CN106085565A - 一种微晶玻璃加工用微乳化切削液 - Google Patents
一种微晶玻璃加工用微乳化切削液 Download PDFInfo
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- CN106085565A CN106085565A CN201610420996.0A CN201610420996A CN106085565A CN 106085565 A CN106085565 A CN 106085565A CN 201610420996 A CN201610420996 A CN 201610420996A CN 106085565 A CN106085565 A CN 106085565A
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- Prior art keywords
- parts
- cutting fluid
- nano
- acid
- devitrified glass
- Prior art date
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- 239000002173 cutting fluid Substances 0.000 title claims abstract description 26
- 239000011521 glass Substances 0.000 title claims abstract description 16
- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 16
- 238000012545 processing Methods 0.000 title claims abstract description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 claims abstract description 16
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims abstract description 16
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 10
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 10
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000011734 sodium Substances 0.000 claims abstract description 10
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 10
- 229910017083 AlN Inorganic materials 0.000 claims abstract description 9
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims abstract description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000021319 Palmitoleic acid Nutrition 0.000 claims abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 8
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 8
- 229910021538 borax Inorganic materials 0.000 claims abstract description 8
- 239000011575 calcium Substances 0.000 claims abstract description 8
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- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 8
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- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 8
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 8
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 8
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 8
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- 229910052725 zinc Inorganic materials 0.000 claims abstract description 7
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 229920001661 Chitosan Polymers 0.000 claims description 5
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- 229910052782 aluminium Inorganic materials 0.000 claims description 4
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- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- DCRGCLPPXPCTFL-UHFFFAOYSA-N C(C)(=O)OC=C.[O] Chemical compound C(C)(=O)OC=C.[O] DCRGCLPPXPCTFL-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims 1
- 150000002019 disulfides Chemical class 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims 1
- 229910000165 zinc phosphate Inorganic materials 0.000 claims 1
- 238000001816 cooling Methods 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 4
- 238000005461 lubrication Methods 0.000 abstract description 3
- 238000005520 cutting process Methods 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- 238000003754 machining Methods 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 4
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 4
- 239000001099 ammonium carbonate Substances 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 238000003682 fluorination reaction Methods 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000005555 metalworking Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
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- 238000012827 research and development Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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Abstract
本发明公开了一种微晶玻璃加工用微乳化切削液，由以下重量份数的原料组分组成：柠檬酸3‑4份、氟化锆3‑4份、乙二醇12‑14份、三聚磷酸钠2‑3份、棕榈油酸3‑4份、月硅酸聚氧乙烯酯1‑2份、机油12‑14份、纳米蒙脱土1‑2份、石油磺酸钠1‑2份、氮化铝12‑14份、六铝酸钙4‑5份、硼砂1‑2份、纳米氧化铈2‑4份、纳米二氧化钛5‑8份、硝酸钯0.5‑1.5份、500SN基础油0.5‑1.5份、二烷基二硫代磷酸锌0.5‑1.5份、硫酸铵溶液1‑2份、四氯化碳1‑2份、古尔胶2‑4份、多酚2‑4份、低密度聚乙烯0.5‑1.5份、助剂6‑8份、水200份。本发明切削液为透明液体，容易观察切削液的浑浊情况，不易腐坏，低污染，加工时无泡沫，对机床无腐蚀，具有优异的冷却，润滑和清洗性能，可以提高切削工具的使用寿命，工件加工精度高。
Description
技术领域
本发明涉及切削液领域，尤其涉及一种微晶玻璃加工用微乳化切削液。
背景技术
切削液应具备良好的冷却性能、润滑性能、防锈性能、除油清洗功能、防腐功能、易稀释特点。目前切削液可分为两类，油溶性切削液和水溶性切削液。一般油溶性切削液润滑性能好，但冷却性能差，且含有大量有机物，污染环境。一些水溶性切削液虽然冷却性能好，又存在润滑性和防锈效果差的问题，因此研发兼具润滑性、冷却性、防锈性、易清洗、无毒、无味、对人体无侵蚀、对设备不腐蚀、对环境不污染的切削液就显得很重要。
发明内容
本发明创新的提供一种微晶玻璃加工用微乳化切削液。
本发明所采用的技术方案是：
一种微晶玻璃加工用微乳化切削液，由以下重量份数的原料组分组成：柠檬酸3-4份、氟化锆3-4份、乙二醇12-14份、三聚磷酸钠2-3份、棕榈油酸3-4份、月硅酸聚氧乙烯酯1-2份、机油12-14份、纳米蒙脱土1-2份、石油磺酸钠1-2份、氮化铝12-14份、六铝酸钙4-5份、硼砂1-2份、纳米氧化铈2-4份、纳米二氧化钛5-8份、硝酸钯0.5-1.5份、500SN基础油0.5-1.5份、二烷基二硫代磷酸锌0.5-1.5份、硫酸铵溶液1-2份、四氯化碳1-2份、古尔胶2-4份、多酚2-4份、低密度聚乙烯0.5-1.5份、助剂6-8份、水200份。
所述的一种微晶玻璃加工用微乳化切削液，由以下重量份数的原料组分组 成：柠檬酸3份、氟化锆4份、乙二醇13份、三聚磷酸钠2份、棕榈油酸3份、月硅酸聚氧乙烯酯1份、机油13份、纳米蒙脱土2份、石油磺酸钠1份、氮化铝13份、六铝酸钙4份、硼砂2份、纳米氧化铈3份、纳米二氧化钛5份、硝酸钯1份、500SN基础油1份、二烷基二硫代磷酸锌1份、硫酸铵溶液2份、四氯化碳2份、古尔胶2份、多酚3份、低密度聚乙烯1份、助剂7份、水200份。
所述的助剂由下列重量份的原料制成：聚氧乙烯山梨糖醇酐单油酸酯2-3份、纳米氮化铝0.1-0.2份、碳酸氢铵2-3份、乙醇胺1-2份、羧甲基壳聚糖2-3份、二乙二醇丁醚1-2份、丙二醇5-8份、桃胶2-3份、硅酸钠1-2份、尿素3-4份、过硫酸铵1-2份、水20-24份；制备方法是将过硫酸铵溶于水后，再加入其它剩余物料，搅拌10-15分钟，加热至70-80℃，搅拌反应1-2小时，即得。
本发明的有益效果为：本发明切削液为透明液体，容易观察切削液的浑浊情况，不易腐坏，低污染，加工时无泡沫，对机床无腐蚀，具有优异的冷却，润滑和清洗性能，可以提高切削工具的使用寿命，工件加工精度高。
具体实施方式
为了便于本发明内容的理解，下面将结合实施例对本发明作进一步说明，以下实施例仅为本发明的一部分实施例。
实施例1
一种微晶玻璃加工用微乳化切削液，取聚氧乙烯山梨糖醇酐单油酸酯2g、纳米氮化铝0.1g、碳酸氢铵2g、乙醇胺1g、羧甲基壳聚糖2g、二乙二醇丁醚1g、丙二醇5g、桃胶2g、硅酸钠1g、尿素3g、过硫酸铵1g、水20g；制备方 法是将过硫酸铵溶于水后，再加入其它剩余物料，搅拌10-15分钟，加热至70-80℃，搅拌反应1-2小时，即得，取6g备用。
一种微晶玻璃加工用微乳化切削液，由以下份数的原料组分组成：柠檬酸3g、氟化锆3g、乙二醇12g、三聚磷酸钠2g、棕榈油酸3g、月硅酸聚氧乙烯酯1g、机油12g、纳米蒙脱土1g、石油磺酸钠1g、氮化铝12g、六铝酸钙4g、硼砂1g、纳米氧化铈2g、纳米二氧化钛5g、硝酸钯0.5g、500SN基础油0.5g、二烷基二硫代磷酸锌0.5、硫酸铵溶液1g、四氯化碳1g、古尔胶2g、多酚2g、低密度聚乙烯0.5g、助剂6g、水200g。
实施例2
一种微晶玻璃加工用微乳化切削液，取聚氧乙烯山梨糖醇酐单油酸酯2g、纳米氮化铝0.1g、碳酸氢铵2g、乙醇胺1g、羧甲基壳聚糖2g、二乙二醇丁醚1g、丙二醇5g、桃胶2g、硅酸钠1g、尿素3g、过硫酸铵1g、水20g；制备方法是将过硫酸铵溶于水后，再加入其它剩余物料，搅拌10-15分钟，加热至70-80℃，搅拌反应1-2小时，即得，取6g备用。
一种微晶玻璃加工用微乳化切削液，由以下份数的原料组分组成：柠檬酸4g、氟化锆4g、乙二醇14g、三聚磷酸钠3g、棕榈油酸4g、月硅酸聚氧乙烯酯2g、机油14g、纳米蒙脱土2g、石油磺酸钠2g、氮化铝14g、六铝酸钙5g、硼砂2g、纳米氧化铈4g、纳米二氧化钛8g、硝酸钯1.5g、500SN基础油1.5g、二烷基二硫代磷酸锌1.5g、硫酸铵溶液2g、四氯化碳2g、古尔胶4g、多酚g、低密度聚乙烯1.5g、助剂8g、水200g。
实施例3
一种微晶玻璃加工用微乳化切削液，取聚氧乙烯山梨糖醇酐单油酸酯2g、纳米氮化铝0.1g、碳酸氢铵2g、乙醇胺1g、羧甲基壳聚糖2g、二乙二醇丁醚 1g、丙二醇5g、桃胶2g、硅酸钠1g、尿素3g、过硫酸铵1g、水20g；制备方法是将过硫酸铵溶于水后，再加入其它剩余物料，搅拌10-15分钟，加热至70-80℃，搅拌反应1-2小时，即得，取6g备用。
一种微晶玻璃加工用微乳化切削液，由以下份数的原料组分组成：柠檬酸3g、氟化锆4g、乙二醇13g、三聚磷酸钠2g、棕榈油酸3g、月硅酸聚氧乙烯酯1g、机油13g、纳米蒙脱土2g、石油磺酸钠1g、氮化铝13g、六铝酸钙4g、硼砂2g、纳米氧化铈3g、纳米二氧化钛5g、硝酸钯1g、500SN基础油1g、二烷基二硫代磷酸锌1g、硫酸铵溶液2g、四氯化碳2g、古尔胶2g、多酚3g、低密度聚乙烯1g、助剂7g、水200g。
以上内容仅仅是对本发明所作的举例和说明，所属本技术领域的技术人员对所描述的具体实施例做各种各样的修改或补充或采用类似的方式替代，只要不偏离发明的构思或者超越本权利要求书所定义的范围，均应属于本发明的保护范围。
Claims (3)
1.一种微晶玻璃加工用微乳化切削液，其特征在于，由以下重量份数的原料组分组成：柠檬酸3-4份、氟化锆3-4份、乙二醇12-14份、三聚磷酸钠2-3份、棕榈油酸3-4份、月硅酸聚氧乙烯酯1-2份、机油12-14份、纳米蒙脱土1-2份、石油磺酸钠1-2份、氮化铝12-14份、六铝酸钙4-5份、硼砂1-2份、纳米氧化铈2-4份、纳米二氧化钛5-8份、硝酸钯0.5-1.5份、500SN基础油0.5-1.5份、二烷基二硫代磷酸锌0.5-1.5份、硫酸铵溶液1-2份、四氯化碳1-2份、古尔胶2-4份、多酚2-4份、低密度聚乙烯0.5-1.5份、助剂6-8份、水200份。
2.根据权利要求1所述的一种微晶玻璃加工用微乳化切削液，其特征在于，由以下重量份数的原料组分组成：柠檬酸3份、氟化锆4份、乙二醇13份、三聚磷酸钠2份、棕榈油酸3份、月硅酸聚氧乙烯酯1份、机油13份、纳米蒙脱土2份、石油磺酸钠1份、氮化铝13份、六铝酸钙4份、硼砂2份、纳米氧化铈3份、纳米二氧化钛5份、硝酸钯1份、500SN基础油1份、二烷基二硫代磷酸锌1份、硫酸铵溶液2份、四氯化碳2份、古尔胶2份、多酚3份、低密度聚乙烯1份、助剂7份、水200份。
3.根据权利要求1所述的一种微晶玻璃加工用微乳化切削液，其特征在于，所述的助剂由下列重量份的原料制成：聚氧乙烯山梨糖醇酐单油酸酯2-3份、纳米氮化铝0.1-0.2份、碳酸氢铵2-3份、乙醇胺1-2份、羧甲基壳聚糖2-3份、二乙二醇丁醚1-2份、丙二醇5-8份、桃胶2-3份、硅酸钠1-2份、尿素3-4份、过硫酸铵1-2份、水20-24份；制备方法是将过硫酸铵溶于水后，再加入其它剩余物料，搅拌10-15分钟，加热至70-80℃，搅拌反应1-2小时，即得。
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