CN106009259A - Low-toxicity anti-corrosive plastic sheet and preparation method thereof - Google Patents
Low-toxicity anti-corrosive plastic sheet and preparation method thereof Download PDFInfo
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- CN106009259A CN106009259A CN201610365942.9A CN201610365942A CN106009259A CN 106009259 A CN106009259 A CN 106009259A CN 201610365942 A CN201610365942 A CN 201610365942A CN 106009259 A CN106009259 A CN 106009259A
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- 239000002985 plastic film Substances 0.000 title claims abstract description 33
- 231100000053 low toxicity Toxicity 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- -1 polypropylene Polymers 0.000 claims abstract description 97
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 75
- 238000003756 stirring Methods 0.000 claims abstract description 66
- 239000000463 material Substances 0.000 claims abstract description 62
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 50
- 239000004593 Epoxy Substances 0.000 claims abstract description 37
- 239000005725 8-Hydroxyquinoline Substances 0.000 claims abstract description 25
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims abstract description 25
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229960003540 oxyquinoline Drugs 0.000 claims abstract description 25
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims abstract description 25
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 22
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims abstract description 21
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000004743 Polypropylene Substances 0.000 claims abstract description 21
- 239000004283 Sodium sorbate Substances 0.000 claims abstract description 21
- 229940068041 phytic acid Drugs 0.000 claims abstract description 21
- 229920001155 polypropylene Polymers 0.000 claims abstract description 21
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 claims abstract description 21
- 235000019250 sodium sorbate Nutrition 0.000 claims abstract description 21
- 238000001125 extrusion Methods 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000001816 cooling Methods 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 239000002131 composite material Substances 0.000 claims description 34
- 229920000642 polymer Polymers 0.000 claims description 31
- IGFROWMWDMZLTQ-UHFFFAOYSA-N 1,1,1-trifluoronon-2-ene Chemical group CCCCCCC=CC(F)(F)F IGFROWMWDMZLTQ-UHFFFAOYSA-N 0.000 claims description 24
- SUKFIGBCBNVMIK-UHFFFAOYSA-N C#C.C(C)(C)(C)C1=CC=CC=C1 Chemical group C#C.C(C)(C)(C)C1=CC=CC=C1 SUKFIGBCBNVMIK-UHFFFAOYSA-N 0.000 claims description 24
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 24
- 229960005489 paracetamol Drugs 0.000 claims description 24
- 229920001577 copolymer Polymers 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 10
- 238000005260 corrosion Methods 0.000 abstract description 4
- ZSYQVVKVKBVHIL-UHFFFAOYSA-N 1-tert-butyl-4-ethynylbenzene Chemical group CC(C)(C)C1=CC=C(C#C)C=C1 ZSYQVVKVKBVHIL-UHFFFAOYSA-N 0.000 abstract 1
- CSEAKGXTWOWTOQ-UHFFFAOYSA-N 5-hydrazinyl-5-oxopentanoic acid Chemical compound NNC(=O)CCCC(O)=O CSEAKGXTWOWTOQ-UHFFFAOYSA-N 0.000 abstract 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- ZVSKZLHKADLHSD-UHFFFAOYSA-N benzanilide Chemical compound C=1C=CC=CC=1C(=O)NC1=CC=CC=C1 ZVSKZLHKADLHSD-UHFFFAOYSA-N 0.000 abstract 1
- DJUWPHRCMMMSCV-UHFFFAOYSA-N bis(7-oxabicyclo[4.1.0]heptan-4-ylmethyl) hexanedioate Chemical compound C1CC2OC2CC1COC(=O)CCCCC(=O)OCC1CC2OC2CC1 DJUWPHRCMMMSCV-UHFFFAOYSA-N 0.000 abstract 1
- 229920005569 poly(vinylidene fluoride-co-hexafluoropropylene) Polymers 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 description 9
- 238000005452 bending Methods 0.000 description 8
- 239000007921 spray Substances 0.000 description 8
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses a low-toxicity anti-corrosive plastic sheet and a preparation method thereof. The preparation method comprises the following steps: bis((3,4-epoxy-cyclohexyl)methyl)adipate is added into ethylene glycol; stirring is carried out at 110 DEG C for 5 minutes; then 3-tridecafluoro-hexyl propene and N-acetyl-p-aminophenol are added; the temperature is adjusted to 120 DEG C; stirring is carried out for 35 minutes; then glutaric hydrazide and 4-tert-butyl phenylacetylene are added; stirring is carried out for 2 hours to obtain an epoxy combination; 8-hydroxyquinoline and nonylphenol are mixed; heat-preservation stirring is carried out at 70 DEG C for 20 minutes; ultrafine barium sulfate is added; stirring is carried out for 45 minutes; the epoxy composition and butanone are added; stirring is carried out at 105 DEG C for 2 hours; a solvent is removed; cooling is carried out to obtain a prepolymer; polypropylene, N-phenyl benzamide, and a polyvinylidene fluoride-hexafluoropropylene copolymer are mixed; sodium sorbate, inositol hexaphosphate and alcohol ester-12 are added and stirred uniformly; diatomite is added and mixed uniformly to obtain a main material; the main material and the prepolymer are added into an extruder; extrusion is carried out to obtain the low-toxicity anti-corrosive plastic sheet which is high in anti-corrosion property and mechanical property, and wide in application range.
Description
Technical field
The present invention relates to plastic material field, particularly relate to a kind of low toxicity anti-rot plastic sheet material and preparation method thereof.
Background technology
Metal material and goods thereof, such as precision instrument and equipment, weaponry etc., easily cause surface corrosion in transport, storage process, produce electrochemical corrosion and chemical attack so that it is surface fracture, hydraulic performance decline.Development and progress along with society, plastics are seen everywhere in life, because it is of many uses, throw-out also gets more and more, causing inevitably pollution to environment, plastics itself can be caused certain erosion, not only have a strong impact on the purity of chemical products by the chemical products simultaneously having, it is also easy to the danger caused in various degree, the safety of harm surrounding population；Under some harsh environments used by plastics, in the air of coastal environments, due to the restriction of condition of storage, the damage of plastics can be greatly accelerated by the corrosion function of salt fog, moisture etc..It is thus desirable to design new formula, prepare the plastic sheet that antiseptic power is strong, the most also should have hypotoxicity, to protect environment and crowd's safety.
Summary of the invention
The object of the invention is just to provide a kind of low toxicity anti-rot plastic sheet material.It is achieved through the following technical solutions: the preparation method of a kind of low toxicity anti-rot plastic sheet material, comprises the following steps:
(1) by double ((3,4-epoxycyclohexyl) methyl) adipate ester adds in ethylene glycol, stir 5 minutes in 110 DEG C, add 3-ten trifluoro hexyl propylene, N-acetaminophen, adjusting temperature is 120 DEG C, stirs 35 minutes, adds glutaryl hydrazine and 4-tert-butyl benzene acetylene, stir 2 hours, obtain epoxy composite；
(2) by 8-hydroxyquinoline, nonyl phenol mixing, insulated and stirred 20 minutes at 70 DEG C, adding ultra-fine barium sulfate, stir 45 minutes, be subsequently adding epoxy composite and butanone, stir 2 hours at 105 DEG C, after removing solvent, cooling obtains performed polymer；
(3) polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer；It is subsequently adding sodium sorbate and inositol hexaphosphate, Lauryl Alcohol ester, stirs；Adding kieselguhr, mix homogeneously obtains main material；Finally adding in extruder by main material and performed polymer, extrusion obtains low toxicity anti-rot plastic sheet material.
In the present invention, double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: (40～60): (4～10): (8～16): (0.8～2): (1.2～2.5).
Preferably, double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: (45～55): (5～8): (10～15): (1～1.8): (1.5～2).
Further preferred, double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: 48: 6: 12: 1.5: 1.8.
In the present invention, 8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are (3～10): (8～15): (14～20): 100；Preferably, 8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are (5～9): (9～14): (15～18): 100；It is further preferred that the mass ratio of 8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, epoxy composite is 8: 10: 16: 100.
In the present invention, polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer, sodium sorbate, inositol hexaphosphate, Lauryl Alcohol ester, diatomaceous mass ratio are 100: 22: 16: 4: 15: 6.Main material is 2: 1 with the mass ratio of performed polymer.
The invention also discloses and state low toxicity anti-rot plastic sheet material prepared by the preparation method of low toxicity anti-rot plastic sheet material, may be used for the aspect such as wet environment, chemical storage.
The invention have the advantage that
(1) little molecule corrosion preventive compound is mixed by the present invention with larger molecular organics, then by screw extruder extrusion molding, beneficially preservative dispersion stabilization in high polymer so that plastic sheet has the good characteristic such as high intensity, anticorrosion simultaneously.
(2) inventive formulation is reasonable, with low cost, utilizes the reactivity that epoxy is excellent with alkene, is wrapped in macromole by individual little point of material；The plastic sheet of preparation can effectively be protected in long-term placement process, and particularly in the coastal region waiting corrosive environment more severe, antiseptic effect is notable; improve service life and the aging resistance intensity of sheet material; and mechanical strength is high, and especially finished product toxicity is the lowest, and range is wide.
Detailed description of the invention
Embodiment 1
By double ((3,4-epoxycyclohexyl) methyl) adipate ester adds in ethylene glycol, stir 5 minutes in 110 DEG C, add 3-ten trifluoro hexyl propylene, N-acetaminophen, adjusting temperature is 120 DEG C, stirs 35 minutes, adds glutaryl hydrazine and 4-tert-butyl benzene acetylene, stir 2 hours, obtain epoxy composite；By 8-hydroxyquinoline, nonyl phenol mixing, insulated and stirred 20 minutes at 70 DEG C, adding ultra-fine barium sulfate, stir 45 minutes, be subsequently adding epoxy composite and butanone, stir 2 hours at 105 DEG C, after removing solvent, cooling obtains performed polymer；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer；It is subsequently adding sodium sorbate and inositol hexaphosphate, Lauryl Alcohol ester, stirs；Adding kieselguhr, mix homogeneously obtains main material；Finally adding in extruder by main material and performed polymer, extrusion obtains low toxicity anti-rot plastic sheet material.Tensile yield strength 3241kg/cm2, bending strength 80.9Mpa；By alkaline-resisting and salt spray test.Above-mentioned double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: 48: 6: 12: 1.5: 1.8；8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are 8: 10: 16: 100；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer, sodium sorbate, inositol hexaphosphate, Lauryl Alcohol ester, diatomaceous mass ratio are 100: 22: 16: 4: 15: 6；Main material is 2: 1 with the mass ratio of performed polymer.
Embodiment 2
By double ((3,4-epoxycyclohexyl) methyl) adipate ester adds in ethylene glycol, stir 5 minutes in 110 DEG C, add 3-ten trifluoro hexyl propylene, N-acetaminophen, adjusting temperature is 120 DEG C, stirs 35 minutes, adds glutaryl hydrazine and 4-tert-butyl benzene acetylene, stir 2 hours, obtain epoxy composite；By 8-hydroxyquinoline, nonyl phenol mixing, insulated and stirred 20 minutes at 70 DEG C, adding ultra-fine barium sulfate, stir 45 minutes, be subsequently adding epoxy composite and butanone, stir 2 hours at 105 DEG C, after removing solvent, cooling obtains performed polymer；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer；It is subsequently adding sodium sorbate and inositol hexaphosphate, Lauryl Alcohol ester, stirs；Adding kieselguhr, mix homogeneously obtains main material；Finally adding in extruder by main material and performed polymer, extrusion obtains low toxicity anti-rot plastic sheet material.Tensile yield strength 311kg/cm2, bending strength 79.9Mpa；By alkaline-resisting and salt spray test.Above-mentioned double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: 45: 5: 12: 1.5: 1.8；8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are 5: 10: 16: 100；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer, sodium sorbate, inositol hexaphosphate, Lauryl Alcohol ester, diatomaceous mass ratio are 100: 22: 16: 4: 15: 6；Main material is 2: 1 with the mass ratio of performed polymer.
Embodiment 3
By double ((3,4-epoxycyclohexyl) methyl) adipate ester adds in ethylene glycol, stir 5 minutes in 110 DEG C, add 3-ten trifluoro hexyl propylene, N-acetaminophen, adjusting temperature is 120 DEG C, stirs 35 minutes, adds glutaryl hydrazine and 4-tert-butyl benzene acetylene, stir 2 hours, obtain epoxy composite；By 8-hydroxyquinoline, nonyl phenol mixing, insulated and stirred 20 minutes at 70 DEG C, adding ultra-fine barium sulfate, stir 45 minutes, be subsequently adding epoxy composite and butanone, stir 2 hours at 105 DEG C, after removing solvent, cooling obtains performed polymer；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer；It is subsequently adding sodium sorbate and inositol hexaphosphate, Lauryl Alcohol ester, stirs；Adding kieselguhr, mix homogeneously obtains main material；Finally adding in extruder by main material and performed polymer, extrusion obtains low toxicity anti-rot plastic sheet material.Tensile yield strength 315kg/cm2, bending strength 79.5Mpa；By alkaline-resisting and salt spray test.Above-mentioned double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: 48: 6: 10: 1: 1.5；8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are 8: 9: 15: 100；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer, sodium sorbate, inositol hexaphosphate, Lauryl Alcohol ester, diatomaceous mass ratio are 100: 22: 16: 4: 15: 6；Main material is 2: 1 with the mass ratio of performed polymer.
Embodiment 4
By double ((3,4-epoxycyclohexyl) methyl) adipate ester adds in ethylene glycol, stir 5 minutes in 110 DEG C, add 3-ten trifluoro hexyl propylene, N-acetaminophen, adjusting temperature is 120 DEG C, stirs 35 minutes, adds glutaryl hydrazine and 4-tert-butyl benzene acetylene, stir 2 hours, obtain epoxy composite；By 8-hydroxyquinoline, nonyl phenol mixing, insulated and stirred 20 minutes at 70 DEG C, adding ultra-fine barium sulfate, stir 45 minutes, be subsequently adding epoxy composite and butanone, stir 2 hours at 105 DEG C, after removing solvent, cooling obtains performed polymer；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer；It is subsequently adding sodium sorbate and inositol hexaphosphate, Lauryl Alcohol ester, stirs；Adding kieselguhr, mix homogeneously obtains main material；Finally adding in extruder by main material and performed polymer, extrusion obtains low toxicity anti-rot plastic sheet material.Tensile yield strength 309kg/cm2, bending strength 80.1Mpa；By alkaline-resisting and salt spray test.Above-mentioned double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: 45: 6: 12: 1.5: 1；8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are 9: 10: 15: 100；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer, sodium sorbate, inositol hexaphosphate, Lauryl Alcohol ester, diatomaceous mass ratio are 100: 22: 16: 4: 15: 6；Main material is 2: 1 with the mass ratio of performed polymer.
Embodiment 5
By double ((3,4-epoxycyclohexyl) methyl) adipate ester adds in ethylene glycol, stir 5 minutes in 110 DEG C, add 3-ten trifluoro hexyl propylene, N-acetaminophen, adjusting temperature is 120 DEG C, stirs 35 minutes, adds glutaryl hydrazine and 4-tert-butyl benzene acetylene, stir 2 hours, obtain epoxy composite；By 8-hydroxyquinoline, nonyl phenol mixing, insulated and stirred 20 minutes at 70 DEG C, adding ultra-fine barium sulfate, stir 45 minutes, be subsequently adding epoxy composite and butanone, stir 2 hours at 105 DEG C, after removing solvent, cooling obtains performed polymer；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer；It is subsequently adding sodium sorbate and inositol hexaphosphate, Lauryl Alcohol ester, stirs；Adding kieselguhr, mix homogeneously obtains main material；Finally adding in extruder by main material and performed polymer, extrusion obtains low toxicity anti-rot plastic sheet material.Tensile yield strength 312kg/cm2, bending strength 80.4Mpa；By alkaline-resisting and salt spray test.Above-mentioned double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: 55: 8: 12: 1.5: 1.8；8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are 9: 10: 20: 100；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer, sodium sorbate, inositol hexaphosphate, Lauryl Alcohol ester, diatomaceous mass ratio are 100: 22: 16: 4: 15: 6；Main material is 2: 1 with the mass ratio of performed polymer.
Embodiment 6
By double ((3,4-epoxycyclohexyl) methyl) adipate ester adds in ethylene glycol, stir 5 minutes in 110 DEG C, add 3-ten trifluoro hexyl propylene, N-acetaminophen, adjusting temperature is 120 DEG C, stirs 35 minutes, adds glutaryl hydrazine and 4-tert-butyl benzene acetylene, stir 2 hours, obtain epoxy composite；By 8-hydroxyquinoline, nonyl phenol mixing, insulated and stirred 20 minutes at 70 DEG C, adding ultra-fine barium sulfate, stir 45 minutes, be subsequently adding epoxy composite and butanone, stir 2 hours at 105 DEG C, after removing solvent, cooling obtains performed polymer；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer；It is subsequently adding sodium sorbate and inositol hexaphosphate, Lauryl Alcohol ester, stirs；Adding kieselguhr, mix homogeneously obtains main material；Finally adding in extruder by main material and performed polymer, extrusion obtains low toxicity anti-rot plastic sheet material.Tensile yield strength 308kg/cm2, bending strength 80.1Mpa；By alkaline-resisting and salt spray test.Above-mentioned double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: 48: 6: 12: 1.8: 2；8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are 9: 10: 18: 100；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer, sodium sorbate, inositol hexaphosphate, Lauryl Alcohol ester, diatomaceous mass ratio are 100: 22: 16: 4: 15: 6；Main material is 2: 1 with the mass ratio of performed polymer.
Embodiment 7
By double ((3,4-epoxycyclohexyl) methyl) adipate ester adds in ethylene glycol, stir 5 minutes in 110 DEG C, add 3-ten trifluoro hexyl propylene, N-acetaminophen, adjusting temperature is 120 DEG C, stirs 35 minutes, adds glutaryl hydrazine and 4-tert-butyl benzene acetylene, stir 2 hours, obtain epoxy composite；By 8-hydroxyquinoline, nonyl phenol mixing, insulated and stirred 20 minutes at 70 DEG C, adding ultra-fine barium sulfate, stir 45 minutes, be subsequently adding epoxy composite and butanone, stir 2 hours at 105 DEG C, after removing solvent, cooling obtains performed polymer；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer；It is subsequently adding sodium sorbate and inositol hexaphosphate, Lauryl Alcohol ester, stirs；Adding kieselguhr, mix homogeneously obtains main material；Finally adding in extruder by main material and performed polymer, extrusion obtains low toxicity anti-rot plastic sheet material.Tensile yield strength 311kg/cm2, bending strength 80.1Mpa；By alkaline-resisting and salt spray test.Above-mentioned double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: 40: 6: 12: 0.8: 1.8；8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are 8: 8: 14: 100；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer, sodium sorbate, inositol hexaphosphate, Lauryl Alcohol ester, diatomaceous mass ratio are 100: 22: 16: 4: 15: 6；Main material is 2: 1 with the mass ratio of performed polymer.
Embodiment 8
By double ((3,4-epoxycyclohexyl) methyl) adipate ester adds in ethylene glycol, stir 5 minutes in 110 DEG C, add 3-ten trifluoro hexyl propylene, N-acetaminophen, adjusting temperature is 120 DEG C, stirs 35 minutes, adds glutaryl hydrazine and 4-tert-butyl benzene acetylene, stir 2 hours, obtain epoxy composite；By 8-hydroxyquinoline, nonyl phenol mixing, insulated and stirred 20 minutes at 70 DEG C, adding ultra-fine barium sulfate, stir 45 minutes, be subsequently adding epoxy composite and butanone, stir 2 hours at 105 DEG C, after removing solvent, cooling obtains performed polymer；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer；It is subsequently adding sodium sorbate and inositol hexaphosphate, Lauryl Alcohol ester, stirs；Adding kieselguhr, mix homogeneously obtains main material；Finally adding in extruder by main material and performed polymer, extrusion obtains low toxicity anti-rot plastic sheet material.Tensile yield strength 308kg/cm2, bending strength 80.8Mpa；By alkaline-resisting and salt spray test.
Above-mentioned double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: 60: 6: 12: 1.5: 2；8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are 10: 10: 20: 100；Polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer, sodium sorbate, inositol hexaphosphate, Lauryl Alcohol ester, diatomaceous mass ratio are 100: 22: 16: 4: 15: 6；Main material is 2: 1 with the mass ratio of performed polymer.
Claims (10)
1. the preparation method of a low toxicity anti-rot plastic sheet material, it is characterised in that comprise the following steps:
(1) by double ((3,4-epoxycyclohexyl) methyl) adipate ester adds in ethylene glycol, stir 5 minutes in 110 DEG C, add 3-ten trifluoro hexyl propylene, N-acetaminophen, adjusting temperature is 120 DEG C, stirs 35 minutes, adds glutaryl hydrazine and 4-tert-butyl benzene acetylene, stir 2 hours, obtain epoxy composite；
(2) by 8-hydroxyquinoline, nonyl phenol mixing, insulated and stirred 20 minutes at 70 DEG C, adding ultra-fine barium sulfate, stir 45 minutes, be subsequently adding epoxy composite and butanone, stir 2 hours at 105 DEG C, after removing solvent, cooling obtains performed polymer；
(3) polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer；It is subsequently adding sodium sorbate and inositol hexaphosphate, Lauryl Alcohol ester, stirs；Adding kieselguhr, mix homogeneously obtains main material；Finally adding in extruder by main material and performed polymer, extrusion obtains low toxicity anti-rot plastic sheet material.
The preparation method of low toxicity anti-rot plastic sheet material the most according to claim 1, it is characterized in that: double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: (40～60): (4～10): (8～16): (0.8～2): (1.2～2.5).
The preparation method of low toxicity anti-rot plastic sheet material the most according to claim 2, it is characterized in that: double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: (45～55): (5～8): (10～15): (1～1.8): (1.5～2).
The preparation method of low toxicity anti-rot plastic sheet material the most according to claim 3, it is characterized in that: double ((3,4-epoxycyclohexyl) methyl) adipate ester, ethylene glycol, 3-ten trifluoro hexyl propylene, N-acetaminophen, glutaryl hydrazine, the mass ratio of 4-tert-butyl benzene acetylene are 100: 48: 6: 12: 1.5: 1.8.
The preparation method of low toxicity anti-rot plastic sheet material the most according to claim 1, it is characterised in that: 8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are (3～10): (8～15): (14～20): 100.
The preparation method of low toxicity anti-rot plastic sheet material the most according to claim 5, it is characterised in that: 8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are (5～9): (9～14): (15～18): 100.
The preparation method of low toxicity anti-rot plastic sheet material the most according to claim 6, it is characterised in that: 8-hydroxyquinoline, nonyl phenol, ultra-fine barium sulfate, the mass ratio of epoxy composite are 8: 10: 16: 100.
The preparation method of low toxicity anti-rot plastic sheet material the most according to claim 1, it is characterised in that: polypropylene, N-phenylbenzamaide, Kynoar-hexafluoropropylene copolymer, sodium sorbate, inositol hexaphosphate, Lauryl Alcohol ester, diatomaceous mass ratio are 100: 22: 16: 4: 15: 6.
The preparation method of low toxicity anti-rot plastic sheet material the most according to claim 1, it is characterised in that: main material is 2: 1 with the mass ratio of performed polymer.
The low toxicity anti-rot plastic sheet material that the most according to claim 1, prepared by the preparation method of low toxicity anti-rot plastic sheet material.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1553931A (en) * | 2000-12-06 | 2004-12-08 | �������⻯ѧƷ�ع�����˾ | Polypropylene resin composition |
| CN103881301A (en) * | 2012-12-24 | 2014-06-25 | 江苏绿材谷新材料科技发展有限公司 | High temperature-resistant epoxy resin composition for pultrusion and preparation method |
| CN105255428A (en) * | 2015-10-09 | 2016-01-20 | 烟台德邦先进硅材料有限公司 | Packaging epoxy resin mixture and preparation method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1553931A (en) * | 2000-12-06 | 2004-12-08 | �������⻯ѧƷ�ع�����˾ | Polypropylene resin composition |
| CN103881301A (en) * | 2012-12-24 | 2014-06-25 | 江苏绿材谷新材料科技发展有限公司 | High temperature-resistant epoxy resin composition for pultrusion and preparation method |
| CN105255428A (en) * | 2015-10-09 | 2016-01-20 | 烟台德邦先进硅材料有限公司 | Packaging epoxy resin mixture and preparation method thereof |
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Application publication date: 20161012 |