CN106070229B - 一种氟唑菌苯胺和丁香菌酯的杀菌组合物 - Google Patents
一种氟唑菌苯胺和丁香菌酯的杀菌组合物 Download PDFInfo
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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Abstract
本发明属于农用杀菌剂领域，具体涉及一种有效成分含有氟唑菌苯胺和丁香菌酯的杀菌组合物。本发明组分合理，兼具治疗和保护作用，杀菌效果好，可以减少用药次数、降低用药成本，且杀菌效果不是各组分活性的简单叠加，而是具有显著的增效作用，并且可以减缓抗性的产生，对作物安全性好。
Description
技术领域
本发明属于农用杀菌剂领域，具体涉及一种有效成分含有氟唑菌苯胺和丁香菌酯的杀菌组合物。
背景技术
氟唑菌苯胺，英文通用名：penflufen, 是一种琥珀酸脱氢酶抑制剂，主要作用于呼吸链电子传递复合体II，阻断能量代谢；可以防治种传、土传的担子菌和子囊菌病害,主要有丝核菌引起的马铃薯黑痣病、小麦纹枯病、水稻纹枯病、油菜菌核病等，还有小麦散黑穗病、小麦腥黑穗病、玉米小斑病等。处理后的种子在萌发过程中可以吸收氟唑菌 苯胺，通过木质部传导到植物体的其他部位，起到保护作物的作用。
丁香菌酯，英文通用名：coumoxystrobin, 是一种甲氧基丙烯酸甲酯类化合物，具有保护和治疗作用，是一种高效光谱的农用杀菌剂，对由鞭毛菌、结合菌、子囊菌、担子菌及半知菌引起的植物病害如油菜菌核病、苹果树腐烂病、水稻稻瘟病、香蕉叶斑病、苹果斑点落叶病等有很好的防效。
单一种类的杀菌剂，作用机理往往比较单一，长期反复使用在很多情况下会导致真菌菌株抗药性的产生。不同种类、作用机理的杀菌剂品种进行复配，时防止抗性产生的常用的方法。合理的复配可以扩大杀菌谱、延缓抗药性、减少用药量，本申请发明人在大量室内筛选和田间试验的基础上，筛选出将氟唑菌苯胺与丁香菌酯复配，具有明显的增效作用。且关于氟唑菌苯胺与丁香菌酯复配的目前尚无人报道。
发明内容
本发明的目的在于提供一种具有协同增效作用、使用成本低、防效好的含氟唑菌苯胺和丁香菌酯的增效农药组合物。
为实现上述目的，本发明提出如下技术方案：
一种含有氟唑菌苯胺和丁香菌酯的增效农药组合物，所述氟唑菌苯胺和丁香菌酯的重量比为1:40-30：1，优选的，氟唑菌苯胺和丁香菌酯的重量比为1:10-10:1，更优选的，氟唑菌苯胺和丁香菌酯的重量比为7:3。
进一步的，所述的含氟唑菌苯胺和丁香菌酯的增效组合物，制成可湿性粉剂、水分散粒剂、悬浮剂、水乳剂、微乳剂、悬浮种衣剂。
进一步的，所述组合物用于防除农作物的病害，包括油菜菌核病、水稻纹枯病。
与现有技术相比，本发明的有益效果在于：本发明组分合理，兼具治疗和保护作用，杀菌效果好，可以减少用药次数、降低用药成本，且杀菌效果不是各组分活性的简单叠加，而是具有显著的增效作用，并且可以减缓抗性的产生，对作物安全性好。本发明对油菜菌核病、水稻纹枯病均具有较好的防止效果。
具体实施方式
为了使本发明的目的、技术方案以及优点更加明确，下面结合实施例对本发明进行详细说明。
一、室内毒力测定
试验目标物为水稻纹枯病菌，试验采用菌落直径法。取氟唑菌苯胺和丁香菌酯母液，配置成药液平板，每皿约10mL,同时设置无药平板对照，每处理重复3次。在预培养菌落边缘用灭菌的打孔器制取5mm直径的菌丝快，分别移到不同培养基平板上，28℃培养3天，量取菌落直径（mm）,并计算抑菌率，通过抑制率的机率值和系列浓度的对数值之间的线性回归分析，求出各处理的EC50，用孙云沛法计算混剂的共度系数（CTC），以此来评价药剂对病菌的活性。试验结果见表1。
由表1可以看出，氟唑菌苯胺与丁香菌酯在1:40-30：1时混配对水稻纹枯病菌表现出协同增效作用，其中，当氟唑菌苯胺与丁香菌酯在1：1时共毒系数最高，为191.57。
二、制剂实施例
实施例1:30%氟唑菌苯胺·丁香菌酯可湿性粉剂（1:1）
氟唑菌苯胺 15%
丁香菌酯 15%
十二烷基硫酸钠 1%
木质素磺酸钠 1%
NNO 1%
白炭黑 4%
高岭土 余量
实施例2:20%氟唑菌苯胺·丁香菌酯水分散粒剂（7:3）
氟唑菌苯胺 14%
丁香菌酯 6%
十二烷基硫酸钠 3%
烷基萘磺酸盐 4%
尿素 3%
淀粉 2%
硅藻土 余量
实施例3:50%氟唑菌苯胺·丁香菌酯悬浮剂（9：1）
氟唑菌苯胺 45%
丁香菌酯 5%
十二烷剂苯磺酸钙 15%
有机硅消泡剂 1%
黄原胶 1%
乙二醇 8%
去离子水 余量
三、田间药效试验
为更好的验证本发明的实际应用效果，采用本发明实施例的药剂进行防治水稻纹枯病田间药效试验。
供试药剂：（1）30%氟唑菌苯胺·丁香菌酯可湿性粉剂；（2）20%氟唑菌苯胺·丁香菌酯水分散粒剂；（3）50%氟唑菌苯胺·丁香菌酯悬浮剂；（4）对比例1:30%氟唑菌苯胺悬浮剂（制剂配方同实施例3，不含丁香菌酯）；（4）对比例2:20%丁香菌酯可湿性粉剂（实施例2，不含氟唑菌苯胺）。
分别于施药后10天、30天调查病情指数并计算防效，试验结果见表2：
由表2可以看出，氟唑菌苯胺与丁香菌酯复配具有很好的增效作用，特别是当两者比例为7：3时，在有效成分用量为4g/亩时，防效均高于90%，且表现出很好的增产作用。试验期间，未发现药害，说明所述的组合物对农作物安全性较好。
Claims (4)
1.一种复配杀菌剂，其特征在于，所述杀菌剂活性成分包括氟唑菌苯胺和丁香菌酯，其中，氟唑菌苯胺和丁香菌酯的重量比为1:10-20:1。
2.根据权利要求1所述的复配杀菌剂，其特征在于，所述氟唑菌苯胺和丁香菌酯的重量比优选为7:3。
3.根据权利要求1所述的复配杀菌剂，其特征在于，它的剂型为可湿性粉剂、水分散粒剂、悬浮剂、水乳剂、微乳剂、悬浮种衣剂中任一种。
4.根据权利要求1-3中任一项权利要求所述的复配杀菌剂用于防治农作物病害的用途。
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| CN104161042A (zh) * | 2013-05-18 | 2014-11-26 | 陕西美邦农药有限公司 | 一种含氟唑菌苯胺与甲氧基丙烯酸酯类的农药组合物 |
| EP2807924A1 (en) * | 2013-05-28 | 2014-12-03 | Basf Se | A method for combating fungal turfgrass pathogens |
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