CN106009493A - 酚醛泡沫外墙保温材料及其制备方法 - Google Patents
酚醛泡沫外墙保温材料及其制备方法 Download PDFInfo
- Publication number
- CN106009493A CN106009493A CN201610624855.0A CN201610624855A CN106009493A CN 106009493 A CN106009493 A CN 106009493A CN 201610624855 A CN201610624855 A CN 201610624855A CN 106009493 A CN106009493 A CN 106009493A
- Authority
- CN
- China
- Prior art keywords
- parts
- insulation material
- phenol formaldehyde
- wall heat
- formaldehyde foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012774 insulation material Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000006260 foam Substances 0.000 title abstract description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title abstract description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 29
- 239000012745 toughening agent Substances 0.000 claims abstract description 21
- 229920003987 resole Polymers 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000004088 foaming agent Substances 0.000 claims abstract description 8
- 239000010439 graphite Substances 0.000 claims abstract description 8
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012266 salt solution Substances 0.000 claims abstract description 5
- 238000005187 foaming Methods 0.000 claims abstract 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 18
- 239000013078 crystal Substances 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 14
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 12
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 7
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 6
- 229920000053 polysorbate 80 Polymers 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 229940001468 citrate Drugs 0.000 claims description 2
- 229940001447 lactate Drugs 0.000 claims description 2
- 229940049920 malate Drugs 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 229940095064 tartrate Drugs 0.000 claims description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 238000007711 solidification Methods 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 238000009413 insulation Methods 0.000 abstract description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract 1
- 229920000136 polysorbate Polymers 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- 229920005830 Polyurethane Foam Polymers 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 3
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 3
- 239000011496 polyurethane foam Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- -1 phenolic aldehyde Chemical class 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 239000001433 sodium tartrate Substances 0.000 description 2
- 229960002167 sodium tartrate Drugs 0.000 description 2
- 235000011004 sodium tartrates Nutrition 0.000 description 2
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000008156 Ringer's lactate solution Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011489 building insulation material Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 150000003893 lactate salts Chemical group 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/145—Halogen containing compounds containing carbon, halogen and hydrogen only only chlorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/08—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
本发明提出了一种酚醛泡沫外墙保温材料及其制备方法，按重量份数计算，包括以下原料：甲阶酚醛树脂60～70份、硫酸钙晶须4～8份、表面活性剂3～6份、发泡剂5～10份、固化剂10～15份与增韧剂3～6份，所述增韧剂是纳米氢氧化铝与氧化石墨在醇酸盐溶液中形成的混合物。制备方法：包括以下步骤：1)将甲阶酚醛树脂、硫酸钙晶须、固化剂以及增韧剂在40～60℃条件下进行混合均匀，得到混合物A；2)将混合物A、表面活性剂以及发泡剂混合搅拌均匀，快速倒入预热的模具中发泡，固化即可。该保温板强度和氧指数高，导热系数低。
Description
技术领域
本发明属于建筑外墙材料技术领域，具体涉及一种酚醛泡沫外墙保温材料及其制备方法。
背景技术
酚醛保温板和聚氨酯硬泡同属有机类热固性高效保温材料，尤其近年建筑节能率的逐渐提高，应用保温材料技术性能越来越高，市场需求量越来越大。在建筑应用保温材料应用中，不但要求物理技术性能高，而且必须达到防火性能。甲阶酚醛树脂生产的泡沫和聚氨酯硬泡虽属相对较好的保温材料，但两类保温材料各有不同的优、缺点，不具有很好综合技术性能。聚氨酯树脂合成的聚氨酯硬泡，具有轻质、高强、导热系数低、韧性好和施工方便等特点，但防火性能最高只能达到B1级防火性能、氧指数最高只能达到30％。
甲阶酚醛树脂生产的酚醛保温板，具备聚氨酯硬泡保温材料主要基本优点，但防火性能比聚氨酯硬泡突出，耐火燃穿透、耐高温、低烟，氧指数高达50％，但酚醛保温板与聚氨酯硬泡比较，酚醛保温板最大的缺点是脆性大、酸性大。由于酚醛保温板的脆性大，酚醛保温板在使用时存在掉粉、弹性低、压缩强度低，导热系数不达标等问题，固有优异防火性能没能得到很好利用，因此，影响该产品应用技术的扩展，同时给运输、施工带来很多不便。尤其拉拔强度低，不易满足相关标准要求。由于酸性大，使得酚醛保温板与金属、水泥基材料接触会有一定腐蚀性。
发明内容
为了解决以上酚醛泡沫板的导热系数较高、韧性不好的问题，本发明提出一种酚醛泡沫外墙保温材料，该保温板强度和氧指数高，导热系数低。
本发明的技术方案是这样实现的：
一种酚醛泡沫外墙保温材料，按重量份数计算，包括以下原料：
甲阶酚醛树脂60～70份、硫酸钙晶须4～8份、表面活性剂3～6份、发泡剂5～10份、固化剂10～15份与增韧剂3～6份，所述增韧剂是纳米氢氧化铝与氧化石墨在醇酸盐溶液中形成的混合物。
进一步，所述醇酸盐为乳酸盐、苹果酸盐、酒石酸盐或者柠檬酸盐；优选为乳酸钠、苹果酸钠、酒石酸钠或者柠檬酸钠。
进一步，所述醇酸盐溶液的浓度为3～8wt％。
进一步，所述表面活性剂为吐温80。
进一步，所述发泡剂为环戊烷、正戊烷或二氯甲烷。
进一步，所述固化剂为磷酸和对甲苯磺酸的混合酸或者盐酸。
本发明的另一个目的是提供一种酚醛泡沫外墙保温材料的制备方法，包括以下步骤：
1)将甲阶酚醛树脂、硫酸钙晶须、固化剂以及增韧剂在40～60℃条件下进行混合均匀，得到混合物A；
2)将混合物A、表面活性剂以及发泡剂混合搅拌均匀，快速倒入预热的模具中发泡，固化即可。
进一步，所述步骤2)预热模具的预热温度为30～50℃。
本发明有益效果：
1、本发明的酚醛泡沫外墙保温材料其增韧剂是纳米氢氧化铝与氧化石墨在醇酸盐溶液中形成的混合物，增韧效果显著，并且具有更好的阻燃与耐热性能。在40～60℃条件下，甲阶酚醛树脂、固化剂以及增韧剂进行混合，有利于甲阶酚醛树脂的增韧改性。
2、硫酸钙晶须是以石膏为原材料,通过人为控制,以单晶形式生长的，具有均匀的横截面、完整的外形、完善的内部结构的纤维状单晶体。硫酸钙晶须集增强纤维和超细无机填料二者的优势于一体。与目前常用的填充剂相比较,晶须材料可显著增强材料的强度、韧性。
3、本发明的酚醛泡沫外墙保温材料的25℃导热系数为0.023～0.027W/m·K，压缩强度为0.246～0.258MPa，垂直于板面强度为0.123～0.131MPa，氧指数为62～68。
具体实施方式
实施例1
一种酚醛泡沫外墙保温材料，按重量份数计算，包括以下原料：
甲阶酚醛树脂65份、硫酸钙晶须6份、4份吐温80、环戊烷7份、磷酸和对甲苯磺酸的混合酸12份与增韧剂4份，增韧剂是纳米氢氧化铝与氧化石墨在5wt％柠檬酸钠溶液中形成的混合物。
制备方法，包括以下步骤：
1)将甲阶酚醛树脂、硫酸钙晶须、磷酸和对甲苯磺酸的混合酸以及增韧剂在50℃条件下进行混合均匀，得到混合物A；
2)将混合物A、吐温80以及环戊烷混合搅拌均匀，快速倒入40℃预热的模具中发泡，固化即可。
实施例2
一种酚醛泡沫外墙保温材料，按重量份数计算，包括以下原料：
甲阶酚醛树脂60份、硫酸钙晶须4份、3份吐温80、正戊烷5份、盐酸11份与增韧剂3份，增韧剂是纳米氢氧化铝与氧化石墨在3wt％酒石酸钠溶液中形成的混合物。
制备方法，包括以下步骤：
1)将甲阶酚醛树脂、盐酸、硫酸钙晶须以及增韧剂在40℃条件下进行混合均匀，得到混合物A；
2)将混合物A、吐温80以及正戊烷混合搅拌均匀，快速倒入30℃预热的模具中发泡，固化即可。
实施例3
一种酚醛泡沫外墙保温材料，按重量份数计算，包括以下原料：
甲阶酚醛树脂68份、硫酸钙晶须7份、5份吐温80、正戊烷8份、磷酸和对甲苯磺酸的混合酸(磷酸与对苯磺酸的质量比为3:1)10份与增韧剂5份，增韧剂是纳米氢氧化铝与氧化石墨在7wt％乳酸钠溶液中形成的混合物。
制备方法，包括以下步骤：
1)将甲阶酚醛树脂、硫酸钙晶须、磷酸和对甲苯磺酸的混合酸以及增韧剂在55℃条件下进行混合均匀，得到混合物A；
2)将混合物A、吐温80以及正戊烷混合搅拌均匀，快速倒入45℃预热的模具中发泡，固化即可。
实施例4
一种酚醛泡沫外墙保温材料，按重量份数计算，包括以下原料：
甲阶酚醛树脂70份、硫酸钙晶须8份、6份吐温80、二氯甲烷10份、盐酸15份与增韧剂6份，增韧剂是纳米氢氧化铝与氧化石墨在6wt％苹果酸钠溶液中形成的混合物。
制备方法，包括以下步骤：
1)将甲阶酚醛树脂、硫酸钙晶须、盐酸以及增韧剂在60℃条件下进行混合均匀，得到混合物A；
2)将混合物A、吐温80以及二氯甲烷混合搅拌均匀，快速倒入50℃预热的模具中发泡，固化即可。
实施例5
将实施例1-4制备得到的保温板进行性能检测，结果见表1。
表1实施例1-4保温板性能检测结果
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (8)
1.一种酚醛泡沫外墙保温材料，其特征在于，按重量份数计算，包括以下原料：
甲阶酚醛树脂60～70份、硫酸钙晶须4～8份、表面活性剂3～6份、发泡剂5～10份、固化剂10～15份与增韧剂3～6份，所述增韧剂是纳米氢氧化铝与氧化石墨在醇酸盐溶液中形成的混合物。
2.根据权利要求1所述的酚醛泡沫外墙保温材料，其特征在于，所述醇酸盐为乳酸盐、苹果酸盐、酒石酸盐或者柠檬酸盐。
3.根据权利要求1或2所述的酚醛泡沫外墙保温材料，其特征在于，所述醇酸盐溶液的浓度为3～8wt％。
4.根据权利要求1或2所述的酚醛泡沫外墙保温材料，其特征在于，所述表面活性剂为吐温80。
5.根据权利要求1或2所述的酚醛泡沫外墙保温材料，其特征在于，所述发泡剂为环戊烷、正戊烷或二氯甲烷。
6.根据权利要求1或2所述的酚醛泡沫外墙保温材料，其特征在于，所述固化剂为磷酸和对甲苯磺酸的混合酸或者盐酸。
7.一种如权利要求1所述的酚醛泡沫外墙保温材料的制备方法，其特征在于，包括以下步骤：
1)将甲阶酚醛树脂、硫酸钙晶须、固化剂以及增韧剂在40～60℃条件下进行混合均匀，得到混合物A；
2)将混合物A、表面活性剂以及发泡剂混合搅拌均匀，快速倒入预热的模具中发泡，固化即可。
8.根据权利要求7所述的酚醛泡沫外墙保温材料的制备方法，其特征在于，所述步骤2)预热模具的预热温度为30～50℃。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610624855.0A CN106009493A (zh) | 2016-08-01 | 2016-08-01 | 酚醛泡沫外墙保温材料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610624855.0A CN106009493A (zh) | 2016-08-01 | 2016-08-01 | 酚醛泡沫外墙保温材料及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106009493A true CN106009493A (zh) | 2016-10-12 |
Family
ID=57133695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610624855.0A Pending CN106009493A (zh) | 2016-08-01 | 2016-08-01 | 酚醛泡沫外墙保温材料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106009493A (zh) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106928648A (zh) * | 2017-04-20 | 2017-07-07 | 北京石油化工学院 | 一种晶须增强增韧无卤阻燃酚醛泡沫塑料及其制备方法 |
| CN107459765A (zh) * | 2017-08-03 | 2017-12-12 | 合肥泓定科技有限公司 | 酚醛泡沫保温板及其制备方法 |
| GB2563043A (en) * | 2017-05-31 | 2018-12-05 | Acell Ind Ltd | Phenolic moulding material |
| WO2019211559A1 (fr) * | 2018-05-04 | 2019-11-07 | Saint-Gobain Isover | Materiau d'isolation thermique comprenant des particules d'oyde de graphite partiellement oxydees |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1834152A (zh) * | 2006-03-21 | 2006-09-20 | 上海胜星树脂涂料有限公司 | 一种常温发泡制备酚醛泡沫保温材料的方法 |
| CN102924864A (zh) * | 2012-11-27 | 2013-02-13 | 北京立高防水工程有限公司 | 改性环保酚醛保温材料及其制备方法 |
| CN103589197A (zh) * | 2013-11-25 | 2014-02-19 | 桂林理工大学 | 一种采用氧化石墨烯制备增韧剂的方法及其应用 |
| CN103694625A (zh) * | 2013-12-19 | 2014-04-02 | 山东圣泉化工股份有限公司 | 一种改性酚醛泡沫体 |
| CN103788570A (zh) * | 2012-10-31 | 2014-05-14 | 合肥杰事杰新材料股份有限公司 | 一种改性酚醛泡沫体及其制备方法 |
| CN104927302A (zh) * | 2014-03-20 | 2015-09-23 | 江南大学 | 一种由石墨烯增韧的环氧树脂复合材料及其制备方法 |
| CN105414456A (zh) * | 2015-11-23 | 2016-03-23 | 合肥李诺新材料贸易有限公司 | 一种泵阀铸件用可形成网状致密结构的碱性酚醛树脂自硬砂及其制备方法 |
-
2016
- 2016-08-01 CN CN201610624855.0A patent/CN106009493A/zh active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1834152A (zh) * | 2006-03-21 | 2006-09-20 | 上海胜星树脂涂料有限公司 | 一种常温发泡制备酚醛泡沫保温材料的方法 |
| CN103788570A (zh) * | 2012-10-31 | 2014-05-14 | 合肥杰事杰新材料股份有限公司 | 一种改性酚醛泡沫体及其制备方法 |
| CN102924864A (zh) * | 2012-11-27 | 2013-02-13 | 北京立高防水工程有限公司 | 改性环保酚醛保温材料及其制备方法 |
| CN103589197A (zh) * | 2013-11-25 | 2014-02-19 | 桂林理工大学 | 一种采用氧化石墨烯制备增韧剂的方法及其应用 |
| CN103694625A (zh) * | 2013-12-19 | 2014-04-02 | 山东圣泉化工股份有限公司 | 一种改性酚醛泡沫体 |
| CN104927302A (zh) * | 2014-03-20 | 2015-09-23 | 江南大学 | 一种由石墨烯增韧的环氧树脂复合材料及其制备方法 |
| CN105414456A (zh) * | 2015-11-23 | 2016-03-23 | 合肥李诺新材料贸易有限公司 | 一种泵阀铸件用可形成网状致密结构的碱性酚醛树脂自硬砂及其制备方法 |
Non-Patent Citations (1)
| Title |
|---|
| 胡源等: "《阻燃聚合物纳米复合材料》", 31 July 2008 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106928648A (zh) * | 2017-04-20 | 2017-07-07 | 北京石油化工学院 | 一种晶须增强增韧无卤阻燃酚醛泡沫塑料及其制备方法 |
| CN106928648B (zh) * | 2017-04-20 | 2020-05-22 | 北京石油化工学院 | 一种晶须增强增韧无卤阻燃酚醛泡沫塑料及其制备方法 |
| GB2563043A (en) * | 2017-05-31 | 2018-12-05 | Acell Ind Ltd | Phenolic moulding material |
| GB2563043B (en) * | 2017-05-31 | 2023-01-11 | Acell Ind Ltd | Phenolic moulding material |
| CN107459765A (zh) * | 2017-08-03 | 2017-12-12 | 合肥泓定科技有限公司 | 酚醛泡沫保温板及其制备方法 |
| WO2019211559A1 (fr) * | 2018-05-04 | 2019-11-07 | Saint-Gobain Isover | Materiau d'isolation thermique comprenant des particules d'oyde de graphite partiellement oxydees |
| FR3080850A1 (fr) * | 2018-05-04 | 2019-11-08 | Saint-Gobain Isover | Materiau d’isolation thermique |
| KR20210003134A (ko) * | 2018-05-04 | 2021-01-11 | 쌩-고벵 이조베르 | 부분적으로 산화된 산화흑연 입자를 포함하는 단열 재료 |
| JP2021522395A (ja) * | 2018-05-04 | 2021-08-30 | サン−ゴバン イゾベール | 部分的に酸化された酸化黒鉛粒子を有する断熱材料 |
| JP7411572B2 (ja) | 2018-05-04 | 2024-01-11 | サン－ゴバン イゾベール | 部分的に酸化された酸化黒鉛粒子を有する断熱材料 |
| KR102698176B1 (ko) | 2018-05-04 | 2024-08-26 | 쌩-고벵 이조베르 | 부분적으로 산화된 산화흑연 입자를 포함하는 단열 재료 |
| US12227937B2 (en) | 2018-05-04 | 2025-02-18 | Saint-Gobain Isover | Thermal insulation material comprising partially oxidized graphite oxide particles |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101440170B (zh) | 生物质改性酚醛泡沫塑料的制备方法 | |
| CN106243614A (zh) | 改性酚醛泡沫保温材料及其制备方法 | |
| CN107556036B (zh) | 保温板及其制备方法 | |
| CN106009493A (zh) | 酚醛泡沫外墙保温材料及其制备方法 | |
| CN107473681B (zh) | 硅酸钙板材及其制备方法 | |
| CN102924864B (zh) | 改性环保酚醛保温材料及其制备方法 | |
| CN104030724A (zh) | 一种硫氧镁胶凝材料防火门芯板及其制作方法 | |
| CN107266853A (zh) | 酚醛泡沫保温板及其制备方法 | |
| CN106243613A (zh) | 酚醛泡沫保温复合板及其制备方法 | |
| CN101525465B (zh) | 增韧酚醛泡沫的制备方法 | |
| CN104109298A (zh) | 改性挤塑板及其制备方法 | |
| CN102838374A (zh) | 一种外墙用发泡水泥保温材料及其制备方法 | |
| WO2019052336A1 (zh) | 保温制品及其制备方法 | |
| CN103435970A (zh) | 一种用于墙体保温的改性酚醛泡沫及其制备方法 | |
| CN109160987A (zh) | 硅烷化纳米二氧化硅改性木质素基酚醛树脂及其制备方法和应用 | |
| CN102875111A (zh) | 无机防火芯板及其制作方法 | |
| CN104446130A (zh) | 一种复合纳米保温隔热板材及其制备方法 | |
| CN107629404A (zh) | 晶须硅改性酚醛树脂及其制备方法和应用 | |
| CN107446305A (zh) | 酚醛树脂保温板及其制备方法 | |
| CN106589796B (zh) | 一种浮石酚醛树脂复合泡沫材料及其制备方法 | |
| CN106189062A (zh) | 酚醛泡沫保温板及其制备方法 | |
| CN108676268A (zh) | 防火gpes硬质泡沫复合塑料保温板及其制备方法 | |
| CN104031325B (zh) | 聚苯乙烯泡沫板、其生产方法以及用于其的固化剂 | |
| CN103382278A (zh) | 一种酚醛泡沫防火保温板及其制备方法 | |
| CN103351575B (zh) | 一种无机土接枝改性酚醛树脂泡沫的生产方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161012 |