2008, 江西科学技术出版社 *

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Address after: Shushan District of Hefei City, Anhui Province, Jiangmen 230000 garden business office floor B-1014 room 10

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Application publication date: 20161116

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