CN106009714A - Thermoplastic elastomer composition, resin, preparation method thereof and application thereof in manufacturing runways and courts - Google Patents
Thermoplastic elastomer composition, resin, preparation method thereof and application thereof in manufacturing runways and courts Download PDFInfo
- Publication number
- CN106009714A CN106009714A CN201610333367.4A CN201610333367A CN106009714A CN 106009714 A CN106009714 A CN 106009714A CN 201610333367 A CN201610333367 A CN 201610333367A CN 106009714 A CN106009714 A CN 106009714A
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- China
- Prior art keywords
- thermoplastic elastomer
- resin
- mixing
- composition
- white oil
- Prior art date
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- Granted
Links
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 67
- 239000011347 resin Substances 0.000 title claims abstract description 56
- 229920005989 resin Polymers 0.000 title claims abstract description 55
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims abstract description 22
- -1 polypropylene Polymers 0.000 claims abstract description 20
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 11
- 239000004743 Polypropylene Substances 0.000 claims abstract description 10
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 10
- 239000000314 lubricant Substances 0.000 claims abstract description 10
- 229920001155 polypropylene Polymers 0.000 claims abstract description 10
- 239000004611 light stabiliser Substances 0.000 claims description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- 238000001125 extrusion Methods 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 230000003064 anti-oxidating effect Effects 0.000 claims description 9
- 239000012467 final product Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 7
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 7
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 claims description 7
- 239000011787 zinc oxide Substances 0.000 claims description 7
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 239000006096 absorbing agent Substances 0.000 claims description 6
- 239000012188 paraffin wax Substances 0.000 claims description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 5
- 239000008116 calcium stearate Substances 0.000 claims description 5
- 235000013539 calcium stearate Nutrition 0.000 claims description 5
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 claims description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 4
- 230000005764 inhibitory process Effects 0.000 claims description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 4
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical class [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000004200 microcrystalline wax Substances 0.000 claims description 3
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 3
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 3
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 2
- 229910052625 palygorskite Inorganic materials 0.000 claims description 2
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 5
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 12
- 239000002250 absorbent Substances 0.000 description 9
- 230000002745 absorbent Effects 0.000 description 9
- 239000004567 concrete Substances 0.000 description 6
- 238000011056 performance test Methods 0.000 description 6
- 239000004568 cement Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 238000004500 asepsis Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 description 2
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 2
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000000386 athletic effect Effects 0.000 description 2
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- RLRINNKRRPQIGW-UHFFFAOYSA-N 1-ethenyl-2-[4-(2-ethenylphenyl)butyl]benzene Chemical compound C=CC1=CC=CC=C1CCCCC1=CC=CC=C1C=C RLRINNKRRPQIGW-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 230000008736 traumatic injury Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C13/00—Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
- E01C13/06—Pavings made in situ, e.g. for sand grounds, clay courts E01C13/003
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a thermoplastic elastomer composition, a resin, a preparation method thereof and application thereof in running and court; the thermoplastic elastomer composition comprises 20-40% of SEBS resin by mass percent; 20-50% of white oil; polypropylene: 10 to 30 percent; 10-30% of filler; 0.2-1% of lubricant; 0.3 to 0.6 percent of antioxidant auxiliary agent; 0.2 to 0.4 percent of anti-aging auxiliary agent; 0.05 to 0.2 percent of cross-linking agent; 0.2 to 2 percent of wear-resistant auxiliary agent; wherein the sum of the mass percentages of the components meets 100 percent. The thermoplastic elastomer resin is prepared from the thermoplastic elastomer composition. The thermoplastic elastomer composition and the resin are used for preparing outdoor runways and courts, and can improve the wear resistance and weather resistance of outdoor European sports fields such as runways or courts in the using process.
Description
Technical field
The present invention relates to macromolecular material extremely processing technique field, be specifically related to a kind of thermoplastic elastomer (TPE) group
Compound, resin and preparation method thereof and its application in runway and court.
Background technology
Plastic cement race track is also known as round-the-clock athletics tracks, and it is by base polyurethane prepolymer for use as, admixtured polyether, useless wheel
Tire rubber, EPDM rubber grain or PU granule, pigment, auxiliary agent, filler composition.Plastic cement race track has smooth
Spend, comprcssive strength is high, hardness is elastic suitably, the characteristic of stable physical property, beneficially athlete's speed
With the performance of technology, it is effectively improved sports achievement, reduces traumatic injury rate.
The composition material that plastic cement race track or court are commonly used is that styrene-based-ethylene/butylene-styrene block is common
The thermoplastic elastomer (TPE) (TPE) of polymers (SEBS), said composition is a kind of to have the high resiliency of rubber, height
The material of intensity, environment-protecting asepsis, processing characteristics are superior, and the course of processing need not vulcanize, and waste and scrap can follow
Ring uses, and reduces environmental hazard.But, when it is as the material in plastic cement race track and outdoor court, one
Aspect can not meet the demand accepting high temperature or strong ultraviolet radiation for a long time, on the other hand can not meet motion right
Demand in anti-wear performance.
Summary of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of thermoplastic elastomer (TPE) combination
Thing, improves material anti-wear performance during the use on the outdoor athletic ground, Europe such as runway or court and weather-proof
Performance.
For solving the problems referred to above, the technical solution adopted in the present invention is as follows:
A kind of composition for thermoplastic elastomer, it following raw material including being calculated in mass percent calculation:
SEBS resin: 20-40%；
White oil: 20-50%；
Polypropylene: 10-30%；
Filler: 10-30%；
Lubricant: 0.2-1%；
Antioxidation auxiliary agent: 0.3-0.6%；
Antiager: 0.2-0.4%；
Cross-linking agent: 0.05-0.2%；
Antiwear assistant: 0.2-2%；
The mass percent sum of the most each component meets 100%.
Described SEBS resin is one or both mixing in star-like SEBS resin, line style SEBS resin.
Described white oil be kinematic viscosity be 30mm-70mm2/ s, color inhibition grade more than 4 grades naphthenic base white oil,
One or both mixing in paraffin wax base white oil；Described polypropylene is in HOPP, COPP
One or both mixing；Described filler is calcium carbonate powder, barium sulfate powder, Pulvis Talci, mica powder, recessed
One or both mixing in convex rod powder.
Described lubricant is Tissuemat E, calcium stearate, zinc stearate, microcrystalline wax, erucyl amide, hard
One or more mixing in fat acid butyl ester, oleamide, titanate esters；Described antioxidation auxiliary agent is anti-
Oxygen agent 1098, antioxidant 1010, antioxidant 245, antioxidant 1076, irgasfos 168, thio-2 acid
One or more mixing in the double lauryl of double octadecyl esters, thio-2 acid；Described antiager is
UV absorbent UV-0, UV absorbent UV-9, ultraviolet absorbent UV-531, ultra-violet absorption
Agent UVP-327, light stabilizer AM101, light stabilizer GW-540, light stabilizer 744, light stabilizer
One or more mixing in 770；Described cross-linking agent is cumyl peroxide, dual-tert-butyl peroxidating
One or both mixing in diisopropyl benzene；Described antiwear assistant is four acicular type zinc oxide crystal whisker.
Another object of the present invention is to provide a kind of thermoplastic elastomer resin, it is by of the present invention
Composition for thermoplastic elastomer be prepared from, there is good anti-wear performance and weather resistance；Concrete scheme
As follows:
A kind of thermoplastic elastomer resin, this thermoplastic elastomer resin is by thermoplastic elastomehc of the present invention
Elastomeric composition is prepared from.
Third object of the present invention is providing the preparation method of a kind of thermoplastic elastomer resin, passes through the party
Method obtains thermoplastic elastomer resin of the present invention, and obtained thermoplastic elastomer resin can be used for family
Outer track or the making in court.
A kind of preparation method of thermoplastic elastomer resin, this preparation method comprises the following steps:
1) according to the proportioning in the composition for thermoplastic elastomer described in any one of claim 1-5, by SEBS
Resin and white oil mixing uniformly stand 12-24 hour, obtain mixture for 5-10 minute；
2) in said mixture add polypropylene, filler, lubricant, antioxidation auxiliary agent, antiager,
Cross-linking agent and antiwear assistant, mix homogeneously；
3) by double screw extruder extrusion, pelletize, to obtain final product
Preparation method the most according to claim 6, it is characterised in that step 3) in twin-screw extrusion
Machine one district temperature is 150～170 DEG C, and head and other each district temperature are 190～230 DEG C.
Fourth object of the present invention is to provide a kind of composition for thermoplastic elastomer, resin making open air
Application in runway and/or court.
The composition for thermoplastic elastomer of the present invention application in making outdoor runway and/or court.
The thermoplastic elastomer resin of the present invention application in making outdoor runway and/or court.
Compared to existing technology, the beneficial effects of the present invention is:
Composition for thermoplastic elastomer the most of the present invention, resin-phase can significantly improve for prior art
The anti-wear performance of thermoplastic elastomer (TPE)；
Composition for thermoplastic elastomer the most of the present invention, resin have excellence weather resistance and
Without foaming phenomena during use, have no irritating odor, environment-protecting asepsis.
Below in conjunction with detailed description of the invention, the present invention is described in further detail.
Detailed description of the invention
Composition for thermoplastic elastomer of the present invention, it following raw material including being calculated in mass percent calculation:
SEBS resin: 20-40%；
White oil: 20-50%；
Polypropylene: 10-30%；
Filler: 10-30%；
Lubricant: 0.2-1%；
Antioxidation auxiliary agent: 0.3-0.6%；
Antiager: 0.2-0.4%；
Cross-linking agent: 0.05-0.2%；
Antiwear assistant: 0.2-2%；
The mass percent sum of the most each component meets 100%.
Described SEBS resin is one or both mixing in star-like SEBS resin, line style SEBS resin.
Described white oil be kinematic viscosity be 30mm-70mm2/ s, the color inhibition grade cycloalkyl more than 4 grades is white
One or both mixing in oil, paraffin wax base white oil；Viscosity is 30mm-70mm2/ s, color inhibition grade is more than
The naphthenic base white oil of 4 grades, paraffin wax base white oil can make thermoplastic elastic material have excellence weather resistance and
And in use without foaming phenomena, have no irritating odor, environment-protecting asepsis.Described polypropylene is that homopolymerization gathers
One or both mixing in propylene, COPP；Described filler be calcium carbonate powder, barium sulfate powder,
One or both mixing in Pulvis Talci, mica powder, attapulgite.
Described lubricant is Tissuemat E, calcium stearate, zinc stearate, microcrystalline wax, erucyl amide, hard
One or more mixing in fat acid butyl ester, oleamide, titanate esters；Described antioxidation auxiliary agent is anti-
Oxygen agent 1098, antioxidant 1010, antioxidant 245, antioxidant 1076, irgasfos 168, thio-2 acid
One or more mixing in the double lauryl of double octadecyl esters, thio-2 acid；Described antiager is
UV absorbent UV-0, UV absorbent UV-9, ultraviolet absorbent UV-531, ultra-violet absorption
Agent UVP-327, light stabilizer AM101, light stabilizer GW-540, light stabilizer 744, light stabilizer
One or more mixing in 770；Described cross-linking agent is cumyl peroxide, dual-tert-butyl peroxidating
One or both mixing in diisopropyl benzene；Described antiwear assistant is four acicular type zinc oxide crystal whisker；At this
In bright, research finds that four acicular type zinc oxide crystal whisker can significantly improve the anti-wear performance of thermoplastic elastomer (TPE).
Another object of the present invention is to provide a kind of thermoplastic elastomer resin, it is by of the present invention
Composition for thermoplastic elastomer be prepared from, there is good anti-wear performance and weather resistance；Concrete scheme
As follows:
A kind of thermoplastic elastomer resin, this thermoplastic elastomer resin is by thermoplastic elastomehc of the present invention
Elastomeric composition is prepared from.
Third object of the present invention is providing the preparation method of a kind of thermoplastic elastomer resin, passes through the party
Method obtains thermoplastic elastomer resin of the present invention, and obtained thermoplastic elastomer resin can be used for family
Outer track or the making in court.
A kind of preparation method of thermoplastic elastomer resin, this preparation method comprises the following steps:
1) according to the proportioning in the composition for thermoplastic elastomer described in any one of claim 1-5, by SEBS
Resin and white oil mixing uniformly stand 12-24 hour, obtain mixture for 5-10 minute；
2) in said mixture add polypropylene, filler, lubricant, antioxidation auxiliary agent, antiager,
Cross-linking agent and antiwear assistant, mix homogeneously；
3) by double screw extruder extrusion, pelletize, to obtain final product
Preparation method the most according to claim 6, it is characterised in that step 3) in twin-screw extrusion
Machine one district temperature is 150～170 DEG C, and head and other each district temperature are 190～230 DEG C.
Fourth object of the present invention is to provide a kind of composition for thermoplastic elastomer, resin making open air
Application in runway and/or court.
The composition for thermoplastic elastomer of the present invention application in making outdoor runway and/or court.
The thermoplastic elastomer resin of the present invention application in making outdoor runway and/or court.
The following is specific embodiment of the present invention, in the following embodiments raw material, auxiliary agents used and setting more
For all being obtained by buying pattern.
Embodiment 1:
A kind of thermoplastic elastomer resin, its concrete preparation method is as follows:
1) the paraffin wax base white oil of the star-like SEBS resin of 20wt%, 37wt% is added high speed mixer, mixed
Close 5 minutes, then stand 12 hours；
2) COPP of 10wt%, the Pulvis Talci of 30wt%, the calcium stearate of 1wt%, 0.2wt% are added
Antioxidant 1098, the irgasfos 168 of 0.1wt%, the cumyl peroxide of 0.1wt%, the purple of 0.2wt%
The four acicular type zinc oxide crystal whisker mixing of the light stabilizer 770 and 1.2wt% of ultraviolet absorbers UV-9,0.2wt%
10 minutes；
3) material mixed being added double screw extruder, double screw extruder one district temperature is 150～170
DEG C, head and other each district temperature are 190～230 DEG C；Extrusion, pelletize, to obtain final product.
The performance test data such as table of environment-friendly type wear-resisting weather-proof composition for thermoplastic elastomer prepared by the present embodiment
Shown in 1.
Embodiment 2:
A kind of thermoplastic elastomer resin, its concrete preparation method is as follows:
1) naphthenic base white oil of the line style SEBS resin of 40wt%, 20wt% is added high speed mixer, mixed
Close 7 minutes, then stand 15 hours；
2) HOPP of 20wt%, the Pulvis Talci of 18wt%, the PE wax of 0.8wt%, 0.3wt% are added
Antioxidant 245, the double octadecyl ester of thio-2 acid of 0.3wt%, the cumyl peroxide of 0.1wt%,
UV absorbent UVP-327 of 0.2wt%, the four needle-like oxygen of light stabilizer 744 and 0.2wt% of 0.1wt%
Change zinc whisker to mix 8 minutes；
3) material mixed being added double screw extruder, double screw extruder one district temperature is 150～170
DEG C, head and other each district temperature are 190～230 DEG C, and pelletize after extrusion to obtain final product.
The performance test data such as table of environment-friendly type wear-resisting weather-proof composition for thermoplastic elastomer prepared by the present embodiment
Shown in 1.
Embodiment 3:
A kind of thermoplastic elastomer resin, its concrete preparation method is as follows:
1) by the line style SEBS resin of 20wt%, the star-like resin of high molecular of 10wt%, the stone of 40wt%
Cerul white oil adds high speed mixer, mixes 10 minutes, then stands 24 hours；
2) COPP of 10wt%, the Pulvis Talci of 10wt%, the zinc stearate of 0.2wt%, 0.5wt% are added
Antioxidant 1010, the dilauryl thiodipropionate of 0.3wt%, the irgasfos 168 of 0.2wt%, 0.2wt%
Dual-tert-butyl dicumyl peroxide, the ultraviolet absorbent UV-531 of 0.1wt%, 0.1wt% light steady
The four acicular type zinc oxide crystal whisker determining agent AM101,1.4wt% mixes 10 minutes；
3) material mixed being added double screw extruder, double screw extruder one district temperature is 150～170
DEG C, head and other each district temperature are 190～230 DEG C, and pelletize after extrusion to obtain final product.
The performance test data such as table of environment-friendly type wear-resisting weather-proof composition for thermoplastic elastomer prepared by the present embodiment
Shown in 1.
Embodiment 4:
A kind of thermoplastic elastomer resin, its concrete preparation method is as follows:
1) the paraffinic base white oil of the star-like SEBS resin of 15.8wt%, 30wt% is added high speed mixer,
Mix 9 minutes, then stand 20 hours；
2) add the HOPP of 30wt%, the barium sulfate powder of 20wt%, the erucyl amide of 0.25wt%,
The antioxidant 1076 of 0.4wt%, the dilauryl thiodipropionate of 0.2wt%, the irgasfos 168 of 0.2wt%,
The dual-tert-butyl dicumyl peroxide of 0.15wt%, UV absorbent UV-0 of 0.5wt%, 0.5wt%
Light stabilizer GW-540,2wt% four acicular type zinc oxide crystal whisker mix 10 minutes；
3) material mixed being added double screw extruder, double screw extruder one district temperature is 150～170
DEG C, head and other each district temperature are 190～230 DEG C, and pelletize after extrusion to obtain final product.
The performance test data such as table of environment-friendly type wear-resisting weather-proof composition for thermoplastic elastomer prepared by the present embodiment
Shown in 1.
Comparative example 1:
1) the paraffin wax base white oil of the star-like SEBS resin of 20wt%, 37wt% is added high speed mixer, mixed
Close 5 minutes, then stand 12 hours；
2) COPP of 10wt%, the Pulvis Talci of 30wt%, the calcium stearate of 1wt%, 0.2wt% are added
Antioxidant 1098, the irgasfos 168 of 0.1wt%, the cumyl peroxide of 0.1wt%, the purple of 0.2wt%
The silicone powder of the light stabilizer 770 and 1.2wt% of ultraviolet absorbers UV-9,0.2wt% mixes 10 minutes；
3) material mixed being added double screw extruder, double screw extruder one district temperature is 150～170
DEG C, head and other each district temperature are 190～230 DEG C, and pelletize after extrusion to obtain final product.
The performance test data such as table of environment-friendly type wear-resisting weather-proof composition for thermoplastic elastomer prepared by this comparative example
Shown in 1.
Table 1: embodiment 1-4 and the performance test data of comparative example 1
Note: 1. xenon lamp aging test condition: black standard temperature (65 ± 5) DEG C, relative humidity (50 ± 5) %, spray cycle:
Water spraying time 18 ± 0.5 minutes every time, sprays water interval time: 102 ± 0.5 minutes, exposure time 2000 hours,
Irradiance 550w/m2
2.Taber wears away condition: H-18 emery wheel, counterweight 2000g, revolution 1000r, rotating speed 72rpm
As can be seen from Table 1, the thermoplastic elastomer resin described in embodiment 1-4, test through xenon lamp aging
After, there is excellent bending strength conservation rate, case hardness conservation rate, and surface without telling oil, crack performance.
Taber wear test illustrates that this material has the anti-wear performance of excellence.The material of the present invention have excellence wear-resisting,
Weather resistance, and material environment friendly, nontoxic, in use will not cause infringement to human body, price is low,
Easy to process, waste material can reclaim, and does not results in the pollution of environment, is to prepare plastic cement race track and outdoor ball
Appropriately selected.
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to limit present invention protection with this
Scope, the change of any unsubstantiality that those skilled in the art is done on the basis of the present invention and replacement
Belong to scope of the present invention.
Claims (9)
1. a composition for thermoplastic elastomer, it is characterised in that it following raw material including being calculated in mass percent calculation:
SEBS resin: 20-40%；
White oil: 20-50%；
Polypropylene: 10-30%；
Filler: 10-30%；
Lubricant: 0.2-1%；
Antioxidation auxiliary agent: 0.3-0.6%；
Antiager: 0.2-0.4%；
Cross-linking agent: 0.05-0.2%；
Antiwear assistant: 0.2-2%；
The mass percent sum of the most each component meets 100%.
Composition for thermoplastic elastomer the most according to claim 1, it is characterised in that described SEBS resin is one or both mixing in star-like SEBS resin, line style SEBS resin.
Composition for thermoplastic elastomer the most according to claim 1, it is characterised in that described white oil be kinematic viscosity be 30mm2/s-70mm2/ s, the color inhibition grade naphthenic base white oil more than 4 grades, one or both mixing in paraffin wax base white oil；Described polypropylene is one or both mixing in HOPP, COPP；Described filler is one or both mixing in calcium carbonate powder, barium sulfate powder, Pulvis Talci, mica powder, attapulgite.
Composition for thermoplastic elastomer the most according to claim 1, it is characterized in that, described lubricant is one or more mixing in Tissuemat E, calcium stearate, zinc stearate, microcrystalline wax, erucyl amide, butyl stearate, oleamide, titanate esters；Described antioxidation auxiliary agent is one or more mixing in antioxidant 1098, antioxidant 1010, antioxidant 245, antioxidant 1076, irgasfos 168, the double octadecyl ester of thio-2 acid, the double lauryl of thio-2 acid；Described antiager is one or more mixing in UV absorbers UV-0, UV absorbers UV-9, UV absorbers UV-531, UV absorbers UVP-327, light stabilizer AM101, light stabilizer GW-540, light stabilizer 744, light stabilizer 770；Described cross-linking agent is one or both mixing in cumyl peroxide, dual-tert-butyl dicumyl peroxide；Described antiwear assistant is four acicular type zinc oxide crystal whisker.
5. the thermoplastic elastomer resin of a kind, it is characterised in that this thermoplastic elastomer resin is prepared from by the composition for thermoplastic elastomer described in any one of claim 1-5.
6. the preparation method of a thermoplastic elastomer resin as claimed in claim 5, it is characterised in that this preparation method comprises the following steps:
1) according to the proportioning in the composition for thermoplastic elastomer described in any one of claim 1-5, by SEBS resin and white oil mixing 5-10 minute uniformly, stand 12-24 hour, obtain mixture；
2) in said mixture, polypropylene, filler, lubricant, antioxidation auxiliary agent, antiager, cross-linking agent and antiwear assistant, mix homogeneously are added；
3) by double screw extruder extrusion, pelletize, to obtain final product.
Preparation method the most according to claim 6, it is characterised in that step 3) in double screw extruder one district temperature be 150～170 DEG C, head and other each district temperature are 190～230 DEG C.
8. the application in making outdoor runway and/or court of the composition for thermoplastic elastomer described in claim 1.
9. the application in making outdoor runway and/or court of the thermoplastic elastomer resin described in claim 5.
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