CN105901003A - Pesticide composition containing fluazaindolizine - Google Patents
Pesticide composition containing fluazaindolizine Download PDFInfo
- Publication number
- CN105901003A CN105901003A CN201610266341.2A CN201610266341A CN105901003A CN 105901003 A CN105901003 A CN 105901003A CN 201610266341 A CN201610266341 A CN 201610266341A CN 105901003 A CN105901003 A CN 105901003A
- Authority
- CN
- China
- Prior art keywords
- miaow pyridine
- trifluoro miaow
- pyridine amide
- composition pesticide
- amide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 239000000575 pesticide Substances 0.000 title claims abstract description 27
- PHCCDUCBMCYSNQ-UHFFFAOYSA-N fluazaindolizine Chemical compound COC1=CC=C(Cl)C(S(=O)(=O)NC(=O)C=2N=C3C(Cl)=CC(=CN3C=2)C(F)(F)F)=C1 PHCCDUCBMCYSNQ-UHFFFAOYSA-N 0.000 title abstract description 4
- 239000005783 Fluopyram Substances 0.000 claims abstract description 28
- KVDJTXBXMWJJEF-UHFFFAOYSA-N fluopyram Chemical compound ClC1=CC(C(F)(F)F)=CN=C1CCNC(=O)C1=CC=CC=C1C(F)(F)F KVDJTXBXMWJJEF-UHFFFAOYSA-N 0.000 claims abstract description 28
- IBBMAWULFFBRKK-UHFFFAOYSA-N picolinamide Chemical compound NC(=O)C1=CC=CC=N1 IBBMAWULFFBRKK-UHFFFAOYSA-N 0.000 claims description 73
- -1 pyridine acyl Amine Chemical class 0.000 claims description 37
- 229910052731 fluorine Inorganic materials 0.000 claims description 32
- 239000011737 fluorine Substances 0.000 claims description 32
- 150000003457 sulfones Chemical class 0.000 claims description 30
- 239000000839 emulsion Substances 0.000 claims description 25
- CWGATOJEFAKFBK-UHFFFAOYSA-N Ac-(E)-8-Tridecen-1-ol Natural products C1C(O)C(C)C(C(C)CC)OC11OC(CC=C(C)C(OC2OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C2)C(C)C=CC=C2C3(C(C(=O)O4)C=C(C)C(O)C3OC2)O)CC4C1 CWGATOJEFAKFBK-UHFFFAOYSA-N 0.000 claims description 23
- 239000005645 nematicide Substances 0.000 claims description 23
- ZPAKHHSWIYDSBJ-QDXJZMFISA-N avermectin b2 Chemical compound O1C(C)C(O)C(OC)CC1OC1C(OC)CC(O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)C(O)C4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)OC1C ZPAKHHSWIYDSBJ-QDXJZMFISA-N 0.000 claims description 22
- 239000008187 granular material Substances 0.000 claims description 17
- 239000003094 microcapsule Substances 0.000 claims description 16
- 239000000725 suspension Substances 0.000 claims description 16
- 239000004615 ingredient Substances 0.000 claims description 13
- 239000000470 constituent Substances 0.000 claims description 8
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 8
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 239000005660 Abamectin Substances 0.000 abstract description 7
- 241000244206 Nematoda Species 0.000 abstract description 5
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 abstract description 2
- 229950008167 abamectin Drugs 0.000 abstract description 2
- XSNMWAPKHUGZGQ-UHFFFAOYSA-N fluensulfone Chemical compound FC(F)=C(F)CCS(=O)(=O)C1=NC=C(Cl)S1 XSNMWAPKHUGZGQ-UHFFFAOYSA-N 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 244000052769 pathogen Species 0.000 abstract 1
- 230000001717 pathogenic effect Effects 0.000 abstract 1
- 230000009044 synergistic interaction Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 31
- 206010011732 Cyst Diseases 0.000 description 22
- 208000031513 cyst Diseases 0.000 description 22
- 241000243786 Meloidogyne incognita Species 0.000 description 20
- 241000244203 Caenorhabditis elegans Species 0.000 description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 235000010469 Glycine max Nutrition 0.000 description 18
- 244000068988 Glycine max Species 0.000 description 18
- 241000498254 Heterodera glycines Species 0.000 description 18
- 241001143352 Meloidogyne Species 0.000 description 18
- 230000003449 preventive effect Effects 0.000 description 18
- 230000001988 toxicity Effects 0.000 description 18
- 231100000419 toxicity Toxicity 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 241000196324 Embryophyta Species 0.000 description 10
- 241000243785 Meloidogyne javanica Species 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 7
- 201000010099 disease Diseases 0.000 description 7
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 7
- 239000008346 aqueous phase Substances 0.000 description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
- 210000000481 breast Anatomy 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 210000000582 semen Anatomy 0.000 description 6
- 235000015170 shellfish Nutrition 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000005711 Benzoic acid Substances 0.000 description 3
- 229920002261 Corn starch Polymers 0.000 description 3
- 241000482313 Globodera ellingtonae Species 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 241001480224 Heterodera Species 0.000 description 3
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 244000046052 Phaseolus vulgaris Species 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 235000010489 acacia gum Nutrition 0.000 description 3
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 229960000892 attapulgite Drugs 0.000 description 3
- 235000010233 benzoic acid Nutrition 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 239000008120 corn starch Substances 0.000 description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 150000002333 glycines Chemical class 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 229910052625 palygorskite Inorganic materials 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- YCPLVBXZQTYYIK-UHFFFAOYSA-N [5-[(2,6-dichlorophenyl)sulfonylmethyl]pyridin-3-yl]-(4-methylpiperidin-1-yl)methanone Chemical compound C1CC(C)CCN1C(=O)C1=CN=CC(CS(=O)(=O)C=2C(=CC=CC=2Cl)Cl)=C1 YCPLVBXZQTYYIK-UHFFFAOYSA-N 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 150000003851 azoles Chemical class 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000009916 joint effect Effects 0.000 description 2
- 210000003734 kidney Anatomy 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 244000000010 microbial pathogen Species 0.000 description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- CWGATOJEFAKFBK-PDVFGPFMSA-N 5-o-demethyl-22,23-dihydro-23-hydroxy-(13r,23s)-avermectin a1a Chemical group C1[C@H](O)[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CWGATOJEFAKFBK-PDVFGPFMSA-N 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 229930192734 Avilamycin Natural products 0.000 description 1
- 239000004190 Avilamycin Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000399949 Ditylenchus dipsaci Species 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241000193943 Pratylenchus Species 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 102000019259 Succinate Dehydrogenase Human genes 0.000 description 1
- 108010012901 Succinate Dehydrogenase Proteins 0.000 description 1
- 244000126002 Ziziphus vulgaris Species 0.000 description 1
- 235000008529 Ziziphus vulgaris Nutrition 0.000 description 1
- XIRGHRXBGGPPKY-OTPQUNEMSA-N [(2r,3s,4r,6s)-6-[(2'r,3's,3ar,4r,4'r,6s,7ar)-6-[(2s,3r,4r,5s,6r)-2-[(2r,3s,4s,5s,6s)-6-[(2r,3as,3'ar,6'r,7r,7's,7ar,7'ar)-7'-acetyl-7'-hydroxy-6'-methyl-7-(2-methylpropanoyloxy)spiro[4,6,7,7a-tetrahydro-3ah-[1,3]dioxolo[4,5-c]pyran-2,4'-6,7a-dihydro-3ah- Chemical compound O([C@H]1[C@H](O)C[C@@H](O[C@@H]1C)O[C@H]1[C@H](O)CC2(O[C@]3(C)C[C@@H](O[C@H](C)[C@H]3O2)O[C@H]2[C@@H](OC)[C@@H](C)O[C@H]([C@@H]2O)O[C@H]2[C@H](O)[C@H](OC)[C@H](OC3[C@@H]([C@@H]4O[C@]5(O[C@H]4CO3)[C@@H]3OCO[C@H]3[C@@](O)([C@@H](C)O5)C(C)=O)OC(=O)C(C)C)O[C@@H]2COC)O[C@@H]1C)C(=O)C1=C(C)C(Cl)=C(O)C(Cl)=C1OC XIRGHRXBGGPPKY-OTPQUNEMSA-N 0.000 description 1
- MSXOVFSZHBOQNC-UHFFFAOYSA-N [6-[(2,6-dichlorophenoxy)methyl]pyridin-2-yl]-(4-methylpiperidin-1-yl)methanone Chemical compound C1CC(C)CCN1C(=O)C1=CC=CC(COC=2C(=CC=CC=2Cl)Cl)=N1 MSXOVFSZHBOQNC-UHFFFAOYSA-N 0.000 description 1
- BKVLGIBPKWJIBY-UHFFFAOYSA-N [6-[(2,6-dichlorophenyl)sulfonylmethyl]pyridin-2-yl]-(4-methylpiperidin-1-yl)methanone Chemical compound C1CC(C)CCN1C(=O)C1=CC=CC(CS(=O)(=O)C=2C(=CC=CC=2Cl)Cl)=N1 BKVLGIBPKWJIBY-UHFFFAOYSA-N 0.000 description 1
- WHDHEVMINMZADQ-UHFFFAOYSA-N [F].N1C=CC=C1 Chemical compound [F].N1C=CC=C1 WHDHEVMINMZADQ-UHFFFAOYSA-N 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- SHURRSUZDBDBMX-JLSLGBNPSA-N avermectin B2a Natural products CC[C@H](C)[C@H]1O[C@@]2(C[C@@H]3C[C@@H](CC=C(/C)[C@@H](O[C@H]4C[C@H](OC)[C@@H](O[C@H]5C[C@H](OC)[C@@H](O)[C@H](C)O5)[C@H](C)O4)[C@@H](C)C=CC=C6/OC[C@@H]7[C@H](O)C(=C[C@@H](C(=O)O3)[C@]67O)C)O2)C[C@@H](O)[C@@H]1C SHURRSUZDBDBMX-JLSLGBNPSA-N 0.000 description 1
- 229960005185 avilamycin Drugs 0.000 description 1
- 235000019379 avilamycin Nutrition 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 229940054066 benzamide antipsychotics Drugs 0.000 description 1
- 150000003936 benzamides Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000003031 feeding effect Effects 0.000 description 1
- 244000053095 fungal pathogen Species 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 230000002438 mitochondrial effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035806 respiratory chain Effects 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide composition containing fluazaindolizine. The pesticide composition comprises an effective component A, an effective component B and common assistants. The effective component A is selected from the fluazaindolizine, and the effective component B is selected from one of abamectin B2, fluopyram and fluensulfone; the weight ratio of the effective component A to the effective component B is 30:1-1:30. The pesticide composition has obvious synergistic interaction in nematodes, pesticide usage is reduced, using cost is low, and environmental pollution is reduced. The pesticide composition is applicable to control of crop nematodosis caused by pathogen nematode.
Description
Technical field
The present invention relates to a kind of composition pesticide, be used for preventing and treating crop nematicide.
Background technology
Avermectin B2 (avermectin B2) is the active component of abamectin fermented generation,
Its main active is avermectin B2a, to root-knot nematode, the multiple nematicide such as Ditylenchus dipsaci,
Parasite has extra high kills activity.
Fluopyram (fluopyram), is a kind of new benzamides series bactericidal agent, logical
Cross and hinder the electron transfer of succinate dehydrogenase in respiratory chain to suppress mitochondrial respiratory, can in case
The crop diseases that control is caused by fungal pathogen, including including fruit, vegetable, Rhizoma Solani tuber osi and flowers
70 various crop on all have application, meanwhile, the nematicide on plant is also had good by it
Prevention effect.
Fluorine alkene line sulfone (fluensulfone), belongs to non-stifling novel nematicide, to each
The nematicide of growth stage all has good prevention effect.The effect side of usual non-fumigating nematicide
Formula is to make nematicide lose ability to act, but after a period of time, nematicide can recover, and fluorine alkene line sulfone is then
It is that nematicide is thoroughly killed.The time of fluorine alkene line sulfone entrance soil is only 12 hours, and other
The time of nematicide entrance soil is typically about 5 days.
Trifluoro miaow pyridine amide (fluazaindolizine), non-stifling property nematicide, to greatly
Soybean cyst nematode Heterodera glycines on bean, root-knot nematode, kidney shape nematicide, the pratylenchus on Semen Maydis, root
Tie lines worm, minute hand nematicide, kidney shape nematicide on Cotton Gossypii, root-knot nematode etc. are respectively provided with fabulous life
Thing activity.
Plant nematode is the pathogenic microorganism that a class is very harmful, and it has a very wide distribution, plants
Class is various, adaptive capacity to environment is strong, can colonize in the root system of plant, stem, leaf, seed,
In plumelet and fruit, by feeding activity host plant can be caused mechanical damage, and rob and post
The nutrition of main plant, especially its esophageal gland secretions can cause host plant that a series of diseases occur
Become, also can jointly infect host plant with other pathogenic microorganism, cause compound disease, cause
Production loss.In the world, the agricultural losses that plant nematode is caused every year are up to
More than 100000000000 dollars, seriously constrain the development of agricultural economy.
It is found by experiment that, by Avermectin B2, fluopyram, fluorine alkene line sulfone and trifluoro
Miaow pyridine amide is used in mixed way the plant pathogeny line insect such as Meloidogyne incognita and soybean cyst nematode Heterodera glycines
There is synergistic function, especially to Root Knot line in 30:1～1:30 proportion
Worm and soybean cyst nematode Heterodera glycines have obvious potentiation.
Summary of the invention
It is an object of the invention to provide a kind of synergetic pesticide composition, preventing for crop nematicide
The prevention and control of control, especially root of the crop Root-knot and Cyst nematode provide one effectively to manage work
Tool.
The present invention is achieved through the following technical solutions: a kind of composition pesticide, including effective ingredient
A and effective ingredient B and usual auxiliaries, wherein effective constituents A is selected from trifluoro miaow pyridine amide,
Effective ingredient B one in Avermectin B2, fluopyram, fluorine alkene line sulfone；Have
The ratio of weight and number of effect composition A and effective ingredient B is 30:1～1:30；Effective constituents A and
Effective ingredient B weight summation percentage by weight in composition pesticide is 0.1%～60%.
Composition pesticide of the present invention adds suitable auxiliary agent, can be made by certain technological means
Become the dosage form that granule, aqueous emulsion, micro-capsule suspension etc. are agriculturally conventional.
Auxiliary agent described in the composition pesticide of the present invention may is that wetting agent, dispersant, helps
Suspension, thickening agent, interleaving agent, defoamer, disintegrating agent, binding agent, filler or filler etc..
It is known substance, is various auxiliary agents conventional in pesticidal preparations, can have according to different situations
Changed, be not particularly limited.
The composition pesticide that the present invention provides, it is adaptable to preventing and treating is by Meloidogyne incognita and Semen sojae atricolor born of the same parents
The crop nematicide that capsule nematicide causes.
The composition pesticide that the present invention provides has the advantages that.
1, the composition pesticide that the present invention provides, shows significantly in certain ratio range
Potentiation, the prevention effect of compositions is significantly improved than single dose, reduces making of pesticide
With dosage, decrease times for spraying, reduce drug cost, decrease pesticide to ecological environment
Adverse effect.
2, the composition pesticide that the present invention provides, two kinds of effective ingredient mechanism of action are different,
Compensate for defect when single dose uses and limitation, long-term single use can be overcome easily to produce
The shortcoming of resistance, extends the service life of medicament, and the comprehensive control to nematode resistance has important
Meaning.
Detailed description of the invention
In order to be more fully understood that the essence of the present invention, below in conjunction with embodiment to present disclosure
Being described further, but can not be considered as limitation of the present invention, the following stated is only used for explaining this
Invention, for the amendment made without departing from present invention spirit and principle, replaces or improves, all belong to
In the scope of protection of present invention.
Embodiment one: Toxicity Determination
According to the abundant method of Sun Yun, evaluate the collaborative work of pharmacy mix according to co-toxicity coefficient (CTC)
With, i.e. CTC≤80 are joint action of antagonism, and 80 ＜ CTC ＜ 120 are joint action of antagonism,
CTC >=120 are synergistic function.Actual measurement toxicity index (ATI)=(EC of standard agent50/
The EC of reagent agent50)×100；The toxicity index of theoretical toxicity index TTI=A medicament × mixed
In agent, in the toxicity index × mixture of the percentage composition+B medicament of A medicament, the percentage of B medicament contains
Amount；Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theory virulence refers to
Number (TTI)] × 100.
1, Avermectin B2 trifluoro miaow pyridine amide is to Meloidogyne incognita (Meloidogyne
Incongnita Chitwood) Toxicity Determination, subjects picks up from the Fructus Cucumidis sativi in field
Root knot nematode disease insect gall use the graceful funnel of shellfish send out the Meloidogyne incognita separated
(Meloidogyne incongnita Chitwood)。
Table 1, Avermectin B2 trifluoro miaow pyridine amide are to Meloidogyne incognita
The Toxicity Determination result of (Meloidogyne incongnita Chitwood)
As shown in Table 1, Avermectin B2 and trifluoro miaow pyridine amide mixed ratio are at 30:1～1:30
Between, Meloidogyne incognita (Meloidogyne incongnita Chitwood) is had bright
Aobvious potentiation, co-toxicity coefficient is all more than 150；Avermectin B2 and trifluoro miaow pyridine acyl
Amine mixture between 20:1～1:20 to Meloidogyne incognita (Meloidogyne incongnita
Chitwood) having obvious potentiation, co-toxicity coefficient is all more than 200；Avilamycin
B2 and trifluoro miaow pyridine amide mixture between 10:1～1:10 to Meloidogyne incognita
(Meloidogyne incongnita Chitwood) has obvious potentiation, altogether poison system
Number is all more than 220.
2, Avermectin B2 trifluoro miaow pyridine amide is to soy bean cyst roundworm (Heterodera
Glycines Ichinohe) Toxicity Determination, subjects picks up from the Semen sojae atricolor cyst in field
Nematicide insect gall use the graceful funnel of shellfish send out the soy bean cyst roundworm (Heterodera separated
glycines Ichinohe)。
Table 2, Avermectin B2 trifluoro miaow pyridine amide are to soy bean cyst roundworm
The Toxicity Determination result of (Heterodera glycines Ichinohe)
As shown in Table 2, Avermectin B2 and trifluoro miaow pyridine amide mixed ratio are at 30:1～1:30
Between, soy bean cyst roundworm (Heterodera glycines Ichinohe) is had substantially
Potentiation, co-toxicity coefficient is all more than 170；Azoles phosphine and trifluoro miaow pyridine amide mixture exist
Between 20:1～1:20, to soy bean cyst roundworm (Heterodera glycines Ichinohe)
Having obvious potentiation, co-toxicity coefficient is all more than 200；Azoles phosphine and trifluoro miaow pyridine amide
Mixture is between 10:1～1:10, to soy bean cyst roundworm (Heterodera glycines
Ichinohe) having obvious potentiation, co-toxicity coefficient is all more than 220.
3, fluopyram trifluoro miaow pyridine amide is to Meloidogyne incognita (Meloidogyne
Incongnita Chitwood) Toxicity Determination, subjects picks up from the Fructus Cucumidis sativi in field
Root knot nematode disease insect gall use the graceful funnel of shellfish send out the Meloidogyne incognita separated
(Meloidogyne incongnita Chitwood)。
Table 3, fluopyram trifluoro miaow pyridine amide are to Meloidogyne incognita
The Toxicity Determination result of (Meloidogyne incongnita Chitwood)
As shown in Table 3, fluopyram and trifluoro miaow pyridine amide mixed ratio are at 30:1～1:30
Between, Meloidogyne incognita (Meloidogyne incongnita Chitwood) is had bright
Aobvious potentiation, co-toxicity coefficient is all more than 160；Fluopyram and trifluoro miaow pyridine amide
Mixture between 20:1～1:20 to Meloidogyne incognita (Meloidogyne incongnita
Chitwood) having obvious potentiation, co-toxicity coefficient is all more than 200；Fluorine pyrrole bacterium acyl
Amine and trifluoro miaow pyridine amide mixture between 10:1～1:10 to Meloidogyne incognita
(Meloidogyne incongnita Chitwood) has obvious potentiation, altogether poison system
Number is all more than 220.
4, fluopyram trifluoro miaow pyridine amide is to soy bean cyst roundworm (Heterodera
Glycines Ichinohe) Toxicity Determination, subjects picks up from the Semen sojae atricolor cyst in field
Nematicide insect gall use the graceful funnel of shellfish send out the soy bean cyst roundworm (Heterodera separated
glycines Ichinohe)。
Table 4, fluopyram trifluoro miaow pyridine amide are to soy bean cyst roundworm
The Toxicity Determination result of (Heterodera glycines Ichinohe)
As shown in Table 4, fluopyram and trifluoro miaow pyridine amide mixed ratio are at 30:1～1:30
Between, soy bean cyst roundworm (Heterodera glycines Ichinohe) is had substantially
Potentiation, co-toxicity coefficient is all more than 170；Fluopyram is mixed with trifluoro miaow pyridine amide
Fit between 20:1～1:20, to soy bean cyst roundworm (Heterodera glycines
Ichinohe) having obvious potentiation, co-toxicity coefficient is all more than 200；Fluorine pyrrole bacterium acyl
Amine and trifluoro miaow pyridine amide mixture are between 10:1～1:10, to soy bean cyst roundworm
(Heterodera glycines Ichinohe) has obvious potentiation, co-toxicity coefficient
All more than 220.
5, fluorine alkene line sulfone trifluoro miaow pyridine amide is to Meloidogyne incognita (Meloidogyne
Incongnita Chitwood) Toxicity Determination, subjects picks up from the Fructus Cucumidis sativi in field
Root knot nematode disease insect gall use the graceful funnel of shellfish send out the Meloidogyne incognita separated
(Meloidogyne incongnita Chitwood)。
Table 5, fluorine alkene line sulfone trifluoro miaow pyridine amide are to Meloidogyne incognita
The Toxicity Determination result of (Meloidogyne incongnita Chitwood)
As shown in Table 5, fluorine alkene line sulfone and trifluoro miaow pyridine amide mixed ratio are at 30:1～1:30
Between, Meloidogyne incognita (Meloidogyne incongnita Chitwood) is had bright
Aobvious potentiation, co-toxicity coefficient is all more than 170；Fluorine alkene line sulfone mixes with trifluoro miaow pyridine amide
Fit between 20:1～1:20 Meloidogyne incognita (Meloidogyne incongnita
Chitwood) having obvious potentiation, co-toxicity coefficient is all more than 200；Fluorine alkene line sulfone
And trifluoro miaow pyridine amide mixture between 10:1～1:10 to Meloidogyne incognita
(Meloidogyne incongnita Chitwood) has obvious potentiation, altogether poison system
Number is all more than 220.
6, fluorine alkene line sulfone trifluoro miaow pyridine amide is to soy bean cyst roundworm (Heterodera
Glycines Ichinohe) Toxicity Determination, subjects picks up from the Semen sojae atricolor cyst in field
Nematicide insect gall use the graceful funnel of shellfish send out the soy bean cyst roundworm (Heterodera separated
glycines Ichinohe)。
Table 6, fluorine alkene line sulfone trifluoro miaow pyridine amide are to soy bean cyst roundworm
The Toxicity Determination result of (Heterodera glycines Ichinohe)
As shown in Table 6, fluorine alkene line sulfone and trifluoro miaow pyridine amide mixed ratio are at 30:1～1:30
Between, soy bean cyst roundworm (Heterodera glycines Ichinohe) is had substantially
Potentiation, co-toxicity coefficient is all more than 160；Fluorine alkene line sulfone and trifluoro miaow pyridine amide mixture
Between 20:1～1:20, to soy bean cyst roundworm (Heterodera glycines
Ichinohe) having obvious potentiation, co-toxicity coefficient is all more than 200；Fluorine alkene line sulfone
And trifluoro miaow pyridine amide mixture is between 10:1～1:10, to soy bean cyst roundworm
(Heterodera glycines Ichinohe) has obvious potentiation, co-toxicity coefficient
All more than 220.
Embodiment 2:12% Avermectin B2 trifluoro miaow pyridine amide micro-capsule suspension
Following material is weight ratio: weigh the 2% former medicine of Avermectin B2,10% trifluoro miaow pyridine
The former medicine of amide, is dissolved in 15%600# solvent naphtha, adds 1.5% agriculture breast 33# and 7% diphenyl
Methane diisocyanate, is uniformly mixed as oil phase；7% polyvinyl alcohol water solution is added
Suitable quantity of water is stirred for aqueous phase；Oil phase and aqueous phase are mixed, exists by high-shear emulsion machine
Emulsification pretreatment under the conditions of 10000 turns every point, forms uniform emulsion, under 500 turns every point stirring
1% glycerol is the most uniformly dripped into emulsion, within 80 minutes, drips, 25 DEG C of water-baths, 500
Turn every point of lower reaction of stirring 4 hours, be warmed up to 60 DEG C and solidify 2 hours, add 2% I
Primary glue solution, 1% polycarboxylate salt dispersant and 4% ethylene glycol, regulation pH is neutral, spends
Ionized water supplies 100% weight portion, obtains the 12% Avermectin B2 trifluoro miaow micro-glue of pyridine amide
Capsule suspending agent.
Use above-mentioned 12% Avermectin B2 trifluoro miaow pyridine amide micro-capsule suspension for preventing and treating
Fructus Cucumidis sativi root-knot nematode, dosage 240g a.i./ha, after medicine, 60 days preventive effects are 92.9%；2%
Avermectin B2 micro-capsule suspension dosage 40g a.i./ha, 10% trifluoro miaow pyridine amide are micro-
Capsule suspension dosage 200g a.i./ha, after medicine 60 days preventive effects be respectively 79.1%,
81.2%.
Embodiment 3:22% fluopyram B2 trifluoro miaow pyridine amide micro-capsule suspension
Following material is weight ratio: weigh the 2% former medicine of fluopyram, 20% trifluoro miaow pyridine acyl
The former medicine of amine, is dissolved in 15%600# solvent naphtha, adds 2% agriculture breast 33# and 5% diphenyl methane
Diisocyanate, is uniformly mixed as oil phase；10% polyvinyl alcohol water solution is added appropriate
Water is stirred for aqueous phase；Oil phase and aqueous phase are mixed, by high-shear emulsion machine 10000
Emulsification pretreatment under the conditions of turning every point, forms uniform emulsion, by 1% under 500 turns every point stirring
Ethylenediamine the most uniformly drips into emulsion, within 40 minutes, drips, 25 DEG C of water-baths, 500 turns
Reaction 4 hours under every point of stirring, is warmed up to 60 DEG C and solidifies 2 hours, add 1% Arabic
Glue solution, 2% polycarboxylate salt dispersant, 1% alkylphenol polyoxyethylene and 4% ethylene glycol,
Regulation pH is neutral, supplies 100% weight portion with deionized water, obtains 22% fluopyram
B2 trifluoro miaow pyridine amide micro-capsule suspension.
Use above-mentioned 22% fluopyram B2 trifluoro miaow pyridine amide micro-capsule suspension for preventing
Controlling Fructus Capsici root-knot nematode, dosage 220g a.i./ha, after medicine, 60 days preventive effects are 90.5%；
2% fluopyram micro-capsule suspension dosage 20g a.i./ha, 10% trifluoro miaow pyridine amide
Micro-capsule suspension dosage 200g a.i./ha, after medicine 60 days preventive effects be respectively 78.2%,
82.3%.
Embodiment 4:24% fluorine alkene line sulfone trifluoro miaow pyridine amide micro-capsule suspension
Following material is weight ratio: weigh the 6% former medicine of Avermectin B2,18% trifluoro miaow pyridine
The former medicine of amide, is dissolved in 14%600# solvent naphtha, adds 3.5% agriculture breast 33# and 5% diphenyl
Methane diisocyanate, is uniformly mixed as oil phase；15% polyvinyl alcohol water solution is added
Suitable quantity of water is stirred for aqueous phase；Oil phase and aqueous phase are mixed, exists by high-shear emulsion machine
Emulsification pretreatment under the conditions of 10000 turns every point, forms uniform emulsion, under 500 turns every point stirring
1% ethylenediamine is the most uniformly dripped into emulsion, within 40 minutes, drips, 25 DEG C of water-baths, 500
Turn every point of lower reaction of stirring 4 hours, be warmed up to 60 DEG C and solidify 2 hours, add 1% I
Primary glue solution, 2% polycarboxylate salt dispersant, 1% alkylphenol polyoxyethylene and 4% ethylene glycol,
Regulation pH is neutral, supplies 100% weight portion with deionized water, just can get 24% trifluoro miaow
Pyridine amide fluorine alkene line sulfone micro-capsule suspension.
Use above-mentioned 24% fluorine alkene line sulfone trifluoro miaow pyridine amide micro-capsule suspension big for preventing and treating
Bean Cyst nematode, dosage 240g a.i./ha, after medicine, 60 days preventive effects are 85.1%；6% fluorine
Alkene line sulfone micro-capsule suspension dosage 60g a.i./ha, 10% trifluoro miaow pyridine amide microcapsule
Suspending agent dosage 180g a.i./ha, after medicine, 60 days preventive effects are respectively 70.2%, 78.3%.
Embodiment 5:20% trifluoro miaow pyridine amide Avermectin B2 aqueous emulsion
Following material is weight ratio: weigh 5% Avermectin B2,15% trifluoro miaow pyridine acyl
Amine, 12% agriculture breast 2201#, 10%BBM-3,1% epoxychloropropane, 2% ethylene glycol, 5
% dimethylbenzene, 0.3% arabic gum, 0.5% benzoic acid, surplus is deionized water.Above-mentioned former
Expecting blended, high speed shear emulsifying prepares 20% trifluoro miaow pyridine amide Avermectin B2 water and milk
Agent.
Use above-mentioned 20% trifluoro miaow pyridine amide Avermectin B2 aqueous emulsion for preventing and treating Kidney bean
Cyst nematode disease, dosage 200g a.i./ha, after medicine, 60 days preventive effects are 89.1%；5% Ah
Dimension rhzomorph B2 aqueous emulsion dosage 50g a.i./ha, 15% trifluoro miaow pyridine amide aqueous emulsion medication
Amount 150g a.i./ha, after medicine, 60 days preventive effects are respectively 78.6%, 78.9%.
Embodiment 6:20% trifluoro miaow pyridine amide fluopyram aqueous emulsion
Following material is weight ratio: weigh 10% fluopyram, 10% trifluoro miaow pyridine amide,
15% agriculture breast 2201#, 11%BBM-3,1.5% epoxychloropropane, 1% ethylene glycol, 5% 2
Toluene, 0.3% arabic gum, 0.5% benzoic acid, surplus is deionized water.Above-mentioned raw materials warp
Mixing, high speed shear emulsifying prepares 20% trifluoro miaow pyridine amide fluopyram aqueous emulsion.
Use above-mentioned 20% trifluoro miaow pyridine amide fluopyram aqueous emulsion for preventing and treating Roots of Peanut
Tie lines worm, dosage 300g a.i./ha, after medicine, 60 days preventive effects are 87.3%；10% fluorine pyrrole bacterium
Amide aqueous emulsion dosage 150g a.i./ha, 10% trifluoro miaow pyridine amide aqueous emulsion dosage
150g a.i./ha, after medicine, 60 days preventive effects are respectively 76.3%, 84.8%.
Embodiment 7:18% fluorine alkene line sulfone trifluoro miaow pyridine amide aqueous emulsion
Following material is weight ratio: weigh 3% fluorine alkene line sulfone, 15% trifluoro miaow pyridine amide,
15% agriculture breast 2201#, 12%BBM-3,2% epoxychloropropane, 1% ethylene glycol, 5% diformazan
Benzene, 0.1% arabic gum, 0.5% benzoic acid, surplus is deionized water.Above-mentioned raw materials is through mixed
Closing, high speed shear emulsifying prepares 18% trifluoro miaow pyridine amide fluorine alkene line sulfone aqueous emulsion.
Use above-mentioned 18% fluorine alkene line sulfone trifluoro miaow pyridine amide aqueous emulsion for preventing and treating Semen vignae sinensis cyst
Nematicide, dosage 240g a.i./ha, after medicine, 60 days preventive effects are 94.4%；3% fluorine alkene line sulfone
Aqueous emulsion dosage 40g a.i./ha, 15% trifluoro miaow pyridine amide aqueous emulsion dosage 200g
A.i./ha, after medicine, 60 days preventive effects are respectively 79.4%, 85.7%.
Embodiment 8:8% trifluoro miaow pyridine amide Avermectin B2 granule
Following material is weight ratio: weigh 1% Avermectin B2,7% trifluoro miaow pyridine amide,
5% sodium lignin sulfonate, 5% polyvinylpyrrolidone, 4% glucose, 5% corn starch, 2%
Rice chaff, surplus attapulgite.Above-mentioned raw materials is mix homogeneously in mixed cylinder, through extruding, makes
Grain, it is dried, and screened step prepares 8% trifluoro miaow pyridine amide Avermectin B2 granule.
Use above-mentioned 8% trifluoro miaow pyridine amide Avermectin B2 granule for preventing and treating tomato root
Tie lines worm, dosage 240g a.i./ha, after medicine, 60 days preventive effects are 93.8%；1% Avermectin
Element B2 granule dosage 30g a.i./ha, 7% trifluoro miaow pyridine amide granule dosage 210g
A.i./ha, after medicine, 60 days preventive effects are respectively 84.8%, 79.2%.
Embodiment 9:4% trifluoro miaow pyridine amide fluopyram granule
Following material is weight ratio: weigh 1% fluopyram, 3% trifluoro miaow pyridine amide,
8% sodium lignin sulfonate, 7% polyvinylpyrrolidone, 5% glucose, 4% corn starch, 4%
Rice chaff, surplus attapulgite.Above-mentioned raw materials is mix homogeneously in mixed cylinder, through extruding, makes
Grain, it is dried, and screened step prepares 4% trifluoro miaow pyridine amide fluopyram granule.
Use above-mentioned 4% trifluoro miaow pyridine amide fluopyram granule for preventing and treating Radix Momordicae Charantiae
Tie lines worm, dosage 240g a.i./ha, after medicine, 60 days preventive effects are 96.6%；3% trifluoro miaow
Pyridine amide granule dosage 180g a.i./ha, 1% fluopyram granule dosage 60g
A.i./ha, after medicine, 60 days preventive effects are respectively 79.5%, 88.0%.
Embodiment 10:2% fluorine alkene line sulfone trifluoro miaow pyridine amide granule
Following material is weight ratio: weigh 1% fluorine alkene line sulfone, 1% trifluoro miaow pyridine amide, 7%
Sodium lignin sulfonate, 5% polyvinylpyrrolidone, 6% glucose, 4% corn starch, 3% rice chaff,
Surplus attapulgite.Above-mentioned raw materials is mix homogeneously in mixed cylinder, through extruding, pelletize, does
Dry, and screened step prepares 2% trifluoro miaow pyridine amide fluorine alkene line sulfone granule.
Use above-mentioned 2% fluorine alkene line sulfone trifluoro miaow pyridine amide granule for preventing and treating jujube tree root knot
Nematicide, dosage 300g a.i./ha, after medicine, 60 days preventive effects are 95.2%；1% fluorine alkene line sulfone
Granule dosage 150g a.i./ha, 1% trifluoro miaow pyridine amide granule dosage 150g
A.i./ha, after medicine, 60 days preventive effects are respectively 85.3%, 87.4%.
Claims (6)
1. the composition pesticide containing trifluoro miaow pyridine amide, it is characterised in that: include effectively
Composition A and effective ingredient B and usual auxiliaries, wherein effective constituents A is selected from trifluoro miaow pyridine acyl
Amine, effective ingredient B one in Avermectin B2, fluopyram, fluorine alkene line sulfone；
The ratio of weight and number of effective constituents A and effective ingredient B is 30:1～1:30, effective constituents A
It is 0.1%～60% with effective ingredient B weight summation percentage by weight in composition pesticide.
Composition pesticide containing trifluoro miaow pyridine amide the most according to claim 1, its
It is characterised by: the ratio of weight and number of effective constituents A and effective ingredient B is 20:1～1:20.
Composition pesticide containing trifluoro miaow pyridine amide the most according to claim 1, its
It is characterised by: the ratio of weight and number of effective constituents A and effective ingredient B is 10:1～1:10.
Composition pesticide containing trifluoro miaow pyridine amide the most according to claim 1, its
It is characterised by: the ratio of weight and number of effective constituents A and effective ingredient B is 1:3.
Composition pesticide containing trifluoro miaow pyridine amide the most according to claim 1, its
Be characterised by: described composition pesticide adds appropriate auxiliary agent be processed into granule, aqueous emulsion,
Micro-capsule suspension.
6. the composition pesticide containing trifluoro miaow pyridine amide described in claim 1 is made in preventing and treating
The application of thing nematicide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610266341.2A CN105901003A (en) | 2016-04-25 | 2016-04-25 | Pesticide composition containing fluazaindolizine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610266341.2A CN105901003A (en) | 2016-04-25 | 2016-04-25 | Pesticide composition containing fluazaindolizine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105901003A true CN105901003A (en) | 2016-08-31 |
Family
ID=56753424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610266341.2A Withdrawn CN105901003A (en) | 2016-04-25 | 2016-04-25 | Pesticide composition containing fluazaindolizine |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105901003A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106165691A (en) * | 2016-07-22 | 2016-11-30 | 深圳诺普信农化股份有限公司 | Nematicidal composition |
| CN106359413A (en) * | 2016-08-31 | 2017-02-01 | 冯涵丽 | Insecticide composition containing fluorine thiamethoxam sulfone and trifluoro-pyrimidine amide |
| CN106900725A (en) * | 2017-02-16 | 2017-06-30 | 广东真格生物科技有限公司 | A kind of nematicidal composition containing trifluoro miaow pyridine acid amides and ivermectin |
| CN107568218A (en) * | 2017-08-08 | 2018-01-12 | 河北兴柏农业科技有限公司 | A kind of Avermectin B2 micro-capsule suspension and preparation method thereof |
| CN112244023A (en) * | 2020-09-22 | 2021-01-22 | 广东真格生物科技有限公司 | Nanoemulsion preparation containing triflumidine amide and preparation method thereof |
| CN112314608A (en) * | 2020-09-29 | 2021-02-05 | 广东真格生物科技有限公司 | Pesticide composition containing fluxapyroxad and application thereof |
| CN112493237A (en) * | 2019-09-16 | 2021-03-16 | 山东省联合农药工业有限公司 | Pesticide composition containing cinnamaldehyde and preparation method and application thereof |
| WO2021051244A1 (en) * | 2019-09-16 | 2021-03-25 | 山东省联合农药工业有限公司 | Cinnamaldehyde-containing pesticide composition, preparation method therefor and use thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103188934A (en) * | 2010-10-18 | 2013-07-03 | 纳幕尔杜邦公司 | Nematocidal sulfonamides |
| CN104903318A (en) * | 2013-01-14 | 2015-09-09 | 纳幕尔杜邦公司 | Preparation of Nematocidal Sulfonamide |
| CN105175413A (en) * | 2011-10-13 | 2015-12-23 | 纳幕尔杜邦公司 | Solid Forms Of Nematocidal Sulfonamides |
-
2016
- 2016-04-25 CN CN201610266341.2A patent/CN105901003A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103188934A (en) * | 2010-10-18 | 2013-07-03 | 纳幕尔杜邦公司 | Nematocidal sulfonamides |
| CN105175413A (en) * | 2011-10-13 | 2015-12-23 | 纳幕尔杜邦公司 | Solid Forms Of Nematocidal Sulfonamides |
| CN104903318A (en) * | 2013-01-14 | 2015-09-09 | 纳幕尔杜邦公司 | Preparation of Nematocidal Sulfonamide |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106165691A (en) * | 2016-07-22 | 2016-11-30 | 深圳诺普信农化股份有限公司 | Nematicidal composition |
| CN106359413A (en) * | 2016-08-31 | 2017-02-01 | 冯涵丽 | Insecticide composition containing fluorine thiamethoxam sulfone and trifluoro-pyrimidine amide |
| CN106900725A (en) * | 2017-02-16 | 2017-06-30 | 广东真格生物科技有限公司 | A kind of nematicidal composition containing trifluoro miaow pyridine acid amides and ivermectin |
| CN107568218A (en) * | 2017-08-08 | 2018-01-12 | 河北兴柏农业科技有限公司 | A kind of Avermectin B2 micro-capsule suspension and preparation method thereof |
| CN112493237A (en) * | 2019-09-16 | 2021-03-16 | 山东省联合农药工业有限公司 | Pesticide composition containing cinnamaldehyde and preparation method and application thereof |
| WO2021051244A1 (en) * | 2019-09-16 | 2021-03-25 | 山东省联合农药工业有限公司 | Cinnamaldehyde-containing pesticide composition, preparation method therefor and use thereof |
| CN112244023A (en) * | 2020-09-22 | 2021-01-22 | 广东真格生物科技有限公司 | Nanoemulsion preparation containing triflumidine amide and preparation method thereof |
| CN112314608A (en) * | 2020-09-29 | 2021-02-05 | 广东真格生物科技有限公司 | Pesticide composition containing fluxapyroxad and application thereof |
| CN112314608B (en) * | 2020-09-29 | 2022-04-26 | 广东真格生物科技有限公司 | Pesticide composition containing fluxapyroxad and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105901003A (en) | Pesticide composition containing fluazaindolizine | |
| CN104855392B (en) | A kind of nematicidal composition | |
| CN101642131A (en) | Pesticide composition | |
| CN106986683A (en) | A kind of medicine fertilizer | |
| CN105076185A (en) | Insecticide composition with chlorfenapyr and neonicotinoid insecticides, and preparation and application of insecticide composition | |
| CN104430477A (en) | Pesticide composition containing fluensulfone and neonicotinoid insecticide | |
| CN106172444A (en) | Composition pesticide containing Avermectin B2 | |
| CN105594705A (en) | Pesticide composition containing fluazinam and fluopyram | |
| CN103651563B (en) | A kind of Fungicidal insecticidal composition containing brassin lactones | |
| CN101755828A (en) | Pesticidal composition containing flubendiamide and chlorpyrifos | |
| CN115530173B (en) | Synergistic pesticide for preventing and treating sugarcane borer | |
| CN103404530B (en) | Insecticide compound and application and preparation thereof | |
| CN106035334A (en) | Pesticidal composition containing amino-oligosaccharin and fludioxonil | |
| CN101444221B (en) | Composite containing oxadiazines and pyrromonazole pesticide | |
| CN104585224A (en) | Pesticide composition containing fluensulfone and pyrethroid insecticide | |
| CN105454238A (en) | Pesticide composition containing flupyradifurone and fluopyram | |
| CN111096330A (en) | Emulsion in water containing phenthoate and emamectin benzoate | |
| CN104982436A (en) | Insecticidal composition containing niclosamide and neonicotinoid pesticide | |
| CN107771859A (en) | A kind of containing fluopyram and the nematicide of bacillus subtilis | |
| CN105076168A (en) | Pesticide composition containing albendazole and fluopyram | |
| CN108174858A (en) | A kind of nematicidal composition containing fluorine thiophene worm sulfone | |
| CN101444213A (en) | Desinsection composite and application thereof | |
| CN103719149B (en) | A kind of Fungicidal insecticidal composition containing ZEN 90160 | |
| CN103651561B (en) | A kind of Fungicidal insecticidal composition containing fenhexamid | |
| CN108432762A (en) | A kind of nematicidal composition containing S-Ethyl ethylthio sulfonate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20160831 |
|
| WW01 | Invention patent application withdrawn after publication |