CN105903404B - A kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents and preparation method thereof - Google Patents
A kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents and preparation method thereof Download PDFInfo
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- CN105903404B CN105903404B CN201610250890.0A CN201610250890A CN105903404B CN 105903404 B CN105903404 B CN 105903404B CN 201610250890 A CN201610250890 A CN 201610250890A CN 105903404 B CN105903404 B CN 105903404B
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- CN
- China
- Prior art keywords
- foaming agent
- splashproof
- gemini quaternary
- active agents
- surface active
- Prior art date
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- 239000004088 foaming agent Substances 0.000 title claims abstract description 52
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 40
- 150000003242 quaternary ammonium salts Chemical class 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000006260 foam Substances 0.000 claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003380 propellant Substances 0.000 claims abstract description 20
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 19
- 239000002562 thickening agent Substances 0.000 claims abstract description 18
- 239000003381 stabilizer Substances 0.000 claims abstract description 17
- -1 Bactericidal cleaner Substances 0.000 claims abstract description 16
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 14
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 14
- 230000001629 suppression Effects 0.000 claims description 17
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical group CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 15
- 230000000996 additive effect Effects 0.000 claims description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 239000003093 cationic surfactant Substances 0.000 claims description 9
- 229920002401 polyacrylamide Polymers 0.000 claims description 9
- 244000025254 Cannabis sativa Species 0.000 claims description 8
- 229920001353 Dextrin Polymers 0.000 claims description 8
- 239000004375 Dextrin Substances 0.000 claims description 8
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- 240000001519 Verbena officinalis Species 0.000 claims description 8
- 235000018718 Verbena officinalis Nutrition 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 8
- 235000019425 dextrin Nutrition 0.000 claims description 8
- 235000012054 meals Nutrition 0.000 claims description 8
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 8
- 229920000053 polysorbate 80 Polymers 0.000 claims description 8
- 239000001294 propane Substances 0.000 claims description 8
- 244000060011 Cocos nucifera Species 0.000 claims description 7
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 7
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 6
- 240000004510 Agastache rugosa Species 0.000 claims description 5
- KHSLHYAUZSPBIU-UHFFFAOYSA-M benzododecinium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 KHSLHYAUZSPBIU-UHFFFAOYSA-M 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical group CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 244000223760 Cinnamomum zeylanicum Species 0.000 claims description 4
- 229920002907 Guar gum Polymers 0.000 claims description 4
- 229920002752 Konjac Polymers 0.000 claims description 4
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 235000010443 alginic acid Nutrition 0.000 claims description 4
- 229920000615 alginic acid Polymers 0.000 claims description 4
- 239000001273 butane Substances 0.000 claims description 4
- 235000010418 carrageenan Nutrition 0.000 claims description 4
- 239000000679 carrageenan Substances 0.000 claims description 4
- 229920001525 carrageenan Polymers 0.000 claims description 4
- 229940113118 carrageenan Drugs 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 229960000228 cetalkonium chloride Drugs 0.000 claims description 4
- 235000017803 cinnamon Nutrition 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 239000000665 guar gum Substances 0.000 claims description 4
- 235000010417 guar gum Nutrition 0.000 claims description 4
- 229960002154 guar gum Drugs 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920000609 methyl cellulose Polymers 0.000 claims description 4
- 239000001923 methylcellulose Substances 0.000 claims description 4
- 235000010981 methylcellulose Nutrition 0.000 claims description 4
- 229960002900 methylcellulose Drugs 0.000 claims description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 4
- 229920001277 pectin Polymers 0.000 claims description 4
- 239000001814 pectin Substances 0.000 claims description 4
- 235000010987 pectin Nutrition 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 235000010413 sodium alginate Nutrition 0.000 claims description 4
- 239000000661 sodium alginate Substances 0.000 claims description 4
- 229940005550 sodium alginate Drugs 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 229920001285 xanthan gum Polymers 0.000 claims description 4
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 4
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 3
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims description 3
- 244000247812 Amorphophallus rivieri Species 0.000 claims description 3
- 235000001206 Amorphophallus rivieri Nutrition 0.000 claims description 3
- 241000206575 Chondrus crispus Species 0.000 claims description 3
- 229920002581 Glucomannan Polymers 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 235000010489 acacia gum Nutrition 0.000 claims description 3
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 3
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 claims description 3
- 229940046240 glucomannan Drugs 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 239000000252 konjac Substances 0.000 claims description 3
- 235000010485 konjac Nutrition 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims 2
- QDYLMAYUEZBUFO-UHFFFAOYSA-N cetalkonium chloride Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 QDYLMAYUEZBUFO-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- PGQAXGHQYGXVDC-UHFFFAOYSA-N dodecyl(dimethyl)azanium;chloride Chemical compound Cl.CCCCCCCCCCCCN(C)C PGQAXGHQYGXVDC-UHFFFAOYSA-N 0.000 claims 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims 2
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- XICHKUZHYIMXSQ-UHFFFAOYSA-N C(CCCCCCCCCCC)[Mg]C(C1=CC=CC=C1)(C)C Chemical compound C(CCCCCCCCCCC)[Mg]C(C1=CC=CC=C1)(C)C XICHKUZHYIMXSQ-UHFFFAOYSA-N 0.000 claims 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 1
- 235000019082 Osmanthus Nutrition 0.000 claims 1
- 241000333181 Osmanthus Species 0.000 claims 1
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims 1
- 238000004945 emulsification Methods 0.000 claims 1
- NULGSOGHGHDGBH-UHFFFAOYSA-N n,n-dimethyl-1-phenylmethanamine;hydrobromide Chemical compound [Br-].C[NH+](C)CC1=CC=CC=C1 NULGSOGHGHDGBH-UHFFFAOYSA-N 0.000 claims 1
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 1
- 238000004332 deodorization Methods 0.000 abstract description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000001954 sterilising effect Effects 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- 238000011105 stabilization Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000000443 aerosol Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- SXPWTBGAZSPLHA-UHFFFAOYSA-M cetalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SXPWTBGAZSPLHA-UHFFFAOYSA-M 0.000 description 2
- 238000004440 column chromatography Methods 0.000 description 2
- 230000013872 defecation Effects 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- LUAJORAYKAAWIF-UHFFFAOYSA-N dodecyl(dimethyl)-lambda3-chlorane Chemical compound C(CCCCCCCCCCC)Cl(C)C LUAJORAYKAAWIF-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 0 *[*@](C=COC(c(cc1)ccc1C(OC=C(CC=COC(*)=O)I=*N)=O)=O)(C=COC(N)=O)N Chemical compound *[*@](C=COC(c(cc1)ccc1C(OC=C(CC=COC(*)=O)I=*N)=O)=O)(C=COC(N)=O)N 0.000 description 1
- HMDFOXQIYPYCRX-UHFFFAOYSA-N 1-(2-chloropropan-2-yl)-2-dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1C(C)(C)Cl HMDFOXQIYPYCRX-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CBSOFSBFHDQRLV-UHFFFAOYSA-N N-methylbenzylamine hydrochloride Chemical compound [Cl-].C[NH2+]CC1=CC=CC=C1 CBSOFSBFHDQRLV-UHFFFAOYSA-N 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical class CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- VWKWTYFNIQRCMT-UHFFFAOYSA-M [Cl-].C(C1=CC=CC=C1)[NH3+].C(CCCCCCCCCCCCCCC)[N+](CC1=CC=CC=C1)(C)C.[Cl-] Chemical compound [Cl-].C(C1=CC=CC=C1)[NH3+].C(CCCCCCCCCCCCCCC)[N+](CC1=CC=CC=C1)(C)C.[Cl-] VWKWTYFNIQRCMT-UHFFFAOYSA-M 0.000 description 1
- 238000001856 aerosol method Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical class CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
- C09K23/018—Mixtures of two or more different organic oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C219/00—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton
- C07C219/02—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C219/20—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents, it includes surfactant, foam stabilizer, thickener, emulsifying agent, propellant, Bactericidal cleaner, deionized water, and the invention also discloses the preparation method of above-mentioned Gemini quaternary ammonium salt surface active agents and splashproof foaming agent.The Gemini quaternary ammonium salt surface active agents of the present invention can stable foam, make foam surface tension force suitable and there is certain intensity, and the dosage of foaming agent in splashproof foaming agent can be reduced and foam yield is not reduced；Splashproof foaming agent based on above-mentioned Gemini quaternary ammonium salt surface active agents can be substantially prevented from it is caused when dirt crashes into collection vessel dabble, and with deodorization, antibacterial effect, be adapted to large-scale promotion application.
Description
Technical field
The present invention relates to hygiene article sector, more particularly to a kind of splashproof based on Gemini quaternary ammonium salt surface active agents
Foaming agent and preparation method thereof.
Background technology
Closestool is that present family of China, a kind of of hotel's generally existing facilitate facility, but currently without a technology energy
Enough solves the technology that people does not dabble with deodorization at a convenient time, the water for especially in stool being often closestool splashes people's hip or clothing
It is very unhygienic on clothes, very big inconvenience is brought to user.Existing detergent of closet and the articles for use of sterilization are mostly liquid, and one
As be in direct or indirect addition water tank, with entering closestool during Water flushing for cistern, so as to have the function that cleaning, but but without
Method solves the problems, such as mentioned above to prevent closestool from dabbling.
The patent application of Application No. 201510381166.7 discloses a kind of splashproof foaming agent and its application, disclosed
Splashproof foaming agent includes any one or more in following surfactant：Lauryl sodium sulfate, sodium alkyl benzene sulfonate, alkene
Base sodium sulfonate, fatty alcohol-ether sodium sulfate, foregoing invention is canned using aerosol, and button can eject foam during use, with human body
Contactless, foam can effectively play a part of splash-proof, deodorization, sterilization, sterilization, lubrication.But matching somebody with somebody disclosed in foregoing invention
It is only surfactant in side, has no sterilization, disinfection composition, and do not disclose its foam stabilization degree.
The patent application of Application No. 201510097321.2 discloses Spattering-proof for closet foam aerosol and preparation method thereof,
It is that raw material adds a kind of filling manufactured foam aerosol of propellant using compositions such as foaming agent mixing thickeners, refills in inhalator jar
In, foam is produced by shower nozzle.But also without sterilization, disinfection composition in the formula disclosed in foregoing invention, and it is also not disclosed
Foam stabilization degree.
The content of the invention
In order to solve the above problems, the present invention provides a kind of foam stabilization persistently and easily washed away with current, possesses sterilization suppression
Taste and cleaning efficacy, added with Gemini quaternary ammonium salt surface active agents so as to being reduced in the case where not influenceing foam yield
The splashproof foaming agent of frother dosages.
The technical solution adopted by the present invention is：A kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents,
Characterized in that, consist of the following composition, including surfactant 5-15%, foam stabilizer 0.01-0.1%, thickener 1-5%,
Emulsifying agent 0.01-0.5%, foaming agent 20-40%, propellant 0.3-3%, Bactericidal cleaner 5-15%, suppression taste additive 5-
10%th, surplus is deionized water, and above-mentioned each component content sum is 100%；
Further, described foam stabilizer is glycerine, polyacrylamide, polyvinyl alcohol, polyethers, dodecyl dimethyl chlorine
Change ammonium, the one or more in cocinic acid di-methylcarbinol acid amides, the thickener is sodium alginate, xanthans, and cellulose spreads out
Biology, starch, pectin, dextrin, alginates, carragheen, Arabic gum, konjac glucomannan, polyacrylamide, sodium cellulose glycolate,
One or more in methylcellulose, carrageenan, guar gum or dextrin；
Further, described foaming agent is neopelex, Cocoamidopropyl betaine, coconut oleoyl amine hydroxyl
The one or more of sulfobetaines, lauroylamidopropyl betaine, the emulsifying agent are in Span-40, Tween-80
One or two；
Further, described propellant is propane, butane or dimethyl ether；
Further, described Bactericidal cleaner is citric acid, sodium ethylene diamine tetracetate, hydrogen peroxide, dodecyl two
One kind or several in methyl-benzyl ammonium chloride, cetalkonium chloride, dodecyl dimethyl benzyl ammonium bromide
Kind；
Further, described suppression taste additive is the one or more in horsewhip grass meal, wrinkled giant hyssop powder, ground cinnamon；
Further, described surfactant is Gemini quaternary cationic surfactants；
Further, the structural formula of described Gemini quaternary cationic surfactants is as follows：
The invention also discloses the preparation method of the above-mentioned splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents,
Characterized in that, comprise the following steps that：
1) weigh raw material according to formula as below, surfactant 5-15%, foam stabilizer 0.01-0.1%, thickener 1-5%,
Emulsifying agent 0.01-0.5%, foaming agent 20-40%, propellant 0.3-3%, Bactericidal cleaner 5-15%, suppression taste additive 5-
10%th, surplus is deionized water, and above-mentioned each component content sum is 100%；
2) by the surfactant weighed in step 1, foam stabilizer, thickener, emulsifying agent, foaming agent, Bactericidal cleaner, suppression
Taste additive, deionized water are mixed at 20-50 DEG C, obtain mixed material；
3) by mixed mixed material in the propellant and step 2 that are weighed in step 1 in the shape that pressure is 0.3-1MPa
Poured under state in aluminium pot and valve is installed, shower nozzle, that is, obtain splashproof foaming agent；
Further, described foam stabilizer is glycerine, polyacrylamide, polyvinyl alcohol, polyethers, dodecyl dimethyl chlorine
Change the one or more in ammonium, cocinic acid di-methylcarbinol acid amides；
The thickener is sodium alginate, xanthans, cellulose derivative, starch, pectin, dextrin, alginates, OK a karaoke club
Glue, Arabic gum, konjac glucomannan, polyacrylamide, sodium cellulose glycolate, methylcellulose, carrageenan, guar gum or dextrin
In one or more；
Described foaming agent is neopelex, Cocoamidopropyl betaine, coconut oleoyl amine hydroxyl sulfobetaines
The one or more of alkali, lauroylamidopropyl betaine；
The emulsifying agent is one or both of Span-40, Tween-80；
Described propellant is propane, butane or dimethyl ether；
Described Bactericidal cleaner is citric acid, sodium ethylene diamine tetracetate, hydrogen peroxide, dodecyl dimethyl benzyl chloride
Change the one or more in ammonium, cetalkonium chloride, dodecyl dimethyl benzyl ammonium bromide；
Described suppression taste additive is the one or more in horsewhip grass meal, wrinkled giant hyssop powder, ground cinnamon；
Described surfactant is Gemini quaternary cationic surfactants；
The structural formula of described Gemini quaternary cationic surfactants is as follows：
Above-mentioned Gemini quaternary cationic surfactants have low surface tension, contribute to the stabilization of foam, energy
It is enough effectively to reduce pressure difference so that foams drain speed is slower, and thinning of liquid film is also slower.
Beneficial effects of the present invention：
Relative to closestool of the prior art splashproof foaming agent, the Gemini quaternary ammonium salts used in inventive formulation
Surfactant is the noval chemical compound that synthesizes first, can stable foam, make foam surface tension force suitable and with certain strong
Degree, and the dosage of foaming agent in splashproof foaming agent can be reduced and foam yield is not reduced；Based on above-mentioned Gemini quaternary ammoniums
The splashproof foaming agent of type surfactant can be substantially prevented from it is caused when dirt crashes into collection vessel dabble, and with anti-
Smelly, antibacterial effect, it is adapted to large-scale promotion application.
Brief description of the drawings
Fig. 1 is the Gemini quaternary ammonium salt surface active agent structural formulas of the present invention.
Embodiment
Embodiment 1：
The preparation method for the Gemini quaternary ammonium salt surface active agents being shown below, is comprised the following steps that：
1) by 0.1mol propionic acid and 0.12mol NC2H5(CH=CHOH)2It is fitted into after well mixed in reflux, adds
50mL hexamethylenes, 0.1g p-methyl benzenesulfonic acids, 0.3g zinc powders, 110 DEG C of back flow reactions 4 hours, after reaction terminates, reaction solution is spent
Anhydrous sodium sulfate drying is used after ion water washing, boiling off solvent in Rotary Evaporators obtains residue, and then column chromatography purifies, and obtains
To propionic acid-N- ethyl divinyl hydramine monoesters, yield 94%；
2) 0.05mol propionic acid-N- ethyl divinyl hydramine monoesters is mixed with 50mL chloroforms, addition 5mL triethylamines, and with
Cooling, the mitigation solution of 0.025mol paraphthaloyl chlorides and 30mL chloroforms is then added dropwise, drips off within about 2 hours, after dripping often
Warm stirring reaction 20 hours, after reaction terminates, reaction solution is washed with deionized water to neutrality, and nothing is used after being then washed with deionized
Aqueous sodium persulfate is dried, and is boiled off solvent in Rotary Evaporators and is obtained residue, and then column chromatography purifies, and obtains not quaternized target
Compound precursor, yield 92%；
3) the not quaternized target compound precursors of 0.01mol are well mixed with 30mL methanol, arrived at a low price at 50 DEG C
0.02mol dithyl sulfates react with the mixed solution of 30mL methanol, dripping off within about 2 hours, back flow reaction 10 hours at 50 DEG C
It is evaporated off alcohol after end, and with re-crystallizing in ethyl acetate, obtaining white powder i.e. Gemini quaternary ammonium salt surface active agents, yield is
82%.
Determined through surface tension instrument, the critical micelle concentration of obtained Gemini quaternary ammonium salt surface active agents is 3 × 10- 4Mol/L, surface tension 22.1mN/m.
Embodiment 2：
(1) a kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents, it is characterised in that by below into
It is grouped into, including Gemini quaternary ammonium salt surface active agents 5%, the foam stabilizer cocinic acid as shown in the structural formula of embodiment 1 are double
Glycollic amide 0.1%, thickener sodium cellulose glycolate 5%, emulsifying agent Tween-80 0.5%, foaming agent coconut oleoyl amine
CAB 20%, propellant liquefied propane 3%, Bactericidal cleaner dodecyl dimethyl benzyl ammonium bromide 10%, suppression taste
Additive horsewhip grass meal 5%, surplus are deionized water, and above-mentioned each component content sum is 100%.
(2) preparation method of above-mentioned splashproof foaming agent：
1) raw material is weighed according to formula as below, the Gemini quaternary ammonium salt surface active agents as shown in the structural formula of embodiment 1
5%th, foam stabilizer cocinic acid di-methylcarbinol acid amides 0.1%, thickener sodium cellulose glycolate 5%, emulsifying agent Tween-80
0.5%th, foaming agent Cocoamidopropyl betaine 20%, propellant liquefied propane 3%, Bactericidal cleaner dodecyl dimethyl
Benzylphosphonium Bromide ammonium 10%, suppression taste additive horsewhip grass meal 5%, surplus are deionized water, and above-mentioned each component content sum is
100%；
2) by the surfactant weighed in step 1, foam stabilizer, thickener, emulsifying agent, foaming agent, Bactericidal cleaner, suppression
Taste additive, deionized water are mixed at 20 DEG C, obtain mixed material；
3) by mixed mixed material in the propellant and step 2 that are weighed in step 1 in the state that pressure is 0.3MPa
Under pour into aluminium pot and valve be installed, shower nozzle, that is, obtain splashproof foaming agent.
(3) application method of above-mentioned splashproof foaming agent：
Before closestool defecation, aluminium pot shower nozzle is directed at the closestool water surface, the propellant for making to squeeze out by movable valve gasifies
The gas formed afterwards contacts in material liquid, so as to which the related substances in material liquid be acted on, forms foam and sprays, is laid in horse
Effective coating is formed on inner bucket water face, strip analogies 80g is put into apart from coating 50cm, does not produce and dabble, through observing, 20
Foam total amount is 90% just generated after minute, and durable lather is stable, and water punching can be clean, and has the effect of cleaning closestool concurrently,
So that dirt is not easy wall built-up.
Embodiment 3：
(1) a kind of splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents, it is characterised in that by below into
It is grouped into, including Gemini quaternary ammonium salt surface active agents 5%, the foam stabilizer cocinic acid as shown in the structural formula of embodiment 1 are double
Glycollic amide 0.1%, thickener sodium cellulose glycolate 5%, emulsifying agent Tween-80 0.5%, foaming agent coconut oleoyl amine
CAB 20%, propellant liquefied propane 3%, Bactericidal cleaner dodecyl dimethyl benzyl ammonium bromide 10%, suppression taste
Additive horsewhip grass meal 5%, surplus are deionized water, and above-mentioned each component content sum is 100%.
(2) preparation method of above-mentioned splashproof foaming agent：
1) raw material is weighed according to formula as below, the Gemini quaternary ammonium salt surface active agents as shown in the structural formula of embodiment 1
10%th, foam stabilizer cocinic acid di-methylcarbinol acid amides 0.1%, thickener polyacrylamide 5%, emulsifying agent Tween-80
0.5%th, foaming agent neopelex 20%, propellant liquefied propane 3%, Bactericidal cleaner hexadecyldimethyl benzyl ammonium benzyl
Ammonium chloride 10%, the mixture 5% of suppression taste additive horsewhip grass meal and wrinkled giant hyssop powder, surplus are deionized water, above-mentioned each component
Content sum is 100%；
2) by the surfactant weighed in step 1, foam stabilizer, thickener, emulsifying agent, foaming agent, Bactericidal cleaner, suppression
Taste additive, deionized water are mixed at 30 DEG C, obtain mixed material；
3) by mixed mixed material in the propellant and step 2 that are weighed in step 1 in the state that pressure is 0.3MPa
Under pour into aluminium pot and valve be installed, shower nozzle, that is, obtain splashproof foaming agent.
(3) application method of above-mentioned splashproof foaming agent：
Before closestool defecation, aluminium pot shower nozzle is directed at the closestool water surface, the propellant for making to squeeze out by movable valve gasifies
The gas formed afterwards contacts in material liquid, so as to which the related substances in material liquid be acted on, forms foam and sprays, is laid in horse
Effective coating is formed on inner bucket water face, strip analogies 80g is put into apart from coating 50cm, does not produce and dabble, through observing, 20
Foam total amount is 90% just generated after minute, and durable lather is stable, and water punching can be clean, and has the effect of cleaning closestool concurrently,
So that dirt is not easy wall built-up.
Above-described embodiment is in the art the purpose is to be to allow simply to illustrate that the technical concepts and features of the present invention
Those of ordinary skill can understand present disclosure and implement according to this, and it is not intended to limit the scope of the present invention.It is all
It is the equivalent change or modification according to made by the essence of present invention, should all covers in protection scope of the present invention.
Claims (8)
- A kind of 1. splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents, it is characterised in that consist of the following composition, Including surfactant 5-15%, foam stabilizer 0.01-0.1%, thickener 1-5%, emulsifying agent 0.01-0.5%, foaming agent 20- 40%th, propellant 0.3-3%, Bactericidal cleaner 5-15%, suppression taste additive 5-10%, surplus are deionized water, above-mentioned each group It is 100% to divide content sum；Described surfactant is Gemini quaternary cationic surfactants；The structural formula of described Gemini quaternary cationic surfactants is as follows：
- 2. splashproof foaming agent as claimed in claim 1, it is characterised in that described foam stabilizer is glycerine, polyacrylamide, gathered One or more in vinyl alcohol, polyethers, dodecyl dimethyl ammonium chloride, cocinic acid di-methylcarbinol acid amides, the thickening Agent is sodium alginate, xanthans, cellulose derivative, starch, pectin, dextrin, alginates, carragheen, Arabic gum, konjaku It is a kind of or more in glue, polyacrylamide, sodium cellulose glycolate, methylcellulose, carrageenan, guar gum or dextrin Kind.
- 3. splashproof foaming agent as claimed in claim 1, it is characterised in that described foaming agent be neopelex, Cocoamidopropyl betaine, coconut oleoyl amine hydroxy sulfo lycine, the one or more of lauroylamidopropyl betaine, it is described Emulsifying agent is one or both of Span-40, Tween-80.
- 4. splashproof foaming agent as claimed in claim 1, it is characterised in that described propellant is propane, butane or dimethyl ether.
- 5. splashproof foaming agent as claimed in claim 1, it is characterised in that described Bactericidal cleaner is citric acid, ethylenediamine Tetraacethyl sodium, hydrogen peroxide, dodecyl benzyl dimethyl ammonium chloride, cetalkonium chloride, dodecyl One or more in dimethylbenzyl ammonium bromide.
- 6. splashproof foaming agent as claimed in claim 1, it is characterised in that described suppression taste additive is horsewhip grass meal, wrinkled giant hyssop One or more in powder, ground cinnamon.
- A kind of 7. preparation side of the splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents as claimed in claim 1 Method, it is characterised in that comprise the following steps that：1) raw material, surfactant 5-15%, foam stabilizer 0.01-0.1%, thickener 1-5%, emulsification are weighed according to formula as below It is agent 0.01-0.5%, foaming agent 20-40%, propellant 0.3-3%, Bactericidal cleaner 5-15%, suppression taste additive 5-10%, remaining It is 100% to measure as deionized water, above-mentioned each component content sum；Described surfactant is Gemini quaternary cationic surfactants；The structural formula of described Gemini quaternary cationic surfactants is as follows：2) surfactant weighed in step 1, foam stabilizer, thickener, emulsifying agent, foaming agent, Bactericidal cleaner, suppression taste are added Add agent, deionized water to be mixed at 20-50 DEG C, obtain mixed material；3) by mixed mixed material in the propellant and step 2 that are weighed in step 1 in the state of pressure is 0.3-1MPa Pour into aluminium pot and valve is installed, shower nozzle, that is, obtain splashproof foaming agent.
- 8. the preparation method of the splashproof foaming agent based on Gemini quaternary ammonium salt surface active agents as claimed in claim 7, its It is characterised by, described foam stabilizer is glycerine, polyacrylamide, polyvinyl alcohol, polyethers, dodecyl dimethyl ammonium chloride, coconut palm One or more in seed oil acid di-methylcarbinol acid amides；The thickener is sodium alginate, xanthans, cellulose derivative, starch, pectin, dextrin, alginates, carragheen, Ah Draw in primary glue, konjac glucomannan, polyacrylamide, sodium cellulose glycolate, methylcellulose, carrageenan, guar gum or dextrin It is one or more kinds of；Described foaming agent is neopelex, Cocoamidopropyl betaine, coconut oleoyl amine hydroxy sulfo lycine, the moon The one or more of osmanthus amido propyl betaine；The emulsifying agent is one or both of Span-40, Tween-80；Described propellant is propane, butane or dimethyl ether；Described Bactericidal cleaner is citric acid, sodium ethylene diamine tetracetate, hydrogen peroxide, dodecyl dimethyl Benzylmagnesium chloride One or more in ammonium, cetalkonium chloride, dodecyl dimethyl benzyl ammonium bromide；Described suppression taste additive is the one or more in horsewhip grass meal, wrinkled giant hyssop powder, ground cinnamon.
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| CN112056970A (en) * | 2019-06-11 | 2020-12-11 | 北京摩室科技有限公司 | Foam flushing-free toilet and operation method thereof |
| CN110507944B (en) * | 2019-09-29 | 2021-11-23 | 应急管理部天津消防研究所 | High-concentration environment-friendly fluorine-free compressed air foam extinguishing agent |
| CN113801028B (en) * | 2021-10-15 | 2023-11-10 | 成都科宏达科技有限公司 | A kind of hydrogen peroxide special surfactant and its compound |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011122006A (en) * | 2009-12-08 | 2011-06-23 | Air Water Inc | Surfactant and cleaning method using the same |
| CN103611464A (en) * | 2013-11-14 | 2014-03-05 | 陕西师范大学 | Amphiprotic-anionic surfactant composite foaming agent and method for testing foam stabilizing property of amphiprotic-anionic surfactant composite foaming agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011122006A (en) * | 2009-12-08 | 2011-06-23 | Air Water Inc | Surfactant and cleaning method using the same |
| CN103611464A (en) * | 2013-11-14 | 2014-03-05 | 陕西师范大学 | Amphiprotic-anionic surfactant composite foaming agent and method for testing foam stabilizing property of amphiprotic-anionic surfactant composite foaming agent |
Non-Patent Citations (1)
| Title |
|---|
| 季铵盐类Gemini表面活性剂的合成与表面活性;杨百勤等;《印染助剂》;20140430;第31卷(第4期);15-18 * |
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