CN106106511A - A kind of composition pesticide containing fosthiazate - Google Patents
A kind of composition pesticide containing fosthiazate Download PDFInfo
- Publication number
- CN106106511A CN106106511A CN201610544379.1A CN201610544379A CN106106511A CN 106106511 A CN106106511 A CN 106106511A CN 201610544379 A CN201610544379 A CN 201610544379A CN 106106511 A CN106106511 A CN 106106511A
- Authority
- CN
- China
- Prior art keywords
- fosthiazate
- agent
- tioxazafen
- weight
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005959 Fosthiazate Substances 0.000 title claims abstract description 86
- DUFVKSUJRWYZQP-UHFFFAOYSA-N fosthiazate Chemical compound CCC(C)SP(=O)(OCC)N1CCSC1=O DUFVKSUJRWYZQP-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 239000000203 mixture Substances 0.000 title claims abstract description 42
- 239000000575 pesticide Substances 0.000 title claims abstract description 17
- IHNSIFFSNUQGQN-UHFFFAOYSA-N tioxazafen Chemical compound C1=CSC(C=2ON=C(N=2)C=2C=CC=CC=2)=C1 IHNSIFFSNUQGQN-UHFFFAOYSA-N 0.000 claims abstract description 67
- -1 usual auxiliaries Chemical compound 0.000 claims abstract description 12
- 241000482313 Globodera ellingtonae Species 0.000 claims abstract description 7
- 239000000839 emulsion Substances 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 239000003094 microcapsule Substances 0.000 claims description 20
- 239000000725 suspension Substances 0.000 claims description 20
- 206010011732 Cyst Diseases 0.000 claims description 18
- 208000031513 cyst Diseases 0.000 claims description 18
- 239000008187 granular material Substances 0.000 claims description 17
- 239000002270 dispersing agent Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 14
- 239000008367 deionised water Substances 0.000 claims description 13
- 229910021641 deionized water Inorganic materials 0.000 claims description 13
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- 239000002775 capsule Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- WQPDQJCBHQPNCZ-UHFFFAOYSA-N cyclohexa-2,4-dien-1-one Chemical compound O=C1CC=CC=C1 WQPDQJCBHQPNCZ-UHFFFAOYSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002190 fatty acyls Chemical group 0.000 description 1
- 230000003031 feeding effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 239000004518 granules dosage form Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 229940031703 low substituted hydroxypropyl cellulose Drugs 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 229940124561 microbicide Drugs 0.000 description 1
- 239000002855 microbicide agent Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000001253 polyvinylpolypyrrolidone Substances 0.000 description 1
- 235000013809 polyvinylpolypyrrolidone Nutrition 0.000 description 1
- 229920000523 polyvinylpolypyrrolidone Polymers 0.000 description 1
- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- GGHDAUPFEBTORZ-UHFFFAOYSA-N propane-1,1-diamine Chemical compound CCC(N)N GGHDAUPFEBTORZ-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of containing fosthiazate with the composition pesticide of tioxazafen, including usual auxiliaries, fosthiazate and tioxazafen, fosthiazate is 20:1～1:20 with the ratio of weight and number of tioxazafen；Fosthiazate and with tioxazafen with certain compounding after nematicide had obvious synergism, it is adaptable to the crop nematicide that preventing and treating pathogen nematicide causes, especially root of the crop Root-knot and cyst nematode disease.
Description
Technical field
The composition pesticide that the present invention relates to, is that compositions is to cause of disease with fosthiazate and tioxazafen as effective ingredient
Nematicide Meloidogyne incognita and soybean cyst nematode Heterodera glycines and the crop nematicide caused thereof have synergistic function, it is adaptable to preventing and treating
By the crop nematicide of pathogen nematicide, root of the crop Root-knot that especially Meloidogyne incognita causes and soy bean cyst roundworm
The crop Cyst nematode caused.
Background technology
Fosthiazate (fosthiazate), for organophosphor nematicide.Model of action is the acetylcholine ester of suppression insect
Enzyme, has good interior absorption, is mainly used in preventing and treating nematicide, aphid etc., and quick-acting is good, and the lasting period is long, and fosthiazate uses latter 2 months
In rear soil, fosthiazate remains to reach root-knot nematode lethasl concentration, remains to reduce nematicide movable after 3 months.
Tioxazafen, chemical name: 3-phenyl-5-(thiophene-2-base)-1,2,4-diazole.Meng Shan opens for 2008
The non-stifling property nematicide sent out, because it is more environmentally friendly, it is safer to use, less on the impact of people, is described as the ideal of fosthiazate
Succedaneum, greenhouse and field experiment show, the performance of this novel nematicide is produced equivalent to or better than the comparison of current commercialization
Product.It is reported, tioxazafen is to the soybean cyst nematode Heterodera glycines on Semen sojae atricolor, root-knot nematode, kidney shape nematicide, the root-rot line on Semen Maydis
Worm, root-knot nematode, minute hand nematicide, kidney shape nematicide on Cotton Gossypii, root-knot nematode etc. are respectively provided with fabulous biological activity.
Plant nematode is the pathogenic microorganism that a class is very harmful, and it has a very wide distribution, of a great variety, environment adaptation
Ability is strong, can colonize in the root system of plant, stem, leaf, seed, plumelet and fruit, can be by feeding activity to host plant
Cause mechanical damage, and rob the nutrition of host plant, especially its esophageal gland secretions can cause host plant occur one be
Epidemy becomes, and also can jointly infect host plant with other pathogenic microorganism, cause compound disease, cause production loss.In the whole world
In the range of, the agricultural losses that plant nematode is caused every year are up to more than 100,000,000,000 dollars, seriously constrain agricultural economy
Development.
Being found by experiment that, fosthiazate and tioxazafen are used in mixed way black to Meloidogyne incognita with soybean cyst nematode Heterodera glycines
Deng plant pathogeny line insect have synergistic function especially in 20:1～1:20 proportion to Meloidogyne incognita and big
Bean Cyst nematode has obvious potentiation, and preferred weight ratio is 6:1～1:6, and more excellent part by weight is 3:1～1:3.
Can be the dosage form agriculturally commonly used with excipient by certain technological means fosthiazate and tioxazafen compositions
Such as granule, aqueous emulsion, micro-capsule suspension, the popularization and application of the present invention that is more convenient for after excipient.
Summary of the invention
It is an object of the invention to provide the synergetic pesticide composition that a kind of effective ingredient is fosthiazate and tioxazafen,
Prevention and control for crop nematicide especially provide one effectively to manage instrument for root of the crop Root-knot and Cyst nematode.
The present invention is achieved through the following technical solutions:
The present invention relates to a kind of synergistic composition compounding containing fosthiazate and tioxazafen, fosthiazate with
The part by weight of tioxazafen is 20:1～1:20, and preferred weight ratio is 6:1～1:6, and more excellent part by weight is 3:1～1:
3。
Described composition pesticide effective ingredient total content is 0.1%～60%.
Described microbicide compositions add auxiliary agent and excipient by certain technological means make granule, aqueous emulsion,
The dosage form that micro-capsule suspension etc. are agriculturally conventional.
Described granule dosage form weight percent consists of: fosthiazate 0.1～30%, tioxazafen0.1～30%,
Dispersant 0.1～15%, wetting agent 0.1～10%, binding agent 0.1～14%, carrier complement to 100%.Concrete production stage
For: concrete production stage is: by effective ingredient and other auxiliary agent mix homogeneously, pulverize with micro jet, through mediating, so
Rear addition fluidized-bed granulation dryer carries out pelletize, dry, screening, prepares the granule of corresponding weight percentage.
Described aqueous emulsion agent weight percent consists of: fosthiazate 0.1～30%, tioxazafen0.1～30%,
Dispersant 0.1～13%, emulsifying agent 0.1～13%, thickening agent 0.1～3%, antifreezing agent 0.1～5%, stabilizer 0.1～5%,
Deionized water complements to 100%.Concrete production stage is: effective ingredient and other auxiliary agent is mixed, divides through high speed shear emulsifying
After Saning, preparing the aqueous emulsion of corresponding weight percentage, described aqueous emulsion Active principals is not higher than 40%.
Described micro-capsule suspension dosage form weight percent consists of: fosthiazate 0.1～30%, tioxazafen0.1
～30%, capsule-core solvent 0.1～15%, oiliness cyst material 0.1～15%, aqueous cyst material 0.1～12%, emulsifying agent
0.1～6%, dispersant 0.1～5%, antifreezing agent 0.1～3%, thickening agent 0.1～2%, pH adjusting agent 0.1～2%, deionization
Water complements to 100%.Concrete production stage is: fosthiazate and tioxazafen is dissolved in capsule-core solvent, adds emulsifying agent
Stir, add oiliness cyst material, be uniformly mixed as oil phase；Aqueous cyst material and part thickening agent are added
Water is stirred for aqueous phase；Oil phase and aqueous phase are mixed, shear by high-shear emulsion machine, form uniform emulsion, 28～
35 DEG C are reacted 2～4 hours, are warmed up to 60～80 DEG C of resolidifications 1～4 hours, add remaining thickening agent and dispersant and anti-
Freezing agent, regulation pH is neutral, supplies with deionized water, just can get the micro-capsule suspension of corresponding percentage composition, described micro-glue
The total content of capsule suspending agent active component is not higher than 40%.
Described defoamer can be one or more in silicone compound, epoxy soybean oil, methanol, silicone oil etc..
Described antifreezing agent can be one or more in glycerol, propylene glycol, diethylene glycol, carbamide etc..
Described wetting agent can be sodium lauryl sulphate, dodecylbenzene sodium sulfonate, sodium butylnaphthalenesulfonate, alkyl sulphur
In acid sodium, tea seed cake powder, spaonin powder, Fructus Sapindi Mukouossi powder etc. one or more, corn starch, sorghum starch, Fagopyrum esculentum Moench powder.
Described dispersant can be alkylphenol polyoxyethylene formaldehyde condensation products, naphthalenesulfonate formaldehyde condensation compound, to first
Epoxide fatty acyl anilinesulfonic acid, lignosulfonates, polycarboxylate, alkylphenol polyoxyethylene sulfate, alkyl benzene sulphonate
Calcium salt, fatty acid ester sulfate, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, polyglycol distearate, sorbose
One or more in alcohol oleate, nekal etc., special dispersant can also is that a kind of combed metal carboxylate
Terpolymer dispersants (BBM-3 hereinafter relates to all replacing of this terpolymer dispersants with BBM-3), this copolymer
Come from patent application 201310521909.7, be a kind of with acrylic homolog, mono polyethylene glycol maleate, propylene
Acid esters is monomer, with free-radical polymerized method synthesis in aqueous phase system, concrete, by the monomer group of following weight ratio
Become: acrylate 10～50 parts, acrylic homolog 10～80 parts, mono polyethylene glycol maleate 10～50 parts, work
Skill step is as follows: 1000 parts of distilled waters, 10 parts of surfactants is joined in four mouthfuls of reaction flasks, heats while stirring；When
When the temperature of solution rises to 60 DEG C in reaction bulb, add 200 parts of acrylate, 500 parts of acrylic homolog, 100 parts of maleic acids
Single poly glycol monomethyl ether ester and 30 parts of initiator solutions added in 1 hour, then 60 DEG C of insulation reaction 2 hours；Insulation reaction
Being down to room temperature after end while stirring, with the carboxylic acid in sodium hydroxide solution and in system, dosis neutralisata is carboxyl molal quantity
50%, prepare destination scatter agent solution.
Described disintegrating agent can be carboxymethyl starch sodium, low-substituted hydroxypropyl cellulose, cross-linking sodium carboxymethyl cellulose,
Polyvinylpolypyrrolidone, chitosan, sodium alginate sodium bicarbonate, magnesium chloride, aluminum chloride, sodium chloride, carbamide, ammonium sulfate, bentonite etc.
In one or more.
Described thickening agent can be polyvinyl acetate, xanthan gum, gelatin, Radix Acaciae senegalis, aluminium-magnesium silicate, phenolic aldehyde tree
One or more in fat, hydroxymethyl cellulose, sodium alginate etc..
Described solid carrier can be precipitated calcium carbonate, potter's clay, Kaolin, kieselguhr, bentonite, white carbon, clay,
One or more in attapulgite, Pulvis Talci, quartz sand, wood powder, walnut parting, lignin, Testa Tritici, rice chaff, wood flour etc..
Described oiliness cyst material is selected from methyl diphenylene diisocyanate, hexamethylene diisocyanate, 4,4'-bis-
One or more in diphenylmethane diisocyanate.
Described capsule-core solvent is selected from toluene, dimethylbenzene, solvent naphtha S-150, solvent naphtha S-200, ethanol, isopropanol, just
Butanol, n-octyl alcohol, n-amyl alcohol, acetone, Ketohexamethylene, hexane, dimethylformamide, N-Methyl pyrrolidone, acetonitrile, dichloromethane
One or more in alkane, ethyl acetate, methyl oleate, dibutyl phthalate.
Described aqueous cyst material one in ethylene glycol, glycerol, ethylenediamine, propane diamine, the third triamine, the water or
Several.
Described emulsifying agent selected from agriculture breast 33#, agriculture breast 34#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 1601#,
Agriculture breast 1602#, T60, S80, TX-10, OP-10, NP-10, Nonyl pheno (EO=10) ether phosphate, triphenoethyl benzene
One in phenol polyethenoxy ether phosphate, BBM-3, epoxychloropropane.
Described solvent is one or more in dimethylbenzene, ethylene glycol, benzoic acid, Ketohexamethylene, solvent naphtha.
Described pH adjusting agent one in acetic acid, sodium hydroxide.
Described deionized water is industrialization deionized water.
Described binding agent can be sucrose, polyvinyl alcohol, Polyethylene Glycol, sodium carboxymethyl cellulose, polyvinylpyrrolidine
Ketone, carboxymethylcellulose calcium, carboxy-propyl cellulose, dextrin, amylodextrin, polyvinylpyrrolidone, viscosity Kaolin, paraffin,
One or more in Colophonium, wood powder etc..
Composition pesticide of the present invention has significant synergistic function, is used alone than single dose and significantly improves agriculture
The prevention effect of nematicide on crop；Decrease Pesticide use amount, reduce use cost, alleviate the pollution to environment.
Detailed description of the invention
In order to be more fully understood that the essence of the present invention, below in conjunction with embodiment, present disclosure is described further,
But can not be considered as limitation of the present invention, the following stated is only used for explaining the present invention, for without departing from present invention spirit and principle
The amendment made, replace or improve, belong to the scope of protection of present invention.
According to the abundant method of Sun Yun, evaluate the synergism of pharmacy mix, i.e. CTC≤80 according to co-toxicity coefficient (CTC) for association
Same antagonism, 80 ＜ CTC ＜ 120 are joint action of antagonism, and CTC >=120 are synergistic function.Actual measurement toxicity index
(ATI)=(EC of standard agent50The EC of/reagent agent50)×100；The toxicity index of theoretical toxicity index TTI=A medicament ×
The percentage composition of B medicament in the toxicity index × mixture of the percentage composition+B medicament of A medicament in mixture；Co-toxicity coefficient (CTC)=
[mixture actual measurement toxicity index (ATI)/mixture theory toxicity index (TTI)] × 100.
Embodiment one: fosthiazate tioxazafen is to cloth Meloidogyne incognita (Meloidogyne incongnita
Chitwood) Toxicity Determination, subjects is picked up from and is used the graceful funnel of shellfish to send out in the Cucumber root-knot nematode disease insect gall in field
The Meloidogyne incognita (Meloidogyne incongnita Chitwood) separated.
Table 1, fosthiazate tioxazafen are to Meloidogyne incognita (Meloidogyne incongnita Chitwood)
Toxicity Determination result
As shown in Table 1, fosthiazate and tioxazafen mixed ratio are between 20:1～1:20, to Meloidogyne incognita
(Meloidogyne incongnita Chitwood) has obvious potentiation, and co-toxicity coefficient is all more than 140；Thiazole
Phosphine and tioxazafen mixture between 6:1～1:6 to Meloidogyne incognita (Meloidogyne incongnita
Chitwood) having obvious potentiation, co-toxicity coefficient is all more than 200；Fosthiazate and tioxazafen mixture at 3:1～
Between 1:3, Meloidogyne incognita (Meloidogyne incongnita Chitwood) had obvious potentiation, altogether poison
Coefficient is all more than 220.
Embodiment two: fosthiazate tioxazafen is to soy bean cyst roundworm (Heterodera glycines
Ichinohe) Toxicity Determination, subjects is picked up from and is used the graceful funnel of shellfish to send out in the soybean cyst nematode insect gall in field
The soy bean cyst roundworm (Heterodera glycines Ichinohe) separated.
Table 2, fosthiazate tioxazafen are to soy bean cyst roundworm
The Toxicity Determination result of (Heterodera glycines Ichinohe)
As shown in Table 2, fosthiazate and tioxazafen mixed ratio are between 20:1～1:20, to soy bean cyst roundworm
(Heterodera glycines Ichinohe) has obvious potentiation, and co-toxicity coefficient is all more than 150；Fosthiazate with
Tioxazafen mixed ratio is between 6:1～1:6, to soy bean cyst roundworm (Heterodera glycines Ichinohe)
Having obvious potentiation, co-toxicity coefficient is all more than 200；Fosthiazate and tioxazafen mixed ratio 3:1～1:3 it
Between, soy bean cyst roundworm (Heterodera glycines Ichinohe) is had obvious potentiation, co-toxicity coefficient is equal
More than 220.
Below in conjunction with preparation embodiment to further instruction of the present invention.
Evaluating synergistic method according to Gowing method, its formula is as follows:
In formula:
X is fosthiazate with certain dosage prevention effect to water nemas time alone；
Y is tioxazafen with certain dosage prevention effect to nemas time alone；
E0For fosthiazate and tioxazafen with certain ratio mix to when using to the prevention effect of nemas
Theoretical value or desired value；
E is that fosthiazate mixes the measured value to nemas prevention effect or observation with tioxazafen with certain ratio
Value.
Evaluation criterion: as E E0During ＞ 10%, it is expressed as synergistic function；As 10%≤E E0When≤10%, performance
For collaborative summation action；As E E0During ＜ 10%, show as joint action of antagonism.
Embodiment three: 30% fosthiazate tioxazafen micro-capsule suspension
Weigh the 20% former medicine of fosthiazate, the former medicine of 10%tioxazafen, be dissolved in 15%150# solvent naphtha, add
1.5% agriculture breast 33# and 7% methyl diphenylene diisocyanate, is uniformly mixed as oil phase；By 7% polyvinyl alcohol water solution
Add in suitable quantity of water and be stirred for aqueous phase；Oil phase and aqueous phase are mixed, by high-shear emulsion machine under the conditions of 10000 turns every point
Emulsification pretreatment, forms uniform emulsion, under 500 turns every point stirring the most uniformly drips 1% glycerol into emulsion, within 80 minutes, drip
Add, react 4 hours under 25 DEG C of water-baths, 500 turns every point stirring, be warmed up to 60 DEG C and solidify 2 hours, add 2% xanthan gum
Aqueous solution, 1% polycarboxylate salt dispersant and 4% ethylene glycol, regulation pH is neutral, supplies 100% weight portion with deionized water, i.e.
Obtain 30% fosthiazate tioxazafen micro-capsule suspension.Identical technological process and auxiliary agent content is used to prepare 20% respectively
Fosthiazate micro-capsule suspension and 10%tioxazafen micro-capsule suspension.After testing, envelop rate >=93%, particle diameter (0.45-
2.0 μm standard screens) >=95%, suspensibility >=90%, persistent foamability (after 1min)≤15mL, dispersibility >=90%, pH value
6.7-7.3, heat storage stability is qualified, and low-temperature stability is qualified.
Table 3, it is used for preventing and treating Cucumber root-knot nematode disease, Banana Root Root-knot, after medicine 60 days, E-E0It is all higher than 20%.
Embodiment four: 20% fosthiazate tioxazafen micro-capsule suspension
Weigh the 10% former medicine of fosthiazate, the former medicine of 10%tioxazafen, be dissolved in 15%150# solvent naphtha, add 2%
Agriculture breast 33# and 5% methyl diphenylene diisocyanate, be uniformly mixed as oil phase；10% polyvinyl alcohol water solution is added
Suitable quantity of water is stirred for aqueous phase；Oil phase and aqueous phase are mixed, shears under the conditions of 10000 turns every point by high-shear emulsion machine
Emulsifying, forms uniform emulsion, under 500 turns every point stirring the most uniformly drips 1% ethylenediamine into emulsion, dropping in 40 minutes
Complete, react 4 hours under 25 DEG C of water-baths, 500 turns every point stirring, be warmed up to 60 DEG C and solidify 2 hours, add 1% xanthan glue
Solution, 2% polycarboxylate salt dispersant, 1% lignosulfonates and 4% ethylene glycol, regulation pH is neutral, supplies with deionized water
100% weight portion, just can get 20% fosthiazate tioxazafen micro-capsule suspension.Use identical technological process and help
Agent content prepares 10% fosthiazate micro-capsule suspension and 10%tioxazafen micro-capsule suspension respectively.After testing, encapsulating
Rate >=93%, particle diameter (0.45-2.0 μm standard screen) >=95%, suspensibility >=90%, persistent foamability (after 1min)≤15mL,
Dispersibility >=90%, pH value 6.7-7.3, heat storage stability is qualified, and low-temperature stability is qualified.
Table 4, to be used for preventing and treating pepper root Root-knot, watermelon root-knot sick, after medicine 60 days, E-E0It is all higher than 20%.
Embodiment five: 24% fosthiazate tioxazafen micro-capsule suspension
Weigh the 6% former medicine of fosthiazate, the former medicine of 18%tioxazafen, be dissolved in 14%150# solvent naphtha, add 3.5%
Agriculture breast 33# and 5% methyl diphenylene diisocyanate, be uniformly mixed as oil phase；15% polyvinyl alcohol water solution is added
Suitable quantity of water is stirred for aqueous phase；Oil phase and aqueous phase are mixed, shears under the conditions of 10000 turns every point by high-shear emulsion machine
Emulsifying, forms uniform emulsion, under 500 turns every point stirring the most uniformly drips 1% ethylenediamine into emulsion, dropping in 40 minutes
Complete, react 4 hours under 25 DEG C of water-baths, 500 turns every point stirring, be warmed up to 60 DEG C and solidify 2 hours, add 1% xanthan glue
Solution, 2% polycarboxylate salt dispersant, 1% lignosulfonates and 4% ethylene glycol, regulation pH is neutral, supplies with deionized water
100% weight portion, just can get 24% fosthiazate tioxazafen micro-capsule suspension.Use identical technological process and help
Agent content prepares 6% fosthiazate micro-capsule suspension and 18%tioxazafen micro-capsule suspension respectively.After testing, envelop rate
>=97%, particle diameter (0.45-2.0 μm standard screen) >=96%, suspensibility >=90%, persistent foamability (after 1min)≤13mL, point
Dissipating property >=90%, pH value 6.8-7.2, heat storage stability is qualified, and low-temperature stability is qualified.
Table 5, it is used for preventing and treating soybean cyst nematode, Radix Melo Root-knot, after medicine 60 days, E-E0It is all higher than 20%.
Embodiment six: 20% fosthiazate tioxazafen aqueous emulsion
Weigh 15% fosthiazate, 5%tioxazafen, 12% agriculture breast 2201#, 10%BBM-3,1% epoxychloropropane,
2% ethylene glycol, 5% dimethylbenzene, 0.3% xanthan gum, 0.5% benzoic acid, surplus is deionized water.Above-mentioned raw materials is blended, high
It is 20% fosthiazate tioxazafen aqueous emulsion that speed emulsification pretreatment prepares effective ingredient.Use identical technological process and auxiliary agent
Content prepares 15% Fosthiazate aqueous emulsion and 5%tioxazafen aqueous emulsion.
Table 6, it is used for preventing and treating Kidney bean cyst nematode disease, Fructus psidii guajavae immaturus root knot nematode disease, after medicine 60 days, E-E0It is all higher than 20%.
Embodiment seven: 20% fosthiazate tioxazafen aqueous emulsion
Weigh 10% fosthiazate, 10%tioxazafen, 15% agriculture breast 2201#, 11%BBM-3,1.5% epoxy chloropropionate
Alkane, 1% ethylene glycol, 5% dimethylbenzene, 0.3% xanthan gum, 0.5% benzoic acid, surplus is deionized water.Above-mentioned raw materials is blended,
It is 20% fosthiazate tioxazafen aqueous emulsion that high speed shear emulsifying prepares effective ingredient.Use identical technological process and help
Agent content prepares 10% Fosthiazate aqueous emulsion and 10%tioxazafen aqueous emulsion.
Table 7, it is used for preventing and treating hami melon root knot nematode disease, groundnut root knot nematode disease, after medicine 60 days, E-E0It is all higher than 20%.
Embodiment eight: 20% fosthiazate tioxazafen aqueous emulsion
Weigh 5% fosthiazate, 15%tioxazafen, 15% agriculture breast 2201#, 12%BBM-3,2% epoxychloropropane,
1% ethylene glycol, 5% dimethylbenzene, 0.1% xanthan gum, 0.5% benzoic acid, surplus is deionized water.Above-mentioned raw materials is blended, high
It is 20% fosthiazate tioxazafen aqueous emulsion that speed emulsification pretreatment prepares effective ingredient.Use identical technological process and auxiliary agent
Content prepares 5% Fosthiazate aqueous emulsion and 15%tioxazafen aqueous emulsion.
Table 8, it is used for preventing and treating Rhizoma Solani tuber osi root knot nematode disease, Semen vignae sinensis Cyst nematode, after medicine 60 days, E-E0It is all higher than 20%.
Embodiment nine: 10% fosthiazate tioxazafen granule
Weigh 8% fosthiazate, 2%tioxazafen, 5% sodium lignin sulfonate, 5% polyvinylpyrrolidone, 4% Fructus Vitis viniferae
Sugar, 5% corn starch, 2% rice chaff, surplus attapulgite.Above-mentioned raw materials is mix homogeneously in mixed cylinder, through extruding, pelletize,
It is dried, and screened step prepares 10% fosthiazate tioxazafen granule, uses identical technique and auxiliary agent content 8%
Fosthiazate granule and 2%tioxazafen granule.
Table 9, it is used for preventing and treating that horse tomato root-knot eelworm is sick, Radix Chaenomelis Root-knot, after medicine 60 days, E-E0It is all higher than 20%.
Embodiment ten: 15% fosthiazate tioxazafen granule
Weigh 10% fosthiazate, 5%tioxazafen, 8% sodium lignin sulfonate, 7% polyvinylpyrrolidone, 5% Portugal
Grape sugar, 4% corn starch, 4% rice chaff, surplus attapulgite.Above-mentioned raw materials is mix homogeneously in mixed cylinder, through extruding, makes
Grain, it is dried, and screened step prepares 15% fosthiazate tioxazafen granule, uses identical technique and auxiliary agent content
10% fosthiazate granule and 5%tioxazafen granule.
Table 10, it is used for preventing and treating that horse tomato root-knot eelworm is sick, Radix Chaenomelis Root-knot, after medicine 60 days, E-E0It is all higher than 20%.
Embodiment 11: 12% fosthiazate tioxazafen granule
Weigh 4% fosthiazate, 8%tioxazafen, 7% sodium lignin sulfonate, 5% polyvinylpyrrolidone, 6% Fructus Vitis viniferae
Sugar, 4% corn starch, 3% rice chaff, surplus attapulgite.Above-mentioned raw materials is mix homogeneously in mixed cylinder, through extruding, pelletize,
It is dried, and screened step prepares 12% fosthiazate tioxazafen granule.Use identical technique and auxiliary agent content 4%
Fosthiazate granule and 8%tioxazafen granule.
Table 11, it is used for preventing and treating Citrus root knot nematode disease, Radix Jujubae Root-knot, after medicine 60 days, E-E0It is all higher than 20%.
Claims (10)
1. the composition pesticide containing fosthiazate, it is characterised in that: effective ingredient is fosthiazate and tioxazafen.
A kind of composition pesticide containing fosthiazate the most according to claim 1, it is characterised in that: fosthiazate and
The part by weight of tioxazafen is 20:1～1:20.
A kind of composition pesticide containing fosthiazate the most according to claim 1, it is characterised in that: fosthiazate and
The part by weight of tioxazafen is 6:1～1:6.
A kind of composition pesticide containing fosthiazate the most according to claim 1, it is characterised in that: fosthiazate and
The part by weight of tioxazafen is 3:1～1:3.
A kind of composition pesticide containing fosthiazate the most according to claim 1, it is characterised in that: the weight of effective ingredient
Summation percentage by weight in the composition is 0.1%～60%, and remaining is insecticides adjuvant.
A kind of composition pesticide containing fosthiazate the most according to claim 5, it is characterised in that: the agent of described compositions
Type is granule, aqueous emulsion, micro-capsule suspension.
Micro-capsule suspension the most according to claim 6, it is characterised in that each components by weight is: fosthiazate 0.1～
20%, tioxazafen0.1～20%, capsule-core solvent 0.1～15%, oiliness cyst material 0.1～15%, aqueous cyst material
0.1～12%, emulsifying agent 0.1～6%, dispersant 0.1～5%, antifreezing agent 0.1～3%, thickening agent 0.1～2%, pH regulator
Agent 0.1～2%, deionized water complement to 100%；
Concrete production stage is: fosthiazate and tioxazafen are dissolved in capsule-core solvent, adds emulsifier for mixing uniformly, then
Add oiliness cyst material, be uniformly mixed as oil phase；Aqueous cyst material and part thickening agent are added to the water stirring all
Even for aqueous phase；Oil phase and aqueous phase are mixed, shear by high-shear emulsion machine, form uniform emulsion, 28～35 DEG C of reactions 2～
4 hours, it is warmed up to 60～80 DEG C of resolidifications 1～4 hours, adds remaining thickening agent and dispersant and antifreezing agent, regulate pH
For neutrality, supply with deionized water, just can get the micro-capsule suspension of corresponding percentage composition, described micro-capsule suspension activity
The total content of composition is not higher than 40%.
A kind of composition pesticide containing fosthiazate the most according to claim 6, it is characterised in that each composition weight percentage
Ratio is: fosthiazate 0.1～30%, tioxazafen0.1～30%, dispersant 0.1～13%, emulsifying agent 0.1～13%, thickening
Agent 0.1～3%, antifreezing agent 0.1～5%, stabilizer 0.1～5%, deionized water complement to 100%；
Concrete production stage is: effective ingredient and other auxiliary agent are mixed, and after high speed shear emulsion dispersion, prepares corresponding weight
The aqueous emulsion of percentage composition, described aqueous emulsion Active principals is not higher than 40%；
Described dispersant is combed metal carboxylate terpolymer (BBM-3), is made up of the monomer of following weight ratio: acrylic acid
Ester 10～50 parts, acrylic homolog 10～80 parts, mono polyethylene glycol maleate 10～50 parts, above proportioning is attached most importance to
Amount part, three's sum is 100 parts；
Described combed metal carboxylate terpolymer (BBM-3) is prepared by the following method: by 1000 parts of distilled waters, 10 parts of surfaces
Activating agent joins in four mouthfuls of reaction flasks, heats while stirring；When in reaction bulb, the temperature of solution rises to 60 DEG C, add
200 parts of acrylate, 500 parts of acrylic homolog, 100 parts of mono polyethylene glycol maleates and 30 parts of initiator solutions
Add in 1 hour, then 60 DEG C of insulation reaction 2 hours；Insulation reaction is down to room temperature after terminating while stirring, molten with sodium hydroxide
Carboxylic acid in liquid and in system, dosis neutralisata is the 50% of carboxyl molal quantity, prepares destination scatter agent solution.
A kind of composition pesticide containing fosthiazate the most according to claim 6, it is characterised in that the weight hundred of each component
Proportion by subtraction is: fosthiazate 0.1～30%, tioxazafen0.1～30%, dispersant 0.1～15%, wetting agent 0.1～10%, viscous
Knot agent 0.1～14%, carrier complement to 100%；
Concrete production stage is: concrete production stage is: by effective ingredient and other auxiliary agent mix homogeneously, use ultra micro comminution by gas stream
Machine is pulverized, and through mediating, is subsequently adding in fluidized-bed granulation dryer and carries out pelletize, dry, screening, prepare corresponding weight percent and contain
The granule of amount.
10. a kind of composition pesticide containing fosthiazate described in any one of claim 1 to 9 is being prevented and treated by Meloidogyne incognita
The application on crop Cyst nematode that the root of the crop Root-knot caused and soy bean cyst roundworm cause.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106962372A (en) * | 2017-03-20 | 2017-07-21 | 佛山市普尔玛农化有限公司 | A kind of the pyridine acid amides of miaow containing trifluoro and Tioxazafen kill line composition |
| CN107183048A (en) * | 2017-06-01 | 2017-09-22 | 华北制药集团爱诺有限公司 | A kind of nematicidal composition containing chlopyrifos and Tioxazafen |
| CN110506742A (en) * | 2019-09-23 | 2019-11-29 | 河北军星生物化工有限公司 | A kind of fosthiazate water-soluble granula and preparation method thereof containing stabilizer |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104587891A (en) * | 2013-10-30 | 2015-05-06 | 上海是大高分子材料有限公司 | Comb type carboxylate ternary copolymer and preparation technology thereof |
| CN104936451A (en) * | 2012-12-04 | 2015-09-23 | 孟山都技术公司 | Nematicidal aqueous suspension concentrate composition |
-
2016
- 2016-07-08 CN CN201610544379.1A patent/CN106106511A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104936451A (en) * | 2012-12-04 | 2015-09-23 | 孟山都技术公司 | Nematicidal aqueous suspension concentrate composition |
| CN104587891A (en) * | 2013-10-30 | 2015-05-06 | 上海是大高分子材料有限公司 | Comb type carboxylate ternary copolymer and preparation technology thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106962372A (en) * | 2017-03-20 | 2017-07-21 | 佛山市普尔玛农化有限公司 | A kind of the pyridine acid amides of miaow containing trifluoro and Tioxazafen kill line composition |
| CN107183048A (en) * | 2017-06-01 | 2017-09-22 | 华北制药集团爱诺有限公司 | A kind of nematicidal composition containing chlopyrifos and Tioxazafen |
| CN110506742A (en) * | 2019-09-23 | 2019-11-29 | 河北军星生物化工有限公司 | A kind of fosthiazate water-soluble granula and preparation method thereof containing stabilizer |
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Application publication date: 20161116 |